CN103233226A - 一种氧化钛-羟基磷灰石复合层及其构建方法 - Google Patents
一种氧化钛-羟基磷灰石复合层及其构建方法 Download PDFInfo
- Publication number
- CN103233226A CN103233226A CN2013101244032A CN201310124403A CN103233226A CN 103233226 A CN103233226 A CN 103233226A CN 2013101244032 A CN2013101244032 A CN 2013101244032A CN 201310124403 A CN201310124403 A CN 201310124403A CN 103233226 A CN103233226 A CN 103233226A
- Authority
- CN
- China
- Prior art keywords
- titanium
- metal
- titanium oxide
- hydroxyapatite composite
- composite bed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052588 hydroxylapatite Inorganic materials 0.000 title claims abstract description 58
- 239000002131 composite material Substances 0.000 title claims abstract description 51
- 238000010276 construction Methods 0.000 title claims abstract description 30
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 118
- 239000010936 titanium Substances 0.000 claims abstract description 107
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 107
- 238000004070 electrodeposition Methods 0.000 claims abstract description 24
- 238000005488 sandblasting Methods 0.000 claims abstract description 19
- 238000005341 cation exchange Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims description 79
- 239000002184 metal Substances 0.000 claims description 79
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 58
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 13
- 229910001424 calcium ion Inorganic materials 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- 125000002091 cationic group Chemical group 0.000 claims description 10
- 239000008151 electrolyte solution Substances 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
- -1 phosphate anion Chemical class 0.000 claims description 9
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 239000003082 abrasive agent Substances 0.000 claims description 4
- 159000000007 calcium salts Chemical class 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 abstract description 15
- 239000007943 implant Substances 0.000 abstract description 6
- 230000004071 biological effect Effects 0.000 abstract description 4
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000010335 hydrothermal treatment Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 16
- 238000007669 thermal treatment Methods 0.000 description 7
- 210000000988 bone and bone Anatomy 0.000 description 5
- JJIQGEZLLWXYKV-UHFFFAOYSA-N calcium;dinitrate;hydrate Chemical compound O.[Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O JJIQGEZLLWXYKV-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 230000000975 bioactive effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 201000010814 Synostosis Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 210000004409 osteocyte Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Images
Landscapes
- Materials For Medical Uses (AREA)
- Prostheses (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310124403.2A CN103233226B (zh) | 2013-04-11 | 2013-04-11 | 一种氧化钛-羟基磷灰石复合层及其构建方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310124403.2A CN103233226B (zh) | 2013-04-11 | 2013-04-11 | 一种氧化钛-羟基磷灰石复合层及其构建方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103233226A true CN103233226A (zh) | 2013-08-07 |
CN103233226B CN103233226B (zh) | 2015-05-20 |
Family
ID=48881290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310124403.2A Active CN103233226B (zh) | 2013-04-11 | 2013-04-11 | 一种氧化钛-羟基磷灰石复合层及其构建方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103233226B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109023366A (zh) * | 2018-09-02 | 2018-12-18 | 张家港市六福新材料科技有限公司 | 一种羟基磷灰石-二氧化钛复合材料的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587442A (zh) * | 2004-07-06 | 2005-03-02 | 厦门大学 | 纳米有序羟基磷灰石涂层的电化学制备方法 |
CN102732898A (zh) * | 2012-06-29 | 2012-10-17 | 西安交通大学 | 在医用钛或钛合金表面制备微纳米复合结构的方法 |
-
2013
- 2013-04-11 CN CN201310124403.2A patent/CN103233226B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587442A (zh) * | 2004-07-06 | 2005-03-02 | 厦门大学 | 纳米有序羟基磷灰石涂层的电化学制备方法 |
