JPS61113646A - Gel composition containing silicone oil - Google Patents
Gel composition containing silicone oilInfo
- Publication number
- JPS61113646A JPS61113646A JP23549284A JP23549284A JPS61113646A JP S61113646 A JPS61113646 A JP S61113646A JP 23549284 A JP23549284 A JP 23549284A JP 23549284 A JP23549284 A JP 23549284A JP S61113646 A JPS61113646 A JP S61113646A
- Authority
- JP
- Japan
- Prior art keywords
- silicone oil
- weight
- comparative example
- water
- gel composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は安定性、使用性に優れるシリコンオイルを含む
ゲル組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a gel composition containing silicone oil that is excellent in stability and usability.
［従来の技術］
従来、シリコンオイルはさまざまな製品に使用されてい
る。特に化粧料においては、シリコンオイルがなめらか
な使用性を持ち戻水性に優れており、また揮散性シリコ
ンオイルを配合すると当初のびがよく且つ塗布にともな
ってシリコンオイルが揮散してしまうので塗布後の化粧
くずれが少ないメーキャップ化粧料を製造することがで
きることから、のびのよい使用感を求められるフエーシ
ャル化粧料や水はじきの性能を要求されるハンドクリー
ムやａ髪化粧料あるいはまたメーキャップ化粧料などに
配合が期待されてきた。また、シリコンオイルは皮膚安
全性が高いという化粧料原料としての条件も備えている
。[Prior Art] Silicone oil has conventionally been used in various products. Particularly in cosmetics, silicone oil is smooth to use and has excellent water rehydration properties, and when volatile silicone oil is blended, it spreads easily at the beginning, but since the silicone oil evaporates as it is applied, Since it is possible to produce makeup cosmetics that do not cause makeup smearing, it can be incorporated into facial cosmetics that require a long-wearing feel, hand creams that require water-repellent performance, hair cosmetics, and makeup cosmetics. has been expected. Silicone oil also has the requirements for being a cosmetic raw material, as it is highly safe for the skin.
［発明が解決しようとする問題点〕
しかしながら、シリコンオイルは安定な増粘系を得るの
が非常に困難であるという欠点を有しており、強く要望
されているにもかかわらず、このものを多量に配合し且
つ適当な粘度を有する組成物は得られていない。[Problems to be solved by the invention] However, silicone oil has the disadvantage that it is very difficult to obtain a stable thickening system, and despite strong demand, this oil has not been used. A composition containing a large amount and having an appropriate viscosity has not been obtained.
これまで、安定性良好なシリコンオイルの増粘系を得る
ためにはシリコンオイルをワックス類とともに固化する
方法や、シリカあるいは親油化処理したシリカで増粘す
るなどの方法がとられてきた。しかしながら、ワックス
類とともに固化する方法はのびが重くべたつくといった
使用性上の欠点や、流動性がないため応用できる範囲が
限られている。また、シリカで増粘する方法は経時での
安定性が悪く、使用前によく振ることが必須であり好ま
しくない。Up to now, in order to obtain a highly stable silicone oil thickening system, methods have been used, such as solidifying silicone oil with waxes, or thickening it with silica or silica treated to make it lipophilic. However, the method of solidifying with waxes has disadvantages in usability such as being difficult to spread and is sticky, and lacks fluidity, which limits its applicability. Further, the method of thickening with silica is not preferred because it has poor stability over time and requires shaking well before use.
［問題点を解決するための手段］
本発明者らは、こうした事情にかんがみ、シリコンオイ
ルの増粘法について鋭意研究を重ねた結果、シリコンオ
イルに特定のシリコン化合物と有機変性粘土鉱物と水と
を特定量配合することにより、任意の粘度を有する経時
安定性及び使用性が良好なゲル組成物が得られることを
見出し、この知見に基づいて本発明を完成するに至った
。[Means for Solving the Problems] In view of these circumstances, the present inventors have conducted extensive research on methods of thickening silicone oil, and have found that silicone oil contains a specific silicon compound, an organically modified clay mineral, and water. It was discovered that a gel composition having a desired viscosity and good stability over time and ease of use can be obtained by blending a specific amount of the following, and based on this knowledge, the present invention was completed.
