WO2020213662A1 - ペリクル用粘着剤、ペリクル、ペリクル付露光原版、半導体装置の製造方法、液晶表示板の製造方法、露光原版の再生方法及び剥離残渣低減方法 - Google Patents
ペリクル用粘着剤、ペリクル、ペリクル付露光原版、半導体装置の製造方法、液晶表示板の製造方法、露光原版の再生方法及び剥離残渣低減方法 Download PDFInfo
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- WO2020213662A1 WO2020213662A1 PCT/JP2020/016628 JP2020016628W WO2020213662A1 WO 2020213662 A1 WO2020213662 A1 WO 2020213662A1 JP 2020016628 W JP2020016628 W JP 2020016628W WO 2020213662 A1 WO2020213662 A1 WO 2020213662A1
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- pellicle
- original plate
- exposure original
- pressure
- sensitive adhesive
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/62—Pellicles, e.g. pellicle assemblies, e.g. having membrane on support frame; Preparation thereof
- G03F1/64—Pellicles, e.g. pellicle assemblies, e.g. having membrane on support frame; Preparation thereof characterised by the frames, e.g. structure or material, including bonding means therefor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/10—Homopolymers or copolymers of unsaturated ethers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/26—Phase shift masks [PSM]; PSM blanks; Preparation thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/62—Pellicles, e.g. pellicle assemblies, e.g. having membrane on support frame; Preparation thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/66—Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/708—Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
- G03F7/70983—Optical system protection, e.g. pellicles or removable covers for protection of mask
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
- H01L21/0274—Photolithographic processes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
Definitions
- the present invention relates to an adhesive for pellicle, a pellicle, an exposure original plate with a pellicle, a method for manufacturing a semiconductor device, a method for manufacturing a liquid crystal display plate, a method for regenerating an exposure original plate, and a method for reducing peeling residue.
- the "exposure original plate” is a general term for a mask for lithography and a reticle.
- the basic structure of the pellicle consists of a pellicle frame and a pellicle membrane stretched on the pellicle frame.
- the pellicle film is made of nitrocellulose, cellulose acetate, a fluorine-based polymer, or the like that well transmits light used for exposure (g-line, i-line, 248 nm, 193 nm, 157 nm, etc.).
- the pellicle frame is made of an aluminum alloy such as A7075, A6061, A5052, which has been subjected to black alumite treatment or the like, stainless steel, polyethylene, or the like.
- a good solvent for the pellicle film is applied to the upper part of the pellicle frame, and the pellicle film is air-dried and adhered, or adhered with an adhesive such as acrylic resin, epoxy resin, or fluororesin. Further, since the exposure original plate is mounted on the lower part of the pellicle frame, it is used for protection for the purpose of protecting the pressure-sensitive adhesive layer obtained from polybutene resin, polyvinyl acetate resin, acrylic resin, silicone resin, etc., and the pressure-sensitive adhesive layer. Provide a liner.
- the pellicle is installed so as to surround the pattern area formed on the surface of the exposure original plate. Since the pellicle is provided to prevent dust from adhering to the exposure original plate, the pattern region and the outside of the pellicle are separated from each other so that dust outside the pellicle does not adhere to the pattern surface.
- phase shift film As the mask substrate film used in recent years, a phase shift film has come to be generally adopted in order to cope with the miniaturization of design rules.
- the phase shift film is very delicate, and mask cleaning under excessive conditions may damage the phase shift film such as corrosion and scraping. Therefore, in recent years, the chemical solution used for mask cleaning has been reexamined. Or tend to weaken the cleaning conditions.
- the mask pattern of advanced products has changed from the positive type mask pattern, which has been the mainstream until now, to the negative type mask pattern, and along with this, there is no light-shielding layer in the part where the pellicle is attached. There are many. Without the light-shielding layer, the pellicle adhesive may be exposed to light through the mask substrate. Then, when the pellicle is peeled off, more residue of the adhesive layer may remain on the mask substrate.
- repelicle When the pellicle is used by attaching it to the mask, if foreign matter or haze is generated or the pellicle film is damaged, it is necessary to peel off the pellicle, re-clean the mask, and replace it with a new pellicle. (Hereafter referred to as "repellicle"). The most important thing in the repelicle is to re-clean the mask so that it is in a highly clean state, but in order to re-clean the mask under weak cleaning conditions in recent years, when the pellicle is peeled off, It is important how to reduce the residue remaining on the mask substrate.
- Fuctional water is generally an aqueous solution that has been given reproducible and useful functions by artificial treatment, and the scientific basis for treatment and function has been clarified, and is about to be clarified. It is defined as what is. Specific examples include fine bubble water such as ozone water, hydrogen water, microbubble water, and nanobubble water, electrolyzed water, supercritical water, and subcritical water. Ozone water and hydrogen are used to clean the photomask. A lot of water is used. In addition, the detergency can be improved by adding a small amount of ammonia.
- a lithographic pellicle in which a pellicle film is attached to the upper end surface of the pellicle frame via an adhesive layer for attaching a pellicle film, and an adhesive layer for attaching a mask is provided on the other end surface, such as an ArF excimer laser (193 nm).
- Patent Document 1 and Patent Document 2 As a technique for reducing the residue, attempts have been made to add a surface modifier or the like to the pressure-sensitive adhesive (Patent Document 1 and Patent Document 2). Further, as a technique for reducing the residue, a large pellicle having an adhesive layer having a cohesive breaking strength of 20 g / mm 2 or more (Patent Document 3), and a ratio of peel strength to tensile strength of 0.10 or more is 0. A pellicle having a pellicle adhesive of 33 or less is disclosed (Patent Document 4).
