KR20000059365A - Cu-Zn-Al, Sr, Ti, B alloys for EDM(Energy Discharge Machine) wire and its manufacturing method - Google Patents

Cu-Zn-Al, Sr, Ti, B alloys for EDM(Energy Discharge Machine) wire and its manufacturing method Download PDF

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KR20000059365A
KR20000059365A KR1019990006912A KR19990006912A KR20000059365A KR 20000059365 A KR20000059365 A KR 20000059365A KR 1019990006912 A KR1019990006912 A KR 1019990006912A KR 19990006912 A KR19990006912 A KR 19990006912A KR 20000059365 A KR20000059365 A KR 20000059365A
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weight percent
strontium
titanium
aluminum
zinc
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KR100302546B1 (en
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김창주
한승전
정윤철
이기업
이봉수
이종택
도청락
도광락
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황해웅
한국기계연구원
도청락
주식회사 한도산업
장용성
주식회사 한얼
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C9/00—Alloys based on copper
    • C22C9/04—Alloys based on copper with zinc as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

Abstract

PURPOSE: An alloy and a producing method thereof are provided to produce a rod wire with a material containing high content and equivalent of zinc by improving a hot and a cold rolling process. CONSTITUTION: An alloy for the electrode wire of an energy discharge machine is composed of 35.0 to 45.0wt% of Zn, 0.1 to 10.0wt% of an element mixed with one or two sorts among Al, Sr, Ti and B and the remaining of Cu. The mixed element is composed of 0.1 to 10.0wt% of Al, 0.01 to 1.0wt% of Sr, 0.005 to 0.5wt% of Ti and 0.001 to 0.1wt% of B.

Description

방전가공기 전극선용 동-아연-알루미늄, 스트론튬, 티타늄, 보론계 합금 및 그 제조방법{Cu-Zn-Al, Sr, Ti, B alloys for EDM(Energy Discharge Machine) wire and its manufacturing method}Copper-zinc-aluminum, strontium, titanium, boron-based alloys and electrode manufacturing methods for electric discharge machine electrode lines {Cu-Zn-Al, Sr, Ti, B alloys for Energy Discharge Machine (EDM) wire and its manufacturing method}

본 발명은 방전가공기(Energy Discharge Machine : EDM) 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)계 합금 및 그 제조방법에 관한 것으로, 특히 알루미늄(Al)을 첨가하여 고용 및 석출강화 효과에 의해 재료의 강도를 높이고, 스트론튬(Sr)을 미량 첨가하여 주상정에서의 공정조직을 미세화시키거나, 티타늄(Ti)과 보론(B)을 미량 첨가하여 주상정 자체를 미세화시키거나, 스트론튬(Sr), 티타늄(Ti)및 보론(B)을 함께 첨가하여 주상정에서의 공정조직을 미세화시킴과 아울러 주상정 자체를 미세화시켜 취성을 억제시킴으로써 열간 및 냉간가공성을 개선하여 아연(Zn)의 함량이 높거나 아연(Zn) 당량이 높은 재질이라도 그 선재제조를 용이하게 하는 합금 및 그 제조방법에 관한 것이다.The present invention relates to a copper (Cu) -zinc (Zn) -aluminum (Al), strontium (Sr), titanium (Ti), boron (B) -based alloy, and a manufacturing method for an EDM electrode wire. In particular, by adding aluminum (Al) to increase the strength of the material by the solid solution and precipitation strengthening effect, by adding a small amount of strontium (Sr) to refine the process structure in the columnar tablets, or titanium (Ti) and boron ( A small amount of B) is added to refine the columnar tablet itself, or strontium (Sr), titanium (Ti) and boron (B) are added together to refine the process structure in the columnar tablet and to make the columnar tablet itself fine and brittle. The present invention relates to an alloy and a method for manufacturing the same, which facilitate the manufacture of wire rods even by a material having a high zinc (Zn) content or a high zinc (Zn) equivalent by improving hot and cold workability.

일반적으로 와이어 방전가공은 수중에서 세선의 와이어 전극과 피삭물 간의 방전을 제어하여 공작물을 가공하는 방법으로, 주로 복잡하게 절단하려는 금형가공에 사용되고 있다.In general, wire discharge machining is a method of processing a workpiece by controlling the discharge between the wire electrode of the fine wire and the workpiece in water, and is mainly used for mold processing for complicated cutting.

그러나 금속뿐만 아니라 도전성이 있는 것이라면 초경합금이나 세라믹스 등과 같이 난가공성 재료의 가공에도 정밀성이 있어서 향후 확대보급이 확실시되고 있다.However, if the conductive material is not only metal but also conductive, the processing of hard-working materials such as cemented carbide and ceramics is precise, and the expansion and expansion is assured in the future.

