WO2009041384A1 - 触媒およびその製法、ならびに該触媒を用いた塩素の製造方法 - Google Patents

触媒およびその製法、ならびに該触媒を用いた塩素の製造方法 Download PDF

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Publication number
WO2009041384A1
WO2009041384A1 PCT/JP2008/067085 JP2008067085W WO2009041384A1 WO 2009041384 A1 WO2009041384 A1 WO 2009041384A1 JP 2008067085 W JP2008067085 W JP 2008067085W WO 2009041384 A1 WO2009041384 A1 WO 2009041384A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
producing
same
chlorine
alkali metal
Prior art date
Application number
PCT/JP2008/067085
Other languages
English (en)
French (fr)
Inventor
Nobuhiko Horiuchi
Kenichi Sugimoto
Masami Murakami
Kenji Iwata
Original Assignee
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals, Inc. filed Critical Mitsui Chemicals, Inc.
Priority to KR1020107008826A priority Critical patent/KR101161958B1/ko
Priority to US12/733,848 priority patent/US8222178B2/en
Priority to EP08834482.5A priority patent/EP2198959A4/en
Priority to JP2009534316A priority patent/JP5414527B2/ja
Priority to CN200880108776.8A priority patent/CN101827653B/zh
Publication of WO2009041384A1 publication Critical patent/WO2009041384A1/ja
Priority to US13/526,353 priority patent/US20120258856A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/04—Preparation of chlorine from hydrogen chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

　本発明は、触媒の存在下で塩化水素を酸素により酸化して塩素を製造する方法等に使用可能な、銅元素、アルカリ金属元素、および希土類元素を含有する活性に優れる触媒を提供することを目的とする。本発明の触媒は、銅元素、アルカリ金属元素、および希土類元素を含有する触媒であって、前記触媒の細孔直径が５～１５ｎｍの範囲において、０．４～２．０ｍｌ／ｇの細孔容積を有することを特徴とする。
PCT/JP2008/067085 2007-09-27 2008-09-22 触媒およびその製法、ならびに該触媒を用いた塩素の製造方法 WO2009041384A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020107008826A KR101161958B1 (ko) 2007-09-27 2008-09-22 촉매 및 그의 제법, 및 상기 촉매를 이용한 염소의 제조방법
US12/733,848 US8222178B2 (en) 2007-09-27 2008-09-22 Catalyst and production process thereof, and chlorine production using the catalyst
EP08834482.5A EP2198959A4 (en) 2007-09-27 2008-09-22 CATALYST, PRODUCTION PROCESS AND METHOD FOR PRODUCING CHLORINE USING THE CATALYST
JP2009534316A JP5414527B2 (ja) 2007-09-27 2008-09-22 触媒およびその製法、ならびに該触媒を用いた塩素の製造方法
CN200880108776.8A CN101827653B (zh) 2007-09-27 2008-09-22 催化剂及其制法、以及使用该催化剂的氯的制造方法
US13/526,353 US20120258856A1 (en) 2007-09-27 2012-06-18 Catalyst and production process thereof, and chlorine production using the catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007251808 2007-09-27
JP2007-251808 2007-09-29

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/526,353 Division US20120258856A1 (en) 2007-09-27 2012-06-18 Catalyst and production process thereof, and chlorine production using the catalyst

Publications (1)

Publication Number Publication Date
WO2009041384A1 true WO2009041384A1 (ja) 2009-04-02

Family

ID=40511269

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/067085 WO2009041384A1 (ja) 2007-09-27 2008-09-22 触媒およびその製法、ならびに該触媒を用いた塩素の製造方法

Country Status (7)

