WO1994025738A1 - Dichtungsanordnung für eine durchführung einer welle durch ein gehäuse sowie verfahren zu ihrem betrieb - Google Patents
Dichtungsanordnung für eine durchführung einer welle durch ein gehäuse sowie verfahren zu ihrem betrieb Download PDFInfo
- Publication number
- WO1994025738A1 WO1994025738A1 PCT/DE1994/000421 DE9400421W WO9425738A1 WO 1994025738 A1 WO1994025738 A1 WO 1994025738A1 DE 9400421 W DE9400421 W DE 9400421W WO 9425738 A1 WO9425738 A1 WO 9425738A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sealing arrangement
- shaft
- fluid
- chamber
- vapor
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/02—Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type
- F01D11/04—Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type using sealing fluid, e.g. steam
Definitions
- the invention relates to a sealing arrangement for a shaft having an axis to pass through a stationary housing which encloses an interior to which a fluid can be applied, from which the shaft emerges, with a ring surrounding the shaft and adjacent to seals along the axis on both sides and through at least one of the seals, the vapor chamber which can be acted upon by the fluid and which is open to the surroundings.
- the invention also relates to a method for operating such a sealing arrangement.
- the invention relates in particular to a sealing arrangement for use on a steam turbine in order to seal a passage of a rotating shaft from a housing of the steam turbine.
- This causes steam to flow through a seal along the shaft . emerges from the housing, collected in a vapor chamber and released into the environment.
- This vapor turns into mist due to condensation and is therefore visible on the sealing arrangement as a "vapor flag".
- Such a simple function control is particularly interesting and in many cases desirable on a steam turbine for industrial purposes, the power output of which is usually between approximately 1 MW and approximately 50 MW; In the case of such a steam turbine, the stress on the environment caused by a vane plume is generally maintained within acceptable limits.
- Sealing arrangements for the passage of shafts are known in various forms in the prior art; in particular, there is a large number of design options for the individual components of the sealing arrangements, in particular especially the seals themselves. Sealing arrangements for use on steam turbines can be found in DE 26 43 484 AI and DE 33 33 530 AI; Various design options for components of the sealing arrangements are also described in these documents.
- EP 0 463 532 A1 relates to the disposal of steam which emerges from a seal arrangement, this steam being condensed in a so-called "vapor condenser arrangement". The main focus in this document is on the design of the vapor condenser itself. This is designed in particular as a non-pressurized heat exchanger, which means that the vapor condensation takes place in it at about normal atmospheric pressure. A release of vapor into the environment does not take place, but the vapor is completely condensed.
- GB-PS 1 267 548 also relates to a sealing arrangement on a steam turbine of the type described in EP 0 463 532 AI.
- the sealing arrangement should not only be usable for the passage of a rotating shaft, in particular an output shaft of a steam turbine, but also for the passage of a valve spindle which is displaceable along its axis and is not necessarily rotatable.
- the term "shaft” is to be interpreted in the present case so that it encompasses rotatable shafts and displaceable spindles in equal measure.
- Seals for sealing arrangements of the type described are described in function and design in the book "Thermal Turbomachinery" by W. Traupel, Springer-Verlag, Berlin 1977, Vol. 1, Chap. 10. Seals in particular of the type of the labyrinth seals are described in detail; other seals, in particular stuffing box seals, in particular stuffing box seals with carbon rings, are mentioned only in passing and are disadvantageous for steam turbines in
- a sealing arrangement of the type described in the introduction always has, as already stated, a certain load of vapors in the environment which, under certain circumstances, may require special precautions for air pollution control.
- the reliability of a function check based on a vapor flag is only limited, since minor changes are difficult to detect.
- the function check must therefore essentially be limited to determining whether damage to the sealing arrangement has already occurred or not.
- the invention is therefore based on the object of specifying a sealing arrangement of the type mentioned at the outset, which both restricts the load on the environment and provides reliable diagnosis, i.e. in particular, it allows a reliable determination that damage is in the offing.
- a method for operating such a sealing arrangement is also to be specified.