- the present invention has been made in view of such a situation, and when the pellicle is peeled off from the exposure original plate after using lithography, particularly after using ArF lithography, the pellicle that can reduce the residue sticking to the exposure original plate can be reduced. It is an object of the present invention to provide a pressure-sensitive adhesive, a pellicle, an exposure original plate with a pellicle, a method for regenerating an exposure original plate, and a method for reducing peeling residue. It is an object of the present invention to provide a method for manufacturing a semiconductor device and a liquid crystal display board capable of improving production efficiency.
- the above-mentioned [1] to [5] which contains an acrylic polymer and have a polyvinyl ether compound content of 0.5 to 10 parts by mass with respect to 100 parts by mass of the solid content of the acrylic polymer.
- 3] The adhesive for a pellicle according to any one of.
- [6] The pressure-sensitive adhesive for pellicle according to the above [4] or [5], wherein the acrylic polymer contains a (meth) acrylic acid ester having an ether bond as a monomer component.
- the (meth) acrylic acid ester having an ether bond is a (meth) acrylic acid ester having an alkylene oxide group.
- the exposure original plate with a pellicle according to the above [22], wherein the portion to which the pressure-sensitive adhesive layer of the exposure original plate is attached has a non-light-shielding region or a translucent light-shielding region.
- the exposure original plate with a pellicle according to the above [22], wherein the portion to which the pressure-sensitive adhesive layer of the exposure original plate is attached has a transparent region.
- [28] The exposure original plate with a pellicle according to the above [22], wherein the exposure original plate is a quartz substrate.
- a method for manufacturing a semiconductor device comprising a step of exposing with an exposure original plate with a pellicle according to any one of [22] to [28].
- a method for manufacturing a liquid crystal display board comprising a step of exposing with an exposure original plate with a pellicle according to any one of [22] to [28].
- a pellicle having a pellicle film, a pellicle frame having the pellicle film provided on one end face, and a pressure-sensitive adhesive layer obtained from the pellicle adhesive provided on the other end face of the pellicle frame. It is an application of a pellicle that is attached to an exposure original plate that has an area that is not shaded or a translucent light-shielding region in the portion where the adhesive layer is attached in the exposure original plate.
- the peeling residue reducing pellicle according to [40] wherein the composition according to [40] contains 0.5 to 10 parts by mass of a polyvinyl ether compound with respect to 100 parts by mass of the solid content of the acrylic resin.
- An adhesive for attaching a pellicle to an exposure original plate is formed from a composition containing an acrylic resin and a polyvinyl ether compound, and the adhesive is applied to one end face of a pellicle frame to form an adhesive layer.
- a method for producing a peeling residue-reducing pellicle which comprises making, attaching a protective member to the peelable member, applying an adhesive to the other end face of the pellicle frame, and attaching a pellicle film to the adhesive.
- a method for reducing the peeling residue of the adhesive layer of the pellicle remaining on the exposure original plate when the pellicle is peeled off from the exposure original plate to which the pellicle is attached [45] A method characterized by using the pellicle according to any one of.
- the peeling residue of the adhesive layer of the pellicle remaining on the exposure original plate can be reduced.
- a pellicle, an exposure original plate with a pellicle, a method for regenerating the exposure original plate, and a method for reducing peeling residue In the method for regenerating the pellicle, the exposure original plate with the pellicle, the exposure original plate, and the peeling residue reduction method of the present invention, even if the exposure light is irradiated through the exposure original plate, the peeling residue of the adhesive is generated when the pellicle is peeled from the exposure original plate.
- the pellicle 10 of the present invention has a pellicle film 12 stretched on the upper end surface of the pellicle frame 11 via an adhesive layer 13 for attaching the pellicle film.
- the pellicle 10 is attached.
- An adhesive layer 14 for adhering to the exposure original plate (mask substrate or reticle) 1 is usually formed on the lower end surface of the pellicle frame 11, and a liner (not shown) is detachably attached to the lower end surface of the adhesive layer 14. It is made up of.
- the pellicle frame 11 may be provided with an air pressure adjusting hole (vent) 15, and a dust removing filter 16 may be provided for the purpose of removing particles.
- the size of these pellicle components is the same as that of a normal pellicle, for example, a pellicle for semiconductor lithography, a pellicle for a large liquid crystal display board manufacturing lithography process, etc., and the material thereof is also a known material as described above. can do.
- the type of the pellicle film 12 is not particularly limited, and for example, an amorphous fluoropolymer or the like conventionally used for an excimer laser is used.
- the amorphous fluoropolymer include Cytop (trade name manufactured by Asahi Glass Co., Ltd.), Teflon (registered trademark) AF (trade name manufactured by DuPont) and the like. These polymers may be dissolved in a solvent and used when the pellicle film is produced, and can be appropriately dissolved in, for example, a fluorine-based solvent.
- the base material of the pellicle frame 11 for example, a conventionally used aluminum alloy material, preferably JIS A7075, JIS A6061, JIS A5052 material or the like is used, but when an aluminum alloy material is used, the pellicle frame is used. There is no particular limitation as long as the strength of is secured.
- the surface of the pellicle frame is preferably roughened by sandblasting or chemical polishing, and a polymer film may be provided after the roughening.
- a conventionally known method can be adopted as the method for roughening the frame surface.
- a method is preferable in which the surface of the aluminum alloy material is blasted with stainless steel, carborundum, glass beads or the like, and further chemically polished with NaOH or the like to roughen the surface.
- the present inventors have repeated many studies and experiments in order to solve the above-mentioned problems of the present invention, paying particular attention to the characteristics of the pressure-sensitive adhesive forming the pressure-sensitive adhesive layer, and comparing and analyzing the experimental results. It was found that the following means are effective.
