WO2002000032A1 - Petits fours creux contenant du chocolat souffle et leur procede de production - Google Patents
Petits fours creux contenant du chocolat souffle et leur procede de production Download PDFInfo
- Publication number
- WO2002000032A1 WO2002000032A1 PCT/JP2001/005457 JP0105457W WO0200032A1 WO 2002000032 A1 WO2002000032 A1 WO 2002000032A1 JP 0105457 W JP0105457 W JP 0105457W WO 0200032 A1 WO0200032 A1 WO 0200032A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- chocolate
- hollow
- dough
- weight
- confectionery
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/0002—Processes of manufacture not relating to composition and compounding ingredients
- A23G3/0004—Processes specially adapted for manufacture or treatment of sweetmeats or confectionery
- A23G3/0019—Shaping of liquid, paste, powder; Manufacture of moulded articles, e.g. modelling, moulding, calendering
- A23G3/0042—Moulding or shaping of cellular or expanded articles
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D13/00—Finished or partly finished bakery products
- A21D13/30—Filled, to be filled or stuffed products
- A21D13/32—Filled, to be filled or stuffed products filled or to be filled after baking, e.g. sandwiches
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
- A23G1/52—Aerated, foamed, cellular or porous products, e.g. gas expanded
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
- A23G1/54—Composite products, e.g. layered laminated, coated, filled
Definitions
- the present invention relates to a puffed chocolate-containing hollow confectionery and a method for producing the same.
- Japanese Patent Application Laid-Open No. 48-62984 discloses a method for producing foamed confectionery and an apparatus for producing the same, in which a tempered chocolate dough is stirred to remove gas into the dough. Introduced ⁇ A method is adopted in which the gas in the chocolate dough is expanded and solidified by decompression and cooling after cooling.
- Japanese Patent Publication No. 4-19821 discloses an aerated chocolate and a method for producing the same.
- a polyglycerin-condensed ricinoleate was added in an amount of 0.0 to 1.0%.
- the chocolate dough is stirred and cooled while containing gas in the dough to make the temperature 8 to U ° C lower than the melting point and the specific gravity to 1.0 or less, and then to expand under reduced pressure of 50 Torr or less. Then, it is cooled and solidified to form an aerated chocolate with an apparent specific gravity of 0.3 or less.
- WO 00/57715 employs an aerated chocolate made by adding a mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid, and a method for producing the same.
- a cereal or starchy hollow confectionery is prepared, and then a chocolate dough filling obtained by injecting an oily confectionery dough such as chocolate dough or cream dough into the hollow portion of the hollow confectionery by a hollow needle.
- Manufacturing method of hollow confectionery Is conventionally known (for example, Japanese Unexamined Patent Publication No. 6-209711). That is, a mixture of cereal raw materials such as flour, starch, seasoning raw materials, and charging water is steamed to make a steamed dough, and then the steamed dough is put into a mixer and stirred to mix air. The steamed dough with aeration is molded into a sheet, and two sheets are combined, punched and formed.
- the punched molded product is dried and then treated with hot air to prepare an expanded hollow confection.
- chickpea dough or cream dough is injected into the hollow portion of the expanded hollow confectionery using a hollow needle having an inner diameter of 2 to 3 mm to form a hollow confectionery filled with an oily confectionery base.
- the apparent specific gravity of the expanded chocolate is a value obtained by the following formula.
- the weight of the aerated chocolate dough is the weight measured before expansion, and the volume of the expanded chocolate is the same pressure and the same temperature as when the aerated chocolate dough is expanded in the chamber. Represents the measured volume.
- the volume of the aerated chocolate dough is measured at normal pressure.
- the hollow confectionery containing expanded chocolate according to the present invention contains 0.2 to 1.5 weight of diglycerin fatty acid ester. /. 1 to 3% by weight of BOB (1,3-dibehenoy 2-oleoyl glycerol) seed agent (equivalent mixture of crystalline powder BOB and powdered sugar) or 0.5 to 1.5% by weight of crystalline powder BOB And a hollow confectionery filled with the air-containing chocolate dough, and the air-containing chocolate monolate production housed in the hollow confectionery is expanded.
- BOB 1,3-dibehenoy 2-oleoyl glycerol
- the solidified puffed chocolate is obtained by adjusting the apparent specific gravity to 0.14 to 0.30, or a mixed oil of edible fats and oils and trisaturated fatty acid glycerides containing behenic acid and BOB seeding agent is added. 33% by weight, or 0.5 to 1.5% by weight of crystalline powder BOB, and a hollow confectionery filled with the aerated chocolate dough. Expanding the pneumatic chocolate monolate dough contained in the hollow confectionery It is characterized by being obtained by adjusting the 0.14 to 0.30 the apparent specific gravity of the expanded chocolate obtained solidify.
- the above-mentioned expanded chocolate-containing hollow confection has the following different steps,
- the hollow confectionery filled with the aerated chocolate dough is treated under reduced pressure conditions of 6000 to 12000 Pa, and the expanded aerated chocolate dough in the hollow confection is expanded and cooled to obtain the expanded chocolate. Adjusting the apparent specific gravity of the rate to 0.14 to 0.30, and at the same time, adjusting the filling rate of the expanded chocolate rate in the hollow part of the hollow confectionery to 80 to 100%
- the hollow confectionery filled with the aerated chocolate dough is treated under a reduced pressure condition of 6000 to 12000 Pa, and the aerated chocolate dough in the hollow confection is expanded and cooled to expand the chocolate. Adjusting the apparent specific gravity of the chocolate to 0.14 to 0.30, and at the same time, setting the filling rate of the expanded chocolate in the hollow portion of the hollow confectionery to 80 to 100%.