- a sealing arrangement for a shaft having an axis is passed through a fixed housing which encloses an interior to which a fluid can be applied, from which the shaft emerges, with a shaft surrounding the shaft on both sides of the shaft Seals adjacent and through which one of the seals can be acted upon by the fluid vapor chamber, which is open to the environment, in which the vapor chamber is additionally connected to a suction device.
- the suction device With the suction device, it is possible to partially extract the fluid from the vapor chamber and thus to reduce the pollution of the environment;
- a suitable design and adjustment of the suction device can ensure that a well-defined, largely constant portion is sucked off from the total fluid supplied to the vapor chamber, so that fluctuations in the delivery of the fluid through the seal depend solely on the in effect the dismissed rest. So small ones
- Fluctuations in the inflow of the fluid to the vapor chamber cause large fluctuations in the outflow of the fluid into the environment, which can be detected easily and with the simplest means, in particular by just looking. In this way, a sensitive control of the inflow of the fluid to the vapor chamber, and thus a sensitive control of the sealing effect, of the sealing arrangement is possible.
- the vapor chamber is connected to the environment via a vapor tube and the suction device is connected to the vapor tube. The reaction of the suction device to a flow of the fluid in the seals and in the vapor chamber is thus kept low and the mode of operation of the seal arrangement is improved.
- a suction device is a radiator in the manner of a steam jet pump, in which the fluid with which the housing is acted on serves as a propellant and is preferably supplied from the interior of the housing.
- the sealing arrangement which has been strengthened in this way works largely independently alongside the housing and the device accommodated in the housing, which substantially supports its operational reliability.
- the suction device is preferably preceded by a control valve with which the suction effect can be adjusted.
- a sealing chamber which surrounds the shaft and is adjacent to the seals on both sides along the axis, is preferably arranged in the sealing arrangement between the vapor chamber and the fluid and can be delivered via an associated feed line.
- a barrier chamber can fulfill several functions: it can serve to provide defined thermodynamic conditions, in particular a defined pressure, in front of the vapor chamber, regardless of the conditions in the interior, in order to act largely independently of the seal leading to the vapor chamber ensure.
- the supply line belonging to the barrier chamber is advantageously connected to the interior, in particular to a region of the interior in which there is a pressure appropriate for the barrier chamber. It should be noted that there is always a pressure drop in the interior of the housing of a working steam turbine, due to the expansion of the steam along the turbine. According to the respective specification, a connection of the feed line to the inlet, outlet or to a tap of the steam turbine is possible.
- a leakage chamber which surrounds the shaft and is adjacent to the shaft on both sides of seals between the vapor chamber and the interior and from which fluid can be removed via an associated discharge line.
- This discharge line can in particular be connected to a leakage condenser in which the discharged fluid is condensed.
- This leakage condenser is preferably designed for condensing the fluid in a
- the leakage chamber can be used to form a defined th pressure gradient along the sealing arrangement, in that a predetermined pressure corresponding to the requirements is maintained in the leakage chamber.
- the flow of the fluid that reaches the vapor chamber can be influenced by adjusting the pressure in the leakage chamber. This is particularly important if the sealing arrangement is subjected to a very high pressure from the interior of the housing, which can be the case, for example, in the area of the inflow of a steam turbine.
- the sealing arrangement is particularly preferably designed for the simultaneous sealing of two bushings, each bushing having a vapor chamber connected to the suction device.
- a respective control valve is preferably located between each vapor chamber and the suction device, in order thus to enable the suction effect to be set individually for each vapor chamber; in this way, in particular, differences in the loading of the bushings from the interior can be compensated for.
- Functional differences determined in terms of production technology can also be compensated for. Larger functional differences are preferably compensated for by means of appropriate blocking and / or leakage chambers.
- a sealing arrangement of any configuration the fluid being applied to the housing and the fluid flowing into the vapor chamber through at least one of the seals, is carried out according to the invention in such a way that the fluid is sucked out of the vapor chamber except for a remainder which is discharged into the environment becomes.
- a predetermined constant proportion is expediently sucked off from the fluid that has flowed into the vapor chamber, so that the fluctuations in the flow of fluid acting on the vapor chamber are mainly communicated to the rest released into the environment, and thus to the vapor tail.
