WO2016067926A1 - ガラス及びガラスの製造方法 - Google Patents
ガラス及びガラスの製造方法 Download PDFInfo
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- WO2016067926A1 WO2016067926A1 PCT/JP2015/079180 JP2015079180W WO2016067926A1 WO 2016067926 A1 WO2016067926 A1 WO 2016067926A1 JP 2015079180 W JP2015079180 W JP 2015079180W WO 2016067926 A1 WO2016067926 A1 WO 2016067926A1
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- Prior art keywords
- light
- glass
- less
- chamfered
- guide plate
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C19/00—Surface treatment of glass, not in the form of fibres or filaments, by mechanical means
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B9/00—Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor
- B24B9/02—Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground
- B24B9/06—Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground of non-metallic inorganic material, e.g. stone, ceramics, porcelain
- B24B9/08—Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground of non-metallic inorganic material, e.g. stone, ceramics, porcelain of glass
- B24B9/10—Machines or devices designed for grinding edges or bevels on work or for removing burrs; Accessories therefor characterised by a special design with respect to properties of materials specific to articles to be ground of non-metallic inorganic material, e.g. stone, ceramics, porcelain of glass of plate glass
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/08—Glass having a rough surface
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Definitions
- the present invention relates to glass and a method for producing glass.
- liquid crystal display devices are provided in portable information terminals such as liquid crystal televisions, tablet terminals, and smartphones.
- the liquid crystal display device includes a planar light emitting device that functions as a backlight, and a liquid crystal panel that is disposed on the light emitting surface side of the planar light emitting device.
- planar light emitting devices There are two types of planar light emitting devices: a direct type and an edge light type, but an edge light type that can reduce the size of the light source is often used.
- the edge light type planar light emitting device includes a light source, a light guide plate, a reflection sheet, a diffusion sheet, and the like.
- the light from the light source enters the light guide plate from the light incident surface formed on the side surface of the light guide plate.
- the light guide plate has a plurality of reflective dots formed on a light reflecting surface opposite to the light emitting surface facing the liquid crystal panel.
- the reflection sheet is arranged to face the light reflection surface, and the diffusion sheet is arranged to face the light emission surface.
- the light incident on the light guide plate from the light source travels while being reflected by the reflective dots and the reflective sheet, and is emitted from the light exit surface.
- the light emitted from the light exit surface is diffused by the diffusion sheet and then enters the liquid crystal panel.
- glass having high transmittance and excellent heat resistance can be used (for example, see Patent Documents 1 and 2).
- a thin liquid crystal display device mounted on a portable information terminal or the like is desired.
- the glass used as the light guide plate is also required to be thinner.
- edge portions a configuration in which the corners of the light exit surface and the entrance surface and the corners of the light reflection surface and the entrance surface (hereinafter, these corners are collectively referred to as “edge portions”) intersect at right angles.
- chamfered portions are formed at the edge portions.
- the chamfered portion is formed by grinding an edge portion of glass. During this grinding process, cullet (glass waste) is generated from the glass. When this cullet adheres to the glass used as the light guide plate, the incident light is reflected in the same manner as the reflective dots.
- the incident light is reflected by the cullet, so that the light reflected by the cullet is emitted from the light emitting surface together with the reflected light reflected by the predetermined reflecting dots. Therefore, luminance unevenness occurs on the light exit surface, and the display quality of the liquid crystal display device using this light guide plate is degraded.
- One of the exemplary purposes of an embodiment of the present invention is to provide a glass and a glass manufacturing method capable of suppressing the amount of cullet generated.
- a glass having first and second surfaces facing each other and at least one first end surface provided between the first surface and the second surface; Having at least one first chamfered surface connecting the first surface or the second surface and the first end surface; Glass with a surface roughness Ra of the first chamfered surface of 0.4 ⁇ m or less is provided.
- the amount of cullet generated can be suppressed, and the occurrence of uneven brightness can be prevented when glass is used as a light guide plate.
- FIG. 1 is a schematic configuration diagram illustrating a liquid crystal display device using glass as a light guide plate according to an embodiment.
- FIG. 2 is a diagram illustrating a light reflecting surface of the light guide plate.
- FIG. 3 is a perspective view of the light guide plate.
- FIG. 4 is a view for explaining a chamfered surface formed on the light guide plate.
- FIG. 5 is a process diagram of a glass manufacturing method according to an embodiment.
- Drawing 6 is a figure for explaining the cutting composition of the manufacturing method of glass which is a certain embodiment.
- FIG. 7 is a diagram for explaining the mirror surface processing step.
- FIG. 8 is a diagram showing the relationship between the surface roughness of the light incident side chamfered portion and the amount of cullet generated.
- FIG. 9 is a diagram for explaining a method of measuring the amount of cullet generated.
- FIG. 1 shows a liquid crystal display device 1 using glass as a light guide plate according to an embodiment of the present invention.
- the liquid crystal display device 1 is mounted on an electronic device that is reduced in size and thickness, such as a portable information terminal.
- the liquid crystal display device 1 has a liquid crystal panel 2 and a planar light emitting device 3.
- the liquid crystal panel 2 has a configuration in which an alignment layer, a transparent electrode, a glass substrate, and a polarizing filter are laminated so as to sandwich a liquid crystal layer disposed in the center.
- a color filter is disposed on one side of the liquid crystal layer.
- the molecules in the liquid crystal layer rotate around the light distribution axis by applying a driving voltage to the transparent electrode, and perform predetermined display by rotation around the light distribution axis.
- the planar light emitting device 3 adopts an edge light type in order to reduce the size and thickness.
- the planar light emitting device 3 includes a light source 4, a light guide plate 5, a reflection sheet 6, a diffusion sheet 7, and reflection dots 10A to 10C.
- the light incident on the light guide plate 5 from the light source 4 travels while being reflected by the reflection dots 10A to 10C and the reflection sheet 6, and is emitted from the light emission surface 51 of the light guide plate 5 facing the liquid crystal panel 2.
- the light emitted from the light emitting surface 51 is diffused by the diffusion sheet 7 and then enters the liquid crystal panel 2.