- the hollow confectionery filled with the aerated chocolate dough is treated under reduced pressure of 6000 to 12000 Pa, and the aerated chocolate dough in the hollow confection is expanded and cooled to obtain the expanded chocolate. Adjusting the apparent specific gravity of the chocolate to 0.14 to 0.30, and at the same time, setting the filling rate of the expanded chocolate in the hollow portion of the hollow confectionery to 80 to 100%.
- the hollow confectionery filled with the aerated chocolate dough is treated under reduced pressure conditions of 6000 to 12000 Pa to expand and cool the aerated chocolate dough in the hollow confectionery.
- the hollow confectionery filled with the aerated chocolate dough is treated under reduced pressure conditions of 6000 to 12000 Pa, and the aerated chocolate dough in the hollow confection is expanded and cooled to thereby expand the chocolate confectionery. Adjusting the apparent specific gravity of the chocolate to 0.14 to 0.30, and at the same time, setting the filling rate of the expanded chocolate in the hollow portion of the hollow confectionery to 80 to 100%.
- Examples of the diglycerin fatty acid ester used in the present invention include diglycerin monostearate and diglycerin monopalmitate, each of which can be used alone or in combination.
- the amount of the diglycerin fatty acid ester is preferably 0.2 to 1.5% by weight. This is because if the amount of diglycerin fatty acid ester is less than 0.2% by weight, the effect of aerating is insufficient, while if it exceeds 1.5% by weight, the inherent taste of these emulsifiers is felt. It is not desirable on taste.
- a mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid is heated to melt the crystals, and then cooled to remove behenic acid-containing oil.
- This is a process for producing an aerated chocolate, characterized by adding a pre-saturated fatty acid glyceride to a chocolate dough and whipping it. It is preferable to add the trisaturated fatty acid glyceride so as to be in the range of 0.3 to 5% by weight in the final chocolate dough.
- the addition amount is larger than this, the melting point of the fat or oil becomes too high, but whipping is performed, but the viscosity of the chocolate dough increases sharply in the middle of whipping, and solidifies in the middle of the whipping depending on the whipping temperature.
- Edible oils and fats here include, for example, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, evening primrose oil, palm oil, shea butter, monkey fat, potato oil, coconut oil, palm kernel oil And the like, and processed fats and oils which have been subjected to hardening, fractionation, transesterification and the like. These fats and oils are preferably liquid at 20 ° G. When the mixed oil of liquid fats and oils and trisaturated fatty acid glyceride containing behenic acid at 20 ° C is added to chocolate dough and whipped, the trisaturated fatty acid glycerides containing behenic acid are in a crystalline state.
- the trisaturated fatty acid glyceride containing behenic acid can be obtained, for example, by adding fats and oils containing erucic acid to an iodine value of usually 1 or less and a melting point of 60 ° G or more by hydrogenation.
- An oil containing 30% by weight or more of erucic acid includes, for example, rapeseed oil having high erucic acid.
- the edible oil and fat used in the present invention and the trisaturated fatty acid glyceride containing behenic acid are preferably mixed in a weight ratio of 85:15 to 95: 5.
- the proportion of the trisaturated fatty acid glyceride is higher than this ratio, the fluidity of the mixed oil is deteriorated, so that it is not only difficult to handle but also tends to have poor whipping properties when mixed with chocolate dough. If the tri-saturated fatty acid glyceride is less than this ratio, the whipping property will be poor when mixed with chocolate dough. Furthermore, a mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid is completed. After melting completely, the temperature of the mixed oil is cooled to 30 to 45 G to precipitate crystals, and then it is better to use oils and fats prepared by cooling.
- an oil / fat composition obtained by dispersing trisaturated fatty acid glyceride crystals containing behenic acid in a low melting point oil / fat having a low melting point is obtained, which is suitable as an additive for aerated.
- trisaturated fatty acid glycerides containing behenic acid be present in a crystallized state, so that trisaturated fatty acid glycerides containing libehenic acid can be separated from other fats and oils, such as in chocolate dough. Since it does not interact with coco avatars etc., it does not worsen the dissolution of chocolate in the mouth. However, when used in a completely melted state, the specific gravity of the lichocholate, which does not have the amount of crystals required for whipping, does not decrease, or the trisaturated fatty acid glyceride containing behenic acid is used in other oils and fats.
- the crystalline powder BOB means a substance serving as a crystal nucleus of the chocolate dough.
- the compounding amount of the BOB seed agent or the crystalline powder BOB is preferably 1 to 3% by weight or 0.5 to 1.5% by weight. If the amount of the BOB seed agent is less than ⁇ % by weight or the amount of crystalline powder BOB is less than 0.5% by weight, stable crystals do not appear on the chocolate dough, while the amount of the BOB seed agent is 3% by weight. % Or the amount of crystalline powder BOB exceeding 1.5% by weight is not preferable in terms of cost and taste.
- the apparent specific gravity of the expanded chocolate which has been expanded and solidified in the hollow confectionery is set to 0.14 to 0.30, and preferably 0.14 to 0.25.
- the apparent specific gravity of the puffed chocolate rate exceeds 0.30, the taste of the entire chocolate rate becomes rich, which is not preferable in taste.
- the apparent specific gravity of the expanded chocolate is less than 0.14, the bubbles of the expanded chocolate are broken, and the gas and the expanded chocolate are separated, and the chocolate becomes a continuous phase. No expanded puffed chicken with good palatability can be obtained.
- Examples of the hollow confectionery used in the present invention include snacks, biscuits, crackers, and pleats I, whose center is partially hollow.
