WO2005117122A1 - Simox基板の製造方法及び該方法により得られるsimox基板 - Google Patents
Simox基板の製造方法及び該方法により得られるsimox基板 Download PDFInfo
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- WO2005117122A1 WO2005117122A1 PCT/JP2005/009166 JP2005009166W WO2005117122A1 WO 2005117122 A1 WO2005117122 A1 WO 2005117122A1 JP 2005009166 W JP2005009166 W JP 2005009166W WO 2005117122 A1 WO2005117122 A1 WO 2005117122A1
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- 238000000034 method Methods 0.000 title claims abstract description 69
- 239000000758 substrate Substances 0.000 title claims description 115
- 238000010438 heat treatment Methods 0.000 claims abstract description 306
- 239000001301 oxygen Substances 0.000 claims abstract description 232
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 232
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 198
- 239000002244 precipitate Substances 0.000 claims abstract description 112
- 239000007789 gas Substances 0.000 claims abstract description 63
- 239000012298 atmosphere Substances 0.000 claims abstract description 60
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 66
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 51
- 230000007547 defect Effects 0.000 claims description 51
- 229910052710 silicon Inorganic materials 0.000 claims description 51
- 239000010703 silicon Substances 0.000 claims description 51
- 238000005468 ion implantation Methods 0.000 claims description 48
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 42
- 238000004519 manufacturing process Methods 0.000 claims description 41
- -1 oxygen ions Chemical class 0.000 claims description 36
- 229910052786 argon Inorganic materials 0.000 claims description 33
- 241000652704 Balta Species 0.000 claims description 31
- 238000005247 gettering Methods 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 19
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 18
- 229910001882 dioxygen Inorganic materials 0.000 claims description 18
- 125000004429 atom Chemical group 0.000 claims description 15
- 238000001556 precipitation Methods 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 11
- 239000011261 inert gas Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 230000004888 barrier function Effects 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 38
- 238000011109 contamination Methods 0.000 abstract description 18
- 238000002347 injection Methods 0.000 abstract 4
- 239000007924 injection Substances 0.000 abstract 4
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 abstract 3
- 150000002500 ions Chemical class 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 153
- 235000012431 wafers Nutrition 0.000 description 136
- 239000010408 film Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 239000013078 crystal Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- 239000000356 contaminant Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000009825 accumulation Methods 0.000 description 5
- 230000006911 nucleation Effects 0.000 description 5
- 238000010899 nucleation Methods 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000012300 argon atmosphere Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000002513 implantation Methods 0.000 description 3
- 241001168730 Simo Species 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000000407 epitaxy Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/76—Making of isolation regions between components
- H01L21/762—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
- H01L21/7624—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology
- H01L21/76243—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology using silicon implanted buried insulating layers, e.g. oxide layers, i.e. SIMOX techniques
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/322—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections
- H01L21/3221—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections of silicon bodies, e.g. for gettering
- H01L21/3225—Thermally inducing defects using oxygen present in the silicon body for intrinsic gettering
Definitions
- the present invention relates to an SOI (Silicon-On-Insulator) substrate in which a single-crystal silicon layer (hereinafter, referred to as an SOI layer) is formed on a silicon single-crystal main body via a buried oxide layer (Buried Oxide).
- SOI Silicon-On-Insulator
- the present invention relates to a method for manufacturing a SIMOX substrate by SIMOX (Separation by Implanted Oxygen) technology and a SIMOX substrate obtained by the method. More specifically, the present invention relates to a method for manufacturing a SIMOX substrate capable of efficiently capturing heavy metal contamination due to ion implantation or high-temperature heat treatment inside the substrate, and a SIMOX substrate obtained by the method.
- An SOI substrate can (1) reduce the parasitic capacitance between an element and a substrate, so that device operation can be performed at high speed, (2) it is excellent in radiation withstand voltage, and (3) it is easy to separate a dielectric. Therefore, it has very excellent features such as high integration density and (4) improvement of latch-up resistance.
- SOI substrate manufacturing methods can be broadly classified into two types.
- One method is a laminating method in which an active wafer to be thinned is bonded to a supporting wafer, and the other method is to implant oxygen ions from the wafer surface to form a wafer surface force.
- This is a SIMOX method in which a buried oxide layer is formed in a region of a predetermined depth.
- the SIMOX method is expected to be an effective method in the future because of the small number of manufacturing steps!
- an oxygen ion implantation step of, after mirror polishing one main surface of a silicon single crystal substrate, implanting this mirror-finished surface force oxygen ions to a predetermined depth in the substrate by implantation,
- a high-temperature heat treatment step for forming a buried oxide layer inside the substrate by performing a high-temperature heat treatment on the substrate into which oxygen ions have been implanted under an oxidizing atmosphere is also configured.
- the silicon single crystal substrate is maintained at a temperature of 500 ° C to 650 ° C, and the surface force of the substrate is about 10 17 to 10 18 atoms / cm 2 , and oxygen atom ions or oxygen molecule ions at a predetermined depth. inject.
- the silicon substrate into which oxygen ions have been implanted is put into a heat treatment furnace maintained at a temperature of 500 ° C to 700 ° C, and the temperature is gradually increased so as not to cause a slip, and is about 1300 ° C to 1390 ° C A heat treatment is performed at a temperature of about 10 hours.
- This high temperature Oxygen ions implanted into the substrate by the heat treatment react with silicon to form a buried oxide layer inside the substrate.
- a gettering technique for removing a metal having a direct adverse effect on device characteristics from a substrate surface force includes a method in which the back surface of the substrate is distorted by sandblasting, and a method in which the back surface of the substrate is frequently used.
- There are external gettering methods such as a method of depositing a crystalline silicon film and a method of injecting high-concentration phosphorus into the backside of the substrate.
- distortion of crystal defects caused by oxygen precipitates deposited inside the silicon substrate is known.
- An internal gettering method using a field is used for mass production as a clean gettering method with excellent mass productivity and in part.
- SIMOX substrates require high-temperature heat treatment at about 1300 ° C after oxygen ion implantation to form a buried oxide layer inside the substrate. It was said that it was difficult to form oxygen precipitates as internal gettering sinks inside.
- silicon single crystal wafers have point defects, i.e., interstitial point defects in which an S element penetrates between lattices, and vacancy type point defects in which the S element forming the lattice is missing. However, this point defect exists in thermal equilibrium.
- interstitial point defects 1 ⁇ 10 17 Zcm 3
- vacancy type point defects 1 ⁇ 10 15 Zcm 3
- interstitial point defects 1 ⁇ 10 16 Zcm 3
- vacancy type point defects 1 ⁇ 10 5 Zcm 3
- point defects exist in a thermo-equilibrium manner and at 1200 ° C. It is known that the point defect concentration is higher than the point defect concentration at 600 ° C.
