JPS6344216B2 - - Google Patents
Info
- Publication number
- JPS6344216B2 JPS6344216B2 JP55500104A JP50010479A JPS6344216B2 JP S6344216 B2 JPS6344216 B2 JP S6344216B2 JP 55500104 A JP55500104 A JP 55500104A JP 50010479 A JP50010479 A JP 50010479A JP S6344216 B2 JPS6344216 B2 JP S6344216B2
- Authority
- JP
- Japan
- Prior art keywords
- dye
- composition
- copper
- usually
- photopolymerizable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 description 60
- 239000000975 dye Substances 0.000 description 53
- -1 6-membered carbocyclic cycloalkane Chemical class 0.000 description 43
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 28
- 239000010949 copper Substances 0.000 description 28
- 229910052802 copper Inorganic materials 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 24
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
- 239000010410 layer Substances 0.000 description 20
- 229920002120 photoresistant polymer Polymers 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 239000000178 monomer Substances 0.000 description 15
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 10
- 150000001334 alicyclic compounds Chemical class 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 239000012965 benzophenone Substances 0.000 description 9
- 230000005855 radiation Effects 0.000 description 9
- 125000001424 substituent group Chemical group 0.000 description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 8
- 238000007747 plating Methods 0.000 description 8
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 229910052736 halogen Inorganic materials 0.000 description 7
- 150000002367 halogens Chemical class 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000001246 bromo group Chemical group Br* 0.000 description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 239000001003 triarylmethane dye Substances 0.000 description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
- 229910052794 bromium Inorganic materials 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000001924 cycloalkanes Chemical class 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- UZOSVZSBPTTWIG-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-chlorocyclohexane Chemical compound ClC1C(Br)C(Br)C(Br)C(Br)C1Br UZOSVZSBPTTWIG-UHFFFAOYSA-N 0.000 description 4
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000004663 dialkyl amino group Chemical group 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 150000008282 halocarbons Chemical class 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- HJUGFYREWKUQJT-UHFFFAOYSA-N tetrabromomethane Chemical compound BrC(Br)(Br)Br HJUGFYREWKUQJT-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OAZWDJGLIYNYMU-UHFFFAOYSA-N Leucocrystal Violet Chemical compound C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 OAZWDJGLIYNYMU-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- 239000004632 polycaprolactone Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LGPAKRMZNPYPMG-UHFFFAOYSA-N (3-hydroxy-2-prop-2-enoyloxypropyl) prop-2-enoate Chemical compound C=CC(=O)OC(CO)COC(=O)C=C LGPAKRMZNPYPMG-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 2
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical group C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- GGRBZHPJKWFAFZ-UHFFFAOYSA-N 3,4-bis(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC(OC(=O)C(C)=C)COC(=O)C(C)=C GGRBZHPJKWFAFZ-UHFFFAOYSA-N 0.000 description 2
- HTWRFCRQSLVESJ-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCOC(=O)C(C)=C HTWRFCRQSLVESJ-UHFFFAOYSA-N 0.000 description 2
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical group OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- MJVAVZPDRWSRRC-UHFFFAOYSA-N Menadione Chemical compound C1=CC=C2C(=O)C(C)=CC(=O)C2=C1 MJVAVZPDRWSRRC-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- MDMKOESKPAVFJF-UHFFFAOYSA-N [4-(2-methylprop-2-enoyloxy)phenyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=C(OC(=O)C(C)=C)C=C1 MDMKOESKPAVFJF-UHFFFAOYSA-N 0.000 description 2
- WOXJBHQBQQJRFA-UHFFFAOYSA-N [4-(dimethylamino)phenyl]-(4-hydroxyphenyl)methanone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(O)C=C1 WOXJBHQBQQJRFA-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001408 amides Chemical group 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229960001506 brilliant green Drugs 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000012458 free base Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- RUAIJHHRCIHFEV-UHFFFAOYSA-N methyl 4-amino-5-chlorothiophene-2-carboxylate Chemical compound COC(=O)C1=CC(N)=C(Cl)S1 RUAIJHHRCIHFEV-UHFFFAOYSA-N 0.000 description 2
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical class OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012719 thermal polymerization Methods 0.000 description 2
- LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- OAKFFVBGTSPYEG-UHFFFAOYSA-N (4-prop-2-enoyloxycyclohexyl) prop-2-enoate Chemical compound C=CC(=O)OC1CCC(OC(=O)C=C)CC1 OAKFFVBGTSPYEG-UHFFFAOYSA-N 0.000 description 1
- XHXSXTIIDBZEKB-UHFFFAOYSA-N 1,2,3,4,5,6,7,8-octamethylanthracene-9,10-dione Chemical compound CC1=C(C)C(C)=C2C(=O)C3=C(C)C(C)=C(C)C(C)=C3C(=O)C2=C1C XHXSXTIIDBZEKB-UHFFFAOYSA-N 0.000 description 1
- AZESNEXPGASJRZ-UHFFFAOYSA-N 1,2,3,4-tetrahydrobenzo[a]anthracene-7,12-dione Chemical compound C1CCCC2=CC=C3C(=O)C4=CC=CC=C4C(=O)C3=C21 AZESNEXPGASJRZ-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- DVFAVJDEPNXAME-UHFFFAOYSA-N 1,4-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(C)=CC=C2C DVFAVJDEPNXAME-UHFFFAOYSA-N 0.000 description 1
- BXJZZJYNVIDEKG-UHFFFAOYSA-N 1-(2,3,4-trichlorophenyl)ethanone Chemical compound CC(=O)C1=CC=C(Cl)C(Cl)=C1Cl BXJZZJYNVIDEKG-UHFFFAOYSA-N 0.000 description 1
- LMGYOBQJBQAZKC-UHFFFAOYSA-N 1-(2-ethylphenyl)-2-hydroxy-2-phenylethanone Chemical compound CCC1=CC=CC=C1C(=O)C(O)C1=CC=CC=C1 LMGYOBQJBQAZKC-UHFFFAOYSA-N 0.000 description 1
- KFQPRNVTVMCYEH-UHFFFAOYSA-N 1-amino-3-(4-methoxyphenoxy)propan-2-ol Chemical compound COC1=CC=C(OCC(O)CN)C=C1 KFQPRNVTVMCYEH-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
- WVOVXOXRXQFTAS-UHFFFAOYSA-N 1-methyl-7-propan-2-ylphenanthrene-9,10-dione Chemical compound C1=CC=C2C3=CC=C(C(C)C)C=C3C(=O)C(=O)C2=C1C WVOVXOXRXQFTAS-UHFFFAOYSA-N 0.000 description 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 1
- KIJPZYXCIHZVGP-UHFFFAOYSA-N 2,3-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(C)=C2 KIJPZYXCIHZVGP-UHFFFAOYSA-N 0.000 description 1
- LZWVPGJPVCYAOC-UHFFFAOYSA-N 2,3-diphenylanthracene-9,10-dione Chemical compound C=1C=CC=CC=1C=1C=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=1C1=CC=CC=C1 LZWVPGJPVCYAOC-UHFFFAOYSA-N 0.000 description 1
- QEPJZNUAPYIHOI-UHFFFAOYSA-N 2-(2-methylprop-2-enoylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)NCCOC(=O)C(C)=C QEPJZNUAPYIHOI-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical compound OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 description 1
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- YQZHOBBQNFBTJE-UHFFFAOYSA-N 2-chloro-3-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(Cl)=C2 YQZHOBBQNFBTJE-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- ACBOBKJKSFYJML-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-sulfanylpropanoic acid Chemical compound CC(S)C(O)=O.CC(S)C(O)=O.CC(S)C(O)=O.CCC(CO)(CO)CO ACBOBKJKSFYJML-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- CKKQLOUBFINSIB-UHFFFAOYSA-N 2-hydroxy-1,2,2-triphenylethanone Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C(=O)C1=CC=CC=C1 CKKQLOUBFINSIB-UHFFFAOYSA-N 0.000 description 1
- DIVXVZXROTWKIH-UHFFFAOYSA-N 2-hydroxy-1,2-diphenylpropan-1-one Chemical compound C=1C=CC=CC=1C(O)(C)C(=O)C1=CC=CC=C1 DIVXVZXROTWKIH-UHFFFAOYSA-N 0.000 description 1
- VZMLJEYQUZKERO-UHFFFAOYSA-N 2-hydroxy-1-(2-methylphenyl)-2-phenylethanone Chemical compound CC1=CC=CC=C1C(=O)C(O)C1=CC=CC=C1 VZMLJEYQUZKERO-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 description 1
- UFFYQSOLZWNGSO-UHFFFAOYSA-N 2-methyl-n-[3-[1-[3-(2-methylprop-2-enoylamino)propoxy]ethoxy]propyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCCCOC(C)OCCCNC(=O)C(C)=C UFFYQSOLZWNGSO-UHFFFAOYSA-N 0.000 description 1
- NTZCFGZBDDCNHI-UHFFFAOYSA-N 2-phenylanthracene-9,10-dione Chemical compound C=1C=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=1C1=CC=CC=C1 NTZCFGZBDDCNHI-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- MWKAGZWJHCTVJY-UHFFFAOYSA-N 3-hydroxyoctadecan-2-one Chemical compound CCCCCCCCCCCCCCCC(O)C(C)=O MWKAGZWJHCTVJY-UHFFFAOYSA-N 0.000 description 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical class CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
- ADUMIBSPEHFSLA-UHFFFAOYSA-N 4-[bis(4-aminophenyl)methyl]aniline Chemical compound C1=CC(N)=CC=C1C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 ADUMIBSPEHFSLA-UHFFFAOYSA-N 0.000 description 1
- YMRDPCUYKKPMFC-UHFFFAOYSA-N 4-hydroxy-2,2,5,5-tetramethylhexan-3-one Chemical compound CC(C)(C)C(O)C(=O)C(C)(C)C YMRDPCUYKKPMFC-UHFFFAOYSA-N 0.000 description 1
- 125000001054 5 membered carbocyclic group Chemical group 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- RKCRIUIBDUVZSP-UHFFFAOYSA-N 7,8,9,10-tetrahydrotetracene-1,2-dione Chemical compound C1CCCC2=C1C=C1C=C3C=CC(=O)C(=O)C3=CC1=C2 RKCRIUIBDUVZSP-UHFFFAOYSA-N 0.000 description 1