- This hollow confectionery can be manufactured according to the method described in W098 / 56258 and Japanese Patent Application Laid-Open No. 6-209711 introduced above. That is, two sheets of dough such as biscuit, cracker, and pleats are molded into a laminated sheet, cut and molded by cutting, and then subjected to alkali treatment, and baked with or without water washing. Can be obtained.
- steamed dough is mixed to prepare steamed dough. The steamed dough is put into a mixer, air is mixed in while stirring, and the steamed dough is shaped into a sheet.
- the stamped dough is prepared and then dried to prepare a dry stamped dough having a specific gravity of 1.18 to 1.25, which is then expanded with hot air.
- It can be manufactured by As a method for filling the hollow confectionery with the aerated chocolate dough, a method of filling with a hollow needle can be used.
- the volume of the hollow portion of the hollow confection is preferably 10 to 100 ml, and if it is less than 10 ml, the characteristic taste of the hollow confection containing the expanded chocolate according to the present invention cannot be sufficiently recognized. If it exceeds 100 ml, it is not preferable because it is too large to eat.
- the aerated chocolate dough is appropriately mixed with emulsifiers such as cocoa mass, cocoa, cocoa butter, cocoa substitute fat, sugars, lecithin, and milk powder, and the like.
- Rolls (ref ini ng) and conching (Gonch ng) are processed into chocolate dough, and in the case of diglycerin fatty acid esters, 0.2 to 1.5% by weight, and edible oils and behenic acid.
- the trisaturated fatty acid glyceride is finally added at a rate of 0.3 to 5% by weight in the chocolate dough, Thereafter, it is obtained by aeration treatment.
- the “aeration treatment” means that the chickpea is added to the chickpea with stirring under a pressure or an ordinary pressure while adding a diglycerin fatty acid ester or a mixed oil of edible fat / oil and trisaturated fatty acid glyceride containing behenic acid.
- This aeration treatment is performed in a state where, when diglycerin fatty acid ester is added, the chicken dough is melted in a temperature range of 0 to 12 ° C higher than the melting point of fats and oils contained in the dough.
- a mixed oil of edible oil and fat and trisaturated fatty acid glyceride containing behenic acid is added to chickpea dough, it is appropriately selected in a temperature range of 30 to 40 ° G.
- the aeration treatment when the diglycerin fatty acid ester is added can be performed while cooling to a temperature range higher by 0 to 3 ° C. than the melting point of fats and oils put into the dough or while keeping the temperature in the temperature range. May be carried out after the addition of the BOB seed agent or crystalline powder BOB under a temperature condition of 0 to 3 ° G higher than the melting point of the fat contained in the dough.
- the specific gravity of the dough is 0.80 to 1.00.
- the chocolate dough contains the temperature of the thiocholate raw material to which the diglycerin fatty acid ester or the mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid before the aeration treatment is added.
- the temperature in a temperature range of 0 to 12 ° C higher than the melting point of fats and oils, introduction and dispersion of gas becomes easy, Fine bubbles can be dispersed in the chocolate dough.
- the chocolate temperature to which diglycerin fatty acid ester or mixed oil of edible oil and fat and trisaturated fatty acid glyceride containing behenic acid before aeration treatment is added is 12 ° higher than the melting point of the oil and fat containing it.
- the temperature is higher than C, the emulsified state of the chocolate dough becomes unstable, so that the introduced gas cannot be sufficiently dispersed.
- a mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid is added to the chocolate dough, a BOB seed agent or crystalline powder BOB is added at a temperature range of 30 to 36 ° C. Although it is possible to do so, the specific gravity of the aerated chocolate dough is adjusted to 0.80 to 1.00 by this aeration treatment. If the temperature exceeds 36 ° G, all the fat crystals in the chocolate dough melt and blooming occurs. If the temperature is lower than 30 ° C, the viscosity increases and hinders further work.
- the specific gravity of the aerated chocolate dough containing gas in the form of microbubbles is preferably 0.80 to 1.00, and if the specific gravity exceeds 1.00, the aerated chocolate is cooled under reduced pressure in a later step. The bubbles in the chocolate become coarse, resulting in poor palatability. Furthermore, when the specific gravity of the aerated chocolate dough is less than 0.80, the viscosity increases.Therefore, when filling the hollow confectionery, it is possible to inject using a hollow needle having an inner diameter of 2-3. It will be difficult.
- the timing of adding the BOB seed agent or the crystalline powder BOB may be before or after the pneumatic treatment.
- the chocolate dough When a diglycerin fatty acid ester is added, a trisaturated fatty acid containing edible oil and behenic acid at a temperature 0 to 3 ° G higher than the melting point of the oil and fat contained in the chocolate dough.
- the glyceride mixed oil is added to the chocolate dough, the chocolate dough may be added to the chocolate dough by adding a BOB seed agent or crystalline powdered BOB in a temperature range of 30 to 36 ° G.
- the chick-collected dough can be easily expanded and cooled and solidified in the next step without subjecting the chick to a tempering treatment.
- the temperature of the chocolate dough having a BOB seed agent or crystalline powder BOB, and having a mixed oil of diglycerin fatty acid ester or edible oil and trisaturated fatty acid glyceride containing behenic acid is reduced to an oil or fat. If the melting point is less than the melting point, the crystallization of fats and oils proceeds during work, and the viscosity of the chocolate dough increases. Therefore, it is difficult to inject the dough into the hollow portion of the hollow confection through a hollow needle having an inner diameter of 2 to 3 mm. In addition, the desired expansion ratio cannot be obtained during the decompression treatment in the subsequent step, and a preferable expanded chocolate having an apparent specific gravity of 0.14 to 0.30 cannot be obtained even after cooling and solidification.