- a high-temperature heat treatment at about 1300 ° C is performed after forming an oxygen precipitate at a predetermined temperature lower than the high-temperature heat treatment temperature and in the Balta layer. If applied, the oxygen precipitates formed in the Balta layer were thought to disappear by this high temperature heat treatment.
- the substrate is heated at a temperature of 1200 to 1300C in a hydrogen atmosphere or a nitrogen atmosphere containing a small amount of oxygen.
- a method of manufacturing a semiconductor substrate has been proposed in which a buried oxide layer is formed by performing heat treatment for 6 to 12 hours, and then the temperature is increased stepwise or continuously from low temperature to high temperature and then heat treatment is performed (for example, Patent See Reference 2.) 0 Specific heat shown in Patent Reference 2
- a stepwise heat treatment method is started at 500 ° C, and it is gradually increased at 50 to 100 ° C to a final temperature of 850 ° C, and a continuous heat treatment method is 500 ° C. Starting from this, a method is described in which the final temperature is 850 ° C with a gradient of 0.2-1.0 ° CZ.
- a SIMOX having a region in which a buried oxide layer is not formed partially and having a structure in which gettering means due to crystal defects or crystal distortion is provided on the back surface of a silicon single crystal substrate balta or a silicon single crystal substrate substrate and a manufacturing method thereof have been proposed (e.g., see Patent Document 3.)
- a buried oxide layer is formed on piecemeal near the surface, the heat treatment condition for gettering 500 form to 900 ° C oxygen precipitate nuclei in the range of the density is in the range of 10 5 / cm 3 to 10 9 pieces / cm 3, the deposition in the range of 1000 to 1150 ° C as a second heat treatment It also states that nuclei can be grown and formed into precipitates.
- the amount of crystal defects generated on the substrate surface due to the quantitative contamination of heavy metals is evaluated using the conventional SIMOX, that is, SIMOX in which an oxidized film grown on the entire surface of the wafer is used as a reference sample.
- SIMOX SIMOX in which an oxidized film grown on the entire surface of the wafer is used as a reference sample.
- partial embedding whereas surface defects are hardly observed in the embodiment of Sani ⁇ , pits and stacking faults of the conventional in SIMOX 10 5 to 10 6 pieces / cm 2 was observed Ru.
- Patent Document 2 means that a complete gettering technique has not been established.
- Patent Document 1 Japanese Patent Publication No. 3-9078 (Page 2, column 3, lines 6 to 13)
- Patent Document 2 JP-A-7-193072 (Claims 1 to 3)
- Patent Document 3 JP-A-5-82525 (Claims 1, 2, 4, and 5, paragraphs [0019] to [0023])
- Non-Patent Document 1 J. Electrochem. Soc., 142, 2059, (1995)
- An object of the present invention is to form a gettering sink inside a Balta layer before a high-temperature heat treatment for forming a buried oxide layer and an SOI layer, thereby preventing heavy metal contamination caused by ion implantation and high-temperature heat treatment from occurring.
- An object of the present invention is to provide a method for manufacturing a SIMOX substrate, which can be efficiently captured inside, and a SIMOX substrate obtained by the method.
- Another object of the present invention is to provide a method for manufacturing a SIMOX substrate and a SIMOX substrate obtained by the method, in which the concentration of heavy metals in the defect accumulating layer can be reduced and heavy metals can be efficiently captured inside the metal layer. It is in.
- the present inventors have performed a high-temperature heat treatment for forming a buried oxide layer inside a substrate and an SOI layer thereon after performing a heat treatment for forming oxygen precipitates.
- a high-temperature heat treatment for forming a buried oxide layer inside a substrate and an SOI layer thereon after performing a heat treatment for forming oxygen precipitates.
- oxygen ions are implanted into the silicon wafer 11 as shown in FIGS. 1 (a) to 1 (f) or 2 (a) to 2 (f).
- Oxygen ion implantation process and wafer 11 Is subjected to a first heat treatment at 1300 to 1390 ° C. in a mixed gas atmosphere of oxygen and an inert gas, thereby forming an embedded oxide layer 12 in a region where the surface force of the wafer 11 has a predetermined depth and an embedded oxide layer.
- This is an improvement in the method for manufacturing a SIMOX substrate, including a first heat treatment step of forming an SOI layer 13 on the surface of the wafer on the dangling layer 12.
- the characteristic configuration is that the silicon wafer 11 before oxygen ion implantation has an oxygen concentration of 9 ⁇ 10 17 to 1.8 ⁇ 10 18 atoms / cm 3 (former ASTM) and the buried oxide layer 12 has a A second heat treatment step for forming oxygen precipitation nuclei 14b inside the wafer 11 before or after the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step; The third heat treatment step for growing the oxygen precipitate nuclei 14b formed inside the wafer 11 into the oxygen precipitates 14c following the heat treatment step.
- the second and third heat treatments for growing the oxygen precipitates 14c are performed before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step. Heavy metal contamination caused by the high-temperature heat treatment can be efficiently captured inside the Balta layer 14 by the oxygen precipitates 14c formed by the second and third heat treatments.
- the gettering source consisting of oxygen precipitates 14c is provided in the Balta layer 14 below the defect accumulating layer 14a, and the density of the oxygen precipitates 14c is 1 ⁇ 10 8 to 1 ⁇ 10 12 / It is possible to obtain a SIMOX substrate having a size of cm 3 and a size of the oxygen precipitate 14c of 50 nm or more.
- the invention according to claim 2 is the invention according to claim 1, wherein the second heat treatment in the second heat treatment step is performed by subjecting the wafer to hydrogen, argon, nitrogen, oxygen gas, or a mixed gas atmosphere thereof.
- the third heat treatment in the third heat treatment step is performed by holding the wafer at the temperature of 500 to 900 ° C for 1 to 96 hours, using hydrogen, argon, nitrogen, oxygen gas, or a mixed gas thereof. This is a production method carried out by maintaining at a temperature of 900 to 1250 ° C. higher than the second heat treatment temperature for 1 to 96 hours in an atmosphere.
- the invention according to claim 3 is the invention according to claim 1, wherein the embedded silicon wafer is subjected to the fourth heat treatment in which the first heat-treated wafer is held at 500 to 1200 ° C for 1 to 96 hours.
- This is a production method further including a fourth heat treatment step of regrowing the oxygen precipitates 14c formed inside the warta layer 14 below the dangling layer 12.
- the size of the oxygen precipitate 14c can be regrown by performing the fourth heat treatment.