すなわち、本発明は、シリコンオイル、一般式（１）、
（ＩＩ）または（ＩＩりで示されるポリオキシアルキレ
ン変性オルガノポリシロキサンの一種または二種以上、
有機変性粘土鉱物ならびに水を配合することを特徴とす
るシリコンオイルを含むゲル組成物を提供するものであ
る。That is, the present invention provides silicone oil, general formula (1),
(II) or (II) one or more polyoxyalkylene-modified organopolysiloxanes,
The present invention provides a gel composition containing silicone oil, which is characterized in that it contains an organically modified clay mineral and water.
（一般式（１）、（ＩＩ）、（ＩＩＩ）中、Ｒはメチル
基または一部がフェニル基、Ｒ゛は水素また器よ炭素数
１〜１２のアルキル基、ｐは１〜５の数、ｑ４ま２〜３
の数、ｚ、ｍ、ｎは平均数でポリオキシアルキレン変性
オルガノポリシロキサンが分子中にポリオキシアルキレ
ン基を２〜２０重量％含有し且つ該ポリオキシアルキレ
ン変性オルガノポリシロキサンの粘度が２５℃において
５〜３０００センチストークスになるような数値を表す
、）
以下、本発明の構成について詳述する。(In the general formulas (1), (II), and (III), R is a methyl group or partially a phenyl group, R is hydrogen or an alkyl group having 1 to 12 carbon atoms, and p is a number of 1 to 5. , q4ma2~3
The numbers, z, m, and n are average numbers, and the polyoxyalkylene-modified organopolysiloxane contains 2 to 20% by weight of polyoxyalkylene groups in the molecule, and the viscosity of the polyoxyalkylene-modified organopolysiloxane at 25°C The configuration of the present invention will be described in detail below.
本発明で用いられるシリコンオイルは従来用いられてい
る周知のものを使用することができる。As the silicone oil used in the present invention, conventionally known silicone oils can be used.
たとえば、ジメチルポリシロキサン、メチルフェニルポ
リシロキサン、オクタメチルシクロテトラシロキサン、
デカメチルシクロペンタシロキサンなどが挙げられる。For example, dimethylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane,
Examples include decamethylcyclopentasiloxane.
これらの中から一種又は二種以上が任意に選択される。One or more types are arbitrarily selected from these.
配合量は通常本発明の組成物全量中の２０〜９０重量％
である。The blending amount is usually 20 to 90% by weight based on the total amount of the composition of the present invention.
It is.
本発明で用いられるポリオキシアルキレン変性オルガノ
ポリシロキサン（以下ポリエーテル変性シリコンと略記
する）は前記一般式（１）、（■）。The polyoxyalkylene-modified organopolysiloxane (hereinafter abbreviated as polyether-modified silicone) used in the present invention has the general formula (1) or (■).
または（ＩＩＩ）で表されるものであり、これらのうち
の任意の一種又は二種以上が選ばれて用いられる。or (III), and any one or more of these may be selected and used.
本発明の目的に合致した効果、すなわち経時安定性及び
使用性の良好なシリコン増粘効果を満足せしめるために
は、ポリエーテル変性シリコンはポリオキシアルキレン
基をその分、子量に対して２〜１５重量％の割合で含有
し且つ２５℃においてそのもの自体の粘度が５〜３００
０センチストークスの範囲に存する必要がある。すなわ
ち、ポリオキシアルキレン基のポリエーテル変性シリコ
ン全重量に対する割合が２重量％未満では増粘効果が十
分でなく、２０重量％を越えると経時安定性が悪くなる
。In order to satisfy the effect consistent with the purpose of the present invention, that is, the silicone thickening effect with good stability over time and ease of use, the polyether-modified silicone must have polyoxyalkylene groups of 2 to 2 to Contains 15% by weight and has a viscosity of 5 to 300 at 25°C.
