WO2005087675A1 - 抗菌性ガラスおよび抗菌性ガラスの製造方法 - Google Patents
抗菌性ガラスおよび抗菌性ガラスの製造方法 Download PDFInfo
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- WO2005087675A1 WO2005087675A1 PCT/JP2005/004292 JP2005004292W WO2005087675A1 WO 2005087675 A1 WO2005087675 A1 WO 2005087675A1 JP 2005004292 W JP2005004292 W JP 2005004292W WO 2005087675 A1 WO2005087675 A1 WO 2005087675A1
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- antibacterial
- glass
- antibacterial glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
Definitions
- Antibacterial glass and method for producing antibacterial glass are provided.
- the present invention relates to an antibacterial glass for a washing machine that can elute silver ions by coming into direct contact with water during or after washing of an antibacterial object (an antibacterial glass for a washing machine having an antifungal property).
- the present invention relates to an antibacterial glass suitable as such, and a method for producing such an antibacterial glass.
- an antibacterial glass suitable as an antibacterial glass for a washing machine or the like for performing antibacterial treatment with silver ions during or after washing of an antibacterial object, and when it comes into direct contact with water The present invention relates to an antibacterial glass capable of releasing a predetermined amount of silver ions quickly and for a long period of time, and a method for producing such an antibacterial glass.
- antibacterial glass having a predetermined particle size has been used for building materials, home appliances (including TVs, personal computers, mobile phones, video cameras, etc.), miscellaneous goods, packaging materials, and the like, in order to impart an antibacterial effect.
- An antibacterial resin composition mixed in a predetermined amount into fat is used.
- an antibacterial resin composition there is disclosed a synthetic resin molded article containing borosilicate antibacterial glass that elutes silver ions in the resin (for example, see Patent Document 1).
- the strong synthetic resin molded body is made of SiO
- CaO one or two or more kinds of ⁇ network-modified oxides and 100 parts by weight of a glass solid that also acts as a monovalent Ag in a weight of 100 parts by weight of AgO.
- An antibacterial resin composition containing an antibacterial glass having an average particle size of 20 m or less in a synthetic resin is disclosed.
- the particle size having antibacterial properties is 10-1000 ⁇ m, and the thickness is 0.
- a resin composition containing glass flakes of 120 m in length is disclosed (for example, Patent Document More specifically, as the composition of the glassy glass flakes, when BO is contained, S
- Disclosed antibacterial water-based products composed of 0.5 to 5% by weight of inorganic antibacterial agent containing silver ion and 2 to 20% by weight of inorganic filler with average particle size of 2 to 20m Have been.
- an antibacterial resin composition which exemplifies electric appliances such as a dishwasher, a dish dryer, a refrigerator, a washing machine, and a pot (for example, see Patent Documents). 4 and 5).
- Suya also mean particle size of 20 m or less of ZnO: 5 4- 60 mole 0/0, BO: 25-32 mole 0/0
- alkali metal oxides an antimicrobial glass consisting 5-8 mole 0/0,
- Antibacterial resin compositions containing a predetermined amount of each.
- Patent Document 1 Japanese Patent Application Laid-Open No. 1-313531 (Claims)
- Patent Document 2 Japanese Patent Application Laid-Open No. 7-25635 (Claims)
- Patent Document 4 Japanese Patent Application Laid-Open No. 2000-3238 (Claims)
- Patent Document 5 Japanese Patent Application Laid-Open No. 2000-3239 (Claims)
- Patent Document 6 Japanese Patent Publication No. 7-63701 (Claims)
- Patent Documents 15 are all formed by adding antibacterial glass to the resin, the antibacterial resin compositions are disclosed. Glass was configured to be able to release silver ions for the first time by indirect contact with water that has penetrated into the resin.
- the average particle size of the antibacterial glass is preferably about 20 m or less in order to uniformly mix the resin.
- the antibacterial glass has a predetermined size. Although the glass flakes were used, there was a manufacturing problem that these values had to be restricted to a predetermined range by using a classifying device or the like as a manufacturing device.
