WO2023238530A1 - Procédé de production d'un film électroconducteur, panneau tactile, écran d'affichage - Google Patents

Procédé de production d'un film électroconducteur, panneau tactile, écran d'affichage Download PDF

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Publication number
WO2023238530A1
WO2023238530A1 PCT/JP2023/016108 JP2023016108W WO2023238530A1 WO 2023238530 A1 WO2023238530 A1 WO 2023238530A1 JP 2023016108 W JP2023016108 W JP 2023016108W WO 2023238530 A1 WO2023238530 A1 WO 2023238530A1
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WIPO (PCT)
Prior art keywords
dispersant
conductive film
organic resin
resin layer
manufacturing
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PCT/JP2023/016108
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English (en)
Japanese (ja)
Inventor
宏充 勝井
博幸 安田
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Jsr株式会社
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Publication of WO2023238530A1 publication Critical patent/WO2023238530A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/12—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials

Definitions

  • electrodes and wiring of semiconductor devices have often been formed of metals such as copper and aluminum.
  • metals such as copper and aluminum.
  • nanocarbon materials particularly carbon nanotubes (hereinafter sometimes abbreviated as "CNT")
  • CNT carbon nanotubes
  • conductive films made of nanocarbon materials can be formed into films that exhibit high transparency to visible light, there is a movement toward their active use in semiconductor optical devices.
  • Patent Document 1 listed below describes a composition in which a solvent and CNTs are used as a composition with improved dispersibility of CNTs.
  • Compositions containing the present invention are disclosed.
  • the conductive film produced using the above composition has a problem in that it tends to aggregate during the drying process and the like, and its homogeneity tends to be impaired.
  • a CNT transparent conductive film exhibits conductivity by forming a circuit through which current flows by folding fibrous CNTs like a nonwoven fabric. For this reason, unlike metal films and metal oxide films, it has been difficult to configure them to have stable characteristics, and it has been difficult to develop stable electrical characteristics.
  • a conductive film when used in light emitting devices, touch panels, etc., it is required to form a conductive film as thin as possible in order to increase the transparency of visible light, and it is also required to form a conductive film with high conductivity and uniformity. be done. Even in such a case, a problem arises in that the conductive film is likely to be disconnected, similar to the above-mentioned semiconductor devices such as LSIs. More specifically, for example, when configuring wiring constituting a touch panel, wiring is formed with a width of 50 ⁇ m or less, or when creating a pixel electrode of a display panel, a lead line from a contact hole with a width of 50 ⁇ m or less is created. In some cases, wire breakage is particularly likely to occur.
  • the method for manufacturing a conductive film of the present invention includes: a step (A) of applying an organic resin material containing a polymer having a hydrocarbon group onto a base material to form an organic resin layer; After carrying out the step (A), a step (B) of applying a dispersion liquid containing a dispersant and carbon nanotubes on the organic resin layer to form a coating film; After carrying out the step (B), a step (C) of drying the coating film; After carrying out the step (C), the method includes a step (D) of attaching a dispersant extract and removing the dispersant from the coating film.
  • the step (D) may be a step of forming the coating film by immersing the base material in a dispersant extract.
  • the dispersant is preferably a polymer having a constituent part represented by the following formula (1).
  • the step (B) is a step of applying the dispersion liquid in which the content of the dispersant to the carbon material is within the range of 1,000% by mass to 100,000% by mass on the organic resin layer. I don't mind.
  • the display panel of the present invention includes: A conductive film manufactured by the above manufacturing method is provided.
  • a method for manufacturing a conductive film that has high conductivity and can evenly fix a conductive carbon material over the entire conductive film formation region.
  • FIG. 1 is a schematic diagram showing the overall configuration of an embodiment of a display panel.
  • 3 is a drawing schematically showing a process of forming a conductive film.
  • 3 is a drawing schematically showing a process of forming a conductive film.
  • 3 is a drawing schematically showing a process of forming a conductive film. This is an AFM photograph of the surface of the substrate. This is an AFM photograph of the surface of the substrate.
