KR100304416B1 - 환식올레핀개환복분해중합체의수소화물의제조방법 - Google Patents
환식올레핀개환복분해중합체의수소화물의제조방법 Download PDFInfo
- Publication number
- KR100304416B1 KR100304416B1 KR1019980019147A KR19980019147A KR100304416B1 KR 100304416 B1 KR100304416 B1 KR 100304416B1 KR 1019980019147 A KR1019980019147 A KR 1019980019147A KR 19980019147 A KR19980019147 A KR 19980019147A KR 100304416 B1 KR100304416 B1 KR 100304416B1
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- KR
- South Korea
- Prior art keywords
- group
- ring
- hydride
- polymer
- opening metathesis
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Description
Claims (5)
- 일반식(1) :(식중, R1, R2, R3및 R4는, 서로 동일해도 되고 달라도 되며, 개별적으로, 수소원자, 탄소수 1∼12의 알킬기, 아릴기, 아랄킬기, 알콕시기, 할로겐원자, 탄소수 1∼12의 할로겐화알킬기, 시아노기, 카르복시기 및 알콕시카르보닐기로 이루어진 군으로부터 선택된 1종이고, x는 0∼3의 정수임)로 표시되는 환식 올레핀의 환식 올레핀개환복분해중합체를, 수소의 존재하에, 하기 일반식(2) :MHkQmTpZq(2)[식중, k는 0 또는 1의 정수, m은 1∼3의 정수, p는 0 또는 1의 정수, q는 2∼4의 정수, M은 루테늄, 로듐, 오스뮴, 이리듐, 팔라듐, 백금 또는 니켈원자, H는 수소원자, Q는 할로겐원자, T는 CO, NO, 톨루엔, 아세토니트릴 또는 테트라하이드로푸란, Z는 하기 일반식(3) :PR'1R'2R'3(3)(식중, P는 인원자, R'1, R'2및 R'3은, 서로 동일해도 되고 달라도 되며, 개별적으로, 직선형, 분기형 또는 환식 알킬기, 직선형, 분기형 또는 환식 알케닐기, 아릴기, 직선형, 분기형 또는 환식 알콕시기 및 아릴옥시기로 이루어진 군으로부터 선택된 1종임)으로 표시되는 유기인화합물임]로 표시되는 유기금속착물과 아민화합물로 주로 이루어진 수소화촉매를 이용해서 수소화하고,상기 유기금속착물에 대한 아민화합물의 당량비가 0.1 내지 1,000의 범위인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, M은 루테늄원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 3인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, M은 루테늄원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 4인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 4항에 있어서, M은 오스뮴원자, Q는 염소원자, R'1, R'2및 R'3은 각각 페닐기이고, k는 0, m은 2, p는 0, q는 3인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
- 제 1항에 있어서, 상기 아민화합물은 트리에틸아민인 것을 특징으로 하는 환식 올레핀개환복분해중합체의 수소화물의 제조방법.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1997-138485 | 1997-05-28 | ||
JP97-138485 | 1997-05-28 | ||
JP13848597 | 1997-05-28 | ||
JP1997-301786 | 1997-11-04 | ||
JP30178697 | 1997-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR19980087394A KR19980087394A (ko) | 1998-12-05 |
KR100304416B1 true KR100304416B1 (ko) | 2002-05-09 |
Family
ID=26471491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019980019147A KR100304416B1 (ko) | 1997-05-28 | 1998-05-27 | 환식올레핀개환복분해중합체의수소화물의제조방법 |
Country Status (3)
Country | Link |
---|---|
US (1) | US6197894B1 (ko) |
KR (1) | KR100304416B1 (ko) |
TW (1) | TW411348B (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002076920A1 (en) * | 2001-03-26 | 2002-10-03 | Dow Global Technologies Inc. | Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins |
JP2002363263A (ja) * | 2001-06-08 | 2002-12-18 | Nippon Zeon Co Ltd | 開環共重合体、開環共重合体水素化物、それらの製造方法および組成物 |
MXPA04010803A (es) | 2002-04-29 | 2005-03-07 | Dow Global Technologies Inc | Procesos quimicos integrados para la utilizacion industrial de aceites de semilla. |
JP4490278B2 (ja) * | 2002-10-24 | 2010-06-23 | ダウ グローバル テクノロジーズ インコーポレイティド | オレフィン複分解生成混合物の安定化 |
CA2512815A1 (en) * | 2003-01-13 | 2004-07-29 | Cargill, Incorporated | Method for making industrial chemicals |
KR20050106407A (ko) * | 2003-01-31 | 2005-11-09 | 니폰 제온 가부시키가이샤 | 중합성 조성물, 열가소성 수지 조성물, 가교 수지 및 가교수지 복합 재료 |
WO2005040077A2 (en) * | 2003-10-09 | 2005-05-06 | Dow Global Technologies Inc. | An improved process for the synthesis of unsaturated alcohols |
BRPI0606718A2 (pt) * | 2005-01-10 | 2009-07-14 | Cargill Inc | vela e cera para vela contendo produtos de metátese e semelhantes a metátese |
WO2007081987A2 (en) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
MX2008011524A (es) | 2006-03-07 | 2009-02-03 | Elevance Renewable Sciences | Composiciones que comprenden esteres de poliol insaturados metatesizados. |