It must be within the range of 0 centistokes. That is, if the ratio of the polyoxyalkylene group to the total weight of the polyether-modified silicone is less than 2% by weight, the thickening effect will not be sufficient, and if it exceeds 20% by weight, the stability over time will deteriorate.
またポリエーテル変性シリコンの粘度が５センチスト一
クス未満では増粘効果が十分でなく、３０００センチス
トークスを越えると使用感がべたつき好ましくない。Further, if the viscosity of the polyether-modified silicone is less than 5 centistokes, the thickening effect will not be sufficient, and if it exceeds 3000 centistokes, the feeling of use will be sticky, which is undesirable.
本範囲のゲル組成物に対するポリエーテル変性シリコン
の配合量は全量中の０．１から３０重量％の範囲で選択
されるが、好ましくは０．２〜２５重量％。The amount of polyether-modified silicone added to the gel composition of this range is selected within the range of 0.1 to 30% by weight, preferably 0.2 to 25% by weight based on the total amount.
である、０．１重量％未満では増粘効果が十分でなく経
時安定性も患い、３０重量％を越えるとべたつきが感じ
られ、また化粧もちも悪くなる。If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will suffer, and if it exceeds 30% by weight, it will feel sticky and the makeup will not last long.
本発明で用いられる有機変性粘土鉱物は粘土鉱物の結晶
層間に介在する水や交換性カチオンを有機極性化合物や
有機カチオンで置換したものであり、たとえば、ジオク
タデシルジメチルアンモニウム塩変性モンモリロナイト
、オクタデシルジメチルベンジルアンモニウム塩変性モ
ンモリロナイト、ジオクタデシルジメチルアンモニウム
塩変性モンモリロナイトなどが挙げられる。これらの中
から一種または二種以上が任意に選択される。The organically modified clay mineral used in the present invention is a clay mineral in which the water and exchangeable cations present between the crystal layers are replaced with organic polar compounds or organic cations, such as dioctadecyldimethylammonium salt-modified montmorillonite, octadecyldimethylbenzyl Examples include ammonium salt-modified montmorillonite and dioctadecyldimethylammonium salt-modified montmorillonite. One or more types are arbitrarily selected from these.
配合量は本発明のゲル組成物全量中の０．１〜１５重量
％の範囲で選択されるが、好ましくは０．２〜１０重量
％である。０．１重量％未満では増粘効果が十分でなく
経時安定性も悪い、１５Ｍ量％を越えるとのびが重くな
り使用性が悪くなる。The blending amount is selected within the range of 0.1 to 15% by weight based on the total amount of the gel composition of the present invention, preferably 0.2 to 10% by weight. If it is less than 0.1% by weight, the thickening effect will not be sufficient and the stability over time will be poor, and if it exceeds 15% by weight, it will be difficult to spread and the usability will be poor.
本発明における水の配合量はゲル組成物全量中の０．２
〜８０重量％の範囲で選択されるが、好ましくは０．５
〜６０重量％である。０．２ｆｆｉ量％未満では増粘効
果が十分でなく経時安定性も悪い、８０重量％を越える
とのびが重くなり好ましくない。The amount of water in the present invention is 0.2 in the total amount of the gel composition.
-80% by weight, preferably 0.5% by weight
~60% by weight. If it is less than 0.2% by weight, the thickening effect will not be sufficient and the stability over time will be poor, and if it exceeds 80% by weight, it will become difficult to spread, which is undesirable.
本発明のシリコン増粘組成物を応用した化粧料は、上記
の必須成分に加えて、必要に応じてワックス、油脂、保
湿剤、顔料、粉末、樹脂、香料、防腐剤等が配合される
。Cosmetics to which the silicone thickening composition of the present invention is applied contain, in addition to the above-mentioned essential ingredients, waxes, oils, humectants, pigments, powders, resins, perfumes, preservatives, etc., as necessary.