- This rest the can vary greatly in the event of changes in the sealing arrangement, simple inspection measures are accessible and offers an excellent possibility for function control. It is also limited in its quantity, so that it pollutes the environment to a small extent at most.
- the sealing arrangement of any configuration is particularly suitable for use in a case in which the fluid is a vapor, preferably water vapor. Especially in the case where the fluid is water vapor, it makes a difference
- the monitoring of the sealing arrangement which is subject to high stress is of great importance.
- the sealing arrangement according to the invention requires very little equipment and, in particular, does not require any complex apparatus for diagnostic purposes; the invention thus very much complies with the price expectations customary in connection with steam turbines for industrial purposes.
- FIG. 1 The only figure in the drawing shows a schematic representation of a steam turbine 16, which is located in the interior 5 of a housing 4.
- a steam line 21 steam is supplied to the steam turbine 16, and the steam expanded in the steam turbine 16 is discharged through an exhaust steam line 22. Due to the expansion of the steam, the steam turbine 16 sets the shaft 3 in rotation about its axis 2.
- the shaft 3 is led out of the housing 4 at two bushings 1.
- a suction line 17 is connected to each vapor tube 9 and leads to a suction device 8, namely a radiator. With this radiator 8, part of the steam is sucked out of the vapor tube 9.
- a very sensitive indicator of the condition of the bushing 1 is formed, because even a small fluctuation in the inflow of steam to the vapor chamber 7 is immediately visible as a noticeable change in the size of the vapor plume. A malfunction of the seals 6 can thus be detected early, possibly before they develop into real damage.
- a control valve 10 is included in each suction line 17 in order to be able to regulate the proportion of the vapor extracted from the vapor tube 9 with great care.
- a control valve 10 it is possible to replace the control valve 10 with a fixed throttle, for example an orifice plate, particularly when the sealing arrangement and its monitoring requirements are not too high.
- a leakage chamber 13 is integrated in the leadthrough 1, which likewise surrounds the shaft 3 and is adjacent to it by seals 6. Steam that enters the leakage chamber 13 along the shaft 3 through these seals 6 is partially discharged through an associated discharge line 14 and supplied to a leakage condenser 15.
- the vapor pressure in the leakage condenser 15 can be determined; in particular an adjustment of the inflow to the vapor chamber 7 is possible.
- the need for barrier chambers 13 and the leakage condenser 15 is not always given. In particular, if the vapor pressure in the housing 4 remains relatively low, a leakage condenser 15 can be dispensed with; if necessary, steam would then have to be removed from an optionally available leakage chamber 13 through the exhaust steam line 22.
- the left bushing 1 is connected to the housing 4 in the vicinity of the feed line 21, so that this bushing 1 is acted upon from the interior 5 with steam which is under very high pressure.
- a sealing chamber 11 surrounding the shaft 3 is provided behind a seal 6 and communicates with the exhaust line 22 via a feed line 12, and thus with an area in the interior 5 is under relatively low pressure, is connected.
- the load on the other components of the left bushing 1, namely the leakage chamber 13 and the vapor chamber 7, is reduced and at least partially matched to the load on the components of the right bushing 1, which is in the vicinity of the steam line 22 the housing 4 is connected and is accordingly loaded much less. For this reason, no barrier chamber is provided in the right bushing 1.
- This is provided in the example shown on the assumption that the steam turbine 16 is a so-called back pressure turbine from which the steam is released under a relatively high pressure.
- back pressure Steam turbines are widely used in industry. If, in another case, the pressure in the exhaust steam line 22 is not high enough, depending on the design of the steam turbine 16, steam for the radiator 8 can be removed at another location, in particular from the inlet or a tap of the steam turbine 16.