- the light source 4 is not particularly limited, and a hot cathode tube, a cold cathode tube, or an LED (Light Emitting Diode) can be used.
- the light source 4 is disposed so as to face the light incident surface 53 of the light guide plate 5.
- a reflector 8 is provided on the back side of the light source 4 in order to increase the incident efficiency of the light emitted radially from the light source 4 to the light guide plate 5.
- the reflection sheet 6 has a configuration in which a light reflection member is coated on the surface of a resin sheet such as an acrylic resin.
- the reflection sheet 6 is disposed on the light reflection surface 52 and the non-light incident surfaces 54 to 56 of the light guide plate 5.
- the light reflecting surface 52 is the surface opposite to the light emitting surface 51 of the light guide plate 5.
- the non-light-incident surfaces 54 to 56 are end surfaces excluding the light incident surface 53 among the end surfaces of the light reflecting surface 52. If it is not necessary to particularly increase the incident efficiency, the reflection sheet 6 may be configured not to be disposed on the non-light-incident surfaces 54 to 56.
- the diffusion sheet 7 can be a milky white acrylic resin film or the like. Since the diffusion sheet 7 diffuses the light emitted from the light emitting surface 51 of the light guide plate 5, the back side of the liquid crystal panel 2 can be irradiated with uniform light without uneven brightness.
- the reflection sheet 6 and the diffusion sheet 7 are fixed to a predetermined position of the light guide plate 5 by, for example, adhesion.
- the light guide plate 5 is made of highly transparent glass.
- multi-component oxide glass is used as the glass material used for the light guide plate 5.
- the light guide plate 5 has an effective optical path length of 5 cm to 200 cm, an average internal transmittance in the visible light region (wavelength 380 nm to 780 nm) at the effective optical path length of 80% or more, and JIS Z8701.
- a glass member having a tristimulus value Y value of 90% or more in the XYZ color system in (Appendix) is used.
- S ( ⁇ ) is a transmittance at each wavelength
- y ( ⁇ ) is a weighting coefficient for each wavelength.
- ⁇ (S ( ⁇ ) ⁇ y ( ⁇ )) is the total sum of the weighting coefficient of each wavelength multiplied by the transmittance.
- y ( ⁇ ) corresponds to the M cone (G cone / green) among the retinal cells of the eye, and is most responsive to light having a wavelength of 535 nm.
- the average internal transmittance in the visible light region is preferably 82% or more, more preferably 85% or more, and still more preferably 90% or more in terms of effective optical path length.
- the Y value is preferably 91% or more, more preferably 92% or more, and still more preferably 93% or more in terms of effective optical path length.
- the glass preferably has an average internal transmittance of 90% or more at a wavelength of 400 nm to 700 nm under the condition of an effective optical path length of 50 mm.
- the average internal transmittance at a wavelength of 400 nm to 700 nm under an effective optical path length of 50 mm is preferably 92% or more, more preferably 95% or more, still more preferably 98% or more, and particularly preferably 99% or more.
- the average internal transmittance of glass at a wavelength of 400 nm to 700 nm under the condition of an effective optical path length of 50 mm can be measured by the following method. First, by cleaving the glass in a direction perpendicular to the main surface, the first and second fractured faces (end faces) taken from the central portion of the glass with a size of 50 mm in length and 50 mm in width and facing each other, A sample SA having an arithmetic average roughness Ra ⁇ 0.03 ⁇ m is obtained.
- the total amount A of iron in the glass used as the light guide plate 5 is preferably 100 ppm by mass or less in order to satisfy the above-described internal transmittance at a wavelength of 400 nm to 700 nm, and 40 ppm by mass or less. More preferably, it is more preferably 20 ppm by mass or less.
- the total amount A of the iron content of the glass used as the glass plate is preferably 5 ppm by mass or more in order to improve the solubility of the glass during the production of the multicomponent oxide glass. More preferably, it is at least 10 ppm by mass.
- the total amount A of the iron content of the glass used as the light guide plate 5 can be adjusted by the amount of iron added at the time of glass production.
- the total iron content A of the glass is expressed as the content of Fe 2 O 3 , but all the iron present in the glass exists as Fe 3+ (trivalent iron). I don't mean.
- Fe 3+ and Fe 2+ are simultaneously present in the glass.
- Fe 2+ and Fe 3+ have an absorption coefficient in the wavelength range of 400 nm to 700 nm, but the absorption coefficient of Fe 2+ (11 cm ⁇ 1 Mol ⁇ 1 ) is from the absorption coefficient of Fe 3+ (0.96 cm ⁇ 1 Mol ⁇ 1 ). Therefore , Fe 2+ further reduces the internal transmittance at wavelengths of 400 nm to 700 nm. Therefore, a low content of Fe 2+ is preferable for increasing the internal transmittance at a wavelength of 400 nm to 700 nm.
- the Fe 2+ content B of the glass used as the light guide plate 5 is preferably 20 ppm by mass or less in order to satisfy the above-described internal transmittance at a wavelength of 400 nm to 700 nm, and more preferably 10 ppm by mass or less. Preferably, it is 5 mass ppm or less.
- the Fe 2+ content B of the glass used as the light guide plate 5 is preferably 0.01 ppm by mass or more in order to improve the solubility of the glass during the production of multi-component oxide glass. 0.05 mass ppm or more is more preferable, and 0.1 mass ppm or more is further preferable.
- content B of Fe ⁇ 2+> of the glass used as the light-guide plate 5 can be adjusted with the quantity of the oxidizing agent added at the time of glass manufacture, or a melting temperature. Specific types and addition amounts of oxidizing agents added during glass production will be described later.
- the content A of Fe 2 O 3 was determined by fluorescent X-ray measurement, a content of total iron as calculated as Fe 2 O 3 (mass ppm).
- the content B of Fe 2+ was measured according to ASTM C169-92 (2011). The measured Fe 2+ content B was expressed in terms of Fe 2 O 3 .
- composition of the glass used as the light guide plate 5 is shown below.
- the composition of the glass used as the light guide plate 5 is not limited to these.