- the invention according to claim 4 is the invention according to claim 1 or 2, wherein the second heat treatment in the second heat treatment step is partially or entirely in the range of 500 ° C to 900 ° C.
- the third heat treatment in the third heat treatment step is performed at a temperature of 900 ° C to 1250 ° C by raising the temperature at a rate of 0.1 to 20.0 ° CZ. This is a production method performed in the range of 1 to 96 hours by raising the temperature at a rate of 0.1 to 20 ° CZ in all or part of the range.
- oxygen ions are implanted inside the silicon wafer 11.
- This is an improvement in the method of manufacturing a SIMOX substrate, including a first heat treatment step of forming the SOI layer 13 on the surface of the wafer on the embedded oxide layer 12 while forming the buried oxide layer 12.
- the characteristic configuration is that the silicon wafer 11 before oxygen ion implantation has an oxygen concentration of 9 ⁇ 10 17 to 1.8 ⁇ 10 18 atoms / cm 3 (former ASTM) and the buried oxide layer 12 has a A rapid heat treatment step for implanting vacancies 15 inside the wafer 11 before or after the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step; A second heat treatment step for forming oxygen precipitate nuclei 14b inside the wafer 11 following the second heat treatment step and growing the oxygen precipitate nuclei 14b formed inside the wafer 11 following the second heat treatment step into oxygen precipitates 14c And a third heat treatment step.
- a rapid heat treatment step for implanting vacancies 15 inside the wafer 11 before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step, and growing the oxygen precipitates 14c By performing the second and third heat treatments, heavy metal contamination caused by ion implantation and high-temperature heat treatment can be efficiently captured inside the Balta layer 14 by the oxygen precipitates 14 c formed by the second and third heat treatments. . In addition, by performing the rapid heat treatment step, in-plane uniformity of the oxygen precipitate density distribution in the wafer 11 plane is ensured, and Even with a silicon wafer having an elemental concentration, the reliability of growth of oxygen precipitates is improved.
- the gettering source consisting of oxygen precipitates 14c is provided in the Balta layer 14 below the defect accumulating layer 14a, and the density of the oxygen precipitates 14c is 1 ⁇ 10 8 to 1 ⁇ 10 12 / It is possible to obtain a SIMOX substrate having a size of cm 3 and a size of the oxygen precipitate 14c of 50 nm or more.
- the invention according to claim 6 is the invention according to claim 5, wherein the rapid heat treatment in the rapid heat treatment step is performed under a mixed gas atmosphere of a non-oxidizing gas or an ammonia gas at 1050 to 1050. After maintaining the temperature at 1350 ° C for 1 to 900 seconds, the temperature is reduced at a rate of 10 ° C / sec or more, and the second heat treatment in the second heat treatment step is performed by rapidly heating the wafer with hydrogen, argon, and nitrogen. In an atmosphere of oxygen gas or a mixed gas thereof, the temperature is maintained at 500 to 1000 ° C. for 1 to 96 hours. This is a production method performed by maintaining the atmosphere at a temperature of 900 to 1250 ° C, which is higher than the second heat treatment temperature, for 1 to 96 hours in an atmosphere of nitrogen or oxygen gas or a mixed gas thereof.
- the invention according to claim 7 is the invention according to claim 5, wherein the buried oxide layer is formed by subjecting the first heat-treated wafer to a fourth heat treatment at 500 to 1200 ° C for 1 to 96 hours.
- This is a production method further comprising the step of re-growing the oxygen precipitates 14c formed inside the Balta layer 14 below 12.
- the size of the oxygen precipitate 14c can be regrown by performing the fourth heat treatment.
- the invention according to claim 8 is the invention according to claim 5 or 6, wherein the second heat treatment in the second heat treatment step is partially or entirely in the range of 500 ° C to 1000 ° C.
- the third heat treatment is performed at a temperature of 1000 to 1250 ° C by raising the temperature at a rate of 0.1 to 20.0 ° CZ. This is a production method performed in a range of 1 to 96 hours by raising the temperature at a rate of 0.1 to 20 ° CZ in part or all of the range.
- An invention according to claim 9 is the SIMOX substrate manufactured by the method according to any one of claims 1 to 8, wherein the embedded oxide layer is formed in a region having a predetermined surface depth of the wafer. 12 and an SOI layer 13 formed on the surface of the wafer on the buried oxide layer.
- a defect collecting layer 14a formed immediately below the oxide layer 12 and a barta layer 14 below the buried oxide layer 12, and the gettering comprising oxygen precipitates 14c is formed on the barta layer 14 below the defect collecting layer 14a.
- the gettering source composed of oxygen precipitates 14c is provided in the Balta layer 14 below the defect accumulating layer 14a, and the density of the oxygen precipitates 14c is 1 ⁇ 10 8 to 1 ⁇ 10 12. / cm3, and the size of the oxygen precipitate 14c is 50 nm or more, so it is a stronger gettering source than the defect accumulating layer 14a, so most of the heavy metal contaminants conventionally trapped in the defect accumulating layer 14a Can be gettered to the oxygen precipitates 14c of the Balta layer 14 without being trapped in the defect accumulating layer.
- the method for producing a SIMOX substrate of the present invention includes a method including a second heat treatment step and a third heat treatment step before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step, or a rapid method.
- a method including a second heat treatment step and a third heat treatment step before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step or a rapid method.
- the SIM OX substrate of the present invention has a gettering source that also has an oxygen precipitate force in the Balta layer below the defect accumulating layer, and the density of the oxygen precipitate is 1 ⁇ 10 8 to 1 ⁇ 10 12 / cm 3 Since the size of the oxygen precipitate is 50 nm or more, it becomes a stronger gettering source than the defect accumulating layer, so that the heavy metal trapping concentration in the defect accumulating layer can be reduced, and heavy metal is contained inside the balta layer. It is possible to capture efficiently.
- FIG. 1 is a process chart showing a method for manufacturing a SIMOX substrate according to a first embodiment of the present invention.
- FIG. 2 is a process chart showing another method for manufacturing a SIMOX substrate according to the first embodiment of the present invention.
- FIG. 3 is a process chart showing a method for manufacturing a SIMOX substrate according to a second embodiment of the present invention.
- FIG. 4 is a process chart showing another method for manufacturing a SIMOX substrate according to the second embodiment of the present invention.
- the first heat treatment is performed at 1300 ° C. and 1390 ° C. in a mixed gas atmosphere of oxygen and an inert gas, so that the surface force is embedded in a region having a predetermined depth.
- the present invention relates to a SIMOX substrate having an oxide layer formed thereon and an SOI layer formed on the surface of the oxide layer.
