WO2004036569A1 - 情報記録媒体およびその製造方法、並びに光学情報記録再生装置 - Google Patents
情報記録媒体およびその製造方法、並びに光学情報記録再生装置 Download PDFInfo
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- WO2004036569A1 WO2004036569A1 PCT/JP2003/011172 JP0311172W WO2004036569A1 WO 2004036569 A1 WO2004036569 A1 WO 2004036569A1 JP 0311172 W JP0311172 W JP 0311172W WO 2004036569 A1 WO2004036569 A1 WO 2004036569A1
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- titanium oxide
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/2403—Layers; Shape, structure or physical properties thereof
- G11B7/24035—Recording layers
- G11B7/24038—Multiple laminated recording layers
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
- G11B7/266—Sputtering or spin-coating layers
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24302—Metals or metalloids
- G11B2007/24304—Metals or metalloids group 2 or 12 elements (e.g. Be, Ca, Mg, Zn, Cd)
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24318—Non-metallic elements
- G11B2007/2432—Oxygen
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
- G11B7/0045—Recording
- G11B7/00454—Recording involving phase-change effects
Definitions
- the present invention relates to an information recording medium, a method for manufacturing the same, and an optical information recording / reproducing apparatus.
- This information recording medium has a recording layer 101 a to 101 d using a urethane-urea copolymer which is a photon mode recording material, a PVA (polyvinyl alcohol) film on a glass substrate 104.
- An intermediate layer made of a polymethyl methacrylate (PMMA) film is alternately laminated with 102 a to 102 c.
- a laser beam 108 is condensed on a desired recording layer by an objective lens 106 (a convergent beam 10 ⁇ is irradiated). ) Allows information to be recorded.
- the laser beam 108 used here is a pulse laser beam having a pulse width of about 100 femtoseconds and a very high peak power. By condensing such a pulsed laser beam on the recording layer 101a to 101d, the recording layer 101a to 101 can be used by utilizing two-photon absorption, which is one of the nonlinear absorption phenomena. Information can be recorded in d.
- the two-photon absorption is high in the part (focus point) where the power density of the convergent light is high.
- a phenomenon occurs in which light having half the wavelength of the actually irradiated light is irradiated, and the information bit 105 is written.
- signal reproduction can be performed.
- this information recording medium since a plurality of recording layers are laminated in the optical axis direction (z-axis direction) of the objective lens, three-dimensional information can be recorded, and the recording capacity is increased.
- the conventional information recording medium has a problem that the recording sensitivity of the recording layer is not good. Therefore, when writing once to form one information bit with one pulse, it is necessary to use a femtosecond laser with a very large peak power (about 1 OO kW) as the light source. There was a problem that the structure of this was complicated. When a light source with a lower peak power is used, it is necessary to repeatedly record the same place many times (for example, several tens to several thousand times) (accumulation recording is possible because a photon mode recording material is used). The problem that it becomes slow occurred. Disclosure of the invention
- An information recording medium is an information recording medium including a recording unit capable of recording three-dimensional information, wherein the recording unit includes at least one recording layer, and the recording layer includes titanium oxide. It is characterized by the following.
- the method for manufacturing an information recording medium includes a recording unit capable of recording three-dimensional information, the recording unit including at least one recording layer, and the recording layer including titanium oxide.
- a method of manufacturing characterized by including a step of forming the recording layer by applying a paint containing titanium oxide.
- the optical information recording / reproducing device of the present invention is capable of recording three-dimensional information.
- An optical information recording / reproducing apparatus that includes a recording unit, wherein the recording unit includes at least one recording layer, and wherein the recording layer records and reproduces information on and from an information recording medium containing titanium oxide.
- An optical information recording / reproducing apparatus which reproduces the information using a change in an optical constant.
- FIG. 1 is an explanatory diagram showing a cross-sectional configuration of an information recording medium and a state in which information is recorded and reproduced in a first embodiment of the present invention.
- FIGS. 2A and 2B are diagrams showing the relationship between the thickness of the recording layer of the information recording medium and the reflectance according to the first embodiment of the present invention.
- 3A to 3D are cross-sectional views of the information recording medium according to Embodiment 1 of the present invention in respective manufacturing steps.
- FIG. 4 is a schematic configuration diagram illustrating an optical head of the optical information recording / reproducing apparatus according to the first embodiment of the present invention.
- FIG. 5A is an explanatory diagram illustrating a cross-sectional configuration of an information recording medium and a state of recording and reproducing information in Embodiment 2 of the present invention.
- FIG. 5B is a diagram illustrating recording of the information recording medium illustrated in FIG. 5A. It is an enlarged view of a layer.
- FIG. 6 is a diagram showing the relationship between the thickness of the recording layer of the information recording medium and the reflectance according to Embodiment 2 of the present invention.
- FIG. 7A is an explanatory diagram showing a cross-sectional configuration of an information recording medium and a state in which information is recorded and reproduced in Embodiment 3 of the present invention.
- FIG. 3 is an enlarged view of a recording layer of the information recording medium shown in FIG.
- FIG. 8 is a diagram showing a relationship between an energy one threshold and a peak power threshold and a pulse width of laser light at the time of 1-bit recording in the information recording medium of the embodiment of the present invention.
- FIG. 9 is an explanatory diagram showing a cross-sectional configuration of a conventional information recording medium and a state of recording / reproducing a signal.
- the recording layer contains titanium oxide (T i ⁇ 2 ) that changes its structure by absorbing a predetermined light, a laser having a very high peak power as in the related art is used. One pulse can form one information bit even if it is not light. Therefore, according to the present embodiment, it is possible to provide an information recording medium capable of performing high-speed recording with high sensitivity.
- the titanium oxide may be at least one of an amorphous form and a crystalline form, and the crystalline form is selected from the group consisting of an anatase type, a brookite type, and a rutile type. At least one selected may be used. In particular, it is preferable that the titanium oxide is at least one selected from the group consisting of an anazygase type and a wurtzite type, which is stable, has high sensitivity, and is capable of changing the structure to the rutile type at a high speed. .