- One configuration example of glass used as the light guide plate 5 is a mass percentage display based on oxides, and SiO 2 is 60% to 80%, Al 2 O 3 is 0% to 7%, and MgO is used. 0% -10%, CaO 0% -20%, SrO 0% -15%, BaO 0% -15%, Na 2 O 3% -20%, K 2 O 0% -10%, Fe 2 O 3 is contained at 5 ppm by mass to 100 ppm by mass.
- Another configuration example (configuration example E B ) of the glass used as the light guide plate 5 is an oxide-based mass percentage display, and SiO 2 is 45% to 80%, Al 2 O 3 is more than 7% and 30% or less.
- Still another structural example (structural example E C ) of the glass used as the light guide plate 5 is an oxide-based mass percentage display, and SiO 2 is 45% to 70% and Al 2 O 3 is 10% to 30%.
- B 2 O 3 from 0% to 15%, MgO, CaO, SrO and BaO in total 5% to 30%, Li 2 O, Na 2 O and K 2 O in total from 0% to less than 3%, Fe 2 O 3 is contained in an amount of 5 ppm to 100 ppm by mass.
- composition range of each component of the glass composition used as the light guide plate 5 of the present embodiment having the above-described components will be described below.
- the unit of the content of each composition is expressed in terms of oxide percentage by mass or ppm by mass, and is simply expressed as “%” or “ppm”, respectively.
- SiO 2 is a main component of glass.
- the content of SiO 2 is to maintain the weather resistance and devitrification property of the glass, as represented by mass percentage based on oxides, in the configuration example E A, is preferably 60% or more, more preferably 63% or more, in the configuration example E B, preferably 45% or more, more preferably 50% or more, in the configuration example E C, preferably 45% or more, more preferably 50% or more.
- the content of SiO 2 is easy to dissolve and the foam quality is good, and the content of divalent iron (Fe 2+ ) in the glass is kept low, and the optical properties are good.
- the configuration example E A preferably 80% or less, more preferably 75% or less
- the configuration example E B preferably 80% or less, more preferably 70% or less
- structural example E In C it is preferably 70% or less, more preferably 65% or less.
- Al 2 O 3, in the configuration example E B and E C is an essential component for improving the weather resistance of the glass.
- the content of Al 2 O 3, in the configuration example E A preferably 1% or more, more preferably 2% or more, in the configuration example E B, preferably 7 percent, more preferably 10% or more, in the configuration example E C, preferably 10% or more, more preferably 13% or more.
- the content of Al 2 O 3, in the configuration example E A is preferably 7% or less, more preferably 5% or less, in the configuration example E B, preferably 30% or less, more preferably 23% or less, in the configuration example E C, preferably 30% or less, More preferably, it is 20% or less.
- B 2 O 3 is a component that promotes melting of the glass raw material and improves mechanical properties and weather resistance, but it does not cause inconveniences such as generation of striae due to volatilization and furnace wall erosion.
- the content of B 2 O 3, in the glass E a preferably 5% or less, more preferably 3% or less, in the configuration example E B and E C, preferably 15% or less, more preferably 12% or less.
- Alkali metal oxides such as Li 2 O, Na 2 O, and K 2 O are useful components for accelerating melting of glass raw materials and adjusting thermal expansion, viscosity, and the like.
- the content of Na 2 O, in the configuration example E A preferably 3% or more, more preferably 8% or more.
- the content of Na 2 O is, in the configuration example E B, is preferably 7% or more, more preferably 10% or more.
- the content of Na 2 O, in the configuration example E A and E B it is preferable to be 20% or less, It is more preferably 15% or less, and in the structural example E C, it is preferably 3% or less, and more preferably 1% or less.
- the content of K 2 O is, in the configuration example E A and E B, preferably 10% or less, more preferably 7% or less, in the configuration example E C, preferably 2% or less, more preferably Is 1% or less.
- Li 2 O is an optional component, but in order to facilitate vitrification, to suppress the iron content contained as impurities derived from the raw material, and to reduce the batch cost, the structural examples E A , E B and In E C , 2% or less of Li 2 O can be contained.
- structural example E A and E B Is preferably 5% to 20%, more preferably 8% to 15%.
- structural example E C it is preferably 0% to 2%, more preferably 0% to 1%.
- Alkaline earth metal oxides such as MgO, CaO, SrO, and BaO are useful components for accelerating melting of glass raw materials and adjusting thermal expansion, viscosity, and the like.
- MgO has the effect of lowering the viscosity during glass melting and promoting the melting. Further, MgO may reduce the specific gravity, due to the effect of hardly per flaws in glass plate, structural example E A, the E B and E C, can be contained. Further, the thermal expansion coefficient of the glass low, to the devitrification property and favorable, the content of MgO is in the configuration example E A, preferably 10% or less, more preferably 8% or less, in the configuration example E B, preferably 15% or less, more preferably 12% or less, in the configuration example E C, preferably 10% or less, more preferably 5% or less.
- CaO is a component that promotes melting of the glass raw material and adjusts viscosity, thermal expansion, and the like, and can therefore be contained in the structural examples E A , E B, and E C.
- the content of CaO is preferably 3% or more, more preferably 5% or more.
- the in order to improve the devitrification in the configuration example E A, preferably 20% or less, more preferably 10% or less, in the configuration example E B, preferably not more than 6%, more Preferably it is 4% or less.
- SrO has the effect of increasing the thermal expansion coefficient and lowering the high temperature viscosity of the glass.
- SrO can be contained in the structural examples E A , E B and E C.
- the content of SrO is in the configuration example E A and E C, preferably to 15% or less, more preferably 10% or less, structural example E In B, it is preferably 5% or less, and more preferably 3% or less.
- BaO like SrO, has the effect of increasing the coefficient of thermal expansion and lowering the high temperature viscosity of the glass.
- BaO can be contained in E A , E B and E C.
- the content is preferably set to 3% or less, more preferably 3% or less.
