WO2004092292A1 - 被着体の剥離方法 - Google Patents
被着体の剥離方法 Download PDFInfo
- Publication number
- WO2004092292A1 WO2004092292A1 PCT/JP2004/005291 JP2004005291W WO2004092292A1 WO 2004092292 A1 WO2004092292 A1 WO 2004092292A1 JP 2004005291 W JP2004005291 W JP 2004005291W WO 2004092292 A1 WO2004092292 A1 WO 2004092292A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressure
- pressure vessel
- adhesive
- adherend
- laminated glass
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/1099—After-treatment of the layered product, e.g. cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B43/00—Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
- B32B43/006—Delaminating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L21/6836—Wafer tapes, e.g. grinding or dicing support tapes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/50—Additional features of adhesives in the form of films or foils characterized by process specific features
- C09J2301/502—Additional features of adhesives in the form of films or foils characterized by process specific features process for debonding adherents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2221/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
- H01L2221/67—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68318—Auxiliary support including means facilitating the separation of a device or wafer from the auxiliary support
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2221/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
- H01L2221/67—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68327—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used during dicing or grinding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/81—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a bump connector
- H01L2224/81052—Detaching bump connectors, e.g. after testing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/81—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a bump connector
- H01L2224/818—Bonding techniques
- H01L2224/81801—Soldering or alloying
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01019—Potassium [K]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/095—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00 with a principal constituent of the material being a combination of two or more materials provided in the groups H01L2924/013 - H01L2924/0715
- H01L2924/097—Glass-ceramics, e.g. devitrified glass
- H01L2924/09701—Low temperature co-fired ceramic [LTCC]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/30—Technical effects
- H01L2924/301—Electrical effects
- H01L2924/3025—Electromagnetic shielding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
- Y10T156/1126—Using direct fluid current against work during delaminating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
- Y10T156/1126—Using direct fluid current against work during delaminating
- Y10T156/1137—Using air blast directly against work during delaminating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/11—Methods of delaminating, per se; i.e., separating at bonding face
- Y10T156/1153—Temperature change for delamination [e.g., heating during delaminating, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/19—Delaminating means
- Y10T156/1928—Differential fluid pressure delaminating means
Definitions
- the present invention provides a method for separating an adherend, which can easily and surely peel off an adherend adhered using an adhesive, a method for collecting an electronic component from an electronic component laminate, and It relates to a method of peeling glass.
- Adhesives are used to bond plastic, glass, metal, wood, pottery, rubber, paper, cloth, leather, etc., and adherends bonded with adhesives are used in all fields. .
- adherends are used in all fields. .
- the adhesive strength is strong or when it is desired to peel a fragile adherend without damaging it, an extremely complicated operation was required.
- an interlayer for laminated glass made of a thermoplastic resin sheet such as an adhesive or plasticized polyvinyl butyral resin is sandwiched between glass plates, and the laminated glass obtained by adhering to each other is used when an object collides with the glass.
- a thermoplastic resin sheet such as an adhesive or plasticized polyvinyl butyral resin
- the laminated glass obtained by adhering to each other is used when an object collides with the glass.
- It is widely used as glass for vehicles, such as automobiles and aircraft, and window glass for buildings, etc. to prevent the scattering of glass, the obstacles to the human body, equipment, etc. due to the glass, or for crime prevention.
- it is required to disassemble the used laminated glass and reuse the glass and interlayer film for laminated glass from the viewpoint of recycling.
- adherends used in automobiles and aircraft have very strict quality standards, and those with air bubbles involved when bonding glass are considered to be defective.
- Japanese Patent Application Laid-Open No. 2000-110492 discloses a method of reusing glass pieces that have come off from the adhesive by grinding the laminated glass into small pieces. ing.
- a large amount of glass fragments adhere to the adhesive or the interlayer film for laminated glass, and there is no solution to regenerating them.
- the adhesive to which glass fragments adhered and interlayer films for laminated glass could not be incinerated in a normal furnace, but had to be incinerated in a special furnace.
- JP-A-6-2477751 discloses a method in which a laminated glass is heated to a temperature at which an interlayer film for laminated glass is softened to separate and collect an inner plate and an outer plate separately. I have. However, even with this method, in practice, large-sized automobile windshields and the like cannot be easily separated, and the adhesive may remain on the surface of the recovered glass. was there.
- Patent No. 3137504 discloses that a laminated glass crushed into small pieces is placed in a water tank and a shear force is applied to the interlayer film by stirring at a specific speed difference while swelling the interlayer film for laminated glass. A method of peeling the interlayer film for laminated glass from the laminated glass by performing the method is described. However, although this method allows the glass part to be reused, the glass fragments are not completely removed from the interlayer part, so the quality cannot be reused as it is as an interlayer film for laminated glass. There was a problem and it had to be disposed of as industrial waste.
- Japanese Unexamined Patent Publication No. Hei 6-219973 discloses that the adhesive strength between an interlayer film for laminated glass and glass is reduced by cooling the laminated glass to 110 ° C. or lower.
- a method is disclosed in which a glass is shattered by applying an impact to the glass and, at the same time, an interlayer for laminated glass is separated and recovered.
- the separation of the glass and the interlayer for laminated glass is incomplete, and there is a quality problem if it is reused as it is as an interlayer for glass or laminated glass, and it must be disposed of as industrial waste. I didn't get it.
- Japanese Patent Application Laid-Open No. 6-080945 discloses a method of removing an adhesive from books by using an adhesive that is high in strength and is not cut by a pulp and is easily removed by a filter. ing. However, this method has a problem that it is not suitable for reproducing a wide range of books because the type of adhesive is limited.
- Japanese Unexamined Patent Publication No. 2002-334430 describes that supercritical or subcritical It describes a method of physically and chemically removing organic high molecular substances attached or adhered to an object to be cleaned by squeezing out water or a polar solvent.
- this method for example, an organic polymer substance thinly formed between two objects to be cleaned or an organic polymer substance attached to an object to be cleaned having a complicated shape is supercritical or subcritical. Since water or polar solvent in the form of water cannot be directly dissipated, there is a problem that the applicable range is extremely limited. Summary of the Invention
- An object of the present invention is to provide a method for separating an adherend that can easily and surely peel off an adherend adhered using an adhesive.
- the present invention relates to a method for peeling an adherend adhered using an adhesive, comprising: sealing an adherend and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container; And a step of releasing the pressure inside the pressure-resistant container.
- the fluid that is a gas at normal temperature and normal pressure is preferably at least one selected from the group consisting of air, carbon dioxide, nitrogen, oxygen, methane, ethane, propane, and butane, and contains at least carbon dioxide. Is more preferred.
- the adherend and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container it is preferable to further enclose water in the pressure-resistant container, and more preferably to enclose a release agent. preferable.
- the pressure inside the pressure vessel is preferably set to 0.5 MPa or more, more preferably 5 MPa or more, and at room temperature and normal pressure contained in the pressure vessel. It is further preferable that at least one of the fluids that is a gas is in a supercritical state or a subcritical state. In the step of setting the inside of the pressure vessel to a high pressure state, it is preferable that the inside of the pressure vessel is set to a temperature higher than a temperature lower by 20 ° C. than a glass transition temperature of the adhesive.
