NO744556L - - Google Patents

Info

Publication number: NO744556L
Authority: NO; Norway
Prior art keywords: stands; titanium; reaction product; weight; catalyst component
Prior art date: 1973-12-21

Application number

NO744556A

Other languages

English (en)

Norwegian (no)

Inventor

J Nickl

H Frielingsdorf

G Schweier

H Mueller-Tamm

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-12-21

Filing date

1974-12-17

Publication date

1975-07-21

1974-12-17 Application filed by Basf Ag filed Critical Basf Ag

1975-07-21 Publication of NO744556L publication Critical patent/NO744556L/no

Links

239000003054 catalyst Substances 0.000 claims description 91
239000010936 titanium Substances 0.000 claims description 87
229910052719 titanium Inorganic materials 0.000 claims description 87
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 82
239000007795 chemical reaction product Substances 0.000 claims description 59
229910052751 metal Inorganic materials 0.000 claims description 51
239000002184 metal Substances 0.000 claims description 51
239000000725 suspension Substances 0.000 claims description 48
238000006116 polymerization reaction Methods 0.000 claims description 30
239000007790 solid phase Substances 0.000 claims description 28
238000004519 manufacturing process Methods 0.000 claims description 26
-1 aluminum compound Chemical class 0.000 claims description 22
229910052782 aluminium Inorganic materials 0.000 claims description 21
238000000034 method Methods 0.000 claims description 19
150000001875 compounds Chemical class 0.000 claims description 17
150000003839 salts Chemical class 0.000 claims description 17
229910052739 hydrogen Inorganic materials 0.000 claims description 16
239000001257 hydrogen Substances 0.000 claims description 16
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
239000005977 Ethylene Substances 0.000 claims description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
229910052801 chlorine Inorganic materials 0.000 claims description 11
239000000460 chlorine Substances 0.000 claims description 11
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 9
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 9
125000000217 alkyl group Chemical group 0.000 claims description 9
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 9
229910052794 bromium Inorganic materials 0.000 claims description 9
229910052740 iodine Inorganic materials 0.000 claims description 9
239000011630 iodine Substances 0.000 claims description 9
229920001519 homopolymer Polymers 0.000 claims description 8
239000012071 phase Substances 0.000 claims description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 7
229910052749 magnesium Inorganic materials 0.000 claims description 7
239000011777 magnesium Substances 0.000 claims description 7
150000002739 metals Chemical class 0.000 claims description 6
239000000178 monomer Substances 0.000 claims description 6
150000002430 hydrocarbons Chemical group 0.000 claims description 5
150000002431 hydrogen Chemical class 0.000 claims description 5
150000002894 organic compounds Chemical class 0.000 claims description 5
125000005037 alkyl phenyl group Chemical group 0.000 claims description 4
239000004411 aluminium Substances 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 4
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
230000015572 biosynthetic process Effects 0.000 claims description 3
229910052748 manganese Inorganic materials 0.000 claims description 3
239000011572 manganese Substances 0.000 claims description 3
150000002736 metal compounds Chemical class 0.000 claims description 3
125000003884 phenylalkyl group Chemical group 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 2
125000004093 cyano group Chemical group *C#N 0.000 claims 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 68
239000000047 product Substances 0.000 description 19
159000000003 magnesium salts Chemical class 0.000 description 16
238000003756 stirring Methods 0.000 description 13
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 12
238000002360 preparation method Methods 0.000 description 10
238000001816 cooling Methods 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 9
238000010438 heat treatment Methods 0.000 description 8
238000010992 reflux Methods 0.000 description 7
238000001914 filtration Methods 0.000 description 6
239000002904 solvent Substances 0.000 description 5
RFONJRMUUALMBA-UHFFFAOYSA-N 2-methanidylpropane Chemical compound CC(C)[CH2-] RFONJRMUUALMBA-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 4
239000007787 solid Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
238000001035 drying Methods 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000002156 mixing Methods 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
238000009835 boiling Methods 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000000376 reactant Substances 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000375 suspending agent Substances 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
238000010908 decantation Methods 0.000 description 1
NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000006194 liquid suspension Substances 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
SUSQOBVLVYHIEX-UHFFFAOYSA-N phenylacetonitrile Chemical compound N#CCC1=CC=CC=C1 SUSQOBVLVYHIEX-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000003746 solid phase reaction Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
230000007306 turnover Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO744556A 1973-12-21 1974-12-17 NO744556L (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2363695A DE2363695C3 (de)	1973-12-21	1973-12-21	Verfahren zum Herstellen von Homopolymerisaten des Äthylens oder Copolymerisaten des Äthylens mit a .Monoolefinen

Publications (1)

Publication Number	Publication Date
NO744556L true NO744556L (de)	1975-07-21

Family

ID=5901472

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO744556A NO744556L (de)	1973-12-21	1974-12-17

Country Status (8)

Country	Link
JP (1)	JPS5096684A (de)
AT (1)	AT333502B (de)
BE (1)	BE823221A (de)
DE (1)	DE2363695C3 (de)
FR (1)	FR2255316B1 (de)
GB (1)	GB1456408A (de)
IT (1)	IT1027756B (de)
NO (1)	NO744556L (de)

1973
- 1973-12-21 DE DE2363695A patent/DE2363695C3/de not_active Expired
1974
- 1974-12-11 BE BE151391A patent/BE823221A/xx unknown
- 1974-12-17 NO NO744556A patent/NO744556L/no unknown
- 1974-12-17 IT IT30665/74A patent/IT1027756B/it active
- 1974-12-19 FR FR7442035A patent/FR2255316B1/fr not_active Expired
- 1974-12-19 JP JP49145097A patent/JPS5096684A/ja active Pending
- 1974-12-19 GB GB5485174A patent/GB1456408A/en not_active Expired
- 1974-12-20 AT AT1023074A patent/AT333502B/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
FR2255316A1 (de)	1975-07-18
BE823221A (fr)	1975-06-11
GB1456408A (en)	1976-11-24
ATA1023074A (de)	1976-03-15
JPS5096684A (de)	1975-07-31
DE2363695B2 (de)	1980-02-07
DE2363695A1 (de)	1975-07-03
DE2363695C3 (de)	1980-10-02
IT1027756B (it)	1978-12-20
FR2255316B1 (de)	1979-02-23
AT333502B (de)	1976-11-25

Publication	Publication Date	Title
FI92837C (fi)	1995-01-10	Menetelmä stereosäännöllisten polymeerien valmistamiseksi, joilla on ahtaissa rajoissa oleva molekyylipainojakautuma
SU795488A3 (ru)	1981-01-07	Катализатор полимеризации этилена
US4927797A (en)	1990-05-22	Catalyst system for the polymerization of olefins
US4414132A (en)	1983-11-08	Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
US5066738A (en)	1991-11-19	Polymerization of olefins with an improved catalyst system using a new electron donor
US3231550A (en)	1966-01-25	Olefin polymerization
US4581342A (en)	1986-04-08	Supported olefin polymerization catalyst
EP1751195B1 (de)	2011-03-09	Verfahren zur herstellung eines olefinpolymerisationskatalysators
NO141264B (no)	1979-10-29	Fremgangsmaate til polymerisasjon eller kopolymerisasjon av polyetylen under hoeyt trykk
JPS61293207A (ja)	1986-12-24	徹底予備重合させた担持アルフア−オレフイン重合触媒
NO178731B (no)	1996-02-12	Fremgangsmåte for modifisering av katalysatorer som er beregnet for polymerisasjon av olefiner
CA2006461C (en)	1999-08-17	The preparation and use of a new ziegler-natta catalyst component
US5308818A (en)	1994-05-03	Catalyst system for the polymerization of olefins
US5204303A (en)	1993-04-20	Preparation and use of a new ziegler-natta catayst component
EP2242580A1 (de)	2010-10-27	Ziegler-natta-katalysator
HU203566B (en)	1991-08-28	Process for producing catalyst-component for olefin-polimerization
FI117558B (fi)	2006-11-30	Menetelmä eteenipolymeerien valmistamiseksi
CA1170245A (en)	1984-07-03	Magnesium containing solid
US5891817A (en)	1999-04-06	Electron donors for improved olefin polymerization
JPS60203606A (ja)	1985-10-15	オレフインの改良された重合方法
US5132379A (en)	1992-07-21	Solid alpha-olefin polymerization catalyst compounds
SU417928A3 (de)	1974-02-28
KR950012095B1 (ko)	1995-10-14	올레핀 중합용 촉매
NO744556L (de)	1975-07-21
US3362943A (en)	1968-01-09	Separation of polymers of 1-olefins in monomer solution