- the described sealing arrangement enables a simple function check of a shaft to be carried out and also allows a significant reduction in the load on its surroundings. It is particularly qualified for use on a steam turbine, in particular on a steam turbine for an industrial purpose with a power output between approximately 1 MW and 40 MW.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE59403257T DE59403257D1 (de) | 1993-04-27 | 1994-04-15 | Dichtungsanordnung für eine durchführung einer welle durch ein gehäuse sowie verfahren zu ihrem betrieb |
PL94311223A PL174278B1 (pl) | 1993-04-27 | 1994-04-15 | Układ uszczelniający do przeprowadzenia wału przez stałą obudowę |
RU95119847A RU2117769C1 (ru) | 1993-04-27 | 1994-04-15 | Уплотнительное устройство преимущественно паровой турбины для проводки имеющего ось вала через неподвижный корпус и способ его эксплуатации |
JP52373194A JP3573748B2 (ja) | 1993-04-27 | 1994-04-15 | ケーシングを貫通する軸の貫通部の軸封装置及びその作動方法 |
BR9406436A BR9406436A (pt) | 1993-04-27 | 1994-04-15 | Disposição de vedação para uma passagem de uma arvore atraves de uma carcaça bem como processo para sua operação |
EP94912461A EP0696336B1 (de) | 1993-04-27 | 1994-04-15 | Dichtungsanordnung für eine durchführung einer welle durch ein gehäuse sowie verfahren zu ihrem betrieb |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4313805.5 | 1993-04-27 | ||
DE4313805A DE4313805A1 (de) | 1993-04-27 | 1993-04-27 | Dichtungsanordnung für zumindest eine Durchführung einer Welle durch ein Gehäuse |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994025738A1 true WO1994025738A1 (de) | 1994-11-10 |
Family
ID=6486525
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1994/000421 WO1994025738A1 (de) | 1993-04-27 | 1994-04-15 | Dichtungsanordnung für eine durchführung einer welle durch ein gehäuse sowie verfahren zu ihrem betrieb |
Country Status (10)
Country | Link |
---|---|
US (1) | US5632492A (de) |
EP (1) | EP0696336B1 (de) |
JP (1) | JP3573748B2 (de) |
CN (1) | CN1054179C (de) |
BR (1) | BR9406436A (de) |
CZ (1) | CZ286496B6 (de) |
DE (2) | DE4313805A1 (de) |
PL (1) | PL174278B1 (de) |
RU (1) | RU2117769C1 (de) |
WO (1) | WO1994025738A1 (de) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19523713C2 (de) * | 1995-06-22 | 1997-04-24 | Mannesmann Ag | Verfahren und Vorrichtung zur Sicherung der Funktionstüchtigkeit von Gasdichtungen bei Turboverdichtern |
ATE228203T1 (de) * | 1997-09-26 | 2002-12-15 | Siemens Ag | Gehäuse für eine strömungsmaschine |
JP4095718B2 (ja) | 1998-06-04 | 2008-06-04 | 三菱重工業株式会社 | 蒸気タービン内部のリーク低減構造 |
DE19919653A1 (de) | 1999-04-29 | 2000-11-02 | Abb Alstom Power Ch Ag | Sperrdampfeinspeisung |
US6976679B2 (en) * | 2003-11-07 | 2005-12-20 | The Boeing Company | Inter-fluid seal assembly and method therefor |
EP1712816A1 (de) * | 2005-04-14 | 2006-10-18 | Siemens Aktiengesellschaft | Dichtungssystem zur Abdichtung eines Prozessgasraumes gegen einen Dichtraum |
EP1962000A1 (de) * | 2007-02-26 | 2008-08-27 | Siemens Aktiengesellschaft | Dichtung für eine Strömungsmaschine |
EP1961921A1 (de) * | 2007-02-26 | 2008-08-27 | Siemens Aktiengesellschaft | Dichtung für eine Strömungsmaschine |
DE102007037311B4 (de) | 2007-08-08 | 2009-07-09 | GMK Gesellschaft für Motoren und Kraftanlagen mbH | Wellendichtung für eine Turbine für eine ORC-Anlage, ORC-Anlage mit einer derartigen Turbinenwellendichtung und Verfahren zum Betreiben einer ORC-Anlage |