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- 229940076442 9,10-anthraquinone Drugs 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- RTMBGDBBDQKNNZ-UHFFFAOYSA-L C.I. Acid Blue 3 Chemical compound [Ca+2].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=C(O)C=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1.C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=C(O)C=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 RTMBGDBBDQKNNZ-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WZKXBGJNNCGHIC-UHFFFAOYSA-N Leucomalachite green Chemical compound C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)C1=CC=CC=C1 WZKXBGJNNCGHIC-UHFFFAOYSA-N 0.000 description 1
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- RUDUCNPHDIMQCY-UHFFFAOYSA-N [3-(2-sulfanylacetyl)oxy-2,2-bis[(2-sulfanylacetyl)oxymethyl]propyl] 2-sulfanylacetate Chemical compound SCC(=O)OCC(COC(=O)CS)(COC(=O)CS)COC(=O)CS RUDUCNPHDIMQCY-UHFFFAOYSA-N 0.000 description 1
- VDKDFKRKAPXHBH-UHFFFAOYSA-N [3-(2-sulfanylpropanoyloxy)-2,2-bis(2-sulfanylpropanoyloxymethyl)propyl] 2-sulfanylpropanoate Chemical compound CC(S)C(=O)OCC(COC(=O)C(C)S)(COC(=O)C(C)S)COC(=O)C(C)S VDKDFKRKAPXHBH-UHFFFAOYSA-N 0.000 description 1
- ZTBAAVTUPBPGCH-UHFFFAOYSA-N [4-(diethylamino)phenyl]-(4-hydroxyphenyl)methanone Chemical compound C1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=C(O)C=C1 ZTBAAVTUPBPGCH-UHFFFAOYSA-N 0.000 description 1
- BGNRIPXWQAISQW-UHFFFAOYSA-N [4-(dimethylamino)phenyl]-(2-methoxyphenyl)methanone Chemical group COC1=CC=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 BGNRIPXWQAISQW-UHFFFAOYSA-N 0.000 description 1
- FTHJXHFANRRUOU-UHFFFAOYSA-N [4-[4-(dimethylamino)benzoyl]phenyl] prop-2-enoate Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(OC(=O)C=C)C=C1 FTHJXHFANRRUOU-UHFFFAOYSA-N 0.000 description 1
- 230000037374 absorbed through the skin Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- LHMRXAIRPKSGDE-UHFFFAOYSA-N benzo[a]anthracene-7,12-dione Chemical compound C1=CC2=CC=CC=C2C2=C1C(=O)C1=CC=CC=C1C2=O LHMRXAIRPKSGDE-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000001934 cyclohexanes Chemical class 0.000 description 1
- 125000000596 cyclohexenyl group Chemical class C1(=CCCCC1)* 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- MAWOHFOSAIXURX-UHFFFAOYSA-N cyclopentylcyclopentane Chemical group C1CCCC1C1CCCC1 MAWOHFOSAIXURX-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- PEVJCYPAFCUXEZ-UHFFFAOYSA-J dicopper;phosphonato phosphate Chemical compound [Cu+2].[Cu+2].[O-]P([O-])(=O)OP([O-])([O-])=O PEVJCYPAFCUXEZ-UHFFFAOYSA-J 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 229960004337 hydroquinone Drugs 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 229940086559 methyl benzoin Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- IZRZMBCKGLWYSC-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;2-methylprop-2-enamide Chemical compound CC(=C)C(N)=O.CC(=C)C(N)=O.CC(=C)C(N)=O.NCCNCCN IZRZMBCKGLWYSC-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- BYJPRUDFDZPCBH-UHFFFAOYSA-N n-[2-(2-hydroxyethoxy)ethyl]prop-2-enamide Chemical compound OCCOCCNC(=O)C=C BYJPRUDFDZPCBH-UHFFFAOYSA-N 0.000 description 1
- YQCFXPARMSSRRK-UHFFFAOYSA-N n-[6-(prop-2-enoylamino)hexyl]prop-2-enamide Chemical compound C=CC(=O)NCCCCCCNC(=O)C=C YQCFXPARMSSRRK-UHFFFAOYSA-N 0.000 description 1
- 150000005002 naphthylamines Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- AFAIELJLZYUNPW-UHFFFAOYSA-N pararosaniline free base Chemical compound C1=CC(N)=CC=C1C(C=1C=CC(N)=CC=1)=C1C=CC(=N)C=C1 AFAIELJLZYUNPW-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920002578 polythiourethane polymer Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- FTUYQIPAPWPHNC-UHFFFAOYSA-M sodium;4-[[4-[benzyl(ethyl)amino]phenyl]-[4-[benzyl(ethyl)azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzene-1,3-disulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S([O-])(=O)=O)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 FTUYQIPAPWPHNC-UHFFFAOYSA-M 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000002128 sulfonyl halide group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/105—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having substances, e.g. indicators, for forming visible images
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0266—Marks, test patterns or identification means
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0073—Masks not provided for in groups H05K3/02Â -Â H05K3/46, e.g. for photomechanical production of patterned surfaces
- H05K3/0076—Masks not provided for in groups H05K3/02Â -Â H05K3/46, e.g. for photomechanical production of patterned surfaces characterised by the composition of the mask
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/117—Free radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/126—Halogen compound containing
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Polymerisation Methods In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
è«æ±ã®ç¯å²
ïŒ ãã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³ææãšååŠç·å
ã®
ç §å°ã«ãã該ææã®çè²åœ¢æ ãçæããã®ã«å å
ãªéã®èçŽ çœ®æã·ã¯ãã¢ã«ã«ã³ãšãçµåããŠå«
ã¿ã該眮æã·ã¯ãã¢ã«ã«ã³ã®çœ®æåºã®ïŒå以äžã¯
èçŽ ååã§ïŒãªããïŒåã¯å¡©çŽ ååã§ããå éå
æ§çµæç©çšã³ã³ãã©ã¹ãçè²å€çµæç©ã ïŒ è©²ææ察該眮æã·ã¯ãã¢ã«ã«ã³ã®ã¢ã«æ¯ã
0.2ãïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæ
ç©ã ïŒ è©²ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææãå°ãªããš
ãïŒåã®ã¢ãã眮æåºãæããŠããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒãŸãã¯ïŒé èšèŒã®çµæç©ã ïŒ è©²ããã ã·ã¯ãã¢ã«ã«ã³ããžãšã 圢眮æ以å€
ã®ïŒåã®èçŽ ååãæããïŒå¡ãŸãã¯ïŒå¡ççŽ ç°
ã®ã·ã¯ãã¢ã«ã«ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãŸã
ã¯ïŒé èšèŒã®çµæç©ã ïŒ è©²ææãåŒ ïŒåŒäžãã¯åäžãŸãã¯ç°ãªããæ°ŽçŽ ãã¢ããã
ãªãã·ãããããã·ãççŽ æ°ïŒãããã¯ïŒã®ã¢ã«
ã³ãã·ãççŽ æ°ïŒãããã¯ïŒã®ã¢ã«ãã«ãŸãã¯ã
ãã§ããïŒã®ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææã§ã
ãããããŠè©²çœ®æã·ã¯ãã¢ã«ã«ã³ãåŒ ïŒåŒäžãã¯åäžãŸãã¯ç°ãªããæ°ŽçŽ ãèçŽ ãŸã
ã¯å¡©çŽ ã§ããããå°ãªããšãïŒåã®ïŒžã¯èçŽ ã§ã
ãããããŠïœã¯ïŒãªããïŒã®æŽæ°ã§ããïŒã®ãã
ã ã·ã¯ãã¢ã«ã«ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒã
ïŒãïŒãŸãã¯ïŒé èšèŒã®çµæç©ã æè¡åé æ¬çºæã¯å éåæ§çµæç©çšã³ã³ãã©ã¹ãçè²å€
çµæç©ã«é¢ããã èæ¯æè¡ æžè²æ³ã«ããããªã³ãåè·¯æ¿ã®è£œé ã«ãããŠ
ã¯ãé ã被çããç©å±€æ¿ã®è¡šé¢ã«å éåæ§ãã€ã«
ã ãæ¥çãããã€ãã®å éåæ§å±€ãä¿è·ãã€ã«ã
ãŸãã¯æ¯æäœã§è¢«èŠãããäºãå®ãããã¿ãŒã³ã«
åŸã€ãŠé²å ãããšãå éåæ§å±€ã®é²å ãããéšå
ã¯è溶å€æ§ãã¿ãŒã³ã圢æããäžæ¹æªé²å éšåã¯
容æã«æŽãæµãããšãã§ããã次ãã§é²å ããé
å±€ããšããã³ã°ãŸãã¯ã¡ããã«ä»ãã ãã®ä¹Ÿç¥ããå éåæ§ããã¬ãžã¹ããã€ã«ã ã¯
å žåçã«ã¯è²ãèãéæã§ãããäžã«ããé è¡šé¢
ã«ã€ããŠèŠ³å¯ããŠãããã€ã«ã ã®ååšãŸãã¯äžå
åšãããããããå路暡æ§ãæ£ç¢ºã«æãããŠãã
ãã確ãããããšã¯éåžžã«å°é£ã§ãããããã¬ãž
ã¹ãå±€ã®æ€æ»ãå©ããããã«ãå€æ°ã®ãããããª
ææç³»ãå éåæ§å±€äžã«é åããããšã¯ãæ¢ã«ç¥
ãããŠããã ææç³»ã®éžæã«åœã€ãŠã¯ãæäœæ§åã³å®çšæ§äž¡
è ã«é¢ããŠå€ãã®é æ ®äºé ããããææç³»ã¯ãé
æ¿ãšæ¥è§Šãããšãã«æçã«ç¢ºå¯ãããå±€ãäžãã
ãã®ã§ãªããã°ãªããªããæŽã«ãææç³»ã¯é²å ã«
ããå±€ã®ç¡¬åãèããé»å®³ããŠã¯ãªããªããã
ããææã¯ãå ãåžåããããšã«ããå±€äžãžã®å
ã®ééã劚ãããããããã¯ããªãŒã©ãžã«ã«éå
æå¶å€ãšããŠäœçšããããšã«ããããªãŒã©ãžã«ã«
ãšåå¿ããŠéãåæ¢ãããšãããããªå¹²æžãããŠ
ããããæŽã«ãææç³»ã¯åŠçäžåã³è²¯èµäžã®é·æ
éã«äºãå®å®ã§ããããããã«ç±ãå¡©åºãŸãã¯é ž
ã«ããŸãææã§ãã€ãŠã¯ãªããªãããããªãã
ã°ãããææãããã¬ãžã¹ãã®ç¡¬åã®åã«é床ã®
å解ãåããŠããŸããªãã芳å¯ãããè²ã¯åŒ±ãã
ããŠå®¹æã«èå¥ã§ããªããã®ãšãªããã åŸæ¥æè¡ ç±³åœç¹èš±ç¬¬3113024å·ã¯ããªããšãã«ã¡ã¿ã³æ
æã®ãã€ã³å¡©åºã«åºã¥ãããªãç³»ã«é¢ããããçš®
ã®æŽ»æ§ã¹ã«ããã«ãã©ã€ãåºãæããããããªæ
æã®ç±æåæ§ãæ瀺ããã ç±³åœç¹èš±ç¬¬3525616å·ã¯å°ãªããšãäžçš®ã®ãã€
ã³ããªã¢ãªãŒã«ã¡ã¿ã³ææãšãå°ãªããšãäžçš®ã®
âããã«ã«ã«ããŸãŒã«ãšããããŠé²å ãããšã
ãã²ã³ãé¢è±ããå°ãªããšãäžçš®ã®ããã²ã³åç
åæ°ŽçŽ ãšãããªãè€è£œçšææã«é¢ããããã®ç¹èš±
ã«èšèŒã®ç³»ã§ã¯ãããã²ã³åçåæ°ŽçŽ ã¯è²ã®åœ¢æ
ã®ã¿ãªããâããã«ã«ã«ããŸãŒã«ã®å éååå¿
ãã掻æ§åãããå ããŠããã®ç¹èš±ã§çšããããŠ
ããããã²ã³åçåæ°ŽçŽ ã®å€ãïŒããšãã°ãããµ
ã¯ãã«ã·ã¯ããããµã³ïŒã¯æ¯æ§ã匷ããç®èãé
ããŠåžåãããã€çŒã匷ãåºæãããããã«ãã
ãçš®ã®ããã²ã³åçåæ°ŽçŽ ã¯ãé ç®ãšåå¿ããŠå¹²
æžäœçšã®ããã³ã³ãã¬ãã¯ã¹ã圢æããã ç±³åœç¹èš±ç¬¬3769023å·ã¯ã(1)ããããã·ã¢ã«ã
ã«ã»ã«ããŒã¹ã(2)ãšãã¬ã³åäžé£œåã¢ãããŒã奜
ãŸããã¯ïŒ®âããã«ã¢ãããŒã(3)é²å ãããšããª
ãŒã©ãžã«ã«ãçæããå°ãªããšãäžçš®ã®ååç©ã
(4)çž®åå€ãé žåå€ããã³ïŒãŸãã¯é žãšæ¥è§Šãããš
çè²ããäžéäœçŸ€ããéžãã ã«ã©ãŒåœ¢æå€ã(5)æ¥
çãä¿é²ããææ©ã€ãªãŠååç©ããã³(6)ç£åã®è²¯
èµå®å®æ§æ¹åå€ãããªãæå æ§ã®è€è£œçšææã«é¢
ããããã®ç¹èš±ã«èšèŒã®ç³»ã§ã¯ãããªãŒã©ãžã«ã«
çæå€ã¯ã«ã©ãŒåœ¢æããã³å éååå¿ã®äž¡è ã掻
æ§åããã奜ãŸãã掻æ§åå€ã¯å°ãªããšãïŒåã®
ããã²ã³ååãåäžã®ççŽ ååã«çµåããŠããæ
æ©ããã²ã³ååç©ã§ããã ç±³åœç¹èš±ç¬¬4065315ã¯ããªãããããŒææç³»ã«
é¢ãããææãåºç¯ã«è«ããããããªã¢ãªãŒã«ã¡
ã¿ã³ææã®éé¢å¡©åºãšçµåãããŠã掻æ§å ç·ã«é²
å ããããšããã²ã³ããªãŒã©ãžã«ã«ãéé¢ãåŸã
ææ©ãã©ã€ãã䜿çšããããšãé瀺ãããŠããã
åèšããªã¢ãªãŒã«ã¡ã¿ã³ææã®éé¢å¡©åºã¯ã次åŒ
ã§ç€ºãããã ããããªææãçšããããšã®äžã€ã®åé¡ã¯ãå
ç¹èš±ã®19æ¬60ã62è¡ã«çºæè ããèªããŠããåŠ
ããææã®è²¯èµå®å®æ§ããããªãããšã§ãããå
ç¹èš±èšèŒã®ææç³»ãçšããããšã«ä»éããä»äžã€
ã®åé¡ã¯ãåç¹èš±ã§çšããããŠããææ©ãã©ã€ã
ã®ãããã®ã®æ¯æ§ãé«ãããšã§ããã çºæã®èŠçŽ æ¬çºæã¯ãå éåæ§çµæç©çšã®ãç¹ã«é è¡šé¢ã«
ããªãã¬ãžã¹ãå±€ã圢æããã®ã«æçšãªããããª
çµæç©çšã®ããªã³ãã¢ãŠãææç³»ãæäŸãããæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã¯ããã€ã³åœ¢ããªã¢
ãªãŒã«ã¡ã¿ã³ææãšãïŒå以äžã®èçŽ çœ®æåãæ
ããããžãšã 圢ããã²ã³çœ®æã¯å®è³ªçã«ãªãç±ç
ã«å®å®ãªããªããèç°ååç©ãšãçµã¿åãããŠãª
ãããã®ããªã³ãã¢ãŠãææç³»ã¯ãéåäœãã€ã³
ããŒãå°ãªããšãäžçš®ã®ä»å¯éåæ§ã¢ãããŒãå°
ãªããšãäžçš®ã®å éåéå§å€ãéåžžã¯å°éã®ãã
ãªã¢ãªãŒã«ã¡ã¿ã³ææã®çè²åœ¢æ ãšã³ã³ãã©ã¹ã
ããªãææããã³å°éã®ãã®ä»ã®æ·»å å€ãããªã
å éåæ§çµæç©ã«é åããã掻æ§å ç·ã«é²å ãã
ãšãããªã³ãã¢ãŠãææç³»ã¯ãé²å åºåã«æªé²å
ã®å éåæ§çµæç©ããã³é äžå±€ãã容æã«èå¥ã§
ããé¡èãªçè²å±€ãçºçŸãããã®å±€ã¯çŸåãã¡ã
ãããã³ãšããã³ã°åŠçäžå®å®ã§ããã å ·äœçæ æ§ æ¬çºæã¯ãããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææãšã
ãªããã²ã³åèç°åŒååç©ãšãçµåãããŠãªãæ°
èŠãªããªã³ãã¢ãŠãææç³»ãæäŸãããã®ã§ã
ããåŸè ã®ååç©ã¯ãžãšã 圢ããã²ã³çœ®æããã
ããå°ãªããšãïŒåã®èçŽ ãå«æãã倧æ°å§äžã§
ã¯éæè¯æ§ã§ãã€ãŠæ²žç¹ã¯200âãããé«ããæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã¯ãéåäœãã€ã³ã
ãŒãä»å éåæ§ã®ãšãã¬ã³ååºãäžåãŸãã¯ãã
以äžæããå°ãªããšãäžçš®ã®ä»å éåæ§ã¢ãããŒ
ïŒéåžžã¯äºçš®ä»¥äžã®ã¢ãããŒïŒãå éåéå§å€ãæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã®ããªã¢ãªãŒã«ã¡ã¿
ã³ææã®çè²åœ¢ãšå¯Ÿç §çãªè²ãæããææã溶å€
ããã³å°éã®ãã®ä»ã®æ·»å å€ãããªãä»å éåæ§
