JPH0554110B2 - - Google Patents
Info
- Publication number
- JPH0554110B2 JPH0554110B2 JP58166135A JP16613583A JPH0554110B2 JP H0554110 B2 JPH0554110 B2 JP H0554110B2 JP 58166135 A JP58166135 A JP 58166135A JP 16613583 A JP16613583 A JP 16613583A JP H0554110 B2 JPH0554110 B2 JP H0554110B2
- Authority
- JP
- Japan
- Prior art keywords
- general formula
- formula
- group
- dye
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 claims description 34
- 239000000178 monomer Substances 0.000 claims description 30
- 229920002554 vinyl polymer Polymers 0.000 claims description 20
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 18
- 239000000470 constituent Substances 0.000 claims description 14
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 12
- 150000003512 tertiary amines Chemical class 0.000 claims description 12
- -1 n-amyl group Chemical group 0.000 description 48
- 239000000975 dye Substances 0.000 description 43
- 239000010410 layer Substances 0.000 description 36
- 108010010803 Gelatin Proteins 0.000 description 30
- 229920000159 gelatin Polymers 0.000 description 30
- 235000019322 gelatine Nutrition 0.000 description 30
- 235000011852 gelatine desserts Nutrition 0.000 description 30
- 239000008273 gelatin Substances 0.000 description 29
- 239000000126 substance Substances 0.000 description 18
- 239000000839 emulsion Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- 238000007127 saponification reaction Methods 0.000 description 7
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- CZLCEPVHPYKDPJ-UHFFFAOYSA-N guanidine;2,2,2-trichloroacetic acid Chemical compound NC(N)=N.OC(=O)C(Cl)(Cl)Cl CZLCEPVHPYKDPJ-UHFFFAOYSA-N 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 3
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 3
- KFAGFICBFWGIAW-UHFFFAOYSA-M 3-(2-methyl-1,3-benzothiazol-3-ium-3-yl)propanal;bromide Chemical compound [Br-].C1=CC=C2[N+](CCC=O)=C(C)SC2=C1 KFAGFICBFWGIAW-UHFFFAOYSA-M 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 3
- 239000001043 yellow dye Substances 0.000 description 3
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
- ZZXILYOBAFPJNS-UHFFFAOYSA-N 2-octylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=CC=C1O ZZXILYOBAFPJNS-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