- the glass water treatment agent disclosed in Patent Document 6 has a problem that although the longest diameter is relatively large, the amount of silver ion eluted is basically small. Therefore, similar to the antibacterial resin composition disclosed in Patent Documents 1 to 5, the antibacterial object is brought into direct contact with water during or after washing to quickly release silver ions, and It was practically difficult to attach a predetermined amount of silver ions to an antibacterial substance.
- an antibacterial glass for releasing silver ions upon direct contact with water and exhibiting an antibacterial effect, and has a maximum diameter (tl) within a range of 1 to 50 mm.
- an antibacterial glass having a silver ion elution amount within a range of 0.5 to 100 mgZ (g'24Hrs), which can solve the above-mentioned problem.
- antibacterial glass of the present invention for example, during or after washing of an antibacterial substance, a predetermined amount of silver ions can be released quickly and for a long period of time by direct contact with water. it can. Therefore, a predetermined antibacterial treatment can be repeatedly applied to the antibacterial object.
- antibacterial glass having such a size not only facilitates handling, but also causes adjacent glass to come into contact with each other, agglomeration or fusion, despite extremely high solubility. Can be effectively prevented.
- the antibacterial glass for a washing machine is subjected to an antibacterial treatment with silver ions during or after washing of an antibacterial object.
- the raw materials of the predetermined boric acid-based antibacterial glass are blended in the respective predetermined amounts, it is possible to release a predetermined amount of silver ions over a long period of time by directly contacting with water. As a result, a predetermined antibacterial effect can be continuously exerted. Further, according to such antibacterial glass for a washing machine, a predetermined antibacterial treatment can be stably applied to an antibacterial object washed with a detergent having low reactivity with a detergent. In the case of strong antibacterial glass, use a relatively large amount of BO as a raw material.
- Weight percent 2 to 5 weight percent Ag 2 O, and 15 alkali metal oxides.
- the value be within the range of 35% by weight.
- a predetermined amount of the phosphoric acid-based antibacterial glass raw material is blended in a predetermined amount, by directly contacting with water, for example, in a washing machine application, a predetermined amount of silver ion And a predetermined antibacterial effect can be continuously imparted to the laundry.
- such a phosphate antibacterial glass is excellent in transparency and can release a predetermined amount of silver ions even if it is granular, regardless of whether it is flat. Furthermore, with such a phosphate antibacterial glass, it is possible to obtain an advantage if the production conditions are reduced so that the corrosiveness to a melting furnace or the like during production is reduced.
- the antibacterial glass of the present invention can be cut into an arbitrary size and used in consideration of the environmental conditions and the amount of water to be used or the long-term use time, etc., by adopting a so-called chocolate cut shape.
- it since it has a predetermined thin portion, it is used as a cut point and has an appropriate size according to the size and shape of the place of use. And antibacterial glass of different shapes.
- a coating member is provided around the antibacterial glass, and that the cartridge is inscribed!
- the cartridge is provided with the predetermined covering member and is cartridge-shaped, not only is it easy to handle and exchange, etc., but even when a relatively strong water flow is used, the water is discharged to the outside together with the water flow. Outflow can be effectively prevented.
- Another embodiment of the present invention is a method for producing an antibacterial glass for releasing silver ions by directly contacting with water to exhibit an antibacterial effect, comprising the following step (A): (B) A method for producing an antibacterial glass, comprising:
- the process since the process includes a predetermined manufacturing process, it can release silver ions by coming into direct contact with water and quickly exert an antibacterial effect. As a result, the object to be antibacterial can be washed or washed. Later, an antibacterial glass that releases a predetermined amount of silver ions and can stably perform a predetermined antibacterial treatment on an antibacterial substance can be efficiently obtained.
- Still another embodiment of the present invention relates to a method for producing an antibacterial glass for releasing silver ions upon direct contact with water and exhibiting an antibacterial effect, comprising the following steps ( ⁇ (1) A method for producing an antibacterial glass, characterized by containing one ( ⁇ ').
- the antibacterial effect can be promptly exerted by releasing silver ions by directly contacting with water.
- the antibacterial glass that releases a predetermined amount of silver ions during or after washing of the antibacterial substance and can stably perform a predetermined antibacterial treatment on the antibacterial substance.
- a flat antibacterial glass is formed using a rotating member having a concave portion on the surface. Is preferred.
- FIG. 1] (a)-(f) are views provided for explaining the shape of the antibacterial glass of the first embodiment.
