KR100805753B1 - 에틸렌을 특히 1-헥센으로 올리고머화 처리하기 위한 촉매조성물 및 방법 - Google Patents
에틸렌을 특히 1-헥센으로 올리고머화 처리하기 위한 촉매조성물 및 방법Info
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
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- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
실시예번호 | 올리고머 비율(중량%) | C6 중의 1-헥센(중량%) | |||
C4 | C6 | C8 | C10+ | ||
1 | 1.3 | 84.4 | 1 | 2.3 | 98.9 |
2 | 1.1 | 82.7 | 1.1 | 2.4 | 99.7 |
3 | 1.7 | 70.2 | 2 | 3.9 | 98.4 |
4 | 20 | 5 | 0.5 | 2 | 55.0 |
5 | 0.6 | 85.4 | 0.7 | 2.4 | 99.4 |
6 | 2.3 | 74.2 | 0.6 | 2.4 | 95.2 |
7 | 1.7 | 70.5 | 1.6 | 3.5 | 98.0 |
8 | 2.6 | 61.1 | 1.1 | 4.1 | 97.3 |
Claims (11)
- - 크롬 화합물 1 종 이상,- 하기 화학식 1을 갖는 원소 M의 아릴옥시 화합물 1 종 이상,화학식 1M(RO)2-nXn[상기 화학식에서, M은 마그네슘, 칼슘, 스트론튬 및 바륨으로 구성된 군에서 선택되며, RO는 C6-C80의 아릴옥시 라디칼이고, X는 할로겐 또는, C1-C30의 히드로카르빌 라디칼이며, n은 0∼1의 정수임],- i) 하기 화학식 2에 해당하는 트리스(히드로카르빌)알루미늄, ii) 하기 화학식 2에 해당하는 히드로카르빌알루미늄의 염화물 또는 브롬화물, 그리고 iii) 알루미녹산으로 구성된 군에서 선택된 알루미늄 화합물 1 종 이상화학식 2AlR'mY3-m[상기 화학식에서, R'은 C1-C6 히드로카르빌 라디칼이고, Y는 염소 또는 브롬 원자이며, m은 1∼3임]의 혼합에 의해 얻는 것을 특징으로 하는 촉매 조성물.
- 제1항에 있어서, 크롬 화합물은 동일하거나 또는 상이하며, 할로겐화물, 카르복실레이트, 아세틸아세토네이트, 알콕시 음이온 또는 아릴옥시 음이온으로 구성된 군에서 선택된 음이온 1 종 이상을 포함하는 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 화학식 1의 원소 M의 아릴옥시 화합물 중에서 RO 아릴옥시 라디칼은 하기 화학식 3을 갖는 것을 특징으로 하는 촉매 조성물.화학식 3상기 화학식에서, R1, R2, R3, R4 및 R5는 서로 동일하거나 또는 상이하며, 이들 각각은 수소 원자, 할로겐 원자 또는, C1-C16의 히드로카르빌 라디칼이다.
- 제1항 또는 제2항에 있어서, 원소 M의 아릴옥시 화합물은 비스(2,6-디페닐펜옥시)마그네슘, 비스(2-t-부틸-6-페닐펜옥시)마그네슘 또는 비스(2,4-디-t-부틸-6-페닐펜옥시)마그네슘인 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 히드로카르빌알루미늄 화합물은 디클로로에틸알루미늄, 에틸알루미늄 세스퀴염화물, 클로로디에틸알루미늄, 클로로디이소부틸알루미늄, 트리에틸알루미늄, 트리프로필알루미늄, 트리이소부틸알루미늄 또는 메틸알루미녹산인 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 히드로카르빌 알루미늄 화합물은 트리에틸알루미늄인 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 촉매 성분은 1 종 이상의 포화 탄화수소, 1 종 이상의 불포화 탄화수소, 올레핀 또는 디올레핀 및/또는 1 종 이상의 방향족 탄화수소를 포함하는 용매 중에서 접촉을 수행하는 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 촉매 용액 중의 크롬 농도는 1×10-5∼0.1 몰/ℓ인 것을 특징으로 하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 원소 M의 아릴옥시 화합물:크롬 화합물의 몰비는 1:1∼30:1이고, 히드로카르빌알루미늄:크롬 화합물의 몰비는 1:1∼35:1인 것을 특징으로 하는 것인 촉매 조성물.
- 제1항 또는 제2항에 의한 촉매 조성물을 사용하는 에틸렌의 올리고머화 방법.