なお、さらにエタノール、イソプロピルアルコール等の
低級アルコールやプロピレングリコール、ジプロピレン
グリコール、１．３−フチレンゲリコール等のグリコー
ル類を組成物全量に対して０．１〜１０重量％加えると
さらに増粘し安定性を向上させることができる。Furthermore, if 0.1 to 10% by weight of lower alcohols such as ethanol and isopropyl alcohol, and glycols such as propylene glycol, dipropylene glycol, and 1,3-phthylene gelicol are added to the total amount of the composition, the viscosity will be further increased. Stability can be improved.
［発明の効果］
本発明のシリコンオイルを含むゲル組成物は経時安定性
が良好で且つ使用に際してはのびがよくてべたつきがな
い良好な使用感触を有し、耐水性や経時の持ちにも優れ
たゲル組成物である。[Effects of the Invention] The gel composition containing the silicone oil of the present invention has good stability over time, and when used, it spreads well and has a good feel without stickiness, and has excellent water resistance and durability over time. It is a gel composition.
また、粘度すなわち流動性を自由にコントロールできる
ため、化粧料をはじめ、医薬品の基剤や自動車ワックス
、家具ワックスなど広い範囲にわたって使用することが
できる。In addition, because the viscosity, or fluidity, can be freely controlled, it can be used in a wide range of applications, including cosmetics, pharmaceutical bases, automobile wax, and furniture wax.
〔実施例］
次に実施例によって本発明をさらに詳細に説明する０本
発明はこれにより限定されるものではない、配合量は重
量％である。[Examples] Next, the present invention will be explained in more detail with reference to Examples.The present invention is not limited thereto, and the blending amounts are expressed in weight %.
なお、実施例および比較例の緒特性についての試験法は
次の通り行ったものである。The test methods for the mechanical properties of Examples and Comparative Examples were as follows.
＋１１ 安定性
サンプル管に試料を取り各温度条件に放置し、分離度で
評価（１力月後判定）。+11 Stability A sample was taken in a sample tube and left at each temperature condition, and evaluated by degree of separation (determined after 1 month).
評価基準 Ｏ：分離なし Δ：１１５程度分離 Ｘ ： ２／３以上分離 （２）粘度 ブルックフィールド型粘度針にて測定（３０℃）。Evaluation criteria O: No separation Δ: Separation of about 115 X: 2/3 or more separation (2) Viscosity Measured with a Brookfield type viscosity needle (30°C).
（３）べたつきおよびのび 実使用試験による官能評価（パネル２０名）。(3) Stickiness and spreadability Sensory evaluation by practical use test (20 panelists).
° 評価基準 Ｏ：べたつきなし、のびが軽い。° Evaluation criteria O: No stickiness, easy spread.
Δ：ややべたつく、のびが普通。Δ: Slightly sticky, spreads normally.
×：べたつく、のびか重い。×: Sticky, spreadable and heavy.
（以下余白）
（！Ｉ！法）
Φ〜■をホモディスパーにて攪拌し、日やけ用乳液を得
た。(Left below) (!I! Method) Φ to ■ were stirred in a homodisper to obtain a sunscreen emulsion.
表中に示した特性から、実施例１．２．３は経時安定性
及び使用性に優れていることが判る。From the characteristics shown in the table, it can be seen that Examples 1.2.3 are excellent in stability over time and usability.
（以下余白） （製法） ■〜■をホモディスパーにて攪拌し、クリームを得た。(Margin below) (Manufacturing method) ■~■ were stirred with a homodisper to obtain cream.
表中に示した特性から実施例４．５．６．７．８．９は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Example 4.5.6.7.8.9 is excellent in stability over time and usability.
（以下余白）
（製法）
Φ〜［相］をホモディスパーにて攪拌し、耐水性ファン
デーションを得た。(Left below) (Manufacturing method) Φ~[phase] was stirred in a homodisper to obtain a water-resistant foundation.
