JPH0562720B2 - - Google Patents
Info
- Publication number
- JPH0562720B2 JPH0562720B2 JP5667285A JP5667285A JPH0562720B2 JP H0562720 B2 JPH0562720 B2 JP H0562720B2 JP 5667285 A JP5667285 A JP 5667285A JP 5667285 A JP5667285 A JP 5667285A JP H0562720 B2 JPH0562720 B2 JP H0562720B2
- Authority
- JP
- Japan
- Prior art keywords
- radiation image
- binder solution
- antistatic agent
- stimulable phosphor
- image conversion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 152
- 238000000576 coating method Methods 0.000 claims description 99
- 239000011248 coating agent Substances 0.000 claims description 98
- 230000005855 radiation Effects 0.000 claims description 88
- 239000011230 binding agent Substances 0.000 claims description 76
- 238000006243 chemical reaction Methods 0.000 claims description 53
- 239000002216 antistatic agent Substances 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 28
- 238000003860 storage Methods 0.000 claims description 28
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 23
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 16
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims description 5
- 229910001620 barium bromide Inorganic materials 0.000 claims description 4
- NKQIMNKPSDEDMO-UHFFFAOYSA-L barium bromide Chemical compound [Br-].[Br-].[Ba+2] NKQIMNKPSDEDMO-UHFFFAOYSA-L 0.000 claims description 4
- XQPRBTXUXXVTKB-UHFFFAOYSA-M caesium iodide Inorganic materials [I-].[Cs+] XQPRBTXUXXVTKB-UHFFFAOYSA-M 0.000 claims description 4
- 235000009518 sodium iodide Nutrition 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 4
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 4
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 claims description 3
- 229910001638 barium iodide Inorganic materials 0.000 claims 3
- 229910001623 magnesium bromide Inorganic materials 0.000 claims 3
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims 3
- 239000010410 layer Substances 0.000 description 73
- 239000007788 liquid Substances 0.000 description 41
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 27
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 24
- 239000010408 film Substances 0.000 description 24
- 239000000460 chlorine Substances 0.000 description 18
- 229910052794 bromium Inorganic materials 0.000 description 17
- 229910052801 chlorine Inorganic materials 0.000 description 17
- 239000002245 particle Substances 0.000 description 16
- 229910052740 iodine Inorganic materials 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000020 Nitrocellulose Substances 0.000 description 11
- 229920001220 nitrocellulos Polymers 0.000 description 11
- 230000001681 protective effect Effects 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 229910052791 calcium Inorganic materials 0.000 description 10
- 239000011575 calcium Substances 0.000 description 10
- 229910052712 strontium Inorganic materials 0.000 description 10
- 230000005284 excitation Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910052693 Europium Inorganic materials 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- -1 polyethylene terephthalate Polymers 0.000 description 7
- 229920005749 polyurethane resin Polymers 0.000 description 7
- 229910052771 Terbium Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 229910052793 cadmium Inorganic materials 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 5
- 229910052772 Samarium Inorganic materials 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 238000004020 luminiscence type Methods 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 229910052684 Cerium Inorganic materials 0.000 description 4
- 229910052691 Erbium Inorganic materials 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052689 Holmium Inorganic materials 0.000 description 4
- 229910052779 Neodymium Inorganic materials 0.000 description 4
- 229910052769 Ytterbium Inorganic materials 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- 229910052790 beryllium Inorganic materials 0.000 description 4
- 229910052792 caesium Inorganic materials 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 230000009977 dual effect Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002985 plastic film Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229910052701 rubidium Inorganic materials 0.000 description 4
- 241001473992 Abax Species 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052775 Thulium Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000002601 radiography Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 3
- 229910052716 thallium Inorganic materials 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- PZBLUWVMZMXIKZ-UHFFFAOYSA-N 2-o-(2-ethoxy-2-oxoethyl) 1-o-ethyl benzene-1,2-dicarboxylate Chemical compound CCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCC PZBLUWVMZMXIKZ-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HSUIVCLOAAJSRE-UHFFFAOYSA-N bis(2-methoxyethyl) benzene-1,2-dicarboxylate Chemical compound COCCOC(=O)C1=CC=CC=C1C(=O)OCCOC HSUIVCLOAAJSRE-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- YOYLLRBMGQRFTN-SMCOLXIQSA-N norbuprenorphine Chemical class C([C@@H](NCC1)[C@]23CC[C@]4([C@H](C3)C(C)(O)C(C)(C)C)OC)C3=CC=C(O)C5=C3[C@@]21[C@H]4O5 YOYLLRBMGQRFTN-SMCOLXIQSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- DXIGZHYPWYIZLM-UHFFFAOYSA-J tetrafluorozirconium;dihydrofluoride Chemical class F.F.F[Zr](F)(F)F DXIGZHYPWYIZLM-UHFFFAOYSA-J 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Conversion Of X-Rays Into Visible Images (AREA)
- Radiography Using Non-Light Waves (AREA)
Description
çºæã®åé
æ¬çºæã¯ãèŒå°œæ§èå
äœãå©çšããæŸå°ç·åå€
ææ¹æ³ã«çšããããæŸå°ç·åå€æããã«ã«é¢ãã
ãã®ã§ãããããã«è©³ããã¯ãæ¬çºæã¯ãæ¯æäœ
ãšããã®äžã«èšããããèŒå°œæ§èå äœãå«ææ¯æ
ããçµåå€ãããªãèå äœå±€ãšãæããæŸå°ç·å
å€æããã«ã«é¢ãããã®ã§ããã çºæã®æè¡çèæ¯ããã³åŸæ¥æè¡ïŒœ æŸå°ç·åãç»åãšããŠåŸãæ¹æ³ãšããŠãåŸæ¥ã
ãéå¡©æå ææãããªãä¹³å€å±€ãæããæŸå°ç·å
çãã€ã«ã ãšå¢æçŽãšã®çµã¿åãããçšãããã
ãããæŸå°ç·åçæ³ãå©çšãããŠãããæè¿ãäž
èšæŸå°ç·åçæ³ã«ä»£ãæ¹æ³ã®äžã€ãšããŠãããšã
ã°ç¹éæ55â12145å·å ¬å ±ãªã©ã«èšèŒãããŠãã
ãããªãèŒå°œæ§èå äœãçšããæŸå°ç·åå€ææ¹æ³
ã泚ç®ãããããã«ãªã€ãããã®æŸå°ç·åå€ææ¹
æ³ã¯ãèŒå°œæ§èå äœãæããæŸå°ç·åå€æããã«
ïŒèç©æ§èå äœã·ãŒãïŒãå©çšãããã®ã§ã被å
äœãééããæŸå°ç·ããããã¯è¢«æ€äœããçºãã
ããæŸå°ç·ã該ããã«ã®èŒå°œæ§èå äœã«åžåã
ãããã®ã®ã¡ã«èŒå°œæ§èå äœãå¯èŠå ç·ãèµ€å€ç·
ãªã©ã®é»ç£æ³¢ïŒå±èµ·å ïŒã§æç³»åçã«å±èµ·ããã
ãšã«ããã該èŒå°œæ§èå äœäžã«èç©ãããŠããæŸ
å°ç·ãšãã«ã®ãŒãèå ïŒèŒå°œçºå ïŒãšããŠæŸåºã
ãããã®èå ãå é»çã«èªã¿åã€ãŠé»æ°ä¿¡å·ã
åŸããããŠåŸãããé»æ°ä¿¡å·ãç»ååãããã®ã§
ããã äžè¿°ã®æŸå°ç·åå€ææ¹æ³ã«ããã°ãåŸæ¥ã®æŸå°
ç·åçæ³ã«ããå Žåã«æ¯èŒããŠãã¯ããã«å°ãªã
被æç·éã§æ å ±éã®è±å¯ãªæŸå°ç·ç»åãåŸãããš
ãã§ãããšããå©ç¹ããããåŸã€ãŠããã®æŸå°ç·
åå€ææ¹æ³ã¯ãç¹ã«å»ç蚺æãç®çãšããç·æ®
圱çã®çŽæ¥å»ççšæŸå°ç·æ®åœ±ã«ãããŠå©çšäŸ¡å€ã®
éåžžã«é«ããã®ã§ããã äžèšæŸå°ç·åå€ææ¹æ³ã«çšããæŸå°ç·åå€æã
ãã«ã¯ãåºæ¬æ§é ãšããŠãã©ã¹ããã¯ã·ãŒãçã®
æ¯æäœãšããã®çé¢ã«èšããããèŒå°œæ§èå äœã
åæ£ç¶æ ã§å«ææ¯æããæ¯æäœãããªãèå äœå±€
ãšãããªããã®ã§ããããããŠããã®èå äœå±€ã®
æ¯æäœãšã¯å察åŽã®è¡šé¢ïŒæ¯æäœã«é¢ããŠãªãåŽ
ã®è¡šé¢ïŒã«ã¯éåžžãèå äœå±€ãååŠçãªå€è³ªãã
ãã¯ç©ççãªè¡æããä¿è·ãããã€ããã«è¡šé¢ã
å¹³æ»åããããã«ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããª
ã©ã®éæãªä¿è·èãèšããããŠããã æŸå°ç·åå€ææ¹æ³ã®å®æœã«ãããŠãæŸå°ç·åå€
æããã«ã¯ãæŸå°ç·ã®ç §å°ïŒæŸå°ç·åã®èšé²ïŒã»
å±èµ·å ã®ç §å°ïŒèšé²ãããæŸå°ç·åã®èªåãïŒã»
æ¶å»å ã®ç §å°ïŒæ®åããæŸå°ç·åã®æ¶å»ïŒãšãã
ãµã€ã¯ã«ã§ç¹°ãè¿ã䜿çšãããããããŠæŸå°ç·å
å€æããã«ã®åã¹ããããžã®ç§»è¡ã¯æ¬éç³»ã«ãã
è¡ãªãããïŒãµã€ã¯ã«çµäºåŸããã«ã¯é 次ç©å±€ã
ãŠä¿åãããã ãã®æ¬éããç©å±€ç¶æ ãžãšç§»è¡ããé£ç¶ãããµ
ã€ã¯ã«ã«ãããŠããã®éã«æŸå°ç·åå€æããã«å
å¿ã®æ¥è§Šãæ©æŠãç¹°ãè¿ãçããããã«é«ååç©
質ãããªãããã«ã®è¡šé¢ïŒèå äœå±€åŽè¡šé¢ïŒã垯
é»ãå®ãããã®ããšãæŸå°ç·åå€ææ¹æ³ã®å®æœäž
çš®ã ã®åé¡ãçºçãããåå ãšãªã€ãŠããã ããšãã°ãæŸå°ç·åå€æããã«ã®è¡šé¢ã垯é»ã
ãçµæãããã«ãç©å±€ç¶æ ããæ¬éç³»ã«ç§»ãé
ã«ãããã«è¡šé¢ãšä»ã®ããã«ã®è£é¢ïŒæ¯æäœåŽè¡š
é¢ïŒãšãçžäºã«å¯çããŠäºæéãªã€ãç¶æ ã§æ¬é
ç³»ã«éã蟌ãŸãããããªãããã以åŸã®æ£åžžãªæ
äœãè¡ãªãããšãäžå¯èœãšãªããã®ã§ããããŸ
ããããã«è¡šé¢ã«ã¯ç©ºæ°äžã®å¡µåãä»çãããã
ãªãããã®ãããªããã«ã«ãããŠã¯èªã¿åºãã®é
ã«è¡šé¢ã«ä»çãã塵åã«ãã€ãŠå±èµ·å ãæ£ä¹±ãã
ãããã«ãåŸãããç»åã¯ç»è³ªãèããäœäžãã
ãã®ãšãªãã ãšããã§ãèå äœå±€ã¯äžè¬ã«ãèŒå°œæ§èå äœã®
ç²åãšçµåå€ãšãé©åœãªæº¶å€ã«å ããŠèå äœãçµ
åå€æº¶æ¶²ã«åäžã«åæ£ããå¡åžæ¶²ãçšæãããã®
å¡åžæ¶²ããã¯ã¿ãŒãã¬ãŒããããŒã«ã³ãŒã¿ãŒãªã©
ãçšããŠæ¯æäœäžã«çŽæ¥å¡åžããã®ã¡ä¹Ÿç¥ããã
ãšã«ããããããã¯å¥ã®ã·ãŒãã«å¡åžããŠåœ¢æã
ãèå äœå±€ãæ¯æäœãšæ¥åããããšã«ãããæ¯æ
äœäžã«ä»èšãããŠãããåŸã€ãŠãèŒå°œæ§èå äœç²
åã¯èå äœå±€äžã«ã»ãŒåäžã«åæ£ããŠååšããŠã
ãã ããã«ããã®èå äœå±€è¡šé¢ã«ã¯äžè¬ã«ãéæãª
é«ååç©è³ªãããªã溶液ãå¡åžããããšã«ããã
ãããã¯å¥é圢æããéæãªèèãæ¥çå€çãçš
ããŠæ¥çããããšã«ããä¿è·èãèšããããŠã
ãã æ¬åºé¡äººã¯ãèŒå°œæ§èå äœãåæ£ããŠãªãçµå
å€æº¶æ¶²ãšèŒå°œæ§èå äœãå«æããªãçµåå€æº¶æ¶²ãš
ãçšããŠåæã«éå±€å¡åžããããšã«ãããæ¯æäœ
äžã«ãèŒå°œæ§èå äœãååšããéšåãšèŒå°œæ§èå