현재 방전가공기 전극선으로서 보편적으로 사용되고 있는 재료는 65%동(Cu)-35%아연(Zn) 합금인 황동선과 최근에는 동(Cu)-20∼40%아연(Zn) 합금에 알루미늄(Al), 갈리움(Ga), 크롬(Cr), 망간(Mn) 중에서 1종 또는 2종 이상을 0.1 ∼ 5.0% 이하로 첨가한 합금황동선을 비롯하여 황동선이나 강철선 표면에 아연(Zn)을 도금한 도금선 등의 3 종류로 대별되며, 가장 많이 사용되는 선경은0.20 ∼ 0.30 mm가 주류를 이루나 정밀가공용으로는0.1 mm 이하의 선재도 사용되고 있다.Currently, materials commonly used as electrode wires for electric discharge machines are brass wire, which is a 65% copper (Cu) -35% zinc (Zn) alloy, and recently, aluminum (Al), copper (Cu) -20-40% zinc (Zn) alloy. An alloy brass wire in which one or two or more of gallium (Ga), chromium (Cr), and manganese (Mn) is added in an amount of 0.1 to 5.0% or less, as well as a plating wire in which zinc (Zn) is plated on a brass or steel wire surface. It is divided into three kinds of, and the most used line diameter is 0.20 to 0.30 mm is the mainstream, but for precision processing Wire rods of 0.1 mm or less are also used.

지금까지 밝혀진 바에 의하면 방전가공기 전극선재로서 갖추어야 할 조건은 여러 가지로 많으나, 이 중에서 절삭속도를 좌우하는 요소는 선재의 합금성분 중에 아연(Zn)의 함량이 많을수록 양호하였다.According to the present invention, there are many conditions to be equipped as the electrode wire of the electric discharge machine, but among these, the factor which determines the cutting speed is better as the content of zinc (Zn) in the alloy component of the wire is higher.

이는 방전시 발생되는 열이 증발하는 아연(Zn)과 함께도 소모되기 때문이며, 합금중에 아연(Zn)의 함량이 높을 수록 그 만큼 방열효과도 큰 것으로 확인되고 있다.This is because heat generated during discharge is also consumed with evaporated zinc (Zn), and the higher the content of zinc (Zn) in the alloy, the greater the heat dissipation effect.

따라서 황동합금에서 아연(Zn)의 함량을 높이거나 아연(Zn)의 효과를 얻을 목적으로 기존의 황동합금에 아연(Zn)의 당량을 높이는 효과가 있는 원소인 알루미늄(Al)을 첨가하는 합금이 개발되어 사용중이다.Therefore, an alloy that adds aluminum (Al), an element having the effect of increasing the equivalent of zinc (Zn) to the existing brass alloy, in order to increase the content of zinc (Zn) or to obtain the effect of zinc (Zn) in the brass alloy. It is developed and in use.

방전가공시 절삭성을 증가시킬 목적으로 전극선재인 황동에서 아연(Zn)을 40% 이상 첨가하면 금속기지는 β상의 조직으로 변하여 열간가공성에는 지장이 없으나, 상온에서의 경도가 증가하고 인성이 부족하여져서 냉간가공성이 급속히 나빠져 세선으로의 인발가공이 매우 곤란하여 실용성이 없어진다는 문제점이 있다.When zinc (Zn) is added 40% or more in brass, an electrode wire, to increase machinability during electrical discharge machining, the metal base is changed into β-phase structure, which does not interfere with hot workability, but increases hardness at room temperature and lacks toughness. There is a problem in that cold workability is rapidly deteriorated and drawing process to thin wire is very difficult and practicality is lost.

상기와 같은 문제점을 해결하기 위한 본 발명의 목적은 알루미늄(Al)을 첨가하여 고용 및 석출강화 효과에 의해 재료의 강도를 높이고, 스트론튬(Sr)을 미량 첨가하여 주상정에서의 공정조직을 미세화시키거나, 티타늄(Ti)과 보론(B)을 미량 첨가하여 주상정 자체를 미세화시키거나, 스트론튬(Sr), 티타늄(Ti)및 보론(B)을 함께 첨가하여 주상정에서의 공정조직을 미세화시킴과 아울러 주상정 자체를 미세화시켜 취성을 억제시킴으로써 열간 및 냉간가공성을 개선하여 아연(Zn)의 함량이 높거나 아연(Zn) 당량이 높은 재질이라도 그 선재제조를 용이하게 하는 합금 및 그 제조방법을 제공하는데 있다.An object of the present invention for solving the above problems is to add aluminum (Al) to increase the strength of the material by the solid solution and precipitation strengthening effect, and to add a small amount of strontium (Sr) to refine the process structure in the columnar tablets Alternatively, a small amount of titanium (Ti) and boron (B) may be added to refine the columnar tablet itself, or strontium (Sr), titanium (Ti) and boron (B) may be added together to refine the process structure in the columnar tablet. In addition, by improving the hot and cold workability by minimizing the columnar tablet itself to suppress brittleness, an alloy and a method of manufacturing the same, which facilitate the manufacture of the wire even in a material having a high content of zinc (Zn) or a high content of zinc (Zn). To provide.

