JPH08512339A - アルク−1−エンの単独重合体および共重合体の製造法 - Google Patents
アルク−1−エンの単独重合体および共重合体の製造法Info
- Publication number
- JPH08512339A JPH08512339A JP7503790A JP50379095A JPH08512339A JP H08512339 A JPH08512339 A JP H08512339A JP 7503790 A JP7503790 A JP 7503790A JP 50379095 A JP50379095 A JP 50379095A JP H08512339 A JPH08512339 A JP H08512339A
- Authority
- JP
- Japan
- Prior art keywords
- ene
- metal
- alk
- polymerization
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63925—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Polymerization Catalysts (AREA)
- Saccharide Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.無機酸化物担体上に吸着された化合物のビス(シクロペンタジエニル)−ク ロム−II 〔式中、シクロペンタジエニル環は不活性の有機基を有していてよい〕を用い てアルク−1−エンを重合させることにより、ポリアルク−1−エンを製造する 方法において、第I〜III主族の金属の金属有機化合物または該金属の水素化 物の存在で重合を行なうことを特徴とする、アルク−1−エンの製造法。 2.金属有機化合物として炭化水素−リチウム化合物を使用する、請求項1記載 の方法。 3.炭化水素−リチウム化合物としてn−ブチルリチウムを使用する、請求項2 記載の方法。 4.エチレンまたはエチレンと1個またはそれ以上のC3〜C10−アルク−1− 塩との混合物が重合に使用される、請求項1から3までのいずれか1項に記載の 方法。 5.重合を沈殿重合の方法により行なう、請求項1から4までのいずれか1項に 記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4323192.6 | 1993-07-10 | ||
DE4323192A DE4323192A1 (de) | 1993-07-10 | 1993-07-10 | Verfahren zur Herstellung von Homo- und Copolymerisaten von Alk-1-enen |
PCT/EP1994/002048 WO1995001999A1 (de) | 1993-07-10 | 1994-06-23 | Verfahren zur herstellung von homo- und copolymerisaten von alk-1-enen |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08512339A true JPH08512339A (ja) | 1996-12-24 |
JP3776929B2 JP3776929B2 (ja) | 2006-05-24 |
Family
ID=6492537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50379095A Expired - Fee Related JP3776929B2 (ja) | 1993-07-10 | 1994-06-23 | アルク−1−エンの単独重合体および共重合体の製造法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6197901B1 (ja) |
EP (1) | EP0708787B1 (ja) |
JP (1) | JP3776929B2 (ja) |
KR (1) | KR960703947A (ja) |
CN (1) | CN1078893C (ja) |
DE (2) | DE4323192A1 (ja) |
ES (1) | ES2126765T3 (ja) |
FI (1) | FI960098A0 (ja) |
NO (1) | NO310364B1 (ja) |
WO (1) | WO1995001999A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6518375B1 (en) | 1999-04-01 | 2003-02-11 | Japan Polyolefins Co., Ltd. | Catalyst for the production of ethylene polymer and process for producing ethylene polymer |
US7446073B2 (en) * | 1998-12-30 | 2008-11-04 | Exxonmobil Chemical Patents Inc. | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO960350A (no) † | 1996-01-26 | 1997-04-28 | Borealis As | Fremgangsmåte og katalysatorsystem for polymerisering av etylen, eventuelt sammen med <alfa>-olefiner, og fremstilt polymermateriale |
DE19645939A1 (de) * | 1996-11-07 | 1998-05-14 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von ultrahochmolekularem Polyethylen und Methode zur Aktivierung des Katalysatorträgers |
US6174953B1 (en) * | 1998-02-19 | 2001-01-16 | E. I. Du Pont De Nemours And Company | Low molecular weight (meth) acrylate copolymer emulsions |
DE19833858C2 (de) * | 1998-07-28 | 2000-06-08 | Elenac Gmbh | Geruchsarme Polyethylen-Blends |
US6337297B1 (en) * | 1998-10-12 | 2002-01-08 | Tosoh Corporation | Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst |
GB0021301D0 (en) * | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
DE10314369B4 (de) * | 2003-03-28 | 2005-08-25 | Otto-Von-Guericke-Universität Magdeburg | Polymerisationskatalysatoren auf Porenbetonbasis, Verfahren zu ihrer Herstellung und ihre Verwendung |
RU2545456C2 (ru) | 2010-03-12 | 2015-03-27 | Омерос Корпорейшн | Pde10 ингибиторы и содержащие их композиции и способы |
NZ630803A (en) | 2014-04-28 | 2016-03-31 | Omeros Corp | Optically active pde10 inhibitor |