- the pressure of the hollow confectionery filled with the aerated chocolate dough containing the BOB seed agent or crystalline powder BOB is reduced to 6000 to 12000 Pa.
- the aerated chocolate dough is expanded at a high expansion rate, and then cooled and solidified until the product temperature reaches 20 to 30 ° C, thereby producing an expanded chocolate rate with an apparent specific gravity of 0.14 to 0.30.
- the filling rate is represented by the following formula.
- the volume of expanded chocolate rate is the condition under which the air-containing chocolate production place is expanded in the chamber (that is, decompression). Represents the volume measured under cooling.
- the degree of pressure reduction for expanding the aerated chocolate dough having a specific gravity of 0.80 to 1.00 is desirably 6000 to 12000 Pa.
- the pressure exceeds 12000 Pa the expansion rate of the expanded chocolate rate is extremely low, and when it is less than 6000 Pa, the chocolate rate is reduced. The bubbles are broken, and the gas and the expanded chocolate are separated, so that it is not possible to obtain an expanded chocolate having a favorable palatability in which the chocolate becomes a continuous phase.
- 20 parts by weight of cocoa mass, 20 parts by weight of whole milk powder, 40 parts by weight of sugar, 20 parts by weight of cocoa flour, and 0.4 parts by weight of lecithin are mixed as raw materials by a usual production method, and are subjected to refining and conching processing.
- 10 parts by weight of a mixture obtained by melting 9 parts by weight of cocoa butter substitute fat and 1 part by weight of diglycerin monostearate were added to 90 parts by weight of the above-mentioned chocolate dough, and a chocolate having a fat melting point of 33 ° C was added. I got the dough.
- the chocolate dough was maintained at a product temperature of 45 ° G, and a continuous cooling aeration device [(WI0MD0NHX H0WDEM A-05 type, manufactured by M0ND0MIX BV)] having a cooling function was used.
- the chocolate dough is stirred while cooling to a product temperature of 36 ° G, and nitrogen gas is introduced and dispersed. More aerated chocolate rate dough was obtained.
- the specific gravity of the aerated chocolate rate dough was 0.90.
- To 100 parts by weight of the aerated chocolate dough 3 parts by weight of a BOB seed agent were added and mixed. The viscosity of the chocolate raw material in which the BOB seed agent was dispersed was measured using a No.
- pretzel dough mainly composed of wheat flour is formed into two-ply sheets using a sheet molding machine, cut using a mouth cutter, and then subjected to pH 11.50.
- the chocolate dough is cooled to a product temperature of 28 ° C using a device [(M0 ⁇ MIX image DEN A-05 type, MONDOM IX BV)], and nitrogen gas is introduced with stirring. (2) By dispersing, an aerated chocolate dough was obtained.
- the specific gravity of the aerated chocolate dough was 0,90.
- the viscosity was measured by the same method as in Example 1 and
- 12 g of the air-containing chocolate dough was injected into the hollow part of a hollow confectionery having a hollow part volume of 48 ml produced in the same manner as in Example 1. Thereafter, the poured aerated chocolate dough was expanded and cooled and solidified in the same manner as in Example 1. In this way, an expanded chocolate-containing pretzel hollow confection having an apparent specific gravity of 0.40 was obtained.
- the filling factor in this case was 62%.
- Score 4 points There is a slight difference between the crispness of the solidified chocolate part and the texture of the hollow confectionery part
- Score 3 points There is a difference between the crispness of the solidified chocolate part and the texture of the hollow confectionery part
- Score 1 point There is a clear sense of incongruity between the crispness of the solidified chocolate and the texture of the hollow confectionery, and the solidified chocolate is too hard
- the hardness (N) of the solidified chocolate was measured using a rheometer (NRNI-2002 type) manufactured by Fudo Kagaku Co., Ltd., and was expressed as the maximum stress when the meter reading speed was 3 mm and the meter moving speed was 30 mm / min.
- a chocolate dough having a fat melting point of 33 ° C. containing cocoa butter replacer fat and diglycerin monostearate was obtained.
- the chocolate dough was cooled to a product temperature of 36 ° G using a continuous heat exchanger having a cooling function [Onleta-type B, manufactured by Sakura Seisakusho].
- 3 parts by weight of the BOB seed agent was added to 100 parts by weight of the chocolate rate dough to obtain a chocolate rate dough containing the BOB seed agent.
- the temperature of the product was maintained at 36 ° C, and nitrogen gas was introduced by stirring using a continuous cooling air-purifying device [(M0ND0N1IX HOWDEN A-05 type, manufactured by M0ND0IMIX BV)] ⁇ Included by dispersing Ki-cho chocolate dough was obtained.
- the specific gravity of this aerated chocolate production was 0.90.
- the viscosity of the chocolate raw material in which the BOB seed agent was dispersed was 15 Pa ⁇ s when measured at 35 ° G and 4 rpm using a No. 6 rotor of a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd.). Was.
- the hollow pretzel confection was prepared by modifying the method described in WO98 / 56258.
- the hollow confectionery infused with the aerated chocolate base was placed in a vacuum vessel at an ambient temperature of 10 ° C. and cooled to 23 ° G under a reduced pressure of 9310 Pa. In this way, the aerated chocolate dough was solidified by cooling while being expanded by reducing the pressure, and a hollow confection containing an expanded chocolate having an apparent specific gravity of 0.25 was obtained.
- the filling factor in this case was 100%.