US8113764B2 (en) * | 2008-03-20 | 2012-02-14 | General Electric Company | Steam turbine and a method of determining leakage within a steam turbine |
US8123462B2 (en) * | 2008-10-15 | 2012-02-28 | General Electric Company | Pressurized sealed chamber between multiple pressurized casings of machine and related method |
WO2010074725A2 (en) | 2008-12-15 | 2010-07-01 | Flowserve Management Company | Seal leakage gas recovery system |
FR2946723B1 (fr) * | 2009-06-10 | 2011-08-05 | Snecma | Controle non destructif d'une lechette d'etancheite |
DE102011005026A1 (de) * | 2011-03-03 | 2012-09-06 | Siemens Aktiengesellschaft | Teilfugenabdichtung bei einem Gehäuse für eine Fluidmaschine |
US8888444B2 (en) * | 2011-05-16 | 2014-11-18 | General Electric Company | Steam seal system |
EP2690258A1 (de) * | 2012-07-24 | 2014-01-29 | Siemens Aktiengesellschaft | Dichtungsanordnung einer Dampfturbine wobei eine Sperrflüssigkeit und eine Wrasendampfabsaugung verwendet wird |
DE102012219520A1 (de) * | 2012-10-25 | 2014-04-30 | Siemens Aktiengesellschaft | Prozessgasverdichter-Gasturbinenstrang |
US20140119881A1 (en) * | 2012-10-31 | 2014-05-01 | General Electric Company | Apparatus for recirculating a fluid within a turbomachine and method for operating the same |
DE102014214685A1 (de) * | 2014-07-25 | 2016-01-28 | Thyssenkrupp Ag | Dichtvorrichtung zur Abdichtung einer drehbaren Welle eines Gaskompressors und/oder eines Gasexpanders in einer Anlage zur Herstellung von Salpetersäure |
EP3418502A1 (de) * | 2017-06-20 | 2018-12-26 | Siemens Aktiengesellschaft | Verfahren zur überprüfung einer strömungsmaschine |
CN111335969B (zh) * | 2020-04-01 | 2024-07-16 | 江苏核电有限公司 | 一种核电汽轮机高压缸端部漏汽处理装置及漏气处理方法 |
CN112594013B (zh) * | 2020-12-11 | 2022-03-01 | 西安交通大学 | 用于有机工质透平轴端密封及工质回收的装置及方法 |
Citations (8)
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GB158880A (en) * | 1920-02-04 | 1921-10-20 | Anders Marius Pedersen Lundega | Improvements in or relating to turbine glands |
DE451680C (de) | 1926-04-15 | 1927-11-01 | Bbc Brown Boveri & Cie | Lahyrinthstopfbuechse fuer die Wellen von Maschinen mit hoher Drehzahl |
DE576969C (de) | 1929-09-07 | 1933-05-19 | Siemens Schuckertwerke Akt Ges | Einrichtung zur Verringerung der Stopfbuechsenleckdampfverluste bei Dampfturbinen |
GB618133A (en) * | 1946-01-25 | 1949-02-16 | Goetaverken Ab | Improvements in compressors driven by turbines |
GB838092A (en) * | 1955-10-07 | 1960-06-22 | English Electric Co Ltd | Improvements in and relating to condensing steam turbines |
GB872646A (en) * | 1957-01-18 | 1961-07-12 | English Electric Co Ltd | Improvements in and relating to condensing steam turbines |
DE2643484A1 (de) | 1976-07-22 | 1978-01-26 | Turbodyne Corp | Wellendichtungseinrichtung |
DE3333530A1 (de) | 1982-09-17 | 1984-04-12 | Hitachi, Ltd., Tokyo | Vakuumrueckhalteeinrichtung |
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DE1109722B (de) * | 1959-03-21 | 1961-06-29 | Siemens Ag | Absaugeeinrichtung fuer Turbinen-kondensatoren |
CH382779A (de) * | 1959-03-21 | 1964-10-15 | Siemens Ag | Luft- oder Dampf-Absaugeeinrichtung aus Anlagen mit unterschiedlich anfallenden Luft- oder Dampfmengen |