- the recording layer preferably consists essentially of titanium oxide emissions (T I_ ⁇ 2).
- the recording layer is substantially formed of only titanium oxide, for example, the recording layer contains titanium oxide and a low-refractive-index material (resin, inorganic material, etc.) having a lower refractive index than titanium oxide. Since the reflectivity is higher and the read light amount is larger than that of the medium, the quality of the reproduced signal is good.
- the recording layer is substantially made of oxide.
- tan means that the recording layer is formed only of titanium oxide except for impurity substances that were unintentionally mixed in during the formation of the recording layer. Specifically, for example, it is preferable that the recording layer contains 9 O wt% or more of titanium oxide.
- the recording layer preferably contains titanium oxide and a low-refractive-index material having a smaller refractive index than titanium oxide. This is because the reflectance can be reduced to a desired value by controlling the content of titanium oxide contained in the recording layer. If the reflectivity can be reduced to a desired value, the number of recording layers is large (for example, including 10 to 50 recording layers). The amount of light entering each recording layer can be close to each other.
- the recording layer preferably contains titanium oxide in an amount of 5 wt% or more and less than 100 wt%.
- the recording sensitivity can be improved to a practical level.
- the titanium oxide is granular, and the average particle size of the titanium oxide is preferably shorter than the wavelength of the recording light and the wavelength of the reproducing light. This is because light loss due to diffraction loss of recording light and reproduction light due to titanium oxide can be suppressed. Further, the average particle size of the titanium oxide is preferably shorter than 1 Z 4 of the wavelength of the recording light and the wavelength of the reproducing light. This is because the scattering loss in addition to the diffraction loss can be suppressed, so that the optical loss of the recording light and the reproduction light can be further reduced. In this case, a case where a part of the fine particles are aggregated and there are particles (agglomerates) whose apparent particle diameter is longer than the wavelength of the recording light and the wavelength of the reproducing light is included.
- the apparent particle diameter is preferably shorter than the wavelength of the recording light and the wavelength of the reproducing light.
- the low refractive index material is a resin
- the recording layer can be easily formed, and the sensitivity of recording and reproduction can be increased by the heat insulating effect of the resin.
- the low refractive index material is an inorganic material
- the stability of the recording layer is preferably increased. This is because the anatase-type or brookite-type titanium oxide has a photocatalytic effect and may decompose organic materials by irradiation with ultraviolet rays, but inorganic materials do not have such a problem. .
- the information recording medium of the present embodiment includes a plurality of recording layers, and the recording unit further includes a plurality of intermediate layers substantially transparent to recording light and reproduction light. Are alternately stacked to realize a multilayer structure.
- the information recording medium of the present embodiment preferably further includes a protective layer substantially transparent to recording light and reproduction light, and the protective layer is preferably disposed on the light incident side of the recording unit. . This is because the recording section can be prevented from being scratched or dusted.
- the information recording medium of the present embodiment further includes a protective layer substantially transparent to recording light and reproduction light, and the protective layer is disposed on the light incident side of the recording unit and included in the recording layer. It is preferable to use the same material as the low refractive index material used.
- the intermediate layer is preferably made of the same material as the above low refractive index material. If the intermediate layer and the protective layer are formed from the same material as the low refractive index material included in the recording layer, for example, problems due to chemical reactions such as erosion do not occur, and the intermediate layer and the recording layer, and the protective layer and the recording layer This is because good boundaries can be formed for the layers.
- the same material means the same kind of substance. For example, even when the molecular weight is different due to a difference in the degree of polymerization, the same material is used.
- the same material is used in the information recording medium of the present embodiment.
- information is recorded on a part of the recording layer, the wavelength of light for reproducing the recorded information is ⁇ , and the refraction of the portion of the recording layer where the information is recorded is
- the refractive index is ⁇ ′
- the refractive index of the portion of the recording layer where the above information is not recorded is ⁇
- the thickness L of the recording layer is ⁇ / (2n) ⁇ L ⁇ 3 ⁇ / ( 4 ⁇ ′) or A / n ⁇ L ⁇ 5A / (4 ⁇ ′). This is because if the thickness L of the recording layer satisfies the above relationship, the contrast or the modulation factor of the reflectance is large, and the quality of the reproduced signal is improved.
- the information recording medium of the present invention can be manufactured easily and at low cost.
- the method of manufacturing an information recording medium according to the present embodiment further includes a step of forming an intermediate layer by applying a paint made of a material substantially transparent to recording light and reproduction light,
- the step of forming the intermediate layer and the step of forming the intermediate layer can be repeated in a predetermined order and periodically by a predetermined number. According to this method, a multi-layer information recording medium having a plurality of recording layers and intermediate layers can be easily and at low cost.
- optical information recording / reproducing apparatus of the present embodiment information can be recorded and reproduced on the information recording medium of the present invention.
- the light source that emits the recording light is a pulse laser light source, and the pulse width is preferably 1 picosecond to 5 nanoseconds. Further, the peak power of the light source that emits the recording light is preferably 2 W or more and 300 W or less. This is because one information bit can be formed with one pulse on the information recording medium of the present embodiment.
- information bits are three-dimensionally recorded on the recording portion of the information recording medium in an order that does not pass through the information pits recorded on the recording portion. For example, it is preferable to sequentially form information bits from a position farther away from the objective lens in the recording unit toward a position closer to the objective lens. By forming information bits in such an order, stray light such as scattered light and unnecessary diffracted light due to the information bits can be reduced.
- the light source that emits the recording light and the light source that emits the reproduction light are common. This is because the light source becomes one and the configuration of the optical information recording / reproducing apparatus can be simplified.
- the wavelength of the light source that emits the reproduction light is preferably from 0.388 m to 0.413 m.
- the structural change of titanium oxide used when recording information on an information recording medium using the optical information recording / reproducing apparatus of the present embodiment may be a change from an anatase type or butulkite type to a rutile type. preferable. It may be a change from amorphous to an anazygous, butulkite or rutile type.