- a chocolate dough containing a cocoa butter substitute fat and diglycerin monostearate and having a melting point of 33 ° G was obtained.
- the temperature of the chocolate dough was set at 45 ° C, and the temperature of the chocolate dough was set at 35 ° C using a continuous cooling aeration device having a cooling function (M0ND0MIX HOWDEN A-05, manufactured by M0ND0MIX BV).
- a continuous cooling aeration device having a cooling function M0ND0MIX HOWDEN A-05, manufactured by M0ND0MIX BV.
- aerated chocolate dough 5.6 g was injected into a hollow confection consisting of biscuit dough having a hollow volume of 40 ml using a hollow needle having an inner diameter of 2.5 mm.
- the hollow confectionery composed of Li by Bisuke' door fabric was prepared according to the method of W0 9 8/56258 described. Then, the hollow biscuit confectionery into which the above-mentioned aerated chocolate dough was injected was added. It was cooled to 22 ° C under a reduced pressure of 6650 Pa. The apparent specific gravity of the chocolate portion in the expanded chocolate-containing hollow biscuit confectionery thus obtained was 0.14, and the filling factor in this case was 100%.
- the expanded chocolate-containing hollow biscuit confectionery obtained in this example had a light texture and good palatability.
- 20 parts by weight of cacao mass, 20 parts by weight of whole milk powder, 40 parts by weight of sugar, 20 parts by weight of cocoa butter, and 0.4 parts by weight of lecithin are mixed as raw materials by a usual manufacturing method, and then subjected to refining and conching.
- a melted chocolate dough 10 parts by weight of a mixture obtained by melting 9 parts by weight of cocoa butter replacer fat and 1 part by weight of diglycerin monostearate were added to 90 parts by weight of the above chocolate dough, and the fat and oil having a melting point of 33 ° C was added.
- the chocolate rate dough is set at a product temperature of 45.
- the chocolate dough is cooled down to a product temperature of 36 ° C using a continuous cooling air aeration device [(NI0ND0IWIX H0WDEN A-05 type, manufactured by M0ND0NIIX BV)] that has a cooling function while maintaining the temperature at G While stirring, nitrogen gas was introduced and dispersed to obtain an aerated chocolate dough.
- the specific gravity of the aerated chocolate dough was 0.90.
- Alkali treatment was performed for 5 seconds in an alkaline bath containing a sodium hydroxide solution at a temperature of 80 ° G, and then baked in a mesh oven to produce hollow confectionery made of pretzel dough.
- the hollow confectionery into which the above-described aerated chocolate dough was injected was placed in a reduced-pressure container at an ambient temperature of 10 ° G, and cooled to 23 ° C under a reduced pressure of 9310 Pa. In this manner, the air-containing confectionery dough in the hollow confectionery was solidified while being expanded, thereby obtaining a hollow confectionery filled with expanded chocolate having an apparent specific gravity of 0.25.
- the filling factor in this case was 100%.
- pretzel dough mainly composed of wheat flour is formed into two-ply sheets using a sheet forming machine, cut using a roller cutter, and then subjected to a pH of 1.1.5 and a solution temperature of 80.
- a hollow confectionery consisting of pretzels and grounds was manufactured by subjecting the aluminum liquor bath containing a sodium hydroxide solution of ° G to an alkaline liquor bath for 5 seconds, followed by baking in a mesh oven.
- the above hollow confectionery into which the aerated chocolate dough described above was injected was placed in a reduced-pressure container having an atmosphere temperature of 10 ° C, and cooled to 23 ° G under a reduced pressure of 9310 Pa.
- the hollow confectionery filled with the expanded chocolate flakes having an apparent specific gravity of 0.25 was obtained by swelling the air-containing chocolate dough in the hollow confectionery while expanding the dough.
- the filling factor in this case was 100%.
- the mixed oil of edible fat and oil and trisaturated fatty acid glyceride containing behenic acid is a slightly hydrogenated oil of rapeseed oil of low erucic acid (iodine value 95) 90 parts by weight and trisaturated oil containing behenic acid Extremely hardened oil of high erucic rapeseed oil as fatty acid glyceride (iodine value 1 or less, melting point 62 ° C) 10 parts by weight of the mixed oil is completely melted at 80 ° C, and then a water tank with a water temperature of 15 ° C The oil / fat temperature is cooled down to 40 ° G to precipitate crystals of trisaturated fatty acid glycerides containing benic acid, and the mixed oil in this state is stored at 20 ° C.
- Mixed oils of edible oils and trisaturated fatty acid glycerides containing behenic acid are used in Production Examples 6 and 7 in the same manner.
- a melted chocolate dough was obtained.
- the cocoa butter was kept at 35 ° G, 90 parts by weight of a mixed oil of edible oil / fat and trisaturated fatty acid dariceride containing behenic acid was added to 90 parts by weight, and the temperature was adjusted to 35 ° C. 7 parts by weight of a fat substitute (Fuji Oil Oreo A7) was mixed.
- a chickpea dough containing a mixed oil of cocoa butter primary fat, edible fat and oil, and trisaturated fatty acid glyceride containing behenic acid was obtained.
- the cho After cooling the chocolate dough to a product temperature of 35 ° C using a continuous heat exchanger [Onlator B type @ Sakura Seisakusho] having a cooling function, the chocolate dough is cooled. Three parts by weight of the BOB seed agent was added to 100 parts by weight to obtain a chocolate dough containing the BOB seed agent. The product temperature was kept at 35 ° G, and nitrogen gas was introduced and dispersed by stirring using a continuous cooling aeration device [(M0ND0WIIX HOWDEN A-05 type, manufactured by M0ND0IX BV)]. I got chocolate dough. The specific gravity of the aerated chocolate dough was 0.90.
