NO762080L - - Google Patents

Info

Publication number: NO762080L
Authority: NO; Norway
Prior art keywords: stated; mol; component; catalyst; titanium
Prior art date: 1975-06-16

Application number

NO762080A

Other languages

English (en)

Norwegian (no)

Inventor

R Pearce

V A Wilson

Original Assignee

Ici Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-06-16

Filing date

1976-06-16

Publication date

1976-12-17

1976-06-16 Application filed by Ici Ltd filed Critical Ici Ltd

1976-12-17 Publication of NO762080L publication Critical patent/NO762080L/no

Links

239000007787 solid Substances 0.000 claims description 50
239000003054 catalyst Substances 0.000 claims description 45
238000000034 method Methods 0.000 claims description 42
238000006116 polymerization reaction Methods 0.000 claims description 33
-1 titanium halide Chemical class 0.000 claims description 31
239000010936 titanium Substances 0.000 claims description 30
229910052719 titanium Inorganic materials 0.000 claims description 28
239000000203 mixture Substances 0.000 claims description 24
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 24
229910052782 aluminium Inorganic materials 0.000 claims description 18
150000001875 compounds Chemical class 0.000 claims description 18
239000000178 monomer Substances 0.000 claims description 18
238000010438 heat treatment Methods 0.000 claims description 17
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 16
239000008139 complexing agent Substances 0.000 claims description 15
239000000463 material Substances 0.000 claims description 15
239000002879 Lewis base Substances 0.000 claims description 13
230000008569 process Effects 0.000 claims description 13
229920000642 polymer Polymers 0.000 claims description 12
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
125000005234 alkyl aluminium group Chemical group 0.000 claims description 11
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
150000002430 hydrocarbons Chemical group 0.000 claims description 10
239000000047 product Substances 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 9
239000003153 chemical reaction reagent Substances 0.000 claims description 9
238000011065 in-situ storage Methods 0.000 claims description 9
150000004291 polyenes Chemical class 0.000 claims description 8
150000001336 alkenes Chemical class 0.000 claims description 7
125000000217 alkyl group Chemical group 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 7
150000002902 organometallic compounds Chemical class 0.000 claims description 7
125000004429 atom Chemical group 0.000 claims description 6
150000004820 halides Chemical class 0.000 claims description 6
125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
239000002685 polymerization catalyst Substances 0.000 claims description 6
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims description 5
239000011541 reaction mixture Substances 0.000 claims description 5
238000011282 treatment Methods 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 4
229910052801 chlorine Inorganic materials 0.000 claims description 4
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 4
239000003701 inert diluent Substances 0.000 claims description 4
230000000737 periodic effect Effects 0.000 claims description 4
HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 claims description 4
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
229910052723 transition metal Inorganic materials 0.000 claims description 4
150000003624 transition metals Chemical class 0.000 claims description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
239000005977 Ethylene Substances 0.000 claims description 3
239000000460 chlorine Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
239000012265 solid product Substances 0.000 claims description 3
150000003568 thioethers Chemical class 0.000 claims description 3
150000003573 thiols Chemical class 0.000 claims description 3
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
125000001309 chloro group Chemical group Cl* 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 2
PTUNVBFYPJJYOY-UHFFFAOYSA-N n,n,1,3-tetramethyl-2-oxo-1,3,2$l^{5}-diazaphospholidin-2-amine Chemical compound CN(C)P1(=O)N(C)CCN1C PTUNVBFYPJJYOY-UHFFFAOYSA-N 0.000 claims description 2
239000000126 substance Substances 0.000 claims description 2
229920001577 copolymer Polymers 0.000 claims 1
150000004678 hydrides Chemical class 0.000 claims 1
150000002899 organoaluminium compounds Chemical class 0.000 claims 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 71
239000003085 diluting agent Substances 0.000 description 22
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
229930195733 hydrocarbon Natural products 0.000 description 10
239000004215 Carbon black (E152) Substances 0.000 description 9
239000003638 chemical reducing agent Substances 0.000 description 7
239000002002 slurry Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
238000010908 decantation Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
230000009467 reduction Effects 0.000 description 5
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
238000007334 copolymerization reaction Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
229910010062 TiCl3 Inorganic materials 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
238000002441 X-ray diffraction Methods 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
230000008859 change Effects 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000007527 lewis bases Chemical class 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
229910003074 TiCl4 Inorganic materials 0.000 description 2
230000032683 aging Effects 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
239000008187 granular material Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229960004592 isopropanol Drugs 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
MDYOLVRUBBJPFM-UHFFFAOYSA-N tropolone Chemical compound OC1=CC=CC=CC1=O MDYOLVRUBBJPFM-UHFFFAOYSA-N 0.000 description 2
AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
MDLKWDQMIZRIBY-UHFFFAOYSA-N 1-(dimethylamino)ethanol Chemical compound CC(O)N(C)C MDLKWDQMIZRIBY-UHFFFAOYSA-N 0.000 description 1
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
206010042618 Surgical procedure repeated Diseases 0.000 description 1
229910010068 TiCl2 Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
229920001585 atactic polymer Polymers 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 description 1
OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical class C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 1
ICPMUWPXCAVOOQ-UHFFFAOYSA-N cycloocta-1,3,5-triene Chemical compound C1CC=CC=CC=C1 ICPMUWPXCAVOOQ-UHFFFAOYSA-N 0.000 description 1
KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
201000006549 dyspepsia Diseases 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
208000024798 heartburn Diseases 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000002896 organic halogen compounds Chemical class 0.000 description 1
150000003961 organosilicon compounds Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
229910052698 phosphorus Chemical group 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
208000024981 pyrosis Diseases 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
239000010414 supernatant solution Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
150000007970 thio esters Chemical class 0.000 description 1
125000005323 thioketone group Chemical group 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
QVWDCTQRORVHHT-UHFFFAOYSA-N tropone Chemical compound O=C1C=CC=CC=C1 QVWDCTQRORVHHT-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO762080A 1975-06-16 1976-06-16 NO762080L (nl)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB25538/75A GB1548573A (en)	1975-06-16	1975-06-16	Polymerisation catalyst and process

Publications (1)

Publication Number	Publication Date
NO762080L true NO762080L (nl)	1976-12-17

Family

ID=10229300

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO762080A NO762080L (nl)	1975-06-16	1976-06-16

Country Status (13)

Country	Link
AU (1)	AU502031B2 (nl)
BE (1)	BE843038A (nl)
BR (1)	BR7603896A (nl)
DE (1)	DE2627108A1 (nl)
ES (1)	ES448944A1 (nl)
FI (1)	FI761744A (nl)
FR (1)	FR2314760A1 (nl)
GB (1)	GB1548573A (nl)
IT (1)	IT1071490B (nl)
NL (1)	NL7606503A (nl)
NO (1)	NO762080L (nl)
NZ (1)	NZ181180A (nl)
SE (1)	SE7606849L (nl)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4240928A (en)	1976-03-08	1980-12-23	Toa Nenryo Kogyo Kabushiki Kaisha	Titanium trichloride catalyst and process for the production thereof
JPS5919564B2 (ja) *	1978-04-12	1984-05-07	東亜燃料工業株式会社	α−オレフインの重合用触媒成分の製造方法
JPS595202B2 (ja) *	1978-04-12	1984-02-03	東亜燃料工業株式会社	α−オレフィンの重合用触媒成分の製造方法
IT1193760B (it) *	1978-06-14	1988-08-24	Sumitomo Chemical Co	Procedimento per produrre copolimeri di propilene e pellicola di polipropilene a piu' strati con esso ottenuta
JPS5928573B2 (ja) *	1980-02-05	1984-07-13	チッソ株式会社	α−オレフイン重合体の製造方法
JPS6023764B2 (ja) *	1980-02-27	1985-06-10	チッソ株式会社	α−オレフイン重合体を製造する方法
US4400494A (en) *	1981-08-28	1983-08-23	Standard Oil Company (Indiana)	Olefin polymerization catalyst

1975
- 1975-06-16 GB GB25538/75A patent/GB1548573A/en not_active Expired
1976
- 1976-06-16 DE DE19762627108 patent/DE2627108A1/de not_active Withdrawn
- 1976-06-16 NZ NZ181180A patent/NZ181180A/xx unknown
- 1976-06-16 FI FI761744A patent/FI761744A/fi not_active Application Discontinuation
- 1976-06-16 AU AU14973/76A patent/AU502031B2/en not_active Expired
- 1976-06-16 NO NO762080A patent/NO762080L/no unknown
- 1976-06-16 NL NL7606503A patent/NL7606503A/nl not_active Application Discontinuation
- 1976-06-16 ES ES448944A patent/ES448944A1/es not_active Expired
- 1976-06-16 SE SE7606849A patent/SE7606849L/xx unknown
- 1976-06-16 BR BR7603896A patent/BR7603896A/pt unknown
- 1976-06-16 FR FR7618229A patent/FR2314760A1/fr not_active Withdrawn
- 1976-06-16 BE BE168003A patent/BE843038A/xx unknown
- 1976-06-16 IT IT24432/76A patent/IT1071490B/it active

Also Published As

Publication number	Publication date
IT1071490B (it)	1985-04-10
DE2627108A1 (de)	1976-12-30
ES448944A1 (es)	1977-07-01
NL7606503A (nl)	1976-12-20
FR2314760A1 (fr)	1977-01-14
NZ181180A (en)	1978-04-28
FI761744A (nl)	1976-12-17
BE843038A (fr)	1976-12-16
AU1497376A (en)	1977-12-22
GB1548573A (en)	1979-07-18
BR7603896A (pt)	1977-04-05
SE7606849L (sv)	1976-12-17
AU502031B2 (en)	1979-07-12

Publication	Publication Date	Title
US4301029A (en)	1981-11-17	Olefin polymerization catalyst and the production and use thereof
EP0015048B1 (en)	1983-02-16	Olefine polymerization catalyst and use thereof
US4385161A (en)	1983-05-24	Olefine polymerization process
US4530913A (en)	1985-07-23	Polymerization catalyst and method
US3960765A (en)	1976-06-01	Catalyst for polymerization of olefins and process for preparing the same
US4330646A (en)	1982-05-18	Polymerization of an α-olefin
RU2098428C1 (ru)	1997-12-10	Титансодержащий компонент катализатора полимеризации этилена, катализатор полимеризации этилена и способ полимеризации этилена с использованием этого катализатора
US4579835A (en)	1986-04-01	Polymerization catalyst, production and use
US5155079A (en)	1992-10-13	Multiple site olefin polymerization catalysts
NO141264B (no)	1979-10-29	Fremgangsmaate til polymerisasjon eller kopolymerisasjon av polyetylen under hoeyt trykk
US5064796A (en)	1991-11-12	Support adjuvant for improved vanadium polymerization catalyst
US7208436B2 (en)	2007-04-24	Catalyst components for the polymerization of olefins
US4258167A (en)	1981-03-24	Process for producing powdery isotactic polyolefin
US4308369A (en)	1981-12-29	High efficiency catalyst for polymerizing olefins
NO833428L (no)	1984-04-02	Katalysator for polymerisasjon av olefiner og fremstilling og anvendelse derav
NO762080L (nl)	1976-12-17
US2951066A (en)	1960-08-30	Three-component olefin polymerization catalyst containing an aluminum sesquihalide and a transition metal compound
US4398006A (en)	1983-08-09	Process for producing polybutene-1
US4634751A (en)	1987-01-06	Polymerization catalyst, production and use
US4224186A (en)	1980-09-23	High efficiency catalyst for polymerizing olefins
US4490514A (en)	1984-12-25	High-temperature ethylene polymerization and copolymerization using dialuminoxane cocatalysts
US4578440A (en)	1986-03-25	Polymerization catalyst and method
NO762079L (nl)	1976-12-17
EP0000999A1 (en)	1979-03-07	Titanium trichloride compositions, preparation thereof, catalyst system containing them, and polymerisation of olefins using this system
US4238355A (en)	1980-12-09	High efficiency catalyst for polymerizing olefins