PL422574A1 - Polyampholytes derivatives of dimethylphosphinic acid and of 5-amino-1,3,3-trimethylcyclohexanemethanamine and method for producing it - Google Patents
Polyampholytes derivatives of dimethylphosphinic acid and of 5-amino-1,3,3-trimethylcyclohexanemethanamine and method for producing itInfo
- Publication number
- PL422574A1 PL422574A1 PL422574A PL42257417A PL422574A1 PL 422574 A1 PL422574 A1 PL 422574A1 PL 422574 A PL422574 A PL 422574A PL 42257417 A PL42257417 A PL 42257417A PL 422574 A1 PL422574 A1 PL 422574A1
- Authority
- PL
- Poland
- Prior art keywords
- amino
- trimethylcyclohexanomethanamine
- dimethylphosphinic acid
- trimethylcyclohexanemethanamine
- polyampholytes
- Prior art date
Links
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical class CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002594 sorbent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Zgłoszenie dotyczy poliamfolitu pochodnego kwasu dimetylofosfinowego i 5-amino-1,3,3-trimetylocykloheksanometanaminy przedstawionego wzorem 1, znajdującego zastosowanie jako żywica jonowymienna, sorbent do usuwania jonów metali z roztworów i nośnik katalizatorów. Zgłoszenie dotyczy również sposobu wytwarzania poliamfolitów pochodnych kwasu dimetylofosfinowego i 5-amino-1,3,3-trimetylocykloheksanometanaminy, który polega na tym, że dwie części molowe kwasu fosfinowego poddaje się reakcji z jedną częścią molową 5-amino-1,3,3-trimetylocykloheksanometanaminy i co najmniej dwiema częściami molowymi formaldehydu zawartego w formalinie lub paraformie, a reakcję prowadzi się w temperaturze 300 - 373.K, w obecności 0,4 - 1,2 części molowych HCl, aż do przereagowania substratów i produktów pośrednich, po czym nierozpuszczalny w wodzie poliamfolit wydziela się z mieszaniny poreakcyjnej.The application concerns a polyampholite derivative of dimethylphosphinic acid and 5-amino-1,3,3-trimethylcyclohexanomethanamine represented by formula 1, which is used as an ion exchange resin, a sorbent for removing metal ions from solutions and a catalyst support. The application also relates to a process for the production of polyamphololites derived from dimethylphosphinic acid and 5-amino-1,3,3-trimethylcyclohexanomethanamine, which consists in the fact that two molar parts of phosphinic acid are reacted with one molar part of 5-amino-1,3,3- trimethylcyclohexanomethanamine and at least two molar parts of formaldehyde contained in formalin or paraform, and the reaction is carried out at a temperature of 300-373.K, in the presence of 0.4-1.2 mol parts of HCl, until reactants and intermediates, then insoluble in water, polyampolite is separated from the reaction mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL422574A PL234795B1 (en) | 2017-08-16 | 2017-08-16 | Polyampholytes derivatives of dimethylphosphinic acid and of 5-amino-1,3,3-trimethylcyclohexanemethanamine and method for producing it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL422574A PL234795B1 (en) | 2017-08-16 | 2017-08-16 | Polyampholytes derivatives of dimethylphosphinic acid and of 5-amino-1,3,3-trimethylcyclohexanemethanamine and method for producing it |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL422574A1 true PL422574A1 (en) | 2018-02-12 |
| PL234795B1 PL234795B1 (en) | 2020-04-30 |
Family
ID=61148691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL422574A PL234795B1 (en) | 2017-08-16 | 2017-08-16 | Polyampholytes derivatives of dimethylphosphinic acid and of 5-amino-1,3,3-trimethylcyclohexanemethanamine and method for producing it |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL234795B1 (en) |
-
2017
- 2017-08-16 PL PL422574A patent/PL234795B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL234795B1 (en) | 2020-04-30 |
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