- Embodiment 1 An information recording medium and a method of manufacturing the same, and an optical information recording / reproducing apparatus according to Embodiment 1 of the present invention will be described with reference to FIGS.
- FIG. 1 shows a cross-sectional configuration of an information recording medium according to the present embodiment and a state in which information is recorded and reproduced.
- 2A and 2B show the relationship between the thickness of the recording layer of the information recording medium of the present embodiment and the reflectance.
- FIG. 3 shows sectional views of the information recording medium of the present embodiment in respective manufacturing steps.
- FIG. 4 is a schematic configuration of an optical head of the optical information recording / reproducing apparatus according to the present embodiment. Is shown.
- the recording unit 3 includes a plurality of recording layers 1a to 1f and a plurality of intermediate layers 2a to 2e, and the recording layers and the intermediate layers are alternately stacked. That is, the recording section 3 includes, from the substrate 9 side, a recording layer 1a, an intermediate layer 2a, a recording layer 1b, ..., a recording layer 1e, an intermediate layer 2e, and a recording layer 1f. The layers are stacked in this order.
- the information recording medium of the present embodiment can record information in the thickness direction in addition to recording of planar information by including a plurality of recording layers in the recording unit 3.
- the recording layer 1 will be referred to as an arbitrary one of the recording layers la to lf
- the intermediate layer 2 will be referred to as an arbitrary one of the intermediate layers 2a to 2e.
- the protective layer 4 is on the light incident side when recording and reproducing information.
- a laser beam is condensed by the objective lens 6 on any of the recording layers 1 a to 1 f (convergent light 7) to form information bits 5.
- the laser beam 8 is focused on the desired recording layers 1a to 1f by the objective lens 6 (convergent light 7), and the information is reproduced using the light reflected by the information bits 5.
- the information recording medium of the present embodiment is characterized in that the recording layer 1 contains a titanium oxide (T I_ ⁇ 2).
- T I_ ⁇ 2 a titanium oxide
- the present inventors have found that titanium oxide changes its structure by irradiating a laser beam having a relatively low power, and that information recording and reading are performed by utilizing changes in optical constants accompanying the change in structure. The medium was obtained.
- the recording layer 1 is formed substantially only of titanium oxide (T i 0 2), for example, a small low-refractive index than the titanium oxide recording layer is a titanium oxide It has higher input power than the information recording medium (Embodiment 2) described later formed using a refractive index material (resin, inorganic material, etc.). Light scattering loss or diffraction loss is small and reflectivity is high. That is, the information recording medium of the present embodiment has a large read light amount (high light use efficiency).
- the second embodiment is superior to the second embodiment in that the quality of the reproduced signal is good.
- the phrase “the recording layer is substantially made of titanium oxide” means that the recording layer is made of only titanium oxide except for impurities that are unintentionally mixed in during the formation of the recording layer. I do.
- the recording layer contains 90 wt% or more of titanium oxide. Titanium oxide is at least one of amorphous and crystalline forms, and the crystalline form may be at least one selected from the group consisting of anatase type, prucite type, and rutile type.
- the substrate 9 may be made of, for example, polycarbonate, PMMA, norpolene-based resin (for example, “ARTON” (manufactured by JSR Corporation)), or cycloolefin resin (for example, “ZONEX” (manufactured by Nippon Zeon Co., Ltd.)) Can be formed.
- the intermediate layer 2 is not particularly limited as long as it is substantially transparent to recording light and reproduction light.
- the intermediate layer 2 may be made of PMMA, a photopolymer resin, an ultraviolet curing resin, or polyester. Can be formed.
- the material of the protective layer 4 is not particularly limited as long as it is substantially transparent to the recording light and the reproduction light.
- the protective layer 4 can be formed of polycarbonate, PMMA, photopolymer resin, ultraviolet curable resin, polyester, or the like. . By providing the protective layer 4, the recording section 3 can be protected from scratches, dust, and the like.
- the above-mentioned intermediate layer 2 and protective layer 4 are substantially transparent to the recording light and the reproduction light, which means that the recording light and the reproduction light are transmitted with little absorption except for scattering components.
- the absorption rate per layer of the recording layer is preferably 1% or less, More preferably, it is 0.1% or less.
- the protective layer 4 is formed from substantially the same material as the intermediate layer 2.
- the same material means the same kind of substance. For example, even when the molecular weight is different due to a difference in the degree of polymerization, the same material is used.
- the thickness of the substrate 9 is, for example, 1.1 mm
- the thickness of the recording layers 1a to lf is, for example, 1 or less, respectively
- the intermediate layers 2a to 2e are, respectively
- the thickness of each of the protective layers 4 is, for example, about 3 m to 5 m
- the thickness of the protective layer 4 is, for example, about 100 m.
- a track groove for track support is formed in all layers or any layer.
- the recording layer 1 When the recording layer 1 is irradiated with light having a wavelength shorter than the absorption edge wavelength (wavelength at which light absorption starts) of the titanium oxide contained in the recording layer 1, the titanium oxide absorbs the light.
- the temperature of the recording layer reaches a predetermined temperature due to the heat generated by the light absorption, the structure of the titanium oxide changes, and the information bit 5 is formed on the recording layer 1 by the change of the optical constant accompanying the structure change.
- amorphous titanium oxide changes to anatase-type or brookite-type titanium oxide, and when it reaches about 700 ° C, it becomes ana- or titanium-type. It changes to rutile type titanium oxide via lucite type.
- the structural change from amorphous to the anatase type or wurtzite type can be performed with a relatively small laser power, and the structural change from the anatase type or wurtzite type to the rutile type can be performed with a larger laser power than the above laser power. I can do it.
- the structural change from rutile to amorphous, anatase, and brookite is possible, but it is not possible to change directly from rutile to anatase or brookite.
- the rutile-type titanium oxide is melted (at 180 ° C or higher) to make it amorphous, and then the structure is changed to the anazygose type and the brookite type.
- the laser beam 8 needs to have a higher laser power.
- the recording layer 1 undergoes a large refractive index change ⁇ n due to the above structural change.
