AR085568A1 - 5-(biciclo[4.1.0]hept-3-en-2-il)-penta-2,4-dienos y 5-(biciclo[4.1.0]hept-3-en-2-il)-pent-2-en-4-inos sustituidos como principios activos contra el estres abiotico de las plantas - Google Patents

5-(biciclo[4.1.0]hept-3-en-2-il)-penta-2,4-dienos y 5-(biciclo[4.1.0]hept-3-en-2-il)-pent-2-en-4-inos sustituidos como principios activos contra el estres abiotico de las plantas

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Publication number
AR085568A1
AR085568A1 ARP120101003A ARP120101003A AR085568A1 AR 085568 A1 AR085568 A1 AR 085568A1 AR P120101003 A ARP120101003 A AR P120101003A AR P120101003 A ARP120101003 A AR P120101003A AR 085568 A1 AR085568 A1 AR 085568A1
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AR
Argentina
Prior art keywords
alkyl
bis
hept
silyl
haloalkyl
Prior art date
Application number
ARP120101003A
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English (en)
Inventor
Mller Thomas Dr
Von Koskull-Dring Pascal Dr
Martin Jeffrey Hills
Rosinger Christopher Hugh Dr
Huser-Hahn Isolde Dr
Frackenpohl Jens Dr
Heinemann Ines Dr
Original Assignee
Bayer Cropscience Ag
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Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR085568A1 publication Critical patent/AR085568A1/es