- a method of recovering an electronic component from an electronic component laminate bonded by an adhesive wherein a step of enclosing the electronic component laminate and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container,
- a method of recovering an electronic component from an electronic component laminate having a step of bringing the inside of the pressure vessel into a high pressure state and a step of releasing the pressure inside the pressure vessel is also one of the present inventions.
- a method in which a laminated glass formed by bonding a plurality of glasses with an adhesive or an interlayer film for laminated glass is separated into glass and an adhesive or an interlayer film for laminated glass.
- a method for peeling laminated glass which comprises a step of enclosing a certain fluid in a pressure vessel, a step of raising the pressure inside the pressure vessel, and a step of releasing the pressure inside the pressure vessel, is also provided by the present invention.
- a method for recovering indium-doped tin oxide fine particles from a laminated glass in which the interlayer film for a laminated glass recovered by the method for separating a laminated glass of the present invention is fired is also one of the present invention.
- the method of peeling an adherend according to the present invention is a method of peeling an adherend adhered using an adhesive, wherein the adherend and a fluid that is a gas at normal temperature and normal pressure are sealed in a pressure vessel. Performing a pressure step, a step of bringing the inside of the pressure vessel into a high pressure state, and a step of releasing the pressure inside the pressure vessel.
- the adherend can be completely peeled off without leaving glue or the like by decompressing after the adherend is brought into a high pressure state with a gaseous fluid at normal temperature and normal pressure. The present invention has been completed.
- Fluids at high pressures can easily penetrate into the adhesive bonding the adherend. If the pressure is released while the fluid permeates the adhesive in this way, the volume of the fluid in the adhesive changes, and a stress is generated between the adherend and the adhesive with the change in the volume, It is considered that this stress causes peeling.
- Examples of the mode in which the adhesive strength between the adherend and the adhesive is reduced include, for example, a mode in which the adhesive foams to reduce the bonding area between the adhesive and the adherend, and a mode in which the adhesive foams A mode in which the adhesive force is reduced by swelling if not necessary, or a state in which the expanded fluid is released as a gas to the bonding interface and at least a part of the bonding surface is peeled off by the gas.
- the expanded fluid when the elastic modulus of the adhesive at the time of decompression is high, the expanded fluid cannot release the adhesive and is released as a gas outside the adhesive, and at least a part of the adhesive surface is peeled off. .
- the elastic modulus of the adhesive at the time of decompression when the elastic modulus of the adhesive at the time of decompression is low, the expanded fluid causes the adhesive to foam or swell, thereby reducing the bonding area between the adhesive and the adherend.
- the elastic modulus of the adhesive is too low, outgassing may occur and foaming may not be possible, or even if foaming occurs, the stress generated at the bonding interface may be immediately relaxed.
- the adherend to be subjected to the adherend peeling method of the present invention is not particularly limited as long as it is adhered with an adhesive, but if it has a complicated shape or is fragile, The method for separating an adherend according to the present invention is particularly effective.
- adherends include laminated glass, electronic component laminates, liquid crystal display devices bonded with a sealant, various home appliances, building materials, and the like.
- the electronic component laminate includes a stacked semiconductor, a laminated substrate, and the like, and the collected electronic components include a wafer, a chip, a substrate, and the like.
- can-drink paints which had no method other than baking in the past
- bookbinding adhesives which were obstacles to pulp regeneration
- the adhesive for bonding the adherend is not particularly limited.
- the base resin is a thermoplastic resin having a glass transition temperature of 40 ° C or more.
- a plasticizer for example, a polyvinyl butyl resin, a polybutyl acetal resin, a polyurethane resin, ethylene-monovinegar Examples include acid bur resin, ethylene-ethyl acrylate resin, high-molecular-weight polyvinyl alcohol having a high degree of saponification, poly (meth) acrylate, and polyester resin.
- the plasticizer is not particularly limited.
- the base resin is a polyvinyl butyral resin, a polyvinyl acetal resin, a polyurethane resin, an ethylene-butyl acetate resin, or an ethylene ethyl acrylate resin.
- triethylene glycolosolate 2-ethynolebutyrate, triethyleneglyconoresie-2-ethylhexanoate, triethyleneglycoloseie2-heptanoate and the like are preferably used.
- the base resin is a polyester resin
- an aliphatic hydroxyl group-containing compound, an aromatic hydroxyl group-containing compound, an aliphatic glycidyl group-containing compound, an aromatic glycidyl group-containing compound, and the like are preferably used.
- the plasticizer suitable for these polyester resins may be in any state of a monomer, an oligomer, or a polymer, and the hydroxyl group and the glycidyl group may be in any of the terminal of the molecular skeleton, the side chain, and any position in the molecular skeleton. Good.
- the number of hydroxyl groups and glycidyl groups is preferably one or more per molecule, more preferably two or more.
- the aliphatic hydroxyl group-containing compound is not particularly limited, and examples thereof include polyhydroxyalkanes, alkylene glycols, polyalkylene glycols having an alkylene group having 2 to 4 carbon atoms, long-chain polyols including polytetramethylene ether glycol, and the like.
- Terminal polyalkadiene polyethylene glycol adduct of bisphenol A (1 to 30 carbon atoms), polyethylene glycol adduct of bisphenol A (1 to 30 carbon atoms), hydroxyl-terminated polyester other than the above polyester resin , Hydroxyl-terminated polyproprolatatone, hydroxyl-terminated polycarbonate, acrylic polyol, (partial) saponified ethylene monoacetate copolymer, polyvinyl alcohol, castor oil, ketone resin, xylene resin, and their aliphatic or Good Copolymers and modified products of group a hydroxyl group-containing compounds. These may be used alone or in combination of two or more.
- glycidyl group-containing compound examples include, for example, bisphenol A type epoxy Resins, bisphenol F epoxy resin, bisphenol AD epoxy resin, bisphenol S epoxy resin, etc. bisphenolic epoxy resin; phenol nopolak epoxy resin; aromatic epoxy resin such as trisphenol methane triglycidyl titer and the like; Water additive or bromide; 3,4-epoxycyclohexynolemethinolate 3,4-epoxycyclohexanol oleboxylate, 3,4-epoxy1-2-methinoresic mouth hexinolemethinolle 3,4-epoxy-12-methinole Cyclohexanka ⁇ / poxylate, bis (3,4-epoxycyclohexyl ⁇ ) adipate, bis (3,4-epoxycyclohexylmethyl) adipate, 2- (3,4-epoxycyclohexyl-1-, 5-spiro-1,3-epoxy)
- the glycidyl group of the epoxy is a polyethylene oxide having 1 to 30 (preferably 2 to 16) carbon atoms. Molecules substituted by oxides can also serve as plasticizers.
