RU2005123338A - Эмульсионная полимеризация фторированных мономеров - Google Patents
Эмульсионная полимеризация фторированных мономеров Download PDFInfo
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- RU2005123338A RU2005123338A RU2005123338/04A RU2005123338A RU2005123338A RU 2005123338 A RU2005123338 A RU 2005123338A RU 2005123338/04 A RU2005123338/04 A RU 2005123338/04A RU 2005123338 A RU2005123338 A RU 2005123338A RU 2005123338 A RU2005123338 A RU 2005123338A
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
- D06M15/353—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes containing fluorine
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Claims (11)
1. Способ, состоящий в добавлении фторированного поверхностно-активного вещества с молекулярным весом по меньшей мере примерно 1000 г/моль в процессе эмульсионной полимеризации.
2. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество является перфторполиэфиром, содержащим одну или несколько гидрофильных групп.
3. Способ по п.2, отличающийся тем, что указанные гидрофильные группы включают группы карбоксильных кислот и их солей.
4. Способ по п.2, отличающийся тем, что указанный перфторполиэфир включает вещества, соответствующие формуле
Rf a-O-(CF2O)k(CF2CF2O)p(CF(CF3)CF2O)q-Ql-COOM, или
MOOC-Ql-O-(CF2O)k(CF2CF2O)p(CF(CF3)CF2O)q-Q2-COOZ
где каждая из величин k, р и q представляет собой число от 0 до 15, Rf a представляет собой перфторалкильную группу длиной от 2 до 4 атомов углерода, М и Z - независимо друг от друга представляют собой водород или катион, а Q1 и Q2 независимо друг от друга представляют собой -CF2- или -CF(CF3)-.
5. Способ по п.4, отличающийся тем, что указанный катион является одновалентным катионом.
6. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество имеет формулу
Rf a-O-(CFXCF2O)r-CFX-COOM,
где Rfa представляет собой перфторалкильную группу длиной от 2 до 4 атомов углерода, М представляет собой водород или катион, Х - атом водорода или атом фтора, а r имеет величину от 2 до 15.
7. Способ по п.1, отличающийся тем, что указанное фторсодержащее поверхностно-активное вещество включает перфторполимеры, которые содержат повторяющиеся фрагменты, получаемые из мономера с формулой
где s - это 0, 1 или 2, и t - целое число от 2 до 4, a G - остаток, содержащий одну или несколько гидрофильных групп.
8. Способ по п.7, отличающийся тем, что указанные гидрофильные группы являются неионогенными группами, анионными группами или катионными группами.
9. Способ по п.8, отличающийся тем, что указанные неионогенные группы включают -SO2F, гидроксиалкилен, гидроксиарилен или сложный эфир с формулой -COOR, где R - алкильная группа длиной от 1 до 3 атомов углерода.
10. Способ по п.1, отличающийся тем, что указанные анионные группы включают карбоксильные группы или сульфонатные группы.
11. Способ по п.1, отличающийся тем, что указанные катионные группы включают алкиламонийные группы.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/350,457 | 2003-01-24 | ||
US10/350,457 US7045571B2 (en) | 2001-05-21 | 2003-01-24 | Emulsion polymerization of fluorinated monomers |
Publications (1)
Publication Number | Publication Date |
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RU2005123338A true RU2005123338A (ru) | 2006-02-10 |
Family
ID=32823704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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RU2005123338/04A RU2005123338A (ru) | 2003-01-24 | 2003-12-05 | Эмульсионная полимеризация фторированных мономеров |
Country Status (8)
Country | Link |
---|---|
US (2) | US7045571B2 (ru) |
EP (1) | EP1622949A1 (ru) |
JP (1) | JP2006513303A (ru) |
CN (1) | CN1742027A (ru) |
AU (1) | AU2003300980A1 (ru) |
RU (1) | RU2005123338A (ru) |
WO (1) | WO2004067588A1 (ru) |
ZA (1) | ZA200506758B (ru) |
Families Citing this family (87)
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- 2003-12-05 WO PCT/US2003/040145 patent/WO2004067588A1/en not_active Application Discontinuation
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US7262246B2 (en) | 2007-08-28 |
US20030181572A1 (en) | 2003-09-25 |
JP2006513303A (ja) | 2006-04-20 |
CN1742027A (zh) | 2006-03-01 |
WO2004067588A1 (en) | 2004-08-12 |
ZA200506758B (en) | 2006-05-31 |
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