JPS636106B2 - - Google Patents

Info

Publication number: JPS636106B2
Authority: JP; Japan
Prior art keywords: weight; parts; styrene; methylstyrene; copolymer
Prior art date: 1981-03-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP3319881A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57149348A (en

Inventor

Mitsuo Abe

Hiroshi Kinomura

Hideji Tsuchikawa

Teizo Fukuda

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

JSR Corp

Original Assignee

Japan Synthetic Rubber Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-03-10

Filing date

1981-03-10

Publication date

1988-02-08

1981-03-10 Application filed by Japan Synthetic Rubber Co Ltd filed Critical Japan Synthetic Rubber Co Ltd

1981-03-10 Priority to JP3319881A priority Critical patent/JPS57149348A/ja

1982-09-14 Publication of JPS57149348A publication Critical patent/JPS57149348A/ja

1988-02-08 Publication of JPS636106B2 publication Critical patent/JPS636106B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 claims description 60
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 50
239000000178 monomer Substances 0.000 claims description 42
229920000578 graft copolymer Polymers 0.000 claims description 34
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 30
229920001577 copolymer Polymers 0.000 claims description 27
238000006116 polymerization reaction Methods 0.000 claims description 26
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 24
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 24
229920001971 elastomer Polymers 0.000 claims description 23
239000011342 resin composition Substances 0.000 claims description 23
229920000126 latex Polymers 0.000 claims description 21
239000004816 latex Substances 0.000 claims description 21
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 19
-1 vinyl cyanide compound Chemical class 0.000 claims description 19
238000007334 copolymerization reaction Methods 0.000 claims description 15
239000002245 particle Substances 0.000 claims description 14
238000002156 mixing Methods 0.000 claims description 9
229920005992 thermoplastic resin Polymers 0.000 claims description 7
238000007720 emulsion polymerization reaction Methods 0.000 claims description 5
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
230000007423 decrease Effects 0.000 description 19
238000000034 method Methods 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 12
229920002857 polybutadiene Polymers 0.000 description 11
239000005062 Polybutadiene Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
230000000704 physical effect Effects 0.000 description 6
238000003756 stirring Methods 0.000 description 5
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
230000000379 polymerizing effect Effects 0.000 description 4
229940096992 potassium oleate Drugs 0.000 description 4
MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 4
239000000843 powder Substances 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
239000011790 ferrous sulphate Substances 0.000 description 3
235000003891 ferrous sulphate Nutrition 0.000 description 3
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000005259 measurement Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000008360 acrylonitriles Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000009776 industrial production Methods 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000010992 reflux Methods 0.000 description 2
239000005060 rubber Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
HBPIMFIQONRGEH-UHFFFAOYSA-M C(CN(CC(=O)O)CC(=O)O)N(CC(=O)O)CC(=O)O.S([O-])O.C=O.[Na+].S(=O)(=O)(O)O Chemical compound C(CN(CC(=O)O)CC(=O)O)N(CC(=O)O)CC(=O)O.S([O-])O.C=O.[Na+].S(=O)(=O)(O)O HBPIMFIQONRGEH-UHFFFAOYSA-M 0.000 description 1
OJRUSAPKCPIVBY-KQYNXXCUSA-N C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N Chemical compound C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N OJRUSAPKCPIVBY-KQYNXXCUSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
230000032683 aging Effects 0.000 description 1
230000003712 anti-aging effect Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229940125758 compound 15 Drugs 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
229920003244 diene elastomer Polymers 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000008103 glucose Substances 0.000 description 1
238000010559 graft polymerization reaction Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
238000004898 kneading Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000012778 molding material Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000012966 redox initiator Substances 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP3319881A 1981-03-10 1981-03-10 Thermoplastic resin composition Granted JPS57149348A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP3319881A JPS57149348A (en)	1981-03-10	1981-03-10	Thermoplastic resin composition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP3319881A JPS57149348A (en)	1981-03-10	1981-03-10	Thermoplastic resin composition

Publications (2)

Publication Number	Publication Date
JPS57149348A JPS57149348A (en)	1982-09-14
JPS636106B2 true JPS636106B2 (ko)	1988-02-08

Family

ID=12379776

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP3319881A Granted JPS57149348A (en)	1981-03-10	1981-03-10	Thermoplastic resin composition

Country Status (1)

Country	Link
JP (1)	JPS57149348A (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5849741A (ja) *	1981-06-17	1983-03-24	Sumitomo Naugatuck Co Ltd	グラフトコポリマ−および樹脂の配合物
JPS5817141A (ja) *	1981-07-23	1983-02-01	Mitsubishi Rayon Co Ltd	加工性良好なスチレン系樹脂組成物
JPH0247118A (ja) *	1988-08-10	1990-02-16	Mitsubishi Rayon Co Ltd	熱可塑性樹脂用耐候性耐衝撃性改質剤
GB2349926B (en)	1999-04-15	2003-08-06	Komatsu Mfg Co Ltd	Shift control apparatus of working vehicle
KR100409071B1 (ko) *	2000-07-03	2003-12-11	주식회사 엘지화학	열안정성이 우수한 내열성 열가소성 수지의 제조방법
KR100484720B1 (ko) *	2001-11-20	2005-04-20	주식회사 엘지화학	열가소성 수지 및 그 제조방법

1981
- 1981-03-10 JP JP3319881A patent/JPS57149348A/ja active Granted

Also Published As

Publication number	Publication date
JPS57149348A (en)	1982-09-14

Publication	Publication Date	Title
KR920000740B1 (ko)	1992-01-21	열가소성 수지의 제조방법
JPS6347745B2 (ko)	1988-09-26
EP0208382B1 (en)	1991-09-18	Rubber-reinforced styrenic polymer resins having improved flow and gloss characteristics
EP3770192A1 (en)	2021-01-27	Diene-based rubber latex, manufacturing method thereof, and core-shell structured graft copolymer comprising same
JP3191942B2 (ja)	2001-07-23	高衝撃強度を有する熱可塑性樹脂の製造方法
JPS636106B2 (ko)	1988-02-08
EP0076162B1 (en)	1985-09-11	A process for producing a thermoplastic resin and a resin composition containing the same
JPS63245414A (ja)	1988-10-12	グラフト重合体の製造法
KR940004852B1 (ko)	1994-06-02	내열성 및 저온 내충격성이 우수한 열가소성 수지 조성물의 제조방법
EP0284428A2 (en)	1988-09-28	Graft copolymer and styrene based resin composition
KR100452856B1 (ko)	2005-02-07	내충격성,백색도및체류광택이우수한열가소성수지라텍스제조방법
KR100394735B1 (ko)	2003-11-17	내후성,광택도및내충격성이우수한열가소성수지조성물의제조방법
KR100205059B1 (ko)	1999-06-15	도장성과 가공성이 우수한 내열성 열가소성 수지의 제조방법
JPH0417230B2 (ko)	1992-03-25
KR100775737B1 (ko)	2007-11-09	전사성이 우수한 열가소성 수지 조성물
KR0173164B1 (ko)	1999-03-30	내충격성이 우수한 열가소성 수지 조성물의 제조방법
JPS6039699B2 (ja)	1985-09-07	熱可塑性樹脂組成物
JPS6346781B2 (ko)	1988-09-19
JPS601883B2 (ja)	1985-01-18	熱可塑性樹脂の製造法
KR100402281B1 (ko)	2003-10-22	내충격성, 광택도 및 내후성이 우수한 열가소성 수지조성물 및 그 제조방법
KR930006000B1 (ko)	1993-07-01	광택이 우수한 열가소성 수지 조성물의 제조방법
JPH036252A (ja)	1991-01-11	熱可塑性樹脂組成物
KR100469866B1 (ko)	2005-02-02	내후성 및 내충격성이 향상된 열가소성 수지조성물 및 그제조방법
JP3941152B2 (ja)	2007-07-04	熱可塑性樹脂組成物及びその製造方法
JPH1030047A (ja)	1998-02-03	ゴム変性スチレン系樹脂組成物