- a characteristic configuration of the method for manufacturing a SIM OX substrate according to the present invention is that the oxygen precipitation inside the substrate 11 before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step.
- a method of performing a second heat treatment step before oxygen ion implantation and a third heat treatment step following the second heat treatment step in this order will be described in detail.
- a silicon wafer 11 is prepared.
- the prepared silicon layer 11 has an oxygen concentration of 9 ⁇ 10 17 1.8 ⁇ 10 18 atoms / cm 3 (former ASTM).
- This prepared silicon is epitaxy or a Norreja may be used.
- the prepared silicon wafer 11 is subjected to a second heat treatment.
- oxygen precipitation nuclei 14b are formed inside the wafer 11.
- the second heat treatment in the second heat treatment step is preferably performed by maintaining the wafer at a temperature of 500 to 900 ° C for 1 to 96 hours in an atmosphere of hydrogen, argon, nitrogen, oxygen gas or a mixed gas thereof.
- the gas atmosphere of the second heat treatment is more preferably performed in an argon or trace oxygen (nitrogen or argon gas base) gas atmosphere.
- the reason why the second heat treatment temperature is specified in the range of 500 to 900 ° C is that if the temperature is lower than the lower limit, the nucleation temperature is too low and a long heat treatment is required, and if the temperature exceeds the upper limit, oxygen precipitation nucleation does not occur. That's why.
- the reason why the second heat treatment time is specified in the range of 1 to 96 hours is that if the time is less than the lower limit, the time for forming oxygen precipitation nuclei is too short, and if the time exceeds the upper limit, the productivity is reduced. This is because This second heat treatment is more preferably performed at a temperature of 500 to 800 ° C. for 4 to 35 hours.
- the temperature is raised at a rate of 0.1 to 20.0 ° CZ, preferably at a rate of 0.1 to 5.0 ° CZ, in a partial range or a whole range from 500 ° C to 900 ° C. Depending on the case, it may be performed within a range of 1 to 96 hours, preferably 4 to 35 hours.
- the wafer 11 subjected to the second heat treatment is subjected to a third heat treatment.
- the oxygen precipitate nuclei 14b formed inside the wafer 11 can be grown into oxygen precipitates 14c.
- the wafer subjected to the second heat treatment is heated to 900 to 1250 ° C. higher than the second heat treatment temperature in an atmosphere of hydrogen, argon, nitrogen, oxygen gas or a mixed gas atmosphere thereof. It is preferably carried out by holding for 1 to 96 hours.
- the gas atmosphere of the third heat treatment is more preferably performed in an argon or trace oxygen (nitrogen or argon gas base) gas atmosphere.
- the reason why the third heat treatment temperature is specified in the range of 900 to 1250 ° C is that if the temperature is less than the lower limit value, the growth of oxygen precipitates is difficult to occur sufficiently. is there.
- the reason why the third heat treatment time is specified within the range of 1 to 96 hours is that if the growth is less than the lower limit and the growth of oxygen precipitates is insufficient, the productivity is reduced if the upper limit is exceeded. This is because a combination occurs.
- the third heat treatment is more preferably performed at 1000 to 1200 ° C. for 8 to 24 hours.
- the third heat treatment is carried out by increasing the temperature at a rate of 0.1 to 20 ° CZ, preferably at a rate of 1 to 5 ° CZ, in a part or all of the range from 900 ° C to 1250 ° C.
- the reaction may be carried out for a period of up to 96 hours, preferably 8 to 24 hours.
- oxygen ions are implanted into the inside of the wafer 11 subjected to the third heat treatment.
- This implantation of oxygen ions is also performed conventionally, and is performed by the same means.
- oxygen ions are implanted into the region 11a having a predetermined depth from the surface of the wafer 11 so that the thickness of the SOI layer 13 in the finally obtained SIMOX substrate becomes 10 to 200 nm, preferably 20 to LOOnm. You. If the thickness of the SOI layer 13 is less than 10 nm, it is difficult to control the thickness of the SOI layer 13, and if the thickness of the SOI layer 13 exceeds 200 nm, it is difficult due to the acceleration voltage of the oxygen ion implanter.
- a mask or the like is partially formed at a desired position on the surface of the silicon wafer 11 and oxygen ions are implanted into the inside of the silicon wafer 11 so that a mask is not formed. Since oxygen ions are implanted and oxygen ions are not implanted into the inside of the wafer below the portion where the mask is formed, the subsequent first heat treatment is performed to bury the oxide only below the portion where the mask is not formed. Layer 12 is partially formed. Note that even if heavy metal contamination due to the ion implantation process occurs, the heavy metal, which is a contaminant, is reduced by the oxygen precipitates 14c formed by performing the second heat treatment step and the third heat treatment step. It can be efficiently captured inside.
- the wafer 11 into which oxygen ions have been implanted is subjected to a first heat treatment at a temperature of 1300 to 1390 ° C. in a mixed gas atmosphere of oxygen and an inert gas.
- the inert gas include an argon gas and a nitrogen gas. Therefore, the gas atmosphere of the first heat treatment is preferably a mixed gas of oxygen and argon or a mixed gas of oxygen and nitrogen.
- the heat treatment time of the first heat treatment is preferably 1 to 20 hours, more preferably 10 to 20 hours.
- an oxidized film l ib, 11c is formed on the front and back surfaces of the wafer 11.
- the embedded oxide layer 12 is formed over the entire surface of the wafer 11 or in the area 1 la of the wafer 11 having a predetermined surface depth.
- an SOI layer 13 is formed between the front-side oxidized film l ib and the buried oxidized film 12.
- a defect accumulating layer 14a is inevitably formed immediately below the buried oxide layer 12.
- the oxygen precipitate near the surface layer is dissolved by the first heat treatment, and becomes a DZ layer (denuded zone) in which no oxygen precipitate exists.
- the oxygen precipitates 14c existing in the defect accumulating layer 14a immediately below the buried oxide layer 12 and the Balta layer 14 located therebelow are further grown by increasing the temperature in the early stage of the first heat treatment step, and the oxygen precipitates 14c
- the size of the precipitate increases, the melting starts when the temperature in the middle stage is maintained at 1300-1390 ° C, and the size decreases to a certain size.
- the growth starts again by lowering the temperature at the end of the first heat treatment step. Therefore, even if the first heat treatment step is performed, it is presumed that the oxygen precipitate 14c formed in advance remains in the Balta 14.
- the heavy metal that is the contaminant is removed by the oxygen precipitate 14c formed by performing the second heat treatment step and the third heat treatment step. 14Can be efficiently captured inside.
- the first heat treatment may be followed by a fourth heat treatment in which the wafer subjected to the first heat treatment is kept at 500 to 1200 ° C. for 1 to 96 hours.
