CN103922358A - 高岭石纳米管的制备方法 - Google Patents
高岭石纳米管的制备方法 Download PDFInfo
- Publication number
- CN103922358A CN103922358A CN201410181535.3A CN201410181535A CN103922358A CN 103922358 A CN103922358 A CN 103922358A CN 201410181535 A CN201410181535 A CN 201410181535A CN 103922358 A CN103922358 A CN 103922358A
- Authority
- CN
- China
- Prior art keywords
- kaolinite
- nanotube
- intercalator
- macromole
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910052622 kaolinite Inorganic materials 0.000 title claims abstract description 60
- 239000002071 nanotube Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000009830 intercalation Methods 0.000 claims abstract description 36
- 230000002687 intercalation Effects 0.000 claims abstract description 36
- 150000001875 compounds Chemical class 0.000 claims abstract description 32
- 239000012065 filter cake Substances 0.000 claims abstract description 21
- 238000003756 stirring Methods 0.000 claims abstract description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000138 intercalating agent Substances 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000000706 filtrate Substances 0.000 claims abstract description 7
- 238000002386 leaching Methods 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 230000009471 action Effects 0.000 claims description 14
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 9
- -1 kaolinite small molecules Chemical class 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 150000003384 small molecules Chemical class 0.000 claims description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 5
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 4
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 18
- 230000008569 process Effects 0.000 abstract description 12
- 238000005265 energy consumption Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 2
- 229920002521 macromolecule Polymers 0.000 abstract 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 28
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 17
- 239000000203 mixture Substances 0.000 description 9
- 239000005995 Aluminium silicate Substances 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- 235000013877 carbamide Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000446313 Lamella Species 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 1
- 239000003937 drug carrier Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410181535.3A CN103922358B (zh) | 2014-05-04 | 2014-05-04 | 高岭石纳米管的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410181535.3A CN103922358B (zh) | 2014-05-04 | 2014-05-04 | 高岭石纳米管的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103922358A true CN103922358A (zh) | 2014-07-16 |
CN103922358B CN103922358B (zh) | 2016-03-16 |
Family
ID=51140795
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410181535.3A Active CN103922358B (zh) | 2014-05-04 | 2014-05-04 | 高岭石纳米管的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103922358B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109502597A (zh) * | 2018-12-16 | 2019-03-22 | 桂林理工大学 | 一种高岭石纳米管的制备方法 |
CN109619100A (zh) * | 2018-12-07 | 2019-04-16 | 国际竹藤中心 | 一种埃洛石纳米管/季铵盐复合抗菌微粒及其制备方法和用途 |
CN110156035A (zh) * | 2019-07-03 | 2019-08-23 | 南京大学 | 一种高岭土纳米管制法 |
CN112044405A (zh) * | 2020-08-31 | 2020-12-08 | 宜兴国际环保城科技发展有限公司 | 一种医药废水处理剂及其制备方法 |
CN115160646A (zh) * | 2022-06-27 | 2022-10-11 | 北京理工大学 | 一种改性高岭石及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058425A (zh) * | 2006-04-21 | 2007-10-24 | 同济大学 | 一种制备纳米级片状高岭石的方法 |
CN101104517A (zh) * | 2006-07-14 | 2008-01-16 | 同济大学 | 一种制备高岭石有机插层复合物的新方法 |
CN102167346A (zh) * | 2011-01-30 | 2011-08-31 | 福州大学 | 一种高岭土纳米管及其制备方法 |
CN102602951A (zh) * | 2012-03-22 | 2012-07-25 | 天津大学 | 高岭土纳米管制备方法 |
CN103210020A (zh) * | 2010-10-25 | 2013-07-17 | 应用矿物公司 | 用于聚乙烯的成核剂 |
-
2014