çµæç©ã«é åããŠäœ¿çšããã®ãæ®éã§ããããã®
å éåæ§çµæç©ã¯ãã©ã¡ãããšããã°ãé žåå€ã
ãšãã°éé žåç©ãå«ãã§ããŠã¯ãªããªãã ããªãã¬ãžã¹ã調åç©ãšããŠã®ãã®çµæç©ã¯ã
éåžžã®è²¯èµæ¡ä»¶äžã§ããŸããé è¡šé¢ãšã®æ¥è§Šäžã§
ã®è²¯èµã§ãé·æéå®å®ã§ããããšã確èªãããã
å ããŠããã®çµæç©ã¯ãæ°Žæ§ããã³éæ°Žæ§çŸå液
äžã§ã®çŸåã®éãããŸããé žæ§ããã³ã¢ã«ã«ãªæ§
ã®ã¡ããæ¡ä»¶äžã§ãå®å®ã§ãããæ¬çºæã®ãã€ã³
ææããªã³ãã¢ãŠãç³»ã¯ãå éååå¿ã«æ®ãã§åœ±
é¿ãåãŒãããšããªããé²å åŸ60ç§ä»¥å ã§æ倧æ¿
床ã«éããã 以äžãããªã³ãã¢ãŠãç³»ã«ã€ããŠå ã説æãã
次ãã§å éåç³»ã«ã€ããŠè©³è¿°ããã ããªã³ãã¢ãŠãç³»ã«çšããååç©ã®éžæã«åœã€
ãŠã¯ã次ã®èŠä»¶ãæºããããããã«é æ ®ããªãã
ã°ãªããªãã (a) ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææããã³ããªã
ãã²ã³åèç°åŒååç©ã¯ã掻æ§å ç·ã«é²å ãã
é匷ãè²ãçºè²ããããã«ã泚ææ·±ãéžæãã
ãã°ãªããªããè²ã¯ã匷ãã°ããã§ãªããæªé²
å 被èŠããã³é åºå±€ã«å¯Ÿãéç«ã€ãè²åãã§ãª
ããã°ãªãããå åãªæé耪è²ããŠã¯ãªããª
ãã (b) ããªã³ãã¢ãŠãç³»ã«çšããååç©ã¯ãå åã«
éæ¯æ§ã§ãªããã°ãªãããç®èãåºæãããã
çŒãåºæãããããªçºç ãããŠã¯ãªããªãã (c) çšããååç©ã¯ãå éåæ§ç³»ã®å éåãå®è³ª
çã«å¹²æžããŠã¯ãªããªããæèšããã°ãçšãã
ååç©ã¯ãé£é移åå€ãé£éçé·å€ãšããŠäœçš
ããäœååéã®æ··åããªããŒã圢æããããšã«
ããã硬åããå éåæ§ç³»ãè匱ã«ãããããª
ãã®ã§ãã€ãŠã¯ãªããªããå ããŠãçšããåå
ç©ã¯ãå éåæ§ç³»ã®å éåé床ãé ãããŠã¯ãª
ããªãã (d) çšããååç©ãïŒããªãŒã©ãžã«ã«ã®çæã«ã
ãïŒæŽ»æ§åãããæ³¢é·ç¯å²ã¯ãå éåæ§ç³»äžã®
å éåéå§å€ã®æ倧åžåãšèãããéè€ããŠã¯
ãªããªããçšããããªããã²ã³åèç°åŒååç©
ã¯ãDmaxã300nïœãè¶ ããã®ãæã奜ãŸã
ãã (e) çšããååç©ã¯ãé ãšã³ã³ãã¬ãã¯ã¹ã圢æ
ããããé ãšãã®ä»ã®ç³»ãšã®æ¥çä¿é²å€ãšããŠ
äœçšããŠã¯ãªããªãã (f) çšããååç©ã¯ãã¡ãã济äžã«æº¶åºãããã
ã¡ãã济ãæ±æããããçŸåŸã®æäœã«æ害ã§ã
ã€ããããŠã¯ãªããªãã (g) çšããååç©ã¯ãããããäžè«žã«ããå Žåã
å åãªè²¯èµå®å®æ§ããã³ç±å®å®æ§ããããã°ãª
ããããã€æŽ»æ§å ç·ã«é²å åã«çºè²ããŠã¯ãªã
ãªãã (h) çšããååç©ã¯ã也ç¥ããã³å·»ããšããµã€ã¯
ã«ã®éã«ããŸã貯èµã®éã«æè¯ããããèžçºã
ãããæ¡æ£ãããããŠã¯ãªããªãã åèšã®è«žèŠä»¶ã¯ããã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³æ
æãšããžãšã 圢眮æã§ã¯ãªãå°ãªããšãïŒåã®è
çŽ ãå«æããããªããã²ã³åèç°åŒååç©ãšãçµ
åãããŠãªãæ¬çºæã®ããªã³ãã¢ãŠãç³»ã«ããå
足ãããããšãããã€ãã æ¬çºæã®çµæç©ã«äœ¿çšããããªã¢ãªãŒã«ã¡ã¿ã³
ææãšããã²ã³åèç°åŒååç©ãšã®ã¢ã«æ¯ã¯ãã
ãã²ã³åèç°åŒååç©ã®çš®é¡ã«ãã€ãŠå€ãããäž
è¬ã«ã¯çŽ0.2ãïŒã®ç¯å²ãç¹ã«0.2ãïŒã®ç¯å²ã§ã
ããéééšã§è¡šãããªããææïŒéééšåœããã
ãã²ã³åèç°åŒååç©ã¯ãéåžžçŽ0.01ãïŒããæ®
éã«ã¯çŽ0.1ãïŒã奜ãŸããã¯0.5ãïŒéééšã§ã
ãã ãã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³ææã¯æ°ŽçŽ ã«çµåã
ãäžçŽççŽ ååãæããåããšãã«ç°ã¯çœ®æã§ã
é眮æã§ããããæ®éç°ïŒååœãçŽïŒå以äžã®çœ®
æåºãæããããæ®éã«ã¯ç°ïŒååœãçŽïŒå以äž
ã®çœ®æåºãæãããããã¯éåžžã¯ãªã«ããŸãã¯ã
ã©ã§ãããããæ®éã«ã¯ãã©ã§ããã眮æåºã¯çµ
åããŠããµã³ãã³ãã¢ã¯ãªãžã³çã®ãããªéçž®å
ç³»ã圢æããŠãããã眮æåºã¯ã¢ããïŒã¢ã«ãã«
åºãïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæããã¢
ãåã³ãžã¢ã«ãã«ã¢ãããå«ãïŒããªãã·ããã
ããã·ãŸãã¯ã¢ã«ã³ãã·ãç¹ã«ïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããã¢ã«ã³ãã·ãååçªå·ïŒ
ã80ãæ®éïŒã35ã®ããã²ã³ãïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããã¢ã«ãã«ãéãªããœã«ã«
ããã«ãããããã¹ã«ããã¢ã·ã«çã§ããããšã
ã§ããã眮æåºã¯ã奜䟿æ§ãå éåæ§ç³»ãžã®å¹²æž
ããªãããšãææã®è²ã䜿çšæ¡ä»¶äžã«ãããç±å
ã³é žåå®å®æ§ãªãã³ã«ãã®ä»ã®å®çšæ§ãèæ ®ããŠ
éžæããããããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææäžã®
眮æåºã®ç¹å®ã®éžæã¯æ¬çºæã®ç¯å²å ã§åºãå€å
ã§ããã 倧äœãæ¬çºæã®ãã€ã³ææã¯äžèšã®æ§é ãæã
ãã ïŒåŒäžãRaãRbããã³Rcã¯ãåäžãŸãã¯ç°ãªãã
äžè¬ã«æ°ŽçŽ ãã¢ã«ãã«åºãïŒãïŒãæ®éïŒãïŒå
ã®ççŽ ååãæããã¢ãåã³ãžã¢ã«ãã«ã¢ããã
å«ããã¢ãããããããã·ãŸãã¯ã¢ã«ã³ãã·ã奜
ãŸããã¯ïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæã
ãã¢ã«ã³ãã·ãå«ãããªãã·ãïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããéãªããœã«ã«ããã«ãå
åçªå·ïŒã80ãæ®éïŒã53ã®ã奜ãŸããã¯17ã53
ã®ããã²ã³ãïŒãïŒãæ®éïŒãïŒãããæ®éã«ã¯
ïŒãïŒåã®ã¢ã«ãã«ãã·ã¢ãããããçã§ããã R1ãR2ããã³R3ã¯ãåäžãŸãã¯ç°ãªãRaãRb
ããã³RcãšåäžãŸãã¯ç°ãªããæ®éã«ã¯æ°ŽçŽ ã§
ãããããŸãã¯R2ã«é£æ¥ã¢ãªãŒã«åºãšäžè«žã«ãª
ã€ãŠççŽ ç°ãŸãã¯ãããååãäŸãã°ïŒ®ãåã³
ãæããç°ã圢æããïŒã RaãRbããã³RcãšããŠå¥œãŸããåºã¯ãã¢ããã
ã¢ã«ãã«ãïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæ
ãããžã¢ã«ãã«ã¢ãããïŒãïŒãæ®éïŒãïŒåã®
ççŽ ååãæããã¢ã«ã³ãã·ãŸãã¯ã¯ãã«ã§ã
ãããã奜ãŸããã¯ãããã¯ãå°ãªããšãïŒãæ®
éã«ã¯ïŒãïŒãããæ®éã«ã¯ïŒãïŒåã®ãã¢ã«ã
ã«åã³ãžã¢ã«ãã«ã¢ãããå«ããã¢ããåºã§ã
ãã ãã€ã³ææã®äŸãšããŠã¯ã¯ãªã¹ã¿ã«ãã€ãªã¬ã
ãããã©ã«ã€ãã°ãªãŒã³ãããŒã·ãã¯ãã«ãŒãã
ã©ããµããªã³ãããµããªã³ãããã³ããã«ãŒïŒ¡ãŸ
ãã¯ïŒ¶çãããã ããªã³ãã¢ãŠãææçµæç©ã®ããäžæ¹ã®æ§æå¡
ã§ããããã²ã³åèç°åŒååç©ã¯ã·ã¯ãã¢ã«ã«ã³
ã§ããã倧æ°å§äžã§çŽ200âãè¶ ã沞ç¹ãæãã
å°ãªããšãïŒåã®èçŽ ååãæããããããã眮
æåã¯ãžãšã 圢ã§ãªãïŒããªãã¡ççŽ ååïŒåã«
ïŒå以äžã®çœ®æåºãçµåããããšã¯ãªãïŒãåŠç
æ¡ä»¶äžã§å®å®ã§ããããå ç §å°ã®éã«ã¯çµåéè£
ããããããšãã§ãããã®ä»ã®ç¹ã§ã¯å ç §å°åå®
å®ã§ããããã€å éåã«æªåœ±é¿ãåãŒããªãã æ¬çºæã§çšããããã ã·ã¯ãã¢ã«ã«ã³ã¯ã次åŒ
ã®ãã®ã§ããããšãã§ããã åŒäžãã®ãã¡å°ãªããšãïŒåã¯èçŽ ã§ããã
æ®ãã®ïŒžã¯æ°ŽçŽ ãèçŽ ãŸãã¯å¡©çŽ ã§ããããããŠ
ïœã¯ïŒãªããïŒã®æŽæ°ãæã奜ãŸããã¯ïŒã§ã
ããç¹ã«å¥œãŸããããªããã²ã³åèç°åŒååç©
ã¯ãïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯
ãã«ã·ã¯ããããµã³ã§ããã ããŠãæ¬çºæã®ããªã³ãã¢ãŠãææçµæç©ãå«
æãããä»å éåæ§çµæç©ãç¹ã«ããã¬ãžã¹ãçµ
æç©ãèããŠã¿ããšããã®çµæç©ã¯éåžžãçŽ40ã
80ééïŒ ã®éåäœãã€ã³ããŒãçŽ15ã30ééïŒ ã®
ïŒçš®ä»¥äžã®ã¢ãããŒãçŽ0.001ã10ééïŒ ã®éå
ããªãŒã©ãžã«ã«éå§å€ããªãã¡å éåéå§å€ãçŽ
0.01ãïŒééïŒ ã®ãã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³æ
æãçŽ0.1ãïŒééïŒ ã®ããªããã²ã³åèç°åŒå
åç©ãçŽ0.01ãïŒééïŒ ã®ããã€ã³ææãšã³ã³ã
ã©ã¹ãããªãçè²ããææåã³çŽ0.001ãïŒéé
ïŒ ã®å皮添å å€ãäŸãã°å¯å¡åå€ãé žåé²æ¢å€ã
å å¡«å€ããããœãããŒãæ§åå±å€åã³æ¥çä¿é²å€
ãæãããææãªãã°ãé¡æãå«æãããŠãã
ãã éåäœã¢ãããŒåéäœã¯ãïŒãïŒãéåžžïŒã
ïŒã奜ãŸããã¯ïŒãïŒåã®ä»å éåæ§ãªã¬ãã€ã³
æ§åºãæããããšãã§ãããäžèšã®ä»å éåæ§ãª
ã¬ãã€ã³ã䜿çšã§ããéåæ§ã¢ãããŒã®äŸã§ã
ãã åç¬ãŸãã¯çµåããŠäœ¿çšã§ããé©åœãªéåæ§ã¢
ãããŒãšããŠã¯ïŒã15åã®ççŽ ååãæããã¢ã«
ãã¬ã³ã°ãªã³ãŒã«ãŸãã¯ïŒã10åã®ãšãŒãã«çµå
ãæããããªã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãã
補é ãããã¢ã«ãã¬ã³åã³ããªã¢ã«ãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãé¡ããããé¡èãªç©è³ªã¯ãšã
ã¬ã³æ§äžé£œååºãç¹ã«ããããªãã³åºããšã¹ãã«
ãŸãã¯ã¢ããæ§é ãšå ±åœ¹ãããã®ã§ããããã®ã
ããªååç©ã®å ·äœäŸãšããŠã¯æ¬¡ã®ãããªãã®ãã
ããããªãªãŒã«ã®äžé£œåãšã¹ãã«ãç¹ã«Î±âã¡ã
ã¬ã³ã«ã«ãã³é žã®äžé£œåãšã¹ãã«ãäŸãã°ãšãã¬
ã³ãžã¢ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒããã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»
ããŒã«ããªã¢ã¯ãªã¬ãŒãããšãã¬ã³ãžã¡ã¿ã¯ãªã¬
ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬ãŒ
ããïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ããªã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒâãã³ãŒã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬
ãŒããïŒïŒïŒâã·ã¯ããããµã³ãžãªãŒã«ãžã¢ã¯ãª
ã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããªâåã³ããã©
ã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢
ã¯ãªã¬ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãª
ã¬ãŒããïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬
ãŒãïŒååé100ã1500ã®ããªãšãã¬ã³ã°ãªã³ãŒ
ã«é¡ã®ãã¹ã¢ã¯ãªã¬ãŒãé¡åã³ã¡ã¿ã¯ãªã¬ãŒãé¡
çïŒäžé£œåã¢ããé¡ãç¹ã«Î±âã¡ãã¬ã³ã«ã«ãã³
é žã®ãã®ããããŠç¹ã«ã¢ã«ãã¢ããªã¡ã¬ãžã¢ãã³
é¡åã³é žçŽ ã§äžæãããŠãããªã¡ã¬ãžã¢ãã³é¡ã
äŸãã°ã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããã¡ãã¬ã³ã
ã¹âã¡ã¿ã¯ãªã«ã¢ãããïŒïŒïŒâãããµã¡ãã¬ã³
ãã¹ã¢ã¯ãªã«ã¢ããããžãšãã¬ã³ããªã¢ãã³ããª
ã¹âã¡ã¿ã¯ãªã«ã¢ããããã¹ïŒã¡ã¿ã¯ãªã«ã¢ãã
ããããã·ïŒãšã¿ã³ãβâã¡ã¿ã¯ãªã«ã¢ãããšã
ã«ã¡ã¿ã¯ãªã¬ãŒãåã³ïŒ®âãïŒÎ²âããããã·ãšã
ã«ãªãã·ïŒãšãã«ãã¢ã¯ãªã«ã¢ããã 奜ãŸããå®æœæ æ§ã§ã¯ããšãã¬ã³åäžé£œåä»å
éåæ§ååç©ã¯ã¢ã¯ãªãªã«ãŸãã¯ã¡ã¿ã¯ãªãªã«å
åç©ãŸãã¯ãã®èªå°äœãäŸãã°äœååéã®ãã€ã
ãŒãããªããŒçãããªãã¡ãªãªãŽããŒã§ãããç¹
ã«æçšãªçµæã¯ä¹Ÿç¥ãã€ã«ã ããã¬ãžã¹ãçµæç©
ã奜ãŸãã硬åæ§ãŸãã¯æ¶æ©æ§éåäœãŸãã¯ãªãª
ãŽããŒãšããšãã¬ã³åäžé£œåéåæ§ååç©ãšããŠ
ã¢ã¯ãªãªã«ãšã¹ãã«ãå«æããŠãããšãåŸãã
ããç¹ã«æçšãªã¢ã¯ãªãªã«ãšã¹ãã«ã¯äžèšäžè¬åŒ
ã§è¡šããããã¢ãâåã³ããªã¢ã¯ãªãªã«ååç©ã§
ããã
ç §å°ã«ãã該ææã®çè²åœ¢æ ãçæããã®ã«å å
ãªéã®èçŽ çœ®æã·ã¯ãã¢ã«ã«ã³ãšãçµåããŠå«
ã¿ã該眮æã·ã¯ãã¢ã«ã«ã³ã®çœ®æåºã®ïŒå以äžã¯
èçŽ ååã§ïŒãªããïŒåã¯å¡©çŽ ååã§ããå éå
æ§çµæç©çšã³ã³ãã©ã¹ãçè²å€çµæç©ã ïŒ è©²ææ察該眮æã·ã¯ãã¢ã«ã«ã³ã®ã¢ã«æ¯ã
0.2ãïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çµæ
ç©ã ïŒ è©²ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææãå°ãªããš
ãïŒåã®ã¢ãã眮æåºãæããŠããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒãŸãã¯ïŒé èšèŒã®çµæç©ã ïŒ è©²ããã ã·ã¯ãã¢ã«ã«ã³ããžãšã 圢眮æ以å€
ã®ïŒåã®èçŽ ååãæããïŒå¡ãŸãã¯ïŒå¡ççŽ ç°
ã®ã·ã¯ãã¢ã«ã«ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãŸã
ã¯ïŒé èšèŒã®çµæç©ã ïŒ è©²ææãåŒ ïŒåŒäžãã¯åäžãŸãã¯ç°ãªããæ°ŽçŽ ãã¢ããã
ãªãã·ãããããã·ãççŽ æ°ïŒãããã¯ïŒã®ã¢ã«
ã³ãã·ãççŽ æ°ïŒãããã¯ïŒã®ã¢ã«ãã«ãŸãã¯ã
ãã§ããïŒã®ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææã§ã
ãããããŠè©²çœ®æã·ã¯ãã¢ã«ã«ã³ãåŒ ïŒåŒäžãã¯åäžãŸãã¯ç°ãªããæ°ŽçŽ ãèçŽ ãŸã
ã¯å¡©çŽ ã§ããããå°ãªããšãïŒåã®ïŒžã¯èçŽ ã§ã
ãããããŠïœã¯ïŒãªããïŒã®æŽæ°ã§ããïŒã®ãã
ã ã·ã¯ãã¢ã«ã«ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒã
ïŒãïŒãŸãã¯ïŒé èšèŒã®çµæç©ã æè¡åé æ¬çºæã¯å éåæ§çµæç©çšã³ã³ãã©ã¹ãçè²å€
çµæç©ã«é¢ããã èæ¯æè¡ æžè²æ³ã«ããããªã³ãåè·¯æ¿ã®è£œé ã«ãããŠ
ã¯ãé ã被çããç©å±€æ¿ã®è¡šé¢ã«å éåæ§ãã€ã«
ã ãæ¥çãããã€ãã®å éåæ§å±€ãä¿è·ãã€ã«ã
ãŸãã¯æ¯æäœã§è¢«èŠãããäºãå®ãããã¿ãŒã³ã«
åŸã€ãŠé²å ãããšãå éåæ§å±€ã®é²å ãããéšå
ã¯è溶å€æ§ãã¿ãŒã³ã圢æããäžæ¹æªé²å éšåã¯
容æã«æŽãæµãããšãã§ããã次ãã§é²å ããé
å±€ããšããã³ã°ãŸãã¯ã¡ããã«ä»ãã ãã®ä¹Ÿç¥ããå éåæ§ããã¬ãžã¹ããã€ã«ã ã¯
å žåçã«ã¯è²ãèãéæã§ãããäžã«ããé è¡šé¢
ã«ã€ããŠèŠ³å¯ããŠãããã€ã«ã ã®ååšãŸãã¯äžå
åšãããããããå路暡æ§ãæ£ç¢ºã«æãããŠãã
ãã確ãããããšã¯éåžžã«å°é£ã§ãããããã¬ãž
ã¹ãå±€ã®æ€æ»ãå©ããããã«ãå€æ°ã®ãããããª
ææç³»ãå éåæ§å±€äžã«é åããããšã¯ãæ¢ã«ç¥
ãããŠããã ææç³»ã®éžæã«åœã€ãŠã¯ãæäœæ§åã³å®çšæ§äž¡
è ã«é¢ããŠå€ãã®é æ ®äºé ããããææç³»ã¯ãé
æ¿ãšæ¥è§Šãããšãã«æçã«ç¢ºå¯ãããå±€ãäžãã
ãã®ã§ãªããã°ãªããªããæŽã«ãææç³»ã¯é²å ã«
ããå±€ã®ç¡¬åãèããé»å®³ããŠã¯ãªããªããã
ããææã¯ãå ãåžåããããšã«ããå±€äžãžã®å
ã®ééã劚ãããããããã¯ããªãŒã©ãžã«ã«éå
æå¶å€ãšããŠäœçšããããšã«ããããªãŒã©ãžã«ã«
ãšåå¿ããŠéãåæ¢ãããšãããããªå¹²æžãããŠ
ããããæŽã«ãææç³»ã¯åŠçäžåã³è²¯èµäžã®é·æ
éã«äºãå®å®ã§ããããããã«ç±ãå¡©åºãŸãã¯é ž
ã«ããŸãææã§ãã€ãŠã¯ãªããªãããããªãã
ã°ãããææãããã¬ãžã¹ãã®ç¡¬åã®åã«é床ã®
å解ãåããŠããŸããªãã芳å¯ãããè²ã¯åŒ±ãã
ããŠå®¹æã«èå¥ã§ããªããã®ãšãªããã åŸæ¥æè¡ ç±³åœç¹èš±ç¬¬3113024å·ã¯ããªããšãã«ã¡ã¿ã³æ
æã®ãã€ã³å¡©åºã«åºã¥ãããªãç³»ã«é¢ããããçš®
ã®æŽ»æ§ã¹ã«ããã«ãã©ã€ãåºãæããããããªæ
æã®ç±æåæ§ãæ瀺ããã ç±³åœç¹èš±ç¬¬3525616å·ã¯å°ãªããšãäžçš®ã®ãã€
ã³ããªã¢ãªãŒã«ã¡ã¿ã³ææãšãå°ãªããšãäžçš®ã®
âããã«ã«ã«ããŸãŒã«ãšããããŠé²å ãããšã
ãã²ã³ãé¢è±ããå°ãªããšãäžçš®ã®ããã²ã³åç
åæ°ŽçŽ ãšãããªãè€è£œçšææã«é¢ããããã®ç¹èš±
ã«èšèŒã®ç³»ã§ã¯ãããã²ã³åçåæ°ŽçŽ ã¯è²ã®åœ¢æ