- FIG. 2 is a diagram provided for explaining a relationship between a maximum diameter (tl) of an antibacterial glass and a residual ratio.
- FIG. 3 is a diagram provided to explain the relationship with the amount of silver ion eluted with the number of washings.
- FIG. 4 is a view showing a washing machine to which the antibacterial glass of the first embodiment is applied.
- FIG. 5 is a diagram provided for explaining a shape of an antibacterial glass.
- FIG. 6 is a view provided to explain a coating member of antibacterial glass (part 1).
- FIG. 7] (a)-(c) is a diagram provided to explain a coating member of antibacterial glass (part 2).
- FIG. 8 is a diagram provided for explaining a shape of an antibacterial glass and a covering member.
- FIG. 9 is a diagram provided for explaining a method of using the antibacterial glass.
- FIG. 10 is a diagram provided for explaining an antibacterial method for an antibacterial substance.
- FIG. 11 is a diagram provided for explaining a method for manufacturing the antibacterial glass of the second embodiment (part 1).
- FIG. 13 is a view provided for explaining a method of manufacturing the antibacterial glass of the third embodiment. (Part 1)
- FIG. 14 is a view provided for explaining a method of manufacturing the antibacterial glass of the third embodiment. (Part 2)
- the first embodiment is an antibacterial glass for releasing silver ions in direct contact with water and exhibiting an antibacterial effect, and has a maximum diameter (tl) within a range of 1 to 50 mm. It is an antibacterial glass with a silver ion elution amount in the range of 0.5-100 mg / (g'24Hrs).
- the shape of the antibacterial glass is not particularly limited, but as shown in FIG. 1 (a)-(f), a flat plate having a rectangular shape, a polygonal shape, a circular shape, an elliptical shape, an irregular shape, a perforated shape, etc. It is preferred that it is in the form.
- the antibacterial glass is formed in a flat plate shape such as a rectangular shape or a perforated shape, so that even if it is placed at a predetermined location and brought into direct contact with water, it is washed away by water pressure, This is because it is possible to effectively prevent the power from flowing out of the predetermined location.
- the antibacterial glass is rectangular or the like, it is difficult to coagulate during manufacturing or use, so the size and shape of the antibacterial glass during manufacturing and the control of environmental conditions during use are also considered. This is because it becomes easier.
- the antibacterial glass can be formed into any shape such as a polyhedral, granular, spherical, elliptical, columnar, or pulverized body.
- the maximum diameter (tl) of the antibacterial glass is set to a value within a range of 1 to 50 mm.
- the maximum diameter (tl) of the antibacterial glass is, for example, the maximum length when an arbitrary line is drawn in the shape of the antibacterial glass as shown in FIGS. Means That is, the maximum diameter (tl) of the antibacterial glass is the maximum diameter in the plane direction when the antibacterial glass is, for example, a flat plate, and the maximum diameter of the particles when the antibacterial glass is granular. .
- the reason for limiting the maximum diameter (tl) of the antibacterial glass is that when the maximum diameter to be pressed is less than lmm, it is placed at a predetermined location and pressed directly by water when pressed against water. It may be easily washed away and force to flow out of a specified location, or it may be difficult to release silver ions of a predetermined concentration for a long period of time, or it may be easy to agglomerate during storage. is there.
- the maximum diameter when the shape of the antibacterial glass is flat or the like, it is more preferable to set the maximum diameter to a value in the range of 8 to 30 mm, more preferably to a value in the range of 15 to 20 mm.
- the shape of the antibacterial glass is granular, etc., it is more preferable to set the maximum diameter to a value within the range of 3 to 25 mm in consideration of the easiness of production. More preferably, it is set to a value.
- the thickness of the antibacterial glass is preferably in the range of 0.1 to 10 mm.
- the thickness of the strong antibacterial glass is less than 0.1 mm, it becomes difficult to release silver ions of a predetermined concentration, handling becomes difficult, and stable production This may be difficult.
- the thickness of the antibacterial glass exceeds 10 mm, on the other hand, handling becomes difficult, and it becomes difficult to manufacture it stably.