- 2014-05-04 CN CN201410181535.3A patent/CN103922358B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058425A (zh) * | 2006-04-21 | 2007-10-24 | 同济大学 | 一种制备纳米级片状高岭石的方法 |
CN101104517A (zh) * | 2006-07-14 | 2008-01-16 | 同济大学 | 一种制备高岭石有机插层复合物的新方法 |
CN103210020A (zh) * | 2010-10-25 | 2013-07-17 | 应用矿物公司 | 用于聚乙烯的成核剂 |
CN102167346A (zh) * | 2011-01-30 | 2011-08-31 | 福州大学 | 一种高岭土纳米管及其制备方法 |
CN102602951A (zh) * | 2012-03-22 | 2012-07-25 | 天津大学 | 高岭土纳米管制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109619100A (zh) * | 2018-12-07 | 2019-04-16 | 国际竹藤中心 | 一种埃洛石纳米管/季铵盐复合抗菌微粒及其制备方法和用途 |
CN109619100B (zh) * | 2018-12-07 | 2019-11-01 | 国际竹藤中心 | 一种埃洛石纳米管/季铵盐复合抗菌微粒及其制备方法和用途 |
CN109502597A (zh) * | 2018-12-16 | 2019-03-22 | 桂林理工大学 | 一种高岭石纳米管的制备方法 |
CN110156035A (zh) * | 2019-07-03 | 2019-08-23 | 南京大学 | 一种高岭土纳米管制法 |
CN112044405A (zh) * | 2020-08-31 | 2020-12-08 | 宜兴国际环保城科技发展有限公司 | 一种医药废水处理剂及其制备方法 |
CN112044405B (zh) * | 2020-08-31 | 2023-03-14 | 宜兴国际环保城科技发展有限公司 | 一种医药废水处理剂及其制备方法 |
CN115160646A (zh) * | 2022-06-27 | 2022-10-11 | 北京理工大学 | 一种改性高岭石及其制备方法 |
CN115160646B (zh) * | 2022-06-27 | 2024-01-26 | 北京理工大学 | 一种改性高岭石及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103922358B (zh) | 2016-03-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103922358B (zh) | 高岭石纳米管的制备方法 | |
CN104307552B (zh) | TiO2/g‑C3N4复合可见光催化剂的制备方法 | |
Su et al. | Decoration of TiO 2/gC 3 N 4 Z-scheme by carbon dots as a novel photocatalyst with improved visible-light photocatalytic performance for the degradation of enrofloxacin | |
CN107540019B (zh) | 一种制备二硫化钼/石墨烯交替插层结构材料的方法 | |
CN108889324B (zh) | 一种二硫化钼-氮化碳光催化复合材料的合成方法 | |
CN103787348A (zh) | 一种高岭土/1-丁基-3-甲基溴化咪唑插层纳米复合材料的制备方法 | |
CN106378065A (zh) | 壳聚糖‑氧化石墨烯中空微胶囊的制备方法 | |
CN105905940B (zh) | 一种钛酸镍/二氧化钛复合纳米材料的制备方法 | |
CN105350113B (zh) | 一种氮化碳纳米纤维的制备方法及所得产品 | |
CN105502373A (zh) | 一种石墨烯的绿色制备方法 | |
CN103801298A (zh) | 石墨烯负载镍纳米粒子复合材料的水热快速合成法 | |
CN109174130B (zh) | 一种二维面面SnS2-MoS2复合物的制备方法 | |
CN104043471A (zh) | 一种石墨烯/Ta3N5复合光催化剂的制备方法 | |
CN104801308A (zh) | 一种NiFe2O4/TiO2/海泡石复合光催化剂及其制备方法 | |
CN110180526B (zh) | 一种光催化剂Li2SnO3的制备方法及其在降解抗生素中的运用 | |
CN103801354B (zh) | 一种后退火处理的石墨相氮化碳空心球可见光催化剂 | |
CN105457656A (zh) | 一种异质结光催化剂的制备方法和用途 | |
CN107930633A (zh) | 一种新型SrTiO3/Cu2O结复合纳米材料的制备方法及应用 | |
CN102951671B (zh) | 一种氧化铜纳米粒子的制备方法 | |
CN108295886A (zh) | 一种ZnO-C3N4-CQDs可见光催化复合材料及其制备方法 | |
CN104826641B (zh) | 一种多孔类石墨型氮化碳的制备方法 | |
CN110560164A (zh) | 一种聚多巴胺包覆的C3N4/MXene复合材料及其制备方法 | |
CN102951662B (zh) | 一种α型纳米三氧化二铝粒子的制备方法 | |
CN104402011A (zh) | 高岭土纳米管的制备方法 | |
CN105668607B (zh) | 一种纳米片状硫化铜材料的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Yude Inventor after: Zhang Qian Inventor after: Zhang Baimei Inventor after: Liu Qinfu Inventor after: Zhao Jifen Inventor after: Lu Yinping Inventor after: Wang Yan Inventor before: Zhang Qian Inventor before: Zhang Baimei Inventor before: Liu Qinfu Inventor before: Zhao Jifen Inventor before: Zhang Yude Inventor before: Lu Yinping Inventor before: Wang Yan |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160214 Address after: 454003 School of materials, Henan Polytechnic University, 2001 Century Avenue, Henan, Jiaozuo Applicant after: Zhang Yude Address before: 454001 No. 2001 Century Avenue, Henan, Jiaozuo Applicant before: Zhang Qian |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190619 Address after: 214400 Fengming Road, Huangtang, Xuxiake Town, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Wuxi Feiler Powder Material Co., Ltd. Address before: 454003 College of Materials, Henan University of Technology, 2001 Century Avenue, Jiaozuo City, Henan Province Patentee before: Zhang Yude |
|
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 214400 Fengming Road, Huangtang, Xuxiake Town, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Wuxi Feile high performance materials Co., Ltd Address before: 214400 Fengming Road, Huangtang, Xuxiake Town, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Wuxi Feiler Powder Material Co., Ltd. |