NO315612B1 - Katalysatorkomponent på b¶rer, katalysator på b¶rer, fremstilling av disse,samt addisjonspolymerisasjonsprosess - Google Patents

Katalysatorkomponent på b¶rer, katalysator på b¶rer, fremstilling av disse,samt addisjonspolymerisasjonsprosess Download PDF

Info

Publication number: NO315612B1
Authority: NO; Norway
Prior art keywords: catalyst component; transition metal; alumoxane; supported catalyst; carrier
Prior art date: 1994-11-17

Application number

NO19972260A

Other languages

English (en)

Norwegian (no)

Other versions

NO972260D0 (no

NO972260L (no

Inventor

Grant Berent Jacobsen

Lee Spencer

Peter L Wauteraerts

Original Assignee

Dow Global Technologies Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-11-17

Filing date

1997-05-16

Publication date

2003-09-29

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23335790&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO315612(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1997-05-16 Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc

1997-05-16 Publication of NO972260D0 publication Critical patent/NO972260D0/no

1997-07-16 Publication of NO972260L publication Critical patent/NO972260L/no

2003-09-29 Publication of NO315612B1 publication Critical patent/NO315612B1/no

Links

239000003054 catalyst Substances 0.000 title claims abstract description 177
238000000034 method Methods 0.000 title claims abstract description 81
238000012644 addition polymerization Methods 0.000 title claims abstract description 10
238000002360 preparation method Methods 0.000 title claims abstract description 9
239000000463 material Substances 0.000 claims abstract description 41
150000003623 transition metal compounds Chemical class 0.000 claims abstract description 40
239000000178 monomer Substances 0.000 claims abstract description 12
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XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 91
239000000843 powder Substances 0.000 claims description 62
239000012876 carrier material Substances 0.000 claims description 52
238000010438 heat treatment Methods 0.000 claims description 45
150000001875 compounds Chemical class 0.000 claims description 43
239000000377 silicon dioxide Substances 0.000 claims description 43
238000006116 polymerization reaction Methods 0.000 claims description 42
238000005406 washing Methods 0.000 claims description 39
235000012239 silicon dioxide Nutrition 0.000 claims description 36
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 34
239000002904 solvent Substances 0.000 claims description 34
AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical group C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 claims description 33
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238000013019 agitation Methods 0.000 description 1
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AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
150000008378 aryl ethers Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
KDKNVCQXFIBDBD-UHFFFAOYSA-N carbanide;1,2,3,4,5-pentamethylcyclopentane;zirconium(2+) Chemical group [CH3-].[CH3-].[Zr+2].C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]1[C](C)[C](C)[C](C)[C]1C KDKNVCQXFIBDBD-UHFFFAOYSA-N 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
150000004696 coordination complex Chemical class 0.000 description 1
125000003678 cyclohexadienyl group Chemical group C1(=CC=CCC1)* 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
230000008021 deposition Effects 0.000 description 1
125000002897 diene group Chemical group 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
229940069096 dodecene Drugs 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
125000002312 hydrocarbylidene group Chemical group 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
238000002955 isolation Methods 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002738 metalloids Chemical class 0.000 description 1
125000005394 methallyl group Chemical group 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
150000004291 polyenes Chemical class 0.000 description 1
230000037048 polymerization activity Effects 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000002459 porosimetry Methods 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000010414 supernatant solution Substances 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical class FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
238000009997 thermal pre-treatment Methods 0.000 description 1
150000003568 thioethers Chemical group 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910003452 thorium oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
239000003053 toxin Substances 0.000 description 1
231100000765 toxin Toxicity 0.000 description 1
108700012359 toxins Proteins 0.000 description 1
JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000004260 weight control Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NO19972260A 1994-11-17 1997-05-16 Katalysatorkomponent på b¶rer, katalysator på b¶rer, fremstilling av disse,samt addisjonspolymerisasjonsprosess NO315612B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US34098994A	1994-11-17	1994-11-17
PCT/US1995/014192 WO1996016092A1 (en)	1994-11-17	1995-11-02	Supported catalyst component, supported catalyst, their preparation, and addition polymerization process

Publications (3)

Publication Number	Publication Date
NO972260D0 NO972260D0 (no)	1997-05-16
NO972260L NO972260L (no)	1997-07-16
NO315612B1 true NO315612B1 (no)	2003-09-29

Family

ID=23335790

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19972260A NO315612B1 (no)	1994-11-17	1997-05-16	Katalysatorkomponent på b¶rer, katalysator på b¶rer, fremstilling av disse,samt addisjonspolymerisasjonsprosess

Country Status (19)

Country	Link
EP (1)	EP0792297B1 (xx)
JP (1)	JPH10512902A (xx)
CN (1)	CN1127524C (xx)
AT (1)	ATE229987T1 (xx)
AU (1)	AU699285B2 (xx)
BR (1)	BR9510354A (xx)
CZ (1)	CZ293261B6 (xx)
DE (1)	DE69529230T2 (xx)
ES (1)	ES2184811T3 (xx)
FI (1)	FI972110A0 (xx)
MX (1)	MX9703592A (xx)
MY (1)	MY113329A (xx)
NO (1)	NO315612B1 (xx)
NZ (1)	NZ296399A (xx)
PL (1)	PL320255A1 (xx)
RU (1)	RU2166513C2 (xx)
TW (1)	TW353083B (xx)
WO (1)	WO1996016092A1 (xx)
ZA (1)	ZA959800B (xx)

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US7153909B2 (en)	1994-11-17	2006-12-26	Dow Global Technologies Inc.	High density ethylene homopolymers and blend compositions
US6034024A (en) *	1996-05-10	2000-03-07	Albemarle Corporation	Heat treated alumoxanes
AU5806599A (en) *	1998-09-04	2000-03-27	Dow Chemical Company, The	Long chain branched ethylene homopolymer made by a slurry process and blends thereof
GB9822123D0 (en)	1998-10-09	1998-12-02	Borealis As	Catalyst
HUP0104266A2 (hu)	1998-11-04	2002-03-28	Montell Technology Company Bv.	Komponensek és katalizátorok olefinek polimerizálására
US6432860B1 (en) *	1999-03-22	2002-08-13	Fina Technology, Inc.	Supported metallocene catalysts
ES2286890T3 (es) *	1999-07-15	2007-12-01	Dow Global Technologies Inc.	Homopolimeros de etileno de alta densidad y composiciones de mezcla.
KR20020012346A (ko) *	2000-08-07	2002-02-16	유현식	신디오탁틱 폴리스티렌을 고수율로 제조하고 반응기부착물을 감소시키는 담지촉매
US7220804B1 (en)	2000-10-13	2007-05-22	Univation Technologies, Llc	Method for preparing a catalyst system and its use in a polymerization process
CN1982361B (zh)	2001-08-17	2011-11-16	陶氏环球技术有限责任公司	双峰聚乙烯组合物及其制品
WO2004069880A1 (en) *	2003-02-05	2004-08-19	Lg Chem, Ltd.	Catalyst system for preparing styrene polymer and method for preparing of styrene polymer using the same
DE10348624A1 (de) *	2003-10-15	2005-05-25	Basell Polyolefine Gmbh	Geträgerte Metallalkylverbindung und Verfahren zu deren Herstellung
US7619047B2 (en) *	2006-02-22	2009-11-17	Chevron Phillips Chemical Company, Lp	Dual metallocene catalysts for polymerization of bimodal polymers
DE102006020486A1 (de) *	2006-04-28	2007-10-31	Basell Polyolefine Gmbh	Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
EP2119732A1 (en)	2008-05-16	2009-11-18	Borealis Technology Oy	Metallocene catalyst compositions with improved properties, process for its preparation and use for preparing polyolefin homo- or copolymers
JP5611237B2 (ja)	2009-01-23	2014-10-22	エボニックデグサゲーエムベーハーＥｖｏｎｉｋＤｅｇｕｓｓａＧｍｂＨ	Ｐｅｍｉｂスラリー重合
US20120010354A1 (en)	2009-01-23	2012-01-12	Evonik Oxeno Gmbh	Pe film ss comprising interpolymers with 3-substituted c4-10-alkene with single site catalysts
EP2382246B1 (en)	2009-01-23	2013-08-14	Evonik Oxeno GmbH	Polyolefin gas phase polymerization with 3-substituted c4-10-alkene
WO2011078923A1 (en)	2009-12-23	2011-06-30	Univation Technologies, Llc	Methods for producing catalyst systems
EP2570437B1 (en) *	2010-05-11	2018-07-04	Tosoh Finechem Corporation	Solid support-polymethylaluminoxane complex, method for producing same, olefin polymerization catalyst, and method for producing polyolefin
GB2498936A (en)	2012-01-31	2013-08-07	Norner Innovation As	Polyethylene with multi-modal molecular weight distribution

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JP2538588B2 (ja) *	1987-04-03	1996-09-25	三井石油化学工業株式会社	オレフイン重合用固体触媒の製法
DE4139262A1 (de) *	1991-11-29	1993-06-03	Basf Ag	Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
DE4207899A1 (de) *	1992-03-12	1993-09-16	Basf Ag	Feststoff, enthaltend chemisch gebundene metallalkylgruppen, und seine verwendung
JPH06100614A (ja) *	1992-08-06	1994-04-12	Mitsui Petrochem Ind Ltd	オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
TW298593B (xx) *	1993-02-12	1997-02-21	Hoechst Ag
DE4336659A1 (de) *	1993-10-27	1995-05-04	Witco Gmbh	Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien
ATE171957T1 (de) *	1994-06-03	1998-10-15	Pcd Polymere Ag	Katalysatorträger, geträgerte metallocenkatalysatoren und deren verwendung für die herstellung von polyolefinen

1995
- 1995-11-02 MX MX9703592A patent/MX9703592A/es not_active IP Right Cessation
- 1995-11-02 PL PL95320255A patent/PL320255A1/xx unknown
- 1995-11-02 RU RU97110089/04A patent/RU2166513C2/ru not_active IP Right Cessation
- 1995-11-02 CZ CZ19971522A patent/CZ293261B6/cs not_active IP Right Cessation
- 1995-11-02 AU AU40197/95A patent/AU699285B2/en not_active Ceased
- 1995-11-02 EP EP95939025A patent/EP0792297B1/en not_active Expired - Lifetime
- 1995-11-02 CN CN95196287A patent/CN1127524C/zh not_active Expired - Fee Related
- 1995-11-02 ES ES95939025T patent/ES2184811T3/es not_active Expired - Lifetime
- 1995-11-02 NZ NZ296399A patent/NZ296399A/xx unknown
- 1995-11-02 WO PCT/US1995/014192 patent/WO1996016092A1/en active IP Right Grant
- 1995-11-02 BR BR9510354A patent/BR9510354A/pt not_active IP Right Cessation
- 1995-11-02 JP JP8516891A patent/JPH10512902A/ja not_active Ceased
- 1995-11-02 AT AT95939025T patent/ATE229987T1/de not_active IP Right Cessation
- 1995-11-02 DE DE69529230T patent/DE69529230T2/de not_active Expired - Lifetime
- 1995-11-17 ZA ZA959800A patent/ZA959800B/xx unknown
- 1995-11-17 MY MYPI95003499A patent/MY113329A/en unknown
- 1995-11-30 TW TW084112767A patent/TW353083B/zh active
1997
- 1997-05-16 NO NO19972260A patent/NO315612B1/no unknown
- 1997-05-16 FI FI972110A patent/FI972110A0/fi not_active IP Right Cessation

Also Published As

Publication number	Publication date
CZ293261B6 (cs)	2004-03-17
PL320255A1 (en)	1997-09-15
EP0792297A1 (en)	1997-09-03
ZA959800B (en)	1997-05-19
NZ296399A (en)	1999-02-25
DE69529230D1 (de)	2003-01-30
FI972110A (fi)	1997-05-16
NO972260D0 (no)	1997-05-16
JPH10512902A (ja)	1998-12-08
BR9510354A (pt)	1997-12-23
ES2184811T3 (es)	2003-04-16
CN1127524C (zh)	2003-11-12
EP0792297B1 (en)	2002-12-18
MX9703592A (es)	1997-08-30
DE69529230T2 (de)	2003-09-04
TW353083B (en)	1999-02-21
CZ152297A3 (en)	1997-08-13
FI972110A0 (fi)	1997-05-16
MY113329A (en)	2002-01-31
RU2166513C2 (ru)	2001-05-10
AU4019795A (en)	1996-06-17
NO972260L (no)	1997-07-16
WO1996016092A1 (en)	1996-05-30
AU699285B2 (en)	1998-11-26
CN1164241A (zh)	1997-11-05
ATE229987T1 (de)	2003-01-15

Publication	Publication Date	Title
NO315612B1 (no)	2003-09-29	Katalysatorkomponent på b¶rer, katalysator på b¶rer, fremstilling av disse,samt addisjonspolymerisasjonsprosess
US5783512A (en)	1998-07-21	Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US6258902B1 (en)	2001-07-10	Olefin polymerization process
MXPA97003592A (en)	1997-08-01	Component of supported catalyst, supported catalyst, its preparation and depolimerization process by adic
JP2000507157A (ja)	2000-06-13	溶解度の高いオレフィン重合触媒活性剤
NO315977B1 (no)	2003-11-24	Katalysatorblanding omfattende reaksjonsproduktet av en organometallforbindelse samt anvendelse derav
AU7844300A (en)	2001-05-08	A method for preparing a supported catalyst system and its use in a polymerization process
US7776977B2 (en)	2010-08-17	Method for preparing a catalyst system and its use in a polymerization process
MXPA05000067A (es)	2005-04-08	Activadores de catalizadores de polimerizacion, metodo de preparacion, y su uso en procesos de polimerizacion.
USRE41785E1 (en)	2010-09-28	Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
AU779594B2 (en)	2005-02-03	A method for preparing a supported catalyst system and its use in a polymerization process
US6043180A (en)	2000-03-28	Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
NO321908B1 (no)	2006-07-17	Katalysatorer med funksjonaliserte baerematerialer og understottede katalysatorsystemer
CA2428341A1 (en)	2002-05-23	A method for preparing a catalyst composition and its use in a polymerization process
AU2002324444B2 (en)	2005-07-21	Catalyst system and its use in a polymerization process
JP2001524144A (ja)	2001-11-27	ポリオレフィン類の高収率合成のための触媒系
US6852659B1 (en)	2005-02-08	Method for preparing a catalyst composition and its use in a polymerization process
JP2002504565A (ja)	2002-02-12	担持触媒組成物の製造
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