  • the configuration of the display panel 1 as one embodiment will be explained first, and then the details of one embodiment of the method for manufacturing the conductive film included in the display panel 1 will be explained. Then, a verification and evaluation experiment was conducted to confirm the effects of the present invention using an example of the method for manufacturing a conductive film of the present invention, and finally, the details of the verification and evaluation experiment will be explained.
  • FIG. 1 is a schematic diagram showing the overall configuration of one embodiment of a display panel 1. As shown in FIG. The display panel 1 has a base material 2, and one surface of the base material 2 is provided with an element region 2a and a peripheral region 2b.
  • the base material 2 is formed of a material having translucency, and specifically includes, for example, a glass substrate, a quartz substrate, or an organic resin substrate.
  • the material for the organic resin substrate include polyimide.
  • the organic resin substrate can have a thickness ranging from several micrometers to several tens of micrometers, making it possible to realize a flexible sheet display.
  • the element area 2a is an area where elements for displaying images are formed.
  • a lower layer electrode is provided, and an insulating layer is provided on the lower layer electrode.
  • An organic resin layer is provided on the insulating layer, and a conductive film is provided on the organic resin layer.
  • the material of the organic resin layer is an organic material containing a polymer having hydrocarbon groups.
  • the material of the conductive film is CNT.
  • As the type of CNT single-walled carbon nanotubes or multi-walled carbon nanotubes having two or more layers can be employed, and single-walled carbon nanotubes are preferable.
  • a conductive film made of carbon nanotubes has a transmittance that varies depending on the film thickness, but is a transparent conductive film that is transparent to visible light.
  • the material constituting the organic resin layer is an organic resin material containing a polymer having a hydrocarbon group.
  • examples of the material constituting the organic resin layer include polyimide resin, polyamide resin, polyether resin, polyester resin, and the like.
  • the material constituting the organic resin layer is preferably a material containing an aromatic hydrocarbon, and more preferably a material containing a polycyclic aromatic hydrocarbon.
  • the coating film is formed by applying a dispersion liquid containing carbon nanotubes and a dispersant.
  • the dispersant is not particularly limited, it is preferable to use a polyamic acid having a structural moiety represented by formula (1) in terms of improving the dispersibility of carbon nanotubes. Just to be sure, equation (1) is reproduced.
  • R 1 is a tetravalent organic group that constitutes a tetracarboxylic acid
  • R 2 is a divalent organic group that constitutes a diamine
  • n represents a positive integer.
  • tetravalent organic group constituting the tetracarboxylic acid represented by R1 include pyromellitic acid, 2,3,6,7-naphthalenetetracarboxylic acid, and 1,2,5,6-naphthalenetetracarboxylic acid.
  • Carboxylic acid 1,4,5,8-naphthalenetetracarboxylic acid, 2,3,6,7-anthracenetetracarboxylic acid, 1,2,5,6-anthracenetetracarboxylic acid, 3,3',4,4 '-Biphenyltetracarboxylic acid, 2,3,3',4-biphenyltetracarboxylic acid, bis(3,4-dicarboxyphenyl) ether, 3,3'4,4'-benzophenonetetracarboxylic acid, bis(3 ,4-dicarboxyphenyl) sulfone, bis(3,4-dicarboxyphenyl)methane, 2,2-bis(3,4-dicarboxyphenyl)propane, 1,1,1,3,3,3-hexane Fluoro-2,2-bis(3,4-dicarboxyphenyl)propane, bis(3,4-dicarboxyphenyl)dimethylsilane, bis(3,4-dica
  • divalent organic group constituting the diamine represented by R2 include p-phenylenediamine, m-phenylenediamine, 2,5-diaminotoluene, 2,6-diaminotoluene, 4,4'-diamino Biphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 3,3'-dimethoxy-4,4'-diaminobiphenyl, diaminodiphenylmethane, diaminodiphenyl ether, 2,2'-diaminodiphenylpropane, bis(3 ,5-diethyl-4-aminophenyl)methane, diaminodiphenylsulfone, diaminobenzophenone, diaminonaphthalene, 1,4-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenyl)benzene, 9, 10-bis(
  • R 1 in the above formula (1) is a cyclobutane ring.
  • the ring structure decomposes and a structural change of the polyamic acid occurs, thereby making it possible to remove the dispersant. This is preferable in that it can be easily removed.
  • the above-mentioned dispersion liquid may contain an organic solvent as a dispersion medium.
  • FIGS. 2 to 4. are drawings schematically showing the process of forming a conductive film. Note that in the method for manufacturing a conductive film of this embodiment, a conductive film is manufactured on an insulating layer formed on a substrate.