äœãå®è³ªçã«ååšããªãéšåãšããæ§æãããè
å äœå±€ãèšããæ¹æ³ããã³æŸå°ç·åå€æããã«ã«
ã€ããŠæ¢ã«ç¹èš±åºé¡ããŠããïŒç¹é¡æ59â182212
å·ïŒãåŸã€ãŠããã®æ¹æ³ã«ãã補é ãããããã«
ã«ãããŠã¯ãå¡èã®çé¢ã圢æããããèå äœå±€
ãä¿è·èãšããŠã®æ©èœãæããŠããã çºæã®ç®ç æ¬çºæã¯ã垯é»é²æ¢å¹æãåªããæŸå°ç·åå€æ
ããã«ããã³ãã®è£œé æ³ãæäŸããããšããã®ç®
çãšãããã®ã§ããã ãŸããæ¬çºæã¯ãç¹ã«æ¬éç¹æ§ãåäžããæŸå°
ç·åå€æããã«ããã³ãã®è£œé æ³ãæäŸããããš
ããã®ç®çãšãããã®ã§ããã äžèšã®ç®çã¯ãæ¯æäœãšããã®äžã«èšãããã
èŒå°œæ§èå äœãå«ææ¯æããçµåå€ãããªãèå
äœå±€ãšãæããæŸå°ç·åå€æããã«ã«ãããŠã該
èå äœå±€ãæ¯æäœåŽã®èŒå°œæ§èå äœãååšããéš
åãšããã«è¡šé¢åŽã®èŒå°œæ§èå äœãååšããªãéš
åãšããæ§æãããäž¡éšåã®éã«å¢çé¢ãååšã
ãããã€è©²èŒå°œæ§èå äœãå®è³ªçã«ååšããªãéš
åã«éå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«æãã
ãŠããããšãç¹åŸŽãšããæ¬çºæã®æŸå°ç·åå€æã
ãã«ã«ããéæããããšãã§ããããªããäžèšã®
ãããã«è¡šé¢åŽã®èŒå°œæ§èå äœãååšããªãããš
ã¯ãèŒå°œæ§èå äœç²åã埮éæ··å ¥ããŠããç¶æ ã
æé€ãããã®ã§ã¯ãªãã ãŸããäžèšã®ç®çã¯ã (1) èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãšéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«
æããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«
çžæº¶æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§è©²
èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²ïŒïŒ
ãæ¯æäœåŽãšãªãããã«æ¯æäœè¡šé¢ã«åæã«é
å±€å¡åžããããšãç¹åŸŽãšããæ¬çºæã®æŸå°ç·å
å€æããã«ã®è£œé æ³ãããã³ (2) èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«
æããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«
çžæº¶æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§å¹³
é¢ã·ãŒãäžã«åæã«éå±€å¡åžããŠèå äœå±€ã圢
æããã®ã¡ã該èå äœå±€ãã·ãŒãããåé¢ããŠ
æ¯æäœäžã«ä»èšããããšãç¹åŸŽãšããæŸå°ç·å
å€æããã«ã®è£œé æ³ã ã«ããæå©ã«éæããããšãã§ããã ãªããæ¬çºæã«ãããŠããã«è¡šé¢åŽãšã¯ãèå
äœå±€ã®æ¯æäœã«æ¥ããåŽãšã¯å察åŽãæå³ããã çºæã®å¹æ æ¬çºæã¯ãèŒå°œæ§èå äœãšçµåå€ãšãããªãæŸ
å°ç·åå€æããã«ã®èå äœå±€ã«ãããŠãèŒå°œæ§è
å äœç²åãæ¯æäœåŽã®äžå®é åå ã«ã®ã¿åæ£ç¶æ
ã§ååšãããäžæ¹ãããã«è¡šé¢åŽã®äžå®é åå ã«
ã¯å®è³ªçã«èå äœç²åãååšãããªãã§åž¯é»é²æ¢
å€ã®ã¿ãå«æãããããšã«ãããæ¬éç³»ã«ããã
垯é»çŸè±¡ãé²æ¢ããåæ»ãªæŸå°ç·åã®èšé²åçã
å®çŸãããã®ã§ããã åŸæ¥ã«ãããŠã¯äžè¬ã«ãèå äœç²åãåäžã«å
æ£ããçµåå€æº¶æ¶²ïŒå¡åžæ¶²ïŒãéåžžã®å¡åžæ¹æ³ã«
ãã€ãŠæ¯æäœäžã«å¡åžããããšã«ããèå äœå±€ã®
圢æãè¡ãªãããŠããçµæãèå äœç²åã¯çµåå€
ã«ããèå äœå±€å šäœã«æž¡ã€ãŠåæ£ç¶æ ã§å«ææ¯æ
ãããŠããã æ¬çºæã«ãããŠã¯ãèå äœç²åãåæ£ããŠãªã
å¡åžæ¶²ïŒïŒãšãèå äœç²åãå«ãŸãªãã§åž¯é»é²
æ¢å€ã®ã¿ãå«æããçµåå€æº¶æ¶²ïŒïŒãšãã該å¡
åžæ¶²ïŒïŒãæ¯æäœåŽã«é 眮ããŠåæã«æ¯æäœäž
ã«éå±€ããŠå¡åžããããšã«ãããèå äœå±€ã®æ·±ã
æ¹åã«åž¯é»é²æ¢å€ãåæ£ç¶æ ã§ååšããçµåå€éš
åãšèå äœç²åãåæ£ç¶æ ã§ååšããéšåãšã圢
æããããšãã§ããã ããªãã¡ãèå äœç²åãèå äœå±€ã®æ¯æäœåŽã®
äžå®é åã«åæ£ç¶æ ã§ååšãããããšå察ã®ãã
ã«è¡šé¢åŽã®äžå®é åã«ã¯åž¯é»é²æ¢å€ãåæ£ç¶æ ã§
ååšãããã€èå äœç²åãå®è³ªçã«ååšããªãè
å äœå±€ã圢æããããåŸã€ãŠã垯é»é²æ¢å€ãå«æ
ããéšåã¯åŸãããæŸå°ç·åå€æããã«ã®è¡šé¢åŽ
ã«åœ¢æãããããã垯é»çŸè±¡ãå¹æçã«é²æ¢ãã
ããšãã§ããã ãŸãããã®åž¯é»é²æ¢å€ãå«æããéšåã¯å¹³æ ãª
è¡šé¢ãæãããšãšãã«ãèå äœãååŠçå€åãã
ã³ç©ççè¡æããä¿è·ããããã®ä¿è·èãšåæ§ã®
圹å²ãæãããšãã§ããããã«ãåŸæ¥ã®ããã«è
å äœå±€äžã«å¥å·¥çšãšããŠä¿è·èãèšããå¿ èŠããª
ããæŸå°ç·åå€æããã«ã®è£œé å·¥çšãç°¡ç¥åãã
ããšãã§ããã ãŸãããã®ããšã¯ãåŸæ¥ã®æŸå°ç·åå€æããã«
ã«ãããããã«ãä¿è·èã®ä»èšã«ãã€ãŠèå äœå±€
ãšä¿è·èãšã®éã«ããããã¯æ¥çå€å±€ãä»ããŠä»
èšããå Žåã«ã¯èå äœå±€ãæ¥çå€å±€ããã³ä¿è·è
ã®åå±€éã«ãçé¢ã圢æãããããšããªãããšã
æå³ãããåŸã€ãŠãããã«ã®æ©æ¢°ç匷床ïŒå¯ç匷
床ãªã©ïŒãåäžãããããšãã§ããã ããã«ããããçé¢ã§å±èµ·å ã®æ£ä¹±ãçããã
ãšããªããé®®é床ããã³ç²ç¶æ§ãªã©ç»è³ªã®åäžã
ãç»åãåŸãããšãå¯èœã§ãããåæã«ããã®ç
é¢ã§ã®èå ã®æ£ä¹±ãçããããšããªããããç»è³ª
ã®åäžãšãšãã«æ床ãå¢å€§ãããããšãå¯èœã§ã
ãã çºæã®æ§æ 以äžè¿°ã¹ããããªå¥œãŸããç¹æ§ããã€ãæ¬çºæ
ã®æŸå°ç·åå€æããã«ã¯ãããšãã°ã次ã«è¿°ã¹ã
ãããªè£œé æ³ã«ãã補é ããããšãã§ããã æ¬çºæã®ç¹åŸŽçãªèŠä»¶ã§ããèå äœå±€ã¯ãå®è³ª
çã«æ¯æäœåŽã®èŒå°œæ§èå äœã®ç²åãå«æããéš
åãšãããã«è¡šé¢åŽã®åž¯é»é²æ¢å€ãå«æããéšå
ãšãããªãå±€ã§ããããšãã«çµåå€ã«ããæ¯æã
ããŠãªãå±€ã§ããã èŒå°œæ§èå äœã¯ãå ã«è¿°ã¹ãããã«æŸå°ç·ãç §
å°ããåŸãå±èµ·å ãç §å°ãããšèŒå°œçºå ã瀺ãè
å äœã§ããããå®çšçãªé¢ããã¯æ³¢åœ¢ã400ã
900nïœã®ç¯å²ã«ããå±èµ·å ã«ãã€ãŠ300ã500nïœ
ã®æ³¢é·ç¯å²ã®èŒå°œçºå ã瀺ãèå äœã§ããããšã
æãŸããã æ¬çºæã®æŸå°ç·åå€æããã«ã«çšããããèŒå°œ
æ§èå äœã®äŸãšããŠã¯ã ç±³åœç¹èš±ç¬¬3859527å·æ现æžã«èšèŒãããŠãã
SrSïŒCeãSmãSrSïŒEuãSmãThO2ïŒErãã
ãã³La2O2SïŒEuãSmã ç¹éæ55â12142å·å ¬å ±ã«èšèŒãããŠãã
ZnSïŒCuãPbãBaOã»xAl2O3ïŒEuïŒãã ãã0.8
ïŒïœâŠ10ïŒãããã³ãMãã»xSiO2ïŒïŒ¡ïŒãã ãã
Mãã¯MgãCaãSrãZnãCdããŸãã¯Baã§ããã
ã¯CeãTbãEuãTmãPbãTlãBiããŸãã¯
Mnã§ãããïœã¯ã0.5âŠïœâŠ2.5ã§ããïŒã ç¹éæ55â12143å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-X-yãMgxãCayïŒFXïŒaEu2+ïŒãã ãã
ã¯Clããã³Brã®ãã¡ã®å°ãªããšãäžã€ã§ããã
ïœããã³ïœã¯ãïŒïŒïœïŒïœâŠ0.6ããã€xyâ ïŒã§
ãããïœã¯ã10-6âŠïœâŠïŒÃ10-2ã§ããïŒã ç¹éæ55â12144å·å ¬å ±ã«èšèŒãããŠãã
LnOXïŒxAïŒãã ããLnã¯LaããGdãããã³
Luã®ãã¡ã®å°ãªããšãäžã€ãã¯Clããã³Brã®
ãã¡ã®å°ãªããšãäžã€ãã¯Ceããã³Tbã®ãã¡
ã®å°ãªããšãäžã€ããããŠãïœã¯ãïŒïŒïœïŒ0.1
ã§ããïŒã ç¹éæ55â12145å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãM2+ xïŒFXïŒyAïŒãã ããM2+ã¯Mgã
CaãSrãZnãããã³Cdã®ãã¡ã®å°ãªããšãäž
ã€ãã¯ClãBrãããã³ïŒ©ã®ãã¡ã®å°ãªããšã
äžã€ãã¯EuãTbãCeãTmãDyãPrãHoã
NdãYbãããã³Erã®ãã¡ã®å°ãªããšãäžã€ãã
ããŠïœã¯ãïŒâŠïœâŠ0.6ãïœã¯ãïŒâŠïœâŠ0.2ã§ã
ãïŒã ç¹éæ55â160078å·å ¬å ±ã«èšèŒãããŠããMã
FXã»xAïŒyLnãã ããMãã¯BaãCaãSrã
MgãZnãããã³Cdã®ãã¡ã®å°ãªããšãäžçš®ã
ã¯BeOãMgOãCaOãSrOãBaOãZnOã
Al2O3ãY2O3ãLa2O3ãIn2O3ãSiO2ãTiO2ã
ZrO2ãGeO2ãSnO2ãNb2O5ãTa2O5ãããã³
ThO2ã®ãã¡ã®å°ãªããšãäžçš®ãLnã¯EuãTbã
CeãTmãDyãPrãHoãNdãYbãErãSmã
ããã³Gdã®ãã¡ã®å°ãªããšãäžçš®ãã¯Clã
Brãããã³ïŒ©ã®ãã¡ã®å°ãªããšãäžçš®ã§ããã
ïœããã³ïœã¯ããããïŒÃ10-5âŠïœâŠ0.5ããã
ã³ïŒïŒïœâŠ0.2ã§ããã®çµæåŒã§è¡šããããè
å äœã ç¹éæ56â116777å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzAãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ãã¯ãžã«ã³ããŠã ãã
ã³ã¹ã«ã³ãžãŠã ã®ãã¡ã®å°ãªããšãäžçš®ã§ããã
ïœãïœãïœãããã³ïœã¯ãããã0.5âŠïœâŠ1.25ã
ïŒâŠïœâŠïŒã10-6âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœ
âŠ10-2ã§ããã®çµæåŒã§è¡šããããèå äœã ç¹éæ57â23673å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzBãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ã§ãããïœãïœãïœãã
ãã³ïœã¯ãããã0.5âŠïœâŠ1.25ãïŒâŠïœâŠïŒã
10-6âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœâŠïŒÃ10-1ã§
ããã®çµæåŒã§è¡šããããèå äœã ç¹éæ57â23675å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzAãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ãã¯ç çŽ ããã³ç¡ çŽ ã®
ãã¡ã®å°ãªããšãäžçš®ã§ãããïœãïœãïœããã
ã³ïœã¯ãããã0.5âŠïœâŠ1.25ãïŒâŠïœâŠïŒã10-6
âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœâŠïŒÃ101ã§ãã
ã®çµæåŒã§è¡šããããèå äœã ç¹éæ58â69281å·å ¬å ±ã«èšèŒãããŠããMã
OXïŒxCeãã ããMãã¯PrãNdãPmãSmã
EuãTbãDyãHoãErãTmãYbãããã³Biã
ããªã矀ããéžã°ããå°ãªããšãäžçš®ã®äžäŸ¡éå±
ã§ãããã¯Clããã³Brã®ãã¡ã®ããããäžæ¹
ãããã¯ãã®äž¡æ¹ã§ãããïœã¯ïŒïŒïœïŒ0.1ã§ã
ãã®çµæåŒã§è¡šããããèå äœã ç¹éæ58â206678å·å ¬å ±ã«èšèŒãããŠãã
Ba1-xMx/2Lx/2FXïŒyEu2+ãã ããïŒã¯LiãNaã
ãRbãããã³Csãããªã矀ããéžã°ããå°ãª
ããšãäžçš®ã®ã¢ã«ã«ãªéå±ãè¡šããïŒïŒ¬ã¯ãScã
ãLaãCeãPrãNdãPmãSmãGdãTbã
DyãHoãErãTmãYbãLuãAlãGaãInãã
ãã³Tlãããªã矀ããéžã°ããå°ãªããšãäžçš®
ã®äžäŸ¡éå±ãè¡šããïŒïŒžã¯ãClãBrãããã³ïŒ©
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²
ã³ãè¡šããïŒãããŠãïœã¯10-2âŠïœâŠ0.5ãïœã¯
ïŒïŒïœâŠ0.1ã§ããã®çµæåŒã§è¡šããããèå
äœã ç¹éæ59â27980å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xAïŒyEu2+ãã ããã¯ãClãBrãã
ãã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®
ããã²ã³ã§ããïŒïŒ¡ã¯ãããã©ãã«ãªãããŠé žå
åç©ã®çŒæç©ã§ããïŒãããŠãïœã¯10-6âŠïœâŠ
0.1ãïœã¯ïŒïŒïœâŠ0.1ã§ããã®çµæåŒã§è¡šãã
ããèå äœã ç¹éæ59â47289å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xAïŒyEu2+ãã ããã¯ãClãBrãã
ãã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®
ããã²ã³ã§ããïŒïŒ¡ã¯ããããµãã«ãªãã±ã€é žã
ãããµãã«ãªããã¿ã³é žããã³ãããµãã«ãªããž
ã«ã³ããŠã é žã®äžäŸ¡ãããã¯äºäŸ¡éå±ã®å¡©ãããª
ããããµãã«ãªãååç©çŸ€ããéžã°ããå°ãªããš
ãäžçš®ã®ååç©ã®çŒæç©ã§ããïŒãããŠãïœã¯
10-6âŠïœâŠ0.1ãïœã¯ïŒïŒïœâŠ0.1ã§ããã®çµæ
åŒã§è¡šããããèå äœã ç¹éæ59â56479å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xNaXâ²ïŒaEu2+ãã ããããã³Xâ²ã¯ã
ããããClãBrãããã³ïŒ©ã®ãã¡ã®å°ãªããšã
äžçš®ã§ãããïœããã³ïœã¯ããããïŒïŒïœâŠïŒã
ããã³ïŒïŒïœâŠ0.2ã§ããã®çµæåŒã§è¡šããã
ãèå äœã ç¹éæ59â56480å·å ¬å ±ã«èšèŒãããŠããMã
FXã»xNaXâ²ïŒyEu2+ïŒzAãã ããMãã¯ãBaã
Srãããã³Caãããªã矀ããéžã°ããå°ãªããš
ãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒïŒžããã³
Xâ²ã¯ãããããClãBrãããã³ïŒ©ãããªã矀ã
ãéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ããïŒïŒ¡
ã¯ããCrãMnãFeãCoãããã³Niããéžã°
ããå°ãªããšãäžçš®ã®é·ç§»éå±ã§ããïŒãããŠã
ïœã¯ïŒïŒïœâŠïŒãïœã¯ïŒïŒïœâŠ0.2ãããã³ïœã¯
ïŒïŒïœâŠ10-2ã§ããã®çµæåŒã§è¡šããããèå
äœã ç¹éæ59â75200å·å ¬å ±ã«èšèŒãããŠããMã
FXã»aMãXâ²ã»bMâ²ãXâ³2ã»cMã3ã»xAïŒ
yEu2+ãã ããMãã¯BaãSrãããã³Caãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡
éå±ã§ããïŒMãã¯LiãNaããRbãããã³Cs
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«
ãªéå±ã§ããïŒMâ²ãã¯Beããã³Mgãããªã矀ã
ãéžã°ããå°ãªããšãäžçš®ã®äºäŸ¡éå±ã§ããïŒ
Mãã¯AlãGaãInãããã³Tlãããªã矀ããéž
ã°ããå°ãªããšãäžçš®ã®äžäŸ¡éå±ã§ããïŒïŒ¡ã¯é
å±é žåç©ã§ããïŒïŒžã¯ClãBrãããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãïŒXâ²ãXâ³ãããã³Xâ³ã¯ããClãBrãããã³
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ãã
ã²ã³ã§ããïŒãããŠãïœã¯ïŒâŠïœâŠïŒãïœã¯ïŒâŠ