- the refractive index change ⁇ is 0.24. If the recording layer 1 of the information recording medium is made of, for example, anatase-type titanium oxide and the titanium oxide is irradiated with a laser beam to change the structure from the anatase type to the rutile type, the change in the refractive index is caused by this structural change.
- the resulting micro area (rutile-type titanium oxide) can be used as information bit 5, but as described above, the part of recording layer 1 where information bit 5 (rutile-type titanium oxide) and information bit 5 are not formed (anatase). (Titanium oxide), the information can be reproduced with a good SN ratio.
- the information bit 5 formed by the structural change from the anatase type or the wurtzite type to the rutile type is extremely stable because the structural change is a structural change from a metastable crystal form to a stable crystal form. Excellent long-term storage of information.
- the above-mentioned structural change occurs due to relatively low power laser light, and the speed of the structural change from a crystal form to a crystal form, that is, dislocation Speed is relatively fast. Therefore, by utilizing the change in the optical constant accompanying the above structural change, it is possible to realize a writeonce information recording medium having excellent recording stability and capable of high-speed recording and high-sensitivity recording.
- the recording layer 1 is, for example, a mixture of amorphous and crystalline forms, stable, high-sensitivity, and high-speed recording can be performed as long as the recording layer 1 contains the crystalline form (anatase type or brookite type) of titanium oxide. .
- the information bit 5 containing rutile-type titanium oxide is considered to be capable of changing its structure to amorphous, anamorphic type, or wurtzite type by irradiation with the laser beam 8.
- a possible information recording medium can also be realized.
- the non-linear phenomenon is a phenomenon in which the absorption sensitivity of the recording layer 1 is not proportional to the energy of the irradiated light. For example, if the absorption sensitivity has a threshold value, the absorption sensitivity becomes the energy of the light.
- n is 3 or more
- the recording layer 1 in the condensing part absorbs two photons at the same time. It is as if light of a wavelength (predetermined wavelength) was irradiated. If the titanium oxide contained in the recording layer 1 absorbs the light of the above-mentioned predetermined wavelength and the structure of the titanium oxide changes due to the heat generated by the light absorption, the information bit 5 is changed by the change of the optical constant accompanying the structure change. Is formed. In information recording utilizing such a non-linear phenomenon, an area where light absorption occurs can be localized in a small area such as a focused spot, so that information bits 5 can be formed at a high density.
- the absorption edge wavelength of anatase type titanium oxide or wurtzite type titanium oxide is 0.388 / im
- the wavelength is When a pulse laser of 0.76 zm or less is irradiated, information can be recorded using the two-photon absorption phenomenon.
- the absorption edge wavelength of anatase type titanium oxide or wurtzite type titanium oxide is 0.388 zm, and the absorption edge wavelength of rutile type titanium oxide is 0.413 31. Therefore, the recording layer 1 is substantially made of anatase-type titanium oxide or wurtzite-type titanium oxide, and in particular, for an information recording medium in which more information bits 5 (rutile-type titanium oxide) are formed in the three-dimensional direction, It is preferable to use light having a wavelength (for example, 0.65 m) longer than the absorption edge wavelength (0.413 lim) as the reproduction light. This is because light loss is small even when passing through a plurality of recording layers 1.
- information reproduction using a semiconductor laser having the above wavelength is not suitable for an information recording medium in which more information bits 5 are formed in the three-dimensional direction because light absorption occurs, and the number of recording layers 1 is not sufficient. It is suitable for information recording media with relatively few.
- the light has a wavelength of 0.5 or less including 0.405 ⁇ m
- a recording medium on which information is recorded at a high density for example, the information bit 5 using the two-photon absorption phenomenon can be used for a high density information bit 5
- the information on the information recording medium formed on the medium can be reproduced.
- FIG. 2 the relationship between the thickness of the recording layer (the thickness of one of the recording layers selected from the plurality of recording layers 1a to 1f (see FIG. 1)) and the reflectance is shown. The relationship will be described.
- the refractive index of the intermediate layer 2 is 1.6, and the wavelength of the emitted light is 0.65 m.
- the reflectance which is a kind of optical constant, changes with the structural change of the titanium oxide.
- Information can be reproduced by using the difference between the reflectance of the recording part (rutile titanium oxide) and the reflectance of the recording part (rutile titanium oxide).
- the reflectance of the unrecorded portion of titanium oxide, that is, the recording layer in which the information bit 5 is not formed can be used as a focus error signal in a focus support.
- the reflectances of the unrecorded portion and the recorded portion (information bit 5) in the recording layer 1 are periodically changed depending on the thickness thereof.
- the reflectivity of the unrecorded portion of the recording layer 1 is as large as 18% at the thickness (m-0.5) ⁇ / (2 ⁇ ), and the reflectivity of the recording layer (information bit 5) of the recorded portion is It is as large as 25% at the thickness (m-0.5) ⁇ / (2 ⁇ ').
- m is an integer.
- the thickness of the recording layer is determined by the reflectance of the unrecorded part (anatase type titanium oxide). If the thickness of the recording part (rutile type titanium oxide) has a large difference with the reflectance,
- the thickness of the recording layer is determined by, for example, the peak of the reflectance, It should be about ⁇ // 4 ⁇ '.
- the thickness of the recording layer is made thinner than the above-mentioned thickness, and the light reflectance per layer is reduced. It is preferable to reduce the ratio of light incident on each layer.
- the thickness of the recording layer may be set in the range of, for example, 5 nm or more and 50 nm or less according to the number of layers.
- the reflectance change periods (the periods are ⁇ (2 ⁇ ) and ⁇ / ( 2 ⁇ )) is slightly different, for example, the second and third periods, that is, the thickness region where the second chevron curve is drawn in Fig. 2 ⁇ and the third chevron curve are drawn In the thickness region, there is a thickness region where the contrast or the modulation factor becomes larger than the thickness region of the first chevron curve. Therefore, if the thickness of the recording layer is selected from the above-mentioned contrast or the thickness region where the modulation factor is increased, the quality of the reproduced signal can be improved.