- the total content of these alkaline earth metal oxides is a thermal expansion coefficient kept low, and the devitrification characteristics favorable, in order to maintain the strength, in the configuration example E A, preferably 10% to 30%, more preferably from 13% to 27% in the configuration example E B, preferably from 1% to 15%, more preferably from 3% to 10%, in the configuration example E C, Preferably, it is 5% to 30%, more preferably 10% to 20%.
- ZrO 2 is used as an optional component in order to improve the heat resistance and surface hardness of the glass.
- E A , E B and E C 10 % Or less, preferably 5% or less.
- Fe 2 O 3 may be contained in the structural examples E A , E B and E C in an amount of 5 ppm to 100 ppm in order to improve the solubility of the glass. Good.
- the preferable range of the amount of Fe 2 O 3 is as described above.
- the glass used as the light guide plate 5 of the present embodiment may contain SO 3 as a fining agent.
- the SO 3 content is preferably more than 0% and 0.5% or less in terms of mass percentage.
- the SO 3 content is more preferably 0.4% or less, further preferably 0.3% or less, and further preferably 0.25% or less.
- the glass used as the light guide plate 5 of the present embodiment may contain one or more of Sb 2 O 3, SnO 2 and As 2 O 3 as an oxidizing agent and a clarifying agent.
- the content of one or more of Sb 2 O 3 , SnO 2 or As 2 O 3 is preferably 0% to 0.5% in terms of mass percentage.
- the content of one or more of Sb 2 O 3 , SnO 2 and As 2 O 3 is more preferably 0.2% or less, further preferably 0.1% or less, and still more preferably substantially not contained.
- Sb 2 O 3 , SnO 2 and As 2 O 3 act as an oxidizing agent for glass, they may be added within the above range for the purpose of adjusting the amount of Fe 2+ in the glass. However, from the environmental aspect, it is preferable that As 2 O 3 is not substantially contained.
- the glass used as the light guide plate 5 of the present embodiment may contain NiO.
- NiO functions also as a coloring component
- the content of NiO is preferably 10 ppm or less with respect to the total amount of the glass composition described above.
- NiO is preferably 1.0 ppm or less, more preferably 0.5 ppm or less, from the viewpoint of not reducing the internal transmittance of the glass plate at a wavelength of 400 nm to 700 nm.
- the glass used as the light guide plate 5 of the present embodiment may contain Cr 2 O 3 .
- Cr 2 O 3 also functions as a coloring component. Therefore, the content of Cr 2 O 3 is preferably 10 ppm or less with respect to the total amount of the glass composition described above.
- Cr 2 O 3 is preferably 1.0 ppm or less, more preferably 0.5 ppm or less, from the viewpoint of not reducing the internal transmittance of the glass plate at a wavelength of 400 nm to 700 nm.
- the glass used as the light guide plate 5 of the present embodiment may contain MnO 2 .
- MnO 2 when MnO 2 is contained, since MnO 2 functions also as a component that absorbs visible light, the content of MnO 2 is preferably 50 ppm or less with respect to the total amount of the glass composition described above. In particular, MnO 2 is preferably 10 ppm or less from the viewpoint of not reducing the internal transmittance of the glass plate at a wavelength of 400 nm to 700 nm.
- the glass used as the light guide plate 5 of the present embodiment may contain TiO 2 .
- TiO 2 When TiO 2 is contained, TiO 2 also functions as a component that absorbs visible light. Therefore, the content of TiO 2 is preferably 1000 ppm or less with respect to the total amount of the glass composition described above.
- the content of TiO 2 is more preferably 500 ppm or less, and particularly preferably 100 ppm or less, from the viewpoint of not reducing the internal transmittance of the glass plate at a wavelength of 400 nm to 700 nm.
- the glass used as the light guide plate 5 of this embodiment may contain CeO 2 .
- CeO 2 has the effect of reducing the redox of iron, and the ratio of the Fe 2+ amount to the total iron amount can be reduced.
- the CeO 2 content is preferably 1000 ppm or less with respect to the total amount of the glass composition described above.
- the CeO 2 content is more preferably 500 ppm or less, further preferably 400 ppm or less, particularly preferably 300 ppm or less, and most preferably 250 ppm or less.
- the glass used as the light guide plate 5 of this embodiment may contain at least one component selected from the group consisting of CoO, V 2 O 5 and CuO.
- these components When these components are contained, they also function as components that absorb visible light, and therefore the content of the components is preferably 10 ppm or less with respect to the total amount of the glass composition described above. In particular, it is preferable that these components are not substantially contained so as not to lower the internal transmittance of the glass plate at a wavelength of 400 nm to 700 nm.
- the glass used as the light guide plate 5 is not limited to these.
- the light guide plate 5 includes a light emitting surface 51 (first surface), a light reflecting surface 52 (second surface), and a light incident surface 53 (first end surface). , Non-light-incident surfaces 54 to 56 (second end surfaces), light-incident side chamfered surfaces 57 (first chamfered surfaces), and non-light-incident side chamfered surfaces 58 (second chamfered surfaces).
- the light emitting surface 51 is a surface facing the liquid crystal panel 2.
- the light emission surface 51 has a rectangular shape in a plan view (a state where the light emission surface 51 is viewed from above).
- the shape of the light emitting surface 51 is not limited to a rectangular shape.
- the size of the light emitting surface 51 is determined in accordance with the liquid crystal panel 2 and is not particularly limited. For example, a size of 300 mm ⁇ 300 mm or more is preferable, and a size of 500 mm ⁇ 500 mm or more. Is more preferred. Since the light guide plate 5 has high rigidity, the larger the size, the more effective.
- the light reflecting surface 52 is a surface facing the light emitting surface 51.
- the light reflecting surface 52 is formed to be parallel to the light emitting surface 51.
- the shape and size of the light reflecting surface 52 are the same as those of the light emitting surface 51.
- the light reflecting surface 52 is not necessarily parallel to the light emitting surface 51, and may have a configuration in which a step or an inclination is provided.
- the size of the light reflecting surface 52 may be different from that of the light emitting surface 51.
- reflective dots 10A to 10C are formed on the light reflecting surface 52.
- the reflective dots 10A to 10C are obtained by printing white ink in a dot shape, for example.