ã®ã¿ãªããâããã«ã«ã«ããŸãŒã«ã®å éååå¿
ãã掻æ§åãããå ããŠããã®ç¹èš±ã§çšããããŠ
ããããã²ã³åçåæ°ŽçŽ ã®å€ãïŒããšãã°ãããµ
ã¯ãã«ã·ã¯ããããµã³ïŒã¯æ¯æ§ã匷ããç®èãé
ããŠåžåãããã€çŒã匷ãåºæãããããã«ãã
ãçš®ã®ããã²ã³åçåæ°ŽçŽ ã¯ãé ç®ãšåå¿ããŠå¹²
æžäœçšã®ããã³ã³ãã¬ãã¯ã¹ã圢æããã ç±³åœç¹èš±ç¬¬3769023å·ã¯ã(1)ããããã·ã¢ã«ã
ã«ã»ã«ããŒã¹ã(2)ãšãã¬ã³åäžé£œåã¢ãããŒã奜
ãŸããã¯ïŒ®âããã«ã¢ãããŒã(3)é²å ãããšããª
ãŒã©ãžã«ã«ãçæããå°ãªããšãäžçš®ã®ååç©ã
(4)çž®åå€ãé žåå€ããã³ïŒãŸãã¯é žãšæ¥è§Šãããš
çè²ããäžéäœçŸ€ããéžãã ã«ã©ãŒåœ¢æå€ã(5)æ¥
çãä¿é²ããææ©ã€ãªãŠååç©ããã³(6)ç£åã®è²¯
èµå®å®æ§æ¹åå€ãããªãæå æ§ã®è€è£œçšææã«é¢
ããããã®ç¹èš±ã«èšèŒã®ç³»ã§ã¯ãããªãŒã©ãžã«ã«
çæå€ã¯ã«ã©ãŒåœ¢æããã³å éååå¿ã®äž¡è ã掻
æ§åããã奜ãŸãã掻æ§åå€ã¯å°ãªããšãïŒåã®
ããã²ã³ååãåäžã®ççŽ ååã«çµåããŠããæ
æ©ããã²ã³ååç©ã§ããã ç±³åœç¹èš±ç¬¬4065315ã¯ããªãããããŒææç³»ã«
é¢ãããææãåºç¯ã«è«ããããããªã¢ãªãŒã«ã¡
ã¿ã³ææã®éé¢å¡©åºãšçµåãããŠã掻æ§å ç·ã«é²
å ããããšããã²ã³ããªãŒã©ãžã«ã«ãéé¢ãåŸã
ææ©ãã©ã€ãã䜿çšããããšãé瀺ãããŠããã
åèšããªã¢ãªãŒã«ã¡ã¿ã³ææã®éé¢å¡©åºã¯ã次åŒ
ã§ç€ºãããã ããããªææãçšããããšã®äžã€ã®åé¡ã¯ãå
ç¹èš±ã®19æ¬60ã62è¡ã«çºæè ããèªããŠããåŠ
ããææã®è²¯èµå®å®æ§ããããªãããšã§ãããå
ç¹èš±èšèŒã®ææç³»ãçšããããšã«ä»éããä»äžã€
ã®åé¡ã¯ãåç¹èš±ã§çšããããŠããææ©ãã©ã€ã
ã®ãããã®ã®æ¯æ§ãé«ãããšã§ããã çºæã®èŠçŽ æ¬çºæã¯ãå éåæ§çµæç©çšã®ãç¹ã«é è¡šé¢ã«
ããªãã¬ãžã¹ãå±€ã圢æããã®ã«æçšãªããããª
çµæç©çšã®ããªã³ãã¢ãŠãææç³»ãæäŸãããæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã¯ããã€ã³åœ¢ããªã¢
ãªãŒã«ã¡ã¿ã³ææãšãïŒå以äžã®èçŽ çœ®æåãæ
ããããžãšã 圢ããã²ã³çœ®æã¯å®è³ªçã«ãªãç±ç
ã«å®å®ãªããªããèç°ååç©ãšãçµã¿åãããŠãª
ãããã®ããªã³ãã¢ãŠãææç³»ã¯ãéåäœãã€ã³
ããŒãå°ãªããšãäžçš®ã®ä»å¯éåæ§ã¢ãããŒãå°
ãªããšãäžçš®ã®å éåéå§å€ãéåžžã¯å°éã®ãã
ãªã¢ãªãŒã«ã¡ã¿ã³ææã®çè²åœ¢æ ãšã³ã³ãã©ã¹ã
ããªãææããã³å°éã®ãã®ä»ã®æ·»å å€ãããªã
å éåæ§çµæç©ã«é åããã掻æ§å ç·ã«é²å ãã
ãšãããªã³ãã¢ãŠãææç³»ã¯ãé²å åºåã«æªé²å
ã®å éåæ§çµæç©ããã³é äžå±€ãã容æã«èå¥ã§
ããé¡èãªçè²å±€ãçºçŸãããã®å±€ã¯çŸåãã¡ã
ãããã³ãšããã³ã°åŠçäžå®å®ã§ããã å ·äœçæ æ§ æ¬çºæã¯ãããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææãšã
ãªããã²ã³åèç°åŒååç©ãšãçµåãããŠãªãæ°
èŠãªããªã³ãã¢ãŠãææç³»ãæäŸãããã®ã§ã
ããåŸè ã®ååç©ã¯ãžãšã 圢ããã²ã³çœ®æããã
ããå°ãªããšãïŒåã®èçŽ ãå«æãã倧æ°å§äžã§
ã¯éæè¯æ§ã§ãã€ãŠæ²žç¹ã¯200âãããé«ããæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã¯ãéåäœãã€ã³ã
ãŒãä»å éåæ§ã®ãšãã¬ã³ååºãäžåãŸãã¯ãã
以äžæããå°ãªããšãäžçš®ã®ä»å éåæ§ã¢ãããŒ
ïŒéåžžã¯äºçš®ä»¥äžã®ã¢ãããŒïŒãå éåéå§å€ãæ¬
çºæã®ããªã³ãã¢ãŠãææç³»ã®ããªã¢ãªãŒã«ã¡ã¿
ã³ææã®çè²åœ¢ãšå¯Ÿç §çãªè²ãæããææã溶å€
ããã³å°éã®ãã®ä»ã®æ·»å å€ãããªãä»å éåæ§
çµæç©ã«é åããŠäœ¿çšããã®ãæ®éã§ããããã®
å éåæ§çµæç©ã¯ãã©ã¡ãããšããã°ãé žåå€ã
ãšãã°éé žåç©ãå«ãã§ããŠã¯ãªããªãã ããªãã¬ãžã¹ã調åç©ãšããŠã®ãã®çµæç©ã¯ã
éåžžã®è²¯èµæ¡ä»¶äžã§ããŸããé è¡šé¢ãšã®æ¥è§Šäžã§
ã®è²¯èµã§ãé·æéå®å®ã§ããããšã確èªãããã
å ããŠããã®çµæç©ã¯ãæ°Žæ§ããã³éæ°Žæ§çŸå液
äžã§ã®çŸåã®éãããŸããé žæ§ããã³ã¢ã«ã«ãªæ§
ã®ã¡ããæ¡ä»¶äžã§ãå®å®ã§ãããæ¬çºæã®ãã€ã³
ææããªã³ãã¢ãŠãç³»ã¯ãå éååå¿ã«æ®ãã§åœ±
é¿ãåãŒãããšããªããé²å åŸ60ç§ä»¥å ã§æ倧æ¿
床ã«éããã 以äžãããªã³ãã¢ãŠãç³»ã«ã€ããŠå ã説æãã
次ãã§å éåç³»ã«ã€ããŠè©³è¿°ããã ããªã³ãã¢ãŠãç³»ã«çšããååç©ã®éžæã«åœã€
ãŠã¯ã次ã®èŠä»¶ãæºããããããã«é æ ®ããªãã
ã°ãªããªãã (a) ããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææããã³ããªã
ãã²ã³åèç°åŒååç©ã¯ã掻æ§å ç·ã«é²å ãã
é匷ãè²ãçºè²ããããã«ã泚ææ·±ãéžæãã
ãã°ãªããªããè²ã¯ã匷ãã°ããã§ãªããæªé²
å 被èŠããã³é åºå±€ã«å¯Ÿãéç«ã€ãè²åãã§ãª
ããã°ãªãããå åãªæé耪è²ããŠã¯ãªããª
ãã (b) ããªã³ãã¢ãŠãç³»ã«çšããååç©ã¯ãå åã«
éæ¯æ§ã§ãªããã°ãªãããç®èãåºæãããã
çŒãåºæãããããªçºç ãããŠã¯ãªããªãã (c) çšããååç©ã¯ãå éåæ§ç³»ã®å éåãå®è³ª
çã«å¹²æžããŠã¯ãªããªããæèšããã°ãçšãã
ååç©ã¯ãé£é移åå€ãé£éçé·å€ãšããŠäœçš
ããäœååéã®æ··åããªããŒã圢æããããšã«
ããã硬åããå éåæ§ç³»ãè匱ã«ãããããª
ãã®ã§ãã€ãŠã¯ãªããªããå ããŠãçšããåå
ç©ã¯ãå éåæ§ç³»ã®å éåé床ãé ãããŠã¯ãª
ããªãã (d) çšããååç©ãïŒããªãŒã©ãžã«ã«ã®çæã«ã
ãïŒæŽ»æ§åãããæ³¢é·ç¯å²ã¯ãå éåæ§ç³»äžã®
å éåéå§å€ã®æ倧åžåãšèãããéè€ããŠã¯
ãªããªããçšããããªããã²ã³åèç°åŒååç©
ã¯ãDmaxã300nïœãè¶ ããã®ãæã奜ãŸã
ãã (e) çšããååç©ã¯ãé ãšã³ã³ãã¬ãã¯ã¹ã圢æ
ããããé ãšãã®ä»ã®ç³»ãšã®æ¥çä¿é²å€ãšããŠ
äœçšããŠã¯ãªããªãã (f) çšããååç©ã¯ãã¡ãã济äžã«æº¶åºãããã
ã¡ãã济ãæ±æããããçŸåŸã®æäœã«æ害ã§ã
ã€ããããŠã¯ãªããªãã (g) çšããååç©ã¯ãããããäžè«žã«ããå Žåã
å åãªè²¯èµå®å®æ§ããã³ç±å®å®æ§ããããã°ãª
ããããã€æŽ»æ§å ç·ã«é²å åã«çºè²ããŠã¯ãªã
ãªãã (h) çšããååç©ã¯ã也ç¥ããã³å·»ããšããµã€ã¯
ã«ã®éã«ããŸã貯èµã®éã«æè¯ããããèžçºã
ãããæ¡æ£ãããããŠã¯ãªããªãã åèšã®è«žèŠä»¶ã¯ããã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³æ
æãšããžãšã 圢眮æã§ã¯ãªãå°ãªããšãïŒåã®è
çŽ ãå«æããããªããã²ã³åèç°åŒååç©ãšãçµ
åãããŠãªãæ¬çºæã®ããªã³ãã¢ãŠãç³»ã«ããå
足ãããããšãããã€ãã æ¬çºæã®çµæç©ã«äœ¿çšããããªã¢ãªãŒã«ã¡ã¿ã³
ææãšããã²ã³åèç°åŒååç©ãšã®ã¢ã«æ¯ã¯ãã
ãã²ã³åèç°åŒååç©ã®çš®é¡ã«ãã€ãŠå€ãããäž
è¬ã«ã¯çŽ0.2ãïŒã®ç¯å²ãç¹ã«0.2ãïŒã®ç¯å²ã§ã
ããéééšã§è¡šãããªããææïŒéééšåœããã
ãã²ã³åèç°åŒååç©ã¯ãéåžžçŽ0.01ãïŒããæ®
éã«ã¯çŽ0.1ãïŒã奜ãŸããã¯0.5ãïŒéééšã§ã
ãã ãã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³ææã¯æ°ŽçŽ ã«çµåã
ãäžçŽççŽ ååãæããåããšãã«ç°ã¯çœ®æã§ã
é眮æã§ããããæ®éç°ïŒååœãçŽïŒå以äžã®çœ®
æåºãæããããæ®éã«ã¯ç°ïŒååœãçŽïŒå以äž
ã®çœ®æåºãæãããããã¯éåžžã¯ãªã«ããŸãã¯ã
ã©ã§ãããããæ®éã«ã¯ãã©ã§ããã眮æåºã¯çµ
åããŠããµã³ãã³ãã¢ã¯ãªãžã³çã®ãããªéçž®å
ç³»ã圢æããŠãããã眮æåºã¯ã¢ããïŒã¢ã«ãã«
åºãïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæããã¢
ãåã³ãžã¢ã«ãã«ã¢ãããå«ãïŒããªãã·ããã
ããã·ãŸãã¯ã¢ã«ã³ãã·ãç¹ã«ïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããã¢ã«ã³ãã·ãååçªå·ïŒ
ã80ãæ®éïŒã35ã®ããã²ã³ãïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããã¢ã«ãã«ãéãªããœã«ã«
ããã«ãããããã¹ã«ããã¢ã·ã«çã§ããããšã
ã§ããã眮æåºã¯ã奜䟿æ§ãå éåæ§ç³»ãžã®å¹²æž
ããªãããšãææã®è²ã䜿çšæ¡ä»¶äžã«ãããç±å
ã³é žåå®å®æ§ãªãã³ã«ãã®ä»ã®å®çšæ§ãèæ ®ããŠ
éžæããããããªã¢ãªãŒã«ã¡ã¿ã³ãã€ã³ææäžã®
眮æåºã®ç¹å®ã®éžæã¯æ¬çºæã®ç¯å²å ã§åºãå€å
ã§ããã 倧äœãæ¬çºæã®ãã€ã³ææã¯äžèšã®æ§é ãæã
ãã ïŒåŒäžãRaãRbããã³Rcã¯ãåäžãŸãã¯ç°ãªãã
äžè¬ã«æ°ŽçŽ ãã¢ã«ãã«åºãïŒãïŒãæ®éïŒãïŒå
ã®ççŽ ååãæããã¢ãåã³ãžã¢ã«ãã«ã¢ããã
å«ããã¢ãããããããã·ãŸãã¯ã¢ã«ã³ãã·ã奜
ãŸããã¯ïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæã
ãã¢ã«ã³ãã·ãå«ãããªãã·ãïŒãïŒãæ®éïŒã
ïŒåã®ççŽ ååãæããéãªããœã«ã«ããã«ãå
åçªå·ïŒã80ãæ®éïŒã53ã®ã奜ãŸããã¯17ã53
ã®ããã²ã³ãïŒãïŒãæ®éïŒãïŒãããæ®éã«ã¯
ïŒãïŒåã®ã¢ã«ãã«ãã·ã¢ãããããçã§ããã R1ãR2ããã³R3ã¯ãåäžãŸãã¯ç°ãªãRaãRb
ããã³RcãšåäžãŸãã¯ç°ãªããæ®éã«ã¯æ°ŽçŽ ã§
ãããããŸãã¯R2ã«é£æ¥ã¢ãªãŒã«åºãšäžè«žã«ãª
ã€ãŠççŽ ç°ãŸãã¯ãããååãäŸãã°ïŒ®ãåã³
ãæããç°ã圢æããïŒã RaãRbããã³RcãšããŠå¥œãŸããåºã¯ãã¢ããã
ã¢ã«ãã«ãïŒãïŒãæ®éïŒãïŒåã®ççŽ ååãæ
ãããžã¢ã«ãã«ã¢ãããïŒãïŒãæ®éïŒãïŒåã®
ççŽ ååãæããã¢ã«ã³ãã·ãŸãã¯ã¯ãã«ã§ã
ãããã奜ãŸããã¯ãããã¯ãå°ãªããšãïŒãæ®
éã«ã¯ïŒãïŒãããæ®éã«ã¯ïŒãïŒåã®ãã¢ã«ã
ã«åã³ãžã¢ã«ãã«ã¢ãããå«ããã¢ããåºã§ã
ãã ãã€ã³ææã®äŸãšããŠã¯ã¯ãªã¹ã¿ã«ãã€ãªã¬ã
ãããã©ã«ã€ãã°ãªãŒã³ãããŒã·ãã¯ãã«ãŒãã
ã©ããµããªã³ãããµããªã³ãããã³ããã«ãŒïŒ¡ãŸ
ãã¯ïŒ¶çãããã ããªã³ãã¢ãŠãææçµæç©ã®ããäžæ¹ã®æ§æå¡
ã§ããããã²ã³åèç°åŒååç©ã¯ã·ã¯ãã¢ã«ã«ã³
ã§ããã倧æ°å§äžã§çŽ200âãè¶ ã沞ç¹ãæãã
å°ãªããšãïŒåã®èçŽ ååãæããããããã眮
æåã¯ãžãšã 圢ã§ãªãïŒããªãã¡ççŽ ååïŒåã«
ïŒå以äžã®çœ®æåºãçµåããããšã¯ãªãïŒãåŠç
æ¡ä»¶äžã§å®å®ã§ããããå ç §å°ã®éã«ã¯çµåéè£
ããããããšãã§ãããã®ä»ã®ç¹ã§ã¯å ç §å°åå®
å®ã§ããããã€å éåã«æªåœ±é¿ãåãŒããªãã æ¬çºæã§çšããããã ã·ã¯ãã¢ã«ã«ã³ã¯ã次åŒ
ã®ãã®ã§ããããšãã§ããã åŒäžãã®ãã¡å°ãªããšãïŒåã¯èçŽ ã§ããã
æ®ãã®ïŒžã¯æ°ŽçŽ ãèçŽ ãŸãã¯å¡©çŽ ã§ããããããŠ
ïœã¯ïŒãªããïŒã®æŽæ°ãæã奜ãŸããã¯ïŒã§ã
ããç¹ã«å¥œãŸããããªããã²ã³åèç°åŒååç©
ã¯ãïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯
ãã«ã·ã¯ããããµã³ã§ããã ããŠãæ¬çºæã®ããªã³ãã¢ãŠãææçµæç©ãå«
æãããä»å éåæ§çµæç©ãç¹ã«ããã¬ãžã¹ãçµ
æç©ãèããŠã¿ããšããã®çµæç©ã¯éåžžãçŽ40ã
80ééïŒ ã®éåäœãã€ã³ããŒãçŽ15ã30ééïŒ ã®
ïŒçš®ä»¥äžã®ã¢ãããŒãçŽ0.001ã10ééïŒ ã®éå
ããªãŒã©ãžã«ã«éå§å€ããªãã¡å éåéå§å€ãçŽ
0.01ãïŒééïŒ ã®ãã€ã³ããªã¢ãªãŒã«ã¡ã¿ã³æ
æãçŽ0.1ãïŒééïŒ ã®ããªããã²ã³åèç°åŒå
åç©ãçŽ0.01ãïŒééïŒ ã®ããã€ã³ææãšã³ã³ã
ã©ã¹ãããªãçè²ããææåã³çŽ0.001ãïŒéé
ïŒ ã®å皮添å å€ãäŸãã°å¯å¡åå€ãé žåé²æ¢å€ã
å å¡«å€ããããœãããŒãæ§åå±å€åã³æ¥çä¿é²å€
ãæãããææãªãã°ãé¡æãå«æãããŠãã
ãã éåäœã¢ãããŒåéäœã¯ãïŒãïŒãéåžžïŒã
ïŒã奜ãŸããã¯ïŒãïŒåã®ä»å éåæ§ãªã¬ãã€ã³
æ§åºãæããããšãã§ãããäžèšã®ä»å éåæ§ãª
ã¬ãã€ã³ã䜿çšã§ããéåæ§ã¢ãããŒã®äŸã§ã
ãã åç¬ãŸãã¯çµåããŠäœ¿çšã§ããé©åœãªéåæ§ã¢
ãããŒãšããŠã¯ïŒã15åã®ççŽ ååãæããã¢ã«
ãã¬ã³ã°ãªã³ãŒã«ãŸãã¯ïŒã10åã®ãšãŒãã«çµå
ãæããããªã¢ã«ãã¬ã³ãšãŒãã«ã°ãªã³ãŒã«ãã
補é ãããã¢ã«ãã¬ã³åã³ããªã¢ã«ãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒãé¡ããããé¡èãªç©è³ªã¯ãšã
ã¬ã³æ§äžé£œååºãç¹ã«ããããªãã³åºããšã¹ãã«
ãŸãã¯ã¢ããæ§é ãšå ±åœ¹ãããã®ã§ããããã®ã
ããªååç©ã®å ·äœäŸãšããŠã¯æ¬¡ã®ãããªãã®ãã
ããããªãªãŒã«ã®äžé£œåãšã¹ãã«ãç¹ã«Î±âã¡ã
ã¬ã³ã«ã«ãã³é žã®äžé£œåãšã¹ãã«ãäŸãã°ãšãã¬
ã³ãžã¢ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯
ãªã¬ãŒããã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»
ããŒã«ããªã¢ã¯ãªã¬ãŒãããšãã¬ã³ãžã¡ã¿ã¯ãªã¬
ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬ãŒ
ããïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ããªã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒâãã³ãŒã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬
ãŒããïŒïŒïŒâã·ã¯ããããµã³ãžãªãŒã«ãžã¢ã¯ãª
ã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããªâåã³ããã©
ã¡ã¿ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢
ã¯ãªã¬ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãª
ã¬ãŒããïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ãžã¡ã¿ã¯ãªã¬
ãŒãïŒååé100ã1500ã®ããªãšãã¬ã³ã°ãªã³ãŒ
ã«é¡ã®ãã¹ã¢ã¯ãªã¬ãŒãé¡åã³ã¡ã¿ã¯ãªã¬ãŒãé¡
çïŒäžé£œåã¢ããé¡ãç¹ã«Î±âã¡ãã¬ã³ã«ã«ãã³
é žã®ãã®ããããŠç¹ã«ã¢ã«ãã¢ããªã¡ã¬ãžã¢ãã³
é¡åã³é žçŽ ã§äžæãããŠãããªã¡ã¬ãžã¢ãã³é¡ã
äŸãã°ã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ãããã¡ãã¬ã³ã
ã¹âã¡ã¿ã¯ãªã«ã¢ãããïŒïŒïŒâãããµã¡ãã¬ã³
ãã¹ã¢ã¯ãªã«ã¢ããããžãšãã¬ã³ããªã¢ãã³ããª
ã¹âã¡ã¿ã¯ãªã«ã¢ããããã¹ïŒã¡ã¿ã¯ãªã«ã¢ãã
ããããã·ïŒãšã¿ã³ãβâã¡ã¿ã¯ãªã«ã¢ãããšã
ã«ã¡ã¿ã¯ãªã¬ãŒãåã³ïŒ®âãïŒÎ²âããããã·ãšã
ã«ãªãã·ïŒãšãã«ãã¢ã¯ãªã«ã¢ããã 奜ãŸããå®æœæ æ§ã§ã¯ããšãã¬ã³åäžé£œåä»å
éåæ§ååç©ã¯ã¢ã¯ãªãªã«ãŸãã¯ã¡ã¿ã¯ãªãªã«å
åç©ãŸãã¯ãã®èªå°äœãäŸãã°äœååéã®ãã€ã
ãŒãããªããŒçãããªãã¡ãªãªãŽããŒã§ãããç¹
ã«æçšãªçµæã¯ä¹Ÿç¥ãã€ã«ã ããã¬ãžã¹ãçµæç©
ã奜ãŸãã硬åæ§ãŸãã¯æ¶æ©æ§éåäœãŸãã¯ãªãª
ãŽããŒãšããšãã¬ã³åäžé£œåéåæ§ååç©ãšããŠ
ã¢ã¯ãªãªã«ãšã¹ãã«ãå«æããŠãããšãåŸãã
ããç¹ã«æçšãªã¢ã¯ãªãªã«ãšã¹ãã«ã¯äžèšäžè¬åŒ
ã§è¡šããããã¢ãâåã³ããªã¢ã¯ãªãªã«ååç©ã§
ããã
ãåŒããŸãã¯
ãåŒãã¢ã¯ãªãªã«ååç©ã
ãåŒãã®å Žåã
ïŒã¯ïŒšãŸãã¯CH3ã§ããã
Mâ²ã¯ïŒã12åã®ççŽ ååãæããã·ã¯ãã¢ã«
ãã«ïŒäŸãã°ã·ã¯ããã³ãã«ããžã·ã¯ããã³ã
ã«ãã¡ãã«ã·ã¯ããã³ãã«ããžã¡ãã«ã·ã¯ããã³
ãã«çïŒã ïŒã12åã®ççŽ ååãæããã·ã¯ãã¢ã«ã±ãã«
ïŒäŸãã°ãã·ã¯ããã³ããã«ãã¡ãã«ã·ã¯ããã³
ããã«ããžã·ã¯ããã³ããã«ããã·ã¯ããïŒïŒ