- the viscosity of the chocolate dough in which the BOB seed agent was dispersed was measured at 35 ° G and 4 rpm using a No. 6 rotor of a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd.). there were. 12 g of the aerated chocolate flake dough was injected into a pretzel hollow confectionery having a hollow part volume of 48 ml using a hollow needle having an inner diameter of 2.5 mm.
- the hollow pretzel confection was prepared by modifying the method described in W098 / 56258.
- the hollow confectionery infused with the aerated chocolate dough was placed in a vacuum vessel at an ambient temperature of 10 ° G, and cooled to 23 ° C under a reduced pressure of 9310 Pa. In this way, the aerated chocolate dough was solidified by cooling while being expanded by reducing the pressure and solidified by cooling to obtain an expanded specific chocolate-containing hollow confectionery having an apparent specific gravity of 0.25.
- the filling factor in this case was 100%
- a melted chocolate dough was obtained.
- the chiyo collate dough was maintained at 35 ° C, and 90 parts by weight of 3 parts by weight of a mixed oil of edible oil and trisaturated fatty acid dariceride containing behenic acid was added, and cocoa butter adjusted to 35 ° G was used instead. 7 parts by weight of a fat (Fuji Oil Oreo A7) were mixed.
- a chocolate dough containing a mixed oil of cocoa butter primary fat, edible fat and oil, and trisaturated fatty acid glyceride containing behenic acid was obtained.
- a continuous cooling aeration device [(M0ND0WI IX HOWDEN A-05 type, M0ND0M IX BV) having a cooling function for the chocolate rate dough at 35 ° G
- the temperature of the chocolate rate dough is obtained. While maintaining the temperature at 35 ° G to introduce nitrogen gas.
- an aerated chocolate dough having a specific gravity of 0.85 was obtained.
- 2.5 parts by weight of a BOB seed agent was added to 100 parts by weight of the aerated chocolate dough (1) to obtain a dispersed aerated chocolate dough.
- 5.6 g of the aerated chocolate rate production was injected into hollow confectionery made of biscuit dough having a hollow volume of 40 ml using a hollow needle having an inner diameter of 2.5 mm.
- the hollow confectionery made of biscuit dough was produced according to the method described in W098 / 56258. Thereafter, the hollow biscuit confectionery into which the aerated chocolate dough was injected was cooled to 22 ° C. under a reduced pressure of 6650 Pa. The apparent specific gravity of the chocolate part in the expanded biscuit confectionery containing expanded chiyocholate thus obtained was 0.14, and the filling factor in this case was 100%.
- the expanded chocolate-containing hollow biscuit confectionery obtained in the present production example exhibited a light texture and good palatability.
- a method for producing a relatively large hollow confectionery containing expanded chocolate having a very light texture can be established, and the hollow confectionery can be provided.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Confectionery (AREA)
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002504826A JP4922528B2 (ja) | 2000-06-27 | 2001-06-26 | 膨化チョコレート含有中空菓子及びその製法 |
BR0111901-0A BR0111901A (pt) | 2000-06-27 | 2001-06-26 | Produto de confeitaria oco que contém um chocolate expandido, e, processo para a fabricação do mesmo |
KR10-2002-7016968A KR100514337B1 (ko) | 2000-06-27 | 2001-06-26 | 팽화 초콜릿 함유 중공 과자 및 그 제조 방법 |
EP01941255A EP1297750A4 (en) | 2000-06-27 | 2001-06-26 | SMALL HOLLOW OVENS CONTAINING BLOWED CHOCOLATE AND PROCESS FOR PRODUCING THE SAME |
AU2001274625A AU2001274625A1 (en) | 2000-06-27 | 2001-06-26 | Hollow cakes containing puffed chocolate and process for producing the same |
US10/276,736 US20040022903A1 (en) | 2000-06-27 | 2002-06-26 | Hollow cakes containing puffed chocolate and process for producing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000-192370 | 2000-06-27 | ||
JP2000192370 | 2000-06-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002000032A1 true WO2002000032A1 (fr) | 2002-01-03 |
Family
ID=18691514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2001/005457 WO2002000032A1 (fr) | 2000-06-27 | 2001-06-26 | Petits fours creux contenant du chocolat souffle et leur procede de production |