- the luminance of the light incident from the light incident surface 53 is strong, and the luminance is lowered by reflecting and proceeding in the light guide plate 5.
- the size of the reflective dots 10A to 10C is varied from the light incident surface 53 toward the light traveling direction (toward the right direction in FIGS. 1 and 2). Specifically, the diameter (L A ) of the reflective dot 10A in the region close to the light incident surface 53 is set to be small, and the diameter of the reflective dot 10B increases from the region close to the light incident surface 53 toward the light traveling direction. (L B ) and the radius (L C ) of the diameter of the reflective dot 10C are set to be large (L A ⁇ L B ⁇ L C ).
- each reflective dot 10A by changing the size of each reflective dot 10A toward the traveling direction of the light in the light guide plate 5, the brightness of the emitted light emitted from the light emitting surface 51 can be made uniform, and uneven brightness is generated. Can be suppressed.
- the same effect can also be obtained by changing the number density of each reflective dot 10A in the light traveling direction in the light guide plate 5 instead of the size of each reflective dot 10A. Further, the same effect can be obtained by forming a groove on the light reflecting surface 52 to reflect the incident light instead of the reflecting dot 10A.
- the light incident surface 53 that is the first end surface is a surface on which light is incident from the light source 4 described above.
- the non-light incident surfaces 54 to 56 that are the second to fourth end surfaces are surfaces on which light from the light source 4 is not incident.
- the light incident surface 53 is preferably mirror-finished when the glass forming the light guide plate 5 is manufactured.
- the arithmetic average roughness (centerline average roughness) Ra of the surface of the light incident surface 53 is preferably less than 0.10 ⁇ m, more preferably less than 0.03 ⁇ m, still more preferably 0.8. It is 01 ⁇ m or less, particularly preferably 0.005 ⁇ m or less. Therefore, the light incident efficiency of light entering the light guide plate 5 from the light source 4 is enhanced.
- the thickness of the light incident surface 53 (indicated by an arrow W in FIG. 4) is set to a thickness required from the liquid crystal display device 1 on which the planar light emitting device 3 is mounted.
- surface roughness Ra when described as surface roughness Ra, it means the arithmetic average roughness (centerline average roughness) according to JIS B 0601 to JIS B 0031.
- a light incident side surface 57 is formed between the light emitting surface 51 and the light incident surface 53 and between the light reflecting surface 52 and the light incident surface 53.
- a light incident side chamfer 57 is formed between the light emitting surface 51 and the light incident surface 53 and between the light reflecting surface 52 and the light incident surface 53 is shown. It is good also as a structure which forms the light-incidence side chamfering surface 57 only in any one.
- the thickness of the light guide plate 5 according to the present embodiment is 10 mm or less.
- the corner portion is in contact with other components and damaged when the light guide plate 5 is assembled with the planar light emitting device 3.
- the strength of the light guide plate 5 may be reduced.
- the light guide plate 5 according to this embodiment has a thickness of 0.5 mm or more, and further has a light incident side chamfer 57 formed on the upper edge and the lower edge of the light incident surface 53.
- the thickness of the light guide plate 5 is more preferably 0.7 mm or more, further preferably 1.0 mm or more, and further preferably 1.5 mm or more. Sufficient rigidity can be acquired because the thickness of the light-guide plate 5 is 0.7 mm or more. Further, the thickness of the light guide plate 5 is more preferably 3.0 mm or less, which can contribute to a reduction in the thickness of the surface emitting illumination device.
- the light incident side chamfered surface 57 is chamfered.
- an average value X ave of the width dimension X in the longitudinal direction of the chamfered surface (hereinafter simply referred to as the longitudinal direction). Is 0.1 mm.
- X ave is preferably 0.1 mm to 0.5 mm. If X ave is 0.5 mm or less, the width dimension of the light incident surface 53 can be increased. If X ave is 0.1 mm or more, the error of X described later can be reduced.
- the error of the width dimension X of the light incident side chamfered surface 57 is 0.05 mm or less.
- the error in the longitudinal direction of X is preferably within 50% of X ave . That is, X preferably satisfies 0.5X ave ⁇ X ⁇ 1.5X ave .
- Error in the longitudinal direction of the X is more preferably within 40% of the X ave, more preferably within 30% of the X ave, particularly preferably within 20% of the X ave.
- the surface roughness Ra of the light incident side chamfering surface 57 is 0.4 ⁇ m or less.
- the reason why the surface roughness Ra of the light incident side chamfered surface 57 is set to 0.4 ⁇ m or less will be described later for convenience of explanation.
- the surface roughness Ra of the light incident side chamfered surface 57 is preferably 0.1 ⁇ m or less, more preferably 0.05 ⁇ m or less, and even more preferably less than 0.03 ⁇ m.
- the error in the longitudinal direction of Y is preferably within 50% of Y ave . That is, Y preferably satisfies 0.5Y ave ⁇ Y ⁇ 1.5Y ave . Error in the longitudinal direction of the Y is more preferably within 40% of the Y ave, more preferably within 30% of the Y ave, particularly preferably within 20% of the Y ave.
- the surface roughness Ra of the non-light-incident side chamfering surface 58 can be made larger than the surface roughness Ra of the light-incident side chamfering surface 57.
- the surface roughness Ra of the light incident side chamfered surface 57 is preferably 0.4 ⁇ m or more.
- the surface roughness Ra of the non-light-incident side chamfered surface 58 is preferably 1.0 ⁇ m or less.
- the surface roughness Ra of the non-light-incident side chamfered surface 58 is set to be larger than that of the light-incident side chamfered surface 57 so that the non-light-incident side chamfered surface 58 is processed. Compared to the above, productivity is improved.
- the surface roughness Ra of the non-light-incident side chamfering surface 58 is 0.4 ⁇ m or more and 1.0 ⁇ m or less, the adhesiveness between the two when the reflection sheet 6 is adhered to the non-light-incident side chamfering surface 58 Becomes better. If productivity is not taken into consideration, the surface roughness Ra of the non-light-incident side chamfered surface 58 is preferably less than 0.4 ⁇ m from the viewpoint of preventing cracks.
