KR870005035A - 안정제로서 유용한 치환된 페놀 - Google Patents
안정제로서 유용한 치환된 페놀 Download PDFInfo
- Publication number
- KR870005035A KR870005035A KR860009485A KR860009485A KR870005035A KR 870005035 A KR870005035 A KR 870005035A KR 860009485 A KR860009485 A KR 860009485A KR 860009485 A KR860009485 A KR 860009485A KR 870005035 A KR870005035 A KR 870005035A
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- elastomer
- compound
- alkyl
- composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M135/24—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/084—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Lubricants (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 탄성중합체 또는 점착성 수지와 적어도 1의 일반식(I) 화합물을 함유하는 조성물 :여기서, R1은 C1-C8알킬 또는 C3-C12사이클로알킬이고 ; 각각 독립적으로 다른 라디칼 R2는 1 또는 2의 하이드록실기에 의해, 또는-OCO-R4,-CO-OR5또는-CO-NR ; R6에 의해 치환되거나 비치환된 C1-C18알킬기;페닐;또는 벤질이며;R3는 수소 또는 메틸이고 단, R1이 메틸 이외의 것인 경우 R3는 메틸이며 ; R4는 C1-C17알킬, C2-C8알케닐 또는 하기 일반식(Ia)의 라디칼이고 ;(여기서, m은 0.1 또는 2이고, 각각 독립적으로 다른 라디칼 R'은 R1에 대하여 나타낸 의미를 가짐) R5는-O-,-S-또는-NR'-을 중간에 갖고 있는 C1-C20알킬이며 ; R6는 수소이거나 R5에 대하여 나타낸 의미중 하나를 갖는다.
- 제1항에 있어서, 탄성중합체 및 제1항에 따른 일반식(I)의 화합물을 적어도 하나 함유하는 조성물.
- 제2항에 있어서, 각각 독립적으로 다른 라디칼 R2가 1 또는 2의 하이드록실기에 의해, 또는-OCO-R4,-CO-OR5또는-CO-NR3R6에 의해 치환되거나 비치환된 C2-C18알킬기이거나, 또는 벤질 또는 페닐기이고, R4, R5및 R6가 제1항에서 정의한 바와 같은 조성물.
- 제1항에 있어서, R2가 C4-C18알킬인 조성물.
- 제1항에 있어서, 탄성중합체가 폴리디엔, 할로겐-함유 중합체 또는 폴리우레탄인 조성물.
- 제1항에 있어서, 탄성중합체 또는 점착성 수지를 기준으로 하여 일반식(I)의 안정제를 0.05 내지 5.0중량% 함유하는 조성물.
- 제1항에 따른 탄성중합체 또는 점착성 수지에 적어도 하나의 일반식(I) 화합물을 혼입함으로써 이루어지는 안정화 처리된 조성물의 제조방법.
- 제7항에 있어서, 제1항에 따른 탄성중합체에 적어도 하나의 일반식(I) 화합물을 혼입함으로써 이루어지는 방법.
- 제7항에 있어서, 탄성중합체가 폴리디엔, 할로겐-함유 중합체 또는 폴리우레탄인 방법.
- 제7항에 있어서, 탄성중합체 또는 점착성 수지를 기준으로 하여, 일반식(I)의 안정제 0.05 내지 5.0%를 탄성중합체 또는 점착성 수지에 혼입하는 것을 포함하는 방법.
- 2,4-비스(디메틸아미노메틸)-6-메틸메틸페놀을 일반식 R - SH의 머캡탄과 반응시켜 하기 일반식(Ⅱ)의 화합물을 제조하는 방법:여기서, 각각 독립적으로 다른 라디칼 R7은 1 또는 2의 하이드록실기에 의해, 또는 -COO-R4, -CO-OR5또는 -CO-NR5R6에 의해 치환되거나 비치환된 C8-C18알킬기 ; 페닐 ; 또는 벤질기이고 ; R4,R5및 R6는 제1항의 정의한 바와 같음.
- 제11항에 있어서, 라디칼 R7이 각각 독립적으로 다르며 비치환된 C8-C18알킬인 방법.
- 윤활제에, 제11항에 따르는 일반식(Ⅱ)의 화합물을 적어도 하나 혼입시켜, 안정화 처리된 조성물을 제조하는 방법.