이러한 결과는 아연(Zn)의 함량을 40-45%까지로 증가시켰으며 강도와 인성을 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 등의 첨가로써 보완한 새로운 합금으로 절삭속도가 15-20% 개선되었고 절삭시 과열에 의한 피절삭면의 변색을 방지하여 상품성을 높이는 등의 장점을 나타내었다.These results increased the content of zinc (Zn) to 40-45% and a new alloy supplemented with the addition of aluminum (Al), strontium (Sr), titanium (Ti) and boron (B). As a result, the cutting speed has been improved by 15-20% and the merchandise is improved by preventing the discoloration of the cutting surface due to overheating during cutting.

상기한 바와 같은 목적을 달성하고 종래의 결점을 제거하기 위한 과제를 수행하는 본 발명의 실시예인 구성과 그 작용을 상세히 설명하면 다음과 같다.When explaining the configuration and the operation of the embodiment of the present invention to achieve the object as described above and to perform the problem for removing the conventional defects in detail.

본 발명에서는 아연(Zn) 함량과 제 3의 원소의 첨가량의 효과를 최대한 이용하기 위해 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과, 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와, 나머지는 구리(Cu)로 조성하되, 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)계 합금을 개발하였다.In the present invention, in order to make the best use of the effect of the zinc (Zn) content and the amount of the third element added, it has 35.0-45.0 wt% (weight percent) zinc (Zn) and a total content of 0.1-10.0 wt% (weight percent). One or two or more mixed elements added among aluminum (Al), strontium (Sr), titanium (Ti), and boron (B), and the remainder are composed of copper (Cu), but the 0.1 to 10.0 wt% ( Weight percent) of the mixed additive element is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), and 0.005 to 0.5 wt% (weight percent) Copper (Zn) -Aluminum (Al), Strontium (Sr), Titanium (Ti) for electrode line for electric discharge machine composed of titanium (Ti) and 0.001-0.1 wt% (weight percent) boron (B) , Boron (B) -based alloy was developed.

이렇게 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti) 및 보론(B) 등을 적당량 첨가함으로써 재료의 강도와 냉간인발 가공성을 개선하였고, 아연(Zn)의 함량이나 당량을 높인 새로운 방전가공기 전극선의 개발로 절삭속도를 향상하였고, 금형의 정밀도를 높일 수 있는0.1 mm 이하의 세선의 가공도 용이하게 하였다.As such, aluminum (Al), strontium (Sr), titanium (Ti) and boron (B) are added in an appropriate amount to improve the strength of the material and cold drawing workability, and a new electric discharge machine electrode wire which increases the content or equivalent of zinc (Zn). To improve cutting speed and improve mold precision. The processing of the thin wire of 0.1 mm or less was also made easy.

상기와 같은 합금을 제조하는 방법은 최종적으로 선재를 만드는 단계에 사용되는 주괴의 주조방법에 따라 금형에 주조하여 압출가공을 거치는 방법과 연속주조하여 압출가공을 거치지 않는 방법으로 나뉘어지는데 다음과 같다.The method of manufacturing the alloy as described above is divided into a method of casting in a mold according to the casting method of the ingot used in the final step of making a wire rod and an extrusion process and a method of continuous casting and not an extrusion process as follows.

먼저 금형 주조에 의한 주괴제조단계를 거치는 방법을 살펴보면,First, look at how to go through the process of manufacturing ingots by mold casting,

목표로하는 합금성분에 따라 각각의 첨가원소들은 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과, 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와, 나머지는 구리(Cu)로 조성하되, 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)으로 조성되는 조성범위를 만족하도록 각각 평량하는 평량단계와,Depending on the target alloying components, each of the additional elements is 35.0-45.0 wt% (weight percent) zinc (Zn) and aluminum (Al), strontium (Sr), having a total content of 0.1-10.0 wt% (weight percent), The content ratio of the mixed additive elements added to one or two or more of titanium (Ti) and boron (B) and the remainder is made of copper (Cu), but is 0.1 to 10.0 wt% (weight percent). Is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), 0.005 to 0.5 wt% (weight percent) titanium (Ti), and 0.001 to 0.1 wt Composition range composed of copper (Cu) -zinc (Zn) -aluminum (Al), strontium (Sr), titanium (Ti), and boron (B) A basis weight step for each basis weight to satisfy,