- the pressure-sensitive adhesive layer is irradiated with an exposure ray (for example, ultraviolet rays of 193 nm) when the pellicle is used, it is easy to suppress the peeling residue.
- an exposure ray for example, ultraviolet rays of 193 nm
- the inclusion of the polyvinyl ether compound in the pressure-sensitive adhesive facilitates the control of hydrophilicity as the pressure-sensitive adhesive and improves the cohesive force as the pressure-sensitive adhesive. It is inferred that.
- polyvinyl ether compound examples include copolymers of vinyl ethers such as methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, isobutyl vinyl ether, and (2-methoxyethyl) vinyl ether, and two or more kinds of vinyl ethers. Examples thereof include copolymers of the above, copolymers of these vinyl ethers and other monomers, and the like. Among these, a polyvinyl ether compound containing methyl vinyl ether as a raw material monomer is preferable from the viewpoint of controlling the peeling residue.
- the adhesive for pellicle may contain other high molecular weight components in addition to the polyvinyl ether compound.
- these high molecular weight components include acrylic polymers (also referred to as acrylic resins), silicone resins, and thermoplastic elastomers. Since various monomer components can be selected for the acrylic polymer, it is easy to design the acrylic polymer according to the required adhesive properties. Silicone resin has an excellent balance of light resistance, adhesive properties, peeling properties, and the like. Thermoplastic elastomers are cost-competitive.
- these high molecular weight components have compatibility with the polyvinyl ether compound. It is considered that by increasing the compatibility, the vinyl ether group can be uniformly dispersed in the pressure-sensitive adhesive layer, which leads to the improvement of the peeling property.
- the polymer blend state is such that substantially uniform dispersion can be maintained within the period of use under the conditions of use of the adhesive for pellicle.
- the polymer blended state means a state in which a thin film (for example, a thin film of 20 ⁇ m) can be formed by a mixture of a polyvinyl ether compound and a high molecular weight component, or a state in which the mixture maintains transparency. ..
- a compatibilizer or a solvent that dissolves both the polyvinyl ether compound and the high molecular weight component may be used for mixing.
- the acrylic polymer is, for example, a polymer containing a (meth) acrylic acid ester as a monomer component, and if necessary, copolymerizes a monomer component copolymerizable with the (meth) acrylic acid ester. be able to.
- the (meth) acrylic acid ester include a (meth) acrylic acid ester having an ether bond, a (meth) acrylic acid alkyl ester, an unsaturated monomer having a carboxyl group or a hydroxyl group, and the like.
- Examples of the (meth) acrylic acid ester having an ether bond (component (A)) include a (meth) acrylic acid ester having an alkylene oxide group such as an ethylene oxide group, a propylene oxide group, and a butylene oxide group.
- (meth) acrylic acid ester having an ethylene oxide group (also referred to as ethylene oxide group-containing (meth) acrylate) is preferable, and for example, 2-methoxyethyl (meth) acrylate, 2-ethoxyethyl (meth) acrylate, 2 -Butoxyethyl (meth) acrylate, phenoxyethylene glycol (meth) acrylate, methoxypolyethylene glycol (meth) acrylate such as methoxydiethylene glycol (meth) acrylate, ethoxypolyethylene glycol (meth) acrylate such as ethoxydiethylene glycol (meth) acrylate, butoxydiethylene glycol Examples thereof include butoxypolyethylene glycol (meth) acrylate such as (meth) acrylate and phenoxypolyethylene glycol (meth) acrylate such as phenoxydiethylene glycol (meth) acrylate. These may be used alone or in combination of two or
- Examples of the (meth) acrylic acid alkyl ester (component (B)) include a (meth) acrylic acid alkyl ester having an alkyl group having 1 to 14 carbon atoms. Specifically, methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, isoamyl (meth) acrylate, hexyl (meth) acrylate, 2 -Ethylhexyl (meth) acrylate, n-octyl (meth) acrylate, isooctyl (meth) acrylate, isononyl (meth) acrylate, lauryl (meth) acrylate and the like can be mentioned. Among these, (meth) acrylic acid alkyl esters having an alkyl group having 4 or 8 carbon atoms are preferable from the
- Examples of the unsaturated monomer (component (C)) having a carboxyl group or a hydroxyl group include ⁇ , ⁇ -unsaturated carboxylic acids such as (meth) acrylic acid, maleic acid, crotonic acid, itaconic acid, and fumaric acid, and 2 Examples thereof include hydroxyl group-containing methacrylates such as -hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, and 2-hydroxybutyl (meth) acrylate. These may be used alone or in combination of two or more.
- the ratio of the component (A) to be used is preferably 30% by mass or more, more preferably 35% by mass or more, and 35 to 98% by mass in the total monomer components. It is particularly preferable that the amount is 40 to 95% by mass, and it is extremely preferable that the content is 40 to 95% by mass.
- the ratio of the component (B) used is preferably 0 to 70% by mass, more preferably 3 to 55% by mass, based on all the monomer components. By setting the ratio of the component (B) to the above range, the adhesiveness can be easily controlled.
- the ratio of the component (C) used is preferably 0 to 10% by mass, more preferably 2 to 8% by mass, based on all the monomer components.
- the acrylic polymer can be produced by appropriately selecting a known production method such as solution polymerization, bulk polymerization, emulsion polymerization, or radical polymerization. Further, the obtained acrylic polymer may be any of a random copolymer, a block copolymer, a graft copolymer and the like.
