JPS6254759A - Gel composition containing silicone oil - Google Patents
Gel composition containing silicone oilInfo
- Publication number
- JPS6254759A JPS6254759A JP19465385A JP19465385A JPS6254759A JP S6254759 A JPS6254759 A JP S6254759A JP 19465385 A JP19465385 A JP 19465385A JP 19465385 A JP19465385 A JP 19465385A JP S6254759 A JPS6254759 A JP S6254759A
- Authority
- JP
- Japan
- Prior art keywords
- silicone oil
- polyoxyalkylene
- water
- modified
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は安定性、使用性に優れるシリコンオイルを含む
ゲル組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a gel composition containing silicone oil that is excellent in stability and usability.
［従来の技術］
従来１、シリコンオイルはさまざまな製品に使用されて
いる。特に化粧料においては、シリコンオイルがなめら
かな使用性を持ち撲水性に優れており、また揮散性シリ
コンオイルを配合すると当初のびがよく且つ塗布にとも
なってシリコンオイルが揮散してしまうので塗布後の化
粧くずれが少ないメーキャップ化粧料を製造することが
できることから、のびのよい使用感を求められるフェー
シャル化粧料や水はじきの性能を要求されるハンドクリ
ームや頭髪化粧料あるいはまたメーキャップ化粧料など
に配合が期待されてきた。また、シリコンオイルは皮膚
安全性が高いという化粧料原料としての条件も備えてい
る。[Prior Art] Conventionally 1, silicone oil is used in various products. Particularly in cosmetics, silicone oil is smooth to use and has excellent blistering properties, and when volatile silicone oil is blended, it spreads easily at the beginning, but since the silicone oil evaporates as it is applied, Since it is possible to produce makeup cosmetics that do not cause makeup smearing, it can be incorporated into facial cosmetics that require a long-wearing feel, hand creams and hair cosmetics that require water-repellent performance, and makeup cosmetics. It has been expected. Silicone oil also has the requirements for being a cosmetic raw material, as it is highly safe for the skin.
しかしながら、シリコンオイルは安定な増粘系を得るの
が非常に困難であるという欠点を有しており、強く要望
されているにもかかわらず、このものを多量に配合し且
つ適当な粘度を有する組成物は得られていない。However, silicone oil has the disadvantage that it is very difficult to obtain a stable thickening system, and despite strong demand, silicone oil has to be blended in large amounts and has an appropriate viscosity. No composition was obtained.
これまで、安定性良好なシリコンオイルの増粘系を得る
ためにはシリコンオイルをワックス類とともに固化する
方法や、シリカあるいは親油化処理したシリカで増粘す
るなどの方法がとられてきた。しかしながら、ワックス
類とともに固化する方法はのびが重くべたつくといった
使用性上の欠点や、流動性がないため応用できる範囲が
限られている。また、シリカで増粘する方法は経時での
安定性が悪く、使用前によく振ることが必須であり好ま
しくない。Up to now, in order to obtain a highly stable silicone oil thickening system, methods have been used, such as solidifying silicone oil with waxes, or thickening it with silica or silica treated to make it lipophilic. However, the method of solidifying with waxes has disadvantages in usability such as being difficult to spread and is sticky, and lacks fluidity, which limits its applicability. Further, the method of thickening with silica is not preferred because it has poor stability over time and requires shaking well before use.
本発明者らは、シリコンオイルの増粘法について鋭意研
究を重ね、シリコンオイルに特定のシリコン化合物と有
機変性粘土鉱物と水とを特定量配合することにより、任
意の粘度を有する経時安定性及び使用性が良好なゲル組
成物を得、この組成物について特許出願を行っている（
特願昭５９−１８９９９５号、特願昭５９−２３５４９
２号、特願昭６０−５１９４８号など）。The present inventors have conducted extensive research on methods of thickening silicone oil, and have found that by blending specific silicone compounds, organically modified clay minerals, and water in specific amounts with silicone oil, they can achieve stability over time with arbitrary viscosity. We have obtained a gel composition with good usability and have filed a patent application for this composition (
Patent Application No. 189995/1983, Patent Application No. 23549/1983
No. 2, Japanese Patent Application No. 60-51948, etc.).