평량단계후 먼저 동(Cu)을 용해하여 완전히 용해되면 용탕의 가열을 멈춘 후, 아연(Zn)을 한 덩어리씩 용탕 깊숙히 플런저로 밀어 넣어 용탕 속에서 반응시킴으로써 아연(Zn)의 산화를 최대한 억제하며 용해합금하며 계속하여 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti) 및 보론(B) 중에서 선택한 첨가원소도 같은 방법으로 투입하여 용해합금하는 용해합금단계와,After dissolving copper (Cu) completely after the basis weight step, the heating of the molten metal is stopped, and then zinc (Zn) is pushed deep into the molten metal into the plunger and reacted in the molten metal to minimize the oxidation of zinc (Zn). A molten alloy step in which the molten alloy is continuously added to the molten alloy by adding the selected element selected from aluminum (Al), strontium (Sr), titanium (Ti) and boron (B) in the same manner;

용해합금한 용탕을 주조가 적당한 온도까지 다시 가열한 후, 금형에 주조하여 슬라브 상태의 주괴로 제조하는 주괴제조단계와,An ingot manufacturing step of heating the molten alloyed molten alloy back to a suitable temperature and then casting the molten alloy into a slab ingot;

주괴제조단계를 거친 주괴를 열간압출 후 소둔처리와 냉간인발을 반복하여 선재를 제조하는 선재제조단계와,A wire rod manufacturing step of manufacturing wire rods by hot extrusion of the ingots subjected to the ingot manufacturing stage, followed by annealing and cold drawing;

선재제조단계를 거친 최종의 선재를 잔류응력을 제거함과 동시에 강화효과를 주어 직선성과 탄성이 좋은 상태의 방전가공기용 전극선이 되도록 180 ∼ 200℃ 정도의 낮은 온도에서 소둔하는 소둔 단계를 거친다.The final wire rod after the wire manufacturing step is subjected to an annealing step to remove residual stress and to reinforce at the same low temperature of 180 ~ 200 ℃ to give an electrode wire for electric discharge machine of good linearity and elasticity.

또한 연속주조에 의한 주괴제조단계를 거치는 제조방법을 살펴보면,In addition, looking at the manufacturing method of the ingot manufacturing step by continuous casting,

목표로하는 합금성분에 따라 각각의 첨가원소들은 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과, 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와, 나머지는 구리(Cu)로 조성하되, 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)으로 조성되는 조성범위를 만족하도록 각각 평량하는 평량단계와,Depending on the target alloying components, each of the additional elements is 35.0-45.0 wt% (weight percent) zinc (Zn) and aluminum (Al), strontium (Sr), having a total content of 0.1-10.0 wt% (weight percent), The content ratio of the mixed additive elements added to one or two or more of titanium (Ti) and boron (B) and the remainder is made of copper (Cu), but is 0.1 to 10.0 wt% (weight percent). Is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), 0.005 to 0.5 wt% (weight percent) titanium (Ti), and 0.001 to 0.1 wt Composition range composed of copper (Cu) -zinc (Zn) -aluminum (Al), strontium (Sr), titanium (Ti), and boron (B) A basis weight step for each basis weight to satisfy,

평량단계후 먼저 동(Cu)을 용해하여 완전히 용해되면 용탕의 가열을 멈춘 후, 아연(Zn)을 한 덩어리씩 용탕 깊숙히 플런저로 밀어 넣어 용탕 속에서 반응시킴으로써 아연(Zn)의 산화를 최대한 억제하며 용해합금하며 계속하여 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti) 및 보론(B) 중에서 선택한 첨가원소도 같은 방법으로 투입하여 용해합금하는 용해합금단계와,After dissolving copper (Cu) completely after the basis weight step, the heating of the molten metal is stopped, and then zinc (Zn) is pushed deep into the molten metal into the plunger and reacted in the molten metal to minimize the oxidation of zinc (Zn). A molten alloy step in which the molten alloy is continuously added to the molten alloy by adding the selected element selected from aluminum (Al), strontium (Sr), titanium (Ti) and boron (B) in the same manner;

용해합금한 용탕을 주조가 적당한 온도까지 다시 가열한 후, 연속주조에 의해 연속적인 선재상태의 주괴로 제조하는 연속주조단계와,A continuous casting step of heating the molten alloyed molten alloy back to a suitable temperature, and then manufacturing the molten alloy into a continuous wire ingot by continuous casting;

이를 가지고 직접적으로 소둔처리와 냉간인발을 반복하여 선재를 목표로하는 선경으로 인발하여 제조하는 선재제조단계와,With this, the wire rod manufacturing step is carried out by directly drawing an annealing treatment and cold drawing, and drawing the wire with the target of the wire rod,

선재제조단계를 거친 최종의 선재를 잔류응력을 제거함과 동시에 강화효과를 주어 직선성과 탄성이 좋은 상태의 방전가공기용 전극선이 되도록 180 ∼ 200℃ 정도의 낮은 온도에서 소둔하는 소둔 단계를 거친다.The final wire rod after the wire manufacturing step is subjected to an annealing step to remove residual stress and to reinforce at the same low temperature of 180 ~ 200 ℃ to give an electrode wire for electric discharge machine of good linearity and elasticity.