- the above weight average molecular weight is a value measured by gel permeation chromatography (GPC) analysis and means a standard polystyrene equivalent value. GPC analysis can be performed using tetrahydrofuran (THF) as the solution.
- the pressure-sensitive adhesive in the pressure-sensitive adhesive layer preferably contains a reaction product of an acrylic polymer and a curing agent, but in consideration of softness, an acrylic weight that does not react with the curing agent. It may include coalescence.
- the curing agent is not particularly limited as long as it is a curing material used as an ordinary pressure-sensitive adhesive, and for example, a metal salt, a metal alkoxide, an aldehyde compound, a non-amino resin amino compound, a urea compound, an isocyanate compound, etc.
- a metal salt e.g., a metal salt, a metal alkoxide, an aldehyde compound, a non-amino resin amino compound, a urea compound, an isocyanate compound, etc.
- examples thereof include polyfunctional epoxy compounds, metal chelate compounds, melamine compounds, and isocyanate compounds.
- isocyanate compounds and epoxy compounds are preferable from the viewpoint of reactivity with a carboxyl group or a hydroxyl group.
- isocyanate-based compounds include xylylene diisocyanate, hexamethylene diisocyanate, tolylene diisocyanate, multimers, derivatives, and polymers thereof. These may be used alone or in combination of two or more.
- Examples of the epoxy compound include compounds having two or more epoxy groups in the molecule, and specific examples thereof include ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, glycerin diglycidyl ether, and glycerin triglycidyl ether. 1,6-Hexanediol diglycidyl ether, trimethylpropan triglycidyl ether, diglycidyl aniline, diamine glycidyl amine, N, N, N', N'-tetraglycidyl-m-xylylene diamine, 1,3-bis ( N, N'-diamine glycidyl aminomethyl) and the like. These may be used alone or in combination of two or more.
- a silicone resin known as an adhesive can be preferably used.
- an organopolysiloxane having silanol groups at both ends of the molecular chain is represented by R 3 SiO 0.5 (where R indicates a substituted or unsubstituted monovalent hydrocarbon group) in the molecule.
- R indicates a substituted or unsubstituted monovalent hydrocarbon group
- examples thereof include those obtained by partially dehydrating and condensing an organopolysiloxane having a triorganosiloxane unit and a SiO 2 unit.
- These are available as silicone-based adhesives KR-101-10, KR-120, KR-130, and X-40-3068 (all of which are trade names manufactured by Shin-Etsu Chemical Co., Ltd.).
- thermoplastic elastomer examples include styrene-based thermoplastic elastomers, (meth) acrylic acid ester-based thermoplastic elastomers, and olefin-based thermoplastic elastomers. More specifically, the thermoplastic elastomer described in Japanese Patent No. 5513616 can be used. Among these high molecular weight components, the acrylic polymer is preferable because it is easy to control the mixing property with the polyvinyl ether compound. These high molecular weight components may be used alone or in combination of two or more.
- the content of the polyvinyl ether compound is preferably 0.5 parts by mass or more, more preferably 0.5 to 10 parts by mass, based on 100 parts by mass of the solid content of the high molecular weight component. It is particularly preferably 3 to 7 parts by mass.
- the pressure-sensitive adhesive (the composition) forming the pressure-sensitive adhesive layer of the pellicle includes a cross-linking agent, an antistatic agent, a plasticizer, a stabilizer, and a viscosity adjusting agent as long as the characteristics of the present invention are not impaired.
- the shape of the pressure-sensitive adhesive layer 14 is preferably flattened with little deformation when the pellicle is attached, in order to reduce the influence of distortion and the like on the mask substrate to be attached and to suppress the residual stress due to the pellicle attachment.
- a liquid or paste-like pressure-sensitive adhesive in an uncured state is applied to the lower end surface of the pellicle frame 11 and then cured to form a pressure-sensitive adhesive layer.
- the pressure-sensitive adhesive may be applied once, or may be applied several times in order to obtain a predetermined thickness of the pressure-sensitive adhesive layer. In this case, it is preferable to allow the adhesive to stand as appropriate between each round until the shape of the adhesive after application is stable.
- the adhesive may be appropriately diluted with an organic solvent, alcohol, water or the like to reduce the viscosity of the adhesive before application.
- the adhesive can be applied by, for example, a dip, a spray, a brush coating, a coating device using a dispenser, or the like, but the coating using the coating device using a dispenser has stability, workability, yield, and the like. It is preferable from the point of view.
- the pressure-sensitive adhesive layer 14 is applied and formed first, and then the pellicle film 12 is stretched, but the order may be reversed.
- the pellicle film 12 is stretched, for example, by applying an adhesive to the upper end surface of the pellicle frame 11, then heating the pellicle frame 11 to cure the adhesive, and finally applying the adhesive to an aluminum frame larger than the pellicle frame 11.
- the upper end surface of the pellicle frame 11 on which the adhesive layer 13 for attaching the pellicle film is formed is attached to the pellicle film, and the excess protruding outside the pellicle frame 11 of the pellicle film is removed to complete the pellicle.
- the pellicle of the present invention By using the pellicle of the present invention having the configuration described above, it is possible to reduce the amount of adhesive residue when the pellicle is peeled off from the exposure original plate after using lithography. Further, according to the present invention, there is provided a method for reducing the peeling residue of the pressure-sensitive adhesive layer of the pellicle by using the pellicle of the present invention. Therefore, the pellicle of the present invention is useful as a phase shift photomask having the above-mentioned delicate phase shift film or a pellicle to be attached to a surface containing silicon oxide as a main component such as quartz.