［発明が解決しようとする問題点］
しかし、こうして得られたゲル組成物を化粧料などの商
品として製造する場合には、ともに配合する顔料や使用
する化粧用具による微生物汚染から商品を守ることを考
慮せねばならない。すなわち、防腐剤の配合が必須であ
る。[Problems to be Solved by the Invention] However, when the gel composition obtained in this way is manufactured as a product such as a cosmetic, it is necessary to protect the product from microbial contamination from the pigments blended together and the cosmetic tools used. Must be considered. That is, it is essential to include a preservative.
化粧料や食品あるいは医薬品等の分野では、防腐剤とし
てはパラベン類の配合が一般的であるが、しかし、本発
明らが種々実験を繰り返した結果では、上記ゲル組成物
の系に単純にパラベンを配合すると、多くの系で経時安
定性が損なわれてしまうことが判明した。Parabens are commonly added as preservatives in the fields of cosmetics, foods, and pharmaceuticals, but as a result of repeated experiments by the present inventors, parabens are simply added to the gel composition system. It has been found that the stability over time is impaired in many systems when .
［問題点を解決するための手段］
本発明者らは、上記の一欠点にかんがみさらに詳細に検
討を重ねた結果、パラベンを含有する上記組成物のｐＨ
を７以上することによりこの欠点を解消できることを見
いだし、本発明を完成するに至った。[Means for Solving the Problems] In view of the above-mentioned drawback, the present inventors have conducted more detailed studies, and as a result, the pH of the above-mentioned composition containing parabens has been improved.
It has been found that this drawback can be overcome by increasing the number of points to 7 or more, and the present invention has been completed.
すなわち、本発明は、シリコンオイル、一般式（１）、
（ＩＦ）または（ＩＩＩ）で示されるポリオキシアルキ
レン変性オルガノポリシロキサンの一種または二種以上
、有機変性粘土鉱物、パラベンならびにｐＨ７以上の水
を配合することを特徴°とするシリコレオイルを含むゲ
ル組成物を提供するものである。That is, the present invention provides silicone oil, general formula (1),
A gel containing silicone oil characterized by blending one or more polyoxyalkylene-modified organopolysiloxanes represented by (IF) or (III), organically modified clay minerals, parabens, and water with a pH of 7 or more. A composition is provided.
（以下余白）
（一般式（Ｉ）、（Ｉｆ）、（ＩＩＩ）中、Ｒはメチル
基または一部がフェニル基、Ｒ”は水素または炭素数１
〜１２のアルキル基、ｐは１〜５の数、ｑは２〜３の数
、ｘ、ｍ、ｎは平均数でポリオキシアルキレン変性オル
ガノポリシロキサンが分子中にポリオキシアルキレン基
を２〜４０重量％含有し且つ該ポリオキシアルキレン変
性オルガノポリシロキサンの粘度が２５℃において５〜
５０００センチストークスになるような数値を表す、）
以下、本発明の構成について詳述する。(Left below) (In general formulas (I), (If), and (III), R is a methyl group or partially a phenyl group, and R'' is hydrogen or has 1 carbon number.
~12 alkyl groups, p is a number of 1 to 5, q is a number of 2 to 3, x, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane has 2 to 40 polyoxyalkylene groups in the molecule. % by weight, and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 to 5 at 25°C.
The configuration of the present invention will be described in detail below.
゛本発明で用いられるシリコンオイルは従来用いられて
いる周知のものを使用することができる。``As the silicone oil used in the present invention, conventionally known silicone oils can be used.
たとえば、ジメチルポリシロキサン、メチルフェニルポ
リシロキサン、オクタメチルシクロテトラシロキサン、
デカメチルシクロペンタシロキサンなどが挙げられる。For example, dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane,
Examples include decamethylcyclopentasiloxane.