- oxygen precipitates 14c formed in the inside of notch layer 14 below buried oxide layer 12 can be regrown.
- the gas atmosphere of the fourth heat treatment is preferably performed in an argon or trace oxygen (nitrogen or argon gas base) gas atmosphere.
- the reason why the fourth heat treatment temperature is specified within the range of 500 to 1200 ° C is that the growth of oxygen precipitates 14 c is less likely to occur sufficiently below the lower limit, and slipping occurs if the upper limit is exceeded. That's why.
- the reason why the fourth heat treatment time is specified in the range of 1 to 96 hours is that if the growth is less than the lower limit, the growth of the oxygen precipitates 14c is not sufficient, and if the upper limit is exceeded, productivity may be reduced. is there.
- the fourth heat treatment is preferably performed at 1000 to 1200 ° C. for 8 to 24 hours.
- the oxide films lib and 11c formed on the front and back surfaces of the wafer 11 subjected to the first heat treatment are removed with hydrofluoric acid or the like.
- a predetermined A buried oxide layer 12 formed in the depth region, an SOI layer 13 formed on the surface of the wafer above the buried oxide layer, a defect accumulating layer 14a formed immediately below the buried oxide layer 12, and a buried oxide layer are formed in the depth region.
- a gettering source composed of oxygen precipitates 14c in the barta layer 14 below the defect accumulating layer 14a, wherein the density of the oxygen precipitates 14c is 1 ⁇ 10 8 to 1 X10 12 / cm 3 , and the size of the oxygen precipitate 14c is 50 nm or more, whereby a SIMOX substrate is obtained.
- the Balta layer 14 below the defect accumulating layer 14a has an oxygen precipitate 14c having a density of 1 ⁇ 10 8 to 1 ⁇ 10 12 / cm 3 and a size of 50 nm or more.
- sudden heavy metal contamination during the device process can be efficiently captured by the oxide precipitate 14c.
- the silicon oxide precipitate 14c is a stronger gettering source than the defect accumulation layer 14a, the heavy metal contaminant is trapped by the conventional defect accumulation layer 14a, and the heavy metal contaminant is gettered by the oxygen precipitate 14c of the warta layer 14. Can be ring.
- the present invention can be applied to a SIMOX substrate in which a buried oxide layer is partially formed.
- a SIMOX substrate similar to the SIMOX substrate shown in FIG. 1 can be obtained by performing the second heat treatment step and the third heat treatment step between the oxygen ion implantation step and the first heat treatment step.
- the first heat treatment is performed at 1300 to 1390 ° C. in a mixed gas atmosphere of oxygen and an inert gas, so that the surface force of the wafer becomes a region having a predetermined depth.
- the present invention relates to a SIMOX substrate having a buried oxide layer formed thereon and an SOI layer formed on the surface of the wafer.
- a characteristic configuration of the method for manufacturing a SIM OX substrate according to the present invention is that a hole 15 is formed inside the wafer 11 before the oxygen ion implantation step or between the oxygen ion implantation step and the first heat treatment step.
- Rapid heat treatment step for implanting oxygen and oxygen precipitate nuclei 14b formed inside wafer 11 following this rapid heat treatment step And a third heat treatment step following the second heat treatment step for growing the oxygen precipitate nuclei 14b formed inside the wafer 11 into oxygen precipitates 14c.
- a method of performing a rapid heat treatment step before oxygen ion implantation, a second heat treatment step following the rapid heat treatment step, and a third heat treatment step following the second heat treatment step, respectively, is described. , Will be described in detail.
- a silicon wafer 11 is prepared.
- the prepared silicon layer 11 has an oxygen concentration of 8 ⁇ 10 17 1.8 ⁇ 10 18 atoms / cm 3 (former ASTM).
- the silicon to be prepared may be epitaxy or anoreja.
- the prepared silicon wafer 11 is subjected to rapid heat treatment.
- the holes 15 are injected into the inside of the hole 11.
- the rapid heat treatment the in-plane uniformity of the oxygen precipitate density distribution in the wafer surface is ensured, and the reliability of the growth of oxygen precipitates is improved even for silicon wafers having a low oxygen concentration. If the rapid heat treatment is not performed, even if a subsequent process is performed, the oxygen precipitate density distribution in the wafer surface may not be uniform.
- the temperature is kept at 1,050 ° C, 1,350 ° C for 1,900 seconds in a mixed gas atmosphere with non-oxidizing gas or ammonia gas, and then the temperature is reduced at a rate of 10 ° CZ seconds or more. It is preferable to be performed by doing.
- the reason why the rapid heat treatment temperature is specified within the range of 1050 ° C and 1350 ° C is that if the lower limit is less than the lower limit, a sufficient amount of vacancies to promote the formation of oxygen precipitation nuclei cannot be injected into the wafer. If the upper limit value is exceeded, slip dislocations are easily generated during the heat treatment, which causes a problem in device fabrication, which is not preferable.
- the preferred heat treatment temperature is 1100-1300 ° C.
- the reason for setting the holding time to 1 second to 900 seconds is that if the holding time is less than the lower limit, the time required to reach the desired heat treatment attainment temperature differs in the plane of the wafer and in the depth direction, which may cause variations in quality. This is because there is a concern that The upper limit is specified because slip reduction and productivity are taken into account.
- the preferred holding time is 10 60 seconds.
- the injected vacancies disappear when reaching the wafer surface, the concentration decreases near the outermost surface, and the resulting concentration difference causes outward diffusion of the vacancies toward the internal force surface . For this reason, if the cooling rate is low, the dwell time in the temperature drop will be prolonged, and the outdiffusion will proceed to that extent, and the vacancies once injected by the high-temperature RTA heat treatment will decrease, and oxygen precipitation nucleation will occur. It is thought that it will not be possible to secure a sufficient amount for the project.
- the temperature is lowered at a temperature lowering rate of 10 ° CZ seconds or more.
- the reason why the cooling rate is set to 10 ° CZ seconds or more is that if it is less than the lower limit, the effect of suppressing the disappearance of vacancies cannot be obtained.
- the reason why the upper limit was not set is that the effect hardly changes if it exceeds 10 ° CZ seconds.
- the cooling rate should be controlled to 10 to 100 ° C / sec in consideration of productivity. desirable. More preferably, the cooling rate is 15 to 50 ° CZ seconds.
- the wafer 11 subjected to the rapid heat treatment is subjected to a second heat treatment.
- oxygen precipitation nuclei 14b are formed inside the wafer 11.