ïœâŠ10-2ãïœã¯ïŒâŠïœâŠ10-2ããã€ïœïŒïœïŒïœâ§
10-6ã§ããïŒïœã¯ïŒïŒïœâŠ0.5ãïœã¯ïŒïŒïœâŠ0.2
ã§ããã®çµæåŒã§è¡šããããèå äœã æ¬åºé¡äººã«ããç¹é¡æ58â193161å·æ现æžã«èš
èŒãããŠããMãX2ã»aMãXâ²2ïŒxEu2+ãã ãã
Mãã¯BaãSrããã³Caãããªã矀ããéžã°ãã
å°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒïŒžã
ãã³Xâ²ã¯ClãBrããã³ïŒ©ãããªã矀ããéžã°ã
ãå°ãªããšãäžçš®ã®ããã²ã³ã§ãã€ãŠããã€ïŒžâ
Xâ²ã§ããïŒãããŠïœã¯0.1âŠïœâŠ10.0ãïœã¯ïŒïŒ
ïœïŒ0.2ã§ããã®çµæåŒã§è¡šããããèå äœã æ¬åºé¡äººã«ããç¹é¡æ58â208727å·æ现æžã«èš
èŒãããŠããMãFXã»aMãXâ²ïŒxEu2+ãã ãã
Mãã¯BaãSrããã³Caãããªã矀ããéžã°ãã
å°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒMã
ã¯Rbããã³Csãããªã矀ããéžã°ããå°ãªããš
ãäžçš®ã®ã¢ã«ã«ãªéå±ã§ããïŒïŒžã¯ClãBrãã
ã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã
ãã²ã³ã§ããïŒXâ²ã¯ïŒŠãClãBrããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãïŒãããŠïœããã³ïœã¯ããããïŒâŠïœâŠ4.0ã
ãã³ïŒâŠïœâŠ0.2ã§ããã®çµæåŒã§è¡šãããã
èå äœã ãªã©ãæããããšãã§ããã ãŸããäžèšç¹é¡æ58â193161å·æ现æžã«èšèŒã
ããŠããMãX2ã»aMãXâ²2ïŒxEu2+èå äœã«ã¯ã以
äžã«ç€ºããããªæ·»å ç©ãMãX2ã»aMãXâ²21ã¢ã«åœ
ã以äžã®å²åã§å«ãŸããŠããŠãããã æ¬åºé¡äººã«ããç¹é¡çº59â22169å·æ现æžã«èš
èŒãããŠããbMãXâ³ïŒãã ããMãã¯Rbããã³Cs
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«
ãªéå±ã§ãããXâ³ã¯ïŒŠãClãBrããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãããããŠïœã¯ïŒïŒïœâŠ10.0ã§ããïŒïŒç¹é¡æ59
â77225å·æ现æžã«èšèŒãããŠããbKXâ³ã»cMgX
2ã»dMãâ²â²â²â²3ïŒãã ããMãã¯ScããLaãGd
ããã³Luãããªã矀ããéžã°ããå°ãªããšãäž
çš®ã®äžäŸ¡éå±ã§ãããXâ³ãããã³ïŒžâ²â²â²â²ã¯ã
ããããClãBrããã³ïŒ©ãããªã矀ããéžã°
ããå°ãªããšãäžçš®ã®ããã²ã³ã§ããããããŠ
ïœãïœåã³ïœã¯ãããããïŒâŠïœâŠ2.0ãïŒâŠïœ
âŠ2.0ãïŒâŠïœâŠ2.0ã§ãã€ãŠããã€ïŒÃ10-5âŠïœ
ïŒïœïŒïœã§ããïŒïŒç¹é¡æ59â84356å·æ现æžã«èš
èŒãããŠããyBïŒãã ããïœã¯ïŒÃ10-4âŠïœâŠïŒ
Ã10-1ã§ããïŒïŒåã³ç¹é¡æ59â84358å·æ现æžã«
èšèŒãããŠããbAïŒãã ããã¯SiO2åã³P2O5
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®é žåç©
ã§ããããããŠïœã¯10-4âŠïœâŠïŒÃ10-1ã§ããïŒ äžèšã®èŒå°œæ§èå äœã®ãã¡ã§ãäºäŸ¡ã®ãŠãŒãã
ãŠã 賊掻ã¢ã«ã«ãªåé¡éå±ããã²ã³åç©ç³»èå äœ
ããã³åžåé¡å çŽ è³ŠæŽ»åžåé¡ãªãã·ããã²ã³åç©
ç³»èå äœã¯é«èŒåºŠã®èŒå°œçºå ã瀺ãã®ã§ç¹ã«å¥œãŸ
ããããã ããæ¬çºæã«çšããããèŒå°œæ§èå äœ
ã¯äžè¿°ã®èå äœã«éããããã®ã§ã¯ãªããæŸå°ç·
ãç §å°ããã®ã¡ã«å±èµ·å ãç §å°ããå Žåã«ãèŒå°œ
çºå ã瀺ãèå äœã§ããã°ãããªããã®ã§ãã€ãŠ
ãããã èå äœå±€ã®çµåå€ã®äŸãšããŠã¯ããŒã©ãã³çã®
èçœè³ªãããã¹ãã©ã³çã®ããªãµãã«ã©ã€ãããŸ
ãã¯ã¢ã©ãã¢ãŽã ã®ãããªå€©ç¶é«ååç©è³ªïŒãã
ã³ãããªããã«ããã©ãŒã«ãããªé ¢é žããã«ãã
ããã»ã«ããŒã¹ããšãã«ã»ã«ããŒã¹ãå¡©åãããª
ãã³ã»å¡©åããã«ã³ããªããŒãããªã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããå¡©åããã«ã»é ¢é žããã«ã³ã
ãªããŒãããªãŠã¬ã¿ã³ãã»ã«ããŒã¹ã¢ã»ããŒãã
ãã¬ãŒããããªããã«ã¢ã«ã³ãŒã«ãç·ç¶ããªãšã¹
ãã«ãªã©ã®ãããªåæé«ååç©è³ªãªã©ã«ãã代衚
ãããçµåå€ãæããããšãã§ããããã®ãããª
çµåå€ã®ãªãã§ç¹ã«å¥œãŸãããã®ã¯ããããã»ã«
ããŒã¹ãç·ç¶ããªãšã¹ãã«ãããªã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒãããããã»ã«ããŒã¹ãšç·ç¶ããª
ãšã¹ãã«ãšã®æ··åç©ããã³ãããã»ã«ããŒã¹ãšã
ãªã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããšã®æ··åç©ã§ã
ãããªãããããã®çµåå€ã¯æ¶æ©å€ã«ãã€ãŠæ¶æ©
ããããã®ããã€ãŠãããã 次ã«ãæ¬çºæã«çšãããã垯é»é²æ¢å€ã¯ãéå±
ã®ç¡æ©å¡©ã§ãããèå äœå±€è¡šé¢åŽã«éå±ã®ç¡æ©å¡©
ãå«æãããããšã«ãã€ãŠãè¡šé¢ã«åž¯é»ããé»è·
ãè¡šé¢é»å°ã«ããé»è·ã®ç§»åïŒæŸé»ïŒã«ããé²æ¢
ããããšãã§ãããããªãã¡ããã®ç©è³ªã®è¡šé¢é»
æ°æµæãå°ããããããšã«ãããçºçããé»è·ã
容æã«æŸé»ããããšãã§ããã æ¬çºæã«ãããŠåž¯é»é²æ¢å€ãšããŠçšããããé
å±ç¡æ©å¡©ã®ä»£è¡šçãªäŸãšããŠã¯ãLiClãNaClã
NaBrãNaIãNaNO3ãNa3PO4ãCsIãBaBr2ã
BaI2ãMgBr2ãAlBr3çã®éå±ã®ç¡æ©å¡©ãæãã
ããããªãããããã®éå±ç¡æ©å¡©ã¯åžžæž©ã§å®å®ã§
ããéããç¡æ°Žç©ã®ç¶æ ã§ãã€ãŠãããããã¯çµ
æ¶æ°Žãä»å ãããç¶æ ã§ãã€ãŠãããã äžèšã®éå±ç¡æ©å¡©ã®ãã¡ã§å¥œãŸãããã®ã¯ã
LiClãNaBrãNaIãNaNO3ãMgNr2ããã³
AlBr3ã§ãããããã«ãç¡çè²ã§ããããšãåã³
æ°Žãã¢ã«ã³ãŒã«çã®æº¶å€ã«å¯Ÿãã溶解æ§ãé«ãã
ãšçã®ç¹ãããLiClãNaBrãããã³MgBr2ãç¹
ã«å¥œãŸãããããªãã¡ããããã®éå±ããã²ã³å
ç©ã¯ç¡çè²ã§ããããã«å±èµ·å ãåžåããããšã
ãªãããŸããçµåå€æº¶æ¶²ã«æº¶è§£ããããåŸããã
èå äœå±€è¡šé¢ã«ãããåæ£æ§ãé«ããã®ã§ããã èå äœå±€ã¯ãããšãã°ã次ã®ãããªæ¹æ³ã«ãã
æ¯æäœäžã«åœ¢æããããšãã§ããã ãŸãäžèšã®èŒå°œæ§èå äœãšçµåå€ãšãé©åœãªæº¶
å€ã«æ·»å ãããããå åã«æ··åããŠãçµåå€æº¶æ¶²
äžã«èå äœç²åãåäžã«åæ£ããå¡åžæ¶²ïŒïŒã
調補ããã å¡åžæ¶²èª¿è£œçšã®æº¶å€ã®äŸãšããŠã¯ãããšãã°ã
ã¡ã¿ããŒã«ããšã¿ããŒã«ãïœâãããããŒã«ãïœ
âãã¿ããŒã«ãªã©ã®äœçŽã¢ã«ã³ãŒã«ïŒã¡ãã¬ã³ã¯
ãã©ã€ãããšãã¬ã³ã¯ãã©ã€ããªã©ã®å¡©çŽ ååå«
æçåæ°ŽçŽ ïŒã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡
ãã«ã€ãœããã«ã±ãã³ãªã©ã®ã±ãã³ïŒé ¢é žã¡ã
ã«ãé ¢é žãšãã«ãé ¢é žããã«ãªã©ã®äœçŽèèªé žãš
äœçŽã¢ã«ã³ãŒã«ãšã®ãšã¹ãã«ïŒãžãªããµã³ããšã
ã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããšãã¬ã³ã°
ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãªã©ã®ãšãŒãã«ïŒã
ããŠããããã®æ··åç©ãæããããšãã§ããã å¡åžæ¶²ã«ãããçµåå€ãšèŒå°œæ§èå äœãšã®æ··å
æ¯ã¯ãç®çãšããæŸå°ç·åå€æããã«ã®ç¹æ§ãè
å äœã®çš®é¡ãªã©ã«ãã€ãŠç°ãªãããäžè¬ã«ã¯çµå
å€ãšèå äœãšã®æ··åæ¯ã¯ãïŒïŒïŒä¹è³ïŒïŒ100ïŒé
éæ¯ïŒã®ç¯å²ããéžã°ãããããŠç¹ã«ïŒïŒïŒä¹è³
ïŒïŒ40ïŒééæ¯ïŒã®ç¯å²ããéžã¶ããšã奜ãŸããã ãªããå¡åžæ¶²ïŒïŒã«ã¯ã該å¡åžæ¶²äžã«ããã
èå äœã®åæ£æ§ãåäžãããããã®åæ£å€ããŸ
ãã圢æåŸã®èå äœå±€ã«ãããçµåå€ãšèå äœãš
ã®éã®çµååãåäžãããããã®å¯å¡å€ãªã©ã®
çš®ã ã®æ·»å å€ãæ··åãããŠããŠãããããã®ãã
ãªç®çã«çšããããåæ£å€ã®äŸãšããŠã¯ããã¿ã«
é žãã¹ãã¢ãªã³é žãã«ããã³é žã芪油æ§çé¢æŽ»æ§
å€ãªã©ãæããããšãã§ããããããŠå¯å¡å€ã®äŸ
ãšããŠã¯ãçé žããªããšãã«ãçé žããªã¯ã¬ãž
ã«ãçé žãžããšãã«ãªã©ã®çé žãšã¹ãã«ïŒãã¿ã«
é žãžãšãã«ããã¿ã«é žãžã¡ããã·ãšãã«ãªã©ã®ã
ã¿ã«é žãšã¹ãã«ïŒã°ãªã³ãŒã«é žãšãã«ãã¿ãªã«ãš
ãã«ãã°ãªã³ãŒã«é žããã«ãã¿ãªã«ããã«ãªã©ã®
ã°ãªã³ãŒã«é žãšã¹ãã«ïŒãããŠãããªãšãã¬ã³ã°
ãªã³ãŒã«ãšã¢ãžãã³é žãšã®ããªãšã¹ãã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ãšã³ãã¯é žãšã®ããªãšã¹ãã«ãªã©
ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ãšèèªæäºå¡©åºé žãšã®
ããªãšã¹ãã«ãªã©ãæããããšãã§ããã ããã«ãå¡åžæ¶²ã«ã¯ãç»åã®é®®é床ãåäžãã
ãç®çã§ãèŒå°œæ§èå äœã®å±èµ·å æ³¢é·é åã«ãã
ãå¹³ååå°çããèŒå°œæ§èå äœã®èŒå°œçºå æ³¢é·é
åã«ãããå¹³ååå°çãããå°ãããããªåå°ç¹
æ§ãæããçè²å€ãå«æãããŠããŠãããããã®
ãããªçè²å€ãšããŠã¯ãããšãã°ãç¹éæ55â
163500å·å ¬å ±ããã³ç¹éæ57â96300å·å ¬å ±ã«é
瀺ãããŠãããããªçè²å€ãæããããšãã§ã
ãããããã¯ãåããç»åã®é®®é床ãåäžããã
ç®çã§ãå¡åžæ¶²ã«ã¯ç¹éæ55â146447å·å ¬å ±ã«èš
èŒãããŠãããããªçœè²ç²äœãå«æãããŠããŠã
ããã äžèšå¡åžæ¶²ïŒïŒãšã¯å¥ã«ãåèšåž¯é»é²æ¢å€ã
é©åœãªæº¶å€ã«æº¶è§£ãããã¯åæ£ããåŸãçµåå€ã
å ããŠå åã«æ··åãã垯é»é²æ¢å€ãå«æããå¡åž
液ïŒïŒã調補ããã å¡åžæ¶²ïŒïŒã®çµåå€ãšããŠã¯ãäžèšã®èå äœ
局圢æã®ããã®å¡åžæ¶²ïŒïŒã«çšããããçµåå€
ã®ä»ã«ãã»ã«ããŒã¹èªå°äœãããªå¡©åããã«ãã
ãªå¡©åãããªãã³ãããªããã«ãã«ããŒã«ãã¡ã©
ãã³ãããšããŒã«æš¹èããšããã·æš¹èãªã©ãæã
ãããšãã§ãããå¡åžæ¶²ïŒïŒã«çšããããçµå
å€ã¯ãå¡åžæ¶²ïŒïŒã«çšããããçµåå€ãšåäžã§
ãã€ãŠããããããããã¯å šãç°ãªã€ãŠããŠãã
ãããã ããå¡åžæ¶²ïŒïŒã®çµåå€ãšçžæº¶æ§ã®ã
ãçµåå€ã§ããå¿ èŠãããããŸããæŸå°ç·åå€æ
ããã«è¡šé¢ã®é²å·æ§ãªã©ã®ç¹ããã¯å¡åžæ¶²ïŒïŒ
ã®çµåå€ã¯æ¯èŒç硬ããã®ã§ããã®ã奜ãŸããã
äžæ¹ãæ©æ¢°ç匷床ãªã©ã®ç¹ããã¯å¡åžæ¶²ïŒïŒã®
çµåå€ã¯å¡åžæ¶²ïŒïŒã®çµåå€ãšåäžã§ããã®ã
奜ãŸããã å¡åžæ¶²ïŒïŒã«ãããŠåž¯é»é²æ¢å€ãçµåå€æº¶æ¶²
äžã«å«æãããæ¯çã¯ã垯é»é²æ¢å€ã®çš®é¡ãçµå
å€ã®çš®é¡ããã³è£œé ãããããã«ã®æ§æãªã©ã«ã
ã€ãŠãç°ãªãããäžè¬ã«ã¯çµåå€ã®äœ¿çšéã«å¯Ÿã
ãŠ0.1ä¹è³20ééïŒ ã®ç¯å²ããéžã°ããç¹ã«0.5ä¹
è³ïŒééïŒ ã®ç¯å²ããéžã°ããã®ã奜ãŸããã ãŸãã溶å€ãšããŠã¯ãäžèšã®æº¶å€ãçšããããš
ãã§ããããèå äœå±€ã«ããã垯é»é²æ¢å€ã®åæ£
æ§ã®ç¹ããã垯é»é²æ¢å€ã§ããéå±ç¡æ©å¡©ã溶解
ããããããªæº¶å€ãçšããã®ã奜ãŸããããŸãã
å¡åžæ¶²ïŒïŒã®æº¶å€ã¯å¡åžæ¶²ïŒïŒã«çšãããã
溶å€ãšåäžã§ãã€ãŠããããããããã¯ç°ãªã€ãŠ
ããŠããããäœããå¡åžæ¶²ïŒïŒããã³ïŒïŒã
éå±€ãããŠãªãå¡èã®ä¹Ÿç¥é床ãäžèŽãããå¿ èŠ
ãããäºãã«çžæº¶æ§ã®ãã溶å€ãçšããããšãæ
ãŸããã ããã«ãå¡åžæ¶²ïŒïŒã«ã¯äžèšå¡åžæ¶²ïŒïŒã«
çšããããåçš®ã®åæ£å€ãå¯å¡å€ãçè²å€ãªã©ã
å«æãããŠããŠãããã äžèšã®ããã«ããŠèª¿è£œãããå¡åžæ¶²ïŒïŒãšå¡
åžæ¶²ïŒïŒãšããå¡åžæ¶²ïŒïŒãæ¯æäœåŽã«é 眮
ããŠæ¯æäœã®è¡šé¢ã«åäžã«åæã«éå±€å¡åžããã
ãšã«ããã垯é»é²æ¢å€ãå«æãããéšåãããã«
è¡šé¢åŽãšãªãããã«å¡åžæ¶²ã®å¡èã圢æãããã
ã®å¡åžæäœã¯ãããšãã°ãäºé£åŒããããŒåå¡åž
è£ çœ®ãçšããããšã«ããè¡ãªãããšãã§ããã å¡åžæ¶²ïŒïŒããã³å¡åžæ¶²ïŒïŒã®å¡åžéã¯ã
ç®çãšããæŸå°ç·åå€æããã«ã®ç¹æ§ãå¡åžæ¶²ã®
ç²åºŠãçµåå€ãšèå äœãšã®æ··åæ¯ãªã©ã«ãã€ãŠç°
ãªãããéåžžã¯100ïŒïŒä¹è³ïŒïŒïŒïŒäœç©æ¯ïŒã®ç¯
å²ããéžã°ãã奜ãŸããã¯10ïŒïŒä¹è³ïŒïŒïŒã®ç¯
å²ã§ããããŸããäž¡å¡åžæ¶²ãéããŠåž¯é»é²æ¢å€ã®
çµåå€ã«å¯Ÿããæ¯çã¯ãäžè¬ã«0.03ä¹è³ïŒééïŒ
ã®ç¯å²ããéžã°ããç¹ã«0.1ä¹è³ïŒééïŒ ã®ç¯å²
ããéžã°ããã®ã奜ãŸããã ã€ãã§ã圢æãããæ¯æäœåŽã®å¡åžæ¶²ïŒïŒã®
å¡èããã³ãã®äžã«åœ¢æãããå¡åžæ¶²ïŒïŒã®å¡
èãåŸã ã«å ç±ããããšã«ãã也ç¥ããŠãæ¯æäœ
äžãžã®èå äœå±€ã®åœ¢æãå®äºããããã®ããã«ã
ãŠåœ¢æãããèå äœå±€ã¯ãæ¯æäœåŽã®èå äœç²å
ãåæ£ç¶æ ã§ååšããéšåãšãããã«è¡šé¢åŽã®åž¯
é»é²æ¢å€ãå«æãããéšåãšããæ§æãããé»å
é¡åŸ®é¡çã§èŠèŠçã«èŠ³å¯ããŠãäž¡éšåã«ã¯å¢çé¢
ããªããäžå±€ã®èå äœå±€ã圢æããŠããã ãŸããèå äœå±€ã¯ãå¿ ãããäžèšã®ããã«æ¯æ
äœäžã«å¡åžæ¶²ãçŽæ¥å¡åžããŠåœ¢æããå¿ èŠã¯ãª
ããããšãã°ãå¥ã«ã¬ã©ã¹æ¿ãéå±æ¿ããã©ã¹ã
ãã¯ã·ãŒããªã©ã®å¹³é¢ã·ãŒãäžã«å¡åžæ¶²ãäžè¿°ã®
ããã«ããŠåæéå±€å¡åžããããšã«ããèå äœå±€
ã圢æããåŸããããæ¯æäœäžã«æŒå§ããããã
ããã¯æ¥çå€ãçšãããªã©ããŠæ¯æäœãšèå äœå±€
ãšãæ¥åããŠãããããã®å Žåã«ãå¡åžæ¶²ïŒïŒ
ãšå¡åžæ¶²ïŒïŒã¯ææãšããæŸå°ç·åå€æããã«
ã®ç¹æ§ãå¡åžæ¡ä»¶ãªã©ã«å¿ããŠãã©ã¡ããå¹³é¢ã·
ãŒãåŽã«é 眮ããŠéå±€å¡åžãè¡ã€ãŠãããã èå äœå±€ã®å±€åã¯ãç®çãšããæŸå°ç·åå€æã
ãã«ã®ç¹æ§ãèå äœã®çš®é¡ãçµåå€ãšèå äœãšã®
æ··åæ¯ãªã©ã«ãã€ãŠç°ãªãããéåžžã¯20ÎŒïœä¹è³
ïŒmmãšããããã ãããã®å±€åã¯50ä¹è³500ÎŒïœ
ãšããã®ã奜ãŸããããŸãããã®ãã¡ããã«è¡šé¢
åŽã®åž¯é»é²æ¢å€ãå«æãããéšåã¯çŽïŒä¹è³20ÎŒ
ïœã®åããæããããšã奜ãŸãããæ¯æäœåŽã®èŒ
å°œæ§èå äœãååšããéšåãšããã«è¡šé¢åŽã®åž¯é»