Country Status (9)
Country | Link |
---|---|
US (1) | US20040022903A1 (ja) |
EP (1) | EP1297750A4 (ja) |
JP (1) | JP4922528B2 (ja) |
KR (1) | KR100514337B1 (ja) |
CN (1) | CN1543313A (ja) |
AU (1) | AU2001274625A1 (ja) |
BR (1) | BR0111901A (ja) |
TW (1) | TWI221084B (ja) |
WO (1) | WO2002000032A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1166639A1 (en) * | 1999-03-30 | 2002-01-02 | Fuji Oil Company, Ltd. | Foamed chocolate and process for producing the same |
EP1400175A4 (en) * | 2001-05-30 | 2004-08-25 | Meiji Seika Kaisha | LAYERED FAT BASE CAKE IN WHICH AN INGREDIENT IS INCORPORATED AND METHOD FOR PRODUCING THE SAME |
JP2008539774A (ja) * | 2005-05-20 | 2008-11-20 | ネステク ソシエテ アノニム | 多気泡入り菓子 |
JP2009060829A (ja) * | 2007-09-05 | 2009-03-26 | Fuji Oil Co Ltd | 含気泡チョコレート及びその製造法 |
WO2011049166A1 (ja) * | 2009-10-21 | 2011-04-28 | 明治製菓株式会社 | 含浸食品 |
JPWO2013018557A1 (ja) * | 2011-07-29 | 2015-03-05 | 株式会社ロッテ | 含浸チョコレート菓子 |
JP2016220692A (ja) * | 2013-12-27 | 2016-12-28 | 日清オイリオグループ株式会社 | 含水型耐熱性チョコレートの製造方法、含水型耐熱性チョコレート、含水チョコレート生地の粘度上昇抑制方法、及び含水型耐熱性チョコレート中の糖骨格形成方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2490595T3 (es) * | 2005-02-17 | 2014-09-04 | Abbott Laboratories | Administración transmucosal de composiciones de fármacos para tratar y prevenir trastornos en animales |
GB0703719D0 (en) * | 2007-02-27 | 2007-04-04 | Callebaut Barry | Composition |
KR20150008850A (ko) * | 2012-04-24 | 2015-01-23 | 가부시키가이샤 메이지 | 유지 이행을 억제한 소성 복합 과자 |
KR101852660B1 (ko) * | 2012-04-25 | 2018-04-26 | 가부시키가이샤 메이지 | 소성 복합 과자 및 그의 제조 방법 |
KR20140079272A (ko) * | 2012-12-18 | 2014-06-26 | 씨제이제일제당 (주) | 김과 곡물 시트를 이용한 김스낵 및 이의 제조방법 |
JP5650346B1 (ja) * | 2014-06-04 | 2015-01-07 | 森永製菓株式会社 | 含気チョコレート生地の製造方法及び焼成チョコレートの製造方法 |
KR101648134B1 (ko) * | 2014-08-06 | 2016-08-16 | 전주대학교 산학협력단 | 유과 제조 방법 및 이를 이용하여 제조된 유과 |
KR101679300B1 (ko) | 2014-08-11 | 2016-11-24 | 데코리아 제과 주식회사 | 데코레이션 팽화과자의 제조 방법 |
US11064712B2 (en) | 2014-10-09 | 2021-07-20 | Trade Secret Chocolates | Systems and methods for distributing and dispensing chocolate |
US10993457B2 (en) | 2014-10-09 | 2021-05-04 | Trade Secret Chocolates | Systems and methods for distributing and dispensing chocolate |
WO2016057939A2 (en) | 2014-10-09 | 2016-04-14 | Trade Secret Chocolates | Systems and methods for distributing and dispensing chocolate |
US10952454B2 (en) * | 2014-10-09 | 2021-03-23 | Trade Secret Chocolates | Systems and methods for distributing and dispensing chocolate |
US11224233B2 (en) | 2015-10-09 | 2022-01-18 | Trade Secret Chocolates | Systems and methods for distributing and dispensing chocolate |
KR101741749B1 (ko) | 2015-09-25 | 2017-05-30 | 이석원 | 초콜릿빵의 제조방법 및 이에 의해 제조된 초콜릿빵 |
BE1024568B1 (nl) * | 2016-12-08 | 2018-04-11 | The Belgian Chocolate Group Nv | Werkwijze voor het toevoegen van inert gas in een vulling van een chocoladeproduct |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63202341A (ja) * | 1987-02-19 | 1988-08-22 | Morinaga & Co Ltd | 含気チヨコレ−ト及びその製造法 |
JPH05211842A (ja) * | 1992-01-31 | 1993-08-24 | Fuji Oil Co Ltd | 起泡性チョコレート組成物 |
US5505971A (en) * | 1992-12-15 | 1996-04-09 | Meiji Seika Kaisha, Ltd. | Process for the manufacture of expanded hollow confectionery |
JPH0937716A (ja) * | 1995-08-01 | 1997-02-10 | Kao Corp | 起泡性チョコレート利用食品 |
WO2000057715A1 (en) * | 1999-03-30 | 2000-10-05 | Fuji Oil Company, Limited | Foamed chocolate and process for producing the same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61185148A (ja) * | 1985-02-13 | 1986-08-18 | 花王株式会社 | 空洞を有するクツキ−の製造法 |
ES2038123T3 (es) * | 1985-12-20 | 1993-07-16 | Morinaga & Co., Ltd. | Productos de dulceria. |
JP2894946B2 (ja) * | 1994-04-01 | 1999-05-24 | 株式会社ロッテ | プレッツェルおよびその製造方法 |
JP3614535B2 (ja) * | 1995-10-11 | 2005-01-26 | 谷沢菓機工業株式会社 | チョコレートコーティング装置 |
JP3491410B2 (ja) * | 1995-10-12 | 2004-01-26 | 不二製油株式会社 | ショートニングおよびその利用 |
IN185750B (ja) * | 1997-12-08 | 2001-04-21 | Council Scient Ind Res | |
KR100571532B1 (ko) * | 1998-10-08 | 2006-04-14 | 후지 세이유 가부시키가이샤 | 초콜릿 조성물 및 그의 용도 |
-
2001
- 2001-06-26 JP JP2002504826A patent/JP4922528B2/ja not_active Expired - Fee Related
- 2001-06-26 KR KR10-2002-7016968A patent/KR100514337B1/ko active IP Right Grant