- the antibacterial glass if the antibacterial glass is flat, its thickness should be in the range of 0.5-8 mm. It is more preferable to set the value within the range. It is more preferable to set the value within the range of 11 to 5 mm.
- the maximum diameter / thickness of the antibacterial glass described above can be easily measured using, for example, an optical microscope photograph or a caliper.
- the horizontal axis of FIG. 2 shows the maximum diameter (mm) of the antibacterial glass in the plane direction in logarithm, and the vertical axis shows the antibacterial glass in Examples described later when the antibacterial glass of each particle size is used.
- the residual ratio (%) measured according to the method for measuring the residual ratio of lath is shown.
- the residual ratio shows a relatively high value, that is, a value of 50% or more. However, it is understood that it can withstand long-term use.
- the antibacterial glass according to the present invention (maximum diameter in the plane direction of 15 mm) and the antibacterial glass having an average particle diameter of 20 ⁇ m were used.
- the change in the number of washings and the amount of silver ion eluted in this case will be described in detail. That is, the horizontal axis of FIG. 3 indicates the number of washings using each antibacterial glass using the washing machine 50 as shown in FIG. 4, and the vertical axis of FIG.
- the elution amount of ion (mg / (g'24Hrs)) is shown.
- the data on the antibacterial glass of the present invention is shown by a solid line A
- the data on the antibacterial glass having an average particle diameter of 20 ⁇ m is shown by a dotted line B.
- the antibacterial glass of the present invention (antibacterial glass for a washing machine) has a predetermined maximum diameter in the plane direction and is not washed away by water pressure or the like, so that the residual amount is small. It does not decrease significantly. Therefore, it can be understood that the desired elution amount can be maintained even when used repeatedly. Therefore, it is understood that the antibacterial glass of the present invention is immune to long-term use.
- antibacterial glass having an average particle size of 20 m reduces the residual amount of antibacterial glass each time it is used.
- the value of the amount of eluted significantly decreased compared to the amount of silver ion eluted immediately after the start of use. Therefore, it is understood that frequent replenishment of the antibacterial glass is necessary in order to secure a desired elution amount of silver ions.
- the antibacterial glass is formed as a whole through a thin portion 12 having the same component power as the antibacterial glass. It is preferable that a plurality of glass pieces 10a are connected to each other.
- the antibacterial glass of a large area is cut into an arbitrary size by so-called chocolate cutting in consideration of the environmental conditions, the amount of water used, or the long-term use time, etc. Because it can be used. That is, a large-area antibacterial glass can be cut into a predetermined size by using a predetermined thin portion, and the amount of silver ion eluted (elution rate) can be easily adjusted.
- the size and shape of the antibacterial glass can be appropriately determined in accordance with the size and shape of the place of use by using the cut portion as a cut portion.
- boric acid antibacterial glass having the following composition. That is, B O
- the amount of SiO added is 30-60% by weight, the amount of AgO added is 2-5% by weight,
- B O basically functions as a network-forming oxide.
- the invention relates to the function of improving the transparency of antibacterial glass and the uniform release of silver ions. Give.
- SiO functions as a network-modified antioxidant in antibacterial glass.
- Ag O is an essential component in the antibacterial glass, and the glass component dissolves.
- an alkaline earth metal oxide for example, MgO or CaO
- it can function as a network-modified acid oxide, while, like the alkali metal oxide, the antibacterial glass It can also exhibit the function of improving the transparency and the function of adjusting the melting temperature.
- a phosphate antibacterial glass having the following composition. That is, as raw materials, P O, Ag O, and alkali metal oxide
- a phosphate-based antibacterial glass having such a glass composition ability can quickly release a predetermined amount of silver ions by directly contacting with water.
- the antibacterial glass having such a glass composition power it has excellent transparency and releases a predetermined amount of silver ions within a predetermined time even if the particles have a predetermined particle size irrespective of a flat shape. It is possible because it is easy to use.
- such a phosphoric acid-based antibacterial glass can be manufactured and economically reduced in terms of manufacturing conditions, such as reducing the corrosiveness to a melting furnace during manufacturing, or reducing manufacturing costs. You can also get benefits.
- Ag O is an essential component in the antibacterial glass, and the glass component dissolves.
- Alkali metal oxides such as Na O and K O, are basically network-modified oxides.
