CN102634348B - 混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 - Google Patents
混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 Download PDFInfo
- Publication number
- CN102634348B CN102634348B CN201210077772.6A CN201210077772A CN102634348B CN 102634348 B CN102634348 B CN 102634348B CN 201210077772 A CN201210077772 A CN 201210077772A CN 102634348 B CN102634348 B CN 102634348B
- Authority
- CN
- China
- Prior art keywords
- liquid crystal
- visual angle
- film
- chemical formula
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 205
- 230000000007 visual effect Effects 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 230000000694 effects Effects 0.000 claims abstract description 15
- 239000003999 initiator Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims description 42
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 239000004642 Polyimide Substances 0.000 claims description 21
- 229920001721 polyimide Polymers 0.000 claims description 21
- 239000000178 monomer Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 17
- 230000000977 initiatory effect Effects 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 12
- 238000007493 shaping process Methods 0.000 claims description 11
- 239000012298 atmosphere Substances 0.000 claims description 6
- 239000005357 flat glass Substances 0.000 claims description 4
- 108091092195 Intron Proteins 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- -1 allyl ester Chemical class 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 abstract 2
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 22
- 239000013078 crystal Substances 0.000 description 15
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 11
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229920005575 poly(amic acid) Polymers 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920000106 Liquid crystal polymer Polymers 0.000 description 4
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 2
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229920006300 shrink film Polymers 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical group OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 1
- 229960000549 4-dimethylaminophenol Drugs 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004988 Nematic liquid crystal Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229960005083 chloralodol Drugs 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 1
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210077772.6A CN102634348B (zh) | 2012-03-21 | 2012-03-21 | 混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210077772.6A CN102634348B (zh) | 2012-03-21 | 2012-03-21 | 混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102634348A CN102634348A (zh) | 2012-08-15 |
CN102634348B true CN102634348B (zh) | 2014-06-25 |
Family
ID=46618930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210077772.6A Expired - Fee Related CN102634348B (zh) | 2012-03-21 | 2012-03-21 | 混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102634348B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103922937B (zh) * | 2014-04-30 | 2016-08-24 | 甘肃有色冶金职业技术学院 | 一种联苯型丙烯酸酯液晶树脂的合成方法 |
CN104403677B (zh) * | 2014-12-15 | 2016-08-24 | 京东方科技集团股份有限公司 | 一种液晶混合物、图案化相位延迟膜及制备方法、显示装置 |
KR102568775B1 (ko) * | 2015-10-26 | 2023-08-22 | 삼성디스플레이 주식회사 | 플렉서블 디스플레이 장치 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1711335A (zh) * | 2002-11-07 | 2005-12-21 | 电化学工业有限公司(国际) | 可聚合的混合物 |
TWI281560B (en) * | 2000-09-15 | 2007-05-21 | Au Optronics Corp | Arrangement structure of liquid crystal display device |
CN101568559A (zh) * | 2007-03-29 | 2009-10-28 | 株式会社艾迪科 | 聚合性化合物以及聚合性组合物 |