- Glycidyl ester ester epoxy resins such as glycidyl ester and glycidyl ester of dimer acid and hydrogenated products thereof; N, N'-diglycidyl derivatives of cyclic alkylene ureas: ⁇ , ⁇ , ⁇ — of ⁇ -aminophenol
- Glycidylamine type epoxy resins such as triglycidyl derivatives, ⁇ , ⁇ , and ⁇ -tridaridyl derivatives of m-aminophenol and hydrogenated products thereof
- Epoxy bond Polyester resin having at least one bond per molecule; Urethane-modified epoxy resin in which the structure of the above-mentioned various epoxy group-containing compounds has introduced a ⁇ urethane bond ⁇ polycaprolactone bond ⁇ polycaprolataton-modified epoxy resin
- a rubber component such as NBR, CTBN, polybutadiene, or acrylic rubber
- the adhesive composed of a base resin having no adhesiveness and a plasticizer also includes a solvent-based adhesive.
- the aqueous solution of polybutyl alcohol is obtained by adding water as a plasticizer to polybutyl alcohol as a base resin.
- the thermoplastic composition resin is not particularly limited as long as the glass transition temperature is 40 ° C or less.
- Bul-based resins such as biel acetate, polyvinyl alcohol, polyvinyl chloride and polybierptylal; acrylic resins such as poly (meth) acrylic acid and poly (meth) acrylate; polyester-based resins, nitrocellulose, starch, etc. Is mentioned.
- the curable resin is not particularly limited, and examples thereof include a phenol resin, a resorcin resin, a franc resin, a urea resin, a melamine resin, a polyester resin, Examples include polyurethane resin, epoxy resin, and silicone resin.
- the elastomer is not particularly limited.
- the elastomer is not particularly limited.
- natural rubber butadiene atarilonitrile rubber, styrene-isoprene-styrene resin, styrene-ethylene ethylene Butadiene-styrene tree, ethylene-propylene rubber, styrene-butadiene Synthetic rubber such as a tylene-based resin may be used.
- These rubbers may be hydrogenated. Further, these rubbers may be those imparted with flexibility by compounding a plasticizer.
- the method for separating an adherend according to the present invention includes a step of enclosing the adherend and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container.
- the fluid that is a gas at normal temperature and normal pressure is not particularly limited, but is preferably at least one selected from the group consisting of air, carbon dioxide, nitrogen, oxygen, methane, ethane, propane, and butane.
- the critical point of carbon dioxide is relatively close to normal temperature, it is possible to treat the adherend in a high-density state. It has excellent ability to penetrate into the adhesive, and can realize extremely high peeling efficiency.
- carbon dioxide is odorless, non-toxic and non-flammable, and therefore has high utility value in terms of safety. Also, when used in combination with a fluid other than carbon dioxide, these excellent properties can be exhibited.
- the method for enclosing the fluid which is a gas at normal temperature and normal pressure is not particularly limited, and the fluid may be sealed in the pressure vessel in any state of gas, liquid and solid.
- gaseous or liquid carbon dioxide may be blown, or dry ice carbon dioxide may be introduced.
- the amount of the fluid that is gaseous at normal temperature and normal pressure is not particularly limited as long as an appropriate amount is selected according to the capacity of the pressure vessel to be used, but at least when the temperature of the pressure vessel is raised to a certain temperature. It is preferable that the pressure inside the pressure vessel is sealed so as to make it 0.5 MPa or more.
- the adherend In the step of enclosing the adherend and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container, it is preferable that water be further enclosed in the pressure-resistant container.
- water By using water in combination, the adherend can be more easily and reliably peeled off.
- the water is not particularly limited, and ordinary tap water, distilled water, and the like can be used.
- the amount of water to be filled is not particularly limited, but a preferred lower limit to the volume of the pressure vessel is 0.01 g Zin L, and a preferable upper limit is 0.2 g Zm L. 0. O lg If it is less than Zm L, a sufficient effect of removing the adherend may not be obtained. If it exceeds 0.2 g ZmL, it is difficult to make water exist as a homogeneous phase in the pressure vessel, and the water separates into a condensed phase and a non-condensed phase. In this case, if the adherend is immersed in the condensed phase that has separated, the peeling efficiency may be inferior.Therefore, there is a force that prevents the adherend from being immersed in the condensed phase by any means. Need to be done.
- the adherend and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container it is preferable to further enclose a release agent in the pressure-resistant container.
- a release agent in the pressure-resistant container.
- the release agent is solvated in the fluid.
- the released mold agent can penetrate into the adhesive and exhibit an extremely high peeling effect.
- the release agent is not particularly limited, and examples thereof include a surfactant, an organic salt that generates various ions, an inorganic salt that generates various ions, a chelate compound, and a low molecular weight organic compound.
- the surfactant is not particularly limited, and includes fatty acids (salts), monosulfo fatty acid esters (salts), alkylbenzene sulfonic acids (salts), alkyl ether sulfates (salts), and triethanolamine alkyl sulfates.
- the organic salts or inorganic acids that generate the above-mentioned various ions are not particularly limited.
- alkali metals and alkaline earth metals such as potassium, sodium, and magnesium
- carboxylic acids such as octylic acid, hexylic acid, butyric acid, acetic acid, and formic acid.
- organic acids such as acids, and salts of phosphoric acid, sulfuric acid, nitric acid, hydrochloric acid, and the like with inorganic acids.
- an alkali metal salt and an alkaline earth metal salt of an organic acid having 5 to 16 carbon atoms are preferable, and a carboxylic acid or dicarbon having 6 to 10 carbon atoms is preferable.
- the magnesium salt of the acid is more preferred.
- the magnesium salt of the carboxylic acid or dicarboxylic acid is not particularly limited, and examples thereof include magnesium 2-ethylbutyrate, Examples include magnesium herbate, magnesium hexanoate, magnesium heptanoate, magnesium octoate, magnesium nonanoate, magnesium decanoate, magnesium gnoletanolate, and magnesium adipic acid.
- the chelate compound is not particularly limited, and examples thereof include: carboxylic acids (salts) such as ethylenediaminetetraacetic acid (salt), tri-triacetate (salt), and hydroxyliminodiacetic acid (salt); hydrogen-containing compounds; Examples thereof include phosphonic acids such as hydroxyethylidene diphosphoric acid, and diketones. Above all,] -diketones are preferable because of their excellent compatibility with plasticizers and resins used in the intermediate for adherends. As the above-mentioned i3 diketones, for example, acetylacetone, benzoyltrifluoroacetone, dipivaloylmethane and the like are preferable.
- the low molecular weight organic compound is not particularly limited, and examples thereof include a fluorine-containing compound; a silicon-containing compound such as silicone oil; and an alcohol.
- a fluorine-containing compound such as silicone oil
- a silicon-containing compound such as silicone oil
- an alcohol an alcohol
- the adhesive component of the adhesive has a hydrophilic group such as a hydroxyl group, an ester group, an amino group, and a carbonyl group
- water can also act as an effective release agent.
- release agents may be used alone or in combination of two or more.
- the pressure vessel is not particularly limited as long as it has a sufficient pressure resistance.