Country Link
US (2) US8222178B2 (ja)
EP (1) EP2198959A4 (ja)
JP (1) JP5414527B2 (ja)
KR (1) KR101161958B1 (ja)
CN (1) CN101827653B (ja)
TW (1) TW200922692A (ja)
WO (1) WO2009041384A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102000583A (zh) * 2010-11-18 2011-04-06 烟台万华聚氨酯股份有限公司 一种氯化氢氧化制氯气的催化剂及其制备方法
WO2011118386A1 (ja) * 2010-03-25 2011-09-29 三井化学株式会社 塩素の製造方法
JP2012061450A (ja) * 2010-09-17 2012-03-29 Mitsui Chemicals Inc 塩素製造用再生触媒の製造方法、劣化触媒の再生方法、塩素の製造方法及び塩素製造用触媒の活性維持方法
JPWO2010110392A1 (ja) * 2009-03-26 2012-10-04 三井化学株式会社 塩素製造用触媒および該触媒を用いた塩素の製造方法
WO2023032917A1 (ja) 2021-09-03 2023-03-09 三井化学株式会社 塩酸酸化触媒および塩素の製造方法
WO2023032918A1 (ja) 2021-09-03 2023-03-09 三井化学株式会社 塩酸酸化触媒および塩素の製造方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5130155B2 (ja) * 2008-08-28 2013-01-30 住友化学株式会社 塩素の製造方法
EP2445831B1 (de) * 2009-06-24 2013-08-14 Basf Se Verfahren zur herstellung von chlor aus hci
JP5636601B2 (ja) * 2010-03-11 2014-12-10 住友化学株式会社 固定床反応器による塩素の製造方法
US8822370B2 (en) * 2011-05-16 2014-09-02 Uop Llc Substantially non-porous substrate supported noble metal-and lanthanide-containing catalysts
CN105642318B (zh) * 2014-11-11 2018-08-21 上海氯碱化工股份有限公司 氯化氢催化氧化制氯气的催化剂制法及应用
CN104923239A (zh) * 2015-05-29 2015-09-23 华东理工大学 用于氯化氢催化氧化制氯气的铜基催化剂及其制备方法和应用
CN109952270B (zh) * 2016-12-02 2023-01-17 三井化学株式会社 基于氯化氢氧化的氯的制造方法
CN115845855B (zh) * 2022-12-09 2024-05-28 上海氯碱化工股份有限公司 用于氯化氢催化制氯的耐氟化氢催化剂及其制备方法

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JPH01257102A (ja) * 1988-04-06 1989-10-13 Mitsui Toatsu Chem Inc 塩化水素から塩素を製造する方法
JPH105592A (ja) * 1996-06-21 1998-01-13 Mitsui Petrochem Ind Ltd 塩化水素から塩素を製造するための触媒

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WO1988000171A1 (en) * 1986-06-26 1988-01-14 Mitsui Toatsu Chemicals, Inc. Process for producing chlorine
JPH01257102A (ja) * 1988-04-06 1989-10-13 Mitsui Toatsu Chem Inc 塩化水素から塩素を製造する方法
JPH105592A (ja) * 1996-06-21 1998-01-13 Mitsui Petrochem Ind Ltd 塩化水素から塩素を製造するための触媒

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010110392A1 (ja) * 2009-03-26 2012-10-04 三井化学株式会社 塩素製造用触媒および該触媒を用いた塩素の製造方法
JP5468065B2 (ja) * 2009-03-26 2014-04-09 三井化学株式会社 塩素製造用触媒および該触媒を用いた塩素の製造方法
WO2011118386A1 (ja) * 2010-03-25 2011-09-29 三井化学株式会社 塩素の製造方法
JP2012061450A (ja) * 2010-09-17 2012-03-29 Mitsui Chemicals Inc 塩素製造用再生触媒の製造方法、劣化触媒の再生方法、塩素の製造方法及び塩素製造用触媒の活性維持方法
CN102000583A (zh) * 2010-11-18 2011-04-06 烟台万华聚氨酯股份有限公司 一种氯化氢氧化制氯气的催化剂及其制备方法
JP2014503341A (ja) * 2010-11-18 2014-02-13 ワンホア ケミカル グループ カンパニー リミテッド 塩化水素の酸化によって塩素を調製するための触媒およびその調製方法
WO2023032917A1 (ja) 2021-09-03 2023-03-09 三井化学株式会社 塩酸酸化触媒および塩素の製造方法
WO2023032918A1 (ja) 2021-09-03 2023-03-09 三井化学株式会社 塩酸酸化触媒および塩素の製造方法
KR20240033078A (ko) 2021-09-03 2024-03-12 미쓰이 가가쿠 가부시키가이샤 염산 산화 촉매 및 염소의 제조 방법
KR20240033278A (ko) 2021-09-03 2024-03-12 미쓰이 가가쿠 가부시키가이샤 염산 산화 촉매 및 염소의 제조 방법

Also Published As

Publication number Publication date
TW200922692A (en) 2009-06-01
US8222178B2 (en) 2012-07-17
US20120258856A1 (en) 2012-10-11
CN101827653A (zh) 2010-09-08
EP2198959A1 (en) 2010-06-23
KR101161958B1 (ko) 2012-07-04
CN101827653B (zh) 2015-04-08
JP5414527B2 (ja) 2014-02-12
JPWO2009041384A1 (ja) 2011-01-27
KR20100058655A (ko) 2010-06-03
EP2198959A4 (en) 2014-06-04
US20100196255A1 (en) 2010-08-05

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