상기와 같은 본 발명은 알루미늄(Al)을 첨가하여 고용 및 석출강화 효과에 의해 재료의 강도를 높이고, 스트론튬(Sr)을 미량 첨가하여 주상정에서의 공정조직을 미세화시키거나, 티타늄(Ti)과 보론(B)을 미량 첨가하여 주상정 자체를 미세화시키거나, 스트론튬(Sr), 티타늄(Ti)및 보론(B)을 함께 첨가하여 주상정에서의 공정조직을 미세화시킴과 아울러 주상정 자체를 미세화시켜 취성을 억제시킴으로써 열간 및 냉간가공성을 개선하여 아연(Zn)의 함량이 높거나 아연(Zn) 당량이 높은 재질이라도 그 선재제조를 용이하게 하는 합금 및 그 제조방법을 제공하였다.In the present invention as described above, by adding aluminum (Al) to increase the strength of the material by the solid-solution and precipitation strengthening effect, and adding a small amount of strontium (Sr) to refine the process structure in the columnar column, or titanium (Ti) and A small amount of boron (B) is added to refine the columnar tablet itself, or strontium (Sr), titanium (Ti) and boron (B) are added together to refine the process structure in the columnar tablet and to refine the columnar tablet itself. By improving the hot and cold workability by inhibiting brittleness, even an alloy having a high content of zinc (Zn) or a high content of zinc (Zn) provides an alloy and a method of manufacturing the same that facilitate the manufacture of the wire.

이러한 결과는 아연(Zn)의 함량을 40-45%까지로 증가시켰으며 강도와 인성을 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 등의 첨가로써 보완한 새로운 합금으로 절삭속도가 15-20% 개선되었고 절삭시 과열에 의한 피절삭면의 변색을 방지하여 상품성을 높이는 등의 장점을 나타내었다.These results increased the content of zinc (Zn) to 40-45% and a new alloy supplemented with the addition of aluminum (Al), strontium (Sr), titanium (Ti) and boron (B). As a result, the cutting speed has been improved by 15-20% and the merchandise is improved by preventing the discoloration of the cutting surface due to overheating during cutting.

다음의 표 1은 본 발명에서 제시하는 합금들의 예이며, 표 2는 이러한 합금재로 만든0.25 mm의 선경을 갖는 방전가공기용 와이어로써 합금공구강재인 STS-11 금형강을 대상으로 절단시험한 결과를 나타내는 것이다.Table 1 below is an example of the alloys presented in the present invention, Table 2 is made of such an alloy material This is a wire for electric discharge machining machine with 0.25mm wire diameter and shows the result of cutting test on STS-11 mold steel which is alloy steel.

표 2에서 보면 아연(Zn)과 첨가원소의 함량이 증가할수록 선재의 파단강도가 증가하여 고강도화가 되며, 아연(Zn)의 함량이 낮고 첨가원소의 함량만 많아지면 금형강의 피절단면의 경면성이 좋지 않음을 나타내었다.In Table 2, as the content of zinc (Zn) and added elements increases, the breaking strength of the wire increases, resulting in high strength. When the content of zinc (Zn) is low and the content of added elements is high, the specularity of the cut surface of the mold steel is increased. It was not good.

그러나 모든 경우에 있어서 절단가공시 선재로부터 발생되는 가루의 량은 적음을 나타내었다.In all cases, however, the amount of powder generated from the wire rod during cutting was small.