これらの中から一種又は二種以上が任意に選択される。One or more types are arbitrarily selected from these.
配合量は通常本発明の組成物全量中の２０〜９０重量％
である。The blending amount is usually 20 to 90% by weight based on the total amount of the composition of the present invention.
It is.
本発明で用いられるポリオキシアルキレン変性オルガノ
ポリシロキサン（以下、ポリエーテル変性シリコンと略
記する）は前記一般式（１）、（ＩＩ）または（ＩＩＩ
）で表されるものであり、これらのうちの任意の一種又
は二種以上が選ばれて用いられる。The polyoxyalkylene-modified organopolysiloxane (hereinafter abbreviated as polyether-modified silicone) used in the present invention has the general formula (1), (II) or (III).
), and any one or more of these may be selected and used.
本発明の目的に合致した効果、すなわち経時安定性及び
使用性の良好なシリコン増粘効果を満足せしめるために
は、ポリエーテル変性シリコンはポリオキシアルキレン
基をその分子量に対して２〜４０重量％の割合で含有し
且つ２５℃においてそのもの自体の粘度が５〜５０００
センチストークスの範囲に存する必要がある。すなわち
、ポリオキシアルキレン基のポリエーテル変性シリコン
全重量に対する割合が２重量％未満では増粘効果が十分
でなく、４０重量％を越えるとその割合の増加に従って
経時安定性が悪くなっていく傾向にある。またポリエー
テル変性シリコンの粘度が５センチスト一クス未満では
増粘効果が十分でなく、５０００センチストークスを越
えると使用感がべたつき好ましくない、より、好ましく
は３０００センチストークス以下である。In order to satisfy the effect consistent with the purpose of the present invention, that is, the silicone thickening effect with good stability over time and ease of use, the polyether-modified silicone should contain 2 to 40% by weight of polyoxyalkylene groups based on its molecular weight. and has a viscosity of 5 to 5000 at 25°C.
It must be within the centistoke range. That is, if the ratio of polyoxyalkylene groups to the total weight of polyether-modified silicone is less than 2% by weight, the thickening effect will not be sufficient, and if it exceeds 40% by weight, the stability over time will tend to deteriorate as the ratio increases. be. Further, if the viscosity of the polyether-modified silicone is less than 5 centistokes, the thickening effect will not be sufficient, and if it exceeds 5000 centistokes, the feeling of use will be sticky, which is undesirable.More preferably, the viscosity is 3000 centistokes or less.
本発明のゲル組成物に対するポリエーテル変性シリコン
の配合量は全量中の０．１から３０重量％の範囲で選択
されるが、好ましくは０．２〜２５重量％である。０．
１重量％未満では増粘効果が十分でなく経時安定性も悪
い。３０重量％を越えるとべたつきが感じられ、また化
粧もちも悪（なる。The amount of polyether-modified silicone added to the gel composition of the present invention is selected within the range of 0.1 to 30% by weight based on the total amount, preferably 0.2 to 25% by weight. 0.
If it is less than 1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 30% by weight, it will feel sticky and the makeup will not last long.
本発明で用いられる有機変性粘土鉱物は粘土鉱物の結晶
層間に介在する水や交換性カチオンを有機極性化合物や
有機カチオンで置換したものであり、たとえば、ジオク
タデシルジメチルアンモニウム塩変性モンモリロナイト
、オクタデシルジメチルベンジルアンモニウム塩変性モ
ンモリロナイト、ジヘキサデシルジメチルアンモニウム
塩弯性モンモリロナイトなどが挙げられる。これらの中
から一種または二種以上が任意に選択される。The organically modified clay mineral used in the present invention is a clay mineral in which the water and exchangeable cations present between the crystal layers are replaced with organic polar compounds or organic cations, such as dioctadecyldimethylammonium salt-modified montmorillonite, octadecyldimethylbenzyl Examples include ammonium salt-modified montmorillonite and dihexadecyldimethylammonium salt curved montmorillonite. One or more types are arbitrarily selected from these.