ïŒïŒïŒããããâïŒâãšã³âã€ã«çïŒã âCpH2qMâ³ ãŸã㯠ïŒCqH2qïŒsCqH2q+s ïŒåŒäžã ïœã¯ïŒã10ã®æŽæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°ã§ããã Mâ³ã¯æ°ŽçŽ ãããããã·ã«ãããšããã·ãççŽ
ååïŒãïŒåã®ã¢ã«ã³ãã·åºã§ããïŒã§ããã ãŸããã¢ã¯ãªãªã«ååç©ã åŒ
ãã«ïŒäŸãã°ã·ã¯ããã³ãã«ããžã·ã¯ããã³ã
ã«ãã¡ãã«ã·ã¯ããã³ãã«ããžã¡ãã«ã·ã¯ããã³
ãã«çïŒã ïŒã12åã®ççŽ ååãæããã·ã¯ãã¢ã«ã±ãã«
ïŒäŸãã°ãã·ã¯ããã³ããã«ãã¡ãã«ã·ã¯ããã³
ããã«ããžã·ã¯ããã³ããã«ããã·ã¯ããïŒïŒ
ïŒïŒïŒããããâïŒâãšã³âã€ã«çïŒã âCpH2qMâ³ ãŸã㯠ïŒCqH2qïŒsCqH2q+s ïŒåŒäžã ïœã¯ïŒã10ã®æŽæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°ã§ããã ïœã¯ïŒãïŒã®æŽæ°ã§ããã Mâ³ã¯æ°ŽçŽ ãããããã·ã«ãããšããã·ãççŽ
ååïŒãïŒåã®ã¢ã«ã³ãã·åºã§ããïŒã§ããã ãŸããã¢ã¯ãªãªã«ååç©ã åŒ
ãåŒã
ã®å Žåã
ã¯åŒ
âC2H2x-yâ
ãåŒäžã
ïœã¯ïŒãïŒã®æŽæ°ã§ããã
ïœã¯ïŒãïŒã®æŽæ°ã§ããã
ïŒäŸãã°ïœïŒïŒã®ãšãã¯âC2H4âãâC3H6âãâ
ã€ãœâC3H6âãâC5H10âãâããªâC6H12âçã®
ãããªïŒäŸ¡ã®ã¢ã«ãã¬ã³ãïœïŒïŒã®ãšãã¯
ã€ãœâC3H6âãâC5H10âãâããªâC6H12âçã®
ãããªïŒäŸ¡ã®ã¢ã«ãã¬ã³ãïœïŒïŒã®ãšãã¯
ãåŒã
ãåŒãç
ã®ãããªïŒäŸ¡ã®ã¢ã«ãã¬ã³ããŸãã¯
ïœïŒïŒã®ãšãã¯
ãåŒã
ã§è¡šããããïŒäŸ¡ã®ãšãŒãã«ãŸãã¯ãšã¹ãã«åºã§
ããã ç¹ã«å¥œãŸããã¢ã¯ãªãªã«ååç©ã¯ããªãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ã
ãªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢
ã¯ãªã¬ãŒãåã³ãã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯
ãªã¬ãŒãã§ããã 代衚çãªéåäœãã€ã³ããŒãšããŠã¯ãããªã¹ã
ã¬ã³ãããªã«ãŒãããŒããããªãŠã¬ã¿ã³ãããªã
ã«ã ã¢ã«ããããããªããã«ã¢ã»ã¿ãŒã«ïŒäŸã
ã°ãããªããã«ããã©ãŒã«ïŒãããªå¡©åããã«å
ã³å ±éåäœãããªãšãŒãã«é¡ïŒäŸãã°ãããªãšã
ã¬ã³ãªãã·ããããªãããã¬ã³ãªãã·ããããªã
ãã©ããããã©ã³ïŒãããªã¢ã¯ãªã¬ãŒãé¡ïŒäŸã
ã°ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿ã¯
ãªã¬ãŒããããªã¡ãã«ã¢ã¯ãªã¬ãŒãåã³ããªãšã
ã«ã¢ã¯ãªã¬ãŒãïŒããªããã«ãšã¹ãã«é¡ïŒäŸã
ã°ãããªé ¢é žããã«åã³ããªé ¢é žããã«ïŒã¢ã¯ãª
ã«é žãšã¹ãã«ïŒãã»ã«ããŒã¹ãšã¹ãã«é¡ïŒäŸãã°
é ¢é žã»ã«ããŒã¹åã³é ¢é žé ªé žã»ã«ããŒã¹ïŒãã»ã«
ããŒã¹ãšãŒãã«é¡ïŒäŸãã°ãã¡ãã«ã»ã«ããŒã¹å
ã³ãšãã«ã»ã«ããŒã¹ïŒãå€æ§ããªãªã¬ãã€ã³é¡
ïŒäŸãã°ããšãã¬ã³ïŒé ¢é žããã«å ±éåäœïŒãããª
å¡©åãããªãã³ïŒå¡©åãããªãã³ãšã¢ã¯ãªã«ãã
ãªã«ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãåã³é ¢é žããã«ã®å ±
éåäœãå«ãïŒãããªã¢ããé¡ïŒäŸãã°ãããªã«
ããã©ã¯ãã³ãããªã«ããã©ã¯ã¿ã åã³ããªãã
ãµã¡ãã¬ã³ã¢ãžãããïŒåã³ããªãšã¹ãã«é¡ïŒäŸ
ãã°ãããªãšãã¬ã³ã°ãªã³ãŒã«ãã¬ãã¿ã¬ãŒãå
ã³ããªãããµã¡ãã¬ã³ã¹ã¯ã·ããŒãïŒãããã å éåæ§çµæç©ã«äœ¿çšããå éåæ§éå§å€ã¯å
åŠç·å ã§æŽ»æ§åããã185â以äžã§ç±çã«å®å®ã§
ãããã®ã奜ãŸãããããããªéå§å€ãšããŠã¯ã
眮æãŸãã¯é眮æå€æ žããã³é¡ãäŸãã°ïŒïŒ10â
ã¢ã³ãã©ããã³ãïŒâã¯ãã«ã¢ã³ãã©ããã³ãïŒ
âã·ã¯ãã¢ã³ãã©ããã³ãïŒâã¡ãã«ã¢ã³ãã©ã
ãã³ãïŒâãšãã«ã¢ã³ãã©ããã³ãïŒâtertâã
ãã«ã¢ã³ãã©ããã³ããªã¯ã¿ã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒïŒïŒâãããããã³ãïŒïŒ10âããšãã³ã
ã©ããã³ãïŒïŒïŒâãã³ãŸã¢ã³ãã©ããã³ãïŒïŒ
ïŒâãã³ãŸã¢ã³ãã©ããã³ãïŒâã¡ãã«âïŒïŒïŒ
âãããããã³ãïŒïŒïŒâãžã¯ãã«ããããã
ã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©ããã³ãïŒïŒïŒâ
ãžã¡ãã«ã¢ã³ãã©ããã³ãïŒâããšãã«ã¢ã³ãã©
ããã³ãïŒïŒïŒâãžããšãã«ã¢ã³ãã©ããã³ãïŒ
âã¯ãã«âïŒâã¡ãã«ã¢ã³ãã©ããã³ãã¬ãã³ã
ãã³ãïŒïŒïŒïŒïŒïŒ10âããã©ãããããã¿ã»ã³
ããã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ããããã³ãº(a)
âã¢ã³ãã©ã»ã³âïŒïŒ12âãžãªã³ãããã ç±³åœç¹èš±ç¬¬2760863å·ã«èšèŒãããäžèšã®å é
åéå§å€ããŸãã掻æ§ã§ããããæçšã§ãããã
ã®ãã¡ãããã®ã¯85âãšããäœã枩床ã§ãç±çã«
å®å®ã§ããããã·ãã«ã±ã¿ã«ããã«ååç©ãäŸã
ã°ãžã¢ã»ãã«åã³ãã³ãžã«ïŒã¢ã«ãã¢ã±ã¿ã«ãã
ã«ã¢ã«ã³ãŒã«é¡ãäŸãã°ãã³ãŸã€ã³åã³ãããã€
ã³ïŒã¢ã¯ãã€ã³ãšãŒãã«é¡ãäŸãã°ãã³ãŸã€ã³ã¡
ãã«åã³ãšãã«ãšãŒãã«ïŒÎ±âçåæ°ŽçŽ çœ®æè³éŠ
æã¢ã·ãã€ã³ãαâã¡ãã«ãã³ãŸã€ã³ïŒÎ±âã¢ãª
ã«ãã³ãŸã€ã³åã³Î±âããšãã«ãã³ãŸã€ã³ã ãã³ãŸã€ã³ãšãŒãã«é¡ã®å ·äœäŸãšããŠã¯ããã³
ãŸã€ã³ã¡ãã«ãšãŒãã«ããã³ãŸã€ã³ãšãã«ãšãŒã
ã«ããã³ãŸã€ã«ããšãã«ãšãŒãã«ãã¡ãã«ãã³ãŸ
ã€ã³åã³ãšãã«ãã³ãŸã€ã³ãããã ããçš®ã®è³éŠæã±ãã³ãäŸãã°ãã³ãŸããšãã³
åã³ïŒïŒ4â²âãã¹âïŒãžã¢ã«ãã«ã¢ããïŒãã³ãŸ
ããšãã³ãæçšã§ããããã®å ·äœäŸãšããŠã¯ãã³
ãŸããšãã³ãïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒã
ã³ãŸããšãã³ãïŒïŒ4â²âãã¹ïŒãžãšãã«ã¢ããïŒ
ãã³ãŸããšãã³ãïŒâããããã·â4â²ãžãšãã«ã¢
ãããã³ãŸããšãã³ãïŒâããããã·â4â²âãžã¡
ãã«ã¢ãããã³ãŸããšãã³ãïŒâã¢ã¯ãªã«ãªãã·
â4â²âãžã¡ãã«ã¢ãããã³ãŸããšãã³ãåã³ïŒâ
ã¡ããã·â4â²âãžã¡ãã«ã¢ãããã³ãŸããšãã³ã
ããã éåéå§å€ã¯ã¢ã·ãã€ã³ãšãŒãã«ãã¢ã«ãã«åº
ãïŒãïŒåã®ççŽ ååãå«æããŠããã¢ã«ãã«çœ®
æã¢ã³ãã©ããã³ããã³ãŸããšãã³ãŸãã¯ã¢ã«ã
ã«ã¢ãããã³ãŸããšãã³ã®å°ãªããšãäžçš®ãå«æ
ããã®ã奜ãŸããã 奜ãŸããå éåæ§çµæç©ã«ã¯ãç±éåæå¶å€ã
æ·»å ãããç±éåæå¶å€ã®äŸãšããŠã¯ãïœâã¡ã
ãã·ããšããŒã«ããã€ããããã³ãã¢ã«ãã«åã³
ã¢ãªãŒã«çœ®æãã€ããããã³åã³ããã³é¡ãïœâ
ããã«ã«ãã³ãŒã«ãããã¬ããŒã«ãããžã³é žé ã
ãããã«ã¢ãã³é¡ãβâããããŒã«ãïŒïŒïŒâãž
âtertâããã«ïœâã¯ã¬ãŸãŒã«ãïŒïŒ2â²âã¡ãã¬
ã³âãã¹âïŒïŒâãšãã«âïŒâïœâããã«ããšã
ãŒã«ïŒãããªãžã³ãããããã³ãŒã³ããžãããã
ã³ãŒã³ãïœâãã«ããã³ãã¯ãã©ãã«ãäºçé žã¢
ãªãŒã«åã³äºçé žã¢ãªãŒã«ã¢ã«ãã«ãããã ããªãã¬ãžã¹ãçµæç©ãšããŠçšããå éåæ§çµ
æç©ã¯ãéåžžé©åœãªæº¶åªãæ®éã«ã¯ææ©æº¶åªãäŸ
ãã°ïŒãïŒåã®ççŽ ååãæããã±ãã³åç¬äžã«
ãŸãã¯ããããªã±ãã³ãšïŒãïŒåã®ççŽ ååãæ
ããã¢ã«ã«ããŒã«ãšã®æ··æ¶²äžã«åŠæ¹ããããã®äž
ã®åºåœ¢åçŸåçã¯éåžžçŽ10ã50ééïŒ ã§ããã ããªãã¬ãžã¹ãçµæç©ã¯ãé ã·ãŒãäžã«ãéåžž
ã¯äžé¢é å±€ãæããç©å±€æ¿ã«æªç¡¬åããªãã¬ãžã¹
ãå±€ãé å±€ãšæ¥è§Šããããã«é©çšãããããªãã¬
ãžã¹ãå±€çšä¿è·ãã€ã«ã ãæŽã«èšããããšã«ã
ããä¿è·ãã€ã«ã ãæªç¡¬åããªãã¬ãžã¹ãå±€åã³
é å±€ã®ãµã³ãã€ãããšããããšãã§ãããããªã
ã¬ãžã¹ãå±€ã¯çŽ0.00635ã0.127mmïŒ0.25ãïŒã
ã«ïŒãéåžžã¯çŽ0.019ã0.10mmïŒ0.75ãïŒãã«ïŒã®
åãã®ä¹Ÿç¥èåãæãããä¿è·å±€ã¯éåžžçŽ0.0127
ã0.127mmïŒ0.5ãïŒãã«ïŒåãã§ãããäžæŽ»æ§ã®
ä»å ãŸãã¯çž®åéåäœãäŸãã°ããªãããã¬ã³ã®
ãããªïŒãïŒåã®ççŽ ååãæããããªãªã¬ãã€
ã³ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãçã§ãã€ãŠã
ãã 䜿çšã«åœã€ãŠã¯ãå éåæ§ä¹Ÿç¥ãã€ã«ã ã掻æ§
å ç·å æºã«é²å ããããããã¯äžé調ç»åãŸãã¯
ããã»ã¹éæç»ãäŸãã°ããã»ã¹ãã¬ãŸãã¯ã
ãžãã¹ãã³ã·ã«ãŸãã¯ãã¹ã¯ãéããŠè¡ãããé²
å ã¯ãŸãé£ç¶é調ãã¬ãŸãã¯ããžç»åãéããŠã
ãããé²å ã¯éåæ§å±€äžã«ã«ããŒã·ãŒããèšããŠ
ãŸãã¯èšããã«å¯çãŸãã¯æå°æ³ã«ãããããã
ã¯ã«ããŒã·ãŒããçšããŠæå°æ³ã«ããè¡ãªãããš
ãã§ããããããã®æ¹æ³ã¯ãã®åéã§åœæ¥è ã«ã
ãç¥ãããŠãããããªãã¬ãžã¹ãçµæç©ã®é²å ã«
ã¯ãäžè¬ã«çŽ«å€ç·ã䜿çšãããããç·æºã¯å¹æç
éã®çŽ«å€ç·ãäžãããã®ã§ãªããã°ãªããªããç¹
ãŸãã¯ãããŒãæŸå°ç·æºãå¹æçã§ããããã®ã
ããªç·æºãšããŠã¯ãã«ãŒãã³ã¢ãŒã¯ãæ°Žéèžæ°ã¢
ãŒã¯ã玫å€ç·æŸå°æ§çå äœãå«ãèå ç¯ãã¢ã«ãŽ
ã³ã°ããŒç¯ãé»æ°ããå è£ çœ®åã³åççšæå ç¯ã
ããããããã®ãã¡ãæ°Žéèžæ°ã¢ãŒã¯ãç¹ã«å€ªéœ
ç¯ãæã奜é©ã§ããã 也ç¥ãã€ã«ã ããªãã¬ãžã¹ãçµæç©ã¯é²å åŸå ¬
ç¥ã®æ¹æ³ã§ãäŸãã°ã¬ãžã¹ããã€ã«ã ã®æªé²å éš
åãæŽãæµãããšãã§ããææ©æº¶åªãŸãã¯ãã®æ··
åç©ã§ãæ¹æ浞挬ãã©ã·æŽæµãçšãããææã®ç»
åãžã®ã¹ãã¬ãŒãžãšããæµã®å¹ä»ãã«ããçŸåã§
ãããæçšãªæº¶åªãšããŠã¯é ¢é žã»ã«ããŒã¹ãé ¢é ž
ãšãã«ãã¡ãã«ãšãã«ã±ãã³ãã¢ã»ãã³ãããã©
ã¯ãã«ãšãã¬ã³ãïŒãïŒåã®ççŽ ååãæããã¢
ã«ã«ããŒã«é¡ãããã«ã»ããœã«ããã¯ãã«ãã³ãŒ
ã³åã³ãžã¡ãã«ãã«ã ã¢ãããŸãã¯ãããã¯å°é
ã®ææ©æ·»å ç©ãå«æããŠããŠãããæ°ŽãŸãã¯åŒ±ã¢
ã«ã«ãªæ§æº¶æ¶²ãããã ããªãã¬ãžã¹ãçµæç©äžã«çšãã以å€ã«ãåèš
ã®å éåæ§çµæç©ã¯ã玫å€ç·ç¡¬åæ§ã³ãŒãã€ã³ã°
åã³å°å·çµæç©äžã«ã䜿çšã§ããããããã®çµæ
ç©ã¯å€§äœããªãŒã©ãžã«ã«ä»å éåæ§ã¢ãããŒãå
éåéå§å€åã³æ¬çºæã®ããªã³ãã¢ãŠãææçµæ
ç©ããæ¢ã«èšèŒããä»ã®ç¹å®ããæ·»å å€ã«å ãã
å«æããããããã®çµæç©ã¯äžè¬ã«çŽ0.1ãïŒã
ããæ®éã«ã¯çŽ0.2ãïŒééïŒ ã®æ¬çºæã®ããªã³
ãã¢ãŠãææçµæç©ãå«æããã äžè¿°ãããšãã¬ã³åäžé£œåååç©ãæçšã§ãã
ããã¢ã¯ãªãªã«ååç©ãæ®ã«äžè¿°ããããã«ã¢ã¯
ãªãªã«ãªãªãŽããŒåã³ãšã¹ãã«ã®åœ¢ã®ãã®ãç¹ã«
æçšã§ããã æçšãªä»ã®äžçŸ€ã®ãªãªãŽããŒã¯æ¬¡ã®ããã«ããŠ
åŸããããããªãã¡ãææ©ããªãšãŒãã«ããªãªãŒ
ã«ãŸãã¯ããªãšã¹ãã«ããªãªãŒã«ããžã€ãœã·ã¢ã
ãŒããšåå¿ãããããšã«ãããã€ãœã·ã¢ããŒãæ«
端ãã¬ããªããŒãåŸãããã®çæç©ãäžé£œåã¢ã«
ã³ãŒã«ãäŸãã°ããããã·ã«ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ããšåå¿ãããããåç¬ãŸãã¯ä»ã®äžé£œåã¢ãã
ãŒãšçµåããŠãããªãŒã©ãžã«ã«ã®åœ±é¿äžã§éå
ãã硬質匷éç²çæ§ãã€ã«ã ã圢æããç©è³ªãšã
ãã äžèšã®ãã®ã®å€åœ¢ãšããŠãããªã¡ãããŒã«ããª
ã¹ïŒããªã°ãªã³ã¬ãŒãïŒãããªã¡ãããŒã«ããã
ã³ããªã¹ïŒã¡ã«ã«ããããããªããŒãïŒããã³ã¿
ãšãªã¹ãªããŒã«ããã©ãã¹ïŒããªã°ãªã³ã¬ãŒãïŒã
ãã³ã¿ãšãªã¹ãªããŒã«ããã©ãã¹ïŒã¡ã«ã«ããã
ãããªããŒãïŒçã®ãããªéåäœã«ãããšã¹ãã«
ããžã€ãœã·ã¢ããŒããšåå¿ãããããšã«ããããª
ããªãŠã¬ã¿ã³äžéäœãåŸããã®äžéäœãäžé£œåã¢
ã«ã³ãŒã«ãäŸãã°ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ããšåå¿ãããåç¬ãŸãã¯ä»ã®äžé£œåã¢ãããŒãš
çµåããŠãæ¶æ©åŸåªããç®èç¹æ§ãæããããªãŒ
ã©ãžã«ã«éåæ§ç©è³ªãšããã æçšãªãªãªãŽããŒã®ä»ã®äŸã¯ããããã·æ«ç«¯ã
ãªã«ããã©ã¯ãã³ããžã€ãœã·ã¢ããŒããšåå¿ã
ãã次ãã§ã€ãœã·ã¢ããŒãæ«ç«¯äžéäœãäŸãã°ã
ãããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒãã®ãããªäžé£œåã¢
ã«ã³ãŒã«ãšåå¿ãããããšã«ããåŸãããã¢ã¯ãª
ã¬ãŒãæ«ç«¯ä»å ããªã«ããã©ã¯ãã³ããªãŠã¬ã¿ã³
ã§ããã æŽã«ä»ã®æçšãªäžçŸ€ã®ãªãªãŽããŒã¯ãšããã·æš¹
èãã¢ã¯ãªã«é žãšåå¿ãããŠããšããã·ãžã¢ã¯ãª
ã¬ãŒããšããããšã«ããåŸããããäŸãã°ããšã
ã¯ãã«ãããªã³ïŒãã¹ããšããŒã«ïŒ¡åãšããã·æš¹
èãååŠéè«çéã®ã¢ã¯ãªã«é žãšåå¿ãããããš
ãã§ããããã®ãããªçæç©ã¯åæšâEpocrylâ
ãšããŠShell Chemical Companyããåžè²©ãããŠ
ãããã®ã§ãããå¥ã®ãã®ãšããŠã¯ãUnion
Carbide Companyããã®Ucarâ80ãããããã®
ãããªç©è³ªã¯åçš®ã®ã¢ã¯ãªã«ç³»ãšã¹ãã«ãäŸãã°
ããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããã
ãã·ãšãã«ã¢ã¯ãªã¬ãŒãåã³ãžã·ã¯ããã³ãã«ã¢
ã¯ãªã¬ãŒããåã³ä»ã®ããªãªãŒã«ã®äžé£œåãšã¹ã
ã«ãäŸãã°ã¡ãã¬ã³ã«ã«ãã³é žãšã¹ãã«ïŒäŸã
ã°ããšãã¬ã³ãžã¢ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒ
ããã°ãªã»ããŒã«ããªã¢ã¯ãªã¬ãŒãããšãã¬ã³ãž
ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãããã¬ã³ãžã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ããªã¡ã¿
ã¯ãªã¬ãŒããïŒïŒïŒâãã³ãŒã³ãžãªãŒã«ãžã¡ã¿ã¯
ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ååé200ã500ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ã®ãã¹
ã¢ã¯ãªã¬ãŒãåã³ã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒ
ã«ãããã³ããªã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªã
ãŒã«ããªã¢ã¯ãªã¬ãŒãïŒåã³ä»ã®ãšãã¬ã³åäžé£œ
åååç©ãšçµåããŠããªãŒã©ãžã«ã«ã®åœ±é¿äžã§é
åã§ããåªããæ¥çæ§åã³åŒ·éæ§ãæãããã€ã«
ã ãåŸãããã ä»ã®çµæç©ã¯æ«ç«¯äžé£œåãŠã¬ã¿ã³çµæç©ïŒããª
ãšã³ïŒåã³ããªããªãŒã«ã®çµåãã§ãååŠç·å ã®
äœçšã«ããå éåéå§å€äžã«çæããããªãŒã©ãž
ã«ã«ã®åœ±é¿äžã§éåãããããã®ãå«ãã å¡åžåã³å°å·ã€ã³ã¯çµæç©ã¯äž»èŠéã®è圢ææ§
ç©è³ªåã³æå å€åã³æ¯èŒçå°éã®ãã€ã³ææåã³
ããã²ã³ååç©ãå«æãããäŸãã°ãå žåçãªçµ
æç©ã¯15ã70ééïŒ ã®äžè¿°ãããšãã¬ã³åäžé£œå
ååç©ã10ã50ééïŒ ã®ïŒçš®ä»¥äžã®äžé£œåã¢ãã
ãŒãŸãã¯äºãå¥é補é ããéåäœãã€ã³ããŒã
0.1ã15ééïŒ ã®å éåéå§å€ã0.01ãïŒééïŒ
ã®äžè¿°ãããã€ã³ææåã³0.1ãªããïŒééïŒ ã®
ããã²ã³å«æååç©ãå«æããŠãããæŽã«çãç¯
å²ã¯çŽ40ã55ïŒ ã®ãšãã¬ã³åäžé£œåååç©ã30ã
45ïŒ ã®ã¢ãããŒãŸãã¯éåäœãã€ã³ããŒã0.5ã
15ïŒ ã®å šéå§å€ã0.5ãïŒïŒ ã®ææåºå€åã³0.8ã
ïŒïŒ ã®ããã²ã³ååç©ïŒå šãŠééïŒ ïŒãå«æãã
ã§ãããã ããªãã¬ãžã¹ãçµæç©ã¯ããã°ãã°ïŒæã®å¥é¢
å¯èœãªéåäœãã€ã«ã éã«ããªãã¬ãžã¹ãå±€ãæ
ãã ç©å±€ç©ãµã³ãã€ãããšããŠæäŸãããããã€
ã«ã ã®äžæ¹ã¯æŽ»æ§å ç·ã«å¯ŸããŠå®è³ªçã«éæã§ãª
ããã°ãªããªãããã€ã«ã ã¯éåžžçŽ0.00635ã
0.254mmïŒ0.25ã10ãã«ïŒã®åãã§ãããã 以äžãæ¬çºæãäŸç€ºããããå®æœäŸã瀺ããã