- the surface roughness Ra of the non-light-incident surfaces 54 to 56 is 1.5 ⁇ m or less.
- the surface roughness Ra of the non-light-incident surfaces 54 to 56 is preferably 1.0 ⁇ m or less, and more preferably 0.8 ⁇ m or less.
- the non-light incident surfaces 54 to 56 are not polished.
- the surface roughness Ra of the non-light-incident surfaces 54 to 56 is set to be larger than the surface roughness Ra of the light-incident surface 53, and the surface roughness Ra of the non-light-incident surfaces 54 to 56 is preferable. Is 0.03 ⁇ m or more, more preferably 0.1 ⁇ m or more.
- the processing of the non-light-incident surfaces 54 to 56 is easier or unnecessary than the light-incident surface 53, and productivity is improved.
- the non-light-incident surfaces 54 to 56 may be polished.
- FIG. 5 to 7 are diagrams for explaining a method of manufacturing the light guide plate 5.
- FIG. 5 is a process diagram showing a method for manufacturing the light guide plate 5.
- a glass material 12 is prepared.
- the glass material 12 has an effective optical path length of 5 cm to 200 cm, a thickness of 0.5 mm to 10 mm, and an average internal transmittance in the visible light region at the effective optical path length of 80% or more.
- the Y value of the tristimulus values in the XYZ color system in JIS Z8701 (Appendix) is 90% or more.
- the glass material 12 has a shape larger than the predetermined shape of the light guide plate 5.
- a cutting process is performed at each position (one incident light surface side position and three non-light incident surface side positions) indicated by a broken line in FIG. 6 using a cutting device.
- the cutting process does not necessarily have to be performed on the three non-light-incident surface positions, and only one non-light-incident surface position facing the one light-incident surface position is cut. May be.
- the glass substrate 14 is cut from the glass material 12 by performing a cutting process.
- the cutting process is performed on one light incident surface side position and three non-light incident surface side positions.
- the cutting position is appropriately selected according to the shape of the light guide plate 5.
- the first chamfering step (step S12) is performed.
- a non-light-incident side chamfer 58 is provided between the light-emitting surface 51 and the non-light-incident surface 56 and between the light-reflecting surface 52 and the non-light-incident surface 56 using a grinding device.
- chamfering may be performed between the light emitting surface 51 and the light incident surface 53 or between the light reflecting surface 52 and the light incident surface 53. In that case, it is preferable from the viewpoint of productivity that the surface roughness Ra of the chamfered surface obtained is larger than the surface roughness Ra of the light incident side chamfered surface 57 obtained in the second chamfering step described later.
- the non-light-incident surfaces 54 to 56 are ground or polished in the first chamfering process.
- the grinding process or the polishing process for the non-light-incident surfaces 54 to 56 may be performed before or after the above-described non-light-incident side chamfering surface 58 is formed, or may be performed simultaneously.
- the first chamfering step (step S12) can be performed simultaneously with or after the mirror chamfering step (step S14) and the second chamfering step (step S16), which will be described later, but is preferably performed before them.
- processing according to the shape of the light guide plate 5 can be performed at a relatively fast rate in step S12, productivity is improved, and a relatively large cullet generated in step S12 is reflected on the light incident surface 53 or It becomes difficult to damage the incident light side chamfering surface 57.
- the mirror finishing process is then performed in (step S14).
- the light incident surface 53 is formed by performing mirror surface processing on the light incident surface side of the glass substrate 14.
- the light incident surface 53 is a surface on which light is incident from the light source 4. Therefore, the light incident surface 53 is mirror-finished so that the surface roughness Ra is less than 0.03 ⁇ m.
- step S16 When the light incident surface 53 is formed on the glass base material 14 in the mirror surface processing step (step S14), the second chamfering step (step S16) is subsequently performed, so that the light emission surface 51 and the light incident surface 53 are separated.
- a light incident side chamfered surface 57 (chamfered surface) is formed by grinding or polishing between the light reflecting surface 52 and the light incident surface 53. Note that step S16 can be performed before step S14 and can be performed simultaneously with step S14.
- the second chamfering step when the average value in the longitudinal direction of the width X of the light incident side chamfer surface 57 and X ave, so that the error in the longitudinal direction of X is within 50% of the X ave, and the surface roughness Processing is performed so that Ra is 0.4 ⁇ m or less.
- a grindstone When forming the light incident side chamfered surface 57, a grindstone may be used as a tool for performing grinding treatment or polishing treatment.
- a buff or brush made of cloth, leather, rubber or the like is used.
- an abrasive such as cerium oxide, alumina, carborundum, colloidal silica may be used.
- the light guide plate 5 is manufactured by performing the steps shown in the above steps S10 to S16.
- the reflective dots 10A to 10C are printed on the light reflecting surface 52 after the light guide plate 5 is manufactured.
- glass scraps are generated from the glass material 12 and the glass substrate 14 in each process such as the cutting process, the chamfering process, and the mirror finishing process performed when the light guide plate 5 is manufactured. Since the cutting process and the first chamfering process are processes that are less accurate than the mirror surface processing process and the second chamfering process, the generated cullet is relatively large and is therefore difficult to adhere to the light guide plate 5.
- the generated cullet is smaller than the cullet generated in the cutting step and the first chamfering step. For this reason, the cullet generated in the mirror finishing process and the second chamfering process is likely to adhere to the light guide plate 5.
- the cullet generated in the mirror surface processing step and the second chamfering step is the light incident surface 53 and the light incident side surface chamfer. It tends to adhere to the vicinity of the surface 57.
- the reflective dots 10A diameter L A is formed in the vicinity of the light incident surface 53 and light incident side chamfer surface 57. That is, the area where the reflective dots 10A are formed is an area where the area of the light guide plate 5 where the glass is exposed is wide.
- the cullet is glass waste as described above, it has the property of reflecting light.
