KR100304416B1 - 환식올레핀개환복분해중합체의수소화물의제조방법 - Google Patents
환식올레핀개환복분해중합체의수소화물의제조방법 Download PDFInfo
- Publication number
- KR100304416B1 KR100304416B1 KR1019980019147A KR19980019147A KR100304416B1 KR 100304416 B1 KR100304416 B1 KR 100304416B1 KR 1019980019147 A KR1019980019147 A KR 1019980019147A KR 19980019147 A KR19980019147 A KR 19980019147A KR 100304416 B1 KR100304416 B1 KR 100304416B1
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- South Korea
- Prior art keywords
- group
- ring
- hydride
- polymer
- opening metathesis
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Description
Claims (5)
- 일반식(1) :(식중, R1, R2, R3및 R4는, 서로 동일해도 되고 달라도 되며, 개별적으로, 수소원자, 탄소수 1∼12의 알킬기, 아릴기, 아랄킬기, 알콕시기, 할로겐원자, 탄소수 1∼12의 할로겐화알킬기, 시아노기, 카르복시기 및 알콕시카르보닐기로 이루어진 군으로부터 선택된 1종이고, x는 0∼3의 정수임)로 표시되는 환식 올레핀의 환식 올레핀개환복분해중합체를, 수소의 존재하에, 하기 일반식(2) :MHkQmTpZq(2)[식중, k는 0 또는 1의 정수, m은 1∼3의 정수, p는 0 또는 1의 정수, q는 2∼4의 정수, M은 루테늄, 로듐, 오스뮴, 이리듐, 팔라듐, 백금 또는 니켈원자, H는 수소원자, Q는 할로겐원자, T는 CO, NO, 톨루엔, 아세토니트릴 또는 테트라하이드로푸란, Z는 하기 일반식(3) :PR'1R'2R'3(3)(식중, P는 인원자, R'1, R'2및 R'3은, 서로 동일해도 되고 달라도 되며, 개별적으로, 직선형, 분기형 또는 환식 알킬기, 직선형, 분기형 또는 환식 알케닐기, 아릴기, 직선형, 분기형 또는 환식 알콕시기 및 아릴옥시기로 이루어진 군으로부터 선택된 1종임)으로 표시되는 유기인화합물임]로 표시되는 유기금속착물과 아민화합물로 주로 이루어진 수소화촉매를 이용해서 수소화하고,상기 유기금속착물에 대한 아민화합물의 당량비가 0.1 내지 1,000의 범위인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, M은 루테늄원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 3인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, M은 루테늄원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 4인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 4항에 있어서, M은 오스뮴원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 3인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, 상기 아민화합물은 트리에틸아민인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13848597 | 1997-05-28 | ||
JP97-138485 | 1997-05-28 | ||
JP1997-138485 | 1997-05-28 | ||
JP30178697 | 1997-11-04 | ||
JP1997-301786 | 1997-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR19980087394A KR19980087394A (ko) | 1998-12-05 |
KR100304416B1 true KR100304416B1 (ko) | 2002-05-09 |
Family
ID=26471491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019980019147A KR100304416B1 (ko) | 1997-05-28 | 1998-05-27 | 환식올레핀개환복분해중합체의수소화물의제조방법 |
Country Status (3)
Country | Link |
---|---|
US (1) | US6197894B1 (ko) |
KR (1) | KR100304416B1 (ko) |
TW (1) | TW411348B (ko) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002076920A1 (en) * | 2001-03-26 | 2002-10-03 | Dow Global Technologies Inc. | Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins |
JP2002363263A (ja) * | 2001-06-08 | 2002-12-18 | Nippon Zeon Co Ltd | 開環共重合体、開環共重合体水素化物、それらの製造方法および組成物 |
KR20040111565A (ko) | 2002-04-29 | 2004-12-31 | 다우 글로벌 테크놀로지스 인크. | 종자유의 공업적 활용을 위한 통합 화학 공정 |
CN101003459B (zh) * | 2002-10-24 | 2011-08-10 | 陶氏环球技术有限责任公司 | 烯烃易位产物混合物的稳定 |
CN1802341A (zh) * | 2003-01-13 | 2006-07-12 | 卡吉尔公司 | 制备工业化学品的方法 |
ATE461954T1 (de) * | 2003-01-31 | 2010-04-15 | Zeon Corp | Polymerisierbare zusammensetzung, thermoplastische harzzusammensetzung, vernetztes harz und vernetztes harz enthaltende verbundwerkstoffe |
CN100588638C (zh) * | 2003-10-09 | 2010-02-10 | 陶氏环球技术公司 | 合成不饱和醇的改进方法 |
WO2006076364A2 (en) * | 2005-01-10 | 2006-07-20 | Cargill, Incorporated | Candle and candle wax containing metathesis and metathesis-like products |
WO2007081987A2 (en) | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