- a vessel made of metal or the like, an autoclave, a rubber bag, or the like can be used. It is also possible to put the adherend sealed in a plurality of containers and the like in an autoclave for batch processing.
- the method for separating an adherend according to the present invention includes a step of setting the inside of the pressure vessel to a high pressure state.
- the pressure at this time is appropriately selected depending on the type of the adhesive or the interlayer film for laminated glass, but it is preferable that the higher the pressure is, the more the peeling can be completed in a shorter time.
- a preferred lower limit is 0.5 MPa. When the pressure is less than 0.5 MPa, it takes time for the fluid, water and the release agent to penetrate into the adhesive, resulting in poor efficiency, and also a sufficient amount of fluid cannot be penetrated into the adhesive, so that the adhesive can be peeled off. Or not.
- a more preferred lower limit is 5 MPa.
- the temperature at this time is preferably higher than the temperature 20 ° C lower than the glass transition temperature of the adhesive. At lower temperatures, it may take longer for the fluid to penetrate the adhesive. More preferably, it is higher than the temperature which is lower by 10 ° C than the glass transition temperature of the resin constituting the adhesive.
- the upper limit of the temperature is not particularly limited as long as the optimum temperature is set according to the type of the adhesive, but at high temperatures, the density of the fluid decreases, or the affinity between the adherend and the adhesive increases. As a result, the permeability of the fluid into the adhesive is reduced, and the peeling efficiency may be reduced. In the case of a general adhesive, a preferable upper limit is 150 ° C, and a more preferable lower limit is 100 ° C. However, this does not apply when the adhesive is crosslinkable or crystalline.
- At least one kind of fluid that is a gas at normal temperature and normal pressure contained in the pressure vessel is brought into a supercritical state or a subcritical state.
- a fluid in a supercritical state or a subcritical state is extremely excellent in permeability to an adhesive, and can exhibit a high peeling effect.
- the supercritical state means a state in which the pressure is equal to or higher than a critical pressure (hereinafter, also referred to as Pc) and equal to or higher than a critical temperature (hereinafter, also referred to as Tc).
- Pc a critical pressure
- Tc a critical temperature
- the subcritical state is a state other than the supercritical state, and when the pressure and temperature during the reaction are P and T, respectively, 0.5 and PZP c ⁇ l. 0 and 0.5 and TZTc , Or 0.5 means P / P c and 0.5 means TZTc means 1.0.
- the preferred pressure and temperature ranges for the above subcritical state are 0.6 ⁇ PZPc ⁇ l.0 and 0.6, TZTc, or 0.6, P / Pc and 0.6 ⁇ T / Tc. 1. It is 0. Here, the temperature represents Celsius, but if either T c or T is minus in Celsius, the temperature is treated as satisfying the subcritical state, and the pressure is 0.5 ⁇ P / When the condition of Pc is satisfied, it is assumed that the device is in a subcritical state.
- the method of bringing the inside of the pressure vessel into a high pressure state is not particularly limited.
- a gaseous fluid is sealed.
- a method in which a fluid is blown until the pressure reaches a certain level or more; a method in which a fluid or the like is sealed and then further heated are used.
- the method for separating an adherend according to the present invention in a state where the pressure inside the pressure-resistant container is set to a high pressure, A physical force such as vibrating the pressure-resistant container or irradiating ultrasonic waves may be applied. By applying a physical force, peeling of the adherend can be further promoted.
- the method for separating an adherend according to the present invention includes a step of releasing the pressure inside the pressure-resistant container.
- “releasing the pressure” means reducing the pressure in the container in a high pressure state.
- the pressure may be gradually released by cooling the container, or may be rapidly released.
- the method of rapidly decompressing is not particularly limited, and examples thereof include a method of opening the pulp connected to the container.
- the step of decompressing the inside of the pressure-resistant container is preferably performed at a temperature lower than a temperature higher by 1 ° C. than the glass transition temperature of the adhesive. If decompression is performed at a temperature higher than this, the elastic modulus of the adhesive may be low, gas may escape, and the peeling efficiency may decrease. However, this does not apply if the adhesive is cross-linked or crystalline.
- the lower limit of the temperature is not particularly limited, it is preferable that the temperature is higher than the temperature 25 ° C lower than the glass transition temperature of the adhesive. If decompression is performed at a temperature lower than this, the elastic modulus of the adhesive is too high, and a sufficient peeling pressure cannot be obtained, and the peeling efficiency may decrease.
- various modes are selected by selecting the type of fluid, the temperature and pressure during pressurization, the time for keeping the inside of the pressure-resistant container in a high-pressure state, and the method of decompression. Thereby, the adherend can be separated. These conditions are appropriately selected depending on the type of the adherend, the type of the adhesive, the purpose of the peeling, and the like.
- the adhesive when the adhesive is a non-adhesive base resin and a plasticizer that imparts adhesiveness, carbon dioxide is selected as a fluid and treated at a relatively low temperature for a long time to obtain a base resin.
- the plasticizer which is a low molecular weight substance, is dissolved in a fluid without decomposing it, causing the adhesive to lose its adhesiveness, allowing the adherend to be peeled off, and at the same time collecting and recycling the base luster.
- the decomposition accelerator include peroxyacids such as aqueous hydrogen peroxide and peracetic acid; persulfates such as ammonium persulfate, sodium persulfate, and potassium persulfate; and peroxides such as hydrogen peroxide adducts of sodium carbonate.
- Sodium carbonate (salt); peroxide having a peroxy group, such as diisopropyl peroxide pill, may be used in combination. Further, various acid catalysts or alkali catalysts may be used. This method is suitable even when the adherend is fragile because the adherend does not receive a physical impact.
- the fluid is impregnated into the adhesive, and the adhesive is foamed by rapidly decompressing the adhesive to lose the adhesiveness of the adhesive. Can be peeled off.
- the pressurizing process and the depressurizing process may be repeated multiple times as necessary.
- an adherend adhered using an adhesive can be easily and reliably peeled even if it has a complicated shape or is fragile. can do. Further, in the method for separating an adherend according to the present invention, since almost no organic solvent is used, there is no danger that the plasticizer or the like contained in the adhesive is eluted into the solvent, and the load on the environment is also reduced. Extremely small.
- adherends of the present invention for example, laminated glass, electronic component laminates, liquid crystal display devices, various home appliances, building materials, and the like bonded with a sealant are separated and collected for recycling.
- a sealant for example, laminated glass, electronic component laminates, liquid crystal display devices, various home appliances, building materials, and the like bonded with a sealant are separated and collected for recycling.
- a method of recovering an electronic component from an electronic component laminate bonded with an adhesive comprising: sealing an electronic component laminate and a fluid that is a gas at normal temperature and normal pressure in a pressure-resistant container;
- a method of recovering an electronic component from the electronic component laminate which includes a step of bringing the state into a state and a step of releasing the pressure inside the pressure vessel, is also one of the present inventions.