- the amount of reflection of light incident from the light source 4 is greater when the cullet is attached to the region where the reflective dots 10A are formed than when the cullet is attached to the region where the reflective dots 10B and 10C are formed. It changes greatly (the amount of reflection increases). For this reason, especially when cullet adheres to the region where the reflective dots 10A are formed, the luminance unevenness generated in the light guide plate 5 becomes large.
- the processing of the light incident side chamfered surface 57 which is a chamfering process, generates a larger amount of cullet than the processing of the light incident surface 53 that is mirror-finished.
- the present inventors conducted an experiment to measure the amount of cullet generated in the processing of the light incident side chamfered surface 57. Further, in this experiment, when the processing accuracy of the light incident side chamfered surface 57 is changed, the surface roughness Ra of the diffusion sheet 7 changes, and therefore the surface roughness Ra of the light incident side chamfered surface 57 and the generated cullet amount. The correlation with was investigated.
- FIG. 9 is a process diagram showing a method for quantifying the generated cullet.
- a beaker containing pure water is prepared, and the light incident side chamfered surface 57 of the light guide plate 5 that has been chamfered in the pure water and The vicinity is immersed (step S30).
- cullet is adhered to the light incident side chamfered surface 57 and its vicinity. Accordingly, the cullet attached to the light incident side chamfer 57 or the like is also immersed in pure water.
- step S32 ultrasonic cleaning is performed on the light incident side surface 57 of the light guide plate 5 by ultrasonically vibrating the beaker.
- the cullet attached to the incident side chamfered surface 57 and its vicinity falls and accumulates on the bottom of the beaker (the pure water from which the cullet has dropped is also referred to as “cullet water”).
- step S34 the cullet water created in step S32 is filtered through a filter that has previously been weighed. Thereby, the cullet is collected in the filter.
- the filter from which the cullet has been collected is dried using a dryer (step S36).
- step S38 the weight of the filter is measured. Then, by subtracting the weight of the filter that has been measured in advance from the weight measured in step S38, the amount of cullet generated during the chamfering process of the light incident side chamfer 57 can be obtained (step S40). .
- FIG. 8 shows the relationship between the surface roughness Ra of the light incident side chamfered surface 57 and the amount of cullet generated (the mass of cullet generated per 1 mm 2 ). From the figure, it can be seen that the amount of cullet generated correlates with the surface roughness Ra in the range where the surface roughness Ra of the light incident side chamfered surface 57 is larger than 0.3 ⁇ m.
- the present inventors performed a calculation for obtaining the amount of cullet that causes luminance unevenness when cullet adheres to the light incident side chamfered surface 57.
- the diameter of the cullet is 100 ⁇ m or more, the light emission characteristics (such as luminance unevenness) of the light guide plate 5 are affected.
- the attachment position of the cullet that affects the optical characteristics of the light guide plate 5 is an area where the small-diameter (L A ) reflective dots 10A are formed.
- the area of the region where the reflective dots 10 ⁇ / b> A are formed is approximately 10% of the total area of the light guide plate 5.
- the luminance unevenness generated in the region where the small-diameter reflective dots 10A are formed be 3% or less.
- the cullet attached to the region where the reflective dots 10A are formed indicates that the luminance unevenness is 3% or less.
- the area ratio needs to be 3% or less. That is, it is necessary to satisfy the following expression (3).
- the width of the light incident side chamfer surface 57 is proportional to S a from equation (1), in order to sufficiently increase the area of the light incident surface 53, it is preferable to satisfy the S b / S a ⁇ 100. Therefore, in order to always satisfy the above formula (3) and S b / S a ⁇ 100, the cullet generation amount c preferably satisfies the following formula (4).
- the cullet generation amount c satisfying the above formula (4) is 0.5 [ ⁇ g / mm 2 ] or less.
- the amount of cullet generated is 0.5 [ ⁇ g / mm 2 ] or less when the surface roughness Ra of the light incident side chamfered surface 57 is 0.4 ⁇ m or less. Therefore, it was proved that the light guide plate 5 free from luminance unevenness can be realized by setting the surface roughness Ra of the light incident side chamfering surface 57 to 0.4 ⁇ m or less.
- the amount of cullet generated increases as the width dimension X of the light incident side chamfer 57 increases.
- the surface roughness Ra of the light incident side chamfered surface 57 is preferably 0.3 ⁇ m or less in order to reduce the amount of cullet generated to 0.5 [ ⁇ g / mm 2 ] or less, more preferably It is 0.1 ⁇ m or less, more preferably 0.03 ⁇ m or less.