CN101952390A (zh) * | 2008-02-22 | 2011-01-19 | 株式会社艾迪科 | 含有聚合性化合物的液晶组合物和使用该液晶组合物的液晶显示元件 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04172320A (ja) * | 1990-11-05 | 1992-06-19 | Seiko Instr Inc | 液晶配向膜の製作方法 |
DE69419120T2 (de) * | 1993-12-24 | 1999-10-28 | Dainippon Ink & Chemicals | Polymerisierbare Flüssigkristallzusammensetzung und optisch anisotroper Film, der eine solche Zusammensetzung enthält |
JP3760629B2 (ja) * | 1998-04-30 | 2006-03-29 | セイコーエプソン株式会社 | 液晶装置の製造方法 |
KR100732325B1 (ko) * | 2005-02-16 | 2007-06-25 | 주식회사 엘지화학 | 수직 배향 액정 필름을 포함하는 위상차 필름 및 그제조방법 |
JP2007332270A (ja) * | 2006-06-15 | 2007-12-27 | Dainippon Printing Co Ltd | 液晶組成物、カラーフィルタおよび液晶表示装置 |
JP2008050440A (ja) * | 2006-08-23 | 2008-03-06 | Fujifilm Corp | 重合性モノマー、高分子化合物、光学異方性フィルム、光学補償シート、偏光板および液晶表示装置、および光学補償シートの製造方法 |
-
2012
- 2012-03-21 CN CN201210077772.6A patent/CN102634348B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI281560B (en) * | 2000-09-15 | 2007-05-21 | Au Optronics Corp | Arrangement structure of liquid crystal display device |
CN1711335A (zh) * | 2002-11-07 | 2005-12-21 | 电化学工业有限公司(国际) | 可聚合的混合物 |
CN101568559A (zh) * | 2007-03-29 | 2009-10-28 | 株式会社艾迪科 | 聚合性化合物以及聚合性组合物 |
CN101952390A (zh) * | 2008-02-22 | 2011-01-19 | 株式会社艾迪科 | 含有聚合性化合物的液晶组合物和使用该液晶组合物的液晶显示元件 |
Also Published As
Publication number | Publication date |
---|---|
CN102634348A (zh) | 2012-08-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101528786B (zh) | 聚合性化合物和聚合性组合物 | |
JP5572211B2 (ja) | 光学デバイス又は電気光学デバイスのためのエステル基含有液晶 | |
US9139776B2 (en) | Composite comprising a polymer and a blue phase liquid crystal, a method for preparing the composite, and a liquid crystal display device comprising the composite | |
CN104834144A (zh) | 利用紫外聚合协同作用制备宽波反射薄膜的方法及应用 | |
JP5854205B2 (ja) | 液晶配向剤 | |
CN105218717A (zh) | 一种紫外分步聚合制备宽波段光屏蔽薄膜材料的方法 | |
CN102634348B (zh) | 混合液晶溶液、液晶视角扩大膜及其制备、液晶显示器件 | |
CN102516498A (zh) | 一种基于高分子混合网络聚合物分散液晶材料的制备方法 | |
CN102866538B (zh) | 光学补偿膜及其制备方法、显示装置 | |
CN102193250A (zh) | 液晶显示元件的制造方法、聚合物组合物和液晶显示元件 | |
JP2004020658A (ja) | 光学部材の作製方法および光学部材 | |
JP5992047B2 (ja) | 配向性フィルムの製造方法 | |
JP2020079812A (ja) | 液晶配向膜の製造方法および液晶素子 | |
CN113311625A (zh) | 一种聚合物稳定胆甾相液晶变色玻璃及其制备方法和应用 | |
WO2015029596A1 (ja) | 偏光性フィルムの製造方法 | |
JP5979828B2 (ja) | 光学フィルム | |
CN104961894A (zh) | 用作取向膜材料的聚合物及取向膜的制备方法 | |
CN105542795A (zh) | 手性可聚合液晶组合物及其应用 | |
JP7088463B2 (ja) | 液晶組成物、温度応答性調光素子およびその製造方法 | |
TWI797059B (zh) | 液晶配向膜製造用組成物、使用該組成物之液晶配向膜、及其製造方法、以及具有液晶配向膜之液晶顯示元件、及其製造方法 | |
JP6012553B2 (ja) | 配向性フィルムの製造方法 | |
JP6388279B2 (ja) | 周期構造を有する光学フィルムの製造方法 | |
WO2016078159A1 (zh) | 反应性单体、液晶面板及电子设备 | |
JP3651614B2 (ja) | 光学異方体の製造方法及びそれに用いる配向膜形成材料 | |
JP2004346311A (ja) | 液晶配向剤、液晶配向膜の製造方法および液晶表示素子 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210928 Address after: 518000 northwest 2nd floor, 5th floor and 6th floor, danbang science and technology building, Langshan 1st Road, Nanshan District, Shenzhen City, Guangdong Province Patentee after: SHENZHEN DIANBOND TECHNOLOGY Co.,Ltd. Address before: 523808 Zone C, northern industrial city, Songshanhu science and Technology Industrial Park, Dongguan City, Guangdong Province Patentee before: GUANG DONG DONGBOND TECHNOLOGY Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220805 Address after: 523000 Songshan Lake Science and Technology Industrial Park, Dongguan City, Guangdong Province Patentee after: GUANG DONG DONGBOND TECHNOLOGY Co.,Ltd. Address before: 518000 northwest 2nd floor, 5th floor and 6th floor, danbang science and technology building, Langshan 1st Road, Nanshan District, Shenzhen City, Guangdong Province Patentee before: SHENZHEN DIANBOND TECHNOLOGY Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140625 |