합 금 명Alloy Person CuCu ZnZn AlAl SrSr TiTi BB CZ35AlSr0.5CZ35AlSr0.5 나머지Remainder 35%35% 0.4500.450 0.0500.050 -- -- CZ35AlTiB0.5CZ35AlTiB0.5 나머지Remainder 35%35% 0.4700.470 -- 0.0250.025 0.0050.005 CZ40AlSr0.1CZ40AlSr0.1 나머지Remainder 40%40% 0.0900.090 0.0100.010 -- -- CZ40AlSr0.5CZ40AlSr0.5 나머지Remainder 40%40% 0.4500.450 0.0500.050 -- -- CZ40AlSr1.0CZ40AlSr1.0 나머지Remainder 40%40% 0.9000.900 0.1000.100 -- -- CZ40AlSr5.0CZ40AlSr5.0 나머지Remainder 40%40% 4.5004.500 0.5000.500 -- -- CZ40AlSr10.0CZ40AlSr10.0 나머지Remainder 40%40% 9.0009.000 1.0001.000 -- -- CZ40AlTiB0.1CZ40AlTiB0.1 나머지Remainder 40%40% 0.0940.094 -- 0.0050.005 0.0010.001 CZ40AlTiB10.0CZ40AlTiB10.0 나머지Remainder 40%40% 9.4009.400 -- 0.5000.500 0.1000.100 CZ40AlSrTiB0.5CZ40AlSrTiB0.5 나머지Remainder 40%40% 0.4370.437 0.0250.025 0.0120.012 0.0030.003 CZ42Al0.1CZ42Al0.1 나머지Remainder 42%42% 0.1000.100 -- -- -- CZ42Al0.5CZ42Al0.5 나머지Remainder 42%42% 0.5000.500 -- -- -- CZ42Al10.0CZ42Al10.0 나머지Remainder 42%42% 10.00010.000 -- -- -- CZ45AlTiB0.1CZ45AlTiB0.1 나머지Remainder 45%45% 0.0940.094 -- 0.0050.005 0.0010.001 CZ45AlTiB0.5CZ45AlTiB0.5 나머지Remainder 45%45% 0.4700.470 -- 0.0250.025 0.0050.005 CZ45AlSr0.5CZ45AlSr0.5 나머지Remainder 45%45% 0.4500.450 0.0500.050 -- -- CZ45AlSrTiB0.5CZ45AlSrTiB0.5 나머지Remainder 45%45% 0.4370.437 0.0250.025 0.0120.012 0.0030.003

표 1. 합금의 종류 및 성분조성Table 1. Alloy Types and Compositions

합 금 명Alloy Person 선경,(mm)fairyland, (mm) 절삭성Machinability 파단강도(Kgf)Breaking Strength (Kgf) 피절단면의 경면성Mirror surface of cut section 가공시가루발생Powder generation during processing 황동 2 종Brass two 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 많음plenty CZ35AlSr0.5CZ35AlSr0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ35AlTiB0.5CZ35AlTiB0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ40AlSr0.1CZ40AlSr0.1 0.250.25 양호Good 4.5-5.34.5-5.3 양호Good 적음Less CZ40AlSr0.5CZ40AlSr0.5 0.250.25 양호Good 4.5-5.34.5-5.3 양호Good 적음Less CZ40AlSr1.0CZ40AlSr1.0 0.250.25 양호Good 4.8-5.54.8-5.5 양호Good 적음Less CZ40AlSr5.0CZ40AlSr5.0 0.250.25 양호Good 5.2-6.35.2-6.3 양호Good 적음Less CZ40AlSr10.0CZ40AlSr10.0 0.250.25 양호Good 5.5-7.35.5-7.3 양호Good 적음Less CZ40AlTiB0.1CZ40AlTiB0.1 0.250.25 양호Good 4.5-5.34.5-5.3 보통usually 적음Less CZ40AlTiB10.0CZ40AlTiB10.0 0.250.25 양호Good 5.6-7.55.6-7.5 양호Good 적음Less CZ40AlSrTiB0.5CZ40AlSrTiB0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ42Al0.1CZ42Al0.1 0.250.25 양호Good 4.4-5.34.4-5.3 보통usually 적음Less CZ42Al0.5CZ42Al0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ42Al10.0CZ42Al10.0 0.250.25 양호Good 5.7-7.55.7-7.5 양호Good 적음Less CZ45AlTiB0.1CZ45AlTiB0.1 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ45AlTiB0.5CZ45AlTiB0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ45AlSr0.5CZ45AlSr0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less CZ45AlSrTiB0.5CZ45AlSrTiB0.5 0.250.25 양호Good 4.4-5.34.4-5.3 양호Good 적음Less

표 2. 합금의 종류 및 금형강에 대한 절삭시험결과Table 2. Cutting test results for alloy types and mold steel

Claims (3)