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Abstract

Procedimientos para su preparación y a su uso para aumentar la tolerancia al estrés en las plantas frente al estrés abiótico y/o para aumentar el rendimiento de cosecha de las plantas.Reivindicación 1: 5-(Biciclo[4.1.0]hept-3-en-2-il)-penta-2,4-dienos y 5-(biciclo[4.1.0]hept-3-en-2-il)-pent-2-en-4-inos sustituidos de la fórmula general (1) o sus sales, en la que [X-Y] representan las agrupaciones de fórmula [X-Y]1 a [X-Y]4; Q representa las agrupaciones de formula (Q-1) a (Q-4), en las que R6, R7, R8, R9, R10 y R11, respectivamente, tienen el significado según las definiciones que se encuentran más adelante y en las que la flecha representa una unión a la agrupación [X-Y] correspondiente; R1 y R2, independientemente uno de otro, representan hidrógeno, alquilo, haloalquilo, halógeno, trialquilsililo, nitro, ciano, arilo, alcoxicarbonilo, haloalcoxicarbonilo, alquiltio, ariltio; R3 y R4, independientemente uno de otro, representan alcoxi, alcoxialcoxi, cicloalquilalcoxi, haloalcoxi, alquiltio, haloalquiltio, arilalcoxi, arilaquiltio o conjuntamente con el átomo al que están unidos forman un grupo oxo, un grupo hidroxiimino, un grupo alcoxiimino, un grupo cicloalcoxiimino, un grupo cicloalquilalcoxiimino, un grupo arilalcoxiimino o un anillo heterocíclico de 5 - 7 miembros que, dado el caso, puede estar sustituido adicionalmente; R5 representa hidrógeno, alquilo, alquenilo, alquenilalquilo, alcoxialquilo, alquilcarbonilo, arilcarbonilo, heteroarilcarbonilo, cicloalquilcarbonilo, alcoxicarbonilo, alqueniloxicarbonilo, ariloxialquilo, arilalcoxicarbonilo, arilalcoxialquilo, arilalquilo, alcoxialcoxialquilo, alquiltioalquilo, trialquilsililo, alquil(bis-alquil)sililo, alquil(bis-aril)sililo, aril-bis-(alquil)sililo, cicloalquil(bis-alquil)sililo, halo(bis-alquil)sililo, trialquilsililalcoxialquilo, trialquilsililalquilo; R6 y R7, independientemente uno de otro, representan hidrógeno, halógeno, alquilo, haloalquilo; R8 representa halógeno, alquilo, haloalquilo, haloalcoxi, haloalcoxialquilo, haloalcoxihaloalquilo, alcoxihaloalquilo, alquiniloxihaloalquilo, alqueniloxihaloalquilo, alquiltio, haloalquiltio, arilo, arilalquilo, heteroarilo, heteroarilalquilo, tris-(alquil)sililoxi, alquilaminoalquilo, bis-alquilaminoalquilo, arilalquilaminoalquilo; R7 y R8 con los átomos a los que están unidos forman un anillo de 3 a 6 miembros totalmente saturado, dado el caso interrumpido por heteroátomos y dado el caso sustituido adicionalmente; R9 representa hidrógeno, alquilo, alcoxialquilo, cicloalquilo, cicloalquilalquilo, arilo, arilalquilo, heteroarilalquilo, bis-arilalquilo, tris-arilalquilo, alquenilo, alquenilalquilo, cicloalquenilalquilo, alquinilalquilo, trialquilsililalcoxialquilo, alcoxialcoxialquilo, alquiltioalquilo, haloalquilo, arilsulfonilalquilo, trialquilsililo, alquil(bis-aril)sililo, alquil-(bis-alquil)sililo, bis-alquilaminoalquilo; R10 representa hidrógeno, alquilo, cicloalquilo, halógeno, alquenilalquilo, alquinilalquilo, haloalquilo, alquinilo, alquenilo, cianoalquilo, cicloalquilalquilo, arilalquilo, heteroarilalquilo, alquilcarbonilo, alcoxicarbonilo, alqueniloxicarbonilo, alquenilalquiloxicarbonilo, arilalquiloxicarbonilo, cicloalcoxicarbonilo, cicloalquilalcoxicarbonilo, alquilsulfonilo, arilsulfonilo, cicloalquilsulfonilo, alquilsulfinilo, arilsulfinilo, cicloalquilsulfinilo, aIcoxicarboniIaIquilo, hidroxicarbonitalquilo, arilalcoxicarbonilalquilo, cicloalquilalcoxicarbonilalquilo, aIcoxicarboniIcicloaIquiIo, hidroxicarbonilcicloalquilo, arilalcoxicarbonilcicloalquilo, alqueniloxicarbonilcicloalquilo, aminocarbonilcicloalquilo, alquilaminocarbonilcicloalquilo, cicloalquilaminocarbonilcicloalquilo, alcoxicarbonilcicloalquenilo, hidroxicarbonilcicloalquenilo, bis-alquilaminoalquilo, hidroxicarbonilheterociclilo, alcoxicarbonilheterociclilo, alqueniloxicarbonilheterociclilo, aIqueniIaIcoxicarboniIheterocicIio, arilalcoxicarbonilheterociclilo, cicloalcoxicarbonilheterociclilo, cicloalquilalcoxicarbonilheterociclilo, aminocarbonilheterociclilo, alquilaminocarbonilheterociclilo, bis-alquilaminocarbonilheterociclilo, cicloalquilaminocarbonilheterociclilo, arilalquilaminocarbonilheterociclilo, alquenilaminocarbonilheterociclilo, hidroxicarbonilheterociclilalquilo, alcoxicarbonilheterociclilalquilo, hidroxicarbonilcicloalquilalquilo, acoxicarboniIcicIoalquilaIquilo, hidroxilo, alcoxi; R11 representa hidrógeno, alquilo, cicloalquilo, halógeno, alquilalquenilo, halógenoalquilo, alquinilo, alquenilo, cianoalquilo, arilalquilo, heteroarilalquilo, alquilcarbonilo, alcoxicarbonilo, alquilsulfonilo, arilsulfonilo, cicloalquilsulfonilo, alquilsulfinilo, arilsulfinilo, cicloalquilsulfinilo, alcoxicarbonilalquilo, o R10 y R11 con el nitrógeno al que están unidos forman un anillo de tres a ocho miembros dado el caso sustituido con halógeno, alquilo, haloalquilo, alcoxi, alcoxicarbonilo, cicboalcoxicarbonilo, cicloalquilalcoxicarbonilo, alqueniboxicarbonilo, hidroxicarbonilo, aminocarbonilo, alquilaminocarbonilo, cicloalquilaminocarbonilo, arilalquilaminocarbonilo, que dado el caso está interrumpido por O, S o N, o R10 y R11 conjuntamente forman parte de un grupo sulfilimina o amidina dado el caso sustituido o forman un iminofosforano, con excepción de ácido (2Z,4E)-5-(2-hidroxi-1,3-dimetil-5-oxobiciclo[4.1.0]hept-3-en-2-il)-3-metilpenta-2,4-dienoico, ácido (2E,4E)-5-(2-hidroxi-1,3-dimetil-5-oxobiciclo[4.1,0]hept-3-en-2-il)-3-metilpenta-2,4-dienoico, (2Z,4E)-5-(2-hidroxi-1,3-dimetil-5-oxobiciclo[4,1,0]hept-3-en-2-il)-3-metilpenta-2,4-dienoato de metilo y (2E,4E)-5-(2-hidroxi-1,3-dimetil-5-oxobiciclo[4,1,0]hept-3-en-2-il)-3-metilpenta-2,4-dienoato de metilo.
ARP120101003A 2011-04-15 2012-03-26 5-(biciclo[4.1.0]hept-3-en-2-il)-penta-2,4-dienos y 5-(biciclo[4.1.0]hept-3-en-2-il)-pent-2-en-4-inos sustituidos como principios activos contra el estres abiotico de las plantas AR085568A1 (es)

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