- exposure light adheres to a negative type exposure original plate, an exposure original plate having a non-light-shielded area or a semi-transparent light-shielding area on the adhesive sticking portion, an exposure original plate having a transparent region on the adhesive sticking portion, and the like. It is also useful as a pellicle applied to an exposure original plate that irradiates the agent layer.
- the pressure-sensitive adhesive layer of the pellicle used for such an exposure original plate is exposed to an exposure ray through the exposure original plate from a surface opposite to the surface on which the pellicle of the exposure original plate is provided.
- the pellicle of the present invention is used not only as a protective member for suppressing foreign matter from adhering to the exposure master plate in the exposure apparatus, but also for protecting the exposure master plate during storage of the exposure master plate and transportation of the exposure master plate. It may be used as a protective member.
- an exposure original plate such as a photomask
- an exposure original plate with a pellicle can be manufactured.
- the method for manufacturing a semiconductor device or a liquid crystal display plate according to the present embodiment includes a step of exposing a substrate (semiconductor wafer or liquid crystal original plate) with the above-mentioned exposure original plate with a pellicle.
- a substrate semiconductor wafer or liquid crystal original plate
- the above exposure master plate with a pellicle is installed on a stepper in order to form a photoresist pattern corresponding to an integrated circuit or the like on a substrate. To expose.
- the yield in the lithography process can be improved by using the exposure original plate with a pellicle.
- the pellicle may be peeled off from the exposure original plate to perform regenerative cleaning of the exposure original plate.
- Example 1 After precision cleaning of an aluminum alloy pellicle frame (external size 149 mm x 115 mm x 3 mm, wall thickness 2 mm, flatness on the end face side coated with adhesive for mask attachment: 15 um), Soken Kagaku Co., Ltd.
- Acrylic adhesive solution (Product name: SK Dyne SN-70A, 30% by mass (solid content) using an acrylic polymer in which 95% by mass of the monomer component is an ethylene oxide group-containing (meth) acrylate as a base material. ), And a solution containing 2% by mass (solid content) of the polyvinyl ether compound) was applied and allowed to stand at room temperature for 60 minutes.
- a separator was placed on an aluminum plate having a flatness of 5 um, and a pellicle frame coated with an adhesive was placed so that the adhesive was facing downward. As a result, the adhesive was brought into contact with the flat separator and flattened. Next, the pellicle on the aluminum plate was placed in an oven at 60 ° C. for 60 minutes to cure the adhesive. Then, after taking out the pellicle together with the aluminum plate, the separator was peeled off.
- an adhesive (trade name: Cytop CTX-A) manufactured by Asahi Glass Co., Ltd. was applied to the end face on the opposite side of the adhesive application. Then, the pellicle frame was heated at 130 ° C. to cure the adhesive. Finally, the adhesive-coated end face side of the pellicle frame was attached to a pellicle film formed on an aluminum frame larger than the pellicle frame, and the portion outside the pellicle frame was removed to complete the pellicle.
- the 6025 mask substrate and the pellicle prepared earlier were set in the pasting device, and the pellicle was pasted on the mask substrate by pressurizing with a sticking load of 50 N and a load time of 30 seconds.
- Example 2 As a pressure-sensitive adhesive, a solution of an acrylic pressure-sensitive adhesive manufactured by Soken Kagaku Co., Ltd. (product name: SK Dyne SK-1495S, an acrylic polymer containing no (meth) acrylic acid ester having an ether bond as a monomer component is used as a base material.
- a pellicle was completed by the same method and material as in Example 1 except that a pressure-sensitive adhesive containing 5 parts by mass of a polyvinyl ether compound with respect to 100 parts by mass of a solution containing 30% by mass of a solid content was used. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1.
- Example 3 Example 1 except that a pressure-sensitive adhesive containing 2 parts by mass of a polyvinyl ether compound with respect to 100 parts by mass of a solution (product name: SK Dyne SN-70A) of an acrylic pressure-sensitive adhesive manufactured by Soken Kagaku Co., Ltd. was used as the pressure-sensitive adhesive.
- the pellicle was completed by the same method and material as. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1.
- Example 4 Example 1 except that as the pressure-sensitive adhesive, a pressure-sensitive adhesive containing 11 parts by mass of a polyvinyl ether compound with respect to 100 parts by mass of a solution of an acrylic pressure-sensitive adhesive manufactured by Soken Kagaku Co., Ltd. (product name: SK Dyne SK-1495S) was used.
- the pellicle was completed by the same method and material as. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1.
- Example 5 As a pressure-sensitive adhesive, a solution of an acrylic pressure-sensitive adhesive manufactured by Soken Kagaku Co., Ltd. (product name: SK Dyne SK-1425S, an acrylic polymer containing no (meth) acrylic acid ester having an ether bond as a monomer component is used as a base material.
- a pellicle was completed by the same method and material as in Example 1 except that a pressure-sensitive adhesive containing 3 parts by mass of a polyvinyl ether compound with respect to 100 parts by mass of a solution containing 30% by mass of a solid content was used. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1. When the mask substrate after peeling was visually observed, a solute residue of a thin adhesive was observed in the portion where the pellicle was attached. Again, the peeling residue could be removed by ultrasonic cleaning with functional water 5 minutes x 5 times.
- Example 1 The pellicle was completed by the same method and material as in Example 1 except that a polyvinyl ether compound was not used as the pressure-sensitive adhesive and only a solution of an acrylic pressure-sensitive adhesive manufactured by Soken Chemical Co., Ltd. (product name: SK Dyne SK-1495S) was used. .. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1.
