JPS6311055B2 - - Google Patents

Info

Publication number: JPS6311055B2
Authority: JP; Japan
Prior art keywords: crystalline oxide; vanadium; same manner; iron; phase oxidation
Prior art date: 1979-11-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP54143964A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5669207A (en

Inventor

Masayuki Ootake

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Kasei Corp

Original Assignee

Mitsubishi Kasei Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-11-07

Filing date

1979-11-07

Publication date

1988-03-11

1979-11-07 Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp

1979-11-07 Priority to JP14396479A priority Critical patent/JPS5669207A/ja

1981-06-10 Publication of JPS5669207A publication Critical patent/JPS5669207A/ja

1988-03-11 Publication of JPS6311055B2 publication Critical patent/JPS6311055B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 15
239000013078 crystal Substances 0.000 claims description 8
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 26
239000007789 gas Substances 0.000 description 18
238000007254 oxidation reaction Methods 0.000 description 17
239000012071 phase Substances 0.000 description 16
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 14
229910052720 vanadium Inorganic materials 0.000 description 13
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 13
238000002441 X-ray diffraction Methods 0.000 description 12
229910052742 iron Inorganic materials 0.000 description 10
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 10
239000011651 chromium Substances 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
229910052804 chromium Inorganic materials 0.000 description 8
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 8
229910052698 phosphorus Inorganic materials 0.000 description 8
239000011574 phosphorus Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
229910052782 aluminium Chemical group 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000002994 raw material Substances 0.000 description 6
230000003647 oxidation Effects 0.000 description 5
239000000047 product Substances 0.000 description 5
-1 C 4 hydrocarbons Chemical class 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
238000000034 method Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
239000005955 Ferric phosphate Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000002131 composite material Substances 0.000 description 3
229940032958 ferric phosphate Drugs 0.000 description 3
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 3
229910000399 iron(III) phosphate Inorganic materials 0.000 description 3
238000005259 measurement Methods 0.000 description 3
235000011007 phosphoric acid Nutrition 0.000 description 3
239000002243 precursor Substances 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
238000010304 firing Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
239000006104 solid solution Substances 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229910021550 Vanadium Chloride Inorganic materials 0.000 description 1
238000002083 X-ray spectrum Methods 0.000 description 1
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000002253 acid Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
238000001354 calcination Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
ZHXZNKNQUHUIGN-UHFFFAOYSA-N chloro hypochlorite;vanadium Chemical class [V].ClOCl ZHXZNKNQUHUIGN-UHFFFAOYSA-N 0.000 description 1
LJAOOBNHPFKCDR-UHFFFAOYSA-K chromium(3+) trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cr+3] LJAOOBNHPFKCDR-UHFFFAOYSA-K 0.000 description 1
238000001816 cooling Methods 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
LIAWOTKNAVAKCX-UHFFFAOYSA-N hydrazine;dihydrochloride Chemical compound Cl.Cl.NN LIAWOTKNAVAKCX-UHFFFAOYSA-N 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 1
RTOYJIFECJCKIK-UHFFFAOYSA-K iron(3+) phosphate tetrahydrate Chemical compound O.O.O.O.[Fe+3].[O-]P([O-])([O-])=O RTOYJIFECJCKIK-UHFFFAOYSA-K 0.000 description 1
ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
JKJKPRIBNYTIFH-UHFFFAOYSA-N phosphanylidynevanadium Chemical compound [V]#P JKJKPRIBNYTIFH-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229910001392 phosphorus oxide Inorganic materials 0.000 description 1
LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 1
238000003918 potentiometric titration Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
229940048084 pyrophosphate Drugs 0.000 description 1
229940005657 pyrophosphoric acid Drugs 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000010183 spectrum analysis Methods 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
229910001935 vanadium oxide Inorganic materials 0.000 description 1
JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1

Landscapes

Compounds Of Iron (AREA)
Catalysts (AREA)
Furan Compounds (AREA)

JP14396479A 1979-11-07 1979-11-07 Crystalline oxide Granted JPS5669207A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP14396479A JPS5669207A (en)	1979-11-07	1979-11-07	Crystalline oxide

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP14396479A JPS5669207A (en)	1979-11-07	1979-11-07	Crystalline oxide

Publications (2)

Publication Number	Publication Date
JPS5669207A JPS5669207A (en)	1981-06-10
JPS6311055B2 true JPS6311055B2 (fr)	1988-03-11

Family

ID=15351141

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP14396479A Granted JPS5669207A (en)	1979-11-07	1979-11-07	Crystalline oxide

Country Status (1)

Country	Link
JP (1)	JPS5669207A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8658557B2 (en) *	2011-10-25	2014-02-25	Ineos Usa Llc	Catalyst for n-butane oxidation to maleic anhydride

1979
- 1979-11-07 JP JP14396479A patent/JPS5669207A/ja active Granted

Also Published As

Publication number	Publication date
JPS5669207A (en)	1981-06-10

Publication	Publication Date	Title
US20100105926A1 (en)	2010-04-29	Polynary metal oxide phosphate
KR900009016B1 (ko)	1990-12-17	산화 촉매 조성물의 제조방법
US4056487A (en)	1977-11-01	Vanadium phosphorus oxygen oxidation catalysts useful for preparing anhydrides from alkanes
US20100105927A1 (en)	2010-04-29	Polynary vanadyl pyrophosphate
KR100329051B1 (ko)	2002-10-18	인-바나듐옥사이드촉매전구체의제조방법,인-바나듐옥사이드촉매의제조방법,및상기촉매를사용한증기상산화반응에의한무수말레인산의제조방법
US20100069650A1 (en)	2010-03-18	Polynary metal oxide phosphate
JP2893539B2 (ja)	1999-05-24	バナジウム―リン系結晶性酸化物およびそれを含有する触媒の製造法
US4219484A (en)	1980-08-26	Production of maleic anhydride from four-carbon hydrocarbons using catalysts prepared by water reflux techniques
JPH0441454A (ja)	1992-02-12	メタクロレインの製造方法
US20100087663A1 (en)	2010-04-08	Polynary metal vanadium oxide phosphate
US5506187A (en)	1996-04-09	Catalysts for the production of maleic anhydride by the oxidation of butane
US4337173A (en)	1982-06-29	Solid-solution type crystalline oxides and their precursors
JPS622850B2 (fr)	1987-01-22
US4000176A (en)	1976-12-28	Process for simultaneously producing methacrylo-nitrile and butadiene by vapor-phase catalytic oxidation of mixed butenes
US4337174A (en)	1982-06-29	Method for preparing a catalyst and intermediate formed thereby
JP2004008834A (ja)	2004-01-15	メタクリル酸製造用触媒の製造方法
JPS6311055B2 (fr)	1988-03-11
JP2008037693A (ja)	2008-02-21	バナジウム含有酸化物、バナジウムとリンとを有する酸化物、触媒、及び、無水マレイン酸の製造方法
US5792722A (en)	1998-08-11	Catalysts for the production of maleic anhydride by the oxidation of butane
JPS6116508B2 (fr)	1986-04-30
JPS6315016B2 (fr)	1988-04-02
JPH021763B2 (fr)	1990-01-12
JPH024525B2 (fr)	1990-01-29
US4120876A (en)	1978-10-17	Preparation of maleic anhydride from four-carbon hydrocarbons
US4089870A (en)	1978-05-16	Preparation of maleic anhydride from four-carbon hydrocarbons