방전가공기 선재용 합금에 있어서,In the alloy for electric discharge machine wire, 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과,35.0-45.0 wt% (weight percentage) zinc (Zn), 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와,A mixed additive element added with one or two or more of aluminum (Al), strontium (Sr), titanium (Ti), and boron (B) having a total content of 0.1 to 10.0 wt% (% by weight), 나머지는 구리(Cu)로 조성하되,The rest is made of copper (Cu), 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 것을 특징으로 하는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)계 합금.The content ratio of the mixed additive elements of 0.1 to 10.0 wt% (weight percent) is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), and 0.005 to Copper (Cu) -zinc (Zn) -aluminum (Al) for electrode wires for electric discharge machining, characterized in that it is composed of 0.5 wt% (wt%) titanium (Ti) and 0.001-0.1 wt% (wt%) boron (B). ), Strontium (Sr), titanium (Ti), boron (B) -based alloys. 방전가공기 선재용 합금의 제조방법에 있어서,In the manufacturing method of the alloy for electric discharge machine wire, 목표로하는 합금성분에 따라 각각의 첨가원소들은 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과, 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와, 나머지는 구리(Cu)로 조성하되, 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)으로 조성되는 조성범위를 만족하도록 각각 평량하는 평량단계와,Depending on the target alloying components, each of the additional elements is 35.0-45.0 wt% (weight percent) zinc (Zn) and aluminum (Al), strontium (Sr), having a total content of 0.1-10.0 wt% (weight percent), The content ratio of the mixed additive elements added to one or two or more of titanium (Ti) and boron (B) and the remainder is made of copper (Cu), but is 0.1 to 10.0 wt% (weight percent). Is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), 0.005 to 0.5 wt% (weight percent) titanium (Ti), and 0.001 to 0.1 wt Composition range composed of copper (Cu) -zinc (Zn) -aluminum (Al), strontium (Sr), titanium (Ti), and boron (B) A basis weight step for each basis weight to satisfy, 평량단계후 먼저 동(Cu)을 용해하여 완전히 용해되면 용탕의 가열을 멈춘 후, 아연(Zn)을 한 덩어리씩 용탕 깊숙히 플런저로 밀어 넣어 용탕 속에서 반응시킴으로써 아연(Zn)의 산화를 최대한 억제하며 용해합금하며 계속하여 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti) 및 보론(B) 중에서 선택한 첨가원소도 같은 방법으로 투입하여 용해합금하는 용해합금단계와,After dissolving copper (Cu) completely after the basis weight step, the heating of the molten metal is stopped, and then zinc (Zn) is pushed deep into the molten metal into the plunger and reacted in the molten metal to minimize the oxidation of zinc (Zn). A molten alloy step in which the molten alloy is continuously added to the molten alloy by adding the selected element selected from aluminum (Al), strontium (Sr), titanium (Ti) and boron (B) in the same manner; 용해합금한 용탕을 주조가 적당한 온도까지 다시 가열한 후, 금형에 주조하여 슬라브 상태의 주괴로 제조하는 주괴제조단계와,An ingot manufacturing step of heating the molten alloyed molten alloy back to a suitable temperature and then casting the molten alloy into a slab ingot; 주괴제조단계를 거친 주괴를 열간압출 후 소둔처리와 냉간인발을 반복하여 선재를 제조하는 선재제조단계와,A wire rod manufacturing step of manufacturing wire rods by hot extrusion of the ingots subjected to the ingot manufacturing stage, followed by annealing and cold drawing; 선재제조단계를 거친 최종의 선재를 180 ∼ 200℃ 정도의 낮은 온도에서 소둔처리하여 잔류응력을 제거함과 동시에 강화효과를 주어 직선성과 탄성이 좋은 상태의 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)계 합금의 제조방법.The final wire rod after the wire manufacturing step is annealed at a low temperature of 180 ~ 200 ℃ to remove residual stress and strengthening effect. Copper (Zu) -zn (Zn) for electrode line ) -Aluminum (Al), strontium (Sr), titanium (Ti), boron (B) -based alloy manufacturing method. 방전가공기 선재용 합금의 제조방법에 있어서,In the manufacturing method of the alloy for electric discharge machine wire, 목표로하는 합금성분에 따라 각각의 첨가원소들은 35.0 ∼ 45.0 wt%(중량 백분율)아연(Zn)과, 총함량 0.1 ∼ 10.0 wt%(중량 백분율)를 가지는 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B) 중에서 1종 또는 2종 이상 첨가된 혼합첨가원소와, 나머지는 구리(Cu)로 조성하되, 상기 0.1 ∼ 10.0 wt%(중량 백분율)의 혼합첨가원소의 함량비는 0.1 ∼ 10.0 wt%(중량 백분율)알루미늄(Al)과, 0.01 ∼ 1.0 wt%(중량 백분율)스트론튬(Sr)과, 0.005 ∼ 0.5wt%(중량 백분율)티타늄(Ti)과, 0.001 ∼ 0.1 wt%(중량 백분율)보론(B)으로 조성되는 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)으로 조성되는 조성범위를 만족하도록 각각 평량하는 평량단계와,Depending on the target alloying components, each of the additional elements is 35.0-45.0 wt% (weight percent) zinc (Zn) and aluminum (Al), strontium (Sr), having a total content of 0.1-10.0 wt% (weight percent), The content ratio of the mixed additive elements added to one or two or more of titanium (Ti) and boron (B) and the remainder is made of copper (Cu), but is 0.1 to 10.0 wt% (weight percent). Is 0.1 to 10.0 wt% (weight percent) aluminum (Al), 0.01 to 1.0 wt% (weight percent) strontium (Sr), 0.005 to 0.5 wt% (weight percent) titanium (Ti), and 0.001 to 0.1 wt Composition range composed of copper (Cu) -zinc (Zn) -aluminum (Al), strontium (Sr), titanium (Ti), and boron (B) A basis weight step for each basis weight to satisfy, 평량단계후 먼저 동(Cu)을 용해하여 완전히 용해되면 용탕의 가열을 멈춘 후, 아연(Zn)을 한 덩어리씩 용탕 깊숙히 플런저로 밀어 넣어 용탕 속에서 반응시킴으로써 아연(Zn)의 산화를 최대한 억제하며 용해합금하며 계속하여 알루미늄(Al), 스트론튬(Sr), 티타늄(Ti) 및 보론(B) 중에서 선택한 첨가원소도 같은 방법으로 투입하여 용해합금하는 용해합금단계와,After dissolving copper (Cu) completely after the basis weight step, the heating of the molten metal is stopped, and then zinc (Zn) is pushed deep into the molten metal into the plunger and reacted in the molten metal to minimize the oxidation of zinc (Zn). A molten alloy step in which the molten alloy is continuously added to the molten alloy by adding the selected element selected from aluminum (Al), strontium (Sr), titanium (Ti) and boron (B) in the same manner; 용해합금한 용탕을 주조가 적당한 온도까지 다시 가열한 후, 연속주조에 의해 연속적인 선재상태의 주괴로 제조하는 연속주조단계와,A continuous casting step of heating the molten alloyed molten alloy back to a suitable temperature, and then manufacturing the molten alloy into a continuous wire ingot by continuous casting; 이를 가지고 직접적으로 소둔처리와 냉간인발을 반복하여 선재를 목표로하는 선경으로 인발하여 제조하는 선재제조단계와,With this, the wire rod manufacturing step is carried out by directly drawing an annealing treatment and cold drawing, and drawing the wire with the target of the wire rod, 선재제조단계를 거친 최종의 선재를 180 ∼ 200℃ 정도의 낮은 온도에서 소둔처리하여 잔류응력을 제거함과 동시에 강화효과를 주어 직선성과 탄성이 좋은 상태의 방전가공기 전극선용 동(Cu)-아연(Zn)-알루미늄(Al), 스트론튬(Sr), 티타늄(Ti), 보론(B)계 합금의 제조방법.The final wire rod after the wire manufacturing step is annealed at a low temperature of 180 ~ 200 ℃ to remove residual stress and strengthening effect. Copper (Zu) -zn (Zn) for electrode line ) -Aluminum (Al), strontium (Sr), titanium (Ti), boron (B) -based alloy manufacturing method.
KR1019990006912A 1999-03-03 1999-03-03 Cu-Zn-Al, Sr, Ti, B alloys for EDM(Energy Discharge Machine) wire and its manufacturing method KR100302546B1 (en)

