KR20040093069A - 복합 발포 폴리프로필렌 수지 주형물 및 상기물의 제조방법 - Google Patents
복합 발포 폴리프로필렌 수지 주형물 및 상기물의 제조방법 Download PDFInfo
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- KR20040093069A KR20040093069A KR10-2004-7013319A KR20047013319A KR20040093069A KR 20040093069 A KR20040093069 A KR 20040093069A KR 20047013319 A KR20047013319 A KR 20047013319A KR 20040093069 A KR20040093069 A KR 20040093069A
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- Prior art keywords
- beads
- expanded
- polypropylene resin
- peak
- mold
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
- B29C44/0461—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities by having different chemical compositions in different places, e.g. having different concentrations of foaming agent, feeding one composition after the other
- B29C44/0469—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities by having different chemical compositions in different places, e.g. having different concentrations of foaming agent, feeding one composition after the other provided with physical separators between the different materials, e.g. separating layers, mould walls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
- B29C44/445—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
- B29C44/3426—Heating by introducing steam in the mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/24992—Density or compression of components
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249971—Preformed hollow element-containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249976—Voids specified as closed
- Y10T428/249977—Specified thickness of void-containing component [absolute or relative], numerical cell dimension or density
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249981—Plural void-containing components
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Molding Of Porous Articles (AREA)
- Laminated Bodies (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (10)
- 하기를 포함하는 복합 발포 폴리프로필렌 수지 주형물의 제조 방법:여러 연속 공간을 포함하는 주형강을 갖는 주형을 제공하고;각각의 상기 공간 내에, 폴리프로필렌 수지를 포함하는 베이스 수지의 팽창 비드를 충전하고; 및각각의 상기 공간 내에서 상기 팽창 비드를 가열하여, 각각의 팽창 비드를 단일체로 함께 융합 결합시킴;(여기서, 각각의 상기 팽창 비드는 이들의 DSC 곡선에서 고온 흡열 피크를 상기 고온 피크의 저온측에 위치한 내재 흡열 피크에 부가하여 나타내고,여기서, 하나 이상의 상기 공간 내에 충전된 팽창 비드는 동시에 하기 조건 (a) 내지 (c) 를 만족시키는 특정 팽창 비드이다:(a) 상기 특정 팽창 비드는 1,200 MPa 이상의 인장 계수를 갖는 베이스 수지로 형성되며,(b) 상기 특정 팽창 비드의 고온 흡열 피크는 10 g/L 이상, 700 g/L 이하의 겉보기 밀도 D1 g/L 을 가지고, 및(c) 상기 특정 팽창 비드의 고온 흡열 피크는 열량 E1 J/g 에 해당하는 면적을 가지며, 여기서 D1 및 E1 은 하기 상관관계를 갖는다:20 - 0.014 ×D2 ≤E1 ≤65 - 0.072 ×D1).
- 제 1 항에 있어서, 각각의 상기 특정 팽창 비드는 표면 영역 및 내부 영역을 가지며, 여기서 각각의 상기 표면 및 내부 영역은 이들의 DSC 곡선에서 고온 흡열 피크를 상기 고온 피크의 저온측에 위치한 내재 흡열 피크에 부가하여 나타내고, 여기서 상기 표면 영역 및 상기 내부 영역의 상기 고온 흡열 피크는 각각 열량값 Hs 및 Hi 에 해당하는 면적을 가지며, 여기서 Hs 및 Hi 는 하기 상관관계를 갖는 방법:Hs < 0.86 ×Hi.
- 제 1 항 또는 제 2 항에 있어서, 상기 특정 팽창 비드의 폴리프로필렌 수지가 1,200 MPa 이상의 인장 계수를 갖는 방법.