- an alkaline earth metal oxide for example, MgO or CaO
- it can function as a network-modified acid oxide, while, like the alkali metal oxide, the antibacterial glass It can also exhibit the function of improving the transparency and the function of adjusting the melting temperature.
- the elution amount of silver ion in the antibacterial glass is set to a value within the range of 0.5 to 1 OOmgZ (g ⁇ 24Hrs).
- the reason is that when the elution amount of strong silver ions is less than 0.5 mg / (g'24Hrs), the silver ions of a predetermined concentration can be released quickly when they come into direct contact with water. This can be difficult.
- the elution amount of silver ions in the antibacterial glass is more preferable to set to a value within the range of 90 mgZ (g'24Hrs), more preferably to a value within the range of 10-70 mgZ (g'24Hrs). More preferred.
- the elution amount of silver ions in the antibacterial glass can be measured according to the measurement method described in Example 1 described later.
- Complex-forming compounds capable of forming a complex with silver ions, such as ammonium sulfate, ammonium nitrate, sodium chloride, sodium thiosulfate, sodium chloride, ammonium sulfate, and ammonium sulfate. It is preferable to add one or a combination of two or more of tylenediaminetetraacetic acid (EDTA), ammonium acetate, ammonium perchlorate, and ammonium phosphate. Addition of such a complex-forming compound can significantly prevent discoloration and coloring of the antibacterial glass.
- EDTA tylenediaminetetraacetic acid
- ammonium nitrate sodium salt ammonium
- at least one compound selected from the group consisting of sodium thiosulfate is more preferable to use.
- the amount of the complex-forming compound to be added is preferably set to a value within the range of 0.01 to 30% by weight based on the total amount.
- the amount of the powerful complex-forming compound is less than 0.01% by weight, it may be difficult to effectively prevent discoloration.
- the amount of the complex-forming compound exceeds 30% by weight, the antibacterial properties of the antibacterial glass may be reduced or it may be difficult to mix them uniformly.
- the amount of the complex-forming compound to be added is within the range of 0.1 to 20% by weight based on the total amount.
- the value is more preferably set to a value in the range of 0.5 to 10% by weight.
- the covering member has a form in which an antibacterial glass 10 is covered with an inorganic substance and / or an organic substance, or one of the particles 14.
- the particles that coat the antibacterial glass include titanium oxide, silicon oxide, and colloidal. Silica, zinc oxide, tin oxide, lead oxide, white carbon, acrylic particles, styrene particles, polycarbonate particles, and the like, alone or in combination of two or more are preferred.
- the method of coating the antibacterial glass with the particles is not particularly limited.
- the mixture is heated at a temperature of 600 to 1200 ° C to form the glass. It is preferable to fix by a force for fusing or a binder.
- a cartridge around the antibacterial glass by providing a wrapping member as a covering member or a housing.
- the antibacterial glass is enclosed in a cylindrical housing 18 'whose both end surfaces are covered with a mesh member having a smaller particle size. It is preferable to encapsulate 10 and connect them to form a cartridge as shown in FIG. 8 (b).
- the granular antibacterial glass can be composed of phosphoric acid-based glass as a raw material, thereby compensating for the slow dissolution rate by enlarging the glass surface area and obtaining a desired Ag elution amount. It becomes.
- antibacterial glass is dispersed for antioxidant or coloring purposes.
- Surfactants stearic acid, myristic acid, sodium stearate, silane coupling agents, etc., hindered phenolic conjugates as anti-irridation agents, pigments as coloring agents, such as hindered amine compounds, etc. It is preferable to add a dye or the like.
- each of them it is more preferable to set each of them to a value in the range of 0.01 to 30% by weight based on the total amount.
- the method of direct contact between the antibacterial glass and water is not particularly limited.
- the antibacterial glass can be immersed in water, or the antibacterial glass can be put into a stream of water. It is preferable to make silver-ion-containing water by directly contacting the glass with water.
- a bypass 26 is provided and the antibacterial glass 10 for the washing machine is placed there, and when necessary, It is preferable to obtain a silver ion-containing water by opening and closing a valve 28 communicating with the bypass 26 to allow water to flow in and directly contact the antibacterial glass 10 for a washing machine.