- Example 2 The pellicle was completed by the same method and material as in Example 1 except that a polyvinyl ether compound was not used as the pressure-sensitive adhesive and only a solution of an acrylic pressure-sensitive adhesive manufactured by Soken Chemical Co., Ltd. (product name: SK Dyne SK-1425S) was used. .. Further, the pellicle was attached to the mask substrate and peeled off under the same conditions as in Example 1.
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Abstract
Description
この場合、ゴミは露光原版の表面上には直接付着せず、ペリクル膜上に付着するため、リソグラフィ時に焦点を露光原版のパターン上に合わせておけば、ペリクル膜上のゴミは転写に無関係となる。
この再生洗浄は一般的に硫酸過水、アンモニア過水等の薬剤による洗浄や、ブラシ、スポンジ等の物理的な洗浄が使用されている。しかしながら、フォトマスクへのダメージや硫酸イオンのフォトマスクへの残存を抑制するために、機能水による再生洗浄が検討されている。
[1]露光原版にペリクルを貼り付けるためのペリクル用粘着剤であって、
ポリビニルエーテル化合物を含有してなるペリクル用粘着剤。
[2]ポリビニルエーテル化合物が、ビニルエーテル類を単量体成分とする重合体、又は、ビニルエーテル類及びビニルエーテル類と共重合可能な単量体を重合成分とする重合体である前記[1]記載のペリクル用粘着剤。
[3]ビニルエーテル類が、メチルビニルエ―テル、エチルビニルエ―テル、ブチルビニルエ―テル、イソブチルビニルエ―テル及び(2-メトキシエチル)ビニルエーテルからなる群より選択される少なくとも一種である前記[2]記載のペリクル用粘着剤。
[4]さらに、アクリル系重合体、シリコーン樹脂及び熱可塑性エラストマーからなる群より選択される少なくとも一種を含有してなる前記[1]~[3]のいずれかに記載のペリクル用粘着剤。
[5]さらに、アクリル系重合体を含有してなり、アクリル系重合体の固形分100質量部に対してポリビニルエーテル化合物の含有量が0.5~10質量部である前記[1]~[3]のいずれかに記載のペリクル用粘着剤。
[6]アクリル系重合体が、エーテル結合を有する(メタ)アクリル酸エステルを単量体成分とする前記[4]又は[5]記載のペリクル用粘着剤。
[7]エーテル結合を有する(メタ)アクリル酸エステルが、アルキレンオキサイド基を有する(メタ)アクリル酸エステルである前記[6]記載のペリクル用粘着剤。
[8]アルキレンオキサイド基が、エチレンオキサイド基である前記[7]記載のペリクル用粘着剤。
[9]アクリル系重合体が、エーテル結合を含む側鎖を有する前記[4]又は[5]記載のペリクル用粘着剤。
[10]エーテル結合を含む側鎖が、アルキレンオキサイド基を有する前記[9]記載のペリクル用粘着剤。
[11]アルキレンオキサイド基が、エチレンオキサイド基である前記[10]記載のペリクル用粘着剤。
[12]ペリクルフレームと、該ペリクルフレームの一方の端面に設けられた前記[1]~[11]のいずれかに記載のペリクル用粘着剤から得られる粘着剤層と、を有する粘着剤層付ペリクルフレーム。
[13]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記[1]~[11]のいずれかに記載のペリクル用粘着剤から得られる粘着剤層と、を有するペリクル。
[14]粘着剤層が露光光線に照射される前記[13]記載のペリクル。
[15]位相シフトフォトマスクに貼り付けられる前記[13]記載のペリクル。
[16]ネガタイプの露光原版に貼り付けられる前記[13]記載のペリクル。
[17]露光原版における粘着剤層の貼り付け部分に遮光されていない領域又は半透明遮光領域を有する露光原版に貼り付けられる前記[13]記載のペリクル。
[18]露光原版における粘着剤層の貼り付け部分に透明領域を有する露光原版に貼り付けられる前記[13]記載のペリクル。
[19]酸化ケイ素を主成分とする面に貼り付けられる前記[13]記載のペリクル。
[20]酸化ケイ素を主成分とする面が石英面である前記[19]記載のペリクル。
[21]機能水による再生洗浄に対応した前記[13]記載のペリクル。
[22]露光原版に前記[13]又は[14]記載のペリクルが装着されているペリクル付露光原版。
[23]露光原版が位相シフトフォトマスクである前記[22]記載のペリクル付露光原版。
[24]露光原版がネガタイプである前記[22]記載のペリクル付露光原版。
[25]露光原版の粘着剤層の貼り付け部分が遮光されていない領域又は半透明遮光領域を有する前記[22]記載のペリクル付露光原版。
[26]露光原版の粘着剤層の貼り付け部分が透明領域を有する前記[22]記載のペリクル付露光原版。
[27]露光原版が酸化ケイ素を主成分とする前記[22]記載のペリクル付露光原版。
[28]露光原版が石英基板である前記[22]記載のペリクル付露光原版。
[29]前記[22]~[28]のいずれかに記載のペリクル付露光原版によって露光する工程を備える半導体装置の製造方法。
[30]前記[22]~[28]のいずれかに記載のペリクル付露光原版によって露光する工程を備える液晶表示板の製造方法。
[31]前記[22]~[28]のいずれかに記載のペリクル付露光原版からペリクルを剥離し、機能水により露光原版に残った粘着剤の残渣を洗浄することにより露光原版を再生する露光原版の再生方法。
[32]ペリクルを貼り付けた露光原版からペリクルを剥離した際の、露光原版上に残る前記ペリクルの粘着剤層の剥離残渣低減方法であって、前記ペリクルとして前記[13]~[21]のいずれかに記載のペリクルを用いる、剥離残渣低減方法。
[33]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、粘着剤層が露光光線に照射されるペリクルの応用。
