NO760061L - - Google Patents

Info

Publication number: NO760061L
Authority: NO; Norway
Prior art keywords: compound; stated; transition metal; group; component
Prior art date: 1975-01-09

Application number

NO760061A

Other languages

English (en)

Norwegian (no)

Inventor

A B Newton

Original Assignee

Ici Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-01-09

Filing date

1976-01-09

Publication date

1976-07-12

1975-01-09 Priority claimed from GB920/75A external-priority patent/GB1495031A/en

1976-01-09 Application filed by Ici Ltd filed Critical Ici Ltd

1976-07-12 Publication of NO760061L publication Critical patent/NO760061L/no

Links

238000000034 method Methods 0.000 claims abstract description 45
150000003623 transition metal compounds Chemical class 0.000 claims abstract description 35
239000003054 catalyst Substances 0.000 claims description 61
239000007787 solid Substances 0.000 claims description 52
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 48
238000000227 grinding Methods 0.000 claims description 40
238000006116 polymerization reaction Methods 0.000 claims description 40
150000001875 compounds Chemical class 0.000 claims description 36
-1 erfenoxatiin Chemical compound 0.000 claims description 36
229920000642 polymer Polymers 0.000 claims description 34
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 33
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 33
239000007788 liquid Substances 0.000 claims description 23
239000003085 diluting agent Substances 0.000 claims description 22
239000000463 material Substances 0.000 claims description 22
229910052723 transition metal Inorganic materials 0.000 claims description 22
150000003624 transition metals Chemical class 0.000 claims description 22
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 21
229910052782 aluminium Inorganic materials 0.000 claims description 20
239000000178 monomer Substances 0.000 claims description 20
150000002898 organic sulfur compounds Chemical class 0.000 claims description 20
239000002841 Lewis acid Substances 0.000 claims description 18
239000002879 Lewis base Substances 0.000 claims description 17
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
150000001336 alkenes Chemical class 0.000 claims description 14
125000001183 hydrocarbyl group Chemical group 0.000 claims description 14
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 11
150000002894 organic compounds Chemical class 0.000 claims description 11
230000000737 periodic effect Effects 0.000 claims description 11
238000010422 painting Methods 0.000 claims description 10
229910052717 sulfur Inorganic materials 0.000 claims description 10
239000011593 sulfur Substances 0.000 claims description 10
150000002902 organometallic compounds Chemical class 0.000 claims description 9
239000007800 oxidant agent Substances 0.000 claims description 9
150000004291 polyenes Chemical class 0.000 claims description 9
125000003545 alkoxy group Chemical group 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 8
125000004414 alkyl thio group Chemical group 0.000 claims description 8
125000003118 aryl group Chemical group 0.000 claims description 8
125000005110 aryl thio group Chemical group 0.000 claims description 8
125000004104 aryloxy group Chemical group 0.000 claims description 8
125000005843 halogen group Chemical group 0.000 claims description 8
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 7
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
239000002685 polymerization catalyst Substances 0.000 claims description 7
229940124530 sulfonamide Drugs 0.000 claims description 7
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 7