- the region of the thickness L where the contrast or the modulation rate is large is ⁇ / (2n) ⁇ L ⁇ 3 ⁇ / (4 ⁇ ′) in the second chevron, and AZn in the third chevron. ⁇ L ⁇ 5 ⁇ / (4 ⁇ ′).
- L is the thickness of the recording layer
- ⁇ is the wavelength of the reproducing light
- ⁇ ' is the refractive index of the portion of the recording layer where information is recorded (recording portion)
- ⁇ is the recording layer. It is the refractive index of the part where no information is recorded (unrecorded part). Note that if the thickness of the recording layer is too large, the accuracy of the film thickness deteriorates. It is desirable to be within the box.
- a substrate 9 is prepared (see FIG. 3A), and a coating containing titanium oxide is applied on the substrate 9 by using, for example, a method such as spin coating to form a recording layer 1a (FIG. 3B). See). Further, the intermediate layer 2a is formed thereon by applying a paint containing the material of the intermediate layer using a method such as spin coating (see FIG. 3C). Further, a recording layer lb, an intermediate layer 2b, a recording layer 1c,..., And a recording layer 1f are repeatedly formed thereon.
- a coating containing the material of the protective layer 4 is applied to the recording layer 1f to form the protective layer 4, or the protective layer 4 is formed on the recording layer 1f by using a film forming method or the like ( See Figure 3D).
- the intermediate layer or the recording layer is formed in excess, and the excess portion is formed.
- a part of the recording unit 3 on the light incident side may be used as the protective layer 4. That is, a layer similar to the intermediate layers 2 a to 2 e is further formed on the recording layer 1 f to form the protective layer 4, or the recording layer 1 f is formed thick and a part thereof is formed as the protective layer 4. It is also possible to make it work. By doing so, it is not necessary to form the protective layer 4 in a separate step from the recording section 3, and the protective layer 4 can be made of substantially the same material as the recording section.
- a coating containing titanium oxide for example, a suspension in which fine particles of anatase-type titanium oxide or brookite-type titanium oxide (average particle size: 5 nm to 50 nm) are dispersed in a dispersion medium such as water may be used. It can. Since the titanium oxide crystal has a crystal axis, it has polarization anisotropy with respect to the refractive index, but the recording layer 1 prepared using the above suspension in which titanium oxide fine particles are dispersed is used. In this case, since the direction of the crystal axis is random, the polarization anisotropy in the recording layer can be suppressed.
- the optical head of the optical information recording / reproducing apparatus is provided with two types of light sources 20a and 20b for reproduction and recording.
- a beam splitter 18 a, 18 b, a collimator lens 16, a focus error signal / track error signal detecting element 15, An upward mirror 12, a spherical aberration correction element 13, and an objective lens 6 are arranged.
- the light source 20a is, for example, a semiconductor laser light source for reproduction with a wavelength of 0.405 m
- the light source 2 Ob is, for example, a wavelength of 0.76; m with a pulse width of, for example, 1 picosecond. It is a semiconductor pulse laser light source for recording up to 10 nanoseconds.
- the recording light source and the reproduction light source are provided separately, but the recording light source and the reproduction light source are shared by one light source.
- a light source with a wavelength of 65 O nm is used, and pulse oscillation is performed for recording to emit a laser beam with a large peak power, and for reproduction, continuous oscillation is performed to emit a laser beam with a small peak power.
- the laser beam 22 b emitted from the light source 20 b is bent in the Y-axis direction by the beam splitter 18 a, and becomes substantially parallel light by the collimator lens 16, and becomes a diffraction-type focus Error signal Z track Transmits through the error signal detection element 15 (using the 0th-order diffracted light), and the optical path is bent in the z-axis direction by the rising mirror 12. Then, fold in the z-axis direction The bent laser light 8 passes through the spherical aberration correction element 13 and is condensed (convergent light 7) on the recording section 3 of the information recording medium 21 by the objective lens 6, as shown in FIG. Information bit 5 is formed.
- the information pits 5 are formed by using the change in the optical constant of the recording layer.
- the information pit 5 uses the change in the refractive index and the reflectance of the recording layer 1 due to the change in the structure of titanium oxide. Thus, information bit 5 is formed.
- an optical information recording / reproducing apparatus that records information on a conventional information recording medium
- a light source for writing information (recording light)
- the write energy is 25 to 1 per pulse.
- the pulse width is relatively long, for example, from 1 picosecond to 5 nanoseconds, and the beak power is compared with, for example, from 2 W to 300 W.
- Emit recording light with a pulse laser It can be used as a source.
- the structure of a semiconductor laser as a light source can be simplified. This is because a semiconductor laser having a not so high peak power is hardly damaged at the emission end face. It is not clear why information can be recorded with low power.
- information is not recorded only by two-photon absorption or multiphoton absorption. Or, it may be because the multi-photon absorption triggers a plasma generated by a strong electric field, which induces a structural change in the titanium oxide and promotes recording.
- the laser light 22a emitted from the light source 20a is The light passes through 18a and 18b, becomes almost parallel light by the collimating lens 16 and passes through the diffraction type focus error signal / track error signal detection element 15 (0th order diffracted light) Then, the optical path can be bent in the z-axis direction by the rising mirror 12. Then, the laser beam 8 bent in the z-axis direction passes through the spherical aberration correction element 13 and is condensed by the objective lens 6 on the recording section 3 of the information recording medium 21 (convergent light 7).
- the light reflected by the information bit 5 formed on the recording layer 1 is turned in the opposite direction, passes through the objective lens 6, the spherical aberration correction element 13 and the rising mirror 1 and 2 in that order, and outputs the diffraction-type focus error signal /
- the light is split into a plurality of lights by the track error signal detection element 15 (using the first-order diffracted light.
- the track error signal detection element 15 using the first-order diffracted light.
- the diffraction type focus error signal / track error signal detection element 15 In the optical path up to the beam splitter 18b, the split light is not shown.)
- the light is converged by the collimating lens 16 and further deflected in the z-axis direction by the beam splitter 18b.