- 229940081735 acetylcellulose Drugs 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 150000004693 imidazolium salts Chemical class 0.000 description 2
- 125000002883 imidazolyl group Chemical group 0.000 description 2
- 125000005647 linker group Chemical group 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- VQIQPNAYDOXKST-UHFFFAOYSA-M sodium;4-(2-ethylhexoxy)-4-oxobutanoate Chemical compound [Na+].CCCCC(CC)COC(=O)CCC([O-])=O VQIQPNAYDOXKST-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 1
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003852 3-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C(Cl)=C1[H])C([H])([H])* 0.000 description 1
- IWTYTFSSTWXZFU-UHFFFAOYSA-N 3-chloroprop-1-enylbenzene Chemical compound ClCC=CC1=CC=CC=C1 IWTYTFSSTWXZFU-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- 125000002528 4-isopropyl benzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000004217 4-methoxybenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1OC([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000006181 4-methyl benzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])C([H])([H])* 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical group NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- DFENKTCEEGOWLB-UHFFFAOYSA-N n,n-bis(methylamino)-2-methylidenepentanamide Chemical compound CCCC(=C)C(=O)N(NC)NC DFENKTCEEGOWLB-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 125000004923 naphthylmethyl group Chemical group C1(=CC=CC2=CC=CC=C12)C* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 230000006103 sulfonylation Effects 0.000 description 1
- 238000005694 sulfonylation reaction Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor
- G03C8/56—Mordant layers
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
æ¬çºæã¯åçèŠçŽ ã«é¢ãã詳ããã¯åçèŠçŽ ã«
䜿çšãããè²çŽ ã®ããã®è¯å¥œãªåªæå€ã§ããæ°èŠ
ãªããªããŒæ··åç©ãããã³ãããçšããåçèŠçŽ
ã«é¢ãããããã«è©³ããã¯ãç»åç¶ã«çããæ¡æ£
æ§è²çŽ ãåºå®ããããã®åªæå±€ãããã³ãã®æ°èŠ
ãªåªæå±€ãçšããã«ã©ãŒåçèŠçŽ ã«é¢ããã åçæè¡ã®åéã«ãããŠã¯ãã¢ããªã³æ§è²çŽ ã®
åºå®åã®ããã«ãåªæå±€äžã«ãåçš®ã®ç¬¬åã¢ã³ã¢
ããŠã å¡©ããªããŒã䜿çšããããšã¯ããç¥ãããŠ
ãããã³ãŒãšã³ïŒCohenïŒãã®ç±³åœç¹èš±3709690
å·ãªã©ã«çš®ã ã®ããªããŒåªæå€ãé瀺ãããŠã
ããããããŠãã®çš®ã®åªæå€ã§ã¯è²çŽ ã«å¯Ÿããåª
ææ§ãååã§ãªããããè²çŽ ç»åã®æ¿åºŠãé«ãã
ãããšãå°é£ã§ãã€ãããç»åã®æ¿åºŠãæéãšãš
ãã«äœäžãããªã©ã®æ¬ ç¹ãæã€ãŠããã åªææ§ãæ¹è¯ããããã«ãã³ãŒãšã³ïŒCohenïŒ