  • a dispersion containing CNTs is applied onto the organic resin layer 20 to form a pattern of a coating film 30 (corresponding to step (B)). Note that in FIG. 3, for convenience, the coating film 30 is illustrated as being formed over the entire surface of the organic resin layer 20.
  • a pattern is formed by a coating film of a dispersion containing CNTs on the organic resin layer 20 using printing techniques such as casting, screen printing, and inkjet.
  • the solvent contained in the coating film is removed by drying, and the CNTs are fixed on the organic resin layer 20 to form a conductive film 40 (corresponding to step (C)).
  • the conductive film 40 is illustrated as being formed over the entire surface of the organic resin layer 20, but the pattern of the conductive film 40 may be adjusted as appropriate.
  • a dispersant extract is applied onto the conductive film formed on the substrate, and the dispersant is removed from the pattern formed by the coated film (corresponding to step (D)).
  • a dispersion liquid is applied to the entire organic resin layer formed on the substrate, and then dried and washed. After this, it is also possible to separately form a photosensitive resist layer for patterning on the conductive film. In this case, after forming the photosensitive resist layer, the conductive layer is removed by etching, and the remaining photosensitive resist layer is removed.
  • the combination of the dispersant and the dispersant extract is arbitrary, but the dispersant is an alkali-soluble polymer having a functional group that improves solubility in an alkaline aqueous solution, and the dispersant extract is an alkaline aqueous solution. is preferred.
  • an alkaline aqueous solution as a dispersant extract, it becomes possible to selectively leave CNTs that are difficult to disperse in an alkaline aqueous solution on the organic resin layer.
  • the polyamic acid structure of the dispersant may include a site such as cyclobutane that can be decomposed by light or heat to change the entire structure of the polyamic acid.
  • the dispersant may contain an acid-dissociable group.
  • An acid-dissociable group is a group that generates an acidic group such as a carboxyl group or a phenolic hydroxyl group by the action of an acid.
  • the content of the dispersant relative to the CNTs is preferably within the range of 1,000% by mass to 100,000% by mass.
  • the content of the dispersant for the CNTs is within this range, non-uniformity of the solvent in the drying process is prevented, and aggregation and localization of the CNTs due to drying is suppressed.
  • the slit die coating method or the inkjet method is preferable from the viewpoint of uniformity of the coating film thickness and liquid saving. Further, from the viewpoint that electrode patterning can be performed only by coating, the inkjet method is more preferable.
  • the CNTs contained in the coating film exhibit high adhesion to the organic resin layer, localization due to aggregation of the solvent in the drying process is suppressed. Furthermore, even in the solution immersion step for removing the dispersant, peeling and aggregation of CNTs do not occur, and localization of CNTs is suppressed. Therefore, even if a wiring with a very narrow pattern width is formed, locally high resistance parts and disconnections are less likely to occur.
  • the organic resin layer can be formed by using the radiation-sensitive composition for forming the organic resin layer through the steps shown below.
  • the organic resin layer formed by this formation method exhibits unique electrical properties, has excellent adhesion to CNTs, and has good chemical resistance and flatness. Further, according to the formation method, since heating is performed at 140° C. or lower, thermal deterioration of the substrate and elements provided on the substrate is suppressed. Each step will be explained in detail below.
  • the radiation used at this time examples include ultraviolet rays, deep ultraviolet rays, X-rays, and charged particle beams.
  • the mask used may be a multi-tone mask such as a halftone mask or a graytone mask.
  • Synthesis of polymer [Synthesis example 1: Synthesis of polyamic acid] A polyamic acid having a hydrocarbon group in its side chain (hereinafter referred to as "polymer (paa-1)”) was obtained by the synthesis method described in Patent Document 2 above.
  • FIG. 5 and 6 are both photographs taken using AFM of the surface of the substrate.
  • FIG. 5 is an example of a photograph of the substrate surface where the unevenness of CNTs is observed
  • FIG. This is an example of a photograph of a substrate surface that is not observed by AFM, that is, CNTs are covered with a resin/dispersant. If the dispersant on the surface has been removed and CNTs (carbon nanotubes) are exposed as shown in Figure 5, it is rated as “Good (A)”, and as shown in Figure 6, CNTs are partially exposed. A sample was rated as “fair (B)", and a sample where the surface was covered with resin and no exposed CNTs were observed, or the film formation was poor and could not be determined was graded as "poor (C)".