- the plurality of branched lights 17 a to 17 c deflected in one z-axis direction pass through the respective pinholes 14 a to 14 c of the pinhole array 14 and the photodetectors 19 a to 19 c. Detected at 19 c.
- the pinhole array 14 having a plurality of pinholes is installed at a position substantially at the focal point of the entire branched lights 17a to 17c. It may be arranged at a position corresponding to each focal point of 7 a to l 7 c.
- the amount of light drops when the peripheral light of the branched lights 17 a to l 7 c is deleted.
- APD active photodiode
- each of the branched light beams 17a to 17c is detected by a photodetector 19a to 19c having an area smaller than that of each of the branched light beams 17a to 17c. Even if it does, the same effect can be obtained.
- the split beams 17b and 17c corresponding to the track error signal are passed through the pinholes 14b and 14 of the pinhole array 14 to split the split beams 17b and 17c.
- the split light 17a corresponding to the focus error signal is detected by the photodetectors 19b and 19c, and is not directly passed through a pinhole. You may.
- an astigmatism method can be used as the focus detection method. If the area of the photodetector 19a at this time is smaller than the cross-sectional area of the branched light 17a at the detection position, higher-order aberration components can be reduced.
- the information bits 5 are sequentially and three-dimensionally recorded in the recording unit 3 in such an order that the information bits 5 do not pass through the already recorded information bits 5.
- the above-described order is realized by forming information bits 5 in order from the recording layer (the recording layer la in FIG. 1) disposed farthest from the objective lens 6 to the nearest recording layer. It is possible.
- recording may be performed three-dimensionally in the z-axis direction, such as recording layer la, recording layer 1b, recording layer lc,.
- the spherical aberration correction element 13 uses a liquid crystal element with a variable refractive index distribution or a beam expander that combines a concave lens and a convex lens and changes the distance between the two lenses in the optical axis direction over a short period of time. it can.
- the recording order does not always have to be in the one z-axis direction when the unrecorded portion of the information bit 5 exists, as long as the convergent light 7 does not pass through the already recorded information bit 5.
- FIG. 5A shows a cross-sectional configuration of the information recording medium and a state of recording / reproducing in the present embodiment.
- FIG. 5B is an enlarged view of a recording layer of the information recording medium shown in FIG. 5A. 6 shows a relationship between the thickness of the recording layer of the information recording medium and the reflectance in the present embodiment.
- a recording section 33 and a protective layer 34 are formed on a substrate 39 in the information recording medium of the present embodiment.
- 31a to 31f are recording layers
- 32a to 32e are intermediate layers.
- the middle layer 32 is described.
- the information recording medium according to the second embodiment is different from the information recording medium according to the first embodiment in that the recording layer 31 is different from the titanium oxide 311 and the titanium oxide 311 as shown in FIG. 5B. It is a mixture with the low-refractive-index material 310 having a small refractive index, and is characterized in that the titanium oxide 311 is granular and is dispersed in the low-refractive-index material 310. Mixing titanium oxide 311 with low refractive index material 310 By controlling the content of titanium oxide 311 contained in the recording layer 31 by changing the ratio, the refractive index and the amount of change in the refractive index of the recording layer before and after recording can be controlled.
- the recording sensitivity is improved as compared with the conventional information recording medium.
- the average particle diameter of the titanium oxide 311 is smaller than 1/4 of the wavelength of the incident light (for example, 0.405 / xm), for example, the fine particles having a diameter of 5 nm to 50 nm. It is considered that the non-linear phenomenon is easily caused by the quantum size effect and the effect peculiar to fine particles that the impurity level on the fine particle surface increases and the heat conversion efficiency is improved.
- the average particle size of the titanium oxide 311 is preferably smaller than the wavelength of the incident light (recording light and reproducing light). This is to suppress light loss due to diffraction loss of recording light and reproduction light due to titanium oxide 311.
- the average particle size of the titanium oxide 311 is 14 or less of the wavelength of the incident light (recording light and reproducing light). This is because the scattering loss in addition to the diffraction loss can be suppressed, so that the optical loss of the recording light and the reproduction light can be further reduced.
- the average particle size of the titanium oxide 311 is 1/10 or less of the wavelength of the incident light (recording light and reproducing light). This is because the scattering loss can be further reduced.
- the fine particles of titanium oxide 311 are preferably contained in the recording layer in a weight ratio of 5 wt% to less than 100 wt%.
- the recording layer 31 is, for example, a thin film having a thickness of about 1 / m or less, if the recording layer 31 contains 5 wt% or more of titanium oxide 31, a practical level of recording sensitivity can be obtained in the recording layer 31. realizable.
- the low refractive index material 310 may be a resin or an inorganic material as long as it is substantially transparent to recording light and reproduction light.
- substantially transparent to recording light and reproduction light means that almost all of the recording light and reproduction light except for the scattered component are transmitted without absorption.
- the absorption rate per one recording layer is preferably 1% or less, more preferably 0.1% or less.
- the intermediate layer 32 is preferably formed of substantially the same material as the low-refractive-index material 310.
- the protective layer 34 is also formed of a material substantially the same as the low refractive index material 310.
- the cost of the information recording medium can be reduced, and problems such as chemical reaction, such as erosion, occur at the interface between the intermediate layer 32 and the recording layer 31 and the protective layer 34 and the recording layer 31. It is because it can suppress.
- the same material means the same kind of substance. For example, the same material is used even when the molecular weight is different due to a difference in the degree of polymerization.
- the low-refractive-index material 310 When a resin is used as the low-refractive-index material 310, the effect of increasing the recording and reproducing sensitivity is brought about by its heat insulating effect.
- a resin having a refractive index of about 1.5 such as PMMA, a photopolymer resin, an ultraviolet curable resin, or polyester can be used.
- the inorganic materials for example, it can be used S I_ ⁇ 2, C A_ ⁇ 2 or M g F like.
- the recording layer 3 1 (unrecorded state) contains an analog-type or brookite-type titanium oxide, Si 2 , Ca 0 2 , and M g F
- the substrate 39, the protective layer 34, and the intermediate layer 32 have the same functions as the substrate 9, the protective layer 4, and the intermediate layer 2 in the information recording medium of the first embodiment. It can be formed of the same material.
