GB654408A - Improvements in the manufacture of aluminium alkoxides - Google Patents
Improvements in the manufacture of aluminium alkoxidesInfo
- Publication number
- GB654408A GB654408A GB2484/48A GB248448A GB654408A GB 654408 A GB654408 A GB 654408A GB 2484/48 A GB2484/48 A GB 2484/48A GB 248448 A GB248448 A GB 248448A GB 654408 A GB654408 A GB 654408A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- vapour
- alcohol
- vessel
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/28—Metal alcoholates
- C07C31/32—Aluminium alcoholates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aluminium alkoxides are obtained by reacting vapours of alcohols containing not more than four carbon atoms with heated aluminium-bearing materials in the presence of a catalyst as defined below, the temperature to which the aluminium-bearing material is heated being such that the aluminium alkoxides are formed in the vapour phase. The catalyst is defined as anhydrous cupric chloride or a substance which is known to catalyse the reaction in the known methods for producing aluminium alkoxides from aluminium and an alcohol, but which will not volatilize at the reaction temperature. The alcohol may be normal, secondary, iso or tertiary. The aluminium-bearing materials are preferably comminuted and include both pure and impure aluminium as well as aluminium alloys and mixed alloy scrap. The alcohol vapour is preferably carried forward in a stream of nitrogen or hydrogen and the process can be carried out in a continuous manner, the alcohol vapour being passed in counter - current to the aluminium - bearing material as this is advanced through the reaction space. The reaction may be carried out under reduced pressure, atmospheric pressure or higher pressure. The alkoxide vapour formed may be hydrolysed to hydrate of alumina, e.g. by blowing steam into the vessel into which the vapour or smoke is delivered from the reaction space. The alcohol liberated can be recovered by distillation and returned to the process. In an example, a finely divided aluminium-copper alloy mixed with anhydrous cupric chloride is fed into one end of a reaction vessel heated to 200-300 DEG C. and passed through the vessel by a helical screw device. Ethyl alcohol vapour at atmospheric pressure and carried in a stream of nitrogen is passed counter-current to the metal, the rates of feed being controlled so that pure aluminium ethoxide distils over at the outlet end of the vessel. The Provisional Specification is not restricted to alcohols containing up to four carbon atoms but refers to the use of alcohols generally.ALSO:Hydrate of alumina is obtained by hydrolysing the aluminium alkoxide vapour obtained by reacting the vapour of an alcohol containing up to four carbon atoms with heated aluminium-bearing material in the presence of a catalyst the temperature to which the aluminium-bearing material is heated being such that the aluminium alkoxide is formed in the vapour phase (see Group IV (b)). The hydrolysis may be effected by blowing steam into the vessel into which the alkoxide vapour is delivered from the reaction space. The Provisional Specification is not restricted to the use of alcohols containing up to four carbon atoms but refers to alcohol vapours generally.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2484/48A GB654408A (en) | 1948-01-27 | 1948-01-27 | Improvements in the manufacture of aluminium alkoxides |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2484/48A GB654408A (en) | 1948-01-27 | 1948-01-27 | Improvements in the manufacture of aluminium alkoxides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB654408A true GB654408A (en) | 1951-06-20 |
Family
ID=9740370
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2484/48A Expired GB654408A (en) | 1948-01-27 | 1948-01-27 | Improvements in the manufacture of aluminium alkoxides |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB654408A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153447A (en) * | 2011-01-26 | 2011-08-17 | 连云港连连化学有限公司 | Method for preparing and curing low-level alkanol aluminum |
CN102153448A (en) * | 2011-01-26 | 2011-08-17 | 连云港连连化学有限公司 | Method for preparing low-level alkanol aluminum by gas-solid phase reaction |
-
1948
- 1948-01-27 GB GB2484/48A patent/GB654408A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153447A (en) * | 2011-01-26 | 2011-08-17 | 连云港连连化学有限公司 | Method for preparing and curing low-level alkanol aluminum |
CN102153448A (en) * | 2011-01-26 | 2011-08-17 | 连云港连连化学有限公司 | Method for preparing low-level alkanol aluminum by gas-solid phase reaction |
WO2012100555A1 (en) * | 2011-01-26 | 2012-08-02 | Lianyungang Lianlian Chemicals Co., Ltd. | A method for the preparation of lower aluminum alkoxide by gas-solid phase reaction |
CN102153447B (en) * | 2011-01-26 | 2013-08-28 | 连云港连连化学有限公司 | Method for preparing and curing low-level alkanol aluminum |
CN102153448B (en) * | 2011-01-26 | 2014-04-30 | 连云港连连化学有限公司 | Method for preparing low-level alkanol aluminum by gas-solid phase reaction |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2579251A (en) | Manufacture of aluminum alkoxides | |
US8551437B2 (en) | Process for the manufacture of P4O6 with improved yield | |
US2845447A (en) | Production of aluminum alcoholates | |
US2473993A (en) | Synthesis of metal carbonyls | |
TWI362377B (en) | Acetic anhydride and acetate ester co-production | |
US2163720A (en) | Preparation of acetylenic alcohols | |
GB654408A (en) | Improvements in the manufacture of aluminium alkoxides | |
US3000703A (en) | Manufacture of zirconium oxide | |
US2196581A (en) | Manufacture of organic acids from alcohols | |
JPH06234731A (en) | Continuous preparation of disulfide | |
US3183274A (en) | Trimethylolpropane | |
US2921098A (en) | Process for the preparation of 1, 1, 1-trifluoro-2-bromo-2-chloroethane | |
US3458406A (en) | Removal of methyl and ethyl acetate from vinyl acetate | |
US3433838A (en) | Purification of perhaloacetones | |
KR970002901B1 (en) | Method for stabilizing rhodium compound | |
JPH0114892B2 (en) | ||
US3754011A (en) | Method for the preparation of zirconium,hafnium and thorium alkoxides | |
US4148831A (en) | Method of preparing 1,1-difluoroethylene | |
CA2851186C (en) | Treatment of chemical feedstocks | |
CN1032418C (en) | decomposition process for ammonium chloride | |
US2480467A (en) | Production of trifluoroacetic acid compounds | |
JPS6363629A (en) | Production of 2,2-bis(4'-hydroxyphenyl)propane | |
US2770639A (en) | Method of producing aliphatic and alicyclic carbonates | |
GB1285091A (en) | Production of aluminium | |
US2510550A (en) | Production of methyl acetylene and magnesium alcoholates |