- 2001-06-26 EP EP01941255A patent/EP1297750A4/en not_active Withdrawn
- 2001-06-26 CN CNA018118941A patent/CN1543313A/zh active Pending
- 2001-06-26 WO PCT/JP2001/005457 patent/WO2002000032A1/ja active IP Right Grant
- 2001-06-26 BR BR0111901-0A patent/BR0111901A/pt not_active IP Right Cessation
- 2001-06-26 AU AU2001274625A patent/AU2001274625A1/en not_active Abandoned
- 2001-06-27 TW TW090115653A patent/TWI221084B/zh not_active IP Right Cessation
-
2002
- 2002-06-26 US US10/276,736 patent/US20040022903A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63202341A (ja) * | 1987-02-19 | 1988-08-22 | Morinaga & Co Ltd | 含気チヨコレ−ト及びその製造法 |
JPH05211842A (ja) * | 1992-01-31 | 1993-08-24 | Fuji Oil Co Ltd | 起泡性チョコレート組成物 |
US5505971A (en) * | 1992-12-15 | 1996-04-09 | Meiji Seika Kaisha, Ltd. | Process for the manufacture of expanded hollow confectionery |
JPH0937716A (ja) * | 1995-08-01 | 1997-02-10 | Kao Corp | 起泡性チョコレート利用食品 |
WO2000057715A1 (en) * | 1999-03-30 | 2000-10-05 | Fuji Oil Company, Limited | Foamed chocolate and process for producing the same |
Non-Patent Citations (1)
Title |
---|
See also references of EP1297750A4 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1166639A1 (en) * | 1999-03-30 | 2002-01-02 | Fuji Oil Company, Ltd. | Foamed chocolate and process for producing the same |
EP1166639A4 (en) * | 1999-03-30 | 2003-06-18 | Fuji Oil Co Ltd | FOAMED CHOCOLATE AND METHOD FOR THE PRODUCTION THEREOF |
US6737100B1 (en) | 1999-03-30 | 2004-05-18 | Fuji Oil Company, Limited | Foamed chocolate and process for producing the same |
EP1400175A4 (en) * | 2001-05-30 | 2004-08-25 | Meiji Seika Kaisha | LAYERED FAT BASE CAKE IN WHICH AN INGREDIENT IS INCORPORATED AND METHOD FOR PRODUCING THE SAME |
JP2008539774A (ja) * | 2005-05-20 | 2008-11-20 | ネステク ソシエテ アノニム | 多気泡入り菓子 |
JP2009060829A (ja) * | 2007-09-05 | 2009-03-26 | Fuji Oil Co Ltd | 含気泡チョコレート及びその製造法 |
WO2011049166A1 (ja) * | 2009-10-21 | 2011-04-28 | 明治製菓株式会社 | 含浸食品 |
JPWO2013018557A1 (ja) * | 2011-07-29 | 2015-03-05 | 株式会社ロッテ | 含浸チョコレート菓子 |
JP2016220692A (ja) * | 2013-12-27 | 2016-12-28 | 日清オイリオグループ株式会社 | 含水型耐熱性チョコレートの製造方法、含水型耐熱性チョコレート、含水チョコレート生地の粘度上昇抑制方法、及び含水型耐熱性チョコレート中の糖骨格形成方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1543313A (zh) | 2004-11-03 |
KR100514337B1 (ko) | 2005-09-13 |
JP4922528B2 (ja) | 2012-04-25 |
US20040022903A1 (en) | 2004-02-05 |
EP1297750A4 (en) | 2004-03-24 |
TWI221084B (en) | 2004-09-21 |
EP1297750A1 (en) | 2003-04-02 |
AU2001274625A1 (en) | 2002-01-08 |
BR0111901A (pt) | 2004-02-25 |
KR20030010697A (ko) | 2003-02-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2002000032A1 (fr) | Petits fours creux contenant du chocolat souffle et leur procede de production | |
WO2012129080A2 (en) | Method of making a heat stable chocolate confectionery product | |
JP2001061413A (ja) | 含気チョコレート及びその製造法 | |
JP2010004806A (ja) | 焼き菓子用油脂組成物 | |
WO2013161808A1 (ja) | 油脂移行を抑制した焼成複合菓子 | |
JP3818182B2 (ja) | 含気泡チョコレート被覆菓子及びその製造法 | |
JP5297843B2 (ja) | 焼成チョコレート及びその製造方法 | |
JPWO2002076225A1 (ja) | 起泡性チョコレート類及びその製造法 | |
WO2015186270A1 (ja) | 含気チョコレート生地の製造方法及び焼成チョコレートの製造方法 | |
JP6279144B2 (ja) | 冷感付与剤、及び食品に冷感を付与する方法 | |
JP2003250448A (ja) | チョコレート菓子及びその製造方法 | |
WO2002080692A1 (fr) | Procede de production de chocolats contenant de l'eau | |
JP5908067B2 (ja) | 焼成複合菓子およびその製造方法 | |
JP2004254639A (ja) | 焼き菓子の製造方法 | |
JP2003169601A (ja) | 焼き菓子用油脂組成物 | |
JP6063717B2 (ja) | チョコレート複合食品の製造方法 | |
JPS63202341A (ja) | 含気チヨコレ−ト及びその製造法 | |
JP2011229492A (ja) | 耐熱性含気チョコレート及びその製造方法 | |
JPH0338820B2 (ja) | ||
JPS6313656B2 (ja) | ||
JP3444205B2 (ja) | チョコレート類の製造法 | |
JP3752143B2 (ja) | チョコレート被覆菓子およびその製造方法 | |
JP2006197831A (ja) | 油性食品ならびにその製造法 | |
JP2000189056A (ja) | 含水チョコレート類用油脂組成物 | |
JPH0257146A (ja) | 気泡入りチョコレート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 10276736 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020027016968 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2001941255 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 018118941 Country of ref document: CN |
|
WWP | Wipo information: published in national office |
Ref document number: 1020027016968 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2001941255 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 1020027016968 Country of ref document: KR |