- the recording layer 31 may include, for example, 5 Owt% of fine particles of titanium oxide 311 having an average particle diameter of 5 nm to 50 nm, and 50 wt% of the low refractive index material 310.
- the information recording medium of the present embodiment as in the recording layer 1 of the information recording medium of the first embodiment, a non-linear phenomenon such as two-photon absorption is induced at the light-collecting portion of the recording layer 31, and the information is recorded on the recording layer 31.
- the contained titanium oxide 311 absorbs light of a predetermined wavelength. When the titanium oxide 311 absorbs light and reaches a predetermined temperature, a structural change occurs in the titanium oxide 311, and an information bit 35 is formed by a change in an optical constant accompanying the structural change.
- the low refractive index material 310 for example, when the low refractive index material 310 is high melting point S I_ ⁇ 2, etc., hardly varies even when subjected to recording light, but the low refractive index material 310 is a resin In this case, since the resin is easily deformed by heat, the resin is thermally deformed by receiving the recording light, and forms information bits 35 together with the titanium oxide.
- the recording of information on the information recording medium of the present embodiment is the same as that of the first embodiment, so that the recording light has a write energy of 250 pJ per pulse as in the case of the first embodiment. If it is about 10 nJ, it is preferable that the peak power is, for example, about 2 W to 300 W, and the pulse width is, for example, 1 picosecond to 5 nanoseconds.
- the thickness of the recording layer 31 (the thickness of one of the recording layers selected from the plurality of recording layers 31a to 31f (see FIG. 5A)) and the reflectivity Will be described.
- the refractive index of the intermediate layer 32 is 1.6
- the wavelength of the irradiated light is 0.65 / m.
- the dashed line in Fig. 6 indicates an anatase type titanium oxide of 50 wt% and low refraction.
- a reflectance of 6% can be obtained for the unrecorded portion and 8% for the recorded portion.
- Increasing the weight ratio of the low-refractive material in the recording layer decreases the refractive index, so that the peak value of the reflectance also decreases.
- the weight ratio of the low-refractive index material 310 is reduced to increase the reflectance. In this case, the quality of the reproduced signal is improved, but the number of recording layers is large (for example, including 10 to 50 recording layers).
- the weight of the low refractive index material 310 It is preferable to increase the ratio to reduce light loss per layer.
- each layer it is preferable to form each layer by applying a material as in the case of the first embodiment. This is because it can be manufactured easily and at low cost.
- the recording layer 31 including the fine particles of titanium oxide 311 and the low refractive material 310 for example, the fine particles of titanium oxide 311 having an average particle diameter of 5 nm to 50 nm and the low refractive material 310
- it may be formed by applying a suspension liquid (paint) dispersed in water, toluene or isopropyl alcohol (see FIG. 5).
- the optical information recording / reproducing device shown in FIG. 4 can be used. Same as in the case.
- FIG. 7A shows a cross-sectional configuration of the information recording medium according to the present embodiment and how recording / reproducing is performed
- FIG. 7B shows a recording layer of the information recording medium shown in FIG. 7A.
- a recording section 41 and a protective layer 44 are formed on a substrate 49.
- the information recording medium of the present embodiment differs from the information recording media of Embodiments 1 and 2 in that the entire recording section 41 functions as a recording layer.
- the information bits 45 are recorded on almost the same plane in the recording layer (recording section 41), and a plurality of such recording surfaces (4 la to 41f) are provided in the recording layer (recording section 41). It realizes three-dimensional information recording.
- the recording layer 41 has a structure in which fine particles of titanium oxide 411 are dispersed in a low refractive index material 410.
- the fine particles of titanium oxide 411 have the same properties and functions as the fine particles of titanium oxide 311 contained in recording layer 31 of the information recording medium described in the second embodiment.
- the content of titanium oxide 411 is preferably 0.3 wt% to 1 wt%. This is because at 0.3 wt% or more, the recording sensitivity is improved, and at 10 wt%, the scattering loss can be suppressed and the light use efficiency can be increased.
- the low-refractive-index material 410 has the same properties and functions as the low-refractive-index material 310 included in the recording layer 31 of the information recording medium of Embodiment 2, and uses the same material. Can be.
- the substrate 49 and the protective layer 44 are formed of the same material as the low-refractive-index material 410 included in the recording layer 41, material management is easy, and manufacturing can be performed at low cost.
- the recording light has a write energy of 250 ° per pulse, as in the case of the first embodiment. If it is about pJ to about 10 nJ, the peak power is preferably, for example, about 2 W to 300 W, and the pulse width is preferably, for example, 1 picosecond to 5 nanoseconds.
- the information recording medium of the present embodiment similarly to the case of the second embodiment, a paint containing fine particles of titanium oxide 411 and a low refractive index material 410 is coated on a substrate 49.
- a method of forming by applying, or a method of forming the recording layer 41 (recording portion) at a time by injection molding According to these methods, an information recording medium can be easily manufactured at low cost.
- the optical information recording and reproducing apparatus shown in FIG. 4 can be used.
- the present invention is not limited to these, and it is also possible to combine the configurations of the information recording medium and the manufacturing method thereof, and the optical information recording / reproducing apparatus of each embodiment. However, a similar effect can be obtained. Further, the information recording medium and the optical information recording / reproducing apparatus of the present invention include a rewritable type in addition to the additional type.
- an optical disc has been described as an example of an information recording medium, but application to a card-shaped, drum-shaped, or tape-shaped product is also included in the scope of the present invention.
- the objective lens and the collimating lens used in the above embodiment are named for convenience, and are the same as general lenses.
- the information recording medium of the example is an example of the information recording medium shown in FIG. 1 described in the first embodiment.
- a track groove (a groove for groove recording with a pitch of 0.32 ⁇ and a groove depth of 0.2 m) formed on the surface is formed on a substrate 9 of 1.1 mm thick polycarbonate made of polycarbonate.
