CN102153448B - 气固相反应制备低级烷醇铝的方法 - Google Patents
气固相反应制备低级烷醇铝的方法 Download PDFInfo
- Publication number
- CN102153448B CN102153448B CN201110028268.2A CN201110028268A CN102153448B CN 102153448 B CN102153448 B CN 102153448B CN 201110028268 A CN201110028268 A CN 201110028268A CN 102153448 B CN102153448 B CN 102153448B
- Authority
- CN
- China
- Prior art keywords
- aluminium
- low
- aluminum
- lower alkyl
- alkyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 96
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000003746 solid phase reaction Methods 0.000 title claims abstract description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004411 aluminium Substances 0.000 claims description 49
- 238000006243 chemical reaction Methods 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 15
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 12
- 238000010992 reflux Methods 0.000 claims description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 7
- 229960003280 cupric chloride Drugs 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 7
- 239000003054 catalyst Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 231100000817 safety factor Toxicity 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 239000002994 raw material Substances 0.000 description 10
- 238000004821 distillation Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 150000004645 aluminates Chemical class 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- JPUHCPXFQIXLMW-UHFFFAOYSA-N aluminium triethoxide Chemical compound CCO[Al](OCC)OCC JPUHCPXFQIXLMW-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- -1 butanols Chemical compound 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (8)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110028268.2A CN102153448B (zh) | 2011-01-26 | 2011-01-26 | 气固相反应制备低级烷醇铝的方法 |
PCT/CN2011/080380 WO2012100555A1 (en) | 2011-01-26 | 2011-09-29 | A method for the preparation of lower aluminum alkoxide by gas-solid phase reaction |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110028268.2A CN102153448B (zh) | 2011-01-26 | 2011-01-26 | 气固相反应制备低级烷醇铝的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102153448A CN102153448A (zh) | 2011-08-17 |
CN102153448B true CN102153448B (zh) | 2014-04-30 |
Family
ID=44435173
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110028268.2A Active CN102153448B (zh) | 2011-01-26 | 2011-01-26 | 气固相反应制备低级烷醇铝的方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN102153448B (zh) |
WO (1) | WO2012100555A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153448B (zh) * | 2011-01-26 | 2014-04-30 | 连云港连连化学有限公司 | 气固相反应制备低级烷醇铝的方法 |
CN106673959B (zh) * | 2015-11-11 | 2019-11-15 | 中国石油化工股份有限公司 | 一种高纯度铝醇盐的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB654408A (en) * | 1948-01-27 | 1951-06-20 | British Aluminium Co Ltd | Improvements in the manufacture of aluminium alkoxides |
US4052428A (en) * | 1975-12-15 | 1977-10-04 | Stauffer Chemical Company | Stable aluminum alkoxide solutions |
CN1201035A (zh) * | 1997-06-04 | 1998-12-09 | 中国石油化工总公司 | 一种低碳烷氧基铝的制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153448B (zh) * | 2011-01-26 | 2014-04-30 | 连云港连连化学有限公司 | 气固相反应制备低级烷醇铝的方法 |
-
2011
- 2011-01-26 CN CN201110028268.2A patent/CN102153448B/zh active Active
- 2011-09-29 WO PCT/CN2011/080380 patent/WO2012100555A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB654408A (en) * | 1948-01-27 | 1951-06-20 | British Aluminium Co Ltd | Improvements in the manufacture of aluminium alkoxides |