NZ630810A (en) | 2014-04-28 | 2016-03-31 | Omeros Corp | Processes and intermediates for the preparation of a pde10 inhibitor |
JP2018513153A (ja) | 2015-04-24 | 2018-05-24 | オメロス コーポレーション | Pde10インヒビターならびに関連する組成物および方法 |
US9920045B2 (en) | 2015-11-04 | 2018-03-20 | Omeros Corporation | Solid state forms of a PDE10 inhibitor |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3013002A (en) * | 1960-04-05 | 1961-12-12 | Hercules Powder Co Ltd | Polymerization of ethylene with dicyclopentadienyl chromium-metal alkylcatalysts |
CA995396A (en) * | 1971-03-18 | 1976-08-17 | Robert N. Johnson | Catalyst modified with strong reducing agent and silane compounds and use in polymerization of olefins |
US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
US3806500A (en) * | 1972-07-21 | 1974-04-23 | Union Carbide Corp | Polymerization with thermally aged catalyst |
US4015059A (en) * | 1975-12-29 | 1977-03-29 | Union Carbide Corporation | Fused ring catalyst and ethylene polymerization process therewith |
US4424139A (en) * | 1982-03-30 | 1984-01-03 | Phillips Petroleum Company | Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
US4803253A (en) * | 1982-03-30 | 1989-02-07 | Phillips Petroleum Company | Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
DE3634534A1 (de) | 1986-10-10 | 1988-04-14 | Basf Ag | Verfahren zum herstellen von homo- sowie copolymerisaten des ethens mittels eines chromtrioxid-katalysators |
DE3635363A1 (de) | 1986-10-17 | 1988-04-21 | Basf Ag | Verfahren zur neutralisation von reaktionsgemischen, die durch beckmann'sche umlagerung von cyclohexanonoxim erhalten worden sind |
GB8919925D0 (en) * | 1989-09-04 | 1989-10-18 | Bp Chem Int Ltd | Chromium-containing complex polymerisation catalyst |
-
1993
- 1993-07-10 DE DE4323192A patent/DE4323192A1/de not_active Withdrawn
-
1994
- 1994-06-23 CN CN94192743A patent/CN1078893C/zh not_active Expired - Fee Related
- 1994-06-23 ES ES94921621T patent/ES2126765T3/es not_active Expired - Lifetime
- 1994-06-23 KR KR1019960700197A patent/KR960703947A/ko not_active Application Discontinuation
- 1994-06-23 JP JP50379095A patent/JP3776929B2/ja not_active Expired - Fee Related
- 1994-06-23 DE DE59407708T patent/DE59407708D1/de not_active Expired - Fee Related
- 1994-06-23 WO PCT/EP1994/002048 patent/WO1995001999A1/de active IP Right Grant
- 1994-06-23 EP EP94921621A patent/EP0708787B1/de not_active Expired - Lifetime
-
1996
- 1996-01-09 FI FI960098A patent/FI960098A0/fi unknown
- 1996-01-09 NO NO19960089A patent/NO310364B1/no unknown
-
1997
- 1997-09-23 US US08/935,664 patent/US6197901B1/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7446073B2 (en) * | 1998-12-30 | 2008-11-04 | Exxonmobil Chemical Patents Inc. | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
US6518375B1 (en) | 1999-04-01 | 2003-02-11 | Japan Polyolefins Co., Ltd. | Catalyst for the production of ethylene polymer and process for producing ethylene polymer |
Also Published As
Publication number | Publication date |
---|---|
NO310364B1 (no) | 2001-06-25 |
EP0708787B1 (de) | 1999-01-20 |
NO960089L (no) | 1996-01-09 |
FI960098A (fi) | 1996-01-09 |
EP0708787A1 (de) | 1996-05-01 |
CN1078893C (zh) | 2002-02-06 |
DE59407708D1 (de) | 1999-03-04 |
KR960703947A (ko) | 1996-08-31 |
WO1995001999A1 (de) | 1995-01-19 |
US6197901B1 (en) | 2001-03-06 |
CN1127002A (zh) | 1996-07-17 |
NO960089D0 (no) | 1996-01-09 |
ES2126765T3 (es) | 1999-04-01 |
FI960098A0 (fi) | 1996-01-09 |
JP3776929B2 (ja) | 2006-05-24 |
DE4323192A1 (de) | 1995-01-12 |
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