表中に示した特性から実施例１０．１１．１２は経時安
定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Examples 10, 11, and 12 are excellent in stability over time and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性ファンデージ５ンとして十分な機能を有してお
り、化粧もちも良いことがｉ認された。In addition, in actual use tests at the beach (20 panelists), it was found that it has sufficient functionality as a water-resistant foundation and has good makeup retention.
（以下余白）
（製法）
■〜■をホモディスパーで攪拌し、耐水性アイライナー
を得た。(Left below) (Manufacturing method) ① to ② were stirred with a homodisper to obtain a water-resistant eyeliner.
表中に示した特性から実施例１３．１４．１５．１６は
経時安定性および使用性に優れていることが判る。From the properties shown in the table, it can be seen that Examples 13, 14, 15, and 16 are excellent in stability over time and usability.
また、海浜における実使用テスト（パネル２０名）によ
り耐水性アイライナーとして十分な機能を有しており、
塗布後の乾燥が早（化粧もちも良いことが確認された。In addition, it has sufficient functionality as a water-resistant eyeliner according to actual use tests at the beach (20 panelists).
It dries quickly after application (it was confirmed that makeup lasts well too).
（以下余白）
（製法）
■〜■をホモディスパーで攪拌し、つや出しクリームを
得た。(Left below) (Manufacturing method) A glossy cream was obtained by stirring ■ to ■ with a homodisper.
実施例１７．１８は化粧品だけでなく、家具のつや出し
クリームなどにも使用できることを実使用テストにて確
認した。It was confirmed through actual use tests that Examples 17 and 18 can be used not only for cosmetics but also for furniture polishing creams.
特許出願人 株式会社 資 生 堂
手続補正書（自発）
昭和６０年４月’ＺＢ
１、事件の表示
昭和５９年特許願第２３５４９２号
２、発明の名称
シリコンオイルを含むゲル組成物
３、補正をする者
°事件との関係 特許出願人
４、補正の対象
明細書の発明の詳細な説明の欄
５、？！正の内容
（１）明細書第８頁第１０行目「１５重量％」とあるを
、「２０重量％」と補正します。Patent applicant: Shiseido Co., Ltd. Procedural amendment (voluntary) April 1985'ZB 1, Indication of the case 1988 Patent Application No. 235492 2, Name of the invention Gel composition containing silicone oil 3, Amendment Relationship to the case: Patent applicant 4, Detailed description of the invention in the specification subject to amendment, column 5? ! Correct contents (1) The statement "15% by weight" on page 8, line 10 of the specification will be corrected to "20% by weight."
（２）明細書第１頁第１５ ｒ ２０重量％を越えると
経時安定性が悪くなる。」とあるを、ｒ２０！１１％を
越えるとその割合の増加にともなって経時安定性が悪く
なっていく傾向にある。」と補正します。(2) Specification, page 1, 15 r If it exceeds 20% by weight, stability over time will deteriorate. ”, if it exceeds r20!11%, the stability over time tends to deteriorate as the ratio increases. ” and correct it.
（３）明細書第１３頁を別紙１のように補正します。(3) Amend page 13 of the specification as shown in Attachment 1.
（４）明細書第１５頁第１行目［比較例３．４．５．６
」とあるを、「比較例４．５．６．７」と補正します。(4) Specification page 15, line 1 [Comparative example 3.4.5.6
" has been corrected to "Comparative Example 4.5.6.7."
（５）明細書第１５頁の表中「比較例３」とあるを、「
比較例４」と補正します。(5) In the table on page 15 of the specification, replace "Comparative Example 3" with "
Comparative Example 4"
（６）明細書第１５頁の表中「比較例４」とあるを、「
比較例５」と補正します。(6) In the table on page 15 of the specification, replace "Comparative Example 4" with "
Comparative Example 5"
（７）明細書第１５頁の表中「比較例５」とあるを、「
比較例６」と補正します。(7) In the table on page 15 of the specification, replace "Comparative Example 5" with "
Comparative Example 6"
（８）明細書第１５頁の表中「比較例６」とあるを、「
比較例７」と補正します。(8) In the table on page 15 of the specification, replace "Comparative Example 6" with "
Comparative Example 7"
（９）明細書第１７頁第１行目「比較例７．８」とある
を、「比較例８．９」と補正します。(9) In the first line of page 17 of the specification, "Comparative Example 7.8" will be corrected to "Comparative Example 8.9."