配合量は本発明のゲル組成物全量中の０．１〜１５重量
％の範囲で選択されるが、好ましくは０．２〜ｌＯ重量
％である。０．１重量％未満では増粘効果が十分でなく
経時安定性も悪い、 １５重量％を越えるとのびが重く
なり使用性が悪くなる。The blending amount is selected within the range of 0.1 to 15% by weight based on the total amount of the gel composition of the present invention, preferably 0.2 to 10% by weight. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 15% by weight, it will be difficult to spread and the usability will be poor.
本発明における水の配合量はゲル組成物全量中の０．２
〜８０重量％の範囲で選択されるが、好ましくは０．５
〜６０重量％であ′る。０．２重量％未満では増粘効果
が十分でなく経時安定性も悪い。８０重量％を越えると
のびが重くなり好ましくない。 水は前述のとおり、
ｐｉを７以上に調製したものであり、その調製は苛性ソ
ーダ、苛性カリなどの塩基、エデト酸−４ナトリウム塩
、エデト酸−３ナトリウム塩、炭酸ナトリウムなどのア
ルカリ性を示す塩、２−アミノ−２−メチル−１，３−
プロパンジオールと塩酸による緩衝液などで行われる。The amount of water in the present invention is 0.2 in the total amount of the gel composition.
-80% by weight, preferably 0.5% by weight
~60% by weight. If it is less than 0.2% by weight, the thickening effect will not be sufficient and the stability over time will be poor. If it exceeds 80% by weight, it becomes difficult to spread, which is not preferable. As mentioned above, water
It is prepared with a pi of 7 or more, and its preparation is performed using bases such as caustic soda and caustic potash, alkaline salts such as edetate-4sodium salt, edetate-3sodium salt, and sodium carbonate, 2-amino-2- Methyl-1,3-
This is done using a buffer solution such as propanediol and hydrochloric acid.
本発明のシリコン増粘組成物を応用した化粧料は、上記
の必須成分に加えて、必要に応じてワックス、油脂、保
湿剤、顔料、粉末、樹脂、香料などが配合される。Cosmetics to which the silicone thickening composition of the present invention is applied may contain, in addition to the above-mentioned essential ingredients, waxes, oils, humectants, pigments, powders, resins, fragrances, etc., as necessary.
なお、さらにエタノール、イソプロピルアルコール等の
低級アルコールやプロピレングリコール、ジプロピレン
グリコール、１．３−プチレングリコール、グリセリン
等の多価アルコールを組成物全量に対して０．１〜１０
重量％加えるとさらに増粘し安定性を向上させることが
できる。In addition, lower alcohols such as ethanol and isopropyl alcohol, and polyhydric alcohols such as propylene glycol, dipropylene glycol, 1,3-butylene glycol, and glycerin are added in an amount of 0.1 to 10% based on the total amount of the composition.
Adding % by weight can further increase the viscosity and improve stability.
［発明の効果］
本発明のシリコンオイルを含むゲル組成物は耐微生物安
定性に優れ、経時安定性が良好で且つ使用に際してはの
びがよくてべたつきがない良好な使用感触を有し、耐水
性や経時の持ちにも優れたゲル組成物である。[Effects of the Invention] The gel composition containing the silicone oil of the present invention has excellent microbial resistance stability, good stability over time, spreads well when used, has a good feel without stickiness, and is water resistant. It is a gel composition that has excellent durability over time.
また、粘度すなわち流動性を自由にコントロールできる
ため、化粧料をはじめ、医薬品の基剤や自動車ワックス
、家具ワックスなど広い範囲にわたって使用することが
できる。In addition, because the viscosity, or fluidity, can be freely controlled, it can be used in a wide range of applications, including cosmetics, pharmaceutical bases, automobile wax, and furniture wax.
［実施例］
次に実施例によって本発明をさらに詳細に説明する。本
発明はこれにより限定されるものではない、配合量は重
量％である。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereto, and the blending amount is expressed in % by weight.
