WO2011037332A3 - 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 - Google Patents

신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 Download PDF

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WO2011037332A3
WO2011037332A3 PCT/KR2010/005871 KR2010005871W WO2011037332A3 WO 2011037332 A3 WO2011037332 A3 WO 2011037332A3 KR 2010005871 W KR2010005871 W KR 2010005871W WO 2011037332 A3 WO2011037332 A3 WO 2011037332A3
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WIPO (PCT)
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silica particles
hard coating
composition containing
coating composition
preparation
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PCT/KR2010/005871
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English (en)
French (fr)
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WO2011037332A2 (ko
Inventor
권동주
김원국
강양구
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㈜엘지하우시스
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Application filed by ㈜엘지하우시스 filed Critical ㈜엘지하우시스
Priority to JP2012529655A priority Critical patent/JP5601672B2/ja
Priority to DE112010003739.6T priority patent/DE112010003739B4/de
Priority to US13/388,501 priority patent/US9512009B2/en
Priority to CN201080035651.4A priority patent/CN102548897B/zh
Publication of WO2011037332A2 publication Critical patent/WO2011037332A2/ko
Publication of WO2011037332A3 publication Critical patent/WO2011037332A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146—After-treatment of sols
    • C01B33/149—Coating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/146—After-treatment of sols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C01B33/142—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3893—Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
    • C08G18/3895—Inorganic compounds, e.g. aqueous alkalimetalsilicate solutions; Organic derivatives thereof containing no direct silicon-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Laminated Bodies (AREA)
  • Silicon Compounds (AREA)
  • Silicon Polymers (AREA)

Abstract

본 발명은 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물에 관한 것으로, 보다 상세하게는 실리카 입자의 표면의 히드록시기(-OH)에 개시제를 화학적으로 결합시킨 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드코팅 조성물에 관한 것이다. 본 발명에 따른 유-무기 실리카 입자를 포함하는 하드코팅 조성물은 내마모성, 내스크래치성 등이 우수한 하드코팅 필름을 제조할 수 있다.
PCT/KR2010/005871 2009-09-22 2010-08-31 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물 WO2011037332A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2012529655A JP5601672B2 (ja) 2009-09-22 2010-08-31 新規の有機−無機シリカ粒子、その製造方法及びこれを含むハードコーティング組成物
DE112010003739.6T DE112010003739B4 (de) 2009-09-22 2010-08-31 Neuartige organisch-anorganische Siliciumdioxidteilchen und Verfahren zu deren Herstellung
US13/388,501 US9512009B2 (en) 2009-09-22 2010-08-31 Organic-inorganic silica particles, method of preparing the same, and hard coating composition containing the same
CN201080035651.4A CN102548897B (zh) 2009-09-22 2010-08-31 有机-无机二氧化硅粒子、制造方法及硬涂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020090089655A KR101181564B1 (ko) 2009-09-22 2009-09-22 신규한 유-무기 실리카 입자, 이의 제조방법 및 이를 포함하는 하드 코팅 조성물
KR10-2009-0089655 2009-09-22

Publications (2)

Publication Number Publication Date
WO2011037332A2 WO2011037332A2 (ko) 2011-03-31
WO2011037332A3 true WO2011037332A3 (ko) 2011-07-21

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US (1) US9512009B2 (ko)
JP (1) JP5601672B2 (ko)
KR (1) KR101181564B1 (ko)
CN (1) CN102548897B (ko)
DE (1) DE112010003739B4 (ko)
WO (1) WO2011037332A2 (ko)

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EP2475718A1 (de) * 2009-09-09 2012-07-18 Felix Winkelmann Polymere werkstoffe mit gekoppelten komponenten
JP2011157435A (ja) * 2010-01-29 2011-08-18 Dic Corp 無機粒子分散体の製造方法
EP2439219A1 (de) * 2010-10-06 2012-04-11 Sika Technology AG Verringerung des Anteils an Isocyanatgruppen aufweisenden Monomeren in feuchtigkeitshärtenden Polyurethanzusammensetzungen
EP2683770A1 (de) * 2011-03-09 2014-01-15 Felix Winkelmann Polymere compounds mit gekoppelten komponenten
KR101291937B1 (ko) * 2011-04-15 2013-07-31 (주)엘지하우시스 하드코팅용 조성물 및 이를 이용한 저온 성형성 및 슬립성이 우수한 하드코팅 형성용 시트
KR101512881B1 (ko) * 2012-05-31 2015-04-16 주식회사 엘지화학 가스 차단 필름 및 이의 제조방법
CN102993782B (zh) * 2012-12-12 2014-04-16 江南大学 一种聚氨酯丙烯酸酯类低聚物表面改性二氧化硅的制备方法
JP2015078339A (ja) * 2013-09-10 2015-04-23 昭和電工株式会社 有機無機複合体の製造方法、硬化性組成物、硬化性組成物の製造方法、硬化性組成物の硬化物、ハードコート材、及びハードコート膜
CN104725549B (zh) * 2014-02-24 2018-09-04 长兴化学工业(中国)有限公司 高性能纳米复合乳胶
KR101745676B1 (ko) * 2014-05-30 2017-06-09 주식회사 엘지화학 시아네이트계 수지에 대한 분산성이 우수한 실리카졸 조성물 및 이의 제조 방법
KR101745410B1 (ko) 2015-05-12 2017-06-09 엘지전자 주식회사 고분자 기반 초흡습성 코팅 조성물 및 그 이용
CN105585272A (zh) * 2015-10-22 2016-05-18 湖州绿色建材开发有限公司 一种新型混凝土增强剂
KR102184393B1 (ko) * 2017-08-24 2020-11-30 주식회사 엘지화학 유무기 하이브리드 코팅층을 포함하는 기능성 필름
WO2019235206A1 (ja) * 2018-06-05 2019-12-12 Dic株式会社 活性エネルギー線硬化性組成物及びそれを用いたフィルム
TWI741600B (zh) * 2019-05-14 2021-10-01 日商日產化學股份有限公司 分散於酮系溶劑之二氧化矽溶膠及樹脂組成物
CN114605662B (zh) * 2022-04-24 2023-03-24 嘉鱼县宇威新材料科技有限公司 一种丁腈橡胶增韧剂及其制备方法和应用

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Also Published As

Publication number Publication date
CN102548897B (zh) 2015-02-11
JP5601672B2 (ja) 2014-10-08
KR101181564B1 (ko) 2012-09-10
KR20110032258A (ko) 2011-03-30
CN102548897A (zh) 2012-07-04
DE112010003739T5 (de) 2013-05-02
WO2011037332A2 (ko) 2011-03-31
US9512009B2 (en) 2016-12-06
JP2013504512A (ja) 2013-02-07
US20120135216A1 (en) 2012-05-31
DE112010003739B4 (de) 2018-05-17

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