（１０）明細書第１７頁の表中「比較例７」とあるを、
「比較例８」と補正します。(10) "Comparative Example 7" in the table on page 17 of the specification,
Correct it as "Comparative Example 8".
（１１）明細書第１７頁の表中「比較例８」とあるを、
「比較例９」と補正します。(11) "Comparative Example 8" in the table on page 17 of the specification,
Correct it as "Comparative Example 9".
（１２）明細書第１７頁の表における、比較例８０列、
粘度ｃｐｓの段ｒ ３．６００Ｊとあるを、ｒ ３６０
．０００ｊと補正します。(12) Comparative example column 80 in the table on page 17 of the specification,
The viscosity cps stage r 3.600J is r 360
．． Correct it to 000j.
（１３）明細書第１９頁第１行目「比較例９」とあるを
、「比較例１０」と補正します。(13) In the first line of page 19 of the specification, "Comparative Example 9" should be corrected to "Comparative Example 10."
（１４）明細書第１９頁の表中「比較例９」とあるを、
「比較例１０Ｊと補正します。(14) "Comparative Example 9" in the table on page 19 of the specification,
“Corrected to Comparative Example 10J.
（１５）明細書第２１頁を別紙２のように補正します。(15) Amend page 21 of the specification as shown in Attachment 2.
ＮｋＪ＝NkJ=
Claims (1)
（III）で示されるポリオキシアルキレン変性オルガノ
ポリシロキサンの一種または二種以上、有機変性粘土鉱
物ならびに水を配合することを特徴とするシリコンオイ
ルを含むゲル組成物。 ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（II） ▲数式、化学式、表等があります▼（III） ｛一般式（ I ）、（II）、（III）中、Ｒはメチル基ま
たは一部がフェニル基、Ｒ′は水素または炭素数１〜１
２のアルキル基、ｐは１〜５の数、ｑは２〜３の数、ｘ
、 ｍ、 ｎは平均数でポリオキシアルキレン変性オル
ガノポリシロキサンが分子中にポリオキシアルキレン基
を２〜２０重量％含有し且つ該ポリオキシアルキレン変
性オルガノポリシロキサンの粘度が２５℃において５〜
３０００センチストークスになるような数値を表す。｝(1) It is characterized by containing silicone oil, one or more polyoxyalkylene-modified organopolysiloxanes represented by general formula (I), (II), or (III), organically modified clay mineral, and water. Gel composition containing silicone oil. ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(III) {General formulas (I), (II), In (III), R is a methyl group or partially a phenyl group, and R' is hydrogen or has 1 to 1 carbon atoms.
2 alkyl group, p is a number from 1 to 5, q is a number from 2 to 3, x
.