- 서로 융합 결합되고, 그 둘 이상이 서로 색상, 겉보기 밀도, 조성 및 기계적 강도로부터 선택되는 하나 이상의 특징이 상이한 여러 구획을 포함하는 복합 발포 폴리프로필렌 수지 주형물에 있어서,각각의 상기 구획은 폴리프로필렌 수지를 포함하는 베이스 수지의 팽창 비드로부터 형성되고,각각의 상기 구획은 이들의 DSC 곡선에서 고온 흡열 피크를, 상기 고온 피크의 저온측에 위치한 내재 흡열 피크에 부가하여 나타내고,하나 이상의 상기 구획은 동시에 하기 조건 (d) 내지 (f) 를 만족시키는 주형물:(d) 상기 구획은 1,200 MPa 이상의 인장 계수를 갖는 베이스 수지의 특정 팽창 폴리프로필렌 수지 비드로부터 형성되며,(e) 상기 구획은 10 g/L 이상 500 g/L 이하의 겉보기 밀도 D2 g/L 를 가지고, 및(f) 상기 구획의 고온 흡열 피크는 열량 E2 J/g 에 해당하는 면적을 가지며, 여기서 D2 및 E2 는 하기 상관관계를 가짐:20 - 0.020 ×D2 ≤E2 ≤65 - 0.100 ×D2.
- 제 4 항에 있어서, 각각의 상기 특정 팽창 비드가 표면 영역 및 내부 영역을 가지며, 여기서 각각의 상기 표면 영역 및 내부 영역이 이들의 DSC 곡선에서 고온 흡열 피크를 상기 고온 피크의 저온측에 위치한 내재 흡열 피크에 부가하여 나타내고, 상기 표면 영역 및 상기 내부 영역의 고온 흡열 피크는 각각 열량값 Hs 및 Hi 에 해당하는 면적을 가지며, 여기서 Hs 및 Hi 는 하기 상관관계를 갖는 복합 발포 주형물:Hs < 0.86 ×Hi.
- 제 4 항 또는 제 5 항에 있어서, 두 개의 인접 구획 중 하나가 상기 인접한 두 개의 구획 중의 다른 하나보다 30-450 g/L 의 범위인 상대적으로 높은 겉보기 밀도를 가지며, 상대적으로 낮은 겉보기 밀도를 갖는 다른 구획의 밀도는 15-90 g/L 의 범위인 복합 발포 주형물.
- 제 6 항에 있어서, 상대적으로 높은 겉보기 밀도가 상대적으로 낮은 겉보기 밀도의 1.2-25 배 만큼 높은 복합 발포 주형물.
- 제 4 항 내지 제 7 항 중 어느 한 항에 있어서, 상기 특정 팽창 비드의 폴리프로필렌 수지가 1,200 MPa 이상의 인장 계수를 갖는 복합 발포 주형물.
- 제 4 항 내지 제 8 항 중 어느 한 항에 있어서, 충격 흡수제의 형태인 복합 발포 주형물.
- 제 9 항에 있어서, 상기 충격 흡수제가 자동차 범퍼의 코어인 복합 발포 주형물.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JPJP-P-2002-00077383 | 2002-03-19 | ||
JP2002077383 | 2002-03-19 | ||
PCT/JP2003/003318 WO2003078127A1 (en) | 2002-03-19 | 2003-03-19 | Composite foamed polypropylene resin molding and method of producing same |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20040093069A true KR20040093069A (ko) | 2004-11-04 |
KR100943871B1 KR100943871B1 (ko) | 2010-02-24 |
Family
ID=28035507
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020047013319A KR100943871B1 (ko) | 2002-03-19 | 2003-03-19 | 복합 발포 폴리프로필렌 수지 주형물 및 상기물의 제조방법 |
Country Status (11)
Country | Link |
---|---|
US (2) | US7182896B2 (ko) |
EP (1) | EP1485241B1 (ko) |
JP (1) | JP4859076B2 (ko) |
KR (1) | KR100943871B1 (ko) |
CN (1) | CN100402264C (ko) |
AT (1) | ATE396855T1 (ko) |
AU (1) | AU2003219550A1 (ko) |
CA (1) | CA2479139C (ko) |
DE (1) | DE60321323D1 (ko) |
TW (1) | TWI251529B (ko) |
WO (1) | WO2003078127A1 (ko) |
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DE60325812D1 (de) | 2002-08-28 | 2009-03-05 | Jsp Corp | Kern eines Stossfängers |
JP4354209B2 (ja) | 2003-03-04 | 2009-10-28 | 株式会社ジェイエスピー | バンパー構造 |
JP4017558B2 (ja) | 2003-05-20 | 2007-12-05 | 株式会社ジェイエスピー | 型内発泡成形装置及び成形方法 |
US7259189B2 (en) | 2003-06-12 | 2007-08-21 | Jsp Corporation | Expanded polypropylene resin beads and process for the production thereof |
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CN101195697B (zh) * | 2006-12-08 | 2011-12-14 | 株式会社Jsp | 发泡粒子和发泡成型体 |