ãããã¯æ¬çºæãå¶éãããã®ã§ã¯ãªãã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ã¢ã¯ãªã«ç³»éåäœïŒ56ïŒ ã¢ã¯ãªã«é žãšãã«ã 37ïŒ ã¡ã¿ã¯ãªã«é žã¡ãã«åã³ïŒïŒ ã¢ã¯ãªã«é žãã¡ãã«ãšãã«ã±ãã³äž 30âã«ãããåºæç²åºŠ0.458ïŒ 12.63ïœ ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãäžéšãšã¹ã
ã«åã é žäŸ¡270åã³ååé1700 12.63ïœ ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã6.67ïœ ãã³ãŸããšãã³ 1.30ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.067ïœ ããªãªã¢ã³ãã°ãªãŒã³ææïŒC.I.42040ïŒ 0.0027ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 0.39ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.63ïœ ã¡ãã«ãšãã«ã±ãã³ 100.00ïœ æº¶æ¶²ã¯çŽ25ïŒ ã®åºåœ¢åãå«æããŠãããããã
äºè»žå»¶äŒžããããŒãã»ããããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã€ã«ã äžã«ãã¯ã¿ãŒãã€ãã§0.023
mmïŒ0.00092ã€ã³ãïŒã®åãã«å¡åžãããå¡èã
颚也ããããšã«ãã也ç¥èå0.033mmïŒ0.00130ã€
ã³ãïŒã®æ¥µèç·è²ã®ãã€ã«ã ãåŸããé ã被çã
ããšããã·âã¬ã©ã¹ç¹ç¶æ¿ïŒæãSomaca
Model SBCâ12æŽæµåšãçšããŠæŽæµã也ç¥ããã
ãã®éŒæ¿ãXidexç©å±€æ©ãçšããŠ115âã§0.9ã1.2
ïœïŒïŒãïŒãã€ãŒãïŒïŒåã®é床ã§ä¹Ÿç¥å éåæ§
çµæç©ãšç©å±€ãããåŸãããããªãšã¹ãã«ãã€ã«
ã ãå éåæ§çµæç©åã³é ãããªãè€åç©ã¯é»è²
å äžã§ããããªãé²åºããé ãšèå¥ããã«ãå å
ãªã³ã³ãã©ã¹ããæãããããã«ç·è²ãæããŠã
ããé ãµã³ãã€ããäœãColight 1200watt
DMVLâ玫å€ç·é²å æºãçšããŠãéæç»ã«10
åéé²å ãããé²å çŽåŸã匷ã玫è²ç»åããèç·
è²èæ¯ãšåªããã³ã³ãã©ã¹ããæããé²å éšåäž
ã«åœ¢æãããããã®æ¿ãDEA Americana2401çŸ
象液äžã§76.2cmïŒ30â³ïŒã®åŽé§å®€ãçšããŠçŸåã
ãããã®å šäœçã«æ°Žæ§ã®çŸå液ã¯0.75ééïŒ ã®ç
é žãããªãŠã âæ°Žåç©ã26.7ã29.4âïŒ80ã85
ãïŒã§å«æããŠããã1.41KgïŒcm2ïŒ20psiïŒã®åŽ
é§å§ååã³1.05ïœïŒ3.5ãã€ãŒãïŒïŒåã®èµ°è¡é
床ãçšããŠãæ¿ãçŸå液äžã«éããæŽæµåã³ä¹Ÿç¥
åŸãæ®åããé²å ç»åã¯é²å ããå®è³ªçã«äžå€å
ã§æ®ã€ãŠãã匷ãè²ãæããŠãããæ¿ãïŒåé20
ïŒ éç¡«é žã¢ã³ã¢ããŠã 溶液ã«æµžæŒ¬ãã倧éã®æ°Žã§
æŽæµãã20ïŒ HCl溶液ã«ïŒåé浞挬ããå床氎æŽ
ãã次ãã§45åéé žæ§ç¡«é žé 济äžã§900cm2ïŒïŒå¹³
æ¹ãã€ãŒãïŒåœã25ã¢ã³ãã¢ã§åšå²æž©åºŠã§ã¡ãã
ãããã¡ããåŸãã¬ãžã¹ãç»åã®èå¥ã§ããè²å€
åã¯äœãèµ·ããªãã€ãã次ãã§ãæ¿ãåã³æŽæµ
ããïŒåé15ïŒ ãã«ãªãç¡Œé žã«æµžæŒ¬ãã次ãã§
PbïŒSnã¡ãã济äžã§900cm2ïŒïŒå¹³æ¹ãã€ãŒãïŒåœ
ã15ã¢ã³ãã¢ãçšããŠåšå²æž©åºŠã§30åéã¡ããã
ããåã®ããã«ãäœãèå¥ã§ããè²å€åã¯èŠ³å¯ã
ããªãã€ãã玫è²ã¬ãžã¹ãç»åã¯3.0ééïŒ KOH
溶液äž40âã§40ç§é浞挬ããããšã«ããã¹ããªã
ãã³ã°ãããæŽæµåŸãæ¿ãFeCl3溶液äžã§ãšãã
ã³ã°ããããã«ããä¿è·ãããŠããªãé ãå šãŠé€
å»ããã䜿çšå¯èœãªé»æ°åè·¯æ¿ãåŸãããã å®æœäŸ ïŒ çšããããªã³ãã¢ãŠãææãçéã®ãã€ã³ãã©
ã«ã€ãã°ãªãŒã³åã³ä»ã®ææãçéã®ãã©ããµãª
ãã³ã¢ã»ããŒãïŒC.I.42500ïŒã§ãã€ã以å€ã¯å®
æœäŸïŒã®çµæç©ãçšãããå¡åžåŸãçµæç©ã¯é²å
åŸåŸãããæç·è²ã®ããªã³ãã¢ãŠãç»åã«å¯ŸããŠ
é»è²å äžã§è¯å¥œãªã³ã³ãã©ã¹ãã瀺ãããããªèµ€
è²ãããŠãããæ¿ãåäžæ¡ä»¶äžã§çŸåããããé²
å ããé ã¯AcâCu guardãšããã³ã°æº¶æ¶²ãå«æ
ããDEAãšããã³ã°æ¶²äžã§PH8.7åã³æž©åºŠ45âã§
ãšããã³ã°ãããæ¿ã1.8ïœïŒïŒãã€ãŒãïŒãšã
ãã³ã°å®€ã«1.8ïœïŒïŒãã€ãŒãïŒïŒåã®é床ã§é
ãããã¬ãžã¹ãã¯ãããã«æã€ãããè²ã¯å®è³ªäž
å€åããªãã€ãã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ããªïŒã¡ã¿ã¯ãªã«é žã¡ãã«ïŒãã¡ãã«ãšãã« ã±ãã³äž30âã®åºæç²åºŠïŒ0.380 9.36ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã2.50ïœ ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã
2.50ïœ ãã¿ã«é žãžãªã¯ãã« 0.10ïœ ãã³ãŸããšãã³ 0.85ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.030ïœ ïŒâã¡ãã«âïŒïŒïŒâãžâïœâããã«ããšããŒã«
0.002ïœ ããªãªã¢ã³ãã°ãªãŒã³ææïŒC.I.42040ïŒ0.002ïœ ïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã« 0.010ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.255ïœ ãã€ã³ãã©ããµããªã³ 0.175ïœ ã¡ãã«ãšãã«ã±ãã³ 33.0ïœ æº¶æ¶²ã0.023mmïŒ0.00092ã€ã³ãïŒåã®ããªãšã¹
ãã«ãã€ã«ã äžã«0.038mmïŒ1.5ãã«ïŒã®ä¹Ÿç¥èå
ã«å¡åžããã次ãã§ããããå®æœäŸïŒã«ãããã
ãã«æž æµãªé ã被çããç©å±€ç©ã«ç©å±€ããããã€
ã«ã ã15ç§éDMVLâäžã§é²å ããããšã«ã
ãç·è²ã®èæ¯äžã«åŒ·ãèµ€è²ããªã³ãã¢ãŠããåŸ
ããé²å æ¿ã宀枩æ¡ä»¶ã§15åéä¿æãã次ãã§
ïŒïŒïŒïŒïŒâããªã¯ãã«ãšã¿ã³äžã§2.1ïœïŒïŒã
ã€ãŒãïŒïŒåã§20.0âïŒ68ãïŒã§çŸåããã也ç¥
åŸãæ¿ãå®æœäŸïŒã«ãããããã«ã¡ããåæž æµã
ãã次ãã§ãããã51.7âïŒ125ãïŒã§ããçé ž
é ã¡ãã济äžã§45åé900cm2ïŒïŒå¹³æ¹ãã€ãŒãïŒ
åœã25ã¢ã³ãã¢ãçšããŠã¡ãããããã¡ããåŸã
æ¿ãè²æ倱ã«ã€ããŠæ€æ»ãããšãããäœãæ倱ã¯
芳å¯ãããªãã€ããïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸ
ãŒã«ãçšããªãã€ã第äºã®åŠæ¹ã§ã¯ãã¡ããåŸã¬
ãžã¹ãã®æ¥çæ§ãä¹ããã€ã以å€ã¯åæ§ãªçµæã
åŸãããã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ã¢ã¯ãªã«ç³»éåäœãã¡ãã«ãšãã«ã±ãã³ äž30âã®åºæç²åºŠ0.11ãé žäŸ¡55â60 21.00ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã3.30ïœ ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã3.30ïœ ãã³ãŸããšãã³ 1.75ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.092ïœ ïŒâã¡ãã«âïŒïŒïŒâãžâïœâããã«ããšããŒã«
0.0014ïœ ããŒã·ãã¯ãã«â26ïŒC.I.44045ïŒ 0.0040ïœ ããªãªã¢ã³ãã°ãªãŒã³ 0.0008ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 0.300ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.50ïœ ã¡ãã«ãšãã«ã±ãã³ 50.00ïœ ã¡ã¿ããŒã« 2.00ïœ æº¶æ¶²ãåãšåæ§ã«åã0.023mmïŒ0.00092ã€ã³
ãïŒã®ããªãšã¹ãã«æ¯æäœã«0.038mmïŒ0.00150ã€
ã³ãïŒã®ä¹Ÿç¥èåã«å¡åžããã也ç¥åŸãïŒæã®è©Š
éšçã¯ã88.9cmïŒ35â³ïŒÃ15.2cmïŒ6â³ïŒã®28.4ïœ
ïŒïŒãªã³ã¹ïŒã®é ã被çããïŒæã®ãšããã·âã¬
ã©ã¹ç¹ç¶æ¿ã«ããããç©å±€ãããïŒæç®ã®è©Šéšç
ã¯ãåã0.025mmïŒ0.0010ã€ã³ãïŒã®ããªãšãã¬
ã³ã«ç©å±€ããããã®ãã€ã«ã çãåŸã§äœ¿çšããã
ãå£ãžããŒãã§åãã€ãããïŒæã®é æ¿ã¯ã35ã
38âã®Blue ïŒçäžã«ïŒæ¥é眮ãããïŒæç®ã®é
æ¿ã¯åšå²æž©åºŠã®åŒåºãã®äžã«å ¥ãã第äžã®é æ¿ã¯
å®æœäŸïŒã«ãããããã«é²å ãçŸåãããæšæºé
段å åããã³æ¿äžã§ïŒâïŒé段ã®åçé床ã®æ玫
è²ã®ããªã³ãã¢ãŠãç»åãåŸããããããã²ã³å
ã·ã¯ããããµã³ã0.32ïœã®åèåççŽ ã«ãã代ã
ã以å€ã¯ãåæ§ã®çµæç©ã補é ãããé²å åã³çŸ
ååŸãåæ§ãªçŽ«è²ç»åãåŸããããã10âïŒé段
ã§ãã€ããçäžã§ïŒæ¥éãŸãã¯å®€æž©ã§ïŒé±éåŸ
ïŒé äžåã³ããªãšãã¬ã³å ç©å±€è©Šæå ±ïŒãèçŽ åã·
ã¯ããããµã³èªå°äœãçšããåçé床ãŸãã¯ããª
ã³ãã¢ãŠãç»åæ¿åºŠã«äœãå€åãªãã€ãã
Perkin Elmer402玫å€ç·åå å 床èšã«ãã枬å®ã
ããã€ã«ã ã®è²ã¯æåããªãã€ããããã²ã³åã·
ã¯ãããã»ã³ã®ä»£ãã«åèåççŽ ãçšããåŠæ¹ã«
ãããŠã¯ãäžèšã®ããšãèµ·ãããããªãã¡ãçå
ã®è©Šæã¯å®å šã«çŽ«è²ã«å€åããé²å ããŠãäœãã
ãªã³ãã¢ãŠãç»åã圢æãããªãã€ããåçé床
ã¯ïŒâïŒé段äœäžãããåŒåºãäžã«ä¿åããé æ¿
äžã®è©Šæã¯ããæãèæ¯äžã«ããããªããªã³ãã¢
ãŠãç»åãäžããããåçé床ã®æ倱ã¯åæ§ã§ã
ã€ããããªãšãã¬ã³ãšç©å±€ããè©Šæã¯èæ¯æ¿åºŠã«
ãããŠ2.5ä¿æ°å¢å ããåçé床ã®æ倱ã¯ïŒâïŒ
é段ã§ãã€ãã2â²ïŒ3â²ïŒ4â²âããªã¯ãã«ã¢ã»ãã
ãšãã³ãâã¯ãã«ã¹ã¯ã·ã³ã€ãããŸãã¯ãšãŒã
ãã«ã ãçšãããšããåæ§ã®çµæãåŸãããã å®æœäŸ ïŒ å¡åžçµæç©ãäžèšã®æåãã補é ããã Actomer â80ïŒUnion Carbide補ãšããã·å
倧è±æ²¹ïŒ 30.00ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã
20.00ïœ ãã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒã 10.00ïœ é ¢é žããã« 20.00ïœ ãã³ãŸããšãã³ 12.00ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
1.0ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 1.5ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 1.0ïœ æº¶æ¶²ã0.25mmïŒ10ãã«ïŒã®ãã¯ã¿ãŒãã€ãã§ïŒ
æã®åçŽã«å¡åžããã次ãã§ãã®ç²çæ§å¡èãé«
匷床玫å€ç·æºã«60ç§éïŒDMVLâã1200ã¯ã
ãé»çïŒã«é²å ãããæè²ã«çè²ãã匷éãªèåŒ
æ»æ§ãã€ã«ã ãåŸãããããã¯ã¡ã¿ããŒã«ãŸãã¯
ïŒïŒïŒïŒïŒâããªã¯ãã«ãšã¿ã³ã«å¯Ÿãèæ§ã§ãã€
ãã ç£æ¥äžã®å©çšå¯èœæ§ äžèšã®çµæã«ããç«èšŒãããããã«ãæ¬çºæã®
ããªã³ãã¢ãŠãææçµæç©ãçšãããšãå éåæ§
çµæç©ã®è£œé ã«ãããŠãåªããçµæãåŸãããã
ææã¯éåäœã®å 硬åãå¹²æžããªãã®ã§ãå®å®ãª
å¡èãåŸããããæŽã«ãçµæç©ã¯å¡åžçšçµæç©ãš
ããŠãæªç¡¬åãã€ã«ã ãšããŠããé·æéä¿åã§
ããçµæç©ã®æ§è³ªã«æªåœ±é¿ã¯ã¿ãããªããæŽã«ã
ãã®ããªã³ãã¢ãŠãææçµæç©ã¯åŠçäžæ害ãªãŸ
ãã¯å±éºãªç ãçæããããŸãäœãå¬æ¶æ§äœçšã®
城åã¯ãªããæåŸã«ãææã®è²ã¯ä¿æãããåŸç¶
ã®åŠçäžå¿ èŠãªã³ã³ãã©ã¹ããäžããã
ããã ç¹ã«å¥œãŸããã¢ã¯ãªãªã«ååç©ã¯ããªãšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããã©ãšãã¬ã³ã°ãª
ã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ã
ãªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¢
ã¯ãªã¬ãŒãåã³ãã³ã¿ãšãªã¹ãªããŒã«ããã©ã¢ã¯
ãªã¬ãŒãã§ããã 代衚çãªéåäœãã€ã³ããŒãšããŠã¯ãããªã¹ã
ã¬ã³ãããªã«ãŒãããŒããããªãŠã¬ã¿ã³ãããªã
ã«ã ã¢ã«ããããããªããã«ã¢ã»ã¿ãŒã«ïŒäŸã
ã°ãããªããã«ããã©ãŒã«ïŒãããªå¡©åããã«å
ã³å ±éåäœãããªãšãŒãã«é¡ïŒäŸãã°ãããªãšã
ã¬ã³ãªãã·ããããªãããã¬ã³ãªãã·ããããªã
ãã©ããããã©ã³ïŒãããªã¢ã¯ãªã¬ãŒãé¡ïŒäŸã
ã°ããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããããªãšãã«ã¡ã¿ã¯
ãªã¬ãŒããããªã¡ãã«ã¢ã¯ãªã¬ãŒãåã³ããªãšã
ã«ã¢ã¯ãªã¬ãŒãïŒããªããã«ãšã¹ãã«é¡ïŒäŸã
ã°ãããªé ¢é žããã«åã³ããªé ¢é žããã«ïŒã¢ã¯ãª
ã«é žãšã¹ãã«ïŒãã»ã«ããŒã¹ãšã¹ãã«é¡ïŒäŸãã°
é ¢é žã»ã«ããŒã¹åã³é ¢é žé ªé žã»ã«ããŒã¹ïŒãã»ã«
ããŒã¹ãšãŒãã«é¡ïŒäŸãã°ãã¡ãã«ã»ã«ããŒã¹å
ã³ãšãã«ã»ã«ããŒã¹ïŒãå€æ§ããªãªã¬ãã€ã³é¡
ïŒäŸãã°ããšãã¬ã³ïŒé ¢é žããã«å ±éåäœïŒãããª
å¡©åãããªãã³ïŒå¡©åãããªãã³ãšã¢ã¯ãªã«ãã
ãªã«ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãåã³é ¢é žããã«ã®å ±
éåäœãå«ãïŒãããªã¢ããé¡ïŒäŸãã°ãããªã«
ããã©ã¯ãã³ãããªã«ããã©ã¯ã¿ã åã³ããªãã
ãµã¡ãã¬ã³ã¢ãžãããïŒåã³ããªãšã¹ãã«é¡ïŒäŸ
ãã°ãããªãšãã¬ã³ã°ãªã³ãŒã«ãã¬ãã¿ã¬ãŒãå
ã³ããªãããµã¡ãã¬ã³ã¹ã¯ã·ããŒãïŒãããã å éåæ§çµæç©ã«äœ¿çšããå éåæ§éå§å€ã¯å
åŠç·å ã§æŽ»æ§åããã185â以äžã§ç±çã«å®å®ã§
ãããã®ã奜ãŸãããããããªéå§å€ãšããŠã¯ã
眮æãŸãã¯é眮æå€æ žããã³é¡ãäŸãã°ïŒïŒ10â
ã¢ã³ãã©ããã³ãïŒâã¯ãã«ã¢ã³ãã©ããã³ãïŒ
âã·ã¯ãã¢ã³ãã©ããã³ãïŒâã¡ãã«ã¢ã³ãã©ã
ãã³ãïŒâãšãã«ã¢ã³ãã©ããã³ãïŒâtertâã
ãã«ã¢ã³ãã©ããã³ããªã¯ã¿ã¡ãã«ã¢ã³ãã©ãã
ã³ãïŒïŒïŒâãããããã³ãïŒïŒ10âããšãã³ã
ã©ããã³ãïŒïŒïŒâãã³ãŸã¢ã³ãã©ããã³ãïŒïŒ
ïŒâãã³ãŸã¢ã³ãã©ããã³ãïŒâã¡ãã«âïŒïŒïŒ
âãããããã³ãïŒïŒïŒâãžã¯ãã«ããããã
ã³ãïŒïŒïŒâãžã¡ãã«ã¢ã³ãã©ããã³ãïŒïŒïŒâ
ãžã¡ãã«ã¢ã³ãã©ããã³ãïŒâããšãã«ã¢ã³ãã©
ããã³ãïŒïŒïŒâãžããšãã«ã¢ã³ãã©ããã³ãïŒ
âã¯ãã«âïŒâã¡ãã«ã¢ã³ãã©ããã³ãã¬ãã³ã
ãã³ãïŒïŒïŒïŒïŒïŒ10âããã©ãããããã¿ã»ã³
ããã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ããããã³ãº(a)
âã¢ã³ãã©ã»ã³âïŒïŒ12âãžãªã³ãããã ç±³åœç¹èš±ç¬¬2760863å·ã«èšèŒãããäžèšã®å é
åéå§å€ããŸãã掻æ§ã§ããããæçšã§ãããã
ã®ãã¡ãããã®ã¯85âãšããäœã枩床ã§ãç±çã«
å®å®ã§ããããã·ãã«ã±ã¿ã«ããã«ååç©ãäŸã
ã°ãžã¢ã»ãã«åã³ãã³ãžã«ïŒã¢ã«ãã¢ã±ã¿ã«ãã
ã«ã¢ã«ã³ãŒã«é¡ãäŸãã°ãã³ãŸã€ã³åã³ãããã€
ã³ïŒã¢ã¯ãã€ã³ãšãŒãã«é¡ãäŸãã°ãã³ãŸã€ã³ã¡
ãã«åã³ãšãã«ãšãŒãã«ïŒÎ±âçåæ°ŽçŽ çœ®æè³éŠ
æã¢ã·ãã€ã³ãαâã¡ãã«ãã³ãŸã€ã³ïŒÎ±âã¢ãª
ã«ãã³ãŸã€ã³åã³Î±âããšãã«ãã³ãŸã€ã³ã ãã³ãŸã€ã³ãšãŒãã«é¡ã®å ·äœäŸãšããŠã¯ããã³
ãŸã€ã³ã¡ãã«ãšãŒãã«ããã³ãŸã€ã³ãšãã«ãšãŒã
ã«ããã³ãŸã€ã«ããšãã«ãšãŒãã«ãã¡ãã«ãã³ãŸ
ã€ã³åã³ãšãã«ãã³ãŸã€ã³ãããã ããçš®ã®è³éŠæã±ãã³ãäŸãã°ãã³ãŸããšãã³
åã³ïŒïŒ4â²âãã¹âïŒãžã¢ã«ãã«ã¢ããïŒãã³ãŸ
ããšãã³ãæçšã§ããããã®å ·äœäŸãšããŠã¯ãã³
ãŸããšãã³ãïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒã
ã³ãŸããšãã³ãïŒïŒ4â²âãã¹ïŒãžãšãã«ã¢ããïŒ
ãã³ãŸããšãã³ãïŒâããããã·â4â²ãžãšãã«ã¢
ãããã³ãŸããšãã³ãïŒâããããã·â4â²âãžã¡
ãã«ã¢ãããã³ãŸããšãã³ãïŒâã¢ã¯ãªã«ãªãã·
â4â²âãžã¡ãã«ã¢ãããã³ãŸããšãã³ãåã³ïŒâ
ã¡ããã·â4â²âãžã¡ãã«ã¢ãããã³ãŸããšãã³ã
ããã éåéå§å€ã¯ã¢ã·ãã€ã³ãšãŒãã«ãã¢ã«ãã«åº
ãïŒãïŒåã®ççŽ ååãå«æããŠããã¢ã«ãã«çœ®
æã¢ã³ãã©ããã³ããã³ãŸããšãã³ãŸãã¯ã¢ã«ã