é²æ¢å€ãå«æãããéšåãšã®æ¯çã¯ãå±€åïŒå¹³
åïŒã§100ïŒïŒãïŒïŒïŒã®ç¯å²ã«ããããšã奜ãŸ
ããã æ¬çºæã«ãããŠäœ¿çšããæ¯æäœã¯ãåŸæ¥ã®æŸå°
ç·åçæ³ã«ãããå¢æçŽã®æ¯æäœãšããŠçšããã
ãŠããåçš®ã®ææãããã¯æŸå°ç·åå€æããã«ã®
æ¯æäœãšããŠå ¬ç¥ã®åçš®ã®ææããä»»æã«éžã¶ã
ãšãã§ããããã®ãããªææã®äŸãšããŠã¯ãã»ã«
ããŒã¹ã¢ã»ããŒããããªãšã¹ãã«ãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããããªã¢ãããããªã€ãããããª
ã¢ã»ããŒããããªã«ãŒãããŒããªã©ã®ãã©ã¹ãã
ã¯ç©è³ªã®ãã€ã«ã ãã¢ã«ãããŠã ç®ãã¢ã«ãããŠ
ã åéç®ãªã©ã®éå±ã·ãŒããéåžžã®çŽããã©ã€ã¿
çŽãã¬ãžã³ã³ãŒãçŽãäºé žåãã¿ã³ãªã©ã®é¡æã
å«æãããã°ã¡ã³ãçŽãããªããã«ã¢ã«ã³ãŒã«ãª
ã©ããµã€ãžã³ã°ããçŽãªã©ãæããããšãã§ã
ãããã ããæŸå°ç·åå€æããã«ã®æ å ±èšé²ææ
ãšããŠã®ç¹æ§ããã³åæ±ããªã©ãèæ ®ããå Žåã
æ¬çºæã«ãããŠç¹ã«å¥œãŸããæ¯æäœã®ææã¯ãã©
ã¹ããã¯ãã€ã«ã ã§ããããã®ãã©ã¹ããã¯ãã€
ã«ã ã«ã¯ã«ãŒãã³ãã©ãã¯ãªã©ã®å åžåæ§ç©è³ªã
ç·Žã蟌ãŸããŠããŠãããããããã¯äºé žåãã¿ã³
ãªã©ã®å åå°æ§ç©è³ªãç·Žã蟌ãŸããŠããŠãããã
åè ã¯é«é®®é床ã¿ã€ãã®æŸå°ç·åå€æããã«ã«é©
ããæ¯æäœã§ãããåŸè ã¯é«æ床ã¿ã€ãã®æŸå°ç·
åå€æããã«ã«é©ããæ¯æäœã§ããã å ¬ç¥ã®æŸå°ç·åå€æããã«ã«ãããŠã¯ãæ¯æäœ
ãšèå äœå±€ã®çµåã匷åããããããããã¯æŸå°
ç·åå€æããã«ãšããŠã®æ床ãããã¯ç»è³ªïŒé®®é
床ãç²ç¶æ§ïŒãåäžãããããã«ãèå äœå±€ãèš
ããããåŽã®æ¯æäœè¡šé¢ã«ãŒã©ãã³ãªã©ã®é«åå
ç©è³ªãå¡åžããŠæ¥çæ§ä»äžå±€ãšãããããããã¯
äºé žåãã¿ã³ãªã©ã®å åå°æ§ç©è³ªãããªãå åå°
å±€ããããã¯ã«ãŒãã³ãã©ãã¯ãªã©ã®å åžåæ§ç©
質ãããªãå åžåå±€ãèšããããšãè¡ãªãããŠã
ããæ¬çºæã§çšããããæ¯æäœã«ã€ããŠãããã
ãã®åçš®ã®å±€ãèšããããšãã§ãããããã®æ§æ
ã¯ææã®æŸå°ç·åå€æããã«ã®ç®çãçšéãªã©ã«
å¿ããŠä»»æã«éžæããããšãã§ããã ããã«ãç¹éæ58â200200å·å ¬å ±ã«èšèŒãããŠ
ããããã«ãåŸãããç»åã®é®®é床ãåäžããã
ç®çã§ãæ¯æäœã®èå äœå±€åŽã®è¡šé¢ïŒæ¯æäœã®è
å äœå±€åŽã®è¡šé¢ã«æ¥çæ§ä»äžå±€ãå åå°å±€ããã
ã¯å åžåå±€ãªã©ãèšããããŠããå Žåã«ã¯ããã®
è¡šé¢ãæå³ããïŒã«ã¯ã埮现ãªå¹åžãå質ã«åœ¢æ
ãããŠããŠãããã 次ã«æ¬çºæã®å®æœäŸããã³æ¯èŒäŸãèšèŒããã
ãã ãããããã®åäŸã¯æ¬çºæãå¶éãããã®ã§
ã¯ãªãããªãã以äžã®åäŸã§ãéšãã¯ç¹ã«èšèŒã®
ãªãéããéééšããè¡šããã å®æœäŸ ïŒ ããªãŠã¬ã¿ã³æš¹èïŒãã¹ã¢ã©ãã¯4125ãäœåã
ã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒãã¡ãã«ãšãã«ã±ãã³ãšã€
ãœãããã«ã¢ã«ã³ãŒã«ã®æ··å溶åªã«æº¶è§£ããŠããª
ãŠã¬ã¿ã³æš¹è溶液ã調補ããããŸãããããã»ã«
ããŒã¹ïŒRSâ120ããã€ã»ã«ååŠå·¥æ¥(æ ª)補ïŒãã¡
ãã«ãšãã«ã±ãã³ãšã€ãœãããã«ã¢ã«ã³ãŒã«ã®æ··
å溶åªã«æº¶è§£ããŠãããã»ã«ããŒã¹æº¶æ¶²ã調補ã
ããèŒå°œæ§ã®äºäŸ¡ãŠãŒãããŠã 賊掻åŒåèåããª
èå äœïŒBaFBrïŒEu2+ïŒã®ç²åãã¡ãã«ãšãã«
ã±ãã³ãšã€ãœãããã«ã¢ã«ã³ãŒã«ã®æ··å溶åªã«å
æ£ããã®ã¡ããã®åæ£æ¶²ã«äžèšããªãŠã¬ã¿ã³æš¹è
溶液ããã³ãããã»ã«ããŒã¹æº¶æ¶²ãå ããããã«
矀éïŒé¡æïŒPBâ100ã第äžåæå·¥æ¥(æ ª)補ïŒãã
ã³çé žããªã¯ã¬ãžã«ãæ·»å ãããããã©ãããµãŒ
ãçšããŠæº¶è§£ããŠèå äœãå«æããåæ£æ¶²ïŒ»å¡åž
液ïŒïŒïŒœã調補ããã 次ã«ã垯é»é²æ¢å€ãšããŠèåãããªãŠã
ïŒNaBrïŒãã¡ãã«ãšãã«ã±ãã³ãšã€ãœãããã«
ã¢ã«ã³ãŒã«ãšãã®æ··å溶åªã«æ·»å ãå å溶解ãã
ãã®ã¡ããã®æº¶è§£æ¶²ã«ããªãŠã¬ã¿ã³æš¹èïŒãã¹ã¢
ã©ãã¯4125ãäœåãã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒããã
ã»ã«ããŒã¹ïŒRSâ120ããã€ã»ã«ååŠå·¥æ¥(æ ª)補ïŒ
ããã³çé žããªã¯ã¬ãžã«ãæ·»å ãããããã©ãã
ãµãŒãçšããŠæ··åããŠçµåå€æº¶æ¶²ïŒ»å¡åžæ¶²ïŒïŒïŒœ
ã調補ããã å¡åžæ¶²ïŒïŒããã³å¡åžæ¶²ïŒïŒã®çµæãäžèš
ã«ç€ºãã å¡åžæ¶²ïŒïŒã®çµæ BaFBrïŒEu2+èå äœ 800éš ããªãŠã¬ã¿ã³æš¹è 83.1éš ãããã»ã«ããŒã¹ 52éš çŸ€ é 0.052éš çé žããªã¯ã¬ãžã« 2.6éš ã¡ãã«ãšãã«ã±ãã³ 204.6éš ã€ãœãããã«ã¢ã«ã³ãŒã« 39.5éš å¡åžæ¶²ïŒïŒã®çµæ ããªãŠã¬ã¿ã³æš¹è 145éš ãããã»ã«ããŒã¹ 9.1éš çé žããªã¯ã¬ãžã« 4.5éš èåãããªãŠã 1.4éš ã¡ãã«ãšãã«ã±ãã³ 287.5éš ã€ãœãããã«ã¢ã«ã³ãŒã« 51.6éš æ¬¡ã«ãã«ãŒãã³ç·Žã蟌ã¿ããªãšãã¬ã³ãã¬ãã¿
ã¬ãŒãã·ãŒãïŒæ¯æäœãåã¿ïŒ250ÎŒïœïŒãã¬ã©
ã¹æ¿äžã«æ°Žå¹³ã«çœ®ããŠãå¡åžæ¶²ïŒïŒããã³å¡åž
液ïŒïŒã第ïŒå³ã«ç€ºããããªäºé£åŒããããŒå
å¡åžè£ 眮ãçšããŠãæ¯æäœäžã«åæã«éå±€å¡åžã
ãã ããªãã¡ã第ïŒå³ã«ãããŠãäºé£åŒããããŒå
å¡åžè£ 眮ïŒã®å³åŽå°å ¥éšïŒã«ã¯å¡åžæ¶²ïŒïŒã泚
å ¥ããå·ŠåŽå°å ¥éšïŒã«ã¯å¡åžæ¶²ïŒïŒãå°å ¥ã
ããå°å ¥éšïŒïŒïŒã®äžéšéå£éšã®é·ãã¯ãããã
0.500mmããã³0.150mmã§ãã€ããæ¯æäœïŒã®çœ®ã
ããã¬ã©ã¹æ¿ïŒã®ç¢å°ïŒã®æ¹åã«1.0ïœïŒåã®é
床ã§ç§»åãããªãããäžéšéå£éšããå¡åžæ¶²
ïŒïŒããã³ïŒïŒãæ¯æäœïŒäžã«åæã«éå±€å¡
åžããŠãå¡åžæ¶²ïŒïŒã®å¡èïŒããã³å¡åžæ¶²
ïŒïŒã®å¡èïŒã圢æããã ãããŠå¡åžåŸã«ãå¡èã®åœ¢æãããæ¯æäœã也
ç¥åšå ã«å ¥ãããã®ä¹Ÿç¥åšã®å éšã®æž©åºŠã25âã
ã100âã«åŸã ã«äžæãããŠ50åéå¡èã®ä¹Ÿç¥ã
è¡ãªã€ãã ãã®ããã«ããŠæ¯æäœäžã«æ¯æäœåŽã®èŒå°œæ§è
å äœã®ååšããéšåã®å±€åãçŽ340ÎŒïœãããã«
è¡šé¢åŽã®åž¯é»é²æ¢å€ãå«æããéšåã®å±€åãçŽ
7ÎŒïœã®èå äœå±€ã圢æããæ¯æäœããã³èå äœ
å±€ããæ§æãããæŸå°ç·åå€æããã«ã補é ã
ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã«èåãããª
ãŠã ãæ·»å ããªãããšä»¥å€ã¯å®æœäŸïŒãšåæ§ã®æ¹
æ³ã«ãããæ¯æäœããã³èå äœå±€ããæ§æããã
æŸå°ç·åå€æããã«ã補é ããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®ã¿ãçšãã
äºé£åŒããããŒåå¡åžè£ 眮ã®å°å ¥éšïŒïŒäžéšéå£
éšã®é·ãïŒ0.500mmïŒã®ã¿ã䜿çšããããšä»¥å€ã¯
å®æœäŸïŒãšåæ§ã®æ¹æ³ã«ãããæ¯æäœäžã«å±€åã
çŽ340ÎŒïœã®èå äœå±€ã圢æããã 次ã«ããã®èå äœå±€ã®äžã«ããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒãã®éæãã€ã«ã ïŒä¿è·èãåã¿ïŒ7ÎŒïœã
ããªãšã¹ãã«ç³»æ¥çå€ãä»äžãããŠãããã®ïŒã
æ¥çå€å±€åŽãäžã«åããŠçœ®ããŠ90ã100âã®å ç±
ããŒã«ãçšããŠå§çããããšã«ãããéæä¿è·è
ãä»èšããæ¯æäœãèå äœå±€ããã³éæä¿è·èã
ãæ§æãããæŸå°ç·åå€æããã«ã補é ããã å®æœäŸïŒãæ¯èŒäŸïŒããã³æ¯èŒäŸïŒã§åŸããã
åæŸå°ç·åå€æããã«ãã次ã«èšèŒããè¡šé¢æµæ
è©Šéšããã³æ¬éæ§è©Šéšã«ããè©äŸ¡ããã (1) è¡šé¢æµæè©Šéš åé»æ¥µïŒïŒ°â601åãå·å£é»æ°è£œäœæ(æ ª)補ïŒ
ãšçµ¶çžèšïŒEVâ40åè¶ çµ¶çžèšãå·å£é»æ°è£œäœ
æ(æ ª)補ïŒãšãçµåãã110mmÃ110mmã®ãµã€ãºã«
è£æããæŸå°ç·åå€æããã«ãåé»æ¥µã®äžã«èŒ
ããé»å§ãå°å ããŠããã«ã®è¡šé¢ã®é»æ°æµæã
枬å®ããããªãã枬å®ã¯æž©åºŠ23âã湿床50ïŒ
RHã®æ¡ä»¶ã§è¡ãªã€ãã (2) æ¬éæ§è©Šéš æŸå°ç·åå€æããã«ãæŸå°ç·åèšé²èªåè£ çœ®
å ãæ¬éãããããšã«ããã移åãç©å±€ã®ãµã€
ã¯ã«ã100åç¹°ãè¿ãè¡ãªããäºæã®ããã«ã
åæã«æ¬éããåæ°ã枬å®ããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
ææ¹æ³ã«çšããããæŸå°ç·åå€æããã«ã«é¢ãã
ãã®ã§ãããããã«è©³ããã¯ãæ¬çºæã¯ãæ¯æäœ
ãšããã®äžã«èšããããèŒå°œæ§èå äœãå«ææ¯æ
ããçµåå€ãããªãèå äœå±€ãšãæããæŸå°ç·å
å€æããã«ã«é¢ãããã®ã§ããã çºæã®æè¡çèæ¯ããã³åŸæ¥æè¡ïŒœ æŸå°ç·åãç»åãšããŠåŸãæ¹æ³ãšããŠãåŸæ¥ã
ãéå¡©æå ææãããªãä¹³å€å±€ãæããæŸå°ç·å
çãã€ã«ã ãšå¢æçŽãšã®çµã¿åãããçšãããã
ãããæŸå°ç·åçæ³ãå©çšãããŠãããæè¿ãäž
èšæŸå°ç·åçæ³ã«ä»£ãæ¹æ³ã®äžã€ãšããŠãããšã
ã°ç¹éæ55â12145å·å ¬å ±ãªã©ã«èšèŒãããŠãã
ãããªãèŒå°œæ§èå äœãçšããæŸå°ç·åå€ææ¹æ³
ã泚ç®ãããããã«ãªã€ãããã®æŸå°ç·åå€ææ¹
æ³ã¯ãèŒå°œæ§èå äœãæããæŸå°ç·åå€æããã«
ïŒèç©æ§èå äœã·ãŒãïŒãå©çšãããã®ã§ã被å
äœãééããæŸå°ç·ããããã¯è¢«æ€äœããçºãã
ããæŸå°ç·ã該ããã«ã®èŒå°œæ§èå äœã«åžåã
ãããã®ã®ã¡ã«èŒå°œæ§èå äœãå¯èŠå ç·ãèµ€å€ç·
ãªã©ã®é»ç£æ³¢ïŒå±èµ·å ïŒã§æç³»åçã«å±èµ·ããã
ãšã«ããã該èŒå°œæ§èå äœäžã«èç©ãããŠããæŸ
å°ç·ãšãã«ã®ãŒãèå ïŒèŒå°œçºå ïŒãšããŠæŸåºã
ãããã®èå ãå é»çã«èªã¿åã€ãŠé»æ°ä¿¡å·ã
åŸããããŠåŸãããé»æ°ä¿¡å·ãç»ååãããã®ã§
ããã äžè¿°ã®æŸå°ç·åå€ææ¹æ³ã«ããã°ãåŸæ¥ã®æŸå°
ç·åçæ³ã«ããå Žåã«æ¯èŒããŠãã¯ããã«å°ãªã
被æç·éã§æ å ±éã®è±å¯ãªæŸå°ç·ç»åãåŸãããš
ãã§ãããšããå©ç¹ããããåŸã€ãŠããã®æŸå°ç·
åå€ææ¹æ³ã¯ãç¹ã«å»ç蚺æãç®çãšããç·æ®
圱çã®çŽæ¥å»ççšæŸå°ç·æ®åœ±ã«ãããŠå©çšäŸ¡å€ã®
éåžžã«é«ããã®ã§ããã äžèšæŸå°ç·åå€ææ¹æ³ã«çšããæŸå°ç·åå€æã
ãã«ã¯ãåºæ¬æ§é ãšããŠãã©ã¹ããã¯ã·ãŒãçã®
æ¯æäœãšããã®çé¢ã«èšããããèŒå°œæ§èå äœã
åæ£ç¶æ ã§å«ææ¯æããæ¯æäœãããªãèå äœå±€
ãšãããªããã®ã§ããããããŠããã®èå äœå±€ã®
æ¯æäœãšã¯å察åŽã®è¡šé¢ïŒæ¯æäœã«é¢ããŠãªãåŽ
ã®è¡šé¢ïŒã«ã¯éåžžãèå äœå±€ãååŠçãªå€è³ªãã
ãã¯ç©ççãªè¡æããä¿è·ãããã€ããã«è¡šé¢ã
å¹³æ»åããããã«ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããª
ã©ã®éæãªä¿è·èãèšããããŠããã æŸå°ç·åå€ææ¹æ³ã®å®æœã«ãããŠãæŸå°ç·åå€
æããã«ã¯ãæŸå°ç·ã®ç §å°ïŒæŸå°ç·åã®èšé²ïŒã»
å±èµ·å ã®ç §å°ïŒèšé²ãããæŸå°ç·åã®èªåãïŒã»
æ¶å»å ã®ç §å°ïŒæ®åããæŸå°ç·åã®æ¶å»ïŒãšãã
ãµã€ã¯ã«ã§ç¹°ãè¿ã䜿çšãããããããŠæŸå°ç·å
å€æããã«ã®åã¹ããããžã®ç§»è¡ã¯æ¬éç³»ã«ãã
è¡ãªãããïŒãµã€ã¯ã«çµäºåŸããã«ã¯é 次ç©å±€ã
ãŠä¿åãããã ãã®æ¬éããç©å±€ç¶æ ãžãšç§»è¡ããé£ç¶ãããµ
ã€ã¯ã«ã«ãããŠããã®éã«æŸå°ç·åå€æããã«å
å¿ã®æ¥è§Šãæ©æŠãç¹°ãè¿ãçããããã«é«ååç©
質ãããªãããã«ã®è¡šé¢ïŒèå äœå±€åŽè¡šé¢ïŒã垯
é»ãå®ãããã®ããšãæŸå°ç·åå€ææ¹æ³ã®å®æœäž
çš®ã ã®åé¡ãçºçãããåå ãšãªã€ãŠããã ããšãã°ãæŸå°ç·åå€æããã«ã®è¡šé¢ã垯é»ã
ãçµæãããã«ãç©å±€ç¶æ ããæ¬éç³»ã«ç§»ãé
ã«ãããã«è¡šé¢ãšä»ã®ããã«ã®è£é¢ïŒæ¯æäœåŽè¡š
é¢ïŒãšãçžäºã«å¯çããŠäºæéãªã€ãç¶æ ã§æ¬é
ç³»ã«éã蟌ãŸãããããªãããã以åŸã®æ£åžžãªæ
äœãè¡ãªãããšãäžå¯èœãšãªããã®ã§ããããŸ
ããããã«è¡šé¢ã«ã¯ç©ºæ°äžã®å¡µåãä»çãããã
ãªãããã®ãããªããã«ã«ãããŠã¯èªã¿åºãã®é
ã«è¡šé¢ã«ä»çãã塵åã«ãã€ãŠå±èµ·å ãæ£ä¹±ãã
ãããã«ãåŸãããç»åã¯ç»è³ªãèããäœäžãã
ãã®ãšãªãã ãšããã§ãèå äœå±€ã¯äžè¬ã«ãèŒå°œæ§èå äœã®
ç²åãšçµåå€ãšãé©åœãªæº¶å€ã«å ããŠèå äœãçµ
åå€æº¶æ¶²ã«åäžã«åæ£ããå¡åžæ¶²ãçšæãããã®
å¡åžæ¶²ããã¯ã¿ãŒãã¬ãŒããããŒã«ã³ãŒã¿ãŒãªã©
ãçšããŠæ¯æäœäžã«çŽæ¥å¡åžããã®ã¡ä¹Ÿç¥ããã
ãšã«ããããããã¯å¥ã®ã·ãŒãã«å¡åžããŠåœ¢æã
ãèå äœå±€ãæ¯æäœãšæ¥åããããšã«ãããæ¯æ
äœäžã«ä»èšãããŠãããåŸã€ãŠãèŒå°œæ§èå äœç²
åã¯èå äœå±€äžã«ã»ãŒåäžã«åæ£ããŠååšããŠã
ãã ããã«ããã®èå äœå±€è¡šé¢ã«ã¯äžè¬ã«ãéæãª
é«ååç©è³ªãããªã溶液ãå¡åžããããšã«ããã
ãããã¯å¥é圢æããéæãªèèãæ¥çå€çãçš
ããŠæ¥çããããšã«ããä¿è·èãèšããããŠã
ãã æ¬åºé¡äººã¯ãèŒå°œæ§èå äœãåæ£ããŠãªãçµå
å€æº¶æ¶²ãšèŒå°œæ§èå äœãå«æããªãçµåå€æº¶æ¶²ãš
ãçšããŠåæã«éå±€å¡åžããããšã«ãããæ¯æäœ
äžã«ãèŒå°œæ§èå äœãååšããéšåãšèŒå°œæ§èå
äœãå®è³ªçã«ååšããªãéšåãšããæ§æãããè
å äœå±€ãèšããæ¹æ³ããã³æŸå°ç·åå€æããã«ã«
ã€ããŠæ¢ã«ç¹èš±åºé¡ããŠããïŒç¹é¡æ59â182212
å·ïŒãåŸã€ãŠããã®æ¹æ³ã«ãã補é ãããããã«
ã«ãããŠã¯ãå¡èã®çé¢ã圢æããããèå äœå±€
ãä¿è·èãšããŠã®æ©èœãæããŠããã çºæã®ç®ç æ¬çºæã¯ã垯é»é²æ¢å¹æãåªããæŸå°ç·åå€æ
ããã«ããã³ãã®è£œé æ³ãæäŸããããšããã®ç®
çãšãããã®ã§ããã ãŸããæ¬çºæã¯ãç¹ã«æ¬éç¹æ§ãåäžããæŸå°
ç·åå€æããã«ããã³ãã®è£œé æ³ãæäŸããããš
ããã®ç®çãšãããã®ã§ããã äžèšã®ç®çã¯ãæ¯æäœãšããã®äžã«èšãããã
èŒå°œæ§èå äœãå«ææ¯æããçµåå€ãããªãèå
äœå±€ãšãæããæŸå°ç·åå€æããã«ã«ãããŠã該