- the antibacterial substance 32 is treated by showering or directly immersing the silver ion-containing water 30 to perform an antibacterial treatment.
- antibacterial substance examples include woven fabric, fibrous material, nonwoven fabric, mat-like material, clothing, towels, footwear, and the like.
- a melting step To form a molten glass (hereinafter, sometimes referred to as a melting step).
- a molding step (hereinafter, referred to as the maximum diameter (tl) of 1 to 50 mm and the elution amount of silver ion of 0.5 to 100 mgZ (g'24Hrs)) It may be referred to as a molding step.)
- the amount of B O added was 30 60% by weight, and the amount of SiO
- the mixture was stirred under a condition of a rotation speed of 250 rpm for 30 minutes until it was uniformly mixed so as to have a value within the range of% by weight.
- the glass raw material was heated at 1280 ° C. for three and a half hours to prepare a glass melt.
- the heating conditions in the melting furnace can be appropriately changed according to the types and mixing ratios of the raw materials.
- the forming step is a step of converting molten glass obtained by melting glass raw materials into antibacterial glass having a predetermined shape.
- melting process Melting process for producing molten glass
- the amount of PO added was 30 60% by weight, the amount of Ag O was 25% by weight, and
- the mixture is uniformly mixed at a rotation speed of 250 rpm for 30 minutes so that the addition amount of the alkali metal sardine is within a range of 5 to 40% by weight. And stirred until the Then, using a melting furnace, as an example, calorie the glass raw material at 1280 ° C for three and a half hours. Heating produced a glass melt.
- the heating conditions in the melting furnace can be appropriately changed according to the types and mixing ratios of the raw materials.
- the forming step 1 is a step of converting a molten glass obtained by melting a glass material into an antibacterial glass having a predetermined shape, and in particular, maintaining the molten glass in a semi-solid state before it is completely cured. This is a step of forming glass-like glass.
- the molten glass 22 melted by the above-described method is flowed into a predetermined molding container 60 to form a semi-solid glass plate 22 ′.
- the material of the molding container 60 is not particularly limited as long as it has a melting point higher than that of the antibacterial glass 10.
- a heat-resistant material such as carbon is a preferable constituent material in that it can easily cope with the reduction in the weight and precision of the molding container 60.
- a cooling device 61 is attached to the back surface of the molding container 60 to adjust the temperature of the molding container 60 to an optimum value as shown in FIG. A semi-solid state can be created.
- the forming step 2 is a step for forming the semi-solid glass plate 22 ′ formed in the forming step 1 into a glass plate having a predetermined thickness.
- the semi-solid glass plate 22 is inserted into the gap between the rotating members 2CT arranged at the interval dl. At this time, by setting the distance dl larger than the thickness d2 of the semi-solid glass plate 22, the antibacterial glass 10 with the distance dl can be formed as shown in FIG. Can be.
- the antibacterial glass 10 is crushed by a predetermined method to obtain granular, spherical, This is a step of forming into a shape such as a crushed body.
- Example 1 After crushing to a certain size using a crushing jig such as a hammer, crushing is performed using a ball milling method or the like. At this time, the desired shape as described above can be obtained by appropriately changing the conditions such as the milling ball diameter and the processing time.
- a crushing jig such as a hammer
- the composition ratio of B O is 52% by weight and the composition ratio of SiO is 3%.
- Each glass raw material was stirred using a universal mixer at a rotation speed of 250 rpm for 30 minutes until it was uniformly mixed. Next, using a glass melting furnace, the glass raw materials were heated at 1280 ° C. for three and a half hours to produce molten glass.
- the molten glass which has also been taken out of the glass melting furnace, is inserted into the insertion port 4 of the manufacturing apparatus 40 shown in FIG.
- the residual ratio is 90-100% by weight.
- the residual ratio is less than 70-90% by weight.
- the residual ratio is less than 30% by weight.
- the antibacterial property of cotton underwear was evaluated using the obtained antibacterial glass for a washing machine. That is, the cotton underwear was washed with running water containing detergent using the washing machine shown in FIG.
- valve 28 communicating with the bypass 26 on which the washing machine antibacterial glass 10 is placed is opened and closed to allow water to flow, and the washing machine antibacterial glass 10 and the water are separated.