CH449355A (de) * | 1966-12-23 | 1967-12-31 | Bbc Brown Boveri & Cie | Flüssigkeitsgesperrte Stopfbüchse |
US3604206A (en) * | 1968-07-31 | 1971-09-14 | Gen Electric | Shaft-sealing system for nuclear turbines |
CH574564A5 (de) * | 1974-08-16 | 1976-04-15 | Bbc Brown Boveri & Cie | |
CH635401A5 (de) * | 1978-08-31 | 1983-03-31 | Bbc Brown Boveri & Cie | Sperrdampfvorrichtung und verwendung desselben. |
US4193603A (en) * | 1978-12-21 | 1980-03-18 | Carrier Corporation | Sealing system for a turbomachine |
DE8708383U1 (de) * | 1986-08-20 | 1988-10-20 | Körting Hannover AG, 3000 Hannover | Dampfturbinenanlage |
DE4020587A1 (de) * | 1990-06-28 | 1992-01-02 | Siemens Ag | Wrasendampfkondensatoranordnung |
DE69204668T2 (de) * | 1992-07-10 | 1996-03-21 | Ansaldo En S P A | Verfahren zur Abdichtung des Rotors einer geothermischen Nassdampfturbine. |
-
1993
- 1993-04-27 DE DE4313805A patent/DE4313805A1/de not_active Withdrawn
-
1994
- 1994-04-15 CN CN94191910A patent/CN1054179C/zh not_active Expired - Lifetime
- 1994-04-15 DE DE59403257T patent/DE59403257D1/de not_active Expired - Lifetime
- 1994-04-15 WO PCT/DE1994/000421 patent/WO1994025738A1/de active IP Right Grant
- 1994-04-15 EP EP94912461A patent/EP0696336B1/de not_active Expired - Lifetime
- 1994-04-15 CZ CZ19952552A patent/CZ286496B6/cs not_active IP Right Cessation
- 1994-04-15 JP JP52373194A patent/JP3573748B2/ja not_active Expired - Lifetime
- 1994-04-15 BR BR9406436A patent/BR9406436A/pt not_active IP Right Cessation
- 1994-04-15 PL PL94311223A patent/PL174278B1/pl unknown
- 1994-04-15 RU RU95119847A patent/RU2117769C1/ru active
-
1995
- 1995-10-27 US US08/549,057 patent/US5632492A/en not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB158880A (en) * | 1920-02-04 | 1921-10-20 | Anders Marius Pedersen Lundega | Improvements in or relating to turbine glands |
DE451680C (de) | 1926-04-15 | 1927-11-01 | Bbc Brown Boveri & Cie | Lahyrinthstopfbuechse fuer die Wellen von Maschinen mit hoher Drehzahl |
DE576969C (de) | 1929-09-07 | 1933-05-19 | Siemens Schuckertwerke Akt Ges | Einrichtung zur Verringerung der Stopfbuechsenleckdampfverluste bei Dampfturbinen |
GB618133A (en) * | 1946-01-25 | 1949-02-16 | Goetaverken Ab | Improvements in compressors driven by turbines |
GB838092A (en) * | 1955-10-07 | 1960-06-22 | English Electric Co Ltd | Improvements in and relating to condensing steam turbines |
GB872646A (en) * | 1957-01-18 | 1961-07-12 | English Electric Co Ltd | Improvements in and relating to condensing steam turbines |
DE2643484A1 (de) | 1976-07-22 | 1978-01-26 | Turbodyne Corp | Wellendichtungseinrichtung |
DE3333530A1 (de) | 1982-09-17 | 1984-04-12 | Hitachi, Ltd., Tokyo | Vakuumrueckhalteeinrichtung |
Also Published As
Publication number | Publication date |
---|---|
EP0696336B1 (de) | 1997-07-02 |
JP3573748B2 (ja) | 2004-10-06 |
CZ286496B6 (en) | 2000-04-12 |
EP0696336A1 (de) | 1996-02-14 |
CN1121740A (zh) | 1996-05-01 |
US5632492A (en) | 1997-05-27 |
CZ255295A3 (en) | 1996-01-17 |
CN1054179C (zh) | 2000-07-05 |
BR9406436A (pt) | 1996-01-09 |
JPH08510307A (ja) | 1996-10-29 |
DE4313805A1 (de) | 1994-11-03 |
RU2117769C1 (ru) | 1998-08-20 |
PL311223A1 (en) | 1996-02-05 |
PL174278B1 (pl) | 1998-07-31 |
DE59403257D1 (de) | 1997-08-07 |
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