- the second heat treatment in the second heat treatment step is performed by maintaining the rapidly heat-treated wafer at 500 to 1000 ° C for 1 to 96 hours in an atmosphere of hydrogen, argon, nitrogen, oxygen gas or a mixed gas thereof. Is preferred.
- the gas atmosphere of the second heat treatment is more preferably performed under an atmosphere of argon or a small amount of oxygen (based on nitrogen or argon gas).
- the reason why the second heat treatment temperature is specified in the range of 500 to 1000 ° C is that if it is less than the lower limit, the nucleation temperature is too low and a long heat treatment is required, and if it exceeds the upper limit, oxygen precipitation nucleation will occur. Because there is no. Also, the reason why the second heat treatment time is specified within the range of 1 to 96 hours is that if the time is less than the lower limit, the time for forming the oxygen precipitation nuclei 14b is too short, and if the time exceeds the upper limit, the productivity is reduced. This is because This second heat treatment is more preferably performed at a temperature of 500 to 800 ° C. for 4 to 35 hours.
- the second heat treatment is performed at a rate of 0.1 to 20.0 ° C.Z in a partial range or a whole range from 500 ° C. to 1
- the reaction may be performed within a range of 1 to 96 hours, preferably 4 to 35 hours by raising the temperature by 0.1 to 5.0 ° CZ.
- the wafer 11 subjected to the second heat treatment is subjected to a third heat treatment.
- the oxygen precipitate nuclei 14b formed inside the wafer 11 can be grown into oxygen precipitates 14c.
- the wafer subjected to the second heat treatment is heated to 900 to 1250 ° C, which is higher than the second heat treatment temperature, in an atmosphere of hydrogen, argon, nitrogen, oxygen gas or a mixed gas thereof. It is preferable to carry out by holding for 96 hours.
- the gas atmosphere for the third heat treatment is preferably performed in an argon or trace oxygen (nitrogen or argon gas base) gas atmosphere.
- the reason why the third heat treatment temperature is specified in the range of 900 to 1250 ° C is that, if the temperature is less than the lower limit, the growth of oxygen precipitates 14c is not sufficiently performed, and if the upper limit is exceeded, problems such as slipping may occur. is there.
- the reason why the third heat treatment time is specified in the range of 1 to 96 hours is that if the growth is less than the lower limit, the growth of the oxygen precipitate 14c is not sufficient, and if the upper limit is exceeded, the productivity may be reduced. . More preferably, the third heat treatment is performed at 1000 to 1200 ° C. for 8 to 24 hours.
- the third heat treatment is performed by increasing the temperature at a rate of 0.1 to 20 ° CZ, preferably at a rate of 1 to 5 ° CZ, in a part or whole range from 900 ° C to 1250 ° C. It may be carried out for up to 96 hours, preferably 8 to 24 hours!
- oxygen ions are implanted into the inside of the wafer 11 subjected to the third heat treatment.
- This implantation of oxygen ions is also performed conventionally, and is performed by the same means.
- oxygen ions are implanted into the region 11a having a predetermined depth from the surface of the wafer 11 so that the thickness of the SOI layer 13 in the finally obtained SIMOX substrate becomes 10 to 200 nm, preferably 20 to LOOnm. You. If the thickness of the SOI layer 13 is less than lOnm, it is difficult to control the thickness of the SOI layer 13, and if the thickness of the SOI layer 13 exceeds 200 nm, it is difficult due to the acceleration voltage of the oxygen ion implanter.
- a mask or the like is partially formed at a desired position on the surface of the silicon wafer 11 and oxygen ions are implanted into the inside of the silicon wafer 11 so that the mask is not formed.
- Oxygen ions are implanted into the inside of the wafer below, and oxygen ions are not implanted into the inside of the wafer below the area where the mask was formed.
- the buried oxide layer 12 is partially formed only underneath. Even if heavy metal contamination occurs due to the ion implantation process, the heavy metal, which is a contaminant, is converted into 14 layers by the oxygen precipitates 14c formed by performing the second heat treatment step and the third heat treatment step. It can be efficiently captured inside.
- the wafer 11 into which oxygen ions have been implanted is subjected to a first heat treatment at a temperature of 1300 to 1390 ° C. in an inert gas or a mixed gas atmosphere of oxygen and an inert gas.
- the inert gas include an argon gas and a nitrogen gas. Therefore, the gas atmosphere of the first heat treatment is preferably argon alone, a mixed gas of oxygen and argon, or a mixed gas of oxygen and nitrogen.
- the heat treatment time of the first heat treatment is preferably 1 to 20 hours, more preferably 10 to 20 hours.
- an oxidized film l ib, 11c is formed on the front and back surfaces of the wafer 11, and the embedded oxide film 12 is spread over the entire surface of the wafer 11 in a region 1 la where the surface force of the wafer 11 has a predetermined depth. Formed.
- oxygen ions are partially implanted into a region having a predetermined surface depth and a predetermined depth using a mask or the like, the buried oxide layer 12 is partially formed. Further, an SOI layer 13 is formed between the oxidized film lib on the front side and the buried oxidized film 12. In addition, a defect accumulating layer 14a is inevitably formed immediately below the buried oxide layer 12.
- oxygen precipitates near the surface layer are dissolved by the first heat treatment, so that a DZ layer is formed.
- the oxygen precipitates 14c present in the defect accumulating layer 14a immediately below the buried oxide layer 12 and the Balta layer 14 located therebelow are further grown by the temperature rise in the early stage of the first heat treatment step, and the oxygen precipitates 14c are formed.
- the size of the elementary precipitates increases, melting begins when the temperature is maintained at 1300-1390 ° C in the middle stage, and the size decreases to a certain size.However, growth starts again due to the temperature drop at the end of the first heat treatment step. Even if the first heat treatment step is performed, the oxygen precipitate 14c formed in advance remains in the balta 14.
- the heavy metal contamination is caused by the oxygen precipitates 14c formed by performing the second heat treatment step and the third heat treatment step. Heavy metals as dyes can be efficiently captured in the Balta layer 14.
- a fourth heat treatment may be performed in which the wafer subjected to the first heat treatment is kept at 500 to 1200 ° C. for 1 to 96 hours.
- oxygen precipitates 14c formed in the inside of notch layer 14 below buried oxide layer 12 can be regrown.
- the gas atmosphere of the fourth heat treatment is preferably performed in an argon or trace oxygen (nitrogen or argon gas base) gas atmosphere.
- the reason why the fourth heat treatment temperature is specified in the range of 500 to 1200 ° C is that the growth of oxygen precipitates 14 c is less likely to occur sufficiently below the lower limit, and a problem such as slipping occurs if the upper limit is exceeded. That's why.