- a method in which a laminated glass formed by bonding a plurality of glasses with an adhesive or an interlayer film for laminated glass is separated into glass and an adhesive or an interlayer film for laminated glass. Enclosing a fluid in a pressure-resistant container;
- the present invention also includes a method for peeling laminated glass, which includes a step of bringing the inside of the pressure vessel into a high pressure state and a step of releasing the pressure inside the pressure vessel.
- the laminated glass used in the method for peeling laminated glass of the present invention may be a single large-sized glass used as a glass for a vehicle or the like, and may be one cut into small pieces using a cutter or the like, a crusher, or the like. It may be used and crushed into small pieces.
- the collected glass and interlayer film can be reused as they are.
- a pressure vessel having a relatively small capacity can be used, and a large amount of laminated glass can be efficiently processed at once in a short time. be able to.
- the mixture of the obtained glass and an adhesive or an interlayer film for a laminated glass is separated after the peeling is performed by the method for separating a laminated glass of the present invention.
- immersion in water may be performed. Since the specific gravity of the glass and the adhesive or interlayer for laminated glass is significantly different, the glass precipitates at the bottom of the water, while the adhesive or interlayer for laminated glass mainly composed of resin floats. Therefore, it can be separated very easily by a method such as collecting floating resin components.
- a laminated glass can be peeled easily and reliably into glass and an adhesive agent or an interlayer film for laminated glass. Since the obtained glass and interlayer film for laminated glass are completely separated from each other, they can be reused as they are by recycling or the like. In particular, when only one adherend is used, the recovered glass or interlayer film for laminated glass can be reused as it is.
- the metal fine particles can be collected separately from the glass and are not mixed at the time of collection.
- fine metal particles indium-doped tin oxide fine particles and the like are expensive, so it is extremely economically important to collect and recycle them.
- Indium dough The method for recovering the tin oxide fine particles is not particularly limited, but a method in which the interlayer film for laminated glass recovered by the method for peeling laminated glass of the present invention is preferably used. Since no residue derived from glass is mixed into the residue after firing, extremely high purity indium-doped tin oxide fine particles can be recovered.
- a method for recovering indium-doped tin oxide fine particles from a laminated glass obtained by firing the interlayer film for a laminated glass recovered by the method for peeling a laminated glass of the present invention is also one of the present invention.
- Polyethylene butyral resin (average degree of polymerization 1700, residual acetyl group 1 mo 1%, degree of petyralization 69mo 1%) 100 parts by weight of triethylene glycol di-2-ethyl ethyl sanoate (3GO) 41% by weight as plasticizer
- 3GO triethylene glycol di-2-ethyl ethyl sanoate
- the obtained interlayer film for laminated glass is sandwiched between two transparent inorganic flat glass plates (1 Ocm square, thickness lmm) to form a laminated glass structure (laminate), which is used as a rubber bag. Then, it is sandwiched by a 5 mm-thick stainless steel plate for pressing, the pressure inside the rubber bag is reduced to 16 kPa, degassing is performed at 130 ° C, and vacuum pressing is performed to laminate glass. Produced.
- Example 2 The laminated glass produced in Example 1 was crushed into small pieces using a crusher.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- Example 3 The laminated glass produced in Example 1 was cut into small pieces of 1 cm square using a high-speed rotating cutter.
- Example 4 The laminated glass produced in Example 1 was ground using a hammer, and
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- the laminated glass produced in Example 1 was pulverized into small pieces using a pulverizer.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- Example 8 The laminated glass produced in Example 1 was crushed into small pieces using a crusher.
- a 1 L pressure vessel was charged with 40 g of the obtained crushed laminated glass pieces, distilled water (40 g) and a mixed solvent of methanol and butanol (40: 1) in a volume ratio of 1: 1 as a release agent. Carbon dioxide was injected into the pressure-resistant container until the pressure in the pressure-resistant container became 15 MPa. The pressure vessel is heated to 60 ° C, and the pressure inside the pressure vessel becomes stable.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- Example 10 The laminated glass produced in Example 1 was crushed into small pieces using a crusher.
- the pressure vessel was cooled to room temperature and decompressed. When the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- the obtained interlayer film for laminated glass is sandwiched between two transparent inorganic flat glass plates (10 cm square, lmm thick) to form a laminated glass structure (laminate), which is used as a rubber bag. It is sandwiched by a 5 mm-thick stainless steel sheet for pressing, the pressure inside the rubber bag is reduced to 16 kPa, degassed at a temperature of 130 ° C, and vacuum pressed to perform laminated glass.
- laminated glass structure laminated glass structure
- the obtained laminated glass was cut into small pieces of 1 cm square using a high-speed rotating cutter.