ãã«ããç±³åœç¹èš±3898088å·ã«èšèŒã®æ°Žäžæº¶æ§ã
ãªããŒåªæå€ããããã¯ãã€ã³ãã«ïŒCambellïŒ
ãã«ããç±³åœç¹èš±3958995å·ã«èšèŒã®æ°Žåæ£æ§ã
ãªããŒåªæå€ãææ¡ããããããããªãããã®çš®
ã®åªæå€ã¯è²çŽ ã«å¯Ÿãè¯å¥œãªåªææ§ã瀺ããã®
ã®ãåªæãããè²çŽ ãå®å®ãªåœ¢ã§ä¿æããèœåã«
ä¹ãããšããå¥ã®æ¬ ç¹ãæã€ãŠãããããªãã¡ã
ã®çš®ã®åªæå€ã«ããåªæãããè²çŽ ç»åãå«ãå
çã·ã¹ãã ã§ã¯ãè¢å çãããã¯å€ªéœå ãªã©ã®ç §
å°ã«ãããåªæãããè²çŽ ç»åãååŠå€åããã
ã¯å解ãèµ·ããããããšããæ¬ ç¹ããã€ãŠããã åŸã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯åªæãããè²çŽ
ç»åã®ãå ã«ããååŠå€åãŸãã¯å解ã®å°ãªãå
çèŠçŽ ãæäŸããããšã«ããã ãŸã第ïŒã®ç®çã¯ãæ¿åºŠã®é«ãè²çŽ ç»åãäžã
ãåçèŠçŽ ãæäŸããããšã«ããã äžèšã®ç®çã¯ãäžè¬åŒïŒïŒã§è¡šããããã¢ã
ããŒåäœãæ§ææåãšããŠæããããªããŒãšãäž
è¬åŒïŒïŒã§è¡šããããã¢ãããŒåäœãæ§ææå
ãšããŠæããããªããŒãšã®æ··åç©ãåªæå€ãšããŠ
åªæå±€ã«çšããåçèŠçŽ ã«ãã€ãŠéæãããã äžè¬åŒïŒïŒ ïŒâïŒâxïŒâïŒây ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬äžã¢ãã³ãæã
ãããã«ããããŒåäœãè¡šãããã¯ç¬¬äžã¢ãã³
ããã³ç¬¬åã¢ã³ã¢ããŠã å¡©ã®ããããæããªãã
ãã«ã¢ãããŒåäœãè¡šãããïœã¯ïŒãªãã100ã¢
ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ãããã äžè¬åŒïŒïŒ ïŒâïŒâuïŒâïŒâv ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬åã¢ã³ã¢ããŠã
å¡©ãæããããã«ã¢ãããŒåäœãè¡šãããã¯äž
è¬åŒïŒïŒã®ïŒ£ãè¡šãããã®ãšåãã§ãããïœã¯
ïŒãªãã100ã¢ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ã
ããã äžåŒã«ãããŠïŒ¡ãããã¯åã å®çŸ©ãå ã
ãéããïŒçš®é¡ä»¥äžã®ã¢ãããŒãå«ãã§ãããã ããªãã¡ãåŸæ¥ã®ç¬¬åã¢ã³ã¢ããŠã å¡©ããªããŒ
ãåªæå€ãšããŠçšãããšãè²çŽ ã«å¯Ÿããè¯å¥œãªåª
ææ§ã¯åŸãããããåªæãããè²çŽ ç»åããå ã«
ãããååŠå€åãããã¯å解ãåãããããªãã
äžæ¹ç¬¬äžã¢ãã³ããªããŒã¯ãã¢ããªã³æ§è²çŽ ã«å¯Ÿ
ããåªææ§ãèããäœãã ããããã®ïŒçš®ã®ç°ãªãç¹åŸŽãæããåªæå€ã
䜵çšããããšã§ããã®è©³çŽ°ãªçç±ã¯æããã§ã¯ãª
ãããã¢ããªã³æ§è²çŽ ã«å¯Ÿããè¯å¥œãªåªææ§ãšã
åªæãããè²çŽ ãå®å®ã«ä¿æããæ§è³ªãšãåæã«
åããåªæå±€ãåŸãããšãåºæ¥ãã æ¬çºæã®äžè¬åŒïŒïŒã«ãããããã«ã¢ãããŒ
åäœïŒââïŒã¯ãå ·äœçã«ã¯æ¬¡ã®äžè¬åŒïŒïŒããŸ
ãã¯äžè¬åŒïŒïŒã§ç€ºããããã®ã§ããããšã奜
ãŸããã äžè¬åŒïŒïŒ ãåŒäžR1ã¯æ°ŽçŽ ååãŸãã¯ïŒãïŒåã®ççŽ åå
ãæããäœçŽã¢ã«ãã«åºãè¡šãããã¯ïŒã20å
ã®ççŽ ååãæããïŒäŸ¡ã®é£çµåºãè¡šãããã¯
ççŽ ååãšã®äºéçµåãæããçªçŽ ååãæ§ææ
åãšããŠå«ããããç°ãè¡šãããïœã¯ïŒãŸãã¯ïŒ
ã§ãããã äžè¬åŒïŒïŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šãããR4ãR5ã¯ããããåäžãŸãã¯ç°çš®ã®ïŒ
ã12åã®ççŽ ååãæããã¢ã«ãã«åºããããã¯
ïŒã20åã®ççŽ ååãæããã¢ã©ã«ãã«åºãè¡šã
ããR4ãR5ã¯çžäºã«é£çµããŠçªçŽ ååãšãšãã«
ç°ç¶æ§é ã圢æããŠããããïœã¯ïŒãŸãã¯ïŒã§ã
ããã äžè¬åŒïŒïŒã§R1ã¯æ°ŽçŽ ååãããã¯ççŽ æ°
ïŒãïŒåã®äœçŽã¢ã«ãã«åºãäŸãã°ã¡ãã«åºããš
ãã«åºãïœâãããã«åºãïœâããã«åºãïœâã¢
ãã«åºãïœâããã·ã«çãªã©ãè¡šãããæ°ŽçŽ åå