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JP5107692B2 (ja) * | 2007-12-17 | 2012-12-26 | 株式会社ジェイエスピー | ポリプロピレン系樹脂発泡粒子、及びその発泡粒子成形体 |
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JP5360975B2 (ja) * | 2009-05-01 | 2013-12-04 | 株式会社ジェイエスピー | ポリエチレン系樹脂発泡ブロー成形体の製造方法およびポリエチレン系樹脂発泡ブロー成形体 |
KR20140090995A (ko) * | 2011-10-06 | 2014-07-18 | 제이에스피 인터내셔널 에스에이알엘 | 플라스틱 입자상 물질 성형 |
US8961844B2 (en) * | 2012-07-10 | 2015-02-24 | Nike, Inc. | Bead foam compression molding method for low density product |
US9498927B2 (en) | 2013-03-15 | 2016-11-22 | Nike, Inc. | Decorative foam and method |
JP6035208B2 (ja) * | 2013-06-20 | 2016-11-30 | 有限会社ベステック | 発泡樹脂成形における原料充填方法、及び排気充填機 |
KR101822144B1 (ko) * | 2016-04-11 | 2018-01-26 | 덕양산업 주식회사 | 자동차 부품용 폴리올레핀계 복합 수지 조성물 |
JP6628374B1 (ja) * | 2018-08-10 | 2020-01-08 | 株式会社ジェイエスピー | 積層体 |
WO2021081660A1 (en) * | 2019-10-31 | 2021-05-06 | Exxonmobil Chemical Patents Inc. | Polymeric foams, methods, and articles thereof |
US20220072743A1 (en) * | 2020-06-26 | 2022-03-10 | The Research Foundation For The State University Of New York | Thermoplastic components, systems, and methods for forming same |
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-
2003
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- 2003-03-19 AU AU2003219550A patent/AU2003219550A1/en not_active Abandoned
- 2003-03-19 US US10/502,934 patent/US7182896B2/en not_active Expired - Lifetime
- 2003-03-19 EP EP20030715372 patent/EP1485241B1/en not_active Expired - Lifetime
- 2003-03-19 KR KR1020047013319A patent/KR100943871B1/ko active IP Right Grant
- 2003-03-19 WO PCT/JP2003/003318 patent/WO2003078127A1/en active IP Right Grant
- 2003-03-19 CN CNB038064561A patent/CN100402264C/zh not_active Expired - Lifetime
- 2003-03-19 CA CA2479139A patent/CA2479139C/en not_active Expired - Fee Related
- 2003-03-19 DE DE60321323T patent/DE60321323D1/de not_active Expired - Lifetime
- 2003-03-19 AT AT03715372T patent/ATE396855T1/de not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
---|---|
US20050056957A1 (en) | 2005-03-17 |
EP1485241B1 (en) | 2008-05-28 |
JP4859076B2 (ja) | 2012-01-18 |
KR100943871B1 (ko) | 2010-02-24 |
CA2479139C (en) | 2010-08-24 |
TWI251529B (en) | 2006-03-21 |
CA2479139A1 (en) | 2003-09-25 |
CN100402264C (zh) | 2008-07-16 |
US20070026218A1 (en) | 2007-02-01 |
JP2011005868A (ja) | 2011-01-13 |
DE60321323D1 (de) | 2008-07-10 |
AU2003219550A1 (en) | 2003-09-29 |
CN1642708A (zh) | 2005-07-20 |
TW200304923A (en) | 2003-10-16 |
EP1485241A1 (en) | 2004-12-15 |
ATE396855T1 (de) | 2008-06-15 |
US7182896B2 (en) | 2007-02-27 |
WO2003078127A1 (en) | 2003-09-25 |
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