- 윤활제 및 제10항에 따르면 일반식(Ⅱ)의 화합물을 적어도 하나의 함유하는 조성물※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019900018944A KR910005430B1 (ko) | 1985-11-13 | 1990-11-20 | 안정제로서 유용한 치환된 페놀 |
KR1019910007021A KR910007591B1 (ko) | 1985-11-03 | 1991-05-01 | 치환된 페놀의 제조방법 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH487185 | 1985-11-13 | ||
CH4871/85-5 | 1985-11-13 | ||
CH382886 | 1986-09-24 | ||
CH3828/86-6 | 1986-09-24 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910007021A Division KR910007591B1 (ko) | 1985-11-03 | 1991-05-01 | 치환된 페놀의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870005035A true KR870005035A (ko) | 1987-06-04 |
KR910005429B1 KR910005429B1 (ko) | 1991-07-29 |
Family
ID=25693944
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860009485A KR910005429B1 (ko) | 1985-11-03 | 1986-11-11 | 치환된 페놀을 함유하는 안정제 조성물 |
Country Status (15)
Country | Link |
---|---|
US (1) | US4857572A (ko) |
EP (1) | EP0224442B1 (ko) |
JP (1) | JPH0825990B2 (ko) |
KR (1) | KR910005429B1 (ko) |
CN (2) | CN1023123C (ko) |
AU (1) | AU599059B2 (ko) |
BR (1) | BR8605596A (ko) |
CA (1) | CA1289147C (ko) |
CS (1) | CS273623B2 (ko) |
DE (1) | DE3671241D1 (ko) |
ES (1) | ES2014433B3 (ko) |
HK (1) | HK13794A (ko) |
MX (1) | MX9202733A (ko) |
SG (1) | SG95092G (ko) |
SU (1) | SU1526582A3 (ko) |
Families Citing this family (40)
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US4874885A (en) * | 1986-12-24 | 1989-10-17 | Ciba-Geigy Corporation | Process for the preparation of mercaptomethylphenols |
EP0273013B2 (de) * | 1986-12-24 | 1996-07-24 | Ciba-Geigy Ag | Substituierte Phenole als Stabilisatoren |
EP0406826B1 (de) * | 1989-07-07 | 1993-08-11 | Ciba-Geigy Ag | Schmierstoffzusammensetzung |
CA2029708C (en) * | 1989-11-14 | 2003-07-29 | Paul Dubs | Stabilizer mixtures for elastomers |
US5167846A (en) * | 1990-02-05 | 1992-12-01 | Ciba-Geigy Corporation | Sulfoxides of bisthiomethylated and tristhiomethylated phenols |
US5130365A (en) * | 1990-03-14 | 1992-07-14 | Central Glass Company, Limited | Fluororesin based coating composition applicable to plastic surfaces |
DE59104652D1 (de) * | 1990-05-10 | 1995-03-30 | Ciba Geigy Ag | Tinten. |
US5261953A (en) * | 1990-05-10 | 1993-11-16 | Ciba-Geigy Corporation | Inks |
KR0168058B1 (ko) * | 1990-05-22 | 1999-03-20 | 윌터 클리웨인,한스-피터 위트린 | 탄성중합체용 안정화제 혼합물 |
DE59109031D1 (de) * | 1990-06-07 | 1998-09-03 | Ciba Geigy Ag | Verfahren zur Herstellung von Polyurethanstoffen unter Verwendung von spezifischen Stabilisatorsystemen |
DE59104381D1 (de) * | 1990-08-28 | 1995-03-09 | Ciba Geigy Ag | Sulfoxide von Alkylthiomethylphenolen. |
US5128397A (en) * | 1991-05-09 | 1992-07-07 | Ciba-Geigy Corporation | Stabilized ethylene-vinyl acetate copolymer hot melt adhesive systems |
TW222293B (ko) * | 1991-12-06 | 1994-04-11 | Ciba Geigy Ag | |
JPH0693281A (ja) * | 1992-09-14 | 1994-04-05 | Oronaito Japan Kk | エンジン油組成物 |
EP0588561B1 (en) * | 1992-09-14 | 1998-12-02 | Oronite Japan Limited | Low phosphorous engine oil compositions and additive compositions |