WO2007103460A2 (en) * | 2006-03-07 | 2007-09-13 | Elevance Renewable Sciences, Inc. | Colorant compositions comprising metathesized unsaturated polyol esters |
CN101563315B (zh) * | 2006-07-12 | 2013-08-14 | 埃莱文斯可更新科学公司 | 环烯烃与种子油等的开环交叉复分解反应 |
CN101563434B (zh) * | 2006-07-12 | 2012-01-25 | 埃莱文斯可更新科学公司 | 包含复分解不饱和多元醇酯蜡的热熔性胶粘剂组合物 |
US8067610B2 (en) * | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
WO2008063322A2 (en) * | 2006-10-13 | 2008-05-29 | Elevance Renewable Sciences, Inc. | Metathesis methods involving hydrogenation and compositions relating to same |
CN106083579A (zh) | 2006-10-13 | 2016-11-09 | 埃莱文斯可更新科学公司 | 通过烯烃复分解由内烯烃合成末端烯烃的方法 |
EP2076483A4 (en) | 2006-10-13 | 2013-12-04 | Elevance Renewable Sciences | METHODS FOR PRODUCING ORGANIC COMPOUNDS BY METATHESIS AND HYDROCYANATION |
EP3281931A1 (en) * | 2006-10-13 | 2018-02-14 | Elevance Renewable Sciences, Inc. | Methods of making organic compounds by metathesis |
US8263712B2 (en) * | 2007-09-04 | 2012-09-11 | Exxonmobil Research And Engineering Company | Production of elastomeric functionalized olefin polymers |
WO2010051268A1 (en) * | 2008-10-31 | 2010-05-06 | Dow Global Technologies Inc. | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
US9051519B2 (en) | 2009-10-12 | 2015-06-09 | Elevance Renewable Sciences, Inc. | Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters |
CN104508101A (zh) | 2011-12-28 | 2015-04-08 | 艾勒旺斯可再生科学公司 | 可再生脂肪酸蜡及其制造方法 |
JP2015523440A (ja) | 2012-06-20 | 2015-08-13 | エレヴァンス リニューアブル サイエンシズ インコーポ | 天然油メタセシス組成物及びその方法 |
EP2676969B1 (en) | 2012-06-22 | 2016-06-01 | University Of Waterloo | Tandem metathesis and hydrogenation of diene-based polymers in latex |
US11491179B2 (en) | 2017-04-12 | 2022-11-08 | Urigen Pharmaceuticals, Inc. | Article of manufacture comprising local anesthetic, buffer, and glycosaminoglycan in syringe with improved stability |
EP3950765A4 (en) | 2019-03-27 | 2022-12-28 | Zeon Corporation | RING OPENING POLYMER HYDRIDE, RESIN COMPOSITION AND SHAPED ARTICLE |
Citations (1)
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JPH04202404A (ja) * | 1990-11-30 | 1992-07-23 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
Family Cites Families (7)
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JP2684796B2 (ja) | 1989-12-04 | 1997-12-03 | 日本合成ゴム株式会社 | 重合体の水添方法 |
US5075388A (en) * | 1990-12-13 | 1991-12-24 | Rempel Garry L | Amine modified hydrogenation of nitrile rubber |
JP3151862B2 (ja) | 1991-06-11 | 2001-04-03 | 日本ゼオン株式会社 | 熱可塑性ノルボルネン系重合体水素添加物、その製造方法、それを成形した光学素子基板、光学素子、及びレンズ |
WO1992022590A1 (en) * | 1991-06-11 | 1992-12-23 | Nippon Zeon Co., Ltd. | Hydrogenated thermoplastic norbornene polymer, production thereof, and optical element base, optical element and lens molded therefrom |
JPH05239124A (ja) | 1992-02-27 | 1993-09-17 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
US5539060A (en) * | 1993-07-30 | 1996-07-23 | Nippon Zeon Co., Ltd. | Method for hydrogenation of metathesis polymers |
JP3277624B2 (ja) | 1993-07-30 | 2002-04-22 | 日本ゼオン株式会社 | メタセシス重合体の水素添加方法 |
-
1998
- 1998-05-27 US US09/084,593 patent/US6197894B1/en not_active Expired - Lifetime
- 1998-05-27 KR KR1019980019147A patent/KR100304416B1/ko not_active IP Right Cessation
- 1998-05-27 TW TW087108216A patent/TW411348B/zh not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04202404A (ja) * | 1990-11-30 | 1992-07-23 | Japan Synthetic Rubber Co Ltd | 開環重合体水素化物の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
KR19980087394A (ko) | 1998-12-05 |
TW411348B (en) | 2000-11-11 |
US6197894B1 (en) | 2001-03-06 |
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