229920006395 saturated elastomer Polymers 0.000 claims description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
150000003568 thioethers Chemical class 0.000 claims description 6
GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 5
WLYAZICOBONPRR-UHFFFAOYSA-N n,n-diethyl-4-phenoxybenzenesulfonamide Chemical compound C1=CC(S(=O)(=O)N(CC)CC)=CC=C1OC1=CC=CC=C1 WLYAZICOBONPRR-UHFFFAOYSA-N 0.000 claims description 5
QISRUVSLDWSMST-UHFFFAOYSA-N n,n-diphenylbenzenesulfonamide Chemical compound C=1C=CC=CC=1S(=O)(=O)N(C=1C=CC=CC=1)C1=CC=CC=C1 QISRUVSLDWSMST-UHFFFAOYSA-N 0.000 claims description 5
229910052698 phosphorus Inorganic materials 0.000 claims description 5
229930195734 saturated hydrocarbon Natural products 0.000 claims description 5
GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 claims description 4
XEIVFUWZYMWLEP-UHFFFAOYSA-N 9h-thioxanthene 10,10-dioxide Chemical compound C1=CC=C2S(=O)(=O)C3=CC=CC=C3CC2=C1 XEIVFUWZYMWLEP-UHFFFAOYSA-N 0.000 claims description 4
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims description 4
229910001882 dioxygen Inorganic materials 0.000 claims description 4
QXBUYALKJGBACG-UHFFFAOYSA-N 10-methylphenothiazine Chemical compound C1=CC=C2N(C)C3=CC=CC=C3SC2=C1 QXBUYALKJGBACG-UHFFFAOYSA-N 0.000 claims description 3
SSIOPLVRUPBGPG-UHFFFAOYSA-N 10-methylphenothiazine 5,5-dioxide Chemical compound C1=CC=C2N(C)C3=CC=CC=C3S(=O)(=O)C2=C1 SSIOPLVRUPBGPG-UHFFFAOYSA-N 0.000 claims description 3
DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 claims description 3
150000004985 diamines Chemical class 0.000 claims description 3
IKJFYINYNJYDTA-UHFFFAOYSA-N dibenzothiophene sulfone Chemical compound C1=CC=C2S(=O)(=O)C3=CC=CC=C3C2=C1 IKJFYINYNJYDTA-UHFFFAOYSA-N 0.000 claims description 3
MUMVIYLVHVCYGI-UHFFFAOYSA-N n,n,n',n',n",n"-hexamethylmethanetriamine Chemical compound CN(C)C(N(C)C)N(C)C MUMVIYLVHVCYGI-UHFFFAOYSA-N 0.000 claims description 3
FZIFUJULXRFHBB-UHFFFAOYSA-N n,n-diethylbenzenesulfonamide Chemical compound CCN(CC)S(=O)(=O)C1=CC=CC=C1 FZIFUJULXRFHBB-UHFFFAOYSA-N 0.000 claims description 3
BVSPJPNNLDIUFE-UHFFFAOYSA-N n,n-dimethylbenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=CC=C1 BVSPJPNNLDIUFE-UHFFFAOYSA-N 0.000 claims description 3
GJSGGHOYGKMUPT-UHFFFAOYSA-N phenoxathiine Chemical compound C1=CC=C2OC3=CC=CC=C3SC2=C1 GJSGGHOYGKMUPT-UHFFFAOYSA-N 0.000 claims description 3
238000000746 purification Methods 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
VAKOAGKCNQSYBA-UHFFFAOYSA-N 4-bromo-n-methyl-n-phenylbenzenesulfonamide Chemical compound C=1C=C(Br)C=CC=1S(=O)(=O)N(C)C1=CC=CC=C1 VAKOAGKCNQSYBA-UHFFFAOYSA-N 0.000 claims description 2
SOMJAHYGVWAEJH-UHFFFAOYSA-N 4-chloro-n-methyl-n-phenylbenzenesulfonamide Chemical compound C=1C=C(Cl)C=CC=1S(=O)(=O)N(C)C1=CC=CC=C1 SOMJAHYGVWAEJH-UHFFFAOYSA-N 0.000 claims description 2
UQFDBPMIVXVQPD-UHFFFAOYSA-N 6-(benzenesulfonyl)-1,2,3,4-tetrahydronaphthalene Chemical compound C=1C=C2CCCCC2=CC=1S(=O)(=O)C1=CC=CC=C1 UQFDBPMIVXVQPD-UHFFFAOYSA-N 0.000 claims description 2
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 2
229920001577 copolymer Polymers 0.000 claims description 2
VUNCWTMEJYMOOR-UHFFFAOYSA-N hexachlorocyclopentadiene Chemical compound ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl VUNCWTMEJYMOOR-UHFFFAOYSA-N 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
229910052740 iodine Inorganic materials 0.000 claims description 2
239000011630 iodine Substances 0.000 claims description 2
PTUNVBFYPJJYOY-UHFFFAOYSA-N n,n,1,3-tetramethyl-2-oxo-1,3,2$l^{5}-diazaphospholidin-2-amine Chemical compound CN(C)P1(=O)N(C)CCN1C PTUNVBFYPJJYOY-UHFFFAOYSA-N 0.000 claims description 2
125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