èå äœå±€ãæ¯æäœåŽã®èŒå°œæ§èå äœãååšããéš
åãšããã«è¡šé¢åŽã®èŒå°œæ§èå äœãååšããªãéš
åãšããæ§æãããäž¡éšåã®éã«å¢çé¢ãååšã
ãããã€è©²èŒå°œæ§èå äœãå®è³ªçã«ååšããªãéš
åã«éå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«æãã
ãŠããããšãç¹åŸŽãšããæ¬çºæã®æŸå°ç·åå€æã
ãã«ã«ããéæããããšãã§ããããªããäžèšã®
ãããã«è¡šé¢åŽã®èŒå°œæ§èå äœãååšããªãããš
ã¯ãèŒå°œæ§èå äœç²åã埮éæ··å ¥ããŠããç¶æ ã
æé€ãããã®ã§ã¯ãªãã ãŸããäžèšã®ç®çã¯ã (1) èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãšéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«
æããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«
çžæº¶æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§è©²
èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²ïŒïŒ
ãæ¯æäœåŽãšãªãããã«æ¯æäœè¡šé¢ã«åæã«é
å±€å¡åžããããšãç¹åŸŽãšããæ¬çºæã®æŸå°ç·å
å€æããã«ã®è£œé æ³ãããã³ (2) èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«
æããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«
çžæº¶æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§å¹³
é¢ã·ãŒãäžã«åæã«éå±€å¡åžããŠèå äœå±€ã圢
æããã®ã¡ã該èå äœå±€ãã·ãŒãããåé¢ããŠ
æ¯æäœäžã«ä»èšããããšãç¹åŸŽãšããæŸå°ç·å
å€æããã«ã®è£œé æ³ã ã«ããæå©ã«éæããããšãã§ããã ãªããæ¬çºæã«ãããŠããã«è¡šé¢åŽãšã¯ãèå
äœå±€ã®æ¯æäœã«æ¥ããåŽãšã¯å察åŽãæå³ããã çºæã®å¹æ æ¬çºæã¯ãèŒå°œæ§èå äœãšçµåå€ãšãããªãæŸ
å°ç·åå€æããã«ã®èå äœå±€ã«ãããŠãèŒå°œæ§è
å äœç²åãæ¯æäœåŽã®äžå®é åå ã«ã®ã¿åæ£ç¶æ
ã§ååšãããäžæ¹ãããã«è¡šé¢åŽã®äžå®é åå ã«
ã¯å®è³ªçã«èå äœç²åãååšãããªãã§åž¯é»é²æ¢
å€ã®ã¿ãå«æãããããšã«ãããæ¬éç³»ã«ããã
垯é»çŸè±¡ãé²æ¢ããåæ»ãªæŸå°ç·åã®èšé²åçã
å®çŸãããã®ã§ããã åŸæ¥ã«ãããŠã¯äžè¬ã«ãèå äœç²åãåäžã«å
æ£ããçµåå€æº¶æ¶²ïŒå¡åžæ¶²ïŒãéåžžã®å¡åžæ¹æ³ã«
ãã€ãŠæ¯æäœäžã«å¡åžããããšã«ããèå äœå±€ã®
圢æãè¡ãªãããŠããçµæãèå äœç²åã¯çµåå€
ã«ããèå äœå±€å šäœã«æž¡ã€ãŠåæ£ç¶æ ã§å«ææ¯æ
ãããŠããã æ¬çºæã«ãããŠã¯ãèå äœç²åãåæ£ããŠãªã
å¡åžæ¶²ïŒïŒãšãèå äœç²åãå«ãŸãªãã§åž¯é»é²
æ¢å€ã®ã¿ãå«æããçµåå€æº¶æ¶²ïŒïŒãšãã該å¡
åžæ¶²ïŒïŒãæ¯æäœåŽã«é 眮ããŠåæã«æ¯æäœäž
ã«éå±€ããŠå¡åžããããšã«ãããèå äœå±€ã®æ·±ã
æ¹åã«åž¯é»é²æ¢å€ãåæ£ç¶æ ã§ååšããçµåå€éš
åãšèå äœç²åãåæ£ç¶æ ã§ååšããéšåãšã圢
æããããšãã§ããã ããªãã¡ãèå äœç²åãèå äœå±€ã®æ¯æäœåŽã®
äžå®é åã«åæ£ç¶æ ã§ååšãããããšå察ã®ãã
ã«è¡šé¢åŽã®äžå®é åã«ã¯åž¯é»é²æ¢å€ãåæ£ç¶æ ã§
ååšãããã€èå äœç²åãå®è³ªçã«ååšããªãè
å äœå±€ã圢æããããåŸã€ãŠã垯é»é²æ¢å€ãå«æ
ããéšåã¯åŸãããæŸå°ç·åå€æããã«ã®è¡šé¢åŽ
ã«åœ¢æãããããã垯é»çŸè±¡ãå¹æçã«é²æ¢ãã
ããšãã§ããã ãŸãããã®åž¯é»é²æ¢å€ãå«æããéšåã¯å¹³æ ãª
è¡šé¢ãæãããšãšãã«ãèå äœãååŠçå€åãã
ã³ç©ççè¡æããä¿è·ããããã®ä¿è·èãšåæ§ã®
圹å²ãæãããšãã§ããããã«ãåŸæ¥ã®ããã«è
å äœå±€äžã«å¥å·¥çšãšããŠä¿è·èãèšããå¿ èŠããª
ããæŸå°ç·åå€æããã«ã®è£œé å·¥çšãç°¡ç¥åãã
ããšãã§ããã ãŸãããã®ããšã¯ãåŸæ¥ã®æŸå°ç·åå€æããã«
ã«ãããããã«ãä¿è·èã®ä»èšã«ãã€ãŠèå äœå±€
ãšä¿è·èãšã®éã«ããããã¯æ¥çå€å±€ãä»ããŠä»
èšããå Žåã«ã¯èå äœå±€ãæ¥çå€å±€ããã³ä¿è·è
ã®åå±€éã«ãçé¢ã圢æãããããšããªãããšã
æå³ãããåŸã€ãŠãããã«ã®æ©æ¢°ç匷床ïŒå¯ç匷
床ãªã©ïŒãåäžãããããšãã§ããã ããã«ããããçé¢ã§å±èµ·å ã®æ£ä¹±ãçããã
ãšããªããé®®é床ããã³ç²ç¶æ§ãªã©ç»è³ªã®åäžã
ãç»åãåŸãããšãå¯èœã§ãããåæã«ããã®ç
é¢ã§ã®èå ã®æ£ä¹±ãçããããšããªããããç»è³ª
ã®åäžãšãšãã«æ床ãå¢å€§ãããããšãå¯èœã§ã
ãã çºæã®æ§æ 以äžè¿°ã¹ããããªå¥œãŸããç¹æ§ããã€ãæ¬çºæ
ã®æŸå°ç·åå€æããã«ã¯ãããšãã°ã次ã«è¿°ã¹ã
ãããªè£œé æ³ã«ãã補é ããããšãã§ããã æ¬çºæã®ç¹åŸŽçãªèŠä»¶ã§ããèå äœå±€ã¯ãå®è³ª
çã«æ¯æäœåŽã®èŒå°œæ§èå äœã®ç²åãå«æããéš
åãšãããã«è¡šé¢åŽã®åž¯é»é²æ¢å€ãå«æããéšå
ãšãããªãå±€ã§ããããšãã«çµåå€ã«ããæ¯æã
ããŠãªãå±€ã§ããã èŒå°œæ§èå äœã¯ãå ã«è¿°ã¹ãããã«æŸå°ç·ãç §
å°ããåŸãå±èµ·å ãç §å°ãããšèŒå°œçºå ã瀺ãè
å äœã§ããããå®çšçãªé¢ããã¯æ³¢åœ¢ã400ã
900nïœã®ç¯å²ã«ããå±èµ·å ã«ãã€ãŠ300ã500nïœ
ã®æ³¢é·ç¯å²ã®èŒå°œçºå ã瀺ãèå äœã§ããããšã
æãŸããã æ¬çºæã®æŸå°ç·åå€æããã«ã«çšããããèŒå°œ
æ§èå äœã®äŸãšããŠã¯ã ç±³åœç¹èš±ç¬¬3859527å·æ现æžã«èšèŒãããŠãã
SrSïŒCeãSmãSrSïŒEuãSmãThO2ïŒErãã
ãã³La2O2SïŒEuãSmã ç¹éæ55â12142å·å ¬å ±ã«èšèŒãããŠãã
ZnSïŒCuãPbãBaOã»xAl2O3ïŒEuïŒãã ãã0.8
ïŒïœâŠ10ïŒãããã³ãMãã»xSiO2ïŒïŒ¡ïŒãã ãã
Mãã¯MgãCaãSrãZnãCdããŸãã¯Baã§ããã
ã¯CeãTbãEuãTmãPbãTlãBiããŸãã¯
Mnã§ãããïœã¯ã0.5âŠïœâŠ2.5ã§ããïŒã ç¹éæ55â12143å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-X-yãMgxãCayïŒFXïŒaEu2+ïŒãã ãã
ã¯Clããã³Brã®ãã¡ã®å°ãªããšãäžã€ã§ããã
ïœããã³ïœã¯ãïŒïŒïœïŒïœâŠ0.6ããã€xyâ ïŒã§
ãããïœã¯ã10-6âŠïœâŠïŒÃ10-2ã§ããïŒã ç¹éæ55â12144å·å ¬å ±ã«èšèŒãããŠãã
LnOXïŒxAïŒãã ããLnã¯LaããGdãããã³
Luã®ãã¡ã®å°ãªããšãäžã€ãã¯Clããã³Brã®
ãã¡ã®å°ãªããšãäžã€ãã¯Ceããã³Tbã®ãã¡
ã®å°ãªããšãäžã€ããããŠãïœã¯ãïŒïŒïœïŒ0.1
ã§ããïŒã ç¹éæ55â12145å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãM2+ xïŒFXïŒyAïŒãã ããM2+ã¯Mgã
CaãSrãZnãããã³Cdã®ãã¡ã®å°ãªããšãäž
ã€ãã¯ClãBrãããã³ïŒ©ã®ãã¡ã®å°ãªããšã
äžã€ãã¯EuãTbãCeãTmãDyãPrãHoã
NdãYbãããã³Erã®ãã¡ã®å°ãªããšãäžã€ãã
ããŠïœã¯ãïŒâŠïœâŠ0.6ãïœã¯ãïŒâŠïœâŠ0.2ã§ã
ãïŒã ç¹éæ55â160078å·å ¬å ±ã«èšèŒãããŠããMã
FXã»xAïŒyLnãã ããMãã¯BaãCaãSrã
MgãZnãããã³Cdã®ãã¡ã®å°ãªããšãäžçš®ã
ã¯BeOãMgOãCaOãSrOãBaOãZnOã
Al2O3ãY2O3ãLa2O3ãIn2O3ãSiO2ãTiO2ã
ZrO2ãGeO2ãSnO2ãNb2O5ãTa2O5ãããã³
ThO2ã®ãã¡ã®å°ãªããšãäžçš®ãLnã¯EuãTbã
CeãTmãDyãPrãHoãNdãYbãErãSmã
ããã³Gdã®ãã¡ã®å°ãªããšãäžçš®ãã¯Clã
Brãããã³ïŒ©ã®ãã¡ã®å°ãªããšãäžçš®ã§ããã
ïœããã³ïœã¯ããããïŒÃ10-5âŠïœâŠ0.5ããã
ã³ïŒïŒïœâŠ0.2ã§ããã®çµæåŒã§è¡šããããè
å äœã ç¹éæ56â116777å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzAãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ãã¯ãžã«ã³ããŠã ãã
ã³ã¹ã«ã³ãžãŠã ã®ãã¡ã®å°ãªããšãäžçš®ã§ããã
ïœãïœãïœãããã³ïœã¯ãããã0.5âŠïœâŠ1.25ã
ïŒâŠïœâŠïŒã10-6âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœ
âŠ10-2ã§ããã®çµæåŒã§è¡šããããèå äœã ç¹éæ57â23673å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzBãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ã§ãããïœãïœãïœãã
ãã³ïœã¯ãããã0.5âŠïœâŠ1.25ãïŒâŠïœâŠïŒã
10-6âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœâŠïŒÃ10-1ã§
ããã®çµæåŒã§è¡šããããèå äœã ç¹éæ57â23675å·å ¬å ±ã«èšèŒãããŠãã
ïŒBa1-xãMãïœïŒF2ã»aBaX2ïŒyEuãzAãã ãã
Mãã¯ããªãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ã
ã¹ããã³ããŠã ãäºéãããã³ã«ãããŠã ã®ãã¡
ã®å°ãªããšãäžçš®ãã¯å¡©çŽ ãèçŽ ãããã³æ²çŽ
ã®ãã¡ã®å°ãªããšãäžçš®ãã¯ç çŽ ããã³ç¡ çŽ ã®
ãã¡ã®å°ãªããšãäžçš®ã§ãããïœãïœãïœããã
ã³ïœã¯ãããã0.5âŠïœâŠ1.25ãïŒâŠïœâŠïŒã10-6
âŠïœâŠïŒÃ10-1ãããã³ïŒïŒïœâŠïŒÃ101ã§ãã
ã®çµæåŒã§è¡šããããèå äœã ç¹éæ58â69281å·å ¬å ±ã«èšèŒãããŠããMã
OXïŒxCeãã ããMãã¯PrãNdãPmãSmã
EuãTbãDyãHoãErãTmãYbãããã³Biã
ããªã矀ããéžã°ããå°ãªããšãäžçš®ã®äžäŸ¡éå±
ã§ãããã¯Clããã³Brã®ãã¡ã®ããããäžæ¹
ãããã¯ãã®äž¡æ¹ã§ãããïœã¯ïŒïŒïœïŒ0.1ã§ã
ãã®çµæåŒã§è¡šããããèå äœã ç¹éæ58â206678å·å ¬å ±ã«èšèŒãããŠãã
Ba1-xMx/2Lx/2FXïŒyEu2+ãã ããïŒã¯LiãNaã
ãRbãããã³Csãããªã矀ããéžã°ããå°ãª
ããšãäžçš®ã®ã¢ã«ã«ãªéå±ãè¡šããïŒïŒ¬ã¯ãScã
ãLaãCeãPrãNdãPmãSmãGdãTbã
DyãHoãErãTmãYbãLuãAlãGaãInãã
ãã³Tlãããªã矀ããéžã°ããå°ãªããšãäžçš®
ã®äžäŸ¡éå±ãè¡šããïŒïŒžã¯ãClãBrãããã³ïŒ©
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²
ã³ãè¡šããïŒãããŠãïœã¯10-2âŠïœâŠ0.5ãïœã¯
ïŒïŒïœâŠ0.1ã§ããã®çµæåŒã§è¡šããããèå
äœã ç¹éæ59â27980å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xAïŒyEu2+ãã ããã¯ãClãBrãã
ãã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®
ããã²ã³ã§ããïŒïŒ¡ã¯ãããã©ãã«ãªãããŠé žå
åç©ã®çŒæç©ã§ããïŒãããŠãïœã¯10-6âŠïœâŠ
0.1ãïœã¯ïŒïŒïœâŠ0.1ã§ããã®çµæåŒã§è¡šãã
ããèå äœã ç¹éæ59â47289å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xAïŒyEu2+ãã ããã¯ãClãBrãã
ãã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®
ããã²ã³ã§ããïŒïŒ¡ã¯ããããµãã«ãªãã±ã€é žã
ãããµãã«ãªããã¿ã³é žããã³ãããµãã«ãªããž
ã«ã³ããŠã é žã®äžäŸ¡ãããã¯äºäŸ¡éå±ã®å¡©ãããª
ããããµãã«ãªãååç©çŸ€ããéžã°ããå°ãªããš
ãäžçš®ã®ååç©ã®çŒæç©ã§ããïŒãããŠãïœã¯
10-6âŠïœâŠ0.1ãïœã¯ïŒïŒïœâŠ0.1ã§ããã®çµæ
åŒã§è¡šããããèå äœã ç¹éæ59â56479å·å ¬å ±ã«èšèŒãããŠãã
BaFXã»xNaXâ²ïŒaEu2+ãã ããããã³Xâ²ã¯ã
ããããClãBrãããã³ïŒ©ã®ãã¡ã®å°ãªããšã
äžçš®ã§ãããïœããã³ïœã¯ããããïŒïŒïœâŠïŒã
ããã³ïŒïŒïœâŠ0.2ã§ããã®çµæåŒã§è¡šããã
ãèå äœã ç¹éæ59â56480å·å ¬å ±ã«èšèŒãããŠããMã
FXã»xNaXâ²ïŒyEu2+ïŒzAãã ããMãã¯ãBaã
Srãããã³Caãããªã矀ããéžã°ããå°ãªããš
ãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒïŒžããã³
Xâ²ã¯ãããããClãBrãããã³ïŒ©ãããªã矀ã
ãéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ããïŒïŒ¡
ã¯ããCrãMnãFeãCoãããã³Niããéžã°
ããå°ãªããšãäžçš®ã®é·ç§»éå±ã§ããïŒãããŠã
ïœã¯ïŒïŒïœâŠïŒãïœã¯ïŒïŒïœâŠ0.2ãããã³ïœã¯
ïŒïŒïœâŠ10-2ã§ããã®çµæåŒã§è¡šããããèå
äœã ç¹éæ59â75200å·å ¬å ±ã«èšèŒãããŠããMã
FXã»aMãXâ²ã»bMâ²ãXâ³2ã»cMã3ã»xAïŒ
yEu2+ãã ããMãã¯BaãSrãããã³Caãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡
éå±ã§ããïŒMãã¯LiãNaããRbãããã³Cs
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«
ãªéå±ã§ããïŒMâ²ãã¯Beããã³Mgãããªã矀ã
ãéžã°ããå°ãªããšãäžçš®ã®äºäŸ¡éå±ã§ããïŒ
Mãã¯AlãGaãInãããã³Tlãããªã矀ããéž
ã°ããå°ãªããšãäžçš®ã®äžäŸ¡éå±ã§ããïŒïŒ¡ã¯é
å±é žåç©ã§ããïŒïŒžã¯ClãBrãããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãïŒXâ²ãXâ³ãããã³Xâ³ã¯ããClãBrãããã³
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ãã
ã²ã³ã§ããïŒãããŠãïœã¯ïŒâŠïœâŠïŒãïœã¯ïŒâŠ
ïœâŠ10-2ãïœã¯ïŒâŠïœâŠ10-2ããã€ïœïŒïœïŒïœâ§
10-6ã§ããïŒïœã¯ïŒïŒïœâŠ0.5ãïœã¯ïŒïŒïœâŠ0.2
ã§ããã®çµæåŒã§è¡šããããèå äœã æ¬åºé¡äººã«ããç¹é¡æ58â193161å·æ现æžã«èš
èŒãããŠããMãX2ã»aMãXâ²2ïŒxEu2+ãã ãã
Mãã¯BaãSrããã³Caãããªã矀ããéžã°ãã
å°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒïŒžã
ãã³Xâ²ã¯ClãBrããã³ïŒ©ãããªã矀ããéžã°ã
ãå°ãªããšãäžçš®ã®ããã²ã³ã§ãã€ãŠããã€ïŒžâ
Xâ²ã§ããïŒãããŠïœã¯0.1âŠïœâŠ10.0ãïœã¯ïŒïŒ
ïœïŒ0.2ã§ããã®çµæåŒã§è¡šããããèå äœã æ¬åºé¡äººã«ããç¹é¡æ58â208727å·æ现æžã«èš