- silver ion-containing water was prepared.
- antibacterial treatment was applied to cotton underwear 32 as a substance to be bacterium by showering silver ion-containing water 30.
- the cotton underwear 32 thus obtained was left under environmental conditions of 35 ° C., 95% Rh, and 48 hours, and the antibacterial properties were evaluated under the following conditions.
- Example 2 The same procedure as in Example 1 was carried out except that 2 3 2 was changed, and an antibacterial glass for a washing machine was prepared and evaluated. Valued.
- Comparative Example 1 was the same as Example 1 except that the antibacterial glass for a washing machine obtained in Example 1 was adjusted to granular particles having an average particle size of 20 m using a crusher and a classifier. It was evaluated similarly.
- Example 2 the antibacterial glass for a washing machine obtained in Example 1 was adjusted to flaky particles having a long diameter of 200 m and a thickness of 30 m using a crushing device and a classification device. was evaluated in the same manner as in Example 1.
- Comparative Example 3 the antibacterial glass for a washing machine having an average particle diameter of 20 m obtained in Comparative Example 1 was added to polypropylene resin so as to have a concentration of 10% by weight. A resin plate containing antibacterial glass was prepared, and silver ion elution properties and antibacterial properties were evaluated.
- the composition ratio of PO is 70% by weight, and the composition ratio of NaO is 1%. 8% by weight, the composition ratio of CaO is 9% by weight, and the composition ratio of AgO is 3% by weight.
- glass raw materials were stirred using a universal mixer at a rotation speed of 250 rpm for 30 minutes until they were uniformly mixed.
- the glass raw material was heated at 1280 ° C. for three and a half hours to produce a molten glass.
- Example 6 similarly to Example 1, (1) evaluation of silver ion dissolution, (2) evaluation of outflow property, and (3) evaluation of antibacterial property were performed.
- Weight loss rate is less than 10%.
- Weight loss rate is less than 10-20%.
- Weight loss rate is 50% or more.
- a functional glass was prepared and evaluated.
- PA 70 64.5 66.5 68 72 60 71
- the maximum diameter (tl) is extremely large in a flat or granular shape.
- a predetermined amount of silver ions can be released quickly and for a long period of time.
- an antibacterial glass having an extremely large maximum diameter (tl) in a flat or granular shape can be efficiently obtained.
- the antibacterial glass of the present invention silver obtained by directly contacting water with a flat or granular antibacterial glass having an extremely large maximum diameter (tl).
- tl extremely large maximum diameter
- the antibacterial glass of the present invention when the antibacterial glass for a washing machine is brought into direct contact with water, which is forced by force, a predetermined amount of silver ions is rapidly and for a long period of time.
- Suitable to be used in applications where it is required to discharge the water for example, dishwashers, vegetable washer, water purifier, humidifier, humidity supply, disinfectant supply, deodorant supply, etc. Can be.
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US10131574B2 (en) | 2013-06-17 | 2018-11-20 | Corning Incorporated | Antimicrobial glass articles and methods of making and using same |
US10676394B2 (en) | 2013-06-17 | 2020-06-09 | Corning Incorporated | Antimicrobial glass articles and methods of making and using same |
EP2987775A4 (en) * | 2013-07-02 | 2016-11-16 | Koa Glass Co Ltd | ANTIBACTERIAL GLASS |
US9919963B2 (en) | 2014-02-13 | 2018-03-20 | Corning Incorporated | Glass with enhanced strength and antimicrobial properties, and method of making same |
US10710928B2 (en) | 2014-02-13 | 2020-07-14 | Corning Incorporated | Glass with enhanced strength and antimicrobial properties, and method of making same |
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Also Published As
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KR100657123B1 (ko) | 2006-12-13 |
JP5378647B2 (ja) | 2013-12-25 |
JPWO2005087675A1 (ja) | 2008-01-24 |
KR20060012326A (ko) | 2006-02-07 |
JP2013155114A (ja) | 2013-08-15 |
CN101298364B (zh) | 2011-02-16 |
CN101298364A (zh) | 2008-11-05 |
JP5845209B2 (ja) | 2016-01-20 |
CN100413799C (zh) | 2008-08-27 |
CN1771207A (zh) | 2006-05-10 |
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