- a recording layer 3 is formed by alternately forming a recording layer of 0.01 m and an intermediate layer having a thickness of 3 m by a spin coating method (the recording layer 1 a to l ⁇ , the intermediate layer 2 a to 2 e). ), And a protective layer 4 made of a poly-pylonate having a thickness of 75 m was formed.
- the recording layers l a to l ⁇ ⁇ are substantially composed of an analog-type titanium oxide, and the intermediate layers 2 a to 2 e are composed of an ultraviolet curable resin.
- the information recording medium of this example was irradiated with a pulse laser beam having a wavelength of 65 nm while varying the pulse width, and the energy threshold and peak power threshold during 1-bit recording were measured. The results are shown. As the pulse width of the pulse laser beam became longer, the peak power threshold for recording one bit on the information recording medium tended to decrease. By setting the pulse width to 1 picosecond or more, the peak power threshold could be suppressed to 300 W or less. When the pulse width was 5 nanoseconds, information bits could be formed with a peak power threshold of 2 W.
- the energy threshold required for 1-bit recording is the lowest at 250 nJ for a laser beam of 1 picosecond to 10 picoseconds, and tends to gradually increase as the pulse width becomes longer. Was seen. By setting the pulse width to 5 nanoseconds or less, the energy threshold was suppressed to 10 nJ or less.
- the recording sensitivity is improved, and even if it is not a laser beam having a very high peak power as in the prior art, one pulse is required. Can form one information bit You. Therefore, it is possible to provide an information recording medium and an optical information recording / reproducing device capable of high sensitivity and high speed recording.
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Abstract
Description
Claims
Priority Applications (3)
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EP03808873A EP1553577A4 (en) | 2002-10-16 | 2003-09-01 | INFORMATION RECORDING MEDIUM, PROCESS FOR ITS MANUFACTURE AND OPTICAL INFORMATION RECORDING AND REPRODUCTION DEVICE |
JP2004544907A JP4290650B2 (ja) | 2002-10-16 | 2003-09-01 | 情報記録媒体およびその製造方法、並びに光学情報記録再生装置 |
US10/518,144 US20060072437A1 (en) | 2002-10-16 | 2003-09-01 | Information recording process for producing the same and optical information recording and reproducing device |
Applications Claiming Priority (2)
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JP2002301601 | 2002-10-16 | ||
JP2002-301601 | 2002-10-16 |
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WO2004036569A1 true WO2004036569A1 (ja) | 2004-04-29 |
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EP (1) | EP1553577A4 (ja) |
JP (1) | JP4290650B2 (ja) |
CN (1) | CN100407314C (ja) |
WO (1) | WO2004036569A1 (ja) |
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US8238221B2 (en) | 2007-02-16 | 2012-08-07 | Sanyo Electric Co., Ltd. | Optical pickup device and recording/reproduction device |
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US20060120256A1 (en) * | 2003-02-25 | 2006-06-08 | Matsushita Electric Industrial Co., Ltd | Optical information recording carrier |
KR100707216B1 (ko) * | 2006-05-18 | 2007-04-13 | 삼성전자주식회사 | 광 기록 매체 및 데이터 저장 방법 |
CA2680371A1 (en) | 2007-03-15 | 2008-09-18 | Basf Se | Heat-sensitive coating compositions based on resorcinyl triazine derivatives |
ES2377852T3 (es) * | 2007-08-22 | 2012-04-02 | Datalase Ltd | Composición de revestimiento sensible al láser |
US8900414B2 (en) * | 2007-11-07 | 2014-12-02 | Datalase, Ltd. | Fiber products |
JP5645832B2 (ja) | 2008-10-27 | 2014-12-24 | データレース リミテッドDatalase Ltd. | 基材にマーキングするためのレーザー感受性水性組成物 |
JP2012022735A (ja) | 2010-07-13 | 2012-02-02 | Fujifilm Corp | 光情報記録媒体の記録再生方法 |
JP5406134B2 (ja) | 2010-07-13 | 2014-02-05 | 富士フイルム株式会社 | 光情報記録媒体およびその製造方法 |
JP5396343B2 (ja) | 2010-07-13 | 2014-01-22 | 富士フイルム株式会社 | 光情報記録媒体およびその製造方法 |
JP5476329B2 (ja) | 2011-03-25 | 2014-04-23 | 富士フイルム株式会社 | 光情報記録媒体 |
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- 2003-09-01 CN CN038243601A patent/CN100407314C/zh not_active Expired - Fee Related
- 2003-09-01 US US10/518,144 patent/US20060072437A1/en not_active Abandoned
- 2003-09-01 JP JP2004544907A patent/JP4290650B2/ja not_active Expired - Lifetime
- 2003-09-01 EP EP03808873A patent/EP1553577A4/en not_active Withdrawn
- 2003-09-01 WO PCT/JP2003/011172 patent/WO2004036569A1/ja not_active Application Discontinuation
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007055249A1 (ja) * | 2005-11-08 | 2007-05-18 | Matsushita Electric Industrial Co., Ltd. | 情報記録媒体及びその製造方法並びに光学情報記録再生装置 |
JPWO2007055249A1 (ja) * | 2005-11-08 | 2009-04-30 | パナソニック株式会社 | 情報記録媒体及びその製造方法並びに光学情報記録再生装置 |
US8054727B2 (en) | 2005-11-08 | 2011-11-08 | Panasonic Corporation | Information recording medium and method for manufacturing the same, and optical information recording/reproducing device |
US8238221B2 (en) | 2007-02-16 | 2012-08-07 | Sanyo Electric Co., Ltd. | Optical pickup device and recording/reproduction device |
Also Published As
Publication number | Publication date |
---|---|
JPWO2004036569A1 (ja) | 2006-02-16 |
CN100407314C (zh) | 2008-07-30 |
EP1553577A4 (en) | 2007-11-21 |
JP4290650B2 (ja) | 2009-07-08 |
CN1689091A (zh) | 2005-10-26 |
EP1553577A1 (en) | 2005-07-13 |
US20060072437A1 (en) | 2006-04-06 |
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