ãããã¯ã¡ãã«åºãç¹ã«å¥œãŸããã ã¯ïŒãçŽ20åã®ççŽ ååãæããäºäŸ¡ã®é£çµ
åºãäŸãã°ã¢ã«ãã¬ã³åºïŒäŸãã°ã¡ãã¬ã³åºããš
ãã¬ã³åºãããªã¡ãã¬ã³åºããããµã¡ãã¬ã³åºãª
ã©ïŒãããšãã¬ã³åºïŒäŸãã°ïŒ¯âããšãã¬ã³åºã
ïœâããšãã¬ã³åºãïœâããšãã¬ã³åºãªã©ïŒãã¢
ãªãŒã¬ã³ã¢ã«ãã¬ã³åºïŒäŸãã°
䜿çšãããè²çŽ ã®ããã®è¯å¥œãªåªæå€ã§ããæ°èŠ
ãªããªããŒæ··åç©ãããã³ãããçšããåçèŠçŽ
ã«é¢ãããããã«è©³ããã¯ãç»åç¶ã«çããæ¡æ£
æ§è²çŽ ãåºå®ããããã®åªæå±€ãããã³ãã®æ°èŠ
ãªåªæå±€ãçšããã«ã©ãŒåçèŠçŽ ã«é¢ããã åçæè¡ã®åéã«ãããŠã¯ãã¢ããªã³æ§è²çŽ ã®
åºå®åã®ããã«ãåªæå±€äžã«ãåçš®ã®ç¬¬åã¢ã³ã¢
ããŠã å¡©ããªããŒã䜿çšããããšã¯ããç¥ãããŠ
ãããã³ãŒãšã³ïŒCohenïŒãã®ç±³åœç¹èš±3709690
å·ãªã©ã«çš®ã ã®ããªããŒåªæå€ãé瀺ãããŠã
ããããããŠãã®çš®ã®åªæå€ã§ã¯è²çŽ ã«å¯Ÿããåª
ææ§ãååã§ãªããããè²çŽ ç»åã®æ¿åºŠãé«ãã
ãããšãå°é£ã§ãã€ãããç»åã®æ¿åºŠãæéãšãš
ãã«äœäžãããªã©ã®æ¬ ç¹ãæã€ãŠããã åªææ§ãæ¹è¯ããããã«ãã³ãŒãšã³ïŒCohenïŒ
ãã«ããç±³åœç¹èš±3898088å·ã«èšèŒã®æ°Žäžæº¶æ§ã
ãªããŒåªæå€ããããã¯ãã€ã³ãã«ïŒCambellïŒ
ãã«ããç±³åœç¹èš±3958995å·ã«èšèŒã®æ°Žåæ£æ§ã
ãªããŒåªæå€ãææ¡ããããããããªãããã®çš®
ã®åªæå€ã¯è²çŽ ã«å¯Ÿãè¯å¥œãªåªææ§ã瀺ããã®
ã®ãåªæãããè²çŽ ãå®å®ãªåœ¢ã§ä¿æããèœåã«
ä¹ãããšããå¥ã®æ¬ ç¹ãæã€ãŠãããããªãã¡ã
ã®çš®ã®åªæå€ã«ããåªæãããè²çŽ ç»åãå«ãå
çã·ã¹ãã ã§ã¯ãè¢å çãããã¯å€ªéœå ãªã©ã®ç §
å°ã«ãããåªæãããè²çŽ ç»åãååŠå€åããã
ã¯å解ãèµ·ããããããšããæ¬ ç¹ããã€ãŠããã åŸã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯åªæãããè²çŽ
ç»åã®ãå ã«ããååŠå€åãŸãã¯å解ã®å°ãªãå
çèŠçŽ ãæäŸããããšã«ããã ãŸã第ïŒã®ç®çã¯ãæ¿åºŠã®é«ãè²çŽ ç»åãäžã
ãåçèŠçŽ ãæäŸããããšã«ããã äžèšã®ç®çã¯ãäžè¬åŒïŒïŒã§è¡šããããã¢ã
ããŒåäœãæ§ææåãšããŠæããããªããŒãšãäž
è¬åŒïŒïŒã§è¡šããããã¢ãããŒåäœãæ§ææå
ãšããŠæããããªããŒãšã®æ··åç©ãåªæå€ãšããŠ
åªæå±€ã«çšããåçèŠçŽ ã«ãã€ãŠéæãããã äžè¬åŒïŒïŒ ïŒâïŒâxïŒâïŒây ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬äžã¢ãã³ãæã
ãããã«ããããŒåäœãè¡šãããã¯ç¬¬äžã¢ãã³
ããã³ç¬¬åã¢ã³ã¢ããŠã å¡©ã®ããããæããªãã
ãã«ã¢ãããŒåäœãè¡šãããïœã¯ïŒãªãã100ã¢
ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ãããã äžè¬åŒïŒïŒ ïŒâïŒâuïŒâïŒâv ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬åã¢ã³ã¢ããŠã
å¡©ãæããããã«ã¢ãããŒåäœãè¡šãããã¯äž
è¬åŒïŒïŒã®ïŒ£ãè¡šãããã®ãšåãã§ãããïœã¯
ïŒãªãã100ã¢ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ã
ããã äžåŒã«ãããŠïŒ¡ãããã¯åã å®çŸ©ãå ã
ãéããïŒçš®é¡ä»¥äžã®ã¢ãããŒãå«ãã§ãããã ããªãã¡ãåŸæ¥ã®ç¬¬åã¢ã³ã¢ããŠã å¡©ããªããŒ
ãåªæå€ãšããŠçšãããšãè²çŽ ã«å¯Ÿããè¯å¥œãªåª
ææ§ã¯åŸãããããåªæãããè²çŽ ç»åããå ã«
ãããååŠå€åãããã¯å解ãåãããããªãã
äžæ¹ç¬¬äžã¢ãã³ããªããŒã¯ãã¢ããªã³æ§è²çŽ ã«å¯Ÿ
ããåªææ§ãèããäœãã ããããã®ïŒçš®ã®ç°ãªãç¹åŸŽãæããåªæå€ã