Represents a value that equals 3000 centistokes. }
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23549284A JPS61113646A (en) | 1984-11-08 | 1984-11-08 | Gel composition containing silicone oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23549284A JPS61113646A (en) | 1984-11-08 | 1984-11-08 | Gel composition containing silicone oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61113646A true JPS61113646A (en) | 1986-05-31 |
Family
ID=16986846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23549284A Pending JPS61113646A (en) | 1984-11-08 | 1984-11-08 | Gel composition containing silicone oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61113646A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
| JPS6245656A (en) * | 1985-08-22 | 1987-02-27 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPS63250311A (en) * | 1987-04-06 | 1988-10-18 | Kao Corp | Water-in-oil type cosmetic |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| JPH03115207A (en) * | 1989-09-28 | 1991-05-16 | Kobayashi Kose Co Ltd | Oily composition and cosmetic containing same |
| EP0583130A2 (en) * | 1992-08-10 | 1994-02-16 | Dow Corning Corporation | Water dispersible silicone composition |
| US5362482A (en) * | 1987-06-23 | 1994-11-08 | Shiseido Company Ltd. | Water-in-oil emulsion solid cosmetic composition |
| US6174968B1 (en) | 1999-08-24 | 2001-01-16 | Shell Oil Company | Oil gel formulations containing polysiloxane block copolymers dissolved in hydrogenated silicone oils |
| CN1063202C (en) * | 1997-04-16 | 2001-03-14 | 中国科学院化学研究所 | Sandwiched Silicon rubber/montmorillonoid composite material and its preparing method |
| US6780402B1 (en) | 1995-07-28 | 2004-08-24 | L'oreal | Make-up compositions containing phenylated silicone oils, which are resistant to transfer and migration |
| JP2008524115A (en) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | Inflammation-preventing skin external preparation containing modified clay |
| WO2009048125A1 (en) | 2007-10-12 | 2009-04-16 | Genzo Mizutani | Thickener/gellant for oily substance |
| JP2009256235A (en) * | 2008-04-16 | 2009-11-05 | Kao Corp | Gel-form cosmetic |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6166752A (en) * | 1984-09-11 | 1986-04-05 | Shiseido Co Ltd | Gel composition containing silicone oil |
-
1984
- 1984-11-08 JP JP23549284A patent/JPS61113646A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6166752A (en) * | 1984-09-11 | 1986-04-05 | Shiseido Co Ltd | Gel composition containing silicone oil |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0349307B2 (en) * | 1985-05-28 | 1991-07-29 | Shiseido Co Ltd | |
| JPS61271030A (en) * | 1985-05-28 | 1986-12-01 | Shiseido Co Ltd | Oily gel composition |
| JPS6245656A (en) * | 1985-08-22 | 1987-02-27 | Shiseido Co Ltd | Gel composition containing silicone oil |
| JPH0554868B2 (en) * | 1985-08-22 | 1993-08-13 | Shiseido Co Ltd | |
| JPS63250311A (en) * | 1987-04-06 | 1988-10-18 | Kao Corp | Water-in-oil type cosmetic |
| JPH0532363B2 (en) * | 1987-04-06 | 1993-05-14 | Kao Corp | |
| US5362482A (en) * | 1987-06-23 | 1994-11-08 | Shiseido Company Ltd. | Water-in-oil emulsion solid cosmetic composition |
| JPH0344309A (en) * | 1989-06-29 | 1991-02-26 | Unilever Nv | Composition for beauty |
| JPH0625051B2 (en) * | 1989-06-29 | 1994-04-06 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Beauty composition |
| JPH03115207A (en) * | 1989-09-28 | 1991-05-16 | Kobayashi Kose Co Ltd | Oily composition and cosmetic containing same |
| EP0583130A2 (en) * | 1992-08-10 | 1994-02-16 | Dow Corning Corporation | Water dispersible silicone composition |
| EP0583130A3 (en) * | 1992-08-10 | 1994-06-01 | Dow Corning | Water dispersible silicone composition |
| US6780402B1 (en) | 1995-07-28 | 2004-08-24 | L'oreal | Make-up compositions containing phenylated silicone oils, which are resistant to transfer and migration |
| CN1063202C (en) * | 1997-04-16 | 2001-03-14 | 中国科学院化学研究所 | Sandwiched Silicon rubber/montmorillonoid composite material and its preparing method |
| US6174968B1 (en) | 1999-08-24 | 2001-01-16 | Shell Oil Company | Oil gel formulations containing polysiloxane block copolymers dissolved in hydrogenated silicone oils |
| JP2008524115A (en) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | Inflammation-preventing skin external preparation containing modified clay |
| WO2009048125A1 (en) | 2007-10-12 | 2009-04-16 | Genzo Mizutani | Thickener/gellant for oily substance |
| JP2009256235A (en) * | 2008-04-16 | 2009-11-05 | Kao Corp | Gel-form cosmetic |
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