239000011574 phosphorus Substances 0.000 claims description 2
UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 claims description 2
150000003335 secondary amines Chemical class 0.000 claims description 2
150000003512 tertiary amines Chemical class 0.000 claims description 2
GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical compound C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 claims description 2
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 2
239000005864 Sulphur Substances 0.000 claims 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
XJLRCPYQIPAQCA-UHFFFAOYSA-N phenoxathiine 10,10-dioxide Chemical compound C1=CC=C2S(=O)(=O)C3=CC=CC=C3OC2=C1 XJLRCPYQIPAQCA-UHFFFAOYSA-N 0.000 claims 1
FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims 1
150000003456 sulfonamides Chemical class 0.000 claims 1
150000003457 sulfones Chemical class 0.000 claims 1
239000000375 suspending agent Substances 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 35
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 13
239000010936 titanium Substances 0.000 description 13
239000001257 hydrogen Substances 0.000 description 12
229910052739 hydrogen Inorganic materials 0.000 description 12
229910052719 titanium Inorganic materials 0.000 description 12
239000004215 Carbon black (E152) Substances 0.000 description 11
229930195733 hydrocarbon Natural products 0.000 description 11
150000002430 hydrocarbons Chemical class 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
238000007792 addition Methods 0.000 description 9
239000000725 suspension Substances 0.000 description 9
239000000155 melt Substances 0.000 description 8
230000000694 effects Effects 0.000 description 7
229910001220 stainless steel Inorganic materials 0.000 description 7
239000010935 stainless steel Substances 0.000 description 7
238000005406 washing Methods 0.000 description 7
230000000052 comparative effect Effects 0.000 description 6
239000007789 gas Substances 0.000 description 6
150000007517 lewis acids Chemical class 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
229920001155 polypropylene Polymers 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000004743 Polypropylene Substances 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
238000009835 boiling Methods 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 4
239000003701 inert diluent Substances 0.000 description 4
150000007527 lewis bases Chemical class 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
125000004437 phosphorous atom Chemical group 0.000 description 3
239000002002 slurry Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229910010062 TiCl3 Inorganic materials 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
125000005842 heteroatom Chemical group 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
238000003801 milling Methods 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000010998 test method Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
MDYOLVRUBBJPFM-UHFFFAOYSA-N tropolone Chemical compound OC1=CC=CC=CC1=O MDYOLVRUBBJPFM-UHFFFAOYSA-N 0.000 description 2
238000001238 wet grinding Methods 0.000 description 2
OZFAFGSSMRRTDW-UHFFFAOYSA-N (2,4-dichlorophenyl) benzenesulfonate Chemical compound ClC1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=CC=C1 OZFAFGSSMRRTDW-UHFFFAOYSA-N 0.000 description 1
AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
MDLKWDQMIZRIBY-UHFFFAOYSA-N 1-(dimethylamino)ethanol Chemical compound CC(O)N(C)C MDLKWDQMIZRIBY-UHFFFAOYSA-N 0.000 description 1
QAPRKOYITFGXTK-UHFFFAOYSA-N 2,4-dimethyl-1-(4-methylphenyl)sulfonylbenzene Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C1=CC=C(C)C=C1C QAPRKOYITFGXTK-UHFFFAOYSA-N 0.000 description 1