䜵çšããããšã§ããã®è©³çŽ°ãªçç±ã¯æããã§ã¯ãª
ãããã¢ããªã³æ§è²çŽ ã«å¯Ÿããè¯å¥œãªåªææ§ãšã
åªæãããè²çŽ ãå®å®ã«ä¿æããæ§è³ªãšãåæã«
åããåªæå±€ãåŸãããšãåºæ¥ãã æ¬çºæã®äžè¬åŒïŒïŒã«ãããããã«ã¢ãããŒ
åäœïŒââïŒã¯ãå ·äœçã«ã¯æ¬¡ã®äžè¬åŒïŒïŒããŸ
ãã¯äžè¬åŒïŒïŒã§ç€ºããããã®ã§ããããšã奜
ãŸããã äžè¬åŒïŒïŒ ãåŒäžR1ã¯æ°ŽçŽ ååãŸãã¯ïŒãïŒåã®ççŽ åå
ãæããäœçŽã¢ã«ãã«åºãè¡šãããã¯ïŒã20å
ã®ççŽ ååãæããïŒäŸ¡ã®é£çµåºãè¡šãããã¯
ççŽ ååãšã®äºéçµåãæããçªçŽ ååãæ§ææ
åãšããŠå«ããããç°ãè¡šãããïœã¯ïŒãŸãã¯ïŒ
ã§ãããã äžè¬åŒïŒïŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šãããR4ãR5ã¯ããããåäžãŸãã¯ç°çš®ã®ïŒ
ã12åã®ççŽ ååãæããã¢ã«ãã«åºããããã¯
ïŒã20åã®ççŽ ååãæããã¢ã©ã«ãã«åºãè¡šã
ããR4ãR5ã¯çžäºã«é£çµããŠçªçŽ ååãšãšãã«
ç°ç¶æ§é ã圢æããŠããããïœã¯ïŒãŸãã¯ïŒã§ã
ããã äžè¬åŒïŒïŒã§R1ã¯æ°ŽçŽ ååãããã¯ççŽ æ°
ïŒãïŒåã®äœçŽã¢ã«ãã«åºãäŸãã°ã¡ãã«åºããš
ãã«åºãïœâãããã«åºãïœâããã«åºãïœâã¢
ãã«åºãïœâããã·ã«çãªã©ãè¡šãããæ°ŽçŽ åå
ãããã¯ã¡ãã«åºãç¹ã«å¥œãŸããã ã¯ïŒãçŽ20åã®ççŽ ååãæããäºäŸ¡ã®é£çµ
åºãäŸãã°ã¢ã«ãã¬ã³åºïŒäŸãã°ã¡ãã¬ã³åºããš
ãã¬ã³åºãããªã¡ãã¬ã³åºããããµã¡ãã¬ã³åºãª
ã©ïŒãããšãã¬ã³åºïŒäŸãã°ïŒ¯âããšãã¬ã³åºã
ïœâããšãã¬ã³åºãïœâããšãã¬ã³åºãªã©ïŒãã¢
ãªãŒã¬ã³ã¢ã«ãã¬ã³åºïŒäŸãã°
ãåŒããããã¯
ãåŒã
ãªã©ãäœãR2ã¯ççŽ æ°ïŒãçŽ12ã®ã¢ã«ãã¬ã³åº
ãè¡šãããïŒãâCO2âãâCO2âR3âïŒäœãR3ã¯ã¢
ã«ãã¬ã³åºãããšãã¬ã³åºãã¢ãªãŒã¬ã³ã¢ã¬ãã¬
ã³åºãè¡šãããïŒãâCONHâR3âïŒäœãR3ã¯äžèš
ãšåããã®ãè¡šãããïŒã
ãè¡šãããïŒãâCO2âãâCO2âR3âïŒäœãR3ã¯ã¢
ã«ãã¬ã³åºãããšãã¬ã³åºãã¢ãªãŒã¬ã³ã¢ã¬ãã¬
ã³åºãè¡šãããïŒãâCONHâR3âïŒäœãR3ã¯äžèš
ãšåããã®ãè¡šãããïŒã
ãåŒãïŒäœã
R1ãR3ã¯äžèšãšåããã®ãè¡šãããïŒãªã©ãè¡šã
ãã
ãã
ãåŒã
ãåŒãâ
CO2âãâCONHâãâCO2âCH2CH2âãâCO2
âCH2CH2CH2âãâCONHCH2âãâ
CONHCH2CH2âãâCONHCH2CH2CH2âãªã©
ãç¹ã«å¥œãŸããã ã¯ççŽ ååãšã®äºéçµåãæããçªçŽ ååã
æ§ææåãšããŠå«ããããç°ãäŸãã°ã€ãããŸãŒ
ã«ç°ïŒäŸãã°
âCH2CH2CH2âãâCONHCH2âãâ
CONHCH2CH2âãâCONHCH2CH2CH2âãªã©
ãç¹ã«å¥œãŸããã ã¯ççŽ ååãšã®äºéçµåãæããçªçŽ ååã
æ§ææåãšããŠå«ããããç°ãäŸãã°ã€ãããŸãŒ
ã«ç°ïŒäŸãã°
ãåŒã
ãåŒããªã©ãïŒãããª
ã¢ãŸãŒã«ç°ïŒäŸãã°
ãåŒã
ãªã©ãïŒããã©ãŸãŒã«ç°ïŒäŸãã°
ãåŒã
ãåŒããªã©ãïŒãããªãžã³ç°ïŒäŸãã°
ãåŒã
ãåŒããªã©ãïŒãããª
ããžã³ç°ïŒäŸãã°
ãåŒããªã©ãïŒãªã©ã
è¡šãããã€ãããŸãŒã«ç°ãç¹ã«å¥œãŸããã
äžè¬åŒïŒïŒã§è¡šãããã奜ãŸããã¢ãããŒå
äœã®å ·äœäŸã以äžã«ç€ºãã
äœã®å ·äœäŸã以äžã«ç€ºãã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
äžè¬åŒïŒïŒã§R4ãR5ã¯ïŒã12åã®ççŽ åå
ãæããã¢ã«ãã«åºãäŸãã°ç¡çœ®æã¢ã«ãã«åº
ïŒã¡ãã«åºããšãã«åºãïœâãããã«åºãïœâã
ãã«åºãïœâã¢ãã«åºãããã·ã«åºãïœâããã«
åºãïœâãã·ã«åºãïœâããã·ã«åºãªã©ãïŒã眮æ
ã¢ã«ãã«åºïŒã¡ããã·ãšãã«åºãïŒâã·ã¢ããã
ãã«åºããšããã·ã«ã«ããã«ãšãã«åºãã¢ã»ãã