なお、実施例および比較例の諸特性についての試験法は
次の通り行ったものである。The test methods for various properties of Examples and Comparative Examples were as follows.
（１） 安定性
サンプル管Ｇト試料を取り各温度条件に放置し、分離度
で評価（１週間後判定）。(1) Take a sample from the stability sample tube G and leave it at each temperature condition, and evaluate the degree of separation (judgment after 1 week).
評価基準 ○：分離なし Δ：１１５程度分離 Ｘ ： ２／３以上分離 （２）粘度 ブルックフィールド型粘度計にて測定（３０℃）。Evaluation criteria ○: No separation Δ: Separation of about 115 X: 2/3 or more separation (2) Viscosity Measured with a Brookfield viscometer (30°C).
（以下余白）
（製法）
■〜■をホモディスパーにて攪拌し、耐水性アイライナ
ーを得た。(Left below) (Manufacturing method) ① to ② were stirred in a homodisper to obtain a water-resistant eyeliner.
なお、疎水化処理群青はソルビタントリステアレート３
ｇをヘキサン１００艷に溶解し、この中へ群青１７ｇを
加えてホモディスパーで３０分間攪拌した後、エバポレ
ーターによりヘキサンを除去乾燥して得た。In addition, the hydrophobized ultramarine is sorbitan tristearate 3.
g was dissolved in 100 g of hexane, 17 g of ultramarine blue was added thereto, and the mixture was stirred with a homodisper for 30 minutes, and then the hexane was removed with an evaporator and dried.
また、水のｐＨは７．７であった。Moreover, the pH of the water was 7.7.
表中に示した特性から、実施例１．２．３．４は経時安
定性に優れていることが判る。From the characteristics shown in the table, it can be seen that Examples 1.2.3.4 have excellent stability over time.
（以下余白）
※ 顔料組成
二酸化チタン ４０％
タルク ２５
マイカ ２５
黄酸化鉄 ２．７
赤酸化鉄 ６．５
黒酸化鉄 ０．８
（製法）
■〜＠をホモディスパーにて攪拌し、耐水性ファンデー
シランを得た。(Left below) *Pigment composition Titanium dioxide 40% Talc 25 Mica 25 Yellow iron oxide 2.7 Red iron oxide 6.5 Black iron oxide 0.8 (Manufacturing method) ■~@ are stirred in a homodisper to form a water-resistant foundation. Got a run.
また、水のｐｏは９．０であった。Moreover, the po of water was 9.0.
表中に示した特性から実施例５は経時安定性に優れてい
ることが判る。From the characteristics shown in the table, it can be seen that Example 5 has excellent stability over time.
（以下余白） ［実施例６、比較例５］ （以下余白） （製法） ■〜■をホモディスパーにて攪拌し、クリームを得た。(Margin below) [Example 6, Comparative Example 5] (Margin below) (Manufacturing method) ■~■ were stirred with a homodisper to obtain cream.
なお、水のｐＨは１０．８であった。Note that the pH of water was 10.8.
表中に示した特性から実施例６は経時安定性に優れてい
ることが判る。From the characteristics shown in the table, it can be seen that Example 6 has excellent stability over time.
Claims (1)
（III）で示されるポリオキシアルキレン変性オルガノ
ポリシロキサンの一種または二種以上、有機変性粘土鉱
物、パラベンならびにｐＨ７以上の水を配合することを
特徴とするシリコンオイルを含むゲル組成物。 ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（II） ▲数式、化学式、表等があります▼（III） ｛一般式（ I ）、（II）、（III）中、Ｒはメチル基ま
たは一部がフェニル基、Ｒ′は水素または炭素数１〜１
２のアルキル基、ｐは１〜５の数、ｑは２〜３の数、ｘ
、ｍ、ｎは平均数でポリオキシアルキレン変性オルガノ
ポリシロキサンが分子中にポリオキシアルキレン基を２
〜４０重量％含有し且つ該ポリオキシアルキレン変性オ
ルガノポリシロキサンの粘度が２５℃において５〜５０
００センチストークスになるような数値を表す。｝(1) Silicone oil, one or more polyoxyalkylene-modified organopolysiloxanes represented by general formulas (I), (II), or (III), organically modified clay minerals, parabens, and water with a pH of 7 or more are blended. A gel composition containing silicone oil, characterized by: ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(III) {General formulas (I), (II), In (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 to 1 carbon atoms.