Abstract

L'invention concerne un procédé de production d'un film électroconducteur qui présente une électroconductivité élevée et qui est capable de fixer uniformément un matériau carboné électroconducteur sur la totalité d'une région de formation de film électroconducteur.　Le procédé comprend une étape (A) pour appliquer un matériau de résine organique qui contient un polymère ayant un groupe hydrocarboné à un matériau de base et former une couche de résine organique, une étape (B) pour appliquer une dispersion liquide qui contient un dispersant et des nanotubes de carbone à la couche de résine organique et former un film de revêtement après l'étape (A), une étape (C) pour sécher le film de revêtement après l'étape (B), et une étape (D) pour mettre en œuvre une extraction de dispersant pour éliminer le dispersant du film de revêtement après l'étape (C).
PCT/JP2023/016108 2022-06-09 2023-04-24 Procédé de production d'un film électroconducteur, panneau tactile, écran d'affichage WO2023238530A1 (fr)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008177143A (ja) * 2006-03-28 2008-07-31 Toray Ind Inc 透明導電性フィルム、その製造方法および導電性部材
JP2008200613A (ja) * 2007-02-20 2008-09-04 Toray Ind Inc カーボンナノチューブコーティング膜およびその製造方法
JP2010202729A (ja) * 2009-03-02 2010-09-16 Hitachi Chemical Dupont Microsystems Ltd フレキシブルデバイス基板用ポリイミド前駆体樹脂組成物及びそれを用いたフレキシブルデバイスの製造方法、フレキシブルデバイス
JP2010214837A (ja) * 2009-03-18 2010-09-30 Toray Ind Inc 透明導電膜付き基材の製造方法
JP2020090626A (ja) * 2018-12-06 2020-06-11 株式会社マルアイ Ｒｆｉｄ用インキ組成物とそれを用いたｒｆｉｄの導電性パターンの製造方法
WO2021033482A1 (fr) * 2019-08-19 2021-02-25 Jsr株式会社 Composition de dispersion, dispersant, film anisotrope et son procédé de production, et appareil de formation de film anisotrope

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008177143A (ja) * 2006-03-28 2008-07-31 Toray Ind Inc 透明導電性フィルム、その製造方法および導電性部材
JP2008200613A (ja) * 2007-02-20 2008-09-04 Toray Ind Inc カーボンナノチューブコーティング膜およびその製造方法
JP2010202729A (ja) * 2009-03-02 2010-09-16 Hitachi Chemical Dupont Microsystems Ltd フレキシブルデバイス基板用ポリイミド前駆体樹脂組成物及びそれを用いたフレキシブルデバイスの製造方法、フレキシブルデバイス
JP2010214837A (ja) * 2009-03-18 2010-09-30 Toray Ind Inc 透明導電膜付き基材の製造方法
JP2020090626A (ja) * 2018-12-06 2020-06-11 株式会社マルアイ Ｒｆｉｄ用インキ組成物とそれを用いたｒｆｉｄの導電性パターンの製造方法
WO2021033482A1 (fr) * 2019-08-19 2021-02-25 Jsr株式会社 Composition de dispersion, dispersant, film anisotrope et son procédé de production, et appareil de formation de film anisotrope

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