ã·ãšãã«åºãããããã·ãšãã«åºãïŒâãããã«
åºãªã©ãïŒããããã¯ïŒã20åã®ççŽ ååãæãã
ã¢ã©ã«ãã«åºãäŸãã°ç¡çœ®æã¢ã©ã«ãã«åºïŒãã³
ãžã«åºãããšããã«åºããžããšãã«ã¡ãã«åºãã
ããã«ã¡ãã«åºãªã©ãïŒã眮æã¢ã©ã«ãã«åºïŒïŒâ
ã¡ãã«ãã³ãžã«åºãïŒâã€ãœãããã«ãã³ãžã«
åºãïŒâã¡ããã·ãã³ãžã«åºãïŒâïŒïŒâã¡ãã
ã·ããšãã«ïŒãã³ãžã«åºãïŒâã¯ãããã³ãžã«åº
ãªã©ãïŒãªã©ãè¡šããã ãŸãR4ãR5ãçžäºã«é£çµããŠçªçŽ ååãšãšã
ã«ç°ç¶æ§é ã圢æããäŸãšããŠãäŸãã°
ãæããã¢ã«ãã«åºãäŸãã°ç¡çœ®æã¢ã«ãã«åº
ïŒã¡ãã«åºããšãã«åºãïœâãããã«åºãïœâã
ãã«åºãïœâã¢ãã«åºãããã·ã«åºãïœâããã«
åºãïœâãã·ã«åºãïœâããã·ã«åºãªã©ãïŒã眮æ
ã¢ã«ãã«åºïŒã¡ããã·ãšãã«åºãïŒâã·ã¢ããã
ãã«åºããšããã·ã«ã«ããã«ãšãã«åºãã¢ã»ãã
ã·ãšãã«åºãããããã·ãšãã«åºãïŒâãããã«
åºãªã©ãïŒããããã¯ïŒã20åã®ççŽ ååãæãã
ã¢ã©ã«ãã«åºãäŸãã°ç¡çœ®æã¢ã©ã«ãã«åºïŒãã³
ãžã«åºãããšããã«åºããžããšãã«ã¡ãã«åºãã
ããã«ã¡ãã«åºãªã©ãïŒã眮æã¢ã©ã«ãã«åºïŒïŒâ
ã¡ãã«ãã³ãžã«åºãïŒâã€ãœãããã«ãã³ãžã«
åºãïŒâã¡ããã·ãã³ãžã«åºãïŒâïŒïŒâã¡ãã
ã·ããšãã«ïŒãã³ãžã«åºãïŒâã¯ãããã³ãžã«åº
ãªã©ãïŒãªã©ãè¡šããã ãŸãR4ãR5ãçžäºã«é£çµããŠçªçŽ ååãšãšã
ã«ç°ç¶æ§é ã圢æããäŸãšããŠãäŸãã°
ãåŒãïŒäœãïœã¯ïŒã12ã®æŽæ°ãè¡š
ãããïŒã
ãåŒããªã©ãæããããã
äžè¬åŒïŒïŒã§è¡šãããã奜ãŸããã¢ãããŒå
äœã®å ·äœäŸã以äžã«ç€ºãã æ¬çºæã®äžè¬åŒïŒïŒããã³ïŒïŒã«ãããã
ãã«ã¢ãããŒåäœïŒââïŒããã³ïŒââïŒã¯ããã
ã
第äžã¢ãã³ã第åã¢ã³ã¢ããŠã ã®ããããæããª
ãããã«ã¢ãããŒåäœãè¡šããããã®äžã§ãè·é
ããããªããã®ã奜ãŸããã ããã«ã¢ãããŒåäœïŒââïŒãšããŠå¥œãŸããäŸ
ã¯ãäŸãã°ãšãã¬ã³ããããã¬ã³ãïŒâããã³ã
ã€ãœããã³ãã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãã
ãã«ãã«ãšã³ãèèªæé žã®ã¢ããšãã¬ã³æ§äžé£œå
ãšã¹ãã«ïŒäŸãã°é ¢é žããã«ãé ¢é žã¢ãªã«ãª
ã©ãïŒãèèªæé žã®ã¢ããšãã¬ã³æ§äžé£œåã¢ãã
ïŒäŸãã°ïŒ®âããã«ã¢ã»ã¿ãããâããã«ãã
ãªãã³ãªã©ãïŒããšãã¬ã³æ§äžé£œåã®ã¢ãã«ã«ãã³
é žãããã¯ãžã«ã«ãã³é žã®ãšã¹ãã«ïŒäŸãã°ãã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâ
ããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒ
ãããã³ãžã«ã¢ã¯ãªã¬ãŒãããžãšãã«ãã¬ãšãŒ
ãããžãšãã«ã€ã¿ã³ããŒããªã©ãïŒããšãã¬ã³æ§äž
飜åã®ã¢ãã«ã«ãã³é žã¢ããïŒäŸãã°ã¢ã¯ãªã«ã¢
ããããžã¡ãã«ã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ã
ãããžã¢ã»ãã³ã¢ã¯ãªã«ã¢ãããã¢ã¯ãªãã€ã«ã¢
ã«ããªã³ãªã©ãïŒãã¢ããšãã¬ã³æ§äžé£œåååç©
ïŒäŸãã°ã¢ã¯ãªããããªã«ïŒããŸãã¯ãžãšã³é¡ïŒäŸ
ãã°ãã¿ãžãšã³ãã€ãœãã¬ã³ãªã©ãïŒãªã©ã§ããã
ãã®ãã¡ã¹ãã¬ã³ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
ã®ãšã¹ãã«ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢ãã
ãªã©ãç¹ã«å¥œãŸããã ãŸãäžè¬åŒïŒïŒãŸãã¯ïŒïŒã§è¡šããããã¢
ãããŒåäœãæ§ææåãšããŠæããããªããŒãæ¶
æ©ã©ããã¯ã¹ãšããå Žåãããã«ã¢ãããŒåäœïŒâ
âïŒãŸãã¯ïŒââïŒã¯ã第äžã¢ãã³ããã³ç¬¬åã¢ã³
ã¢ããŠã ãããããæããªãããã«ã¢ãããŒåäœ