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Abstract
Description
互いに対向する第1面および第2面ならびに前記第1面と前記第2面の間に設けられる少なくとも一つの第1端面とを有するガラスであって、
前記第1面又は前記第2面と前記第1端面とを接続する少なくとも一つの第1面取り面を有し、
前記第1面取り面の表面粗さRaが0.4μm以下であるガラスが提供される。
互いに対向する第1面および第2面、ならびに前記第1面と前記第2面の間に設けられる少なくとも一つの第1端面及び少なくとも一つの第2端面とを有するガラス基材を準備する工程と、
前記ガラス基材の前記第2端面を面取り加工する第1面取り工程と、
前記ガラス基材の前記第1端面を鏡面加工する鏡面加工工程と、
前記鏡面加工工程に供された前記ガラス基材の前記第1端面を面取り加工することにより、前記第1面又は前記第2面と前記第1端面とを接続する少なくとも一つの第1面取り面を形成し、前記第1面取り面の表面粗さRaを0.4μm以下とせしめる第2面取り工程と、
を備えるガラスの製造方法が提供される。
更に、反射ドット10Aが形成された領域(カレットが付着した場合に輝度ムラに影響を及ぼす領域)の面積は、導光板5の全面積の略10%の広さである。この反射ドット10Aが形成された領域の面積Sb[mm2]は下式(2)により求められる。
ここで、カレット発生量をc[μg/mm2]とすると、入光側面取り面57から生じる直径100μmのカレットの発生個数は、c×Sa/W[個]である。
入光側面取り面57の幅は式(1)よりSaに比例するため、入光面53の面積を十分に大きくするためにも、Sb/Sa≧100を満たすことが好ましい。従って、上記の式(3)及びSb/Sa≧100を常に満たすためには、カレット発生量cは下式(4)を満足させることが好ましい。
上記の式(4)を満たすカレット発生量cは0.5[μg/mm2]以下となる。
2 液晶パネル
3 面状発光装置
4 光源
5 導光板(ガラス)
6 反射シート
7 拡散シート
8 リフレクタ
10A~10C 反射ドット
12 ガラス素材
14 ガラス基材
51 光出射面(第1面)
52 光反射面(第2面)
53 入光面(第1端面)
54,55,56 非入光面(第2端面)
57 入光側面取り面(第1面取り面)
58 非入光側面取り面(第2面取り面)
Claims (10)
- 互いに対向する第1面および第2面、ならびに前記第1面と前記第2面の間に設けられる少なくとも一つの第1端面とを有するガラスであって、
前記第1面又は前記第2面と前記第1端面とを接続する少なくとも一つの第1面取り面を有し、
前記第1面取り面の表面粗さRaが0.4μm以下であるガラス。 - 前記第1面取り面の幅の長手方向における平均値をXave(mm)とするとき、
前記第1面取り面の幅Xの長手方向における誤差がXave(mm)の50%以下である請求項1に記載のガラス。 - 前記第1面と前記第2面の間に、前記第1端面とは異なる少なくとも一つの第2端面を有し、
前記第1面又は前記第2面と前記第2端面とを接続する少なくとも一つの第2面取り面を有し、
前記第2面取り面の表面粗さRaが前記第1面取り面の表面粗さRaよりも大きく、1.5μm以下である請求項1又は2に記載のガラス。 - 前記第2面取り面の幅の長手方向における平均値をYave(mm)とするとき、
前記第2面取り面の幅Yの長手方向における誤差がYave(mm)の50%以下である請求項3に記載のガラス。 - 前記第2端面の表面粗さRaが1.5μm以下である請求項3又は4に記載のガラス。
- 前記第1面は矩形状であり、
前記第1面と前記第2面の間に設けられ、前記第1端面とは異なる少なくとも3つの前記第2端面とを有し、
前記第1面又は前記第2面と前記第2端面とを接続する少なくとも3つの前記第2面取り面を有し、
前記第2面取り面の表面粗さRaがいずれも前記第1面取り面の表面粗さRaよりも大きく、1.5μm以下である請求項3~5のいずか一項に記載のガラス。 - 前記第1面取り面におけるカレット発生量が0.5[μg/mm2]以下である請求項1~6のいずれか一項に記載のガラス。
- 有効光路長が5cm~200cmであり、有効光路長での可視光域の平均内部透過率が80%以上である請求項1~7のいずれか一項に記載のガラス。
- 光路長50mmの条件下での、波長400nm~700nmにおける平均内部透過率が90%以上である請求項1~8のいずれか一項に記載のガラス。
- 互いに対向する第1面および第2面、ならびに前記第1面と前記第2面の間に設けられる少なくとも一つの第1端面及び少なくとも一つの第2端面とを有するガラス基材を準備する工程と、
前記ガラス基材の前記第2端面を面取り加工する第1面取り工程と、
前記ガラス基材の前記第1端面を鏡面加工する鏡面加工工程と、
前記鏡面加工工程に供された前記ガラス基材の前記第1端面を面取り加工することにより、前記第1面又は前記第2面と前記第1端面とを接続する少なくとも一つの第1面取り面を形成し、前記第1面取り面の表面粗さRaを0.4μm以下とせしめる第2面取り工程と、
を備えるガラスの製造方法。
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JP6583623B2 (ja) * | 2015-07-24 | 2019-10-02 | 日本電気硝子株式会社 | 導光板用ガラス板 |
-
2015
- 2015-10-15 JP JP2016556496A patent/JPWO2016067926A1/ja not_active Withdrawn
- 2015-10-15 KR KR1020177010459A patent/KR20170076667A/ko unknown
- 2015-10-15 WO PCT/JP2015/079180 patent/WO2016067926A1/ja active Application Filing
- 2015-10-27 TW TW104135286A patent/TW201621367A/zh unknown
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2017
- 2017-04-26 US US15/497,470 patent/US20170226006A1/en not_active Abandoned
- 2017-12-04 JP JP2017232338A patent/JP6296201B2/ja not_active Expired - Fee Related
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2018
- 2018-01-29 JP JP2018012195A patent/JP6319534B1/ja active Active
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JP2007234218A (ja) * | 1997-09-30 | 2007-09-13 | Hoya Corp | 磁気記録媒体用ガラス基板、磁気記録媒体用ガラス基板の製造方法、及び磁気記録媒体の製造方法 |
JP2005300566A (ja) * | 2003-03-26 | 2005-10-27 | Hoya Corp | フォトマスク用基板、フォトマスクブランク、及びフォトマスク |
JP2007245319A (ja) * | 2006-03-20 | 2007-09-27 | Konica Minolta Opto Inc | ガラスディスクの加工方法 |
JP2012027176A (ja) * | 2010-07-22 | 2012-02-09 | Tosoh Corp | フォトマスク用基板 |
JP2013073667A (ja) * | 2012-07-17 | 2013-04-22 | Asahi Glass Co Ltd | 磁気記録媒体用ガラス基板の製造方法、及び、磁気記録媒体用ガラス基板 |
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JP2018052805A (ja) * | 2016-09-21 | 2018-04-05 | 旭硝子株式会社 | ガラス板 |
WO2018140421A1 (en) * | 2017-01-24 | 2018-08-02 | Corning Incorporated | Methods and apparatus for finishing edges of glass sheets |
Also Published As
Publication number | Publication date |
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JP6319534B1 (ja) | 2018-05-09 |
JPWO2016067926A1 (ja) | 2017-10-12 |
JP2018078121A (ja) | 2018-05-17 |
US20170226006A1 (en) | 2017-08-10 |
JP6296201B2 (ja) | 2018-03-20 |
JP2018039732A (ja) | 2018-03-15 |
KR20170076667A (ko) | 2017-07-04 |
TW201621367A (zh) | 2016-06-16 |
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