ã«ã¢ãããã³ãŸããšãã³ã®å°ãªããšãäžçš®ãå«æ
ããã®ã奜ãŸããã 奜ãŸããå éåæ§çµæç©ã«ã¯ãç±éåæå¶å€ã
æ·»å ãããç±éåæå¶å€ã®äŸãšããŠã¯ãïœâã¡ã
ãã·ããšããŒã«ããã€ããããã³ãã¢ã«ãã«åã³
ã¢ãªãŒã«çœ®æãã€ããããã³åã³ããã³é¡ãïœâ
ããã«ã«ãã³ãŒã«ãããã¬ããŒã«ãããžã³é žé ã
ãããã«ã¢ãã³é¡ãβâããããŒã«ãïŒïŒïŒâãž
âtertâããã«ïœâã¯ã¬ãŸãŒã«ãïŒïŒ2â²âã¡ãã¬
ã³âãã¹âïŒïŒâãšãã«âïŒâïœâããã«ããšã
ãŒã«ïŒãããªãžã³ãããããã³ãŒã³ããžãããã
ã³ãŒã³ãïœâãã«ããã³ãã¯ãã©ãã«ãäºçé žã¢
ãªãŒã«åã³äºçé žã¢ãªãŒã«ã¢ã«ãã«ãããã ããªãã¬ãžã¹ãçµæç©ãšããŠçšããå éåæ§çµ
æç©ã¯ãéåžžé©åœãªæº¶åªãæ®éã«ã¯ææ©æº¶åªãäŸ
ãã°ïŒãïŒåã®ççŽ ååãæããã±ãã³åç¬äžã«
ãŸãã¯ããããªã±ãã³ãšïŒãïŒåã®ççŽ ååãæ
ããã¢ã«ã«ããŒã«ãšã®æ··æ¶²äžã«åŠæ¹ããããã®äž
ã®åºåœ¢åçŸåçã¯éåžžçŽ10ã50ééïŒ ã§ããã ããªãã¬ãžã¹ãçµæç©ã¯ãé ã·ãŒãäžã«ãéåžž
ã¯äžé¢é å±€ãæããç©å±€æ¿ã«æªç¡¬åããªãã¬ãžã¹
ãå±€ãé å±€ãšæ¥è§Šããããã«é©çšãããããªãã¬
ãžã¹ãå±€çšä¿è·ãã€ã«ã ãæŽã«èšããããšã«ã
ããä¿è·ãã€ã«ã ãæªç¡¬åããªãã¬ãžã¹ãå±€åã³
é å±€ã®ãµã³ãã€ãããšããããšãã§ãããããªã
ã¬ãžã¹ãå±€ã¯çŽ0.00635ã0.127mmïŒ0.25ãïŒã
ã«ïŒãéåžžã¯çŽ0.019ã0.10mmïŒ0.75ãïŒãã«ïŒã®
åãã®ä¹Ÿç¥èåãæãããä¿è·å±€ã¯éåžžçŽ0.0127
ã0.127mmïŒ0.5ãïŒãã«ïŒåãã§ãããäžæŽ»æ§ã®
ä»å ãŸãã¯çž®åéåäœãäŸãã°ããªãããã¬ã³ã®
ãããªïŒãïŒåã®ççŽ ååãæããããªãªã¬ãã€
ã³ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãçã§ãã€ãŠã
ãã 䜿çšã«åœã€ãŠã¯ãå éåæ§ä¹Ÿç¥ãã€ã«ã ã掻æ§
å ç·å æºã«é²å ããããããã¯äžé調ç»åãŸãã¯
ããã»ã¹éæç»ãäŸãã°ããã»ã¹ãã¬ãŸãã¯ã
ãžãã¹ãã³ã·ã«ãŸãã¯ãã¹ã¯ãéããŠè¡ãããé²
å ã¯ãŸãé£ç¶é調ãã¬ãŸãã¯ããžç»åãéããŠã
ãããé²å ã¯éåæ§å±€äžã«ã«ããŒã·ãŒããèšããŠ
ãŸãã¯èšããã«å¯çãŸãã¯æå°æ³ã«ãããããã
ã¯ã«ããŒã·ãŒããçšããŠæå°æ³ã«ããè¡ãªãããš
ãã§ããããããã®æ¹æ³ã¯ãã®åéã§åœæ¥è ã«ã
ãç¥ãããŠãããããªãã¬ãžã¹ãçµæç©ã®é²å ã«
ã¯ãäžè¬ã«çŽ«å€ç·ã䜿çšãããããç·æºã¯å¹æç
éã®çŽ«å€ç·ãäžãããã®ã§ãªããã°ãªããªããç¹
ãŸãã¯ãããŒãæŸå°ç·æºãå¹æçã§ããããã®ã
ããªç·æºãšããŠã¯ãã«ãŒãã³ã¢ãŒã¯ãæ°Žéèžæ°ã¢
ãŒã¯ã玫å€ç·æŸå°æ§çå äœãå«ãèå ç¯ãã¢ã«ãŽ
ã³ã°ããŒç¯ãé»æ°ããå è£ çœ®åã³åççšæå ç¯ã
ããããããã®ãã¡ãæ°Žéèžæ°ã¢ãŒã¯ãç¹ã«å€ªéœ
ç¯ãæã奜é©ã§ããã 也ç¥ãã€ã«ã ããªãã¬ãžã¹ãçµæç©ã¯é²å åŸå ¬
ç¥ã®æ¹æ³ã§ãäŸãã°ã¬ãžã¹ããã€ã«ã ã®æªé²å éš
åãæŽãæµãããšãã§ããææ©æº¶åªãŸãã¯ãã®æ··
åç©ã§ãæ¹æ浞挬ãã©ã·æŽæµãçšãããææã®ç»
åãžã®ã¹ãã¬ãŒãžãšããæµã®å¹ä»ãã«ããçŸåã§
ãããæçšãªæº¶åªãšããŠã¯é ¢é žã»ã«ããŒã¹ãé ¢é ž
ãšãã«ãã¡ãã«ãšãã«ã±ãã³ãã¢ã»ãã³ãããã©
ã¯ãã«ãšãã¬ã³ãïŒãïŒåã®ççŽ ååãæããã¢
ã«ã«ããŒã«é¡ãããã«ã»ããœã«ããã¯ãã«ãã³ãŒ
ã³åã³ãžã¡ãã«ãã«ã ã¢ãããŸãã¯ãããã¯å°é
ã®ææ©æ·»å ç©ãå«æããŠããŠãããæ°ŽãŸãã¯åŒ±ã¢
ã«ã«ãªæ§æº¶æ¶²ãããã ããªãã¬ãžã¹ãçµæç©äžã«çšãã以å€ã«ãåèš
ã®å éåæ§çµæç©ã¯ã玫å€ç·ç¡¬åæ§ã³ãŒãã€ã³ã°
åã³å°å·çµæç©äžã«ã䜿çšã§ããããããã®çµæ
ç©ã¯å€§äœããªãŒã©ãžã«ã«ä»å éåæ§ã¢ãããŒãå
éåéå§å€åã³æ¬çºæã®ããªã³ãã¢ãŠãææçµæ
ç©ããæ¢ã«èšèŒããä»ã®ç¹å®ããæ·»å å€ã«å ãã
å«æããããããã®çµæç©ã¯äžè¬ã«çŽ0.1ãïŒã
ããæ®éã«ã¯çŽ0.2ãïŒééïŒ ã®æ¬çºæã®ããªã³
ãã¢ãŠãææçµæç©ãå«æããã äžè¿°ãããšãã¬ã³åäžé£œåååç©ãæçšã§ãã
ããã¢ã¯ãªãªã«ååç©ãæ®ã«äžè¿°ããããã«ã¢ã¯
ãªãªã«ãªãªãŽããŒåã³ãšã¹ãã«ã®åœ¢ã®ãã®ãç¹ã«
æçšã§ããã æçšãªä»ã®äžçŸ€ã®ãªãªãŽããŒã¯æ¬¡ã®ããã«ããŠ
åŸããããããªãã¡ãææ©ããªãšãŒãã«ããªãªãŒ
ã«ãŸãã¯ããªãšã¹ãã«ããªãªãŒã«ããžã€ãœã·ã¢ã
ãŒããšåå¿ãããããšã«ãããã€ãœã·ã¢ããŒãæ«
端ãã¬ããªããŒãåŸãããã®çæç©ãäžé£œåã¢ã«
ã³ãŒã«ãäŸãã°ããããã·ã«ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ããšåå¿ãããããåç¬ãŸãã¯ä»ã®äžé£œåã¢ãã
ãŒãšçµåããŠãããªãŒã©ãžã«ã«ã®åœ±é¿äžã§éå
ãã硬質匷éç²çæ§ãã€ã«ã ã圢æããç©è³ªãšã
ãã äžèšã®ãã®ã®å€åœ¢ãšããŠãããªã¡ãããŒã«ããª
ã¹ïŒããªã°ãªã³ã¬ãŒãïŒãããªã¡ãããŒã«ããã
ã³ããªã¹ïŒã¡ã«ã«ããããããªããŒãïŒããã³ã¿
ãšãªã¹ãªããŒã«ããã©ãã¹ïŒããªã°ãªã³ã¬ãŒãïŒã
ãã³ã¿ãšãªã¹ãªããŒã«ããã©ãã¹ïŒã¡ã«ã«ããã
ãããªããŒãïŒçã®ãããªéåäœã«ãããšã¹ãã«
ããžã€ãœã·ã¢ããŒããšåå¿ãããããšã«ããããª
ããªãŠã¬ã¿ã³äžéäœãåŸããã®äžéäœãäžé£œåã¢
ã«ã³ãŒã«ãäŸãã°ããããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒ
ããšåå¿ãããåç¬ãŸãã¯ä»ã®äžé£œåã¢ãããŒãš
çµåããŠãæ¶æ©åŸåªããç®èç¹æ§ãæããããªãŒ
ã©ãžã«ã«éåæ§ç©è³ªãšããã æçšãªãªãªãŽããŒã®ä»ã®äŸã¯ããããã·æ«ç«¯ã
ãªã«ããã©ã¯ãã³ããžã€ãœã·ã¢ããŒããšåå¿ã
ãã次ãã§ã€ãœã·ã¢ããŒãæ«ç«¯äžéäœãäŸãã°ã
ãããã·ã¢ã«ãã«ã¢ã¯ãªã¬ãŒãã®ãããªäžé£œåã¢
ã«ã³ãŒã«ãšåå¿ãããããšã«ããåŸãããã¢ã¯ãª
ã¬ãŒãæ«ç«¯ä»å ããªã«ããã©ã¯ãã³ããªãŠã¬ã¿ã³
ã§ããã æŽã«ä»ã®æçšãªäžçŸ€ã®ãªãªãŽããŒã¯ãšããã·æš¹
èãã¢ã¯ãªã«é žãšåå¿ãããŠããšããã·ãžã¢ã¯ãª
ã¬ãŒããšããããšã«ããåŸããããäŸãã°ããšã
ã¯ãã«ãããªã³ïŒãã¹ããšããŒã«ïŒ¡åãšããã·æš¹
èãååŠéè«çéã®ã¢ã¯ãªã«é žãšåå¿ãããããš
ãã§ããããã®ãããªçæç©ã¯åæšâEpocrylâ
ãšããŠShell Chemical Companyããåžè²©ãããŠ
ãããã®ã§ãããå¥ã®ãã®ãšããŠã¯ãUnion
Carbide Companyããã®Ucarâ80ãããããã®
ãããªç©è³ªã¯åçš®ã®ã¢ã¯ãªã«ç³»ãšã¹ãã«ãäŸãã°
ããªãã³ãã«ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããããã
ãã·ãšãã«ã¢ã¯ãªã¬ãŒãåã³ãžã·ã¯ããã³ãã«ã¢
ã¯ãªã¬ãŒããåã³ä»ã®ããªãªãŒã«ã®äžé£œåãšã¹ã
ã«ãäŸãã°ã¡ãã¬ã³ã«ã«ãã³é žãšã¹ãã«ïŒäŸã
ã°ããšãã¬ã³ãžã¢ã¯ãªã¬ãŒãããžãšãã¬ã³ã°ãªã³
ãŒã«ãžã¢ã¯ãªã¬ãŒããã°ãªã»ããŒã«ãžã¢ã¯ãªã¬ãŒ
ããã°ãªã»ããŒã«ããªã¢ã¯ãªã¬ãŒãããšãã¬ã³ãž
ã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâãããã¬ã³ãžã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒïŒïŒâãã¿ã³ããªãªãŒã«ããªã¡ã¿
ã¯ãªã¬ãŒããïŒïŒïŒâãã³ãŒã³ãžãªãŒã«ãžã¡ã¿ã¯
ãªã¬ãŒãããã³ã¿ãšãªã¹ãªããŒã«ããã©ã¡ã¿ã¯ãª
ã¬ãŒããïŒïŒïŒâãããã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒ
ããïŒïŒïŒâãããµã³ãžãªãŒã«ãžã¢ã¯ãªã¬ãŒãã
ååé200ã500ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ã®ãã¹
ã¢ã¯ãªã¬ãŒãåã³ã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒ
ã«ãããã³ããªã¢ã¯ãªã¬ãŒãããã³ã¿ãšãªã¹ãªã
ãŒã«ããªã¢ã¯ãªã¬ãŒãïŒåã³ä»ã®ãšãã¬ã³åäžé£œ
åååç©ãšçµåããŠããªãŒã©ãžã«ã«ã®åœ±é¿äžã§é
åã§ããåªããæ¥çæ§åã³åŒ·éæ§ãæãããã€ã«
ã ãåŸãããã ä»ã®çµæç©ã¯æ«ç«¯äžé£œåãŠã¬ã¿ã³çµæç©ïŒããª
ãšã³ïŒåã³ããªããªãŒã«ã®çµåãã§ãååŠç·å ã®
äœçšã«ããå éåéå§å€äžã«çæããããªãŒã©ãž
ã«ã«ã®åœ±é¿äžã§éåãããããã®ãå«ãã å¡åžåã³å°å·ã€ã³ã¯çµæç©ã¯äž»èŠéã®è圢ææ§
ç©è³ªåã³æå å€åã³æ¯èŒçå°éã®ãã€ã³ææåã³
ããã²ã³ååç©ãå«æãããäŸãã°ãå žåçãªçµ
æç©ã¯15ã70ééïŒ ã®äžè¿°ãããšãã¬ã³åäžé£œå
ååç©ã10ã50ééïŒ ã®ïŒçš®ä»¥äžã®äžé£œåã¢ãã
ãŒãŸãã¯äºãå¥é補é ããéåäœãã€ã³ããŒã
0.1ã15ééïŒ ã®å éåéå§å€ã0.01ãïŒééïŒ
ã®äžè¿°ãããã€ã³ææåã³0.1ãªããïŒééïŒ ã®
ããã²ã³å«æååç©ãå«æããŠãããæŽã«çãç¯
å²ã¯çŽ40ã55ïŒ ã®ãšãã¬ã³åäžé£œåååç©ã30ã
45ïŒ ã®ã¢ãããŒãŸãã¯éåäœãã€ã³ããŒã0.5ã
15ïŒ ã®å šéå§å€ã0.5ãïŒïŒ ã®ææåºå€åã³0.8ã
ïŒïŒ ã®ããã²ã³ååç©ïŒå šãŠééïŒ ïŒãå«æãã
ã§ãããã ããªãã¬ãžã¹ãçµæç©ã¯ããã°ãã°ïŒæã®å¥é¢
å¯èœãªéåäœãã€ã«ã éã«ããªãã¬ãžã¹ãå±€ãæ
ãã ç©å±€ç©ãµã³ãã€ãããšããŠæäŸãããããã€
ã«ã ã®äžæ¹ã¯æŽ»æ§å ç·ã«å¯ŸããŠå®è³ªçã«éæã§ãª
ããã°ãªããªãããã€ã«ã ã¯éåžžçŽ0.00635ã
0.254mmïŒ0.25ã10ãã«ïŒã®åãã§ãããã 以äžãæ¬çºæãäŸç€ºããããå®æœäŸã瀺ããã
ãããã¯æ¬çºæãå¶éãããã®ã§ã¯ãªãã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ã¢ã¯ãªã«ç³»éåäœïŒ56ïŒ ã¢ã¯ãªã«é žãšãã«ã 37ïŒ ã¡ã¿ã¯ãªã«é žã¡ãã«åã³ïŒïŒ ã¢ã¯ãªã«é žãã¡ãã«ãšãã«ã±ãã³äž 30âã«ãããåºæç²åºŠ0.458ïŒ 12.63ïœ ã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãäžéšãšã¹ã
ã«åã é žäŸ¡270åã³ååé1700 12.63ïœ ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã6.67ïœ ãã³ãŸããšãã³ 1.30ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.067ïœ ããªãªã¢ã³ãã°ãªãŒã³ææïŒC.I.42040ïŒ 0.0027ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 0.39ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.63ïœ ã¡ãã«ãšãã«ã±ãã³ 100.00ïœ æº¶æ¶²ã¯çŽ25ïŒ ã®åºåœ¢åãå«æããŠãããããã
äºè»žå»¶äŒžããããŒãã»ããããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã€ã«ã äžã«ãã¯ã¿ãŒãã€ãã§0.023
mmïŒ0.00092ã€ã³ãïŒã®åãã«å¡åžãããå¡èã
颚也ããããšã«ãã也ç¥èå0.033mmïŒ0.00130ã€
ã³ãïŒã®æ¥µèç·è²ã®ãã€ã«ã ãåŸããé ã被çã
ããšããã·âã¬ã©ã¹ç¹ç¶æ¿ïŒæãSomaca
Model SBCâ12æŽæµåšãçšããŠæŽæµã也ç¥ããã
ãã®éŒæ¿ãXidexç©å±€æ©ãçšããŠ115âã§0.9ã1.2
ïœïŒïŒãïŒãã€ãŒãïŒïŒåã®é床ã§ä¹Ÿç¥å éåæ§
çµæç©ãšç©å±€ãããåŸãããããªãšã¹ãã«ãã€ã«
ã ãå éåæ§çµæç©åã³é ãããªãè€åç©ã¯é»è²
å äžã§ããããªãé²åºããé ãšèå¥ããã«ãå å
ãªã³ã³ãã©ã¹ããæãããããã«ç·è²ãæããŠã
ããé ãµã³ãã€ããäœãColight 1200watt
DMVLâ玫å€ç·é²å æºãçšããŠãéæç»ã«10
åéé²å ãããé²å çŽåŸã匷ã玫è²ç»åããèç·
è²èæ¯ãšåªããã³ã³ãã©ã¹ããæããé²å éšåäž
ã«åœ¢æãããããã®æ¿ãDEA Americana2401çŸ
象液äžã§76.2cmïŒ30â³ïŒã®åŽé§å®€ãçšããŠçŸåã
ãããã®å šäœçã«æ°Žæ§ã®çŸå液ã¯0.75ééïŒ ã®ç
é žãããªãŠã âæ°Žåç©ã26.7ã29.4âïŒ80ã85
ãïŒã§å«æããŠããã1.41KgïŒcm2ïŒ20psiïŒã®åŽ
é§å§ååã³1.05ïœïŒ3.5ãã€ãŒãïŒïŒåã®èµ°è¡é
床ãçšããŠãæ¿ãçŸå液äžã«éããæŽæµåã³ä¹Ÿç¥
åŸãæ®åããé²å ç»åã¯é²å ããå®è³ªçã«äžå€å
ã§æ®ã€ãŠãã匷ãè²ãæããŠãããæ¿ãïŒåé20
ïŒ éç¡«é žã¢ã³ã¢ããŠã 溶液ã«æµžæŒ¬ãã倧éã®æ°Žã§
æŽæµãã20ïŒ HCl溶液ã«ïŒåé浞挬ããå床氎æŽ
ãã次ãã§45åéé žæ§ç¡«é žé 济äžã§900cm2ïŒïŒå¹³
æ¹ãã€ãŒãïŒåœã25ã¢ã³ãã¢ã§åšå²æž©åºŠã§ã¡ãã
ãããã¡ããåŸãã¬ãžã¹ãç»åã®èå¥ã§ããè²å€
åã¯äœãèµ·ããªãã€ãã次ãã§ãæ¿ãåã³æŽæµ
ããïŒåé15ïŒ ãã«ãªãç¡Œé žã«æµžæŒ¬ãã次ãã§
PbïŒSnã¡ãã济äžã§900cm2ïŒïŒå¹³æ¹ãã€ãŒãïŒåœ
ã15ã¢ã³ãã¢ãçšããŠåšå²æž©åºŠã§30åéã¡ããã
ããåã®ããã«ãäœãèå¥ã§ããè²å€åã¯èŠ³å¯ã
ããªãã€ãã玫è²ã¬ãžã¹ãç»åã¯3.0ééïŒ KOH
溶液äž40âã§40ç§é浞挬ããããšã«ããã¹ããªã
ãã³ã°ãããæŽæµåŸãæ¿ãFeCl3溶液äžã§ãšãã
ã³ã°ããããã«ããä¿è·ãããŠããªãé ãå šãŠé€
å»ããã䜿çšå¯èœãªé»æ°åè·¯æ¿ãåŸãããã å®æœäŸ ïŒ çšããããªã³ãã¢ãŠãææãçéã®ãã€ã³ãã©
ã«ã€ãã°ãªãŒã³åã³ä»ã®ææãçéã®ãã©ããµãª
ãã³ã¢ã»ããŒãïŒC.I.42500ïŒã§ãã€ã以å€ã¯å®
æœäŸïŒã®çµæç©ãçšãããå¡åžåŸãçµæç©ã¯é²å
åŸåŸãããæç·è²ã®ããªã³ãã¢ãŠãç»åã«å¯ŸããŠ
é»è²å äžã§è¯å¥œãªã³ã³ãã©ã¹ãã瀺ãããããªèµ€
è²ãããŠãããæ¿ãåäžæ¡ä»¶äžã§çŸåããããé²
å ããé ã¯AcâCu guardãšããã³ã°æº¶æ¶²ãå«æ
ããDEAãšããã³ã°æ¶²äžã§PH8.7åã³æž©åºŠ45âã§
ãšããã³ã°ãããæ¿ã1.8ïœïŒïŒãã€ãŒãïŒãšã
ãã³ã°å®€ã«1.8ïœïŒïŒãã€ãŒãïŒïŒåã®é床ã§é
ãããã¬ãžã¹ãã¯ãããã«æã€ãããè²ã¯å®è³ªäž
å€åããªãã€ãã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ããªïŒã¡ã¿ã¯ãªã«é žã¡ãã«ïŒãã¡ãã«ãšãã« ã±ãã³äž30âã®åºæç²åºŠïŒ0.380 9.36ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã2.50ïœ ããã©ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã
2.50ïœ ãã¿ã«é žãžãªã¯ãã« 0.10ïœ ãã³ãŸããšãã³ 0.85ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.030ïœ ïŒâã¡ãã«âïŒïŒïŒâãžâïœâããã«ããšããŒã«
0.002ïœ ããªãªã¢ã³ãã°ãªãŒã³ææïŒC.I.42040ïŒ0.002ïœ ïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã« 0.010ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.255ïœ ãã€ã³ãã©ããµããªã³ 0.175ïœ ã¡ãã«ãšãã«ã±ãã³ 33.0ïœ æº¶æ¶²ã0.023mmïŒ0.00092ã€ã³ãïŒåã®ããªãšã¹
ãã«ãã€ã«ã äžã«0.038mmïŒ1.5ãã«ïŒã®ä¹Ÿç¥èå
ã«å¡åžããã次ãã§ããããå®æœäŸïŒã«ãããã
ãã«æž æµãªé ã被çããç©å±€ç©ã«ç©å±€ããããã€
ã«ã ã15ç§éDMVLâäžã§é²å ããããšã«ã
ãç·è²ã®èæ¯äžã«åŒ·ãèµ€è²ããªã³ãã¢ãŠããåŸ
ããé²å æ¿ã宀枩æ¡ä»¶ã§15åéä¿æãã次ãã§
ïŒïŒïŒïŒïŒâããªã¯ãã«ãšã¿ã³äžã§2.1ïœïŒïŒã
ã€ãŒãïŒïŒåã§20.0âïŒ68ãïŒã§çŸåããã也ç¥
åŸãæ¿ãå®æœäŸïŒã«ãããããã«ã¡ããåæž æµã
ãã次ãã§ãããã51.7âïŒ125ãïŒã§ããçé ž
é ã¡ãã济äžã§45åé900cm2ïŒïŒå¹³æ¹ãã€ãŒãïŒ
åœã25ã¢ã³ãã¢ãçšããŠã¡ãããããã¡ããåŸã
æ¿ãè²æ倱ã«ã€ããŠæ€æ»ãããšãããäœãæ倱ã¯
芳å¯ãããªãã€ããïŒâã¡ã«ã«ãããã³ãŸãã¢ãŸ
ãŒã«ãçšããªãã€ã第äºã®åŠæ¹ã§ã¯ãã¡ããåŸã¬
