BR0011184A - Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador - Google Patents
Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisadorInfo
- Publication number
- BR0011184A BR0011184A BR0011184-8A BR0011184A BR0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- catalyst composition
- olefin
- hydro
- oxidation
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 10
- 150000001336 alkenes Chemical class 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title abstract 3
- 239000010931 gold Substances 0.000 title abstract 3
- 229910052737 gold Inorganic materials 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 3
- 229910052719 titanium Inorganic materials 0.000 abstract 3
- 239000010936 titanium Substances 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
"PROCESSO PARA A HIDRO-OXIDAçãO DE OLEFINAS A óXIDOS DE OLEFINAS USANDO CATALISADOR DE OURO OXIDADO, COMPOSIçãO DE CATALISADOR E MéTODO PARA PREPARAR UMA COMPOSIçãO DE CATALISADOR". A presente invenção refere-se a um processo e um catalisador para a hidro-oxidação de uma olefina tendo três ou mais átomos de carbono, tais como propileno, para formar um óxido de olefina, tal como óxido de propileno. O processo envolve contatar a olefina com oxigênio sob condições de reação na presença de hidrogênio e um catalisador. O catalisador contêm ouro oxidado disperso em um suporte contendo titânio, preferivelmente, um suporte tendo uma pluralidade de ambientes de coordenação de titânio, por exemplo, titânio enxertado sobre um titanossilicato. A seletividade ao óxido de olefina é alta a uma boa conversão de olefina. O catalisador usa hidrogênio eficientemente e exibe uma longa vida útil.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12839499P | 1999-04-08 | 1999-04-08 | |
PCT/US2000/009419 WO2000059632A1 (en) | 1999-04-08 | 2000-04-07 | Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0011184A true BR0011184A (pt) | 2002-03-05 |
BR0011184B1 BR0011184B1 (pt) | 2011-06-14 |
Family
ID=22435162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0011184-8A BR0011184B1 (pt) | 1999-04-08 | 2000-04-07 | processo para a hidro-oxidaÇço de olefinas a àxidos de olefinas usando catalisador de ouro oxidado, composiÇço de catalisador e mÉtodo para preparar uma composiÇço de catalisador. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6255499B1 (pt) |
EP (2) | EP1384506A3 (pt) |
JP (2) | JP4646409B2 (pt) |
KR (1) | KR100704141B1 (pt) |
CN (1) | CN1122566C (pt) |
AT (1) | ATE259258T1 (pt) |
AU (1) | AU4335100A (pt) |
BR (1) | BR0011184B1 (pt) |
DE (1) | DE60008235T2 (pt) |
ES (1) | ES2211535T3 (pt) |
ID (1) | ID30342A (pt) |
RU (1) | RU2234369C2 (pt) |
WO (1) | WO2000059632A1 (pt) |
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EP1073649B1 (en) | 1998-04-15 | 2003-09-10 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
DE69906136T2 (de) | 1998-12-16 | 2004-01-08 | Dow Global Technologies, Inc., Midland | Verfahren zur direktoxidation von olefinen zu olefinoxiden |
US6821923B1 (en) * | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
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US6281369B1 (en) † | 2000-12-07 | 2001-08-28 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
US6310224B1 (en) * | 2001-01-19 | 2001-10-30 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
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DE10137826A1 (de) * | 2001-08-02 | 2003-02-13 | Bayer Ag | Verfahren zur Herstellung und Isolierung von Alkenoxiden aus Alkenen |
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KR101239579B1 (ko) * | 2005-01-14 | 2013-03-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 티타노실리케이트의 재생 및 활성 산화 촉매의 재구성 |
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DE69737516T2 (de) * | 1997-06-30 | 2007-11-29 | Dow Global Technologies, Inc., Midland | Katalysatorzusammensetzung und Verfahren zur Direktoxidation von Propen zu Propenoxid |
JP4016121B2 (ja) * | 1997-09-05 | 2007-12-05 | 独立行政法人産業技術総合研究所 | 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法 |
JP4000392B2 (ja) * | 1997-11-05 | 2007-10-31 | 独立行政法人産業技術総合研究所 | 炭化水素の部分酸化用触媒及び含酸素有機化合物の製法 |
CN1256646A (zh) | 1998-02-24 | 2000-06-14 | 工业技术院长代表日本国 | 用于部分氧化不饱和烃的催化剂 |
EP1073649B1 (en) | 1998-04-15 | 2003-09-10 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
NO982818L (no) | 1998-06-18 | 2000-03-15 | Pemby Ltd | Syntetisk fremstilt preparat for behandling og/eller profylakse av overvekt, samt anvendelse derav |
-
2000
- 2000-04-07 EP EP03022759A patent/EP1384506A3/en not_active Withdrawn
- 2000-04-07 EP EP00923185A patent/EP1177041B1/en not_active Expired - Lifetime
- 2000-04-07 WO PCT/US2000/009419 patent/WO2000059632A1/en active Search and Examination
- 2000-04-07 ID IDW00200102172A patent/ID30342A/id unknown
- 2000-04-07 AU AU43351/00A patent/AU4335100A/en not_active Abandoned
- 2000-04-07 AT AT00923185T patent/ATE259258T1/de not_active IP Right Cessation
- 2000-04-07 ES ES00923185T patent/ES2211535T3/es not_active Expired - Lifetime
- 2000-04-07 RU RU2001130070/04A patent/RU2234369C2/ru not_active IP Right Cessation
- 2000-04-07 KR KR1020017012705A patent/KR100704141B1/ko active IP Right Grant
- 2000-04-07 CN CN00806981A patent/CN1122566C/zh not_active Expired - Lifetime
- 2000-04-07 DE DE60008235T patent/DE60008235T2/de not_active Expired - Lifetime
- 2000-04-07 US US09/544,743 patent/US6255499B1/en not_active Expired - Lifetime
- 2000-04-07 JP JP2000609185A patent/JP4646409B2/ja not_active Expired - Lifetime
- 2000-04-07 BR BRPI0011184-8A patent/BR0011184B1/pt not_active IP Right Cessation
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2010
- 2010-10-18 JP JP2010233489A patent/JP5419844B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU4335100A (en) | 2000-10-23 |
EP1384506A2 (en) | 2004-01-28 |
US6255499B1 (en) | 2001-07-03 |
JP4646409B2 (ja) | 2011-03-09 |
CN1122566C (zh) | 2003-10-01 |
DE60008235T2 (de) | 2004-12-02 |
EP1384506A3 (en) | 2004-02-04 |
ID30342A (id) | 2001-11-22 |
EP1177041A1 (en) | 2002-02-06 |
JP5419844B2 (ja) | 2014-02-19 |
JP2002541127A (ja) | 2002-12-03 |
ATE259258T1 (de) | 2004-02-15 |
KR100704141B1 (ko) | 2007-04-09 |
EP1177041B1 (en) | 2004-02-11 |
KR20010102581A (ko) | 2001-11-15 |
ES2211535T3 (es) | 2004-07-16 |
JP2011031243A (ja) | 2011-02-17 |
BR0011184B1 (pt) | 2011-06-14 |
CN1349429A (zh) | 2002-05-15 |
DE60008235D1 (de) | 2004-03-18 |
WO2000059632A1 (en) | 2000-10-12 |
EP1384506A9 (en) | 2004-03-31 |
RU2234369C2 (ru) | 2004-08-20 |
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