èŒãããŠããMãFXã»aMãXâ²ïŒxEu2+ãã ãã
Mãã¯BaãSrããã³Caãããªã矀ããéžã°ãã
å°ãªããšãäžçš®ã®ã¢ã«ã«ãªåé¡éå±ã§ããïŒMã
ã¯Rbããã³Csãããªã矀ããéžã°ããå°ãªããš
ãäžçš®ã®ã¢ã«ã«ãªéå±ã§ããïŒïŒžã¯ClãBrãã
ã³ïŒ©ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã
ãã²ã³ã§ããïŒXâ²ã¯ïŒŠãClãBrããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãïŒãããŠïœããã³ïœã¯ããããïŒâŠïœâŠ4.0ã
ãã³ïŒâŠïœâŠ0.2ã§ããã®çµæåŒã§è¡šãããã
èå äœã ãªã©ãæããããšãã§ããã ãŸããäžèšç¹é¡æ58â193161å·æ现æžã«èšèŒã
ããŠããMãX2ã»aMãXâ²2ïŒxEu2+èå äœã«ã¯ã以
äžã«ç€ºããããªæ·»å ç©ãMãX2ã»aMãXâ²21ã¢ã«åœ
ã以äžã®å²åã§å«ãŸããŠããŠãããã æ¬åºé¡äººã«ããç¹é¡çº59â22169å·æ现æžã«èš
èŒãããŠããbMãXâ³ïŒãã ããMãã¯Rbããã³Cs
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®ã¢ã«ã«
ãªéå±ã§ãããXâ³ã¯ïŒŠãClãBrããã³ïŒ©ãããª
ã矀ããéžã°ããå°ãªããšãäžçš®ã®ããã²ã³ã§ã
ãããããŠïœã¯ïŒïŒïœâŠ10.0ã§ããïŒïŒç¹é¡æ59
â77225å·æ现æžã«èšèŒãããŠããbKXâ³ã»cMgX
2ã»dMãâ²â²â²â²3ïŒãã ããMãã¯ScããLaãGd
ããã³Luãããªã矀ããéžã°ããå°ãªããšãäž
çš®ã®äžäŸ¡éå±ã§ãããXâ³ãããã³ïŒžâ²â²â²â²ã¯ã
ããããClãBrããã³ïŒ©ãããªã矀ããéžã°
ããå°ãªããšãäžçš®ã®ããã²ã³ã§ããããããŠ
ïœãïœåã³ïœã¯ãããããïŒâŠïœâŠ2.0ãïŒâŠïœ
âŠ2.0ãïŒâŠïœâŠ2.0ã§ãã€ãŠããã€ïŒÃ10-5âŠïœ
ïŒïœïŒïœã§ããïŒïŒç¹é¡æ59â84356å·æ现æžã«èš
èŒãããŠããyBïŒãã ããïœã¯ïŒÃ10-4âŠïœâŠïŒ
Ã10-1ã§ããïŒïŒåã³ç¹é¡æ59â84358å·æ现æžã«
èšèŒãããŠããbAïŒãã ããã¯SiO2åã³P2O5
ãããªã矀ããéžã°ããå°ãªããšãäžçš®ã®é žåç©
ã§ããããããŠïœã¯10-4âŠïœâŠïŒÃ10-1ã§ããïŒ äžèšã®èŒå°œæ§èå äœã®ãã¡ã§ãäºäŸ¡ã®ãŠãŒãã
ãŠã 賊掻ã¢ã«ã«ãªåé¡éå±ããã²ã³åç©ç³»èå äœ
ããã³åžåé¡å çŽ è³ŠæŽ»åžåé¡ãªãã·ããã²ã³åç©
ç³»èå äœã¯é«èŒåºŠã®èŒå°œçºå ã瀺ãã®ã§ç¹ã«å¥œãŸ
ããããã ããæ¬çºæã«çšããããèŒå°œæ§èå äœ
ã¯äžè¿°ã®èå äœã«éããããã®ã§ã¯ãªããæŸå°ç·
ãç §å°ããã®ã¡ã«å±èµ·å ãç §å°ããå Žåã«ãèŒå°œ
çºå ã瀺ãèå äœã§ããã°ãããªããã®ã§ãã€ãŠ
ãããã èå äœå±€ã®çµåå€ã®äŸãšããŠã¯ããŒã©ãã³çã®
èçœè³ªãããã¹ãã©ã³çã®ããªãµãã«ã©ã€ãããŸ
ãã¯ã¢ã©ãã¢ãŽã ã®ãããªå€©ç¶é«ååç©è³ªïŒãã
ã³ãããªããã«ããã©ãŒã«ãããªé ¢é žããã«ãã
ããã»ã«ããŒã¹ããšãã«ã»ã«ããŒã¹ãå¡©åãããª
ãã³ã»å¡©åããã«ã³ããªããŒãããªã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããå¡©åããã«ã»é ¢é žããã«ã³ã
ãªããŒãããªãŠã¬ã¿ã³ãã»ã«ããŒã¹ã¢ã»ããŒãã
ãã¬ãŒããããªããã«ã¢ã«ã³ãŒã«ãç·ç¶ããªãšã¹
ãã«ãªã©ã®ãããªåæé«ååç©è³ªãªã©ã«ãã代衚
ãããçµåå€ãæããããšãã§ããããã®ãããª
çµåå€ã®ãªãã§ç¹ã«å¥œãŸãããã®ã¯ããããã»ã«
ããŒã¹ãç·ç¶ããªãšã¹ãã«ãããªã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒãããããã»ã«ããŒã¹ãšç·ç¶ããª
ãšã¹ãã«ãšã®æ··åç©ããã³ãããã»ã«ããŒã¹ãšã
ãªã¢ã«ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããšã®æ··åç©ã§ã
ãããªãããããã®çµåå€ã¯æ¶æ©å€ã«ãã€ãŠæ¶æ©
ããããã®ããã€ãŠãããã 次ã«ãæ¬çºæã«çšãããã垯é»é²æ¢å€ã¯ãéå±
ã®ç¡æ©å¡©ã§ãããèå äœå±€è¡šé¢åŽã«éå±ã®ç¡æ©å¡©
ãå«æãããããšã«ãã€ãŠãè¡šé¢ã«åž¯é»ããé»è·
ãè¡šé¢é»å°ã«ããé»è·ã®ç§»åïŒæŸé»ïŒã«ããé²æ¢
ããããšãã§ãããããªãã¡ããã®ç©è³ªã®è¡šé¢é»
æ°æµæãå°ããããããšã«ãããçºçããé»è·ã
容æã«æŸé»ããããšãã§ããã æ¬çºæã«ãããŠåž¯é»é²æ¢å€ãšããŠçšããããé
å±ç¡æ©å¡©ã®ä»£è¡šçãªäŸãšããŠã¯ãLiClãNaClã
NaBrãNaIãNaNO3ãNa3PO4ãCsIãBaBr2ã
BaI2ãMgBr2ãAlBr3çã®éå±ã®ç¡æ©å¡©ãæãã
ããããªãããããã®éå±ç¡æ©å¡©ã¯åžžæž©ã§å®å®ã§
ããéããç¡æ°Žç©ã®ç¶æ ã§ãã€ãŠãããããã¯çµ
æ¶æ°Žãä»å ãããç¶æ ã§ãã€ãŠãããã äžèšã®éå±ç¡æ©å¡©ã®ãã¡ã§å¥œãŸãããã®ã¯ã
LiClãNaBrãNaIãNaNO3ãMgNr2ããã³
AlBr3ã§ãããããã«ãç¡çè²ã§ããããšãåã³
æ°Žãã¢ã«ã³ãŒã«çã®æº¶å€ã«å¯Ÿãã溶解æ§ãé«ãã
ãšçã®ç¹ãããLiClãNaBrãããã³MgBr2ãç¹
ã«å¥œãŸãããããªãã¡ããããã®éå±ããã²ã³å
ç©ã¯ç¡çè²ã§ããããã«å±èµ·å ãåžåããããšã
ãªãããŸããçµåå€æº¶æ¶²ã«æº¶è§£ããããåŸããã
èå äœå±€è¡šé¢ã«ãããåæ£æ§ãé«ããã®ã§ããã èå äœå±€ã¯ãããšãã°ã次ã®ãããªæ¹æ³ã«ãã
æ¯æäœäžã«åœ¢æããããšãã§ããã ãŸãäžèšã®èŒå°œæ§èå äœãšçµåå€ãšãé©åœãªæº¶
å€ã«æ·»å ãããããå åã«æ··åããŠãçµåå€æº¶æ¶²
äžã«èå äœç²åãåäžã«åæ£ããå¡åžæ¶²ïŒïŒã
調補ããã å¡åžæ¶²èª¿è£œçšã®æº¶å€ã®äŸãšããŠã¯ãããšãã°ã
ã¡ã¿ããŒã«ããšã¿ããŒã«ãïœâãããããŒã«ãïœ
âãã¿ããŒã«ãªã©ã®äœçŽã¢ã«ã³ãŒã«ïŒã¡ãã¬ã³ã¯
ãã©ã€ãããšãã¬ã³ã¯ãã©ã€ããªã©ã®å¡©çŽ ååå«
æçåæ°ŽçŽ ïŒã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡
ãã«ã€ãœããã«ã±ãã³ãªã©ã®ã±ãã³ïŒé ¢é žã¡ã
ã«ãé ¢é žãšãã«ãé ¢é žããã«ãªã©ã®äœçŽèèªé žãš
äœçŽã¢ã«ã³ãŒã«ãšã®ãšã¹ãã«ïŒãžãªããµã³ããšã
ã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããšãã¬ã³ã°
ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãªã©ã®ãšãŒãã«ïŒã
ããŠããããã®æ··åç©ãæããããšãã§ããã å¡åžæ¶²ã«ãããçµåå€ãšèŒå°œæ§èå äœãšã®æ··å
æ¯ã¯ãç®çãšããæŸå°ç·åå€æããã«ã®ç¹æ§ãè
å äœã®çš®é¡ãªã©ã«ãã€ãŠç°ãªãããäžè¬ã«ã¯çµå
å€ãšèå äœãšã®æ··åæ¯ã¯ãïŒïŒïŒä¹è³ïŒïŒ100ïŒé
éæ¯ïŒã®ç¯å²ããéžã°ãããããŠç¹ã«ïŒïŒïŒä¹è³
ïŒïŒ40ïŒééæ¯ïŒã®ç¯å²ããéžã¶ããšã奜ãŸããã ãªããå¡åžæ¶²ïŒïŒã«ã¯ã該å¡åžæ¶²äžã«ããã
èå äœã®åæ£æ§ãåäžãããããã®åæ£å€ããŸ
ãã圢æåŸã®èå äœå±€ã«ãããçµåå€ãšèå äœãš
ã®éã®çµååãåäžãããããã®å¯å¡å€ãªã©ã®
çš®ã ã®æ·»å å€ãæ··åãããŠããŠãããããã®ãã
ãªç®çã«çšããããåæ£å€ã®äŸãšããŠã¯ããã¿ã«
é žãã¹ãã¢ãªã³é žãã«ããã³é žã芪油æ§çé¢æŽ»æ§
å€ãªã©ãæããããšãã§ããããããŠå¯å¡å€ã®äŸ
ãšããŠã¯ãçé žããªããšãã«ãçé žããªã¯ã¬ãž
ã«ãçé žãžããšãã«ãªã©ã®çé žãšã¹ãã«ïŒãã¿ã«
é žãžãšãã«ããã¿ã«é žãžã¡ããã·ãšãã«ãªã©ã®ã
ã¿ã«é žãšã¹ãã«ïŒã°ãªã³ãŒã«é žãšãã«ãã¿ãªã«ãš
ãã«ãã°ãªã³ãŒã«é žããã«ãã¿ãªã«ããã«ãªã©ã®
ã°ãªã³ãŒã«é žãšã¹ãã«ïŒãããŠãããªãšãã¬ã³ã°
ãªã³ãŒã«ãšã¢ãžãã³é žãšã®ããªãšã¹ãã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ãšã³ãã¯é žãšã®ããªãšã¹ãã«ãªã©
ã®ããªãšãã¬ã³ã°ãªã³ãŒã«ãšèèªæäºå¡©åºé žãšã®
ããªãšã¹ãã«ãªã©ãæããããšãã§ããã ããã«ãå¡åžæ¶²ã«ã¯ãç»åã®é®®é床ãåäžãã
ãç®çã§ãèŒå°œæ§èå äœã®å±èµ·å æ³¢é·é åã«ãã
ãå¹³ååå°çããèŒå°œæ§èå äœã®èŒå°œçºå æ³¢é·é
åã«ãããå¹³ååå°çãããå°ãããããªåå°ç¹
æ§ãæããçè²å€ãå«æãããŠããŠãããããã®
ãããªçè²å€ãšããŠã¯ãããšãã°ãç¹éæ55â
163500å·å ¬å ±ããã³ç¹éæ57â96300å·å ¬å ±ã«é
瀺ãããŠãããããªçè²å€ãæããããšãã§ã
ãããããã¯ãåããç»åã®é®®é床ãåäžããã
ç®çã§ãå¡åžæ¶²ã«ã¯ç¹éæ55â146447å·å ¬å ±ã«èš
èŒãããŠãããããªçœè²ç²äœãå«æãããŠããŠã
ããã äžèšå¡åžæ¶²ïŒïŒãšã¯å¥ã«ãåèšåž¯é»é²æ¢å€ã
é©åœãªæº¶å€ã«æº¶è§£ãããã¯åæ£ããåŸãçµåå€ã
å ããŠå åã«æ··åãã垯é»é²æ¢å€ãå«æããå¡åž
液ïŒïŒã調補ããã å¡åžæ¶²ïŒïŒã®çµåå€ãšããŠã¯ãäžèšã®èå äœ
局圢æã®ããã®å¡åžæ¶²ïŒïŒã«çšããããçµåå€
ã®ä»ã«ãã»ã«ããŒã¹èªå°äœãããªå¡©åããã«ãã
ãªå¡©åãããªãã³ãããªããã«ãã«ããŒã«ãã¡ã©
ãã³ãããšããŒã«æš¹èããšããã·æš¹èãªã©ãæã
ãããšãã§ãããå¡åžæ¶²ïŒïŒã«çšããããçµå
å€ã¯ãå¡åžæ¶²ïŒïŒã«çšããããçµåå€ãšåäžã§
ãã€ãŠããããããããã¯å šãç°ãªã€ãŠããŠãã
ãããã ããå¡åžæ¶²ïŒïŒã®çµåå€ãšçžæº¶æ§ã®ã
ãçµåå€ã§ããå¿ èŠãããããŸããæŸå°ç·åå€æ
ããã«è¡šé¢ã®é²å·æ§ãªã©ã®ç¹ããã¯å¡åžæ¶²ïŒïŒ
ã®çµåå€ã¯æ¯èŒç硬ããã®ã§ããã®ã奜ãŸããã
äžæ¹ãæ©æ¢°ç匷床ãªã©ã®ç¹ããã¯å¡åžæ¶²ïŒïŒã®
çµåå€ã¯å¡åžæ¶²ïŒïŒã®çµåå€ãšåäžã§ããã®ã
奜ãŸããã å¡åžæ¶²ïŒïŒã«ãããŠåž¯é»é²æ¢å€ãçµåå€æº¶æ¶²
äžã«å«æãããæ¯çã¯ã垯é»é²æ¢å€ã®çš®é¡ãçµå
å€ã®çš®é¡ããã³è£œé ãããããã«ã®æ§æãªã©ã«ã
ã€ãŠãç°ãªãããäžè¬ã«ã¯çµåå€ã®äœ¿çšéã«å¯Ÿã
ãŠ0.1ä¹è³20ééïŒ ã®ç¯å²ããéžã°ããç¹ã«0.5ä¹
è³ïŒééïŒ ã®ç¯å²ããéžã°ããã®ã奜ãŸããã ãŸãã溶å€ãšããŠã¯ãäžèšã®æº¶å€ãçšããããš
ãã§ããããèå äœå±€ã«ããã垯é»é²æ¢å€ã®åæ£
æ§ã®ç¹ããã垯é»é²æ¢å€ã§ããéå±ç¡æ©å¡©ã溶解
ããããããªæº¶å€ãçšããã®ã奜ãŸããããŸãã
å¡åžæ¶²ïŒïŒã®æº¶å€ã¯å¡åžæ¶²ïŒïŒã«çšãããã
溶å€ãšåäžã§ãã€ãŠããããããããã¯ç°ãªã€ãŠ
ããŠããããäœããå¡åžæ¶²ïŒïŒããã³ïŒïŒã
éå±€ãããŠãªãå¡èã®ä¹Ÿç¥é床ãäžèŽãããå¿ èŠ
ãããäºãã«çžæº¶æ§ã®ãã溶å€ãçšããããšãæ
ãŸããã ããã«ãå¡åžæ¶²ïŒïŒã«ã¯äžèšå¡åžæ¶²ïŒïŒã«
çšããããåçš®ã®åæ£å€ãå¯å¡å€ãçè²å€ãªã©ã
å«æãããŠããŠãããã äžèšã®ããã«ããŠèª¿è£œãããå¡åžæ¶²ïŒïŒãšå¡
åžæ¶²ïŒïŒãšããå¡åžæ¶²ïŒïŒãæ¯æäœåŽã«é 眮
ããŠæ¯æäœã®è¡šé¢ã«åäžã«åæã«éå±€å¡åžããã
ãšã«ããã垯é»é²æ¢å€ãå«æãããéšåãããã«
è¡šé¢åŽãšãªãããã«å¡åžæ¶²ã®å¡èã圢æãããã
ã®å¡åžæäœã¯ãããšãã°ãäºé£åŒããããŒåå¡åž
è£ çœ®ãçšããããšã«ããè¡ãªãããšãã§ããã å¡åžæ¶²ïŒïŒããã³å¡åžæ¶²ïŒïŒã®å¡åžéã¯ã
ç®çãšããæŸå°ç·åå€æããã«ã®ç¹æ§ãå¡åžæ¶²ã®
ç²åºŠãçµåå€ãšèå äœãšã®æ··åæ¯ãªã©ã«ãã€ãŠç°
ãªãããéåžžã¯100ïŒïŒä¹è³ïŒïŒïŒïŒäœç©æ¯ïŒã®ç¯
å²ããéžã°ãã奜ãŸããã¯10ïŒïŒä¹è³ïŒïŒïŒã®ç¯
å²ã§ããããŸããäž¡å¡åžæ¶²ãéããŠåž¯é»é²æ¢å€ã®
çµåå€ã«å¯Ÿããæ¯çã¯ãäžè¬ã«0.03ä¹è³ïŒééïŒ
ã®ç¯å²ããéžã°ããç¹ã«0.1ä¹è³ïŒééïŒ ã®ç¯å²
ããéžã°ããã®ã奜ãŸããã ã€ãã§ã圢æãããæ¯æäœåŽã®å¡åžæ¶²ïŒïŒã®
å¡èããã³ãã®äžã«åœ¢æãããå¡åžæ¶²ïŒïŒã®å¡
èãåŸã ã«å ç±ããããšã«ãã也ç¥ããŠãæ¯æäœ
äžãžã®èå äœå±€ã®åœ¢æãå®äºããããã®ããã«ã
ãŠåœ¢æãããèå äœå±€ã¯ãæ¯æäœåŽã®èå äœç²å
ãåæ£ç¶æ ã§ååšããéšåãšãããã«è¡šé¢åŽã®åž¯
é»é²æ¢å€ãå«æãããéšåãšããæ§æãããé»å
é¡åŸ®é¡çã§èŠèŠçã«èŠ³å¯ããŠãäž¡éšåã«ã¯å¢çé¢
ããªããäžå±€ã®èå äœå±€ã圢æããŠããã ãŸããèå äœå±€ã¯ãå¿ ãããäžèšã®ããã«æ¯æ
äœäžã«å¡åžæ¶²ãçŽæ¥å¡åžããŠåœ¢æããå¿ èŠã¯ãª
ããããšãã°ãå¥ã«ã¬ã©ã¹æ¿ãéå±æ¿ããã©ã¹ã
ãã¯ã·ãŒããªã©ã®å¹³é¢ã·ãŒãäžã«å¡åžæ¶²ãäžè¿°ã®
ããã«ããŠåæéå±€å¡åžããããšã«ããèå äœå±€
ã圢æããåŸããããæ¯æäœäžã«æŒå§ããããã
ããã¯æ¥çå€ãçšãããªã©ããŠæ¯æäœãšèå äœå±€
ãšãæ¥åããŠãããããã®å Žåã«ãå¡åžæ¶²ïŒïŒ
ãšå¡åžæ¶²ïŒïŒã¯ææãšããæŸå°ç·åå€æããã«
ã®ç¹æ§ãå¡åžæ¡ä»¶ãªã©ã«å¿ããŠãã©ã¡ããå¹³é¢ã·
ãŒãåŽã«é 眮ããŠéå±€å¡åžãè¡ã€ãŠãããã èå äœå±€ã®å±€åã¯ãç®çãšããæŸå°ç·åå€æã
ãã«ã®ç¹æ§ãèå äœã®çš®é¡ãçµåå€ãšèå äœãšã®
æ··åæ¯ãªã©ã«ãã€ãŠç°ãªãããéåžžã¯20ÎŒïœä¹è³
ïŒmmãšããããã ãããã®å±€åã¯50ä¹è³500ÎŒïœ
ãšããã®ã奜ãŸããããŸãããã®ãã¡ããã«è¡šé¢
åŽã®åž¯é»é²æ¢å€ãå«æãããéšåã¯çŽïŒä¹è³20ÎŒ
ïœã®åããæããããšã奜ãŸãããæ¯æäœåŽã®èŒ
å°œæ§èå äœãååšããéšåãšããã«è¡šé¢åŽã®åž¯é»
é²æ¢å€ãå«æãããéšåãšã®æ¯çã¯ãå±€åïŒå¹³
åïŒã§100ïŒïŒãïŒïŒïŒã®ç¯å²ã«ããããšã奜ãŸ
ããã æ¬çºæã«ãããŠäœ¿çšããæ¯æäœã¯ãåŸæ¥ã®æŸå°
ç·åçæ³ã«ãããå¢æçŽã®æ¯æäœãšããŠçšããã
ãŠããåçš®ã®ææãããã¯æŸå°ç·åå€æããã«ã®
æ¯æäœãšããŠå ¬ç¥ã®åçš®ã®ææããä»»æã«éžã¶ã
ãšãã§ããããã®ãããªææã®äŸãšããŠã¯ãã»ã«
ããŒã¹ã¢ã»ããŒããããªãšã¹ãã«ãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒããããªã¢ãããããªã€ãããããª
ã¢ã»ããŒããããªã«ãŒãããŒããªã©ã®ãã©ã¹ãã
ã¯ç©è³ªã®ãã€ã«ã ãã¢ã«ãããŠã ç®ãã¢ã«ãããŠ
ã åéç®ãªã©ã®éå±ã·ãŒããéåžžã®çŽããã©ã€ã¿
çŽãã¬ãžã³ã³ãŒãçŽãäºé žåãã¿ã³ãªã©ã®é¡æã
å«æãããã°ã¡ã³ãçŽãããªããã«ã¢ã«ã³ãŒã«ãª
