CN101875507B - 高纯一水硫酸锰的制备方法 - Google Patents
高纯一水硫酸锰的制备方法 Download PDFInfo
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- CN101875507B CN101875507B CN201010243859A CN201010243859A CN101875507B CN 101875507 B CN101875507 B CN 101875507B CN 201010243859 A CN201010243859 A CN 201010243859A CN 201010243859 A CN201010243859 A CN 201010243859A CN 101875507 B CN101875507 B CN 101875507B
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- manganese sulfate
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- high purity
- impurities
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- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000012535 impurity Substances 0.000 claims abstract description 85
- 239000011572 manganese Substances 0.000 claims abstract description 39
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 27
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 23
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 23
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 22
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 20
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 18
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 18
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 7
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000706 filtrate Substances 0.000 claims description 40
- 239000013078 crystal Substances 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 23
- 238000001914 filtration Methods 0.000 claims description 18
- PAVJEQIFHXNOSM-UHFFFAOYSA-H manganese(3+);trisulfate Chemical compound [Mn+3].[Mn+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O PAVJEQIFHXNOSM-UHFFFAOYSA-H 0.000 claims description 15
- 239000002594 sorbent Substances 0.000 claims description 15
- 238000001704 evaporation Methods 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 229910052745 lead Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 44
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 10
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 10
- 239000010405 anode material Substances 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 229910021569 Manganese fluoride Inorganic materials 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 abstract 1
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 abstract 1
- CTNMMTCXUUFYAP-UHFFFAOYSA-L difluoromanganese Chemical compound F[Mn]F CTNMMTCXUUFYAP-UHFFFAOYSA-L 0.000 abstract 1
- 229910000358 iron sulfate Inorganic materials 0.000 abstract 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract 1
- 235000006748 manganese carbonate Nutrition 0.000 abstract 1
- 239000011656 manganese carbonate Substances 0.000 abstract 1
- 229940093474 manganese carbonate Drugs 0.000 abstract 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 31
- 239000011575 calcium Substances 0.000 description 29
- 239000011777 magnesium Substances 0.000 description 27
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 25
- 239000011133 lead Substances 0.000 description 21
- 239000011701 zinc Substances 0.000 description 21
- 239000010949 copper Substances 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000010792 warming Methods 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- KNLQKHUBPCXPQD-UHFFFAOYSA-N manganese;sulfuric acid Chemical compound [Mn].OS(O)(=O)=O KNLQKHUBPCXPQD-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 150000002696 manganese Chemical class 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 metals ion Chemical class 0.000 description 1
- 201000007094 prostatitis Diseases 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103112901B (zh) * | 2013-03-02 | 2014-08-20 | 湘潭大学 | 一种降低硫酸锰中钙、镁、钾、钠离子含量的方法 |
CN103145188B (zh) * | 2013-03-25 | 2015-07-29 | 国药集团化学试剂有限公司 | 一种一水硫酸锰的纯化方法 |
CN103193274A (zh) * | 2013-05-02 | 2013-07-10 | 宜春市同舟新材料科技有限公司 | 硫酸锰的提纯方法及其硫酸锰 |
CN103232071B (zh) * | 2013-05-13 | 2015-11-25 | 深圳市新昊青科技有限公司 | 一种制备高纯硫酸锰的方法 |
CN103771525B (zh) * | 2013-12-30 | 2015-09-30 | 中信大锰矿业有限责任公司大新锰矿分公司 | 一种火法结合湿法生产硫酸锰的新工艺 |
CN106629857A (zh) * | 2017-01-04 | 2017-05-10 | 贵州红星发展大龙锰业有限责任公司 | 一种硫酸锰溶液中杂质镁的分离方法 |
CN109467130A (zh) * | 2019-01-17 | 2019-03-15 | 广西锰华新能源科技发展有限公司 | 一种电池级硫酸锰的制备方法 |
CN114671466A (zh) * | 2022-04-11 | 2022-06-28 | 中南大学 | 一种高纯硫酸锰及利用溶解度性质制备高纯硫酸锰的方法 |
CN115072787A (zh) * | 2022-07-23 | 2022-09-20 | 贵州金瑞新材料有限责任公司 | 一种电池级硫酸锰的制备方法 |
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CN1283592A (zh) * | 2000-07-08 | 2001-02-14 | 中国石油化工股份有限公司巴陵分公司 | 一种高纯碳酸锰的制造方法 |
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CN1283592A (zh) * | 2000-07-08 | 2001-02-14 | 中国石油化工股份有限公司巴陵分公司 | 一种高纯碳酸锰的制造方法 |
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