- the pressure vessel was cooled to room temperature and decompressed.
- the state of the obtained product was visually observed, it was completely separated into glass and an interlayer film for laminated glass.
- the separated interlayer film for laminated glass was collected and placed in an electric furnace and baked at 700 ° C. As a result, indium-doped tin oxide fine particles with extremely high purity could be recovered as a residue.
- the peeling method of the adherend which can easily and reliably peel the adherend adhere
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Sustainable Development (AREA)
- Processing Of Solid Wastes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020057019376A KR101085346B1 (ko) | 2003-04-14 | 2004-04-14 | 피착체의 박리 방법, 전자 부품 적층체로부터 전자 부품을 회수하는 방법 및 합판 유리의 박리 방법 |
US10/553,177 US7909959B2 (en) | 2003-04-14 | 2004-04-14 | Method for releasing adhered article |
CNB200480010024XA CN100368497C (zh) | 2003-04-14 | 2004-04-14 | 被粘物的剥离方法、从电子部件层叠体回收电子部件的方法及夹层玻璃的剥离方法 |
JP2005505418A JP4599294B2 (ja) | 2003-04-14 | 2004-04-14 | 合わせガラスの剥離方法 |
EP04727372.7A EP1619227B1 (en) | 2003-04-14 | 2004-04-14 | Method for releasing adhered article |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003109356 | 2003-04-14 | ||
JP2003-109355 | 2003-04-14 | ||
JP2003-109356 | 2003-04-14 | ||
JP2003109355 | 2003-04-14 | ||
JP2003-276833 | 2003-07-18 | ||
JP2003276832 | 2003-07-18 | ||
JP2003-276832 | 2003-07-18 | ||
JP2003276833 | 2003-07-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004092292A1 true WO2004092292A1 (ja) | 2004-10-28 |
Family
ID=33304036
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/005291 WO2004092292A1 (ja) | 2003-04-14 | 2004-04-14 | 被着体の剥離方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7909959B2 (ja) |
EP (1) | EP1619227B1 (ja) |
JP (1) | JP4599294B2 (ja) |
KR (1) | KR101085346B1 (ja) |
CN (1) | CN100368497C (ja) |
WO (1) | WO2004092292A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007326358A (ja) * | 2006-05-08 | 2007-12-20 | Asahi Glass Co Ltd | 薄板ガラス積層体、薄板ガラス積層体を用いた表示装置の製造方法および、支持ガラス基板 |
JP2009199069A (ja) * | 2008-01-25 | 2009-09-03 | Nitto Denko Corp | 粘着型光学フィルムの剥離方法、及び粘着型光学フィルム |
JP2011132603A (ja) * | 2011-01-07 | 2011-07-07 | Nippon Sheet Glass Co Ltd | 複合材料分離用水溶液、複合材料分離方法、及び回収金属 |
JP2013520244A (ja) * | 2010-02-25 | 2013-06-06 | ザ プロクター アンド ギャンブル カンパニー | 超吸収性ポリマー粒子の再利用 |
JP2018528853A (ja) * | 2015-09-03 | 2018-10-04 | セントレ・ナショナル・デ・ラ・レシェルシェ・サイエンティフィーク | 少なくとも1つの有機構成要素を含む多層システムを分解するための方法および装置 |
JP2019136672A (ja) * | 2018-02-13 | 2019-08-22 | 株式会社リコー | 接合レンズのリサイクル方法 |
WO2021161786A1 (ja) * | 2020-02-14 | 2021-08-19 | Nissha株式会社 | 成形品 |
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8297364B2 (en) | 2009-12-08 | 2012-10-30 | Baker Hughes Incorporated | Telescopic unit with dissolvable barrier |
US8403037B2 (en) * | 2009-12-08 | 2013-03-26 | Baker Hughes Incorporated | Dissolvable tool and method |
US9109429B2 (en) | 2002-12-08 | 2015-08-18 | Baker Hughes Incorporated | Engineered powder compact composite material |
US9079246B2 (en) | 2009-12-08 | 2015-07-14 | Baker Hughes Incorporated | Method of making a nanomatrix powder metal compact |
US8327931B2 (en) * | 2009-12-08 | 2012-12-11 | Baker Hughes Incorporated | Multi-component disappearing tripping ball and method for making the same |
US9682425B2 (en) | 2009-12-08 | 2017-06-20 | Baker Hughes Incorporated | Coated metallic powder and method of making the same |
US9101978B2 (en) | 2002-12-08 | 2015-08-11 | Baker Hughes Incorporated | Nanomatrix powder metal compact |
JP5060791B2 (ja) * | 2007-01-26 | 2012-10-31 | 独立行政法人森林総合研究所 | 木材の乾燥方法、木材への薬剤浸透方法及び乾燥装置 |
US20100112355A1 (en) * | 2008-11-06 | 2010-05-06 | Cessna Aircraft Company | Aircraft Transparency |
US9227243B2 (en) | 2009-12-08 | 2016-01-05 | Baker Hughes Incorporated | Method of making a powder metal compact |
US10240419B2 (en) | 2009-12-08 | 2019-03-26 | Baker Hughes, A Ge Company, Llc | Downhole flow inhibition tool and method of unplugging a seat |
US9243475B2 (en) | 2009-12-08 | 2016-01-26 | Baker Hughes Incorporated | Extruded powder metal compact |
US8425651B2 (en) | 2010-07-30 | 2013-04-23 | Baker Hughes Incorporated | Nanomatrix metal composite |
US8528633B2 (en) | 2009-12-08 | 2013-09-10 | Baker Hughes Incorporated | Dissolvable tool and method |
US9127515B2 (en) | 2010-10-27 | 2015-09-08 | Baker Hughes Incorporated | Nanomatrix carbon composite |
US8573295B2 (en) | 2010-11-16 | 2013-11-05 | Baker Hughes Incorporated | Plug and method of unplugging a seat |
US8424610B2 (en) | 2010-03-05 | 2013-04-23 | Baker Hughes Incorporated | Flow control arrangement and method |
US8776884B2 (en) | 2010-08-09 | 2014-07-15 | Baker Hughes Incorporated | Formation treatment system and method |
US9090955B2 (en) | 2010-10-27 | 2015-07-28 | Baker Hughes Incorporated | Nanomatrix powder metal composite |
US9080098B2 (en) | 2011-04-28 | 2015-07-14 | Baker Hughes Incorporated | Functionally gradient composite article |
US8631876B2 (en) | 2011-04-28 | 2014-01-21 | Baker Hughes Incorporated | Method of making and using a functionally gradient composite tool |
US9139928B2 (en) | 2011-06-17 | 2015-09-22 | Baker Hughes Incorporated | Corrodible downhole article and method of removing the article from downhole environment |
DE102011077860A1 (de) * | 2011-06-21 | 2012-12-27 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von 2-Ethylheptansäure |
US9707739B2 (en) | 2011-07-22 | 2017-07-18 | Baker Hughes Incorporated | Intermetallic metallic composite, method of manufacture thereof and articles comprising the same |
US8783365B2 (en) | 2011-07-28 | 2014-07-22 | Baker Hughes Incorporated | Selective hydraulic fracturing tool and method thereof |
US9833838B2 (en) | 2011-07-29 | 2017-12-05 | Baker Hughes, A Ge Company, Llc | Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle |
US9643250B2 (en) | 2011-07-29 | 2017-05-09 | Baker Hughes Incorporated | Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle |
US9057242B2 (en) | 2011-08-05 | 2015-06-16 | Baker Hughes Incorporated | Method of controlling corrosion rate in downhole article, and downhole article having controlled corrosion rate |
US9033055B2 (en) | 2011-08-17 | 2015-05-19 | Baker Hughes Incorporated | Selectively degradable passage restriction and method |
US9856547B2 (en) | 2011-08-30 | 2018-01-02 | Bakers Hughes, A Ge Company, Llc | Nanostructured powder metal compact |
US9090956B2 (en) | 2011-08-30 | 2015-07-28 | Baker Hughes Incorporated | Aluminum alloy powder metal compact |
US9109269B2 (en) | 2011-08-30 | 2015-08-18 | Baker Hughes Incorporated | Magnesium alloy powder metal compact |
US9643144B2 (en) | 2011-09-02 | 2017-05-09 | Baker Hughes Incorporated | Method to generate and disperse nanostructures in a composite material |
US9347119B2 (en) | 2011-09-03 | 2016-05-24 | Baker Hughes Incorporated | Degradable high shock impedance material |
US9133695B2 (en) | 2011-09-03 | 2015-09-15 | Baker Hughes Incorporated | Degradable shaped charge and perforating gun system |
US9187990B2 (en) | 2011-09-03 | 2015-11-17 | Baker Hughes Incorporated | Method of using a degradable shaped charge and perforating gun system |
US9284812B2 (en) | 2011-11-21 | 2016-03-15 | Baker Hughes Incorporated | System for increasing swelling efficiency |
US9010416B2 (en) | 2012-01-25 | 2015-04-21 | Baker Hughes Incorporated | Tubular anchoring system and a seat for use in the same |
US9068428B2 (en) | 2012-02-13 | 2015-06-30 | Baker Hughes Incorporated | Selectively corrodible downhole article and method of use |
US9605508B2 (en) | 2012-05-08 | 2017-03-28 | Baker Hughes Incorporated | Disintegrable and conformable metallic seal, and method of making the same |
US9816339B2 (en) | 2013-09-03 | 2017-11-14 | Baker Hughes, A Ge Company, Llc | Plug reception assembly and method of reducing restriction in a borehole |
US10865465B2 (en) | 2017-07-27 | 2020-12-15 | Terves, Llc | Degradable metal matrix composite |
CA2936851A1 (en) | 2014-02-21 | 2015-08-27 | Terves, Inc. | Fluid activated disintegrating metal system |
US11167343B2 (en) | 2014-02-21 | 2021-11-09 | Terves, Llc | Galvanically-active in situ formed particles for controlled rate dissolving tools |
US10689740B2 (en) | 2014-04-18 | 2020-06-23 | Terves, LLCq | Galvanically-active in situ formed particles for controlled rate dissolving tools |
US9924897B1 (en) * | 2014-06-12 | 2018-03-27 | Masimo Corporation | Heated reprocessing of physiological sensors |
US9910026B2 (en) | 2015-01-21 | 2018-03-06 | Baker Hughes, A Ge Company, Llc | High temperature tracers for downhole detection of produced water |
US10378303B2 (en) | 2015-03-05 | 2019-08-13 | Baker Hughes, A Ge Company, Llc | Downhole tool and method of forming the same |
JP6490459B2 (ja) * | 2015-03-13 | 2019-03-27 | 古河電気工業株式会社 | ウェハ固定テープ、半導体ウェハの処理方法および半導体チップ |
US10052859B2 (en) * | 2015-05-01 | 2018-08-21 | Euna Park | Apparatus and method for reclaiming curved and bendable display screens |
US10221637B2 (en) | 2015-08-11 | 2019-03-05 | Baker Hughes, A Ge Company, Llc | Methods of manufacturing dissolvable tools via liquid-solid state molding |
US10016810B2 (en) | 2015-12-14 | 2018-07-10 | Baker Hughes, A Ge Company, Llc | Methods of manufacturing degradable tools using a galvanic carrier and tools manufactured thereof |
CN106183358A (zh) * | 2016-07-06 | 2016-12-07 | 中国航空工业集团公司北京航空材料研究院 | 一种分离夹层玻璃断口的方法 |
FR3078539B1 (fr) * | 2018-03-02 | 2020-11-13 | Inst Nat Polytechnique Toulouse | Procede de traitement du polyvinylbutyral (pvb) |
FR3088579B1 (fr) * | 2018-11-21 | 2022-08-26 | Commissariat Energie Atomique | Procede de delamination d’un dispositif multicouche |
CN109491031B (zh) * | 2018-12-20 | 2021-01-01 | 深圳长飞智连技术有限公司 | 一种紧套光纤以及紧套光纤的制作方法 |
CN110834027A (zh) * | 2019-04-09 | 2020-02-25 | 信义玻璃工程(东莞)有限公司 | 夹层玻璃再利用的方法 |
EP3738991A1 (de) * | 2019-05-17 | 2020-11-18 | Evonik Operations GmbH | Verfahren zum lösen von klebstoffen |
GB2591123B (en) * | 2020-01-16 | 2023-01-18 | Rdc Tech Ltd | An apparatus to effect at least partial breakdown of a material or product item or a combination of materials or product items |
CN115090645A (zh) * | 2022-05-23 | 2022-09-23 | 深圳先进技术研究院 | 光伏组件的回收方法以及回收装置 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5009746A (en) | 1990-10-12 | 1991-04-23 | Kimberly-Clark Corporation | Method for removing stickies from secondary fibers using supercritical CO2 solvent extraction |
JPH0547732A (ja) | 1991-08-12 | 1993-02-26 | Nikkiso Co Ltd | 精密洗浄方法および精密洗浄装置 |
JPH10237215A (ja) * | 1997-02-28 | 1998-09-08 | Toshiba Corp | 樹脂廃棄物の分解処理方法および分解処理装置 |
JP2001235718A (ja) | 2000-02-23 | 2001-08-31 | Mitsuo Kamiwano | 液晶パネルのリサイクル処理方法およびリサイクル処理システム |
JP2002155162A (ja) * | 2000-11-22 | 2002-05-28 | Idemitsu Petrochem Co Ltd | ディスク状情報記録媒体のリサイクル方法 |
JP2002177922A (ja) * | 2000-12-11 | 2002-06-25 | Ibiden Co Ltd | 廃棄されたプリント基板からの有価物の回収法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0680945A (ja) | 1992-07-17 | 1994-03-22 | Toyo Ink Mfg Co Ltd | 古紙回収適性を有する製本用ホットメルト接着剤 |
JPH06219793A (ja) | 1993-01-29 | 1994-08-09 | Asahi Glass Co Ltd | 合せガラスの膜とガラスの分離方法および分離装置 |
JPH06247751A (ja) | 1993-02-24 | 1994-09-06 | Asahi Glass Co Ltd | 合せガラスからガラスを回収する方法 |
JP3137504B2 (ja) | 1993-06-08 | 2001-02-26 | 積水化学工業株式会社 | 合わせガラスから中間膜を回収する方法 |
US5462973A (en) * | 1994-07-13 | 1995-10-31 | Hoechst Celanese Corporation | Separation of polyethylene terephthalate and polyvinyl chloride using supercritical carbon dioxide |
US5501761A (en) * | 1994-10-18 | 1996-03-26 | At&T Corp. | Method for stripping conformal coatings from circuit boards |
JPH09227957A (ja) | 1996-02-16 | 1997-09-02 | Yamaichi Syst Purodeyuusu:Kk | 使用済スチール製飲料缶からのスチール再生方法 |