ã©ããµã€ãžã³ã°ããçŽãªã©ãæããããšãã§ã
ãããã ããæŸå°ç·åå€æããã«ã®æ å ±èšé²ææ
ãšããŠã®ç¹æ§ããã³åæ±ããªã©ãèæ ®ããå Žåã
æ¬çºæã«ãããŠç¹ã«å¥œãŸããæ¯æäœã®ææã¯ãã©
ã¹ããã¯ãã€ã«ã ã§ããããã®ãã©ã¹ããã¯ãã€
ã«ã ã«ã¯ã«ãŒãã³ãã©ãã¯ãªã©ã®å åžåæ§ç©è³ªã
ç·Žã蟌ãŸããŠããŠãããããããã¯äºé žåãã¿ã³
ãªã©ã®å åå°æ§ç©è³ªãç·Žã蟌ãŸããŠããŠãããã
åè ã¯é«é®®é床ã¿ã€ãã®æŸå°ç·åå€æããã«ã«é©
ããæ¯æäœã§ãããåŸè ã¯é«æ床ã¿ã€ãã®æŸå°ç·
åå€æããã«ã«é©ããæ¯æäœã§ããã å ¬ç¥ã®æŸå°ç·åå€æããã«ã«ãããŠã¯ãæ¯æäœ
ãšèå äœå±€ã®çµåã匷åããããããããã¯æŸå°
ç·åå€æããã«ãšããŠã®æ床ãããã¯ç»è³ªïŒé®®é
床ãç²ç¶æ§ïŒãåäžãããããã«ãèå äœå±€ãèš
ããããåŽã®æ¯æäœè¡šé¢ã«ãŒã©ãã³ãªã©ã®é«åå
ç©è³ªãå¡åžããŠæ¥çæ§ä»äžå±€ãšãããããããã¯
äºé žåãã¿ã³ãªã©ã®å åå°æ§ç©è³ªãããªãå åå°
å±€ããããã¯ã«ãŒãã³ãã©ãã¯ãªã©ã®å åžåæ§ç©
質ãããªãå åžåå±€ãèšããããšãè¡ãªãããŠã
ããæ¬çºæã§çšããããæ¯æäœã«ã€ããŠãããã
ãã®åçš®ã®å±€ãèšããããšãã§ãããããã®æ§æ
ã¯ææã®æŸå°ç·åå€æããã«ã®ç®çãçšéãªã©ã«
å¿ããŠä»»æã«éžæããããšãã§ããã ããã«ãç¹éæ58â200200å·å ¬å ±ã«èšèŒãããŠ
ããããã«ãåŸãããç»åã®é®®é床ãåäžããã
ç®çã§ãæ¯æäœã®èå äœå±€åŽã®è¡šé¢ïŒæ¯æäœã®è
å äœå±€åŽã®è¡šé¢ã«æ¥çæ§ä»äžå±€ãå åå°å±€ããã
ã¯å åžåå±€ãªã©ãèšããããŠããå Žåã«ã¯ããã®
è¡šé¢ãæå³ããïŒã«ã¯ã埮现ãªå¹åžãå質ã«åœ¢æ
ãããŠããŠãããã 次ã«æ¬çºæã®å®æœäŸããã³æ¯èŒäŸãèšèŒããã
ãã ãããããã®åäŸã¯æ¬çºæãå¶éãããã®ã§
ã¯ãªãããªãã以äžã®åäŸã§ãéšãã¯ç¹ã«èšèŒã®
ãªãéããéééšããè¡šããã å®æœäŸ ïŒ ããªãŠã¬ã¿ã³æš¹èïŒãã¹ã¢ã©ãã¯4125ãäœåã
ã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒãã¡ãã«ãšãã«ã±ãã³ãšã€
ãœãããã«ã¢ã«ã³ãŒã«ã®æ··å溶åªã«æº¶è§£ããŠããª
ãŠã¬ã¿ã³æš¹è溶液ã調補ããããŸãããããã»ã«
ããŒã¹ïŒRSâ120ããã€ã»ã«ååŠå·¥æ¥(æ ª)補ïŒãã¡
ãã«ãšãã«ã±ãã³ãšã€ãœãããã«ã¢ã«ã³ãŒã«ã®æ··
å溶åªã«æº¶è§£ããŠãããã»ã«ããŒã¹æº¶æ¶²ã調補ã
ããèŒå°œæ§ã®äºäŸ¡ãŠãŒãããŠã 賊掻åŒåèåããª
èå äœïŒBaFBrïŒEu2+ïŒã®ç²åãã¡ãã«ãšãã«
ã±ãã³ãšã€ãœãããã«ã¢ã«ã³ãŒã«ã®æ··å溶åªã«å
æ£ããã®ã¡ããã®åæ£æ¶²ã«äžèšããªãŠã¬ã¿ã³æš¹è
溶液ããã³ãããã»ã«ããŒã¹æº¶æ¶²ãå ããããã«
矀éïŒé¡æïŒPBâ100ã第äžåæå·¥æ¥(æ ª)補ïŒãã
ã³çé žããªã¯ã¬ãžã«ãæ·»å ãããããã©ãããµãŒ
ãçšããŠæº¶è§£ããŠèå äœãå«æããåæ£æ¶²ïŒ»å¡åž
液ïŒïŒïŒœã調補ããã 次ã«ã垯é»é²æ¢å€ãšããŠèåãããªãŠã
ïŒNaBrïŒãã¡ãã«ãšãã«ã±ãã³ãšã€ãœãããã«
ã¢ã«ã³ãŒã«ãšãã®æ··å溶åªã«æ·»å ãå å溶解ãã
ãã®ã¡ããã®æº¶è§£æ¶²ã«ããªãŠã¬ã¿ã³æš¹èïŒãã¹ã¢
ã©ãã¯4125ãäœåãã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒããã
ã»ã«ããŒã¹ïŒRSâ120ããã€ã»ã«ååŠå·¥æ¥(æ ª)補ïŒ
ããã³çé žããªã¯ã¬ãžã«ãæ·»å ãããããã©ãã
ãµãŒãçšããŠæ··åããŠçµåå€æº¶æ¶²ïŒ»å¡åžæ¶²ïŒïŒïŒœ
ã調補ããã å¡åžæ¶²ïŒïŒããã³å¡åžæ¶²ïŒïŒã®çµæãäžèš
ã«ç€ºãã å¡åžæ¶²ïŒïŒã®çµæ BaFBrïŒEu2+èå äœ 800éš ããªãŠã¬ã¿ã³æš¹è 83.1éš ãããã»ã«ããŒã¹ 52éš çŸ€ é 0.052éš çé žããªã¯ã¬ãžã« 2.6éš ã¡ãã«ãšãã«ã±ãã³ 204.6éš ã€ãœãããã«ã¢ã«ã³ãŒã« 39.5éš å¡åžæ¶²ïŒïŒã®çµæ ããªãŠã¬ã¿ã³æš¹è 145éš ãããã»ã«ããŒã¹ 9.1éš çé žããªã¯ã¬ãžã« 4.5éš èåãããªãŠã 1.4éš ã¡ãã«ãšãã«ã±ãã³ 287.5éš ã€ãœãããã«ã¢ã«ã³ãŒã« 51.6éš æ¬¡ã«ãã«ãŒãã³ç·Žã蟌ã¿ããªãšãã¬ã³ãã¬ãã¿
ã¬ãŒãã·ãŒãïŒæ¯æäœãåã¿ïŒ250ÎŒïœïŒãã¬ã©
ã¹æ¿äžã«æ°Žå¹³ã«çœ®ããŠãå¡åžæ¶²ïŒïŒããã³å¡åž
液ïŒïŒã第ïŒå³ã«ç€ºããããªäºé£åŒããããŒå
å¡åžè£ 眮ãçšããŠãæ¯æäœäžã«åæã«éå±€å¡åžã
ãã ããªãã¡ã第ïŒå³ã«ãããŠãäºé£åŒããããŒå
å¡åžè£ 眮ïŒã®å³åŽå°å ¥éšïŒã«ã¯å¡åžæ¶²ïŒïŒã泚
å ¥ããå·ŠåŽå°å ¥éšïŒã«ã¯å¡åžæ¶²ïŒïŒãå°å ¥ã
ããå°å ¥éšïŒïŒïŒã®äžéšéå£éšã®é·ãã¯ãããã
0.500mmããã³0.150mmã§ãã€ããæ¯æäœïŒã®çœ®ã
ããã¬ã©ã¹æ¿ïŒã®ç¢å°ïŒã®æ¹åã«1.0ïœïŒåã®é
床ã§ç§»åãããªãããäžéšéå£éšããå¡åžæ¶²
ïŒïŒããã³ïŒïŒãæ¯æäœïŒäžã«åæã«éå±€å¡
åžããŠãå¡åžæ¶²ïŒïŒã®å¡èïŒããã³å¡åžæ¶²
ïŒïŒã®å¡èïŒã圢æããã ãããŠå¡åžåŸã«ãå¡èã®åœ¢æãããæ¯æäœã也
ç¥åšå ã«å ¥ãããã®ä¹Ÿç¥åšã®å éšã®æž©åºŠã25âã
ã100âã«åŸã ã«äžæãããŠ50åéå¡èã®ä¹Ÿç¥ã
è¡ãªã€ãã ãã®ããã«ããŠæ¯æäœäžã«æ¯æäœåŽã®èŒå°œæ§è
å äœã®ååšããéšåã®å±€åãçŽ340ÎŒïœãããã«
è¡šé¢åŽã®åž¯é»é²æ¢å€ãå«æããéšåã®å±€åãçŽ
7ÎŒïœã®èå äœå±€ã圢æããæ¯æäœããã³èå äœ
å±€ããæ§æãããæŸå°ç·åå€æããã«ã補é ã
ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã«èåãããª
ãŠã ãæ·»å ããªãããšä»¥å€ã¯å®æœäŸïŒãšåæ§ã®æ¹
æ³ã«ãããæ¯æäœããã³èå äœå±€ããæ§æããã
æŸå°ç·åå€æããã«ã補é ããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®ã¿ãçšãã
äºé£åŒããããŒåå¡åžè£ 眮ã®å°å ¥éšïŒïŒäžéšéå£
éšã®é·ãïŒ0.500mmïŒã®ã¿ã䜿çšããããšä»¥å€ã¯
å®æœäŸïŒãšåæ§ã®æ¹æ³ã«ãããæ¯æäœäžã«å±€åã
çŽ340ÎŒïœã®èå äœå±€ã圢æããã 次ã«ããã®èå äœå±€ã®äžã«ããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒãã®éæãã€ã«ã ïŒä¿è·èãåã¿ïŒ7ÎŒïœã
ããªãšã¹ãã«ç³»æ¥çå€ãä»äžãããŠãããã®ïŒã
æ¥çå€å±€åŽãäžã«åããŠçœ®ããŠ90ã100âã®å ç±
ããŒã«ãçšããŠå§çããããšã«ãããéæä¿è·è
ãä»èšããæ¯æäœãèå äœå±€ããã³éæä¿è·èã
ãæ§æãããæŸå°ç·åå€æããã«ã補é ããã å®æœäŸïŒãæ¯èŒäŸïŒããã³æ¯èŒäŸïŒã§åŸããã
åæŸå°ç·åå€æããã«ãã次ã«èšèŒããè¡šé¢æµæ
è©Šéšããã³æ¬éæ§è©Šéšã«ããè©äŸ¡ããã (1) è¡šé¢æµæè©Šéš åé»æ¥µïŒïŒ°â601åãå·å£é»æ°è£œäœæ(æ ª)補ïŒ
ãšçµ¶çžèšïŒEVâ40åè¶ çµ¶çžèšãå·å£é»æ°è£œäœ
æ(æ ª)補ïŒãšãçµåãã110mmÃ110mmã®ãµã€ãºã«
è£æããæŸå°ç·åå€æããã«ãåé»æ¥µã®äžã«èŒ
ããé»å§ãå°å ããŠããã«ã®è¡šé¢ã®é»æ°æµæã
枬å®ããããªãã枬å®ã¯æž©åºŠ23âã湿床50ïŒ
RHã®æ¡ä»¶ã§è¡ãªã€ãã (2) æ¬éæ§è©Šéš æŸå°ç·åå€æããã«ãæŸå°ç·åèšé²èªåè£ çœ®
å ãæ¬éãããããšã«ããã移åãç©å±€ã®ãµã€
ã¯ã«ã100åç¹°ãè¿ãè¡ãªããäºæã®ããã«ã
åæã«æ¬éããåæ°ã枬å®ããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šããæãããªããã«ãæ¬çºæã®åž¯é»é²æ¢
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸïŒïŒ
ã¯ãè¡šé¢æµæãé¡èã«å°ãã垯é»æ§ãé²æ¢ããã
ãã®çµæããã«ã®äºææ¬éçŸè±¡ã¯å šãçºçããã
åæ»ãªæ¬éæäœãè¡ãªãããšãã§ããã äžæ¹ã垯é»é²æ¢å€ãå«æãããªãæŸå°ç·åå€æ
ããã«ïŒæ¯èŒäŸïŒïŒãããã³åž¯é»é²æ¢å€ãå«æã
ããããã€ä¿è·å±€ãå¥éä»èšãããæŸå°ç·åå€æ
ããã«ïŒæ¯èŒäŸïŒïŒã¯ãè¡šé¢æµæã倧ããããã
ã«ã®äºææ¬éãïŒãïŒåçºçããã å®æœäŸ ïŒãå®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®èåãããª
ãŠã ã®ä»£ãã«äžèšç¬¬ïŒè¡šã«ç€ºãéå±ç¡æ©å¡©ãçšã
ãããšä»¥å€ã¯å®æœäŸïŒãšåæ§ã®æ¹æ³ã«ãããæ¯æ
äœããã³èå äœå±€ããæ§æãããæŸå°ç·åå€æã
ãã«ã補é ããã ãªããå¡åžæ¶²ïŒïŒã«ãããéå±ç¡æ©å¡©ã®çµå
å€ã«å¯Ÿããæ¯çã¯ãå¡©åãããªãŠã ã®å Žåã¯ïŒé
éïŒ ã§ããããã以å€ã¯å šãŠïŒééïŒ ã§ãã€ãã
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸïŒïŒ
ã¯ãè¡šé¢æµæãé¡èã«å°ãã垯é»æ§ãé²æ¢ããã
ãã®çµæããã«ã®äºææ¬éçŸè±¡ã¯å šãçºçããã
åæ»ãªæ¬éæäœãè¡ãªãããšãã§ããã äžæ¹ã垯é»é²æ¢å€ãå«æãããªãæŸå°ç·åå€æ
ããã«ïŒæ¯èŒäŸïŒïŒãããã³åž¯é»é²æ¢å€ãå«æã
ããããã€ä¿è·å±€ãå¥éä»èšãããæŸå°ç·åå€æ
ããã«ïŒæ¯èŒäŸïŒïŒã¯ãè¡šé¢æµæã倧ããããã
ã«ã®äºææ¬éãïŒãïŒåçºçããã å®æœäŸ ïŒãå®æœäŸ ïŒ å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®èåãããª
ãŠã ã®ä»£ãã«äžèšç¬¬ïŒè¡šã«ç€ºãéå±ç¡æ©å¡©ãçšã
ãããšä»¥å€ã¯å®æœäŸïŒãšåæ§ã®æ¹æ³ã«ãããæ¯æ
äœããã³èå äœå±€ããæ§æãããæŸå°ç·åå€æã
ãã«ã補é ããã ãªããå¡åžæ¶²ïŒïŒã«ãããéå±ç¡æ©å¡©ã®çµå
å€ã«å¯Ÿããæ¯çã¯ãå¡©åãããªãŠã ã®å Žåã¯ïŒé
éïŒ ã§ããããã以å€ã¯å šãŠïŒééïŒ ã§ãã€ãã
ãè¡šã
å®æœäŸïŒãïŒã§åŸãããåæŸå°ç·åå€æããã«
ãåèšè¡šé¢æµæè©Šéšã«ããè©äŸ¡ãããåŸãããçµ
æã第ïŒè¡šã«ç€ºã
ãåèšè¡šé¢æµæè©Šéšã«ããè©äŸ¡ãããåŸãããçµ
æã第ïŒè¡šã«ç€ºã
ãè¡šã
第ïŒè¡šããæãããªããã«ãæ¬çºæã®åž¯é»é²æ¢
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸïŒã
å®æœäŸïŒïŒã¯ãé¡èã«è¡šé¢æµæãéäžããŠåž¯é»æ§
ãé²æ¢ããããšãã§ããã å®æœäŸ 10 å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®çµåå€ãšã
ãŠããªãŠã¬ã¿ã³æš¹èã®ä»£ãã«ããªã¢ã¯ãªã«æš¹è
ïŒã¯ãªã¹ã³ãŒãâ1018GSã倧æ¥æ¬ã€ã³ãååŠå·¥
æ¥(æ ª)補ãããã³ãã©ãã€ãâ66ãRohm and
Hass Corp.補ïŒãçšããå¯å¡å€ãšããŠæŽã«èèª
æããªã€ãœã·ã¢ããŒãïŒã¹ããžãŠãŒã«ïŒ®â75ãäœ
åãã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒãæ·»å ããçè²å€ã§ã
ã矀éã溶å€ã§ããã€ãœãããã«ã¢ã«ã³ãŒã«ãçš
ããªãããšãåã³å¡åžæ¶²ïŒïŒã®çµåå€ãšããŠã
ãªãŠã¬ã¿ã³æš¹èã®ä»£ãã«ããªã¢ã¯ãªã«æš¹èïŒãã€
ã€ããŒã«BRâ102ãäžè±ã¬ã€ãšã³(æ ª)補ïŒã垯é»é²
æ¢å€ãšããŠèåãããªãŠã ã®ä»£ãã«å¡©åãªããŠã
ïŒLiClïŒãå¯å¡å€ãšããŠçé žããªã¯ã¬ãžã«ã®ä»£ãã«
çé žããªããã«ãåã çšããããã«ã€ãœãããã«
ã¢ã«ã³ãŒã«ãçšããªãããšä»¥å€ã¯å®æœäŸïŒã®æ¹æ³
ãšåæ§ã®åŠçãè¡ãªãããšã«ãããäžèšã®çµæã
æããå¡åžæ¶²ïŒïŒããã³ïŒïŒãçšæããã å¡åžæ¶²ïŒïŒã®çµæ BaFBrïŒEu2+èå äœ 800éš ããªã¢ã¯ãªã«æš¹èïŒã¯ãªã¹ã³ãŒãïŒ 56.1éš ããªã¢ã¯ãªã«æš¹èïŒãã©ãã€ãïŒ 9.1éš ãããã»ã«ããŒã¹ 3.7éš èèªæããªã€ãœã·ã¢ããŒã 1.8éš çé žããªã¯ã¬ãžã« 1.3éš ã¡ãã«ãšãã«ã±ãã³ 230éš å¡åžæ¶²ïŒïŒã®çµæ ããªã¢ã¯ãªã«æš¹èïŒãã€ã€ããŒã«ïŒ 65.9éš ãããã»ã«ããŒã¹ 8.1éš çé žããªããã« 7.4éš å¡©åãªããŠã 1.6éš ã¡ãã«ãšãã«ã±ãã³ 412éš æ¬¡ã«ãäžèšå¡åžæ¶²ïŒïŒããã³ïŒïŒãšããã
ãšä»¥å€ã¯å®æœäŸïŒã®æ¹æ³ãšåæ§ã®åŠçãè¡ãªãã
ãšã«ãããæ¯æäœäžã«æ¯æäœåŽã®èŒå°œæ§èå äœã®
ååšããéšåã®å±€åãçŽ348ÎŒïœãããã«è¡šé¢åŽ
ã®åž¯é»é²æ¢å€ãå«æããéšåã®å±€åãçŽ7ÎŒïœã®
èå äœå±€ã圢æããæ¯æäœããã³èå äœå±€ããæ§
æãããæŸå°ç·åå€æããã«ã補é ããã æ¯èŒäŸ ïŒ æ¯èŒäŸïŒã«ãããŠãå®æœäŸ10ã®å¡åžæ¶²ïŒïŒã«
å¡©åãªããŠã ãçšããªãããšä»¥å€ã¯æ¯èŒäŸïŒã®æ¹
æ³ãšåæ§ã®åŠçãè¡ãªãããšã«ãããæ¯æäœãã
ã³èå äœå±€ããæ§æãããæŸå°ç·åå€æããã«ã
補é ããã å®æœäŸ10ããã³æ¯èŒäŸïŒã§åŸãããåæŸå°ç·å
å€æããã«ãåèšãšåæ§ã®è©Šéšã«ããè©äŸ¡ããã
åŸãããçµæã第ïŒè¡šã«ç€ºãã
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸïŒã
å®æœäŸïŒïŒã¯ãé¡èã«è¡šé¢æµæãéäžããŠåž¯é»æ§
ãé²æ¢ããããšãã§ããã å®æœäŸ 10 å®æœäŸïŒã«ãããŠãå¡åžæ¶²ïŒïŒã®çµåå€ãšã
ãŠããªãŠã¬ã¿ã³æš¹èã®ä»£ãã«ããªã¢ã¯ãªã«æš¹è
ïŒã¯ãªã¹ã³ãŒãâ1018GSã倧æ¥æ¬ã€ã³ãååŠå·¥
æ¥(æ ª)補ãããã³ãã©ãã€ãâ66ãRohm and
Hass Corp.補ïŒãçšããå¯å¡å€ãšããŠæŽã«èèª
æããªã€ãœã·ã¢ããŒãïŒã¹ããžãŠãŒã«ïŒ®â75ãäœ
åãã€ãšã«ãŠã¬ã¿ã³(æ ª)補ïŒãæ·»å ããçè²å€ã§ã
ã矀éã溶å€ã§ããã€ãœãããã«ã¢ã«ã³ãŒã«ãçš
ããªãããšãåã³å¡åžæ¶²ïŒïŒã®çµåå€ãšããŠã
ãªãŠã¬ã¿ã³æš¹èã®ä»£ãã«ããªã¢ã¯ãªã«æš¹èïŒãã€
ã€ããŒã«BRâ102ãäžè±ã¬ã€ãšã³(æ ª)補ïŒã垯é»é²
æ¢å€ãšããŠèåãããªãŠã ã®ä»£ãã«å¡©åãªããŠã
ïŒLiClïŒãå¯å¡å€ãšããŠçé žããªã¯ã¬ãžã«ã®ä»£ãã«
çé žããªããã«ãåã çšããããã«ã€ãœãããã«
ã¢ã«ã³ãŒã«ãçšããªãããšä»¥å€ã¯å®æœäŸïŒã®æ¹æ³
ãšåæ§ã®åŠçãè¡ãªãããšã«ãããäžèšã®çµæã
