KR880011185A - 가수분해에 저항하는 유기아인산염 및 이의 제조방법 - Google Patents

가수분해에 저항하는 유기아인산염 및 이의 제조방법 Download PDF

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KR880011185A
KR880011185A KR1019880001407A KR880001407A KR880011185A KR 880011185 A KR880011185 A KR 880011185A KR 1019880001407 A KR1019880001407 A KR 1019880001407A KR 880001407 A KR880001407 A KR 880001407A KR 880011185 A KR880011185 A KR 880011185A
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South Korea
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silane
powder
phosphite
hydrolysis
organic
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KR1019880001407A
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KR900005391B1 (ko
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네리 카를로
노다리 네리오
비싸네티 에릭
산드레 기오반니
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원본 미기재
에니켐 신테시 쏘시에떼 퍼 아찌오니
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Publication of KR880011185A publication Critical patent/KR880011185A/ko
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Publication of KR900005391B1 publication Critical patent/KR900005391B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacturing Of Micro-Capsules (AREA)

Abstract

내용 없음

Description

가수분해에 저항하는 유기아인산염 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 가수분해에 대해 안정성을 가지고 분말형태로된 고체의 유기아인산염을 부여하는 방법에 있어서, 50㎛ 내지 1mm의 입자크기를 가지는 전술한 아인산염의 분말을 유기 아인산염에 대해서 분자내에 최소한 두 개의 알콕시 그룹을 포함하는 실란을 0.1 내지 10 중량 %의 양으로 처리하고, 그리고 실란의 가수분해와 그리고 분말 입자의 표면에서 실리콘 고분자의 형성과 석출이 일어나는 것을 특징으로 하는 고체 유기아인산염의 부여방법.
  2. 제1항에 있어서, 아민산염 분말을 실란과 이 실란을 가수분해하는 소요되는 양과 최소한 같은 양이 물을 포함하는 비활성 유기용매에 현탁하고, 이 현탁액을 실온 (20-25℃)에서 10 내지 120분간 교반하고 유기용매를 증발해내고, 이렇게 수득한 분말을 100 내지 140℃온도에서 10분 내지 12시간의 시간 동안 감압하에서 조작하여 처리하는 것을 특징으로 하는 방법.
  3. 제2항에 있어서, 비활성 유기용매를 핵산과 헵탄에서 선택하는 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 아인산염 분말에 실란을 분무하고, 이 방법을 실온에서 실시하고 이렇게 처리한 분말을 감압하에서 100 내지 140℃온도에서 30분 내지 12시간 동안 유지시키는 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 유기 아민산염이 대략 100℃보다 높은 융점을 가지는 것을 특징으로 하는 방법.
  6. 제5항에 있어서, 전술한 유기 아인산염을 비스(2,4-디-tert-부틸페닐)펜타에리트리롤 이아인산염 ; 디스테아릴 펜타에리트리롤 이아인산염 및 트리스(2,4-디-tert-부틸페닐)아인산염에서 선택하는 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 전술한 실란이 비닐 트리에톡시 실란인 것을 특징으로 하는 방법.
  8. 제1항 재지 제7항의 방법에 따라 수득한, 가수분해에 대해 안정화된 유기 아민산염.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880001407A 1987-02-13 1988-02-13 내가수분해성 유기아인산염과 그 제조방법 KR900005391B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT1936787A IT1202536B (it) 1987-02-13 1987-02-13 Fosfiti organici resistenti all'idrolisi e procedimento per la loro preparazione
IT19367A/87 1987-02-13

Publications (2)

Publication Number Publication Date
KR880011185A true KR880011185A (ko) 1988-10-27
KR900005391B1 KR900005391B1 (ko) 1990-07-28

Family

ID=11157095

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880001407A KR900005391B1 (ko) 1987-02-13 1988-02-13 내가수분해성 유기아인산염과 그 제조방법

Country Status (11)

Country Link
US (1) US4810579A (ko)
EP (1) EP0278578B1 (ko)
JP (1) JPS63216892A (ko)
KR (1) KR900005391B1 (ko)
AT (1) ATE97150T1 (ko)
CA (1) CA1303622C (ko)
DE (1) DE3885472T2 (ko)
ES (1) ES2059488T3 (ko)
IT (1) IT1202536B (ko)
MX (1) MX167664B (ko)
RU (1) RU1799388C (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2647800A1 (fr) * 1989-05-31 1990-12-07 Organo Synthese Ste Fse Phosphite de tris(ditertiobutyl-2,4 phenyle) presentant des proprietes physiques ameliorees
US5102611A (en) * 1990-05-18 1992-04-07 Phillips Petroleum Company Process for making smooth plastic tubing
US5385961A (en) * 1993-01-27 1995-01-31 General Electric Company Amino silicone/phosphite compositions
US5326803A (en) * 1993-01-27 1994-07-05 General Electric Company Organohydrogen polysiloxane coated phosphites
US5614571A (en) * 1994-09-16 1997-03-25 General Electric Company Stabilizer blend containing phosphite
US6362258B1 (en) * 1995-12-29 2002-03-26 General Electric Company Stabilized thermoplastic polymer composition
DE19820157B4 (de) 1997-05-13 2010-04-08 Clariant Produkte (Deutschland) Gmbh Neue Verbindungen auf Basis von Polyalkyl-1-oxa-diazaspirodecan-Verbindungen
US6784226B2 (en) 1999-07-28 2004-08-31 Chi Mei Corporation Process for producing a styrenic resin composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516963A (en) * 1968-07-22 1970-06-23 Weston Chemical Corp Phenolic phosphites used as stabilizers

Also Published As

Publication number Publication date
MX167664B (es) 1993-04-02
EP0278578A3 (en) 1990-08-22
IT1202536B (it) 1989-02-09
EP0278578A2 (en) 1988-08-17
KR900005391B1 (ko) 1990-07-28
DE3885472T2 (de) 1994-03-10
JPS63216892A (ja) 1988-09-09
DE3885472D1 (de) 1993-12-16
RU1799388C (ru) 1993-02-28
ES2059488T3 (es) 1994-11-16
CA1303622C (en) 1992-06-16
EP0278578B1 (en) 1993-11-10
IT8719367A0 (it) 1987-02-13
ATE97150T1 (de) 1993-11-15
US4810579A (en) 1989-03-07

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