2 alkyl group, p is a number from 1 to 5, q is a number from 2 to 3, x
, m, and n are the average numbers, and the polyoxyalkylene-modified organopolysiloxane has 2 polyoxyalkylene groups in its molecule.
-40% by weight, and the viscosity of the polyoxyalkylene-modified organopolysiloxane is 5 to 50% at 25°C.
Represents a numerical value that equals 00 centistokes. }
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19465385A JPS6254759A (en) | 1985-09-03 | 1985-09-03 | Gel composition containing silicone oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19465385A JPS6254759A (en) | 1985-09-03 | 1985-09-03 | Gel composition containing silicone oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6254759A true JPS6254759A (en) | 1987-03-10 |
| JPH036182B2 JPH036182B2 (en) | 1991-01-29 |
Family
ID=16328084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19465385A Granted JPS6254759A (en) | 1985-09-03 | 1985-09-03 | Gel composition containing silicone oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6254759A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02196862A (en) * | 1989-01-26 | 1990-08-03 | Shin Etsu Chem Co Ltd | Lactone modified silicone composition and cosmetic or polishing material containing the same |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| EP0536280A1 (en) * | 1990-06-25 | 1993-04-14 | S.C. JOHNSON & SON, INC. | Furniture polish concentrate and formulations |
| US5236986A (en) * | 1991-02-27 | 1993-08-17 | Shin-Etsu Chemical Co., Ltd. | Silicone polymers and water-dispersable, pasty silicone oil compositions comprising the same |
| US5929163A (en) * | 1992-05-01 | 1999-07-27 | Dow Corning Toray Silicone Co., Ltd. | Silicone gel composition |
| EP0985403A2 (en) * | 1998-09-08 | 2000-03-15 | Shiseido Company, Ltd. | Gelatinous composition |
| JP2005539104A (en) * | 2002-07-25 | 2005-12-22 | アンコル インターナショナル コーポレイション | Viscous composition containing hydrophobic liquid |
| JP2007254538A (en) * | 2006-03-22 | 2007-10-04 | Dow Corning Toray Co Ltd | Gelling agent, gelly composition and cosmetic |
| EP1935924A1 (en) | 2002-09-12 | 2008-06-25 | Shin-Etsu Chemical Company, Ltd. | Novel organopolysiloxane polymer, pasty composition, and cosmetic preparation containing the same |
| JP2008524115A (en) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | Inflammation-preventing skin external preparation containing modified clay |
| WO2014054693A1 (en) * | 2012-10-02 | 2014-04-10 | 東レ・ダウコーニング株式会社 | Treatment agent and cosmetic material, containing co-modified organopolysiloxane |
| EP2898924A1 (en) | 2014-01-23 | 2015-07-29 | Shin-Etsu Chemical Co., Ltd. | Cosmetic composition containing two crosslinking organopolysiloxane polymers |
| KR20160110125A (en) | 2015-03-13 | 2016-09-21 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Gel paste composition and cosmetic using the gel paste composition |
| WO2023063032A1 (en) | 2021-10-12 | 2023-04-20 | 信越化学工業株式会社 | Organoalkoxysilane-containing composition, method for producing same and water absorption inhibitor |
-
1985
- 1985-09-03 JP JP19465385A patent/JPS6254759A/en active Granted
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02196862A (en) * | 1989-01-26 | 1990-08-03 | Shin Etsu Chem Co Ltd | Lactone modified silicone composition and cosmetic or polishing material containing the same |