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US7053005B2 (en) 2000-05-02 2006-05-30 Samsung Electronics Co., Ltd. Method of forming a silicon oxide layer in a semiconductor manufacturing process
US7179537B2 (en) 2000-05-02 2007-02-20 Samsung Electronics Co., Ltd. Spin-on glass composition and method of forming silicon oxide layer in semiconductor manufacturing process using the same
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US7053005B2 (en) 2000-05-02 2006-05-30 Samsung Electronics Co., Ltd. Method of forming a silicon oxide layer in a semiconductor manufacturing process
US7179537B2 (en) 2000-05-02 2007-02-20 Samsung Electronics Co., Ltd. Spin-on glass composition and method of forming silicon oxide layer in semiconductor manufacturing process using the same
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CN102899523A (en) * 2012-10-26 2013-01-30 镇江金叶螺旋桨有限公司 Zirconium and strontium compound micro-alloyed nickel-aluminum bronze and preparation method thereof
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CN102912183A (en) * 2012-10-26 2013-02-06 镇江金叶螺旋桨有限公司 Strontium, titanium and boron composite microalloying manganese brass and preparation method of manganese brass
CN102912184A (en) * 2012-10-26 2013-02-06 江苏大学 Strontium-titanium-boron composite micro-alloyed high-manganese aluminum bronze and method for manufacturing same
CN102925745A (en) * 2012-10-26 2013-02-13 江苏大学 Mg-Sr-Ti-B composite micro-alloyed manganese brass and preparation method thereof
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