[34]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、位相シフトフォトマスクに貼り付けられるペリクルの応用。
[35]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、ネガタイプの露光原版に貼り付けられるペリクルの応用。
[36]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、露光原版における粘着剤層の貼り付け部分に遮光されていない領域又は半透明遮光領域を有する露光原版に貼り付けられるペリクルの応用。
[37]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、露光原版における粘着剤層の貼り付け部分に透明領域を有する露光原版に貼り付けられるペリクルの応用。
[38]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、酸化ケイ素を主成分とする面(特に石英面)に貼り付けられるペリクルの応用。
[39]ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた前記ペリクル用粘着剤から得られる粘着剤層と、を有するペリクルの応用であって、機能水による再生洗浄に対応したペリクルの応用。
[40]ペリクル膜と、該ペリクル膜がその一方の端面に貼り付けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられたペリクルを露光原版に貼り付けるための粘着剤層とを含んで構成される剥離残渣低減ペリクルであって、前記粘着剤層が、アクリル樹脂とポリビニルエーテル化合物とを含有する組成物より形成されることを特徴とする剥離残渣低減ペリクル。
[41]前記[40]記載の組成物は、アクリル樹脂の固形分100質量部に対して、ポリビニルエーテル化合物0.5~10質量部含む、前記[40]記載の剥離残渣低減ペリクル。
[42]前記剥離残渣低減ペリクルが、ArFリソグラフィ用の剥離残渣低減ペリクルである、前記[40]又は[41]記載の剥離残渣低減ペリクル。
[43]ペリクルを露光原版に貼り付けるための粘着剤を、アクリル樹脂とポリビニルエーテル化合物とを含有する組成物より形成し、ペリクルフレームの一方の端面に当該粘着剤を塗布して粘着剤層を作り、これに保護部材を剥離可能に貼着し、ペリクルフレームの他方の端面に接着剤を塗布し、これにペリクル膜を貼り付ける、剥離残渣低減ペリクルの製造方法。
[44]前記組成物は、アクリル樹脂の固形分100質量部に対して、ポリビニルエーテル化合物0.5~10質量部含む、前記[43]記載の剥離残渣低減ペリクル製造方法。
[45]ペリクルを貼り付けた露光原版からペリクルを剥離した際に、露光原版上に残る前記ペリクルの粘着剤層の剥離残渣を低減する方法であって、前記ペリクルとして、前記[40]~[42]のいずれかに記載のペリクルを用いることを特徴とする方法。
上記の重量平均分子量は、ゲル浸透クロマトグラフィー(GPC)分析によって測定される値であって、標準ポリスチレン換算値のことを意味する。GPC分析は、テトラヒドロフラン(THF)を溶解液として用いて行うことができる。
これらの高分子量成分のかでもアクリル系重合体がポリビニルエーテル化合物との混合性を制御しやすいため好ましい。これらの高分子量成分は単独で用いてもよいし、2種以上を組み合わせて用いてもよい。
また、本発明のペリクルを用いることにより、粘着剤層の剥離残渣が低減されることから機能水による洗浄が適用容易となり、位相シフトフォトマスクなどのデリケートな露光原版に対する洗浄性を向上することができる。また、機能水洗浄による環境負荷の低減に貢献できる。
アルミニウム合金製のペリクルフレーム(外形サイズ149mm×115mm×3mm、肉厚2mm、マスク貼り付け用粘着剤塗布端面側の平坦度:15um)を精密洗浄後、平坦度が15um側の端面に綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SN-70A、単量体成分の95質量%がエチレンオキサイド基含有(メタ)アクリレートであるアクリル系重合体を母材として30質量%(固形分)含み、ポリビニルエーテル化合物を2質量%(固形分)含む溶液)を塗布し、60分室温で静置した。その後、平坦度が5umのアルミ板上にセパレータを置き、粘着剤を塗布したペリクルフレームを粘着剤が下向きになるように置いた。これにより粘着剤は平坦なセパレータに接触して平坦加工された。
次に、アルミ板上のペリクルを60℃のオーブンに60分入れて粘着剤を硬化させた。
そして、ペリクルをアルミ板ごと取り出した後、セパレータを剥離した。
最後に、上記ペリクルフレームよりも大きなアルミニウム枠にとったペリクル膜に上記ペリクルフレームの接着剤塗布端面側を貼り付け、ペリクルフレームよりも外側の部分を除去し、ペリクルを完成させた。
紫外線照射後1時間室温で放置した後、ペリクルをマスク基板から0.1mm/秒のスピードで上方にゆっくり剥離した。
粘着剤として、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SK-1495S、エーテル結合を有する(メタ)アクリル酸エステルを単量体成分として含まないアクリル系重合体を母材として含む、固形分30質量%の溶液)100質量部に対してポリビニルエーテル化合物5質量部を含ませた粘着剤を使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
粘着剤として、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SN-70A)100質量部に対してポリビニルエーテル化合物2質量部を含ませた粘着剤を使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
粘着剤として、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SK-1495S)100質量部に対してポリビニルエーテル化合物11質量部を含ませた粘着剤を使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