ã§ãå ±éåå¯èœãªäžé£œåçµåãïŒååäžã«ïŒå以
äžæãããã®ãçšããããšãã§ããããã®ããã«
ã¢ãããŒåäœã®å¥œãŸããå ·äœäŸã¯ãžããã«ãã³ãŒ
ã³ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããã
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããã¡ãã¬ã³ã
ã¹ã¢ã¯ãªã«ã¢ããããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãª
ã¬ãŒããçã§ããããã®äžã§ãžããã«ãã³ãŒã³ã
ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããç¹ã«å¥œãŸããã äžè¬åŒïŒïŒã«ãããŠïœã¯ïŒãªãã100ã¢ã«ïŒ ã
ïœã¯ïŒãªãã98ã¢ã«ïŒ ã奜ãŸããã¯ïœã¯60ãªãã
100ã¢ã«ïŒ ãïœã¯ïŒãªãã40ã¢ã«ïŒ ã§ããã æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããã¢ãããŒå
äœãæ§ææåãšããŠæããããªããŒã®å¥œãŸããå ·
äœäŸã以äžã«ç€ºãã âïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâ10 â11 â12 æ¬çºæã®äžè¬åŒïŒïŒã«ãããããã«ã¢ãããŒ
åäœïŒââïŒã¯ãå ·äœçã«ã¯æ¬¡ã®äžè¬åŒïŒïŒãã
ããã¯äžè¬åŒïŒïŒã§ç€ºããããã®ã§ããããšã
奜ãŸããã äžè¬åŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šããã ã¯åçŽåããããã€ççŽ ååãšã®äº
éçµåãæããçªçŽ ååãæ§ææåãšããŠå«ãã
ããç°ãè¡šããã ã¯äžäŸ¡ã®é°ã€ãªã³ãè¡šã
ããïœã¯ïŒãŸãã¯ïŒã§ãããã äžè¬åŒïŒïŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šãããR4ãR5ã¯äžè¬åŒïŒïŒãšåããã®ãè¡š
ãããR6ã¯R4ãR5ãè¡šããã®ãšåããã®ã®äžã
ãéžã°ããã ã¯äžè¬åŒïŒïŒãšåããã®ãè¡š
ãããR4ãR5ãR6ã¯çžäºã«é£çµããŠçªçŽ ååãš
ãšãã«ç°ç¶æ§é ã圢æããŠããããïœã¯ïŒãŸãã¯
ïŒã§ãããã äžè¬åŒïŒïŒã§ã ã¯åçŽåããããã€ççŽ
ãšã®äºéçµåãæããçªçŽ ååãæ§ææåãšããŠ
å«ããããç°ãè¡šããããã®äŸã¯ã€ãããŸãªãŠã
å¡©ïŒ
äœã®å ·äœäŸã以äžã«ç€ºãã æ¬çºæã®äžè¬åŒïŒïŒããã³ïŒïŒã«ãããã
ãã«ã¢ãããŒåäœïŒââïŒããã³ïŒââïŒã¯ããã
ã
第äžã¢ãã³ã第åã¢ã³ã¢ããŠã ã®ããããæããª
ãããã«ã¢ãããŒåäœãè¡šããããã®äžã§ãè·é
ããããªããã®ã奜ãŸããã ããã«ã¢ãããŒåäœïŒââïŒãšããŠå¥œãŸããäŸ
ã¯ãäŸãã°ãšãã¬ã³ããããã¬ã³ãïŒâããã³ã
ã€ãœããã³ãã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãã
ãã«ãã«ãšã³ãèèªæé žã®ã¢ããšãã¬ã³æ§äžé£œå
ãšã¹ãã«ïŒäŸãã°é ¢é žããã«ãé ¢é žã¢ãªã«ãª
ã©ãïŒãèèªæé žã®ã¢ããšãã¬ã³æ§äžé£œåã¢ãã
ïŒäŸãã°ïŒ®âããã«ã¢ã»ã¿ãããâããã«ãã
ãªãã³ãªã©ãïŒããšãã¬ã³æ§äžé£œåã®ã¢ãã«ã«ãã³
é žãããã¯ãžã«ã«ãã³é žã®ãšã¹ãã«ïŒäŸãã°ãã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâ
ããã«ã¢ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒ
ãããã³ãžã«ã¢ã¯ãªã¬ãŒãããžãšãã«ãã¬ãšãŒ
ãããžãšãã«ã€ã¿ã³ããŒããªã©ãïŒããšãã¬ã³æ§äž
飜åã®ã¢ãã«ã«ãã³é žã¢ããïŒäŸãã°ã¢ã¯ãªã«ã¢
ããããžã¡ãã«ã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ã
ãããžã¢ã»ãã³ã¢ã¯ãªã«ã¢ãããã¢ã¯ãªãã€ã«ã¢
ã«ããªã³ãªã©ãïŒãã¢ããšãã¬ã³æ§äžé£œåååç©
ïŒäŸãã°ã¢ã¯ãªããããªã«ïŒããŸãã¯ãžãšã³é¡ïŒäŸ
ãã°ãã¿ãžãšã³ãã€ãœãã¬ã³ãªã©ãïŒãªã©ã§ããã