CN102732898A (zh) * | 2012-06-29 | 2012-10-17 | 西安交通大学 | 在医用钛或钛合金表面制备微纳米复合结构的方法 |
Non-Patent Citations (1)
Title |
---|
孔丽丽: ""医用钛表面的电化学构筑及生物性能的优化"", 《中国优秀硕士学位论文全文数据库》, 31 December 2009 (2009-12-31), pages 59 - 74 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109023366A (zh) * | 2018-09-02 | 2018-12-18 | 张家港市六福新材料科技有限公司 | 一种羟基磷灰石-二氧化钛复合材料的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103233226B (zh) | 2015-05-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102146577B (zh) | 一种纯钛金属表面微弧氧化处理电解液及其抗菌性生物活性涂层制备方法 | |
Kar et al. | Electrodeposition of hydroxyapatite onto nanotubular TiO2 for implant applications | |
CN104674321B (zh) | 一种钛或钛合金表面含铜抗菌生物陶瓷膜的制备方法和应用 | |
CN104674320B (zh) | 一种钛或钛合金表面耐磨抑菌生物活性陶瓷膜制备方法和应用 | |
CN102586786B (zh) | 一种钛表面形成分级多孔形貌的方法 | |
US20030171820A1 (en) | Bone-implant prosthesis | |
CN100385039C (zh) | 一种医用金属表面生物活性纳米复合层制备方法 | |
CN101575726B (zh) | 含氟羟基磷灰石梯度生物活性膜层的制备方法 | |
CN102747403B (zh) | 在医用钛合金表面制备掺镁羟基磷灰石/二氧化钛活性膜层的方法 | |
TWI480026B (zh) | 具螺紋構造生醫植體及其選擇性表面處理的方法 | |
CN104726921A (zh) | 二氧化钛/含锶氟羟基磷灰石生物活性纳米复合涂层及其制备方法和应用 | |
CN103908699B (zh) | 一种钛合金表面的HA/TiO2层及其制备方法 | |
CN109680266A (zh) | 一种在钛合金表面制备钽原子掺杂的生物活性陶瓷涂层及其制备方法 | |
CN101919741A (zh) | 具有微米-纳米多级微表面结构的牙种植体及制备方法 | |
CN101775632B (zh) | 一种直接在医用镍钛合金表面制备羟基磷灰石膜层的方法 | |
CN104562145A (zh) | 一种复合氧化制备生物陶瓷膜的方法 | |
CN103361702A (zh) | 牙种植体表面改性的一种方法 | |
CN108079381A (zh) | 一种医用钛合金表面生物压电复合涂层的制备方法 | |
CN103668390A (zh) | 具有微米-纳米粗糙结构表面的钛或钛合金材料及制备方法 | |
CN112281199B (zh) | 基于溶液体系的超声辅助微弧氧化复合膜层的制备与应用 | |
CN104001207B (zh) | 一种医用钛表面复合涂层及其制备方法 | |
CN103898591A (zh) | 一种直接制备含有羟基磷灰石的微弧氧化陶瓷膜的方法 | |
CN109706503B (zh) | 一种钛基体表面的抗菌耐磨涂层及制备方法 | |
CN101491692A (zh) | 一种钛酸钙纳米管阵列生物活性涂层的制备方法 | |
CN104746120B (zh) | 含有生物活性磷酸钙涂层的碳/碳复合材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: CHEN XIANSHUAI Free format text: FORMER OWNER: GUANGZHOU INSTITUTE OF ADVANCED TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Effective date: 20150113 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150113 Address after: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant after: Chen Xianshuai Address before: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant before: Guangzhou Institutes of Advanced Technology, Chinese Academy of Sciences |
|
ASS | Succession or assignment of patent right |
Owner name: GUANGZHOU INSTITUTE OF ADVANCED TECHNOLOGY, CHINES Free format text: FORMER OWNER: CHEN XIANSHUAI Effective date: 20150202 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150202 Address after: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant after: Guangzhou Institutes of Advanced Technology, Chinese Academy of Sciences Address before: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant before: Chen Xianshuai |
|
ASS | Succession or assignment of patent right |
Owner name: CHEN XIANSHUAI Free format text: FORMER OWNER: GUANGZHOU INSTITUTE OF ADVANCED TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Effective date: 20150408 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150408 Address after: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant after: Chen Xianshuai Address before: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Applicant before: Guangzhou Institutes of Advanced Technology, Chinese Academy of Sciences |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160127 Address after: 511458, Guangzhou, Guangdong province Nansha District Haibin Road, No. 1121, C building, first floor Patentee after: GUANGZHOU JIANCHI BIOTECHNOLOGY CO., LTD. Address before: 511458 Nansha District Haibin Road, Guangdong, China, No. 1121, No. Patentee before: Chen Xianshuai |
|
CP03 | Change of name, title or address |
Address after: 511457 room 101-103, No. 37, Jinlong Road, Nansha street, Nansha District, Guangzhou City, Guangdong Province (can not be used as a workshop) Patentee after: Guangdong Jianchi Biotechnology Co.,Ltd. Address before: 511458 1st floor, building C, 1121 Haibin Road, Nansha District, Guangzhou City, Guangdong Province Patentee before: GUANGZHOU JIANCHI BIOTECHNOLOGY Co.,Ltd. |
|
CP03 | Change of name, title or address |