MX2008011524A (es) * | 2006-03-07 | 2009-02-03 | Elevance Renewable Sciences | Composiciones que comprenden esteres de poliol insaturados metatesizados. |
US8888908B2 (en) * | 2006-03-07 | 2014-11-18 | Elevance Renewable Sciences, Inc. | Colorant compositions comprising metathesized unsaturated polyol esters |
WO2008008420A1 (en) * | 2006-07-12 | 2008-01-17 | Elevance Renewable Sciences, Inc. | Hot melt adhesive compositions comprising metathesized unsaturated polyol ester wax |
CN101563315B (zh) * | 2006-07-12 | 2013-08-14 | 埃莱文斯可更新科学公司 | 环烯烃与种子油等的开环交叉复分解反应 |
US8067610B2 (en) | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
CN101558032B (zh) * | 2006-10-13 | 2013-06-19 | 埃莱文斯可更新科学公司 | 包括氢化的复分解方法及与其相关的组合物 |
CN102123979A (zh) * | 2006-10-13 | 2011-07-13 | 埃莱文斯可更新科学公司 | 通过烯烃复分解由内烯烃合成末端烯烃的方法 |
WO2008048520A2 (en) | 2006-10-13 | 2008-04-24 | Elevance Renewable Sciences, Inc. | Methods of making organic compounds by metathesis and hydrocyanation |
EP3281931A1 (en) * | 2006-10-13 | 2018-02-14 | Elevance Renewable Sciences, Inc. | Methods of making organic compounds by metathesis |
US8263712B2 (en) * | 2007-09-04 | 2012-09-11 | Exxonmobil Research And Engineering Company | Production of elastomeric functionalized olefin polymers |
EP2350159A1 (en) * | 2008-10-31 | 2011-08-03 | Dow Global Technologies LLC | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
US9051519B2 (en) | 2009-10-12 | 2015-06-09 | Elevance Renewable Sciences, Inc. | Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters |
CN104508101A (zh) | 2011-12-28 | 2015-04-08 | 艾勒旺斯可再生科学公司 | 可再生脂肪酸蜡及其制造方法 |
EA033372B1 (ru) | 2012-06-20 | 2019-10-31 | Elevance Renewable Sciences | Композиция, полученная метатезисом |
EP2676969B1 (en) | 2012-06-22 | 2016-06-01 | University Of Waterloo | Tandem metathesis and hydrogenation of diene-based polymers in latex |
JP2020516695A (ja) | 2017-04-12 | 2020-06-11 | ウリゲン ファーマシューティカルズ、インコーポレイテッド | 改善された安定性を備えた注射器中に局所麻酔薬、緩衝液、およびグルコサミノグリカンを含む製品 |
Citations (1)
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JPH04202404A (ja) * | 1990-11-30 | 1992-07-23 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
Family Cites Families (7)
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JP2684796B2 (ja) | 1989-12-04 | 1997-12-03 | 日本合成ゴム株式会社 | 重合体の水添方法 |
US5075388A (en) * | 1990-12-13 | 1991-12-24 | Rempel Garry L | Amine modified hydrogenation of nitrile rubber |
EP0589041B1 (en) * | 1991-06-11 | 1996-09-04 | Nippon Zeon Co., Ltd. | Hydrogenated thermoplastic norbornene polymer, production thereof, and optical element base, optical element and lens molded therefrom |
JP3151862B2 (ja) | 1991-06-11 | 2001-04-03 | 日本ゼオン株式会社 | 熱可塑性ノルボルネン系重合体水素添加物、その製造方法、それを成形した光学素子基板、光学素子、及びレンズ |
JPH05239124A (ja) | 1992-02-27 | 1993-09-17 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
JP3277624B2 (ja) | 1993-07-30 | 2002-04-22 | 日本ゼオン株式会社 | メタセシス重合体の水素添加方法 |
US5539060A (en) * | 1993-07-30 | 1996-07-23 | Nippon Zeon Co., Ltd. | Method for hydrogenation of metathesis polymers |
-
1998
- 1998-05-27 TW TW087108216A patent/TW411348B/zh not_active IP Right Cessation
- 1998-05-27 US US09/084,593 patent/US6197894B1/en not_active Expired - Lifetime
- 1998-05-27 KR KR1019980019147A patent/KR100304416B1/ko not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04202404A (ja) * | 1990-11-30 | 1992-07-23 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
US6197894B1 (en) | 2001-03-06 |
TW411348B (en) | 2000-11-11 |
KR19980087394A (ko) | 1998-12-05 |
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