JHLUZZZZJZJUTJ-UHFFFAOYSA-N 3-methylhepta-1,3,5-triene Chemical compound CC=CC=C(C)C=C JHLUZZZZJZJUTJ-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
239000012591 Dulbecco’s Phosphate Buffered Saline Substances 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
SZKKRCSOSQAJDE-UHFFFAOYSA-N Schradan Chemical compound CN(C)P(=O)(N(C)C)OP(=O)(N(C)C)N(C)C SZKKRCSOSQAJDE-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
150000001361 allenes Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
238000010923 batch production Methods 0.000 description 1
238000005452 bending Methods 0.000 description 1
150000008331 benzenesulfonamides Chemical class 0.000 description 1
MYSWNMKXSMMSSM-UHFFFAOYSA-J benzenesulfonylbenzene;tetrachlorotitanium Chemical compound Cl[Ti](Cl)(Cl)Cl.C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 MYSWNMKXSMMSSM-UHFFFAOYSA-J 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
VZDYWEUILIUIDF-UHFFFAOYSA-J cerium(4+);disulfate Chemical compound [Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VZDYWEUILIUIDF-UHFFFAOYSA-J 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 description 1
OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical class C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 1
ICPMUWPXCAVOOQ-UHFFFAOYSA-N cycloocta-1,3,5-triene Chemical compound C1CC=CC=CC=C1 ICPMUWPXCAVOOQ-UHFFFAOYSA-N 0.000 description 1
KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 description 1
238000007872 degassing Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
ANCLJVISBRWUTR-UHFFFAOYSA-N diaminophosphinic acid Chemical compound NP(N)(O)=O ANCLJVISBRWUTR-UHFFFAOYSA-N 0.000 description 1
AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000011888 foil Substances 0.000 description 1
XZSDLFHCPIUHJB-UHFFFAOYSA-N formamide;urea Chemical compound NC=O.NC(N)=O XZSDLFHCPIUHJB-UHFFFAOYSA-N 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
150000005826 halohydrocarbons Chemical class 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
239000012535 impurity Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229920001580 isotactic polymer Polymers 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
JCDWETOKTFWTHA-UHFFFAOYSA-N methylsulfonylbenzene Chemical compound CS(=O)(=O)C1=CC=CC=C1 JCDWETOKTFWTHA-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
150000003961 organosilicon compounds Chemical class 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
238000007591 painting process Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000010951 particle size reduction Methods 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229950000688 phenothiazine Drugs 0.000 description 1
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920003205 poly(diphenylsiloxane) Polymers 0.000 description 1
229920001384 propylene homopolymer Polymers 0.000 description 1
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
230000036558 skin tension Effects 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
LGMGPNAOZRUYCD-UHFFFAOYSA-N tert-butylsulfonylbenzene Chemical compound CC(C)(C)S(=O)(=O)C1=CC=CC=C1 LGMGPNAOZRUYCD-UHFFFAOYSA-N 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
238000004448 titration Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
QVWDCTQRORVHHT-UHFFFAOYSA-N tropone Chemical compound O=C1C=CC=CC=C1 QVWDCTQRORVHHT-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
238000004846 x-ray emission Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NO760061A 1975-01-09 1976-01-09 NO760061L (nl)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB920/75A GB1495031A (en)	1975-01-09	1975-01-09	Grinding of a transition metal compound
GB1979075		1975-05-12
GB4463475		1975-10-29

Publications (1)

Publication Number	Publication Date
NO760061L true NO760061L (nl)	1976-07-12

Family

ID=27253787

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO760061A NO760061L (nl)	1975-01-09	1976-01-09

Country Status (11)

Country	Link
JP (1)	JPS5618001B2 (nl)
AU (1)	AU502660B2 (nl)
BR (1)	BR7600104A (nl)
DE (1)	DE2600552A1 (nl)
ES (1)	ES444160A1 (nl)
FI (1)	FI760047A (nl)
FR (1)	FR2454840A1 (nl)
IT (1)	IT1054756B (nl)
NL (1)	NL7600197A (nl)
NO (1)	NO760061L (nl)
SE (1)	SE7600165L (nl)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2429226A1 (fr) *	1978-06-21	1980-01-18	Ato Chimie	Procede pour la preparation de polymeres ou copolymeres d'alphaolefines presentant un haut indice d'isotacticite

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5215108B2 (nl) *	1973-08-13	1977-04-26

1976
- 1976-01-09 JP JP165476A patent/JPS5618001B2/ja not_active Expired
- 1976-01-09 AU AU10172/76A patent/AU502660B2/en not_active Expired
- 1976-01-09 SE SE7600165A patent/SE7600165L/xx not_active Application Discontinuation
- 1976-01-09 BR BR7600104A patent/BR7600104A/pt unknown
- 1976-01-09 FR FR7600452A patent/FR2454840A1/fr active Pending
- 1976-01-09 NO NO760061A patent/NO760061L/no unknown
- 1976-01-09 DE DE19762600552 patent/DE2600552A1/de not_active Ceased
- 1976-01-09 ES ES444160A patent/ES444160A1/es not_active Expired
- 1976-01-09 IT IT19133/76A patent/IT1054756B/it active
- 1976-01-09 FI FI760047A patent/FI760047A/fi not_active Application Discontinuation
- 1976-01-09 NL NL7600197A patent/NL7600197A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
NL7600197A (nl)	1976-07-13
JPS5195994A (nl)	1976-08-23
FR2454840A1 (fr)	1980-11-21
FI760047A (nl)	1976-07-10
IT1054756B (it)	1981-11-30
DE2600552A1 (de)	1976-07-15
SE7600165L (sv)	1976-07-12
ES444160A1 (es)	1977-09-16
BR7600104A (pt)	1976-08-03
AU1017276A (en)	1977-07-14
JPS5618001B2 (nl)	1981-04-25
AU502660B2 (en)	1979-08-02

Publication	Publication Date	Title
FI58928C (fi)	1981-05-11	Foerfarande och katalysatorsystem foer laogtryckspolymerisering av eten enbart eller tillsammans med en alfa-olefin med 3-6 kolatomer
US4121030A (en)	1978-10-17	Transition metal composition
JPH07149831A (ja)	1995-06-13	高い嵩密度を有する超高分子量ポリエチレンの製造方法
US3119799A (en)	1964-01-28	Polymers of acetylenic hydrocarbons and methods for producing the same
SU424360A3 (ru)	1974-04-15	Способ получения полиолефинов
US4204050A (en)	1980-05-20	Polymerization of α-olefins with a dual transition metal catalyst
NO150763B (no)	1984-09-03	Fremgangsmaate for katalytisk polymerisering av propylen
KR840001737B1 (ko)	1984-10-18	α-올레핀의 중합방법
US4370449A (en)	1983-01-25	Transition metal composition and production thereof
US4258161A (en)	1981-03-24	Process for polymerizing propylene
US4243782A (en)	1981-01-06	Transition metal compound
NO760061L (nl)	1976-07-12
US3712874A (en)	1973-01-23	Tetraneopentyltitanium
US4182816A (en)	1980-01-08	Olefine polymerization process
US4161461A (en)	1979-07-17	Treatment of transition metal compound
NO152562B (no)	1985-07-08	Fremgangsmaate for polymerisering og ko-polymerisering av olefiner
US4892852A (en)	1990-01-09	Transition metal composition
EP0000998B1 (en)	1982-03-24	Titanium trichloride compositions, preparation thereof, catalyst system containing them and polymerisation of olefins using this system
NO750159L (nl)	1975-08-25
NO750225L (nl)	1975-08-13
NO762080L (nl)	1976-12-17
GB2101611A (en)	1983-01-19	Catalyst composition, production and use
US4354010A (en)	1982-10-12	Transition metal compound
JPS61130311A (ja)	1986-06-18	オレフイン重合用触媒成分の製造方法
GB1582141A (en)	1980-12-31	Production of transition metal composition useful as an olefine polymerisation catalyst or component thereof