ãžã¹ãã®æ¥çæ§ãä¹ããã€ã以å€ã¯åæ§ãªçµæã
åŸãããã å®æœäŸ ïŒ äžèšã®å éåæ§çµæç©ã補é ããã ã¢ã¯ãªã«ç³»éåäœãã¡ãã«ãšãã«ã±ãã³ äž30âã®åºæç²åºŠ0.11ãé žäŸ¡55â60 21.00ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã3.30ïœ ããªãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒã3.30ïœ ãã³ãŸããšãã³ 1.75ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
0.092ïœ ïŒâã¡ãã«âïŒïŒïŒâãžâïœâããã«ããšããŒã«
0.0014ïœ ããŒã·ãã¯ãã«â26ïŒC.I.44045ïŒ 0.0040ïœ ããªãªã¢ã³ãã°ãªãŒã³ 0.0008ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 0.300ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 0.50ïœ ã¡ãã«ãšãã«ã±ãã³ 50.00ïœ ã¡ã¿ããŒã« 2.00ïœ æº¶æ¶²ãåãšåæ§ã«åã0.023mmïŒ0.00092ã€ã³
ãïŒã®ããªãšã¹ãã«æ¯æäœã«0.038mmïŒ0.00150ã€
ã³ãïŒã®ä¹Ÿç¥èåã«å¡åžããã也ç¥åŸãïŒæã®è©Š
éšçã¯ã88.9cmïŒ35â³ïŒÃ15.2cmïŒ6â³ïŒã®28.4ïœ
ïŒïŒãªã³ã¹ïŒã®é ã被çããïŒæã®ãšããã·âã¬
ã©ã¹ç¹ç¶æ¿ã«ããããç©å±€ãããïŒæç®ã®è©Šéšç
ã¯ãåã0.025mmïŒ0.0010ã€ã³ãïŒã®ããªãšãã¬
ã³ã«ç©å±€ããããã®ãã€ã«ã çãåŸã§äœ¿çšããã
ãå£ãžããŒãã§åãã€ãããïŒæã®é æ¿ã¯ã35ã
38âã®Blue ïŒçäžã«ïŒæ¥é眮ãããïŒæç®ã®é
æ¿ã¯åšå²æž©åºŠã®åŒåºãã®äžã«å ¥ãã第äžã®é æ¿ã¯
å®æœäŸïŒã«ãããããã«é²å ãçŸåãããæšæºé
段å åããã³æ¿äžã§ïŒâïŒé段ã®åçé床ã®æ玫
è²ã®ããªã³ãã¢ãŠãç»åãåŸããããããã²ã³å
ã·ã¯ããããµã³ã0.32ïœã®åèåççŽ ã«ãã代ã
ã以å€ã¯ãåæ§ã®çµæç©ã補é ãããé²å åã³çŸ
ååŸãåæ§ãªçŽ«è²ç»åãåŸããããã10âïŒé段
ã§ãã€ããçäžã§ïŒæ¥éãŸãã¯å®€æž©ã§ïŒé±éåŸ
ïŒé äžåã³ããªãšãã¬ã³å ç©å±€è©Šæå ±ïŒãèçŽ åã·
ã¯ããããµã³èªå°äœãçšããåçé床ãŸãã¯ããª
ã³ãã¢ãŠãç»åæ¿åºŠã«äœãå€åãªãã€ãã
Perkin Elmer402玫å€ç·åå å 床èšã«ãã枬å®ã
ããã€ã«ã ã®è²ã¯æåããªãã€ããããã²ã³åã·
ã¯ãããã»ã³ã®ä»£ãã«åèåççŽ ãçšããåŠæ¹ã«
ãããŠã¯ãäžèšã®ããšãèµ·ãããããªãã¡ãçå
ã®è©Šæã¯å®å šã«çŽ«è²ã«å€åããé²å ããŠãäœãã
ãªã³ãã¢ãŠãç»åã圢æãããªãã€ããåçé床
ã¯ïŒâïŒé段äœäžãããåŒåºãäžã«ä¿åããé æ¿
äžã®è©Šæã¯ããæãèæ¯äžã«ããããªããªã³ãã¢
ãŠãç»åãäžããããåçé床ã®æ倱ã¯åæ§ã§ã
ã€ããããªãšãã¬ã³ãšç©å±€ããè©Šæã¯èæ¯æ¿åºŠã«
ãããŠ2.5ä¿æ°å¢å ããåçé床ã®æ倱ã¯ïŒâïŒ
é段ã§ãã€ãã2â²ïŒ3â²ïŒ4â²âããªã¯ãã«ã¢ã»ãã
ãšãã³ãâã¯ãã«ã¹ã¯ã·ã³ã€ãããŸãã¯ãšãŒã
ãã«ã ãçšãããšããåæ§ã®çµæãåŸãããã å®æœäŸ ïŒ å¡åžçµæç©ãäžèšã®æåãã補é ããã Actomer â80ïŒUnion Carbide補ãšããã·å
倧è±æ²¹ïŒ 30.00ïœ ããªã¡ãããŒã«ãããã³ããªã¢ã¯ãªã¬ãŒã
20.00ïœ ãã³ã¿ãšãªã¹ãªããŒã«ããªã¢ã¯ãªã¬ãŒã 10.00ïœ é ¢é žããã« 20.00ïœ ãã³ãŸããšãã³ 12.00ïœ ïŒïŒ4â²âãã¹ïŒãžã¡ãã«ã¢ããïŒãã³ãŸããšãã³
1.0ïœ ïŒïŒïŒïŒïŒïŒïŒïŒïŒâãã³ã¿ããã âïŒâã¯ãã«
ã·ã¯ããããµã³ 1.5ïœ ãã€ã³ã¯ãªã¹ã¿ã«ãã€ãªã¬ãã 1.0ïœ æº¶æ¶²ã0.25mmïŒ10ãã«ïŒã®ãã¯ã¿ãŒãã€ãã§ïŒ
æã®åçŽã«å¡åžããã次ãã§ãã®ç²çæ§å¡èãé«
匷床玫å€ç·æºã«60ç§éïŒDMVLâã1200ã¯ã
ãé»çïŒã«é²å ãããæè²ã«çè²ãã匷éãªèåŒ
æ»æ§ãã€ã«ã ãåŸãããããã¯ã¡ã¿ããŒã«ãŸãã¯
ïŒïŒïŒïŒïŒâããªã¯ãã«ãšã¿ã³ã«å¯Ÿãèæ§ã§ãã€
ãã ç£æ¥äžã®å©çšå¯èœæ§ äžèšã®çµæã«ããç«èšŒãããããã«ãæ¬çºæã®
ããªã³ãã¢ãŠãææçµæç©ãçšãããšãå éåæ§
çµæç©ã®è£œé ã«ãããŠãåªããçµæãåŸãããã
ææã¯éåäœã®å 硬åãå¹²æžããªãã®ã§ãå®å®ãª
å¡èãåŸããããæŽã«ãçµæç©ã¯å¡åžçšçµæç©ãš
ããŠãæªç¡¬åãã€ã«ã ãšããŠããé·æéä¿åã§
ããçµæç©ã®æ§è³ªã«æªåœ±é¿ã¯ã¿ãããªããæŽã«ã
ãã®ããªã³ãã¢ãŠãææçµæç©ã¯åŠçäžæ害ãªãŸ
ãã¯å±éºãªç ãçæããããŸãäœãå¬æ¶æ§äœçšã®
城åã¯ãªããæåŸã«ãææã®è²ã¯ä¿æãããåŸç¶
ã®åŠçäžå¿ èŠãªã³ã³ãã©ã¹ããäžããã
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1598079A | 1979-02-26 | 1979-02-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56500054A JPS56500054A (ja) | 1981-01-16 |
| JPS6344216B2 true JPS6344216B2 (ja) | 1988-09-02 |
Family
ID=21774671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55500104A Expired JPS6344216B2 (ja) | 1979-02-26 | 1979-10-15 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4297435A (ja) |
| EP (1) | EP0024391A1 (ja) |
| JP (1) | JPS6344216B2 (ja) |
| DE (1) | DE2953553T1 (ja) |
| GB (1) | GB2059619B (ja) |
| HK (1) | HK66383A (ja) |
| WO (1) | WO1980001846A1 (ja) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3324642A1 (de) * | 1983-07-08 | 1985-01-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur stabilisierung von photopolymerisierbaren mischungen |
| JPS6057340A (ja) * | 1983-09-08 | 1985-04-03 | Fuji Photo Film Co Ltd | çŒåºãæ§çµæç© |
| US4572886A (en) * | 1983-11-03 | 1986-02-25 | Texas Instruments Incorporated | Optical method for integrated circuit bar identification |
| GB8702732D0 (en) * | 1987-02-06 | 1987-03-11 | Hercules Inc | Photopolymerisable composition |
| DE3717038A1 (de) * | 1987-05-21 | 1988-12-08 | Basf Ag | Photopolymerisierbare aufzeichnungsmaterialien sowie photoresistschichten und flachdruckplatten auf basis dieser aufzeichnungsmaterialien |
| DE3717036A1 (de) * | 1987-05-21 | 1988-12-08 | Basf Ag | Photopolymerisierbare aufzeichnungsmaterialien sowie photoresistschichten und flachdruckplatten auf basis dieser aufzeichnungsmaterialien |
| DE3717037A1 (de) * | 1987-05-21 | 1988-12-08 | Basf Ag | Photopolymerisierbare aufzeichnungsmaterialien sowie photoresistschichten und flachdruckplatten auf basis dieser aufzeichnungsmaterialien |
| DE3717034A1 (de) * | 1987-05-21 | 1988-12-08 | Basf Ag | Photopolymerisierbare aufzeichnungsmaterialien sowie photoresistschichten und flachdruckplatten auf basis dieser aufzeichnungsmaterialien, sowie neue chinazolon-4-verbindungen |
| EP0360255B1 (en) * | 1988-09-22 | 1995-02-22 | Toray Industries, Inc. | Photosensitive relief printing plate and photosensitive intaglio printing plate |
| US5698373A (en) * | 1988-09-22 | 1997-12-16 | Toray Industries, Incorporated | Photosensitive relief printing plate and photosensitive intaglio printing plate |
| DE4116045A1 (de) * | 1991-05-16 | 1992-11-19 | Chen Ron Hon | Entwicklungsverfahren mit indikationseffekt |
| CA2076727A1 (en) * | 1991-08-30 | 1993-03-01 | Richard T. Mayes | Alkaline-etch resistant dry film photoresist |
| US5407783A (en) * | 1993-07-22 | 1995-04-18 | E. I. Du Pont De Nemours And Company | Photoimageable compositions containing substituted 1, 2 dihalogenated ethanes for enhanced printout image |
| CA2158915A1 (en) | 1994-09-30 | 1996-03-31 | Dekai Loo | Liquid photoimageable resist |
| US7582390B2 (en) * | 2003-05-23 | 2009-09-01 | Fujifilm Corporation | Two-photon absorbing polymerization method, two-photon absorbing optical recording material and two-photon absorbing optical recording method |
| CN100555078C (zh) * | 2003-06-02 | 2009-10-28 | äžäžœæ ªåŒäŒç€Ÿ | æå æ èç»åç©åçšå ¶å¶å€ççµåå 件åæŸç€ºè£ 眮 |
| EP1510862A3 (en) * | 2003-08-25 | 2006-08-09 | Fuji Photo Film Co., Ltd. | Hologram recording method and hologram recording material |
| CN107108773B (zh) | 2014-11-04 | 2019-05-17 | äžé®æéå ¬åž | å åºåæ§æ èç»åç©åå ¶åºåç©ã以ååºåç©çå¶é æ¹æ³ |
| CN113137836B (zh) * | 2021-04-23 | 2023-04-07 | æ³å·äžé£å®¹æ³°åå·¥è¡ä»œæéå ¬åž | äžç§å¶å€é»æ°¯è¯è çå¹²ç¥æ¹æ³å*** |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3113024A (en) * | 1962-05-15 | 1963-12-03 | Horizons Inc | Photosensitive composition containing leuco dye and method for producing visible images using said composition |
| DE1447747A1 (de) * | 1964-12-10 | 1969-01-09 | Kalle Ag | Negativ arbeitendes Kopiermaterial |
| US3712817A (en) * | 1971-03-01 | 1973-01-23 | Horizons Inc | Dry working photosensitive compositions comprising organic halogen compounds,ethylene compounds and carbinol compounds |
| US3769023A (en) * | 1971-05-07 | 1973-10-30 | Horizons Inc | Light sensitive reproduction and electron beam sensitive material |
| US4065315A (en) * | 1976-04-26 | 1977-12-27 | Dynachem Corporation | Phototropic dye system and photosensitive compositions containing the same |
-
1979
- 1979-10-15 WO PCT/US1979/000888 patent/WO1980001846A1/en unknown
- 1979-10-15 GB GB8033215A patent/GB2059619B/en not_active Expired
- 1979-10-15 DE DE792953553T patent/DE2953553T1/de active Granted
- 1979-10-15 JP JP55500104A patent/JPS6344216B2/ja not_active Expired
-
1980
- 1980-08-18 US US06/179,310 patent/US4297435A/en not_active Expired - Lifetime
- 1980-09-10 EP EP80900038A patent/EP0024391A1/en not_active Withdrawn
-
1983
- 1983-12-15 HK HK663/83A patent/HK66383A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56500054A (ja) | 1981-01-16 |
| US4297435A (en) | 1981-10-27 |
| GB2059619A (en) | 1981-04-23 |
| DE2953553T1 (de) | 1982-03-25 |
| WO1980001846A1 (en) | 1980-09-04 |
| GB2059619B (en) | 1983-04-20 |
| HK66383A (en) | 1983-12-23 |
| DE2953553C2 (ja) | 1989-11-09 |
| EP0024391A1 (en) | 1981-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4065315A (en) | Phototropic dye system and photosensitive compositions containing the same | |
| US4343885A (en) | Phototropic photosensitive compositions containing fluoran colorformer | |
| JPS6344216B2 (ja) | ||
| EP0005380B1 (en) | Phototropic photosensitive compositions containing a fluoran colorformer | |
| JP2834002B2 (ja) | 匷åãããçŒãåºãç»åã®ããã®çœ®æïŒïŒïŒâãžããã²ã³åãšã¿ã³å«æå ç»å圢ææ§çµæç© | |
| US4552830A (en) | Carbonylic halides as activators for phototropic compositions | |
| EP0135059A1 (en) | Photoimaging compositions containing substituted cyclohexadienone compounds | |
| JP3508819B2 (ja) | å éåæ§çµæç© | |
| JPH0136924B2 (ja) | ||
| EP0131824B1 (en) | Photopolymerizable composition | |
| EP0005379B2 (en) | Photosensitive compositions containing carbonylic halides as activators | |
| US3202508A (en) | Image photopolymerization transfer process | |
| JPS6331484B2 (ja) | ||
| US4985341A (en) | Photopolymerizable mixture, and a recording material produced therefrom | |
| GB1576217A (en) | Light-sensitive compositions | |
| GB1588368A (en) | Flame retardant radiation sensitive element | |
| US4230790A (en) | Photopolymerizable compositions useful in dry film photoresist | |
| US4339527A (en) | Process for using photopolymerizable compositions | |
| CA1143988A (en) | Contrast colorant for photopolymerizable compositions including a leuco triarylmethane dye and a bromo substituted cyclohexane | |
| JP2982398B2 (ja) | æ°èŠãªæå æ§æš¹èçµæç© | |
| JP3640869B2 (ja) | å éåæ§çµæç© | |
| JPH0313580B2 (ja) | ||
| JPH0742343B2 (ja) | åªããæ¥çåãæããå éåæ§çµæç©ãç©åããã³æ¹æ³ | |
| KR100428515B1 (ko) | êŽê²œíì±ì¡°ì±ë¬Œ | |
| JP2000227657A (ja) | æå æ§æš¹èç©å±€äœ |