US4052428A (en) * | 1975-12-15 | 1977-10-04 | Stauffer Chemical Company | Stable aluminum alkoxide solutions |
CN1201035A (zh) * | 1997-06-04 | 1998-12-09 | 中国石油化工总公司 | 一种低碳烷氧基铝的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2012100555A1 (en) | 2012-08-02 |
CN102153448A (zh) | 2011-08-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101560151B (zh) | 一种以离子液体为催化剂的反应精馏生产醋酸甲酯的工艺 | |
CN101891621A (zh) | 3-乙氧基-4-乙氧羰基苯乙酸的合成方法 | |
CN102153448B (zh) | 气固相反应制备低级烷醇铝的方法 | |
CN112250543A (zh) | 一种药用原料甲醇钠的生产工艺 | |
CN1117164C (zh) | 金属锂的热还原制备及提纯工艺和设备 | |
CN106699564A (zh) | 共沸反应精馏隔壁塔法生产碳酸甲乙酯的方法和装置 | |
CN102153447B (zh) | 低级烷醇铝的制备和固化方法 | |
CN102992959A (zh) | 一种利用高水含量异丙醇制备异丙醇铝的方法 | |
CN103319326B (zh) | 一种草酸氧钒的制备方法 | |
CN104230662B (zh) | 一种高纯5n异丙醇铝的制备方法 | |
CN109305912B (zh) | 由异丁醛缩合制备2,2,4-三甲基-1,3-戊二醇单异丁酸酯的方法 | |
CN112939045B (zh) | 一种超细高纯γ-氧化铝的制备方法 | |
CN102649057A (zh) | Co偶联反应制备草酸酯的催化剂 | |
CN206232637U (zh) | 一种碳酸乙烯酯提纯*** | |
CN113044862B (zh) | 一种利用不同铵光卤石物料间的协同耦合作用对其进行脱水的方法 | |
CN101696153B (zh) | 3,3-二甲基-1-丁醇的制备方法 | |
CN103641676A (zh) | 一种制备甲基环戊二烯的方法 | |
CN105585468B (zh) | 一种以环戊烯为原料制备环戊酮的方法 | |
CN103086969B (zh) | 一种亚氨基芪甲酰氯的合成方法 | |
CN106008241A (zh) | 一种n,n-二甲氨基丙烯酸乙酯的合成方法 | |
CN107602408B (zh) | 一种乙酰氨基丙二酸二乙酯的合成方法 | |
CN104892658A (zh) | 二苯基二氟硅烷的制备方法 | |
CN110066221B (zh) | 一种环丙基甲胺的制备方法 | |
CN111004096B (zh) | 一种2,6-二氯苯甲醛的合成方法 | |
CN103183582A (zh) | 工业甲醇制备色谱纯甲醇的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: JIANGSU LIANLIAN CHEMICAL CO., LTD. Free format text: FORMER NAME: LIANYUNGANG LIANLIAN CHEMICALS CO., LTD. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 222228 Lingang Industrial Zone, Lianyungang, Jiangsu, Guanyun Patentee after: JIANGSU LIANLIAN CHEMICAL CO.,LTD. Address before: 222228 Lingang Industrial Zone, Lianyungang, Jiangsu, Guanyun Patentee before: LIANYUNGANG LIANLIAN CHEMICALS Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 222228 Guanyun Lingang Industrial Zone, Lianyungang City, Jiangsu Province Patentee after: Jiangsu Lianlian Precision Ceramics Co.,Ltd. Address before: 222228 Guanyun Lingang Industrial Zone, Lianyungang City, Jiangsu Province Patentee before: JIANGSU LIANLIAN CHEMICAL Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210816 Address after: 315048 1508-356, building 037, No. 52, Huihai Road, high tech Zone, Ningbo, Zhejiang Patentee after: Ultra micro (Ningbo) new material Co.,Ltd. Address before: 222228 Guanyun Lingang Industrial Zone, Lianyungang City, Jiangsu Province Patentee before: Jiangsu Lianlian Precision Ceramics Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211123 Address after: 201400 building 33, No. 38, SHUNGONG Road, Fengxian District, Shanghai Patentee after: Shanghai Lianlian Huaming New Material Co.,Ltd. Address before: 315048 1508-356, building 037, No. 52, Huihai Road, high tech Zone, Ningbo, Zhejiang Patentee before: Ultra micro (Ningbo) new material Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220822 Address after: 10-1-1, Building 028, Building 5#, No. 15, Lane 587, Juxian Road, High-tech Zone, Ningbo City, Zhejiang Province, 315040 Patentee after: Zhejiang Superfine New Materials Co.,Ltd. Address before: 201400 building 33, No. 38, SHUNGONG Road, Fengxian District, Shanghai Patentee before: Shanghai Lianlian Huaming New Material Co.,Ltd. |
|
TR01 | Transfer of patent right |