粘着剤として、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SK-1425S、エーテル結合を有する(メタ)アクリル酸エステルを単量体成分として含まないアクリル系重合体を母材として含む、固形分30質量%の溶液)100質量部に対してポリビニルエーテル化合物3質量部を含ませた粘着剤を使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
剥離後のマスク基板を目視で観察したところ、ペリクルが貼り付いていた部分に薄い粘着剤の溶質残渣が見られた。こちらも剥離残渣の除去は機能水による超音波洗浄を5分x5回実施することで漸く除去することが出来た。
粘着剤として、ポリビニルエーテル化合物を用いず、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SK-1495S)のみを使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
粘着剤として、ポリビニルエーテル化合物を用いず、綜研化学社製のアクリル粘着剤の溶液(製品名:SKダイン SK-1425S)のみを使用した以外は実施例1と同じ方法と材料でペリクルを完成した。さらに実施例1と同様の条件でペリクルをマスク基板に貼り付け、かつ剥離した。
実施例の結果より、粘着剤としてポリビニルエーテルを含有するアクリル系重合体を使用することで、露光基板に貼り付けた後に193nmの紫外線の照射を受けても、露光基板上に剥離残渣をほとんど残すことなく良好に剥離することができることが確認できた。
10 ペリクル
11 ペリクルフレーム
12 ペリクル膜
13 ペリクル膜貼り付け用接着剤層
14 粘着剤層
15 気圧調整用穴(通気口)
16 除塵用フィルター
Claims (32)
- 露光原版にペリクルを貼り付けるためのペリクル用粘着剤であって、ポリビニルエーテル化合物を含有してなるペリクル用粘着剤。
- ポリビニルエーテル化合物が、ビニルエーテル類を単量体成分とする重合体、又は、ビニルエーテル類及びビニルエーテル類と共重合可能な単量体を重合成分とする重合体である請求項1記載のペリクル用粘着剤。
- ビニルエーテル類が、メチルビニルエ―テル、エチルビニルエ―テル、ブチルビニルエ―テル、イソブチルビニルエ―テル及び(2-メトキシエチル)ビニルエーテルからなる群より選択される少なくとも一種である請求項2記載のペリクル用粘着剤。
- さらに、アクリル系重合体、シリコーン樹脂及び熱可塑性エラストマーからなる群より選択される少なくとも一種を含有してなる請求項1~3いずれか一項記載のペリクル用粘着剤。
- さらに、アクリル系重合体を含有してなり、アクリル系重合体の固形分100質量部に対してポリビニルエーテル化合物の含有量が0.5~10質量部である請求項1~3いずれか一項記載のペリクル用粘着剤。
- アクリル系重合体が、エーテル結合を有する(メタ)アクリル酸エステルを単量体成分とする請求項4又は5記載のペリクル用粘着剤。
- エーテル結合を有する(メタ)アクリル酸エステルが、アルキレンオキサイド基を有する(メタ)アクリル酸エステルである請求項6記載のペリクル用粘着剤。
- アルキレンオキサイド基が、エチレンオキサイド基である請求項7記載のペリクル用粘着剤。
- アクリル系重合体が、エーテル結合を含む側鎖を有する請求項4又は5記載のペリクル用粘着剤。
- エーテル結合を含む側鎖が、アルキレンオキサイド基を有する請求項9記載のペリクル用粘着剤。
- アルキレンオキサイド基が、エチレンオキサイド基である請求項10記載のペリクル用粘着剤。
- ペリクルフレームと、該ペリクルフレームの一方の端面に設けられた請求項1~11いずれか一項記載のペリクル用粘着剤から得られる粘着剤層と、を有する粘着剤層付ペリクルフレーム。
- ペリクル膜と、該ペリクル膜が一方の端面に設けられたペリクルフレームと、該ペリクルフレームの他方の端面に設けられた請求項1~11いずれか一項記載のペリクル用粘着剤から得られる粘着剤層と、を有するペリクル。
- 粘着剤層が露光光線に照射される請求項13記載のペリクル。
- 位相シフトフォトマスクに貼り付けられる請求項13記載のペリクル。
- ネガタイプの露光原版に貼り付けられる請求項13記載のペリクル。
- 露光原版における粘着剤層の貼り付け部分に遮光されていない領域又は半透明遮光領域を有する露光原版に貼り付けられる請求項13記載のペリクル。
- 露光原版における粘着剤層の貼り付け部分に透明領域を有する露光原版に貼り付けられる請求項13記載のペリクル。
- 酸化ケイ素を主成分とする面に貼り付けられる請求項13記載のペリクル。
- 酸化ケイ素を主成分とする面が石英面である請求項19記載のペリクル。
- 機能水による再生洗浄に対応した請求項13記載のペリクル。
- 露光原版に請求項13又は14記載のペリクルが装着されているペリクル付露光原版。
- 露光原版が位相シフトフォトマスクである請求項22記載のペリクル付露光原版。
- 露光原版がネガタイプである請求項22記載のペリクル付露光原版。
- 露光原版の粘着剤層の貼り付け部分が遮光されていない領域又は半透明遮光領域を有する請求項22記載のペリクル付露光原版。
- 露光原版の粘着剤層の貼り付け部分が透明領域を有する請求項22記載のペリクル付露光原版。
- 露光原版が酸化ケイ素を主成分とする請求項22記載のペリクル付露光原版。
- 露光原版が石英基板である請求項22記載のペリクル付露光原版。
- 請求項22~28いずれか一項記載のペリクル付露光原版によって露光する工程を備える半導体装置の製造方法。
- 請求項22~28いずれか一項記載のペリクル付露光原版によって露光する工程を備える液晶表示板の製造方法。
- 請求項22~28いずれか一項記載のペリクル付露光原版からペリクルを剥離し、機能水により露光原版に残った粘着剤の残渣を洗浄することにより露光原版を再生する露光原版の再生方法。
- ペリクルを貼り付けた露光原版からペリクルを剥離した際の、露光原版上に残る前記ペリクルの粘着剤層の剥離残渣低減方法であって、前記ペリクルとして請求項13~21いずれか一項記載のペリクルを用いる、剥離残渣低減方法。
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