- 제10항에 있어서, 에틸렌의 올리고머화 반응은 0.5∼15 ㎫의 압력하에서, 20℃∼180℃의 온도에서 수행하는 것을 특징으로 하는 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR99/16509 | 1999-12-24 | ||
FR9916509A FR2802833B1 (fr) | 1999-12-24 | 1999-12-24 | Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en hexene-1 |
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KR20010062617A KR20010062617A (ko) | 2001-07-07 |
KR100805753B1 true KR100805753B1 (ko) | 2008-02-21 |
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KR1020000080167A KR100805753B1 (ko) | 1999-12-24 | 2000-12-22 | 에틸렌을 특히 1-헥센으로 올리고머화 처리하기 위한 촉매조성물 및 방법 |
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US (1) | US6828269B2 (ko) |
EP (1) | EP1110930B1 (ko) |
JP (1) | JP4747416B2 (ko) |
KR (1) | KR100805753B1 (ko) |
DE (1) | DE60005123T2 (ko) |
ES (1) | ES2207473T3 (ko) |
FR (1) | FR2802833B1 (ko) |
TW (1) | TW562694B (ko) |
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WO2019010498A1 (en) | 2017-07-07 | 2019-01-10 | Siluria Technologies, Inc. | SYSTEMS AND METHODS FOR OXIDIZING METHANE COUPLING |
WO2020114745A1 (en) | 2018-12-04 | 2020-06-11 | Exxonmobil Chemical Patents Inc. | Methods for separating linear alpha olefins from combined product streams |
CN113597419A (zh) | 2019-03-13 | 2021-11-02 | Tpc集团有限责任公司 | 选择性地生产不同线性α-烯烃的弹性制造*** |
FR3112969B1 (fr) * | 2020-07-30 | 2022-08-05 | Ifp Energies Now | Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 |
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EP0808849A1 (en) * | 1996-05-20 | 1997-11-26 | Showa Denko Kabushiki Kaisha | Process for the production of ethylenic polymers |
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GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
FR2093306A6 (fr) * | 1970-06-09 | 1972-01-28 | Solvay | Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines |
US4024050A (en) * | 1975-01-07 | 1977-05-17 | Nalco Chemical Company | Phosphorous ester antifoulants in crude oil refining |
JPS5952166B2 (ja) * | 1976-06-29 | 1984-12-18 | 三井化学株式会社 | ポリオレフインの製造方法 |
US4422957A (en) * | 1980-05-02 | 1983-12-27 | Phillips Petroleum Company | Methods of producing polyolefins using supported high efficiency polyolefin catalyst components |
US4547475A (en) * | 1984-09-07 | 1985-10-15 | The Dow Chemical Company | Magnesium halide catalyst support and transition metal catalyst prepared thereon |
US5543375A (en) * | 1994-02-18 | 1996-08-06 | Phillips Petroleum Company | Olefin production |
US5506184A (en) * | 1994-06-22 | 1996-04-09 | Mobil Oil Corporation | Olefin polymerization catalyst system |
JP3153850B2 (ja) * | 1996-05-20 | 2001-04-09 | 昭和電工株式会社 | エチレン系重合体の製造方法 |
JP3572811B2 (ja) * | 1996-06-17 | 2004-10-06 | 東ソー株式会社 | クロムを含有する廃触媒の処理方法 |
JP3823429B2 (ja) * | 1996-06-28 | 2006-09-20 | 住友化学株式会社 | 触媒系及びオレフィンの反応方法 |
JPH1119158A (ja) * | 1997-07-01 | 1999-01-26 | Sakai Medical Co Ltd | 入浴用車椅子 |
JP4352513B2 (ja) * | 1998-12-11 | 2009-10-28 | 東ソー株式会社 | エチレンの三量化触媒及びその触媒を用いたエチレンの三量化方法 |
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1999
- 1999-12-24 FR FR9916509A patent/FR2802833B1/fr not_active Expired - Lifetime
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2000
- 2000-12-11 DE DE60005123T patent/DE60005123T2/de not_active Expired - Lifetime
- 2000-12-11 EP EP00403477A patent/EP1110930B1/fr not_active Expired - Lifetime
- 2000-12-11 ES ES00403477T patent/ES2207473T3/es not_active Expired - Lifetime
- 2000-12-22 KR KR1020000080167A patent/KR100805753B1/ko active IP Right Grant
- 2000-12-22 TW TW089127720A patent/TW562694B/zh not_active IP Right Cessation
- 2000-12-25 JP JP2000392368A patent/JP4747416B2/ja not_active Expired - Lifetime
- 2000-12-26 US US09/745,441 patent/US6828269B2/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0808849A1 (en) * | 1996-05-20 | 1997-11-26 | Showa Denko Kabushiki Kaisha | Process for the production of ethylenic polymers |
Also Published As
Publication number | Publication date |
---|---|
EP1110930B1 (fr) | 2003-09-10 |
FR2802833B1 (fr) | 2002-05-10 |
DE60005123D1 (de) | 2003-10-16 |
EP1110930A1 (fr) | 2001-06-27 |
DE60005123T2 (de) | 2004-03-25 |
US20010023281A1 (en) | 2001-09-20 |
KR20010062617A (ko) | 2001-07-07 |
JP2001219071A (ja) | 2001-08-14 |
FR2802833A1 (fr) | 2001-06-29 |
TW562694B (en) | 2003-11-21 |
JP4747416B2 (ja) | 2011-08-17 |
ES2207473T3 (es) | 2004-06-01 |
US6828269B2 (en) | 2004-12-07 |
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