- the reason why the fourth heat treatment time is set within the range of 1 to 96 hours is that if the oxygen precipitate 14c does not grow sufficiently below the lower limit, the productivity decreases if the growth exceeds the upper limit. .
- the fourth heat treatment is preferably performed at 1000 to 1200 ° C. for 8 to 24 hours.
- the silicon nitride film 1 lb, 11c on the front and rear surfaces of the wafer 11 subjected to the third heat treatment is removed with hydrofluoric acid or the like.
- the buried oxide layer 12 formed on the wafer surface force at a predetermined depth, the SOI layer 13 formed on the wafer surface on the buried oxide layer, and the buried oxide layer 12 It has a formed defect accumulating layer 14a and a Balta layer 14 below the buried oxide layer 12, and has a gettering source composed of oxygen precipitates 14c in the Balta layer 14 below the defect accumulating layer 14a.
- the SIMOX substrate is characterized in that the density of the substance 14c is 1 ⁇ 10 8 to 1 ⁇ 10 12 Zcm 3 and the size of the oxygen precipitate 14c is 50 nm or more.
- the Balta layer 14 below the defect accumulating layer 14a has an oxygen precipitate 14c having a density of 1 ⁇ 10 8 to 1 ⁇ 10 12 / cm 3 and a size of 50 nm or more.
- sudden heavy metal contamination during the device process can be efficiently captured by the oxide precipitate 14c.
- the silicon oxide precipitate 14c is a stronger gettering source than the defect accumulation layer 14a, the heavy metal contaminant is trapped by the conventional defect accumulation layer 14a, and the heavy metal contaminant is gettered by the oxygen precipitate 14c of the warta layer 14. Can be ring.
- the concentration of heavy metals was forcibly contaminated with a heavy metal so that the substrate in 1 X ⁇ 11 1 X 10 12 atoms / cm 2, the defect collection layer 14a
- the concentration of heavy metals captured can be reduced to a level of 5 ⁇ 10 9 pieces / cm 2 or less.
- the rapid heat treatment step, the second heat treatment step, and the third heat treatment step were performed before the oxygen ion implantation step, but FIGS. 4 (a) to 4 ( g), the same SIMO X as the SIMOX substrate shown in Fig. 3 is obtained even if the rapid heat treatment step, the second heat treatment step, and the third heat treatment step are performed between the oxygen ion implantation step and the first heat treatment step. A substrate is obtained.
- the wafer 11 subjected to the rapid heat treatment was subjected to a second heat treatment at 800 ° C. for 4 hours in a nitrogen atmosphere.
- a third heat treatment was performed in which the wafer subjected to the second heat treatment was maintained at 1000 ° C. for 16 hours in a 3% oxygen gas (nitrogen gas base) atmosphere.
- the wafer is heated to a temperature of 550 ° C. or less, and in this state, a predetermined area of the silicon wafer (for example, an area of about 0.4 m from the substrate surface). ) was implanted with oxygen ions under the following conditions.
- the surface of the wafer was washed with SC-1 and SC-2. Subsequently, as shown in Fig. 3 (f), the wafer 11 was placed in a heat treatment furnace and maintained at a constant temperature of 1350 ° C for 4 hours in an Ar gas atmosphere with an oxygen partial pressure of 0.5%. Increase oxygen partial pressure of atmosphere to 70%! Then, a first heat treatment of holding for 4 hours was performed. After the first heat treatment, the oxidized films l ib and 11c on the front and rear surfaces of the wafer were removed with an HF solution, and the SIMOX shown in FIG. A substrate was obtained. This SIMOX substrate was used as Example 1.
- the wafer was continuously heated at a temperature of 500 ° C. from 1500 ° C. to 1150 ° C. in 25 ° C.Z seconds, and then held at 1150 ° C. for 15 seconds, as shown in FIG. After that, rapid heat treatment was performed to decrease the temperature to 500 ° C at a rate of 25 ° CZ seconds.
- a second heat treatment was performed in which the rapidly heat-treated wafer 11 was kept at 800 ° C. for 4 hours in an argon atmosphere.
- a third heat treatment was performed in which the wafer subjected to the second heat treatment was kept at 1000 ° C.
- a 0.5% oxygen gas (argon gas base) atmosphere was placed in a heat treatment furnace and maintained at a constant temperature of 1350 ° C for 4 hours in an Ar gas atmosphere with an oxygen partial pressure of 0.5%.
- a first heat treatment was performed in which the oxygen partial pressure of the internal atmosphere was increased to 70% and maintained for another 4 hours.
- 1 lb and 1 lc of the oxide film on the front and back surfaces of the wafer were removed with an HF solution to obtain a SIMOX substrate shown in FIG. 4 (g). This SIMOX substrate was used as Example 2.
- the oxygen concentration 1. 3 X 10 18 atoms / cm 3 was grown by the CZ method (old ASTM), carbon concentration 5 X 10 16 atoms / cm 3 ( old ASTM) and the ratio A CZ silicon wafer cut into a predetermined thickness from a silicon ingot having a resistance of 20 ⁇ ⁇ cm was prepared.
- the wafer 11 was subjected to a second heat treatment at 800 ° C. for 4 hours in an atmosphere of 3% oxygen gas (based on argon gas).
- a third heat treatment was performed in which the wafer subjected to the second heat treatment was held at 1000 ° C.
- the wafer is heated to a temperature of 550 ° C. or less, and in this state, a predetermined region of the silicon wafer (for example, Oxygen ions were implanted into the region (about 0.4 m from the substrate surface) under the same conditions as in Example 1 above.
- a predetermined region of the silicon wafer for example, Oxygen ions were implanted into the region (about 0.4 m from the substrate surface) under the same conditions as in Example 1 above.
- the surface of the wafer was washed with SC-1 and SC-2. Subsequently, as shown in Fig. 1 (e), the wafer 11 was placed in a heat treatment furnace and maintained at a constant temperature of 1350 ° C for 4 hours in an Ar gas atmosphere with an oxygen partial pressure of 0.5%. Increase oxygen partial pressure of atmosphere to 70%! Then, a first heat treatment of holding for 4 hours was performed. After the first heat treatment, the oxide films 11b and 11c on the front and rear surfaces of the wafer were removed with an HF solution to obtain a SIMOX substrate shown in FIG. 1 (f). This SIMOX substrate was used as Example 3.
- FIG. 1 (a) cut the oxygen concentration 1.
- 35 X 10 18 atoms / cm 3 was grown by the CZ method from a silicon ingot (old ASTM) and resistivity 20 Omega ⁇ cm to a predetermined thickness
- a CZ silicon wafer was prepared.
- the wafer is continuously heated from 500 ° C to 850 ° C for 0.5 ° C in minutes in an argon atmosphere, and then maintained at 850 ° C for 1 hour.