æããå¡åžæ¶²ïŒïŒããã³ïŒïŒãçšæããã å¡åžæ¶²ïŒïŒã®çµæ BaFBrïŒEu2+èå äœ 800éš ããªã¢ã¯ãªã«æš¹èïŒã¯ãªã¹ã³ãŒãïŒ 56.1éš ããªã¢ã¯ãªã«æš¹èïŒãã©ãã€ãïŒ 9.1éš ãããã»ã«ããŒã¹ 3.7éš èèªæããªã€ãœã·ã¢ããŒã 1.8éš çé žããªã¯ã¬ãžã« 1.3éš ã¡ãã«ãšãã«ã±ãã³ 230éš å¡åžæ¶²ïŒïŒã®çµæ ããªã¢ã¯ãªã«æš¹èïŒãã€ã€ããŒã«ïŒ 65.9éš ãããã»ã«ããŒã¹ 8.1éš çé žããªããã« 7.4éš å¡©åãªããŠã 1.6éš ã¡ãã«ãšãã«ã±ãã³ 412éš æ¬¡ã«ãäžèšå¡åžæ¶²ïŒïŒããã³ïŒïŒãšããã
ãšä»¥å€ã¯å®æœäŸïŒã®æ¹æ³ãšåæ§ã®åŠçãè¡ãªãã
ãšã«ãããæ¯æäœäžã«æ¯æäœåŽã®èŒå°œæ§èå äœã®
ååšããéšåã®å±€åãçŽ348ÎŒïœãããã«è¡šé¢åŽ
ã®åž¯é»é²æ¢å€ãå«æããéšåã®å±€åãçŽ7ÎŒïœã®
èå äœå±€ã圢æããæ¯æäœããã³èå äœå±€ããæ§
æãããæŸå°ç·åå€æããã«ã補é ããã æ¯èŒäŸ ïŒ æ¯èŒäŸïŒã«ãããŠãå®æœäŸ10ã®å¡åžæ¶²ïŒïŒã«
å¡©åãªããŠã ãçšããªãããšä»¥å€ã¯æ¯èŒäŸïŒã®æ¹
æ³ãšåæ§ã®åŠçãè¡ãªãããšã«ãããæ¯æäœãã
ã³èå äœå±€ããæ§æãããæŸå°ç·åå€æããã«ã
補é ããã å®æœäŸ10ããã³æ¯èŒäŸïŒã§åŸãããåæŸå°ç·å
å€æããã«ãåèšãšåæ§ã®è©Šéšã«ããè©äŸ¡ããã
åŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šããæãããªããã«ãæ¬çºæã®åž¯é»é²æ¢
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸ10ïŒ
ã¯åž¯é»é²æ¢å€ãå«æãããªãæŸå°ç·åå€æããã«
ïŒæ¯èŒäŸïŒïŒãšæ¯èŒããŠãé¡èã«è¡šé¢æµæãéäž
ããŠåž¯é»æ§ãé²æ¢ããããã®çµææ¬éç³»ã§ã®ãã
ã«ã®äºææ¬éçŸè±¡ã¯çºçãããåæ»ãªæäœãè¡ãª
ãããšãã§ããã
å€ãå«æãããæŸå°ç·åå€æããã«ïŒå®æœäŸ10ïŒ
ã¯åž¯é»é²æ¢å€ãå«æãããªãæŸå°ç·åå€æããã«
ïŒæ¯èŒäŸïŒïŒãšæ¯èŒããŠãé¡èã«è¡šé¢æµæãéäž
ããŠåž¯é»æ§ãé²æ¢ããããã®çµææ¬éç³»ã§ã®ãã
ã«ã®äºææ¬éçŸè±¡ã¯çºçãããåæ»ãªæäœãè¡ãª
ãããšãã§ããã
第ïŒå³ã¯ãæ¬çºæã®æŸå°ç·åå€æããã«ã®è£œé
æ³ã«äœ¿çšãããå¡åžè£ 眮ã®äžäŸã§ããäºé£åŒãã
ããŒåå¡åžè£ 眮ã®æŠç¥æé¢å³ã§ããã ïŒïŒäºé£åŒããããŒåå¡åžè£ 眮ãïŒïŒå³åŽå°å ¥
éšïŒ»å¡åžæ¶²ïŒïŒïŒœãïŒïŒå·ŠåŽå°å ¥éšïŒ»å¡åžæ¶²
ïŒïŒïŒœãïŒïŒã¬ã©ã¹æ¿ãïŒïŒæ¯æäœãïŒïŒå¡åžæ¶²
ïŒïŒã®å¡èãïŒïŒå¡åžæ¶²ïŒïŒã®å¡èãïŒïŒç¢
å°ã
æ³ã«äœ¿çšãããå¡åžè£ 眮ã®äžäŸã§ããäºé£åŒãã
ããŒåå¡åžè£ 眮ã®æŠç¥æé¢å³ã§ããã ïŒïŒäºé£åŒããããŒåå¡åžè£ 眮ãïŒïŒå³åŽå°å ¥
éšïŒ»å¡åžæ¶²ïŒïŒïŒœãïŒïŒå·ŠåŽå°å ¥éšïŒ»å¡åžæ¶²
ïŒïŒïŒœãïŒïŒã¬ã©ã¹æ¿ãïŒïŒæ¯æäœãïŒïŒå¡åžæ¶²
ïŒïŒã®å¡èãïŒïŒå¡åžæ¶²ïŒïŒã®å¡èãïŒïŒç¢
å°ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœãšããã®äžã«èšããããèŒå°œæ§èå äœ
ãå«ææ¯æããçµåå€ãããªãèå äœå±€ãšãæã
ãæŸå°ç·åå€æããã«ã«ãããŠã該èå äœå±€ãæ¯
æäœåŽã®èŒå°œæ§èå äœãååšããéšåãšããã«è¡š
é¢åŽã®èŒå°œæ§èå äœãååšããªãéšåãšããæ§æ
ãããäž¡éšåã®éã«å¢çé¢ãååšããããã€è©²èŒ
å°œæ§èå äœãååšããªãéšåã«éå±ã®ç¡æ©å¡©ãã
ãªã垯é»é²æ¢å€ãå«æãããŠããããšãç¹åŸŽãšã
ãæŸå°ç·åå€æããã«ã ïŒ åž¯é»é²æ¢å€ããLiClãNaClãNaBrãNaIã
NaNO3ãNa3PO4ãCsIãMgBr2ãBaBr2ãBaI2
åã³AlBr3ãããªã矀ããéžã°ããå°ãªããšãäž
çš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®æŸå°ç·åå€æããã«ã ïŒ åž¯é»é²æ¢å€ããLiClãNaIãNaBrãMgBr2
ããã³AlBr3ãããªã矀ããéžã°ããå°ãªããšã
äžçš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®æŸå°ç·åå€æããã«ã ïŒ åž¯é»é²æ¢å€ããèå äœå±€äžã«çµåå€ã®éã«å¯Ÿ
ããŠ0.03ä¹è³ïŒééïŒ ã®ç¯å²ã§å«æãããŠããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·åå€æããã«ã ïŒ æ¯æäœåŽã®èŒå°œæ§èå äœãååšããéšåã®å¹³
ååã¿ãšããã«è¡šé¢åŽã®èŒå°œæ§èå äœãååšããª
ãéšåã®å¹³ååã¿ãšã®æ¯çãã100ïŒïŒãïŒïŒïŒ
ã®ç¯å²ã«ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·
åå€æããã«ã ïŒ èå äœå±€ã®çµåå€ã®çµæããæ¯æäœåŽã®èŒå°œ
æ§èå äœãååšããéšåãšãããã«è¡šé¢åŽã®èŒå°œ
æ§èå äœãååšããªãéšåãšã§åäžã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·åå€æããã«ã ïŒ èå äœå±€ã®çµåå€ã®çµæããæ¯æäœåŽã®èŒå°œ
æ§èå äœãååšããéšåãšãããã«è¡šé¢åŽã®èŒå°œ
æ§èå äœãååšããªãéšåãšã§ç°ãªã€ãŠããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·åå€æããã«ã ïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãšéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«æ
ããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«çžæº¶
æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§èŒå°œæ§è
å äœãåæ£ããŠãªãçµåå€æº¶æ¶²ïŒïŒãæ¯æäœåŽ
ãšãªãããã«æ¯æäœè¡šé¢ã«åæã«éå±€å¡åžããã
ãšãç¹åŸŽãšããæŸå°ç·åå€æããã«ã®è£œé æ³ã ïŒ åž¯é»é²æ¢å€ããLiClãNaClãNaBrãNaIã
NaNO3ãNa3PO4ãCsIãMgBr2ãBaBr2ãBaI2
ããã³AlBr3ãããªã矀ããéžã°ããå°ãªããšã
äžçš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®æŸå°ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ 垯é»é²æ¢å€ããLiClãNaIãNaBrã
MgBr2ããã³AlBr3ãããªã矀ããéžã°ããå°ãª
ããšãäžçš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®æŸå°ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ 垯é»é²æ¢å€ããçµåå€æº¶æ¶²ïŒïŒäžã«çµå
å€ã®éã«å¯ŸããŠ0.1ä¹è³20ééïŒ ã®ç¯å²ã§å«æã
ããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·åå€
æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒã®å¡åžéãšåž¯é»é²æ¢å€ãå«æããçµåå€æº¶
液ïŒïŒã®å¡åžéãšã®äœç©æ¯ãã100ïŒïŒãïŒïŒ
ïŒã®ç¯å²ã«ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°
ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒããã³åž¯é»é²æ¢å€ãå«æããçµåå€æº¶æ¶²
ïŒïŒã«ãããçµåå€ããå ±ã«åäžçµæãæãã
ãã®ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°ç·å
å€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒããã³åž¯é»é²æ¢å€ãå«æããçµåå€æº¶æ¶²
ïŒïŒã«ãããçµåå€ããäºãã«ç°ãªãçµæãæ
ãããã®ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æŸå°
ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒãšéå±ã®ç¡æ©å¡©ãããªã垯é»é²æ¢å€ãå«æ
ããçµåå€æº¶æ¶²ïŒïŒãšããããããäºãã«çžæº¶
æ§ãæãã溶åªãçšããŠèª¿è£œãã次ãã§å¹³é¢ã·ãŒ
ãäžã«åæã«éå±€å¡åžããŠèå äœå±€ã圢æããã®
ã¡ã該èå äœå±€ãã·ãŒãããåé¢ããŠæ¯æäœäžã«
ä»èšããããšãç¹åŸŽãšããæŸå°ç·åå€æããã«ã®
補é æ³ã ïŒïŒ 垯é»é²æ¢å€ãLiClãNaClãNaBrãNaIã
NaNO3ãNa3PO4ãCsIãMgBr2ãBaBr2ãBaI2
ããã³AlBr3ãããªã矀ããéžã°ããå°ãªããšã
äžçš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé
èšèŒã®æŸå°ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ 垯é»é²æ¢å€ããLiClãNaIãNaBrã
MgBr2ããã³AlBr3ãããªã矀ããéžã°ããå°ãª
ããšãäžçš®ã®éå±ç¡æ©å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒïŒé èšèŒã®æŸå°ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ 垯é»é²æ¢å€ããçµåå€æº¶æ¶²ïŒïŒäžã«çµå
å€ã®éã«å¯ŸããŠ0.1ä¹è³20ééïŒ ã®ç¯å²ã§å«æã
ããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æŸå°ç·å
å€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒã®å¡åžéãšåž¯é»é²æ¢å€ãå«æããçµåå€æº¶
液ïŒïŒã®å¡åžéãšã®äœç©æ¯ãã100ïŒïŒãïŒïŒ
ïŒã®ç¯å²ã«ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æŸ
å°ç·åå€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒããã³åž¯é»é²æ¢å€ãå«æããçµåå€æº¶æ¶²
ïŒïŒã«ãããçµåå€ããå ±ã«åäžçµæãæãã
ãã®ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æŸå°ç·
åå€æããã«ã®è£œé æ³ã ïŒïŒ èŒå°œæ§èå äœãåæ£ããŠãªãçµåå€æº¶æ¶²
ïŒïŒããã³åž¯é»é²æ¢å€ãå«æããçµåå€æº¶æ¶²
ïŒïŒã«ãããçµåå€ããäºãã«ç°ãªãçµæãæ
ãããã®ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æŸ
å°ç·åå€æããã«ã®è£œé æ³ã
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5667285A JPS61213799A (ja) | 1985-03-20 | 1985-03-20 | æŸå°ç·åå€æããã«ããã³ãã®è£œé æ³ |
| US06/771,122 US4728583A (en) | 1984-08-31 | 1985-08-30 | Radiation image storage panel and process for the preparation of the same |
| DE3587955T DE3587955T2 (de) | 1984-08-31 | 1985-09-02 | Schirm zum Speichern eines Strahlungsbildes. |
| DE8585111030T DE3582206D1 (de) | 1984-08-31 | 1985-09-02 | Schirm zum speichern eines strahlungsbildes und verfahren zur herstellung desselben. |
| EP90100227A EP0377470B1 (en) | 1984-08-31 | 1985-09-02 | Radiation image storage panel |
| EP85111030A EP0173352B1 (en) | 1984-08-31 | 1985-09-02 | Radiation image storage panel and process for the preparation of the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5667285A JPS61213799A (ja) | 1985-03-20 | 1985-03-20 | æŸå°ç·åå€æããã«ããã³ãã®è£œé æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61213799A JPS61213799A (ja) | 1986-09-22 |
| JPH0562720B2 true JPH0562720B2 (ja) | 1993-09-09 |
Family
ID=13033909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5667285A Granted JPS61213799A (ja) | 1984-08-31 | 1985-03-20 | æŸå°ç·åå€æããã«ããã³ãã®è£œé æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61213799A (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003090900A (ja) * | 2001-09-18 | 2003-03-28 | Fuji Photo Film Co Ltd | ã·ãŒãã®è£œé æ¹æ³åã³æŸå°ç·åå€æããã« |
| JP2006084267A (ja) * | 2004-09-15 | 2006-03-30 | Konica Minolta Medical & Graphic Inc | æŸå°ç·åå€æããã«åã³æŸå°ç·åæ®åœ±æ¹æ³ |
-
1985
- 1985-03-20 JP JP5667285A patent/JPS61213799A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61213799A (ja) | 1986-09-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4728583A (en) | Radiation image storage panel and process for the preparation of the same | |
| JPH0631911B2 (ja) | æŸå°ç·åå€æããã« | |
| JPH0444720B2 (ja) | ||
| JPH0444959B2 (ja) | ||
| JPH0314160B2 (ja) | ||
| JP2549911B2 (ja) | æŸå°ç·åå€æããã«ãšãã®è£œé æ³ | |
| JPH0521520B2 (ja) | ||
| JPH0452920B2 (ja) | ||
| JPH0475480B2 (ja) | ||
| JPH0314159B2 (ja) | ||
| JPH0452440B2 (ja) | ||
| JPH0552920B2 (ja) | ||
| JPH0523400B2 (ja) | ||
| JPH0562720B2 (ja) | ||
| JPH0314158B2 (ja) | ||
| JPH0554640B2 (ja) | ||
| JPH0631906B2 (ja) | æŸå°ç·ç»åå€æããã« | |
| JPH0552917B2 (ja) | ||
| JPS61264300A (ja) | æŸå°ç·åå€æããã« | |
| JP2549912B2 (ja) | æŸå°ç·åå€æããã«ã®è£œé æ³ | |
| JP2549913B2 (ja) | æŸå°ç·åå€æããã« | |
| JPH0535840B2 (ja) | ||
| JPS61264299A (ja) | æŸå°ç·åå€æããã« | |
| JPH0562719B2 (ja) | ||
| JPH0523640B2 (ja) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |