RU2011116997A - Полиуретановые композиции на основе форполимера для изготовления голографических сред - Google Patents

Полиуретановые композиции на основе форполимера для изготовления голографических сред Download PDF

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RU2011116997A
RU2011116997A RU2011116997/04A RU2011116997A RU2011116997A RU 2011116997 A RU2011116997 A RU 2011116997A RU 2011116997/04 A RU2011116997/04 A RU 2011116997/04A RU 2011116997 A RU2011116997 A RU 2011116997A RU 2011116997 A RU2011116997 A RU 2011116997A
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groups
polyurethane composition
composition according
prepolymers
compounds
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RU2515549C2 (ru
RU2515549C9 (ru
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Марк Штефан ВАЙЗЕР (DE)
Марк Штефан ВАЙЗЕР
Томас РЕЛЛЕ (DE)
Томас РЕЛЛЕ
Фридрих-Карл БРУДЕР (DE)
Фридрих-Карл БРУДЕР
Томас ФЭККЕ (DE)
Томас ФЭККЕ
Деннис ХЕНЕЛЬ (DE)
Деннис ХЕНЕЛЬ
Зебастиан ДЕРР (DE)
Зебастиан ДЕРР
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Байер Матириальсаейнс Аг (De)
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Abstract

1. Полиуретановая композиция, содержащая: ! A) полиизоцианатный компонент, содержащий по меньшей мере один полиуретановый форполимер с терминальными NCO-группами исключительно на основе диолов, у которого NCO-группы являются связанными с первичными остатками, ! B) полимеры, реакционноспособные по отношению к изоцианатам, ! C) соединения, содержащие группы, которые при действии актиничного излучения реагируют с этиленненасыщенными соединениями с полимеризацией (радиационно отверждаемые группы), а сами не содержат NCO-групп, ! D) стабилизаторы радикалов, ! Е) фотоинициаторы, ! F) при необходимости катализаторы, ! G) при необходимости, вспомогательные вещества и добавки. ! 2. Полиуретановая композиция по п.1, отличающаяся тем, что в А) используются NCO-функциональные форполимеры с уретановыми, аллофанатными, биуретовыми и/или амидными группами. ! 3. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров с изоцианатными группами используются уретаны, алофанаты или биуреты из алифатических соединений с изоцианатными группами и олигомерных или полимерных полиолов или полиаминов со среднечисленными молекулярными массами от 500 до 8500 г/моль. ! 4. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров с изоцианатными группами используются аллофанаты из гексаметилендиизоцианата (HDI) или триметилгексаметилендиизоцианата (TMDI) и дифункциональных простых полиэфирполиолов со среднечисленными молекулярными массами от 1000 до 8200 г/моль. ! 5. Полиуретановая композиция по п.1, отличающаяся тем, что соединения, используемые в А) в качестве форполимеров с изоцианатными группами, имеют о

Claims (11)

1. Полиуретановая композиция, содержащая:
A) полиизоцианатный компонент, содержащий по меньшей мере один полиуретановый форполимер с терминальными NCO-группами исключительно на основе диолов, у которого NCO-группы являются связанными с первичными остатками,
B) полимеры, реакционноспособные по отношению к изоцианатам,
C) соединения, содержащие группы, которые при действии актиничного излучения реагируют с этиленненасыщенными соединениями с полимеризацией (радиационно отверждаемые группы), а сами не содержат NCO-групп,
D) стабилизаторы радикалов,
Е) фотоинициаторы,
F) при необходимости катализаторы,
G) при необходимости, вспомогательные вещества и добавки.
2. Полиуретановая композиция по п.1, отличающаяся тем, что в А) используются NCO-функциональные форполимеры с уретановыми, аллофанатными, биуретовыми и/или амидными группами.
3. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров с изоцианатными группами используются уретаны, алофанаты или биуреты из алифатических соединений с изоцианатными группами и олигомерных или полимерных полиолов или полиаминов со среднечисленными молекулярными массами от 500 до 8500 г/моль.
4. Полиуретановая композиция по п.1, отличающаяся тем, что в А) в качестве форполимеров с изоцианатными группами используются аллофанаты из гексаметилендиизоцианата (HDI) или триметилгексаметилендиизоцианата (TMDI) и дифункциональных простых полиэфирполиолов со среднечисленными молекулярными массами от 1000 до 8200 г/моль.
5. Полиуретановая композиция по п.1, отличающаяся тем, что соединения, используемые в А) в качестве форполимеров с изоцианатными группами, имеют остаточное содержание свободного мономерного изоцианата менее чем 0,5 мас.%.
6. Полиуретановая композиция по п.1, отличающаяся тем, что в компоненте В) используются гомополимеры или статистические или блоксополимеры на основе этиленоксида и/или пропиленоксида, при необходимости в комбинации с тетрагидрофураном, бутиленоксидом или ε-капролактоном в качестве мономерных структурных единиц, с ОН-функциональностью от 1,5 до 6 и среднечисленной молекулярной массой от 200 до 18000 г/моль.
7. Полиуретановая композиция по п.1, отличающаяся тем, что соединения, используемые в компоненте С), имеют показатель преломления nD 20>1,55.
8. Полиуретановая композиция по одному из пп.1-7, отличающаяся тем, что в компоненте С) используются уретанакрилаты и уретанметакрилаты на основе ароматических изоцианатов и 2-гидроксиэтилакрилата, гидроксипропилакрилата, 4-гидроксибутилакрилата, полиэтиленоксидмоно(мет)акрилата, полипропиленоксидмоно(мет)акрилата, полиалкиленоксидмоно(мет)акрилата и поли(ε-капролактон)моно(мет)акрилата.
9. Способ изготовления среды для записи визуальных голограмм, при котором полиуретановая композиция по одному из пп.1-8 наносится на субстрат или в форму и подвергается отверждению.
10. Применение среды, получаемой по способу согласно п.9, в качестве оптических элементов, изображений или для воспроизведения или проецирования изображений.
11. Способ записи голограммы, при котором применяется среда по п.10.
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Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL200995A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Polyether-based polyurethane formulations for the production of holographic media
EP2342254B1 (de) * 2008-10-01 2017-09-27 Covestro Deutschland AG Medien für volumenholographische aufzeichnung basierend auf sich selbstentwickelndem polymer
IL200722A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer compositions for optical elements and visual displays
IL200996A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer formulations having a low crosslinking density
IL200997A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Special polyether-based polyurethane formulations for the production of holographic media
EP2218744A1 (de) 2009-02-12 2010-08-18 Bayer MaterialScience AG Methode zur Herstellung von holografischen Photopolymeren auf Polymerfolien
EP2218742A1 (de) 2009-02-12 2010-08-18 Bayer MaterialScience AG Photopolymerzusammensetzungen als verdruckbare Formulierungen
CN102741925B (zh) * 2009-11-03 2015-12-16 拜尔材料科学股份公司 生产全息膜的方法
PL2497085T3 (pl) * 2009-11-03 2014-07-31 Bayer Ip Gmbh Sposób wytwarzania błony holograficznej
ATE548730T1 (de) * 2009-11-03 2012-03-15 Bayer Materialscience Ag Photopolymerformulierungen mit einstellbarem mechanischem modul guv
TWI489205B (zh) * 2009-11-03 2015-06-21 Bayer Materialscience Ag 包含不同寫入共聚單體之光聚合物調配物
KR101746886B1 (ko) * 2009-11-03 2017-06-27 코베스트로 도이칠란드 아게 홀로그래픽 매체의 제조 방법
JP2012077278A (ja) * 2010-10-04 2012-04-19 Pelnox Ltd 光学材料用樹脂組成物およびその硬化物
US20140302425A1 (en) * 2012-04-30 2014-10-09 Bayer Intellectual Property Gmbh Method for producing holographic media
CN107108849B (zh) * 2014-11-24 2022-05-10 Ppg工业俄亥俄公司 用于三维打印的共反应性材料和方法
US11180604B2 (en) 2016-12-20 2021-11-23 Prc-Desoto International, Inc. Polyurethane prepolymers incorporating nonlinear short chain diols and/or soft diisocyanates compositions, and uses thereof
KR102268129B1 (ko) * 2017-10-16 2021-06-22 주식회사 엘지화학 비반응성 불소계 화합물 및 이를 포함하는 광중합성 조성물
KR102166846B1 (ko) 2017-12-11 2020-10-16 주식회사 엘지화학 포토폴리머 조성물
CA2994005A1 (fr) * 2018-02-05 2019-08-05 Hydro-Quebec Copolymeres d'unites ester et ether, leurs procedes de fabrication et leurs utilisations
KR102673184B1 (ko) * 2021-09-14 2024-06-10 주식회사 케이씨씨 감광성 수지 조성물
WO2024005141A1 (ja) * 2022-06-30 2024-01-04 三菱ケミカル株式会社 ホログラム記録媒体用組成物
CN118085183B (zh) * 2024-04-23 2024-07-05 奥提赞光晶(上海)显示技术有限公司 一种提高全息材料折射率差的方法、光致聚合物组合物以及光栅

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6088024A (ja) * 1983-10-21 1985-05-17 Mitui Toatsu Chem Inc べた付の残らない硬化性組成物
DE3677527D1 (de) 1985-11-20 1991-03-21 Mead Corp Ionische farbstoffe als initiatoren enthaltende fotosensitive materialien.
US5250391A (en) 1990-05-10 1993-10-05 Hughes Aircraft Company Photopolymer composition and its use
RU2059669C1 (ru) * 1992-03-19 1996-05-10 Альфред Станиславович Рот Способ изготовления оптических изделий
US5328805A (en) * 1992-08-28 1994-07-12 W. R. Grace & Co.-Conn. Aqueous developable photosensitive polyurethane-(meth)acrylate
US6552097B1 (en) 1993-02-10 2003-04-22 Rathor Ag Prepolymer compositions for insulating foams
JPH07330709A (ja) * 1994-06-02 1995-12-19 Nippon Kayaku Co Ltd ポリウレタン（メタ）アクリレート、それを用いた紫外線硬化型樹脂組成物及びその硬化物
JPH08239650A (ja) * 1995-03-02 1996-09-17 Asahi Glass Co Ltd シーリング材組成物
JPH10319202A (ja) * 1997-05-20 1998-12-04 Nippon Polyurethane Ind Co Ltd プラスチックレンズの製造方法
DE19814872A1 (de) 1998-04-02 1999-10-07 Basf Ag Strahlungshärtbare Zubereitungen
US20030044690A1 (en) * 2001-06-27 2003-03-06 Imation Corp. Holographic photopolymer data recording media, method of manufacture and method of holographically reading, recording and storing data
US6743552B2 (en) 2001-08-07 2004-06-01 Inphase Technologies, Inc. Process and composition for rapid mass production of holographic recording article
US6780546B2 (en) * 2001-08-30 2004-08-24 Inphase Technologies, Inc. Blue-sensitized holographic media
US6765061B2 (en) 2001-09-13 2004-07-20 Inphase Technologies, Inc. Environmentally durable, self-sealing optical articles
DE60306375T2 (de) 2002-05-29 2007-08-30 InPhase Technologies, Inc., Longmont Holographische datenspeichermedien mit einer aluminiumsalzverbindung und einer asymmetrischen acrylatverbindung
JP2005181953A (ja) * 2003-11-27 2005-07-07 Konica Minolta Medical & Graphic Inc ホログラフィック記録メディア、ホログラフィック記録方法およびホログラフィック情報メディア
JP4466141B2 (ja) * 2003-09-17 2010-05-26 コニカミノルタエムジー株式会社 ホログラフィック記録用組成物、ホログラフィック記録メディア、ホログラフィック記録方法及びホログラフィック情報メディア
US20050058911A1 (en) * 2003-09-17 2005-03-17 Konica Minolta Medical & Graphic, Inc. Holographic recording medium, holographic recording method and holographic information medium
JP4466140B2 (ja) * 2003-11-27 2010-05-26 コニカミノルタエムジー株式会社 ホログラフィック記録メディア、ホログラフィック記録方法およびホログラフィック情報メディア
JP2005181954A (ja) * 2003-11-28 2005-07-07 Konica Minolta Medical & Graphic Inc ホログラフィック記録メディア、ホログラフィック記録方法およびホログラフィック情報メディア
JP2006235386A (ja) * 2005-02-25 2006-09-07 Fuji Photo Film Co Ltd ホログラム記録材料およびこれを用いた光記録媒体
US7704643B2 (en) 2005-02-28 2010-04-27 Inphase Technologies, Inc. Holographic recording medium with control of photopolymerization and dark reactions
JP2007101743A (ja) * 2005-09-30 2007-04-19 Fujifilm Corp 光記録用組成物、並びに光記録媒体、光記録方法、及び光記録装置
JP2007279585A (ja) 2006-04-11 2007-10-25 Fujifilm Corp 感光性組成物、並びに光記録媒体、光記録方法及び光記録装置
CN101501579A (zh) * 2006-09-05 2009-08-05 三菱化学株式会社 体积全息光记录介质、体积全息记录层形成用组合物、体积全息记录材料及体积全息光记录方法
JP2010523775A (ja) * 2007-04-11 2010-07-15 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト イミノオキサジアジンジオンを含む放射線架橋性および熱架橋性のｐｕ系
WO2008125199A1 (en) * 2007-04-11 2008-10-23 Bayer Materialscience Ag Aromatic urethane acrylates having a high refractive index
EP2042576A1 (en) * 2007-09-20 2009-04-01 Agfa-Gevaert Security laminates with interlaminated transparent embossed polymer hologram.
IL200996A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer formulations having a low crosslinking density
EP2342254B1 (de) * 2008-10-01 2017-09-27 Covestro Deutschland AG Medien für volumenholographische aufzeichnung basierend auf sich selbstentwickelndem polymer
IL200995A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Polyether-based polyurethane formulations for the production of holographic media
IL200997A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Special polyether-based polyurethane formulations for the production of holographic media
EP2218743A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Prepolymerbasierte Polyurethanformulierungen zur Herstellung holographischer Filme
EP2218742A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Photopolymerzusammensetzungen als verdruckbare Formulierungen
EP2218744A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Methode zur Herstellung von holografischen Photopolymeren auf Polymerfolien
ATE548730T1 (de) * 2009-11-03 2012-03-15 Bayer Materialscience Ag Photopolymerformulierungen mit einstellbarem mechanischem modul guv
IN2012DN03890A (ru) * 2009-11-03 2015-09-04 Bayer Materialscience Ag

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