US6306564B1 (en) * | 1997-05-27 | 2001-10-23 | Tokyo Electron Limited | Removal of resist or residue from semiconductors using supercritical carbon dioxide |
DE19731160C2 (de) * | 1997-07-21 | 1999-05-27 | Pilkington Solar Int Gmbh | Verfahren zum Trennen der Komponenten einer Verbundglasscheibe |
JP4252126B2 (ja) | 1998-06-19 | 2009-04-08 | シャープ株式会社 | 液晶表示装置の製造方法 |
JP3008940B1 (ja) * | 1998-09-25 | 2000-02-14 | 松下電器産業株式会社 | 鉛を含む圧電材料を用いた電子デバイスの分離・回収方法 |
US6383647B1 (en) * | 1998-09-30 | 2002-05-07 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass and laminated glass |
JP2001104928A (ja) | 1999-10-04 | 2001-04-17 | Central Glass Co Ltd | 合わせガラスよりガラスと中間膜とに分離回収する装置 |
BR0103927A (pt) | 2000-09-08 | 2002-05-28 | R & D Technology Inc | Método para reduzir o tamanho de partìcula de um material, partìcula moìda, e, asfalto |
JP3642733B2 (ja) * | 2000-12-20 | 2005-04-27 | セントラル硝子株式会社 | 合わせガラスをガラス片と中間膜片とに分離して回収する装置 |
JP4562297B2 (ja) * | 2001-02-06 | 2010-10-13 | 株式会社アサカ理研 | 超臨界水を用いた電子部品からの無機物部品材料の回収方法 |
JP3875854B2 (ja) * | 2001-05-21 | 2007-01-31 | シャープ株式会社 | 有機高分子物質の除去装置および除去方法 |
JP4306167B2 (ja) * | 2001-11-02 | 2009-07-29 | 株式会社ブリヂストン | 封止用有機樹脂の分解方法 |
JP3897579B2 (ja) | 2001-11-27 | 2007-03-28 | 電気化学工業株式会社 | 合わせガラスから樹脂分を分離する方法 |
JP2003285042A (ja) | 2002-01-24 | 2003-10-07 | Tsuruoka:Kk | 廃合わせガラスの処理方法および中間膜用ポリビニルブチラール樹脂の再生方法 |
-
2004
- 2004-04-14 EP EP04727372.7A patent/EP1619227B1/en not_active Expired - Fee Related
- 2004-04-14 JP JP2005505418A patent/JP4599294B2/ja not_active Expired - Lifetime
- 2004-04-14 WO PCT/JP2004/005291 patent/WO2004092292A1/ja active Application Filing
- 2004-04-14 KR KR1020057019376A patent/KR101085346B1/ko active IP Right Grant
- 2004-04-14 CN CNB200480010024XA patent/CN100368497C/zh not_active Expired - Fee Related
- 2004-04-14 US US10/553,177 patent/US7909959B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5009746A (en) | 1990-10-12 | 1991-04-23 | Kimberly-Clark Corporation | Method for removing stickies from secondary fibers using supercritical CO2 solvent extraction |
JPH0547732A (ja) | 1991-08-12 | 1993-02-26 | Nikkiso Co Ltd | 精密洗浄方法および精密洗浄装置 |
JPH10237215A (ja) * | 1997-02-28 | 1998-09-08 | Toshiba Corp | 樹脂廃棄物の分解処理方法および分解処理装置 |
JP2001235718A (ja) | 2000-02-23 | 2001-08-31 | Mitsuo Kamiwano | 液晶パネルのリサイクル処理方法およびリサイクル処理システム |
JP2002155162A (ja) * | 2000-11-22 | 2002-05-28 | Idemitsu Petrochem Co Ltd | ディスク状情報記録媒体のリサイクル方法 |
JP2002177922A (ja) * | 2000-12-11 | 2002-06-25 | Ibiden Co Ltd | 廃棄されたプリント基板からの有価物の回収法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1619227A4 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007326358A (ja) * | 2006-05-08 | 2007-12-20 | Asahi Glass Co Ltd | 薄板ガラス積層体、薄板ガラス積層体を用いた表示装置の製造方法および、支持ガラス基板 |
JP2009199069A (ja) * | 2008-01-25 | 2009-09-03 | Nitto Denko Corp | 粘着型光学フィルムの剥離方法、及び粘着型光学フィルム |
JP2013520244A (ja) * | 2010-02-25 | 2013-06-06 | ザ プロクター アンド ギャンブル カンパニー | 超吸収性ポリマー粒子の再利用 |
JP2013520533A (ja) * | 2010-02-25 | 2013-06-06 | ザ プロクター アンド ギャンブル カンパニー | ポリマーを含む固化した熱可塑性組成物から、超吸収性ポリマー粒子を分離する方法 |
JP2011132603A (ja) * | 2011-01-07 | 2011-07-07 | Nippon Sheet Glass Co Ltd | 複合材料分離用水溶液、複合材料分離方法、及び回収金属 |
JP2018528853A (ja) * | 2015-09-03 | 2018-10-04 | セントレ・ナショナル・デ・ラ・レシェルシェ・サイエンティフィーク | 少なくとも1つの有機構成要素を含む多層システムを分解するための方法および装置 |
JP2019136672A (ja) * | 2018-02-13 | 2019-08-22 | 株式会社リコー | 接合レンズのリサイクル方法 |
WO2021161786A1 (ja) * | 2020-02-14 | 2021-08-19 | Nissha株式会社 | 成形品 |
JP2021126828A (ja) * | 2020-02-14 | 2021-09-02 | Nissha株式会社 | 成形品 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2004092292A1 (ja) | 2006-07-06 |
KR101085346B1 (ko) | 2011-11-23 |
JP4599294B2 (ja) | 2010-12-15 |
KR20060003344A (ko) | 2006-01-10 |
EP1619227A1 (en) | 2006-01-25 |
CN100368497C (zh) | 2008-02-13 |
EP1619227B1 (en) | 2014-05-07 |
CN1774483A (zh) | 2006-05-17 |
US20060144515A1 (en) | 2006-07-06 |
EP1619227A4 (en) | 2006-08-02 |
US7909959B2 (en) | 2011-03-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2004092292A1 (ja) | 被着体の剥離方法 | |
CN110023439B (zh) | 双面粘合带 | |
TWI279316B (en) | Glass lamination process | |
JPH0561103B2 (ja) | ||
US10899947B2 (en) | Method for plasma-initiated adhesive bonding | |
CN111117497A (zh) | 一种双组份丙烯酸酯结构胶及其制备方法 | |
EP3360903B1 (en) | Poly(vinyl acetal) resin composition, adhesive sheet, interlaminar filling material for touch panel, and laminate | |
WO2007108506A1 (ja) | 合わせガラス用中間膜、それを用いた合わせガラス及びその製造方法 | |
CN108473830A (zh) | 粘接性树脂层以及粘接性树脂膜 | |
KR20110116976A (ko) | 필름 및 점접착 시트 | |
TW201439175A (zh) | 過氧化氫用於聚(乙烯縮丁醛)作爲反應性擠出添加劑 | |
TWI283637B (en) | Resin composition and adhesive agent, laminates using it | |
KR20070073832A (ko) | 프라이머없이 결합하는 방법 | |
JP5228423B2 (ja) | 硬化性樹脂組成物ならびにこれを用いた透明積層体およびその製造方法 | |
JP5376954B2 (ja) | 太陽電池モジュール、積層体及び太陽電池モジュールの製造方法 | |
WO2004109811A1 (ja) | 太陽電池モジュール用充填材層およびこれを用いた太陽電池モジュール | |
JP2003146710A (ja) | 合わせガラス用中間膜及び合わせガラス並びに合わせガラスの製造方法 | |
KR101348675B1 (ko) | 내구성 및 자외선 차단능이 우수한 수지접합유리 | |
JP5943659B2 (ja) | ガラス積層用仮固定接着剤組成物及び該組成物を用いる板ガラスの加工方法 | |
JP3622821B2 (ja) | 積層体の製造方法 | |
WO2011043169A1 (ja) | 合わせガラスの製造方法 | |
KR100541390B1 (ko) | 이형성을 가진 점착성 실리콘 고무 | |
JPH06220245A (ja) | ポリウレタン発泡複合体の剥離方法 | |
JPH11181382A (ja) | タッチパネル一体型表示装置用接着剤組成物及び接着剤フィルム並びにタッチパネル一体型表示装置及びその製造方法 | |
JPH0526802B2 (ja) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2005505418 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020057019376 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004810024X Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004727372 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020057019376 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2004727372 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2006144515 Country of ref document: US Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 10553177 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 10553177 Country of ref document: US |