WO2009054472A1 - ポリエステル系軟質ポリウレタンフォームの製造方法、及びそれに用いられる触媒組成物 - Google Patents

ポリエステル系軟質ポリウレタンフォームの製造方法、及びそれに用いられる触媒組成物 Download PDF

Info

Publication number
WO2009054472A1
WO2009054472A1 PCT/JP2008/069271 JP2008069271W WO2009054472A1 WO 2009054472 A1 WO2009054472 A1 WO 2009054472A1 JP 2008069271 W JP2008069271 W JP 2008069271W WO 2009054472 A1 WO2009054472 A1 WO 2009054472A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst composition
polyester
polyurethane foam
flexible polyurethane
amine compound
Prior art date
Application number
PCT/JP2008/069271
Other languages
English (en)
French (fr)
Inventor
Yoshihiro Takahasi
Original Assignee
Tosoh Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corporation filed Critical Tosoh Corporation
Priority to US12/739,885 priority Critical patent/US8980965B2/en
Priority to EP08842459.3A priority patent/EP2204394B1/en
Priority to CN2008801133022A priority patent/CN101835820B/zh
Publication of WO2009054472A1 publication Critical patent/WO2009054472A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2018—Heterocyclic amines; Salts thereof containing one heterocyclic ring having one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

ポリエステル系軟質ポリウレタンフォームの製造において、成形性に優れ、かつフォーム内部のスコーチがなく、更に製品中から揮発性のアミン化合物をほとんど排出しない低臭気なポリエステル系軟質ポリウレタンフォームの製造方法、及びそれに使用される触媒組成物を提供する。 ポリエステルポリオールとポリイソシアネートとを、特定構造を有するアルキルピペラジン系のアミン化合物、特定構造を有するＮ－ヒドロキシアルキルモルホリン系のアミン化合物、及びジアルキル－ヒドロキシアルキルアミン系のアミン化合物からなる群より選ばれる１種又は２種以上のアミン化合物を含有する触媒組成物、発泡剤及び整泡剤の存在下に反応させてポリエステル系軟質ポリウレタンフォームを製造する。
PCT/JP2008/069271 2007-10-26 2008-10-23 ポリエステル系軟質ポリウレタンフォームの製造方法、及びそれに用いられる触媒組成物 WO2009054472A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/739,885 US8980965B2 (en) 2007-10-26 2008-10-23 Method for producing polyester type flexible polyurethane foam, and catalyst composition to be used therefor
EP08842459.3A EP2204394B1 (en) 2007-10-26 2008-10-23 Process for production of polyester-containing flexible polyurethane foam, and catalyst composition for use in the process
CN2008801133022A CN101835820B (zh) 2007-10-26 2008-10-23 聚酯类软质聚氨酯泡沫塑料的制造方法和其中使用的催化剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007279243 2007-10-26
JP2007-279243 2007-10-26

Publications (1)

Publication Number Publication Date
WO2009054472A1 true WO2009054472A1 (ja) 2009-04-30

Family

ID=40579574

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/069271 WO2009054472A1 (ja) 2007-10-26 2008-10-23 ポリエステル系軟質ポリウレタンフォームの製造方法、及びそれに用いられる触媒組成物

Country Status (5)

Country Link
US (1) US8980965B2 (ja)
EP (1) EP2204394B1 (ja)
JP (1) JP5504611B2 (ja)
CN (1) CN101835820B (ja)
WO (1) WO2009054472A1 (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011105813A (ja) * 2009-11-13 2011-06-02 Tosoh Corp ポリエステル系軟質ポリウレタンフォーム製造用のアミン触媒、及びそれを用いたポリエステル系軟質ポリウレタンフォームの製造方法
JP5670371B2 (ja) * 2011-03-31 2015-02-18 三洋化成工業株式会社 軟質ポリウレタンフォームの製造方法
US9968919B2 (en) 2011-06-29 2018-05-15 Evonik Degussa Gmbh Reducing emissions in polyurethane foam
BR112017007389B1 (pt) * 2014-10-13 2022-07-19 Evonik Operations Gmbh Composição de catalisador e seu uso, processo para produzir poliuretano e espuma de poliuretano

Citations (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1091604A (en) 1964-03-12 1967-11-22 Lankro Chem Ltd Improvements in or relating to polyurethane foams
JPH0485317A (ja) 1990-07-30 1992-03-18 Tosoh Corp ポリウレタン製造用アミン触媒及びポリウレタンの製造法
JPH0616760A (ja) * 1991-07-03 1994-01-25 Tosoh Corp ポリウレタン製造用アミン触媒組成物及びポリウレタンの製造法
JPH07258367A (ja) 1994-03-18 1995-10-09 Air Prod And Chem Inc ポリエステルポリオールをベースとするポリウレタン軟質スラブ材フォーム用の低臭気アミン触媒
JP2001026627A (ja) * 1999-07-13 2001-01-30 Tosoh Corp ポリウレタン製造用触媒及びそれを用いたポリウレタンの製造方法
JP2001172351A (ja) * 1999-12-17 2001-06-26 Kao Corp ポリウレタンの製造法
JP2001172350A (ja) * 1999-12-17 2001-06-26 Kao Corp ポリウレタンの製造法
JP2002179755A (ja) * 2000-12-13 2002-06-26 Inoac Corp 低蛍光性軟質ポリウレタンフォーム
JP2003137951A (ja) * 2001-10-31 2003-05-14 Tosoh Corp 軟質ポリウレタンフォームの製造方法
JP2003206327A (ja) 2002-01-16 2003-07-22 Mitsui Takeda Chemicals Inc 軟質ポリウレタンフォーム、その製造方法およびその用途
JP2004027010A (ja) 2002-06-25 2004-01-29 Tosoh Corp 軟質ポリウレタンフォームの製造方法
JP2004238561A (ja) * 2003-02-07 2004-08-26 Inoac Corp ポリウレタンフォームおよびその製造方法
JP2004359820A (ja) * 2003-06-04 2004-12-24 Kao Corp ポリウレタンフォームの製造法
JP2005029658A (ja) * 2003-07-10 2005-02-03 Kao Corp ポリウレタンフォームの製造法
JP2005171047A (ja) * 2003-12-10 2005-06-30 Kao Corp ポリウレタンフォームの製造法
JP2006045267A (ja) * 2004-07-30 2006-02-16 Sanyo Chem Ind Ltd ヘッドレスト用軟質ポリウレタンフォームの製造方法
JP2006045258A (ja) * 2004-07-30 2006-02-16 Tosoh Corp ポリウレタン樹脂製造用の触媒組成物、及びそれを用いた軟質ポリウレタンフォームの製造方法
JP2006160827A (ja) * 2004-12-03 2006-06-22 Kao Corp 暖房器具用ポリウレタンフォームの製造法
JP2007023115A (ja) * 2005-07-14 2007-02-01 Tosoh Corp 軟質ポリウレタンフォーム製造用の触媒組成物
JP2007077240A (ja) * 2005-09-13 2007-03-29 Tosoh Corp ポリウレタン樹脂製造用の触媒組成物及びポリウレタン樹脂の製造方法
WO2008023436A1 (fr) * 2006-08-25 2008-02-28 Tosoh Corporation Composition de catalyseur pour la production de mousse de polyuréthane flexible
JP2008056849A (ja) * 2006-09-01 2008-03-13 Tosoh Corp ポリウレタン樹脂製造用触媒組成物及びポリウレタン樹脂の製造方法
JP2008195909A (ja) * 2007-02-16 2008-08-28 Inoac Corp 軟質ポリウレタンフォーム

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379757A (en) * 1980-09-29 1983-04-12 Union Carbide Corporation Tertiary amine catalyst mixtures useful in cellular polyurethane formation
CN1029979C (zh) * 1989-07-28 1995-10-11 东曹株式会社 高弹性聚氨酯泡沫体的制造方法
EP0410467B1 (en) * 1989-07-28 1996-12-18 Tosoh Corporation Process for producing high resilience Polyurethane foam
JPH0751613B2 (ja) * 1989-09-11 1995-06-05 東ソー株式会社 高弾性を有する軟質ポリウレタンフォームの製造法
CA2107635C (en) * 1992-10-09 1999-08-17 David T. Green Surgical clip applier
DE19744747A1 (de) * 1997-10-10 1999-04-15 Basf Ag Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen
CN1148395C (zh) * 1998-07-31 2004-05-05 花王株式会社 聚氨酯泡沫体的制造方法
KR100490004B1 (ko) * 1999-12-17 2005-05-17 카오카부시키가이샤 폴리우레탄의 제조법
ES2396703T3 (es) * 2001-10-31 2013-02-25 Tosoh Corporation Proceso para la producción de espumas de poliuretano flexibles
US6774154B2 (en) * 2002-04-08 2004-08-10 Crompton Corporation Semiflexible and flexible polyurethanes foams having low fogging characteristics and improved physical properties

Patent Citations (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1091604A (en) 1964-03-12 1967-11-22 Lankro Chem Ltd Improvements in or relating to polyurethane foams
JPH0485317A (ja) 1990-07-30 1992-03-18 Tosoh Corp ポリウレタン製造用アミン触媒及びポリウレタンの製造法
JPH0616760A (ja) * 1991-07-03 1994-01-25 Tosoh Corp ポリウレタン製造用アミン触媒組成物及びポリウレタンの製造法
JPH07258367A (ja) 1994-03-18 1995-10-09 Air Prod And Chem Inc ポリエステルポリオールをベースとするポリウレタン軟質スラブ材フォーム用の低臭気アミン触媒
JP2001026627A (ja) * 1999-07-13 2001-01-30 Tosoh Corp ポリウレタン製造用触媒及びそれを用いたポリウレタンの製造方法
JP2001172351A (ja) * 1999-12-17 2001-06-26 Kao Corp ポリウレタンの製造法
JP2001172350A (ja) * 1999-12-17 2001-06-26 Kao Corp ポリウレタンの製造法
JP2002179755A (ja) * 2000-12-13 2002-06-26 Inoac Corp 低蛍光性軟質ポリウレタンフォーム
JP2003137951A (ja) * 2001-10-31 2003-05-14 Tosoh Corp 軟質ポリウレタンフォームの製造方法
JP2003206327A (ja) 2002-01-16 2003-07-22 Mitsui Takeda Chemicals Inc 軟質ポリウレタンフォーム、その製造方法およびその用途
JP2004027010A (ja) 2002-06-25 2004-01-29 Tosoh Corp 軟質ポリウレタンフォームの製造方法
JP2004238561A (ja) * 2003-02-07 2004-08-26 Inoac Corp ポリウレタンフォームおよびその製造方法
JP2004359820A (ja) * 2003-06-04 2004-12-24 Kao Corp ポリウレタンフォームの製造法
JP2005029658A (ja) * 2003-07-10 2005-02-03 Kao Corp ポリウレタンフォームの製造法
JP2005171047A (ja) * 2003-12-10 2005-06-30 Kao Corp ポリウレタンフォームの製造法
JP2006045267A (ja) * 2004-07-30 2006-02-16 Sanyo Chem Ind Ltd ヘッドレスト用軟質ポリウレタンフォームの製造方法
JP2006045258A (ja) * 2004-07-30 2006-02-16 Tosoh Corp ポリウレタン樹脂製造用の触媒組成物、及びそれを用いた軟質ポリウレタンフォームの製造方法
JP2006160827A (ja) * 2004-12-03 2006-06-22 Kao Corp 暖房器具用ポリウレタンフォームの製造法
JP2007023115A (ja) * 2005-07-14 2007-02-01 Tosoh Corp 軟質ポリウレタンフォーム製造用の触媒組成物
JP2007077240A (ja) * 2005-09-13 2007-03-29 Tosoh Corp ポリウレタン樹脂製造用の触媒組成物及びポリウレタン樹脂の製造方法
WO2008023436A1 (fr) * 2006-08-25 2008-02-28 Tosoh Corporation Composition de catalyseur pour la production de mousse de polyuréthane flexible
JP2008056849A (ja) * 2006-09-01 2008-03-13 Tosoh Corp ポリウレタン樹脂製造用触媒組成物及びポリウレタン樹脂の製造方法
JP2008195909A (ja) * 2007-02-16 2008-08-28 Inoac Corp 軟質ポリウレタンフォーム

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
EDITED BY GUNTER OERTEL (1985 EDITION): ""Polyurethane Handbook"", HANSER PUBLISHERS (GERMANY, pages: 161 - 233
EDITED BY GUNTER OERTEL: ""Polyurethane Handbook" (1985 edition", HANSER PUBLISHERS (GERMANY, pages: 223 - 233
EDITED BY KENJI IWATA: ""Polyurethane Resin Handbook"(1987 first edition)", THE NIKKAN KOGYO SHIMBUN, LTD, pages: 150 - 221
EDITED BY KENJI IWATA: ""Polyurethane Resin Handbook"(1987 first edition)", THE NIKKAN KOGYO SHIMBUN, LTD., pages: 211 - 221

Also Published As

Publication number Publication date
EP2204394B1 (en) 2017-07-12
EP2204394A1 (en) 2010-07-07
EP2204394A4 (en) 2014-10-15
JP2009120831A (ja) 2009-06-04
US8980965B2 (en) 2015-03-17
CN101835820A (zh) 2010-09-15
CN101835820B (zh) 2012-11-21
JP5504611B2 (ja) 2014-05-28
US20100256249A1 (en) 2010-10-07

Similar Documents

Publication Publication Date Title
WO2009048807A3 (en) Amine catalysts for polyurethane foams
MX2010002339A (es) Catalisis de espumas viscoelasticas con sales de bismuto.
MX2010005757A (es) Composiciones y uso de la composicion formadora de espuma de cis-1,1,1,4,4,4-hexafluoro-2-buteno en la preparacion de espumas a base de poliisocianato.
WO2006039298A3 (en) Molded flexible polyurethane foams with reduced flammability and superior durability
JP2010534253A5 (ja)
WO2009041535A1 (ja) 軟質ポリウレタンフォームおよび熱プレス成形品の製造方法ならびに熱プレス成形品
PL2041199T3 (pl) Sposób wytwarzania lepkosprężystych pianek
JP2011505471A5 (ja)
JP2010534254A5 (ja)
DK2091990T3 (da) Fremgangsmåde til fremstilling af polyurethan-blødskumstoffer
IN2012DN02547A (ja)
WO2005033167A3 (en) Flexible polyurethane foams prepared using modified vegetable oil-based polyols
MX2008012244A (es) Catalizadores de amina adecuados para la produccion de materiales esponjados blandos de poliuretano pobres en emisiones, estables a la recatalisis.
WO2009048802A3 (en) Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents
WO2009106240A3 (de) Viskoelastischer polyurethanschaumstoff mit rizinusöl
ATE373031T1 (de) Verfahren zur herstellung von emissionsarmen polyurethan-weichschaumstoffen
WO2009148559A3 (en) Process for preparing ridig polyisocyanurate foams using natural-oil polyols
WO2003042268A1 (fr) Procede de production de mousse a base de resine synthetique
ATE407160T1 (de) Polyurethanschäume, hergestellt mit katalysatorzusammensetzungen, die das aufschäumen begünstigen und die primäre hydroxylgruppen und ein ethylendiaminrückgrat aufweisen.
ATE388974T1 (de) Verfahren zur herstellung von polyurethan- hartschaumstoffen
PL1984415T3 (pl) Surfaktanty homogenizujące dla polioli i żywic poliuretanowych
IL217882A (en) Polyurethane is formed from a reaction mixture that includes polyisocyanate, polyol and diol, and is free from sulfur, diamines and polyamines
WO2008055189A3 (en) Non-petroleum-based polyurethane foam products having improved performance specifications and method of production
MX2009011894A (es) Espumas de poliisocianurato rigido y procesos para su produccion y uso.
MX2012003659A (es) Proceso para producir espumas de poliuretano rigidas.

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880113302.2

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08842459

Country of ref document: EP

Kind code of ref document: A1

REEP Request for entry into the european phase

Ref document number: 2008842459

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 12739885

Country of ref document: US

Ref document number: 2008842459

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE