KR940018340A - 퍼클로로에틸렌 또는 펜타 클로로에탄의 플루오르화 방법 - Google Patents
퍼클로로에틸렌 또는 펜타 클로로에탄의 플루오르화 방법 Download PDFInfo
- Publication number
- KR940018340A KR940018340A KR1019940001392A KR19940001392A KR940018340A KR 940018340 A KR940018340 A KR 940018340A KR 1019940001392 A KR1019940001392 A KR 1019940001392A KR 19940001392 A KR19940001392 A KR 19940001392A KR 940018340 A KR940018340 A KR 940018340A
- Authority
- KR
- South Korea
- Prior art keywords
- nickel
- chromium
- seconds
- contact time
- aluminum fluoride
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/132—Compounds comprising a halogen and chromium, molybdenum, tungsten or polonium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
본 발명은 플루오르화 수소산을 사용하여 기상에서 퍼클로로에틸렌 또는 펜타클로로에탄의 촉매적 플루오르화 방법에 관한 것이다.
본 발명에서 촉매로는, 알루미늄 플루오르화물이거나, 알루미늄 플루오르화물과 알루미나의 혼합물로 구성된 담체상에 담지된 니켈과 크롬 산화물, 할로겐화물 및/또는 옥시할로겐화물로 이루어진 혼합 촉매를 사용한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 알루미늄 플루오르화물이거나 알루미늄 플루오르화물과 알루미나의 혼합물로 구성된 담체상에 담지된 니켈과 크롬산화물, 할로겐화물 및 옥시할로겐화물로 구성된 군으로 부터 선택된 하나 이상의 물질로 이루어진 혼합촉매를 사용하는 것을 특징으로 하면서, 플루오르 수소산을 사용하여 기상에서 퍼클로로에틸렌 또는 펜타클로로에탄의 여속적인 촉매적 플루오르화 방법.
- 제 1 항에 있어서, 촉매 중의 니켈과 크롬의 함량이 각 금속의 경우에 0.5~20중량%이며, 니켈/크롬 원자비율이 0.5~5인 것을 특징으로 하는 방법.
- 제 2 항에 있어서, 니켈/크롬 원자 비율이 1에 근접하는 것을 특징으로 하는 방법.
- 제 2 항에 있어서, 함량이 각 금속의 경우에 2~10중량%인 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한 항에 있어서, 반응 온도가 200~450℃인 것을 특징으로 하는 방법.
- 제 5 항에 있어서, 반응 온도가 250~400℃인 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한 항에 있어서, 작동 입력이 0~25바 게이지 인 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한 항에 있어서, HF/C2Cl4또는 HF/C2HCl5의 몰비가 1/1~20/1인 것을 특징으로하는 방법.
- 제 8 항에 있어서, 몰비가 2/1~10/1인 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한 항에 있어서, 반응 조건하에 계산된 접촉 시간이 3~100초인 것을 특징으로 하는 방법.
- 제10항에 있어서, 접촉시간이 5~30초인 것을 특징으로 하는 방법.
- 제11항에 있어서, 접촉시간이 7~20초인 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한 항에 있어서, 플루오르화가 덜된 생성물을 반응기로 재순환하는 것을 특징으로 하는 방법.
- 제 1 항 내지 제 4 항중 어느 한항에 있어서, 산소의 존재하에 작동을 수행하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9300779A FR2700766B1 (fr) | 1993-01-27 | 1993-01-27 | Procédé de fluoration de perchloréthylène ou du pentachloréthane. |
FR93-00779 | 1993-01-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940018340A true KR940018340A (ko) | 1994-08-16 |
KR960009678B1 KR960009678B1 (en) | 1996-07-23 |
Family
ID=9443385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR94001392A KR960009678B1 (en) | 1993-01-27 | 1994-01-26 | Process for the fluorination of perchloroethylene or pentachloroethane |
Country Status (13)
Country | Link |
---|---|
US (1) | US5932776A (ko) |
EP (1) | EP0609123B1 (ko) |
JP (1) | JP2510127B2 (ko) |
KR (1) | KR960009678B1 (ko) |
CN (1) | CN1035174C (ko) |
AU (1) | AU663818B2 (ko) |
BR (1) | BR9400337A (ko) |
CA (1) | CA2113510C (ko) |
DE (1) | DE69400034T2 (ko) |
ES (1) | ES2081225T3 (ko) |
FR (1) | FR2700766B1 (ko) |
GR (1) | GR3019016T3 (ko) |
TW (1) | TW277054B (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2700770B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane. |
US5561095A (en) * | 1994-03-31 | 1996-10-01 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
DE69509230T2 (de) * | 1994-03-31 | 1999-09-30 | Exxon Chemical Patents Inc., Linden | Lewissäure enthaltende trägerkatalysatoren für umwandlungsreaktionen von kohlenwasserstoffen |
US5545778A (en) * | 1994-05-25 | 1996-08-13 | Alliedsignal Inc. | Single stage process for producing hydrofluorocarbons from perchloroethylene |
DE19510024C2 (de) * | 1995-03-20 | 1997-02-06 | Hoechst Ag | Verfahren zur Herstellung von Pentafluorethan (R 125) |
JP3853397B2 (ja) * | 1995-05-11 | 2006-12-06 | イネオス フラウアー ホールデイングス リミテッド | ペンタフルオロエタンの製造方法及びペンタフルオロエタンに転化するのに適当な組成物 |
US5981813A (en) * | 1996-05-22 | 1999-11-09 | Ausimont S.P.A. | Fluorination process of halogenated organic compounds |
FR2771027B1 (fr) | 1997-11-20 | 2000-01-14 | Atochem Elf Sa | Catalyseur mixte de fluoration |
JP3520900B2 (ja) * | 1997-12-12 | 2004-04-19 | ダイキン工業株式会社 | ペンタフルオロエタンの製造方法、並びにフッ素化用触媒及びその製造方法 |
US6333294B1 (en) * | 1998-05-22 | 2001-12-25 | Conoco Inc. | Fischer-tropsch processes and catalysts with promoters |
FR2807751B1 (fr) | 2000-04-12 | 2005-05-20 | Solvay | Procede pour la preparation d'un hydro (chloro) fluoroalcane et catalyseur |
FR2807752A1 (fr) * | 2000-04-12 | 2001-10-19 | Solvay | Procede pour la preparation d'un hydrochlorofluoroalcane et catalyseur |
JP4397687B2 (ja) * | 2001-06-28 | 2010-01-13 | ハネウェル・インターナショナル・インコーポレーテッド | 弗素化触媒を調製する方法 |
EP1502906A1 (en) * | 2003-07-31 | 2005-02-02 | Solvay Solexis S.p.A. | Process for activation of AIF3 based catalysts and process for isomerising hydrochlorofluorocarbons |
CN100338001C (zh) * | 2004-11-17 | 2007-09-19 | 浙江莹光化工有限公司 | 一种同时制备1,1,1,2-四氟乙烷和五氟乙烷的方法 |
FR2894250B1 (fr) * | 2005-12-06 | 2008-01-18 | Arkema Sa | Procede de fabrication du pentafluoroethane |
GB0525701D0 (en) | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
GB0525700D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
GB0525699D0 (en) * | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
FR2902780B1 (fr) * | 2006-06-21 | 2008-09-05 | Arkema France | Procede de recuperation de l'acide fluorhydrique |
FR2902788B1 (fr) | 2006-06-21 | 2008-09-05 | Arkema France | Procede de fabrication du pentafluoroethane |
FR2907449B1 (fr) * | 2006-10-20 | 2009-01-02 | Arkema France | Procede de fabrication du pentafluorethane. |
US8975455B2 (en) | 2007-12-14 | 2015-03-10 | Daikin Industries, Ltd. | Method for producing pentafluoroethane |
TWI615194B (zh) * | 2011-10-12 | 2018-02-21 | 拜耳智慧財產有限公司 | 1,1,2-三氯乙烷及/或1,2-二氯乙烷的催化氣相氟化以產生1-氯-2,2-二氟乙烷 |
CN103041819B (zh) * | 2013-01-17 | 2014-07-30 | 金华氟特催化科技有限公司 | 一种用于氟化反应的催化剂及其制备方法 |
CN104001534B (zh) * | 2013-02-21 | 2017-07-07 | 江苏理文化工有限公司 | 一种五氯乙烷催化脱HCl制四氯乙烯的催化剂及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2435551A (en) * | 1944-04-20 | 1948-02-03 | Standard Oil Dev Co | Production of hydrocarbons from carbon monoxide and hydrogen |
US2900423A (en) * | 1957-12-13 | 1959-08-18 | Allied Chem | Manufacture of perfluoropropene |
SE361134B (ko) * | 1968-07-25 | 1973-10-22 | Montedison Spa | |
DK138673B (da) * | 1968-10-10 | 1978-10-16 | Montedison Spa | Katalysator til fremstilling af chlorfluorerede ethaner. |
US3661805A (en) * | 1969-11-21 | 1972-05-09 | Universal Oil Prod Co | Method of manufacturing an extruded catalyst composition |
SE374675B (ko) * | 1970-06-10 | 1975-03-17 | Montedison Spa | |
FR2135473B1 (ko) * | 1971-05-06 | 1973-05-11 | Rhone Progil | |
US4131616A (en) * | 1974-06-24 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Methanation catalyst |
FR2407021A1 (fr) * | 1977-10-26 | 1979-05-25 | Anvar | Nouveaux derives metalliques, leur preparation et leur application en tant que catalyseurs, en particulier pour la fabrication de nitriles par ammoxydation d'alcanes a l'aide de monoxyde d'azote |
FR2501062A1 (fr) * | 1980-12-29 | 1982-09-10 | Ugine Kuhlmann | Catalyseurs de fluoruration en phase gazeuse de derives chlores aliphatiques, a base de microbilles d'oxyde de chrome, et procedes de fluoruration utilisant ces catalyseurs |
EP0128510A3 (en) * | 1983-06-07 | 1985-05-15 | Showa Denko Kabushiki Kaisha | Process for producing difluoromethane |
DE3415055A1 (de) * | 1984-04-21 | 1985-10-24 | Berkenhoff GmbH, 6301 Heuchelheim | Schnellschneide-elektrode zur schneiderosionsbearbeitung |
US4912270A (en) * | 1987-03-13 | 1990-03-27 | Allied-Signal Inc. | Chromia aerogel, method of producing same and fluorination process utilizing same |
US4766260A (en) * | 1987-07-07 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
CA1310335C (en) * | 1988-02-12 | 1992-11-17 | Leo E. Manzer | Gas-phase fluorination process |
IN171977B (ko) * | 1988-06-29 | 1993-02-27 | Du Pont | |
JP2764980B2 (ja) * | 1988-12-28 | 1998-06-11 | 旭硝子株式会社 | パークロロエチレンのフッ素化方法 |
FR2669022B1 (fr) * | 1990-11-13 | 1992-12-31 | Atochem | Procede de fabrication du tetrafluoro-1,1,1,2-ethane. |
IT1251957B (it) * | 1991-10-18 | 1995-05-27 | Ausimont Spa | Procedimento per isomerizzare 1,1,2-trifluoro-1,2-dicloroetano a 1,1,1- trifluoro-2,2,-dicloroetano |
FR2700770B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane. |
-
1993
- 1993-01-27 FR FR9300779A patent/FR2700766B1/fr not_active Expired - Fee Related
-
1994
- 1994-01-14 CA CA002113510A patent/CA2113510C/fr not_active Expired - Fee Related
- 1994-01-21 TW TW083100517A patent/TW277054B/zh not_active IP Right Cessation
- 1994-01-24 ES ES94400139T patent/ES2081225T3/es not_active Expired - Lifetime
- 1994-01-24 AU AU53970/94A patent/AU663818B2/en not_active Ceased
- 1994-01-24 EP EP94400139A patent/EP0609123B1/fr not_active Expired - Lifetime
- 1994-01-24 DE DE69400034T patent/DE69400034T2/de not_active Expired - Lifetime
- 1994-01-26 KR KR94001392A patent/KR960009678B1/ko not_active IP Right Cessation
- 1994-01-26 BR BR9400337A patent/BR9400337A/pt not_active IP Right Cessation
- 1994-01-27 JP JP6007543A patent/JP2510127B2/ja not_active Expired - Fee Related
- 1994-01-27 CN CN94101166A patent/CN1035174C/zh not_active Expired - Lifetime
-
1996
- 1996-02-20 GR GR960400417T patent/GR3019016T3/el unknown
- 1996-11-06 US US08/999,882 patent/US5932776A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2113510A1 (fr) | 1994-07-28 |
AU5397094A (en) | 1994-08-18 |
CA2113510C (fr) | 1999-01-12 |
JP2510127B2 (ja) | 1996-06-26 |
DE69400034D1 (de) | 1996-01-18 |
AU663818B2 (en) | 1995-10-19 |
EP0609123B1 (fr) | 1995-12-06 |
BR9400337A (pt) | 1994-08-16 |
JPH06247884A (ja) | 1994-09-06 |
ES2081225T3 (es) | 1996-02-16 |
DE69400034T2 (de) | 1996-06-27 |
EP0609123A1 (fr) | 1994-08-03 |
FR2700766B1 (fr) | 1995-03-24 |
CN1035174C (zh) | 1997-06-18 |
US5932776A (en) | 1999-08-03 |
FR2700766A1 (fr) | 1994-07-29 |
CN1101338A (zh) | 1995-04-12 |
GR3019016T3 (en) | 1996-05-31 |
TW277054B (ko) | 1996-06-01 |
KR960009678B1 (en) | 1996-07-23 |
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