US5451624A (en) * | 1994-02-15 | 1995-09-19 | Rohm And Haas Company | Stabilized modifier and impact modified thermoplastics |
US6706792B2 (en) | 1995-05-10 | 2004-03-16 | Rohm And Haas Company | Method for improving adhesion of water-based inks to halogen-containing resin articles |
EP0855998B1 (en) * | 1995-10-19 | 2001-01-10 | Ciba Specialty Chemicals Holding Inc. | Antioxidants containing phenol groups and aromatic amine groups |
DE19708661B4 (de) * | 1997-03-04 | 2005-06-16 | Ina-Schaeffler Kg | Vorrichtung zur Variierung der Ventilsteuerzeiten einer Brennkraftmaschine, insbesondere Nockenwellen-Verstelleinrichtung nach dem Flügelzellenprinzip |
DE19850532A1 (de) * | 1998-11-03 | 2000-05-04 | Nematel Dr Rudolf Eidenschink | Bisphenylthio-Verbindungen |
JP2000256691A (ja) * | 1999-03-08 | 2000-09-19 | Nippon Mitsubishi Oil Corp | 内燃機関用潤滑油組成物 |
GB2355463B (en) * | 1999-10-18 | 2001-12-05 | Ciba Sc Holding Ag | Stabilisers for emulsion crude rubbers, synthetic latex and natural rubber latex |
TW491833B (en) | 2000-01-10 | 2002-06-21 | Ciba Sc Holding Ag | Improved process for the preparation of mercaptomethylphenols |
EP1146038B1 (en) * | 2000-04-12 | 2004-06-16 | Kumho Monsanto, Inc. | Novel antioxidant and method of producing the same |
US7056967B2 (en) * | 2001-04-10 | 2006-06-06 | Ciba Specialty Chemicals Corporation | Stabilized medium and high voltage cable insulation composition |
EP1249845B1 (en) | 2001-04-10 | 2012-07-11 | Basf Se | Stabilized medium and high voltage cable insulation composition |
US6838500B2 (en) | 2002-02-07 | 2005-01-04 | Carlisle Stuart D | Adhesive compositions and tapes comprising same |
MX2007007453A (es) | 2004-12-22 | 2007-07-19 | Ciba Sc Holding Ag | Agentes antirradicales. |
KR101312422B1 (ko) * | 2004-12-22 | 2013-09-30 | 시바 홀딩 인코포레이티드 | 항라디칼제 |
KR100729434B1 (ko) * | 2005-09-05 | 2007-06-15 | 금호석유화학 주식회사 | 루이스산을 중합 종결제로 이용한 비극성 공역디엔 중합체의 제조방법 |
CN101346136A (zh) * | 2005-10-24 | 2009-01-14 | 西巴控股公司 | 可氧化剂的保护 |
KR20090006194A (ko) * | 2006-04-13 | 2009-01-14 | 사이텍 테크놀러지 코포레이션 | 안정화된 스판덱스 조성물 |
KR100834961B1 (ko) * | 2006-11-14 | 2008-06-03 | 금호석유화학 주식회사 | 인산 에스테르와 물을 이용한 음이온 중합의 중합 종결방법 |
US8101679B2 (en) | 2007-03-21 | 2012-01-24 | Basf Se | Processing stabilizers for rubber compounding |
CA2690333C (en) * | 2007-07-16 | 2017-07-04 | Basf Se | Synergistic mixture for use as a stabilizer |
EP2285887A1 (en) * | 2008-05-15 | 2011-02-23 | Basf Se | Basic stabilisation systems for emulsion polymerised rubbers |
US20140005317A1 (en) * | 2010-01-15 | 2014-01-02 | Nippon Soda Co., Ltd. | Polybutadiene derivative composition |
JPWO2011086930A1 (ja) * | 2010-01-15 | 2013-05-16 | 日本曹達株式会社 | ポリブタジエン誘導体組成物 |
DE102011003425B4 (de) * | 2011-02-01 | 2015-01-08 | Henkel Ag & Co. Kgaa | Verwendung einer härtbaren Zusammensetzung mit kombinierten Stabilisatoren |
DE102020128803A1 (de) | 2020-11-02 | 2022-05-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verwendung von Eugenol-Derivaten als Stabilisatoren, organisches Material sowie Eugenol-Derivate |