- a second heat treatment was performed.
- FIG. 1 (c) the second heat-treated wafer 11 was heated from 850 ° C to 1100 ° C at a rate of 3.0 ° CZ in an argon atmosphere.
- a third heat treatment was performed at 1100 ° C. for 16 hours.
- the wafer is heated to a temperature of 550 ° C or less, and in this state, the wafer is heated to a predetermined area of the silicon wafer (for example, an area approximately 0. 0 from the substrate surface).
- Oxygen ions were implanted under the same conditions as in Example 1 above.
- the surface of the wafer was washed with SC-1 and SC-2. Subsequently, as shown in Fig. 1 (e), the wafer 11 was placed in a heat treatment furnace and maintained at a constant temperature of 1350 ° C for 4 hours in an Ar gas atmosphere with an oxygen partial pressure of 0.5%. Increase oxygen partial pressure of atmosphere to 70%! Then, a first heat treatment of holding for 4 hours was performed. After the first heat treatment, the oxide films 11b and 11c on the front and rear surfaces of the wafer were removed with an HF solution to obtain a SIMOX substrate shown in FIG. 1 (f). This SIMOX substrate was used as Example 4.
- a fourth heat treatment was performed in which the wafers after the first heat treatment of Examples 1 to 4 were kept at 1000 ° C. for 16 hours in a 0.5% oxygen gas (argon gas base) atmosphere. After this 4th heat treatment The silicon oxide film on the top and bottom surfaces of the wafer was removed with an HF solution to obtain a SIMOX substrate. This SIMOX substrate was used in Examples 5 to 8.
- a CZ silicon wafer cut to a predetermined thickness from a silicon ingot having an oxygen concentration of 1.3 ⁇ 10 18 atoms / cm 3 (former ASTM) and a specific resistance of 20 ⁇ ⁇ cm grown by the CZ method was prepared.
- the wafer is heated to a temperature of 550 ° C. or lower, and in this state, oxygen ions are applied to a predetermined area of the silicon wafer (for example, an area approximately 0. 0 from the substrate surface) under the same conditions as in Example 1 above. Injected.
- the surface of the wafer was washed with SC-1 and SC-2. Subsequently, the wafer was placed in a heat treatment furnace and maintained at a constant temperature of 1350 ° C for 4 hours in an Ar gas atmosphere with an oxygen partial pressure of 0.5%, and then the oxygen partial pressure of the furnace atmosphere was increased to 70% Then, a first heat treatment was performed for 4 hours. After the first heat treatment, the oxide films on the front and rear surfaces of the wafer were removed with an HF solution to obtain a SIMOX substrate. This SIMOX substrate was used as Comparative Example 1.
- the wafer subjected to the first heat treatment of Comparative Example 1 was subjected to a fourth heat treatment in which the wafer was held at 1000 ° C. for 16 hours in a 3% oxygen gas (argon gas base) atmosphere. After the fourth heat treatment, the silicon oxide films on the front and rear surfaces of the wafer were removed with an HF solution to obtain a SIMOX substrate. This SIMO X substrate was used as Comparative Example 2.
- the SOI layer 13, the buried oxide layer 12 and the vacancy immediately below the buried oxide layer of each SIMOX substrate were removed.
- the collapsed layer 14a was dissolved and recovered with an aqueous solution of hydrofluoric-nitric acid, and the recovered solution was subjected to ICP-MS measurement to measure the concentration of nickel contained in the solution.
- the Balta layers 14 of Examples 1 to 8 and Comparative Examples 1 and 2 were separately separated into a Balta layer excluding 1 m from the back surface and a region 1 m from the back surface, and were completely dissolved. Was measured for nickel concentration.
- Example 5 Each of the SIMOX substrates in Example 5 and Comparative Example 2 was cleaved into two parts.
- the cleaved substrate was selectively etched with a Wright etchant.
- the cleaved substrates of Example 5 and Comparative Example 2 were each observed with an optical microscope.
- Example 5 it was observed that oxygen precipitates were grown at a high density inside the substrate at a substrate cleavage surface force of 2 m depth.
- Comparative Example 2 the oxygen precipitate hardly grew. That is, even if a buried oxide film forming heat treatment step requiring 1300 ° C. or more is performed, if the oxygen precipitates are sufficiently grown before the heat treatment, the oxygen precipitates do not disappear. It has been proved that these oxygen precipitates have a gettering effect in the SIMOX manufacturing process.
- the method for producing a SIMOX substrate of the present invention can efficiently capture heavy metal contamination caused by ion implantation or high-temperature heat treatment in the Balta layer.
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US11/597,798 US20080044669A1 (en) | 2004-05-25 | 2005-05-19 | Method for Manufacturing Simox Substrate and Simox Substrate Obtained by the Method |
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JP4706199B2 (ja) * | 2004-07-20 | 2011-06-22 | 株式会社Sumco | Simox基板の製造方法 |
JP5158833B2 (ja) * | 2006-03-31 | 2013-03-06 | 古河電気工業株式会社 | 窒化物系化合物半導体装置および窒化物系化合物半導体装置の製造方法。 |
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JP4952069B2 (ja) * | 2006-06-02 | 2012-06-13 | 大日本印刷株式会社 | 加速度センサの製造方法 |
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- 2005-05-19 WO PCT/JP2005/009166 patent/WO2005117122A1/ja active Application Filing
- 2005-05-19 KR KR1020097023193A patent/KR20090130872A/ko not_active Application Discontinuation
- 2005-05-19 KR KR1020087030622A patent/KR20090006878A/ko not_active Application Discontinuation
- 2005-05-19 US US11/597,798 patent/US20080044669A1/en not_active Abandoned
- 2005-05-19 EP EP05741161.3A patent/EP1768185A4/en not_active Withdrawn
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US11932535B2 (en) | 2018-03-28 | 2024-03-19 | Sumitomo Precision Products Co., Ltd. | MEMS device manufacturing method, MEMS device, and shutter apparatus using the same |
Also Published As
Publication number | Publication date |
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US20080044669A1 (en) | 2008-02-21 |
EP1768185A1 (en) | 2007-03-28 |
EP1768185A4 (en) | 2013-06-19 |
KR20090130872A (ko) | 2009-12-24 |
CN101847595B (zh) | 2013-02-13 |
TW200607021A (en) | 2006-02-16 |
KR20090006878A (ko) | 2009-01-15 |
CN101847595A (zh) | 2010-09-29 |
JP2005340348A (ja) | 2005-12-08 |
CN101010805A (zh) | 2007-08-01 |
TWI267144B (en) | 2006-11-21 |
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