| JPH0577707B2 (en) * | 1989-01-26 | 1993-10-27 | Shinetsu Chem Ind Co | |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| JPH0625051B2 (en) * | 1989-06-29 | 1994-04-06 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Beauty composition |
| EP0536280A1 (en) * | 1990-06-25 | 1993-04-14 | S.C. JOHNSON & SON, INC. | Furniture polish concentrate and formulations |
| US5236986A (en) * | 1991-02-27 | 1993-08-17 | Shin-Etsu Chemical Co., Ltd. | Silicone polymers and water-dispersable, pasty silicone oil compositions comprising the same |
| US5929163A (en) * | 1992-05-01 | 1999-07-27 | Dow Corning Toray Silicone Co., Ltd. | Silicone gel composition |
| EP0985403A2 (en) * | 1998-09-08 | 2000-03-15 | Shiseido Company, Ltd. | Gelatinous composition |
| EP0985403A3 (en) * | 1998-09-08 | 2001-09-05 | Shiseido Company, Ltd. | Gelatinous composition |
| JP2005539104A (en) * | 2002-07-25 | 2005-12-22 | アンコル インターナショナル コーポレイション | Viscous composition containing hydrophobic liquid |
| EP1992656A1 (en) | 2002-09-12 | 2008-11-19 | Shin-Etsu Chemical Company, Ltd. | Novel Organopolysiloxanpolymer, Pasty Composition, and Cosmetic Preparation Containing the Composition |
| EP1935924A1 (en) | 2002-09-12 | 2008-06-25 | Shin-Etsu Chemical Company, Ltd. | Novel organopolysiloxane polymer, pasty composition, and cosmetic preparation containing the same |
| JP2008524115A (en) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | Inflammation-preventing skin external preparation containing modified clay |
| JP2007254538A (en) * | 2006-03-22 | 2007-10-04 | Dow Corning Toray Co Ltd | Gelling agent, gelly composition and cosmetic |
| US9744118B2 (en) | 2012-10-02 | 2017-08-29 | Dow Corning Toray Co., Ltd. | Treatment agent and cosmetic composition comprising co-modified organopolysiloxane |
| JP2014070068A (en) * | 2012-10-02 | 2014-04-21 | Dow Corning Toray Co Ltd | Treatment agent and cosmetic comprising co-modified organopolysiloxane |
| CN104755577A (en) * | 2012-10-02 | 2015-07-01 | 道康宁东丽株式会社 | Treatment agent and cosmetic material, containing co-modified organopolysiloxane |
| WO2014054693A1 (en) * | 2012-10-02 | 2014-04-10 | 東レ・ダウコーニング株式会社 | Treatment agent and cosmetic material, containing co-modified organopolysiloxane |
| CN104755577B (en) * | 2012-10-02 | 2018-04-27 | 道康宁东丽株式会社 | The inorganic agent and cosmetic composition of organopolysiloxane comprising common modification |
| EP2898924A1 (en) | 2014-01-23 | 2015-07-29 | Shin-Etsu Chemical Co., Ltd. | Cosmetic composition containing two crosslinking organopolysiloxane polymers |
| KR20150088194A (en) | 2014-01-23 | 2015-07-31 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Cosmetics |
| US9289372B2 (en) | 2014-01-23 | 2016-03-22 | Shin-Etsu Chemical Co., Ltd. | Cosmetic |
| KR20160110125A (en) | 2015-03-13 | 2016-09-21 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Gel paste composition and cosmetic using the gel paste composition |
| EP3072915A1 (en) | 2015-03-13 | 2016-09-28 | Shin-Etsu Chemical Co., Ltd. | Gel paste composition and cosmetic using the gel paste composition |
| US11020327B2 (en) | 2015-03-13 | 2021-06-01 | Shin-Etsu Chemical Co., Ltd. | Gel paste composition and cosmetic using the gel paste composition |
| WO2023063032A1 (en) | 2021-10-12 | 2023-04-20 | 信越化学工業株式会社 | Organoalkoxysilane-containing composition, method for producing same and water absorption inhibitor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH036182B2 (en) | 1991-01-29 |
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