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US3114713A (en) * | 1959-07-24 | 1963-12-17 | Ethyl Corp | Sulfur-containing phenolic compounds |
US3250712A (en) * | 1959-07-24 | 1966-05-10 | Ethyl Corp | Sulfur-containing phenolic compounds |
US3060121A (en) * | 1960-04-04 | 1962-10-23 | Ethyl Corp | Antioxidants |
US3227667A (en) * | 1960-09-21 | 1966-01-04 | Borden Co | Lignin, phenol, and aldehyde condensation process and product |
US3227677A (en) * | 1962-01-02 | 1966-01-04 | Phillips Petroleum Co | Polyolefins containing bis(hydrocarbyloxycarbonylalkylthioalkyl) phenols as stabilizers |
DE1593821B1 (de) * | 1967-03-17 | 1971-08-05 | Advance Prod Gmbh | Verfahren zur Herstellung von Dialkylhydroxybenzylsulfiden |
US3903173A (en) * | 1967-03-17 | 1975-09-02 | Ciba Geigy Ag | Lower alkylthiomethylene containing phenols |
US3504012A (en) * | 1967-04-07 | 1970-03-31 | Nat Distillers Chem Corp | Hydroxyethyl-beta-(3,5-di-t-butyl-4-hydroxy benzylthio) alkanoate |
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-
1986
- 1986-11-07 EP EP86810511A patent/EP0224442B1/de not_active Expired - Lifetime
- 1986-11-07 DE DE8686810511T patent/DE3671241D1/de not_active Expired - Lifetime
- 1986-11-07 ES ES86810511T patent/ES2014433B3/es not_active Expired - Lifetime
- 1986-11-10 CA CA000522557A patent/CA1289147C/en not_active Expired - Lifetime
- 1986-11-11 KR KR1019860009485A patent/KR910005429B1/ko not_active IP Right Cessation
- 1986-11-11 CS CS816386A patent/CS273623B2/cs not_active IP Right Cessation
- 1986-11-12 BR BR8605596A patent/BR8605596A/pt not_active IP Right Cessation
- 1986-11-13 JP JP61270830A patent/JPH0825990B2/ja not_active Expired - Lifetime
- 1986-11-13 AU AU65171/86A patent/AU599059B2/en not_active Expired
- 1986-11-13 CN CN86107859A patent/CN1023123C/zh not_active Expired - Lifetime
-
1987
- 1987-10-23 SU SU874203506A patent/SU1526582A3/ru active
-
1988
- 1988-02-10 US US07/157,116 patent/US4857572A/en not_active Expired - Lifetime
-
1989
- 1989-07-21 CN CN89104939A patent/CN1026107C/zh not_active Expired - Lifetime
-
1992
- 1992-06-08 MX MX9202733A patent/MX9202733A/es unknown
- 1992-09-21 SG SG950/92A patent/SG95092G/en unknown
-
1994
- 1994-02-24 HK HK137/94A patent/HK13794A/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SG95092G (en) | 1992-12-04 |
KR910005429B1 (ko) | 1991-07-29 |
CN86107859A (zh) | 1987-05-27 |
CS273623B2 (en) | 1991-03-12 |
CS816386A2 (en) | 1990-07-12 |
EP0224442A1 (de) | 1987-06-03 |
AU6517186A (en) | 1987-05-21 |
CN1023123C (zh) | 1993-12-15 |
BR8605596A (pt) | 1987-08-18 |
MX9202733A (es) | 1992-06-30 |
JPH0825990B2 (ja) | 1996-03-13 |
JPS62114955A (ja) | 1987-05-26 |
HK13794A (en) | 1994-03-04 |
EP0224442B1 (de) | 1990-05-16 |
AU599059B2 (en) | 1990-07-12 |
DE3671241D1 (de) | 1990-06-21 |
CN1026107C (zh) | 1994-10-05 |
ES2014433B3 (es) | 1990-07-16 |
SU1526582A3 (ru) | 1989-11-30 |
CN1040364A (zh) | 1990-03-14 |
CA1289147C (en) | 1991-09-17 |
US4857572A (en) | 1989-08-15 |
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