ãã®ãã¡ã¹ãã¬ã³ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
ã®ãšã¹ãã«ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢ãã
ãªã©ãç¹ã«å¥œãŸããã ãŸãäžè¬åŒïŒïŒãŸãã¯ïŒïŒã§è¡šããããã¢
ãããŒåäœãæ§ææåãšããŠæããããªããŒãæ¶
æ©ã©ããã¯ã¹ãšããå Žåãããã«ã¢ãããŒåäœïŒâ
âïŒãŸãã¯ïŒââïŒã¯ã第äžã¢ãã³ããã³ç¬¬åã¢ã³
ã¢ããŠã ãããããæããªãããã«ã¢ãããŒåäœ
ã§ãå ±éåå¯èœãªäžé£œåçµåãïŒååäžã«ïŒå以
äžæãããã®ãçšããããšãã§ããããã®ããã«
ã¢ãããŒåäœã®å¥œãŸããå ·äœäŸã¯ãžããã«ãã³ãŒ
ã³ããšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããã
ãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããã¡ãã¬ã³ã
ã¹ã¢ã¯ãªã«ã¢ããããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãª
ã¬ãŒããçã§ããããã®äžã§ãžããã«ãã³ãŒã³ã
ãšãã¬ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãããšãã¬ã³
ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒããç¹ã«å¥œãŸããã äžè¬åŒïŒïŒã«ãããŠïœã¯ïŒãªãã100ã¢ã«ïŒ ã
ïœã¯ïŒãªãã98ã¢ã«ïŒ ã奜ãŸããã¯ïœã¯60ãªãã
100ã¢ã«ïŒ ãïœã¯ïŒãªãã40ã¢ã«ïŒ ã§ããã æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããã¢ãããŒå
äœãæ§ææåãšããŠæããããªããŒã®å¥œãŸããå ·
äœäŸã以äžã«ç€ºãã âïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâïŒ ïŒŽâ10 â11 â12 æ¬çºæã®äžè¬åŒïŒïŒã«ãããããã«ã¢ãããŒ
åäœïŒââïŒã¯ãå ·äœçã«ã¯æ¬¡ã®äžè¬åŒïŒïŒãã
ããã¯äžè¬åŒïŒïŒã§ç€ºããããã®ã§ããããšã
奜ãŸããã äžè¬åŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šããã ã¯åçŽåããããã€ççŽ ååãšã®äº
éçµåãæããçªçŽ ååãæ§ææåãšããŠå«ãã
ããç°ãè¡šããã ã¯äžäŸ¡ã®é°ã€ãªã³ãè¡šã
ããïœã¯ïŒãŸãã¯ïŒã§ãããã äžè¬åŒïŒïŒ ãåŒäžR1ããïœã¯äžè¬åŒïŒïŒãšåããã®ã
è¡šãããR4ãR5ã¯äžè¬åŒïŒïŒãšåããã®ãè¡š
ãããR6ã¯R4ãR5ãè¡šããã®ãšåããã®ã®äžã
ãéžã°ããã ã¯äžè¬åŒïŒïŒãšåããã®ãè¡š
ãããR4ãR5ãR6ã¯çžäºã«é£çµããŠçªçŽ ååãš
ãšãã«ç°ç¶æ§é ã圢æããŠããããïœã¯ïŒãŸãã¯
ïŒã§ãããã äžè¬åŒïŒïŒã§ã ã¯åçŽåããããã€ççŽ
ãšã®äºéçµåãæããçªçŽ ååãæ§ææåãšããŠ
å«ããããç°ãè¡šããããã®äŸã¯ã€ãããŸãªãŠã
å¡©ïŒ
ãåŒã
ãåŒããª
ã©ãïŒãããªã¢ãŸãªãŠã å¡©ïŒäŸãã°
ãåŒããªã©ãïŒãããªãžããŠã å¡©ïŒäŸã
ã°
ãåŒã
ãåŒããªã©ãïŒãª
ã©ã§ããããã®ãã¡ã€ãããŸãªãŠã å¡©ãããªãžã
ãŠã å¡©ãç¹ã«å¥œãŸãããããã§R4ã¯äžè¬åŒïŒïŒ
ãšåããã®ãè¡šãããã¡ãã«åºããšãã«åºããã³
ãžã«åºãç¹ã«å¥œãŸããã  ã¯é°ã€ãªã³ãè¡šãããäŸãã°ããã²ã³ã€ãª
ã³ïŒäŸãã°å¡©çŽ ã€ãªã³ãèçŽ ã€ãªã³ããšãŠçŽ ã€ãª
ã³ïŒãã¢ã«ãã«ç¡«é žã€ãªã³ïŒäŸãã°ã¡ãã«ç¡«é žã€
ãªã³ããšãã«ç¡«é žã€ãªã³ïŒãã¢ã«ãã«ãããã¯ã¢
ãªãŒã«ã¹ã«ãã³é žã€ãªã³ïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³
é žããšã¿ã³ã¹ã«ãã³é žããã³ãŒã³ã¹ã«ãã³é žãïœ
âãã«ãšã³ã¹ã«ãã³é žïŒãé ¢é žã€ãªã³ãç¡«é žã€ãª
ã³ãªã©ã®äŸãæããããç¹ã«å¡©çŽ ã€ãªã³ãïœâã
ã«ãšã³ã¹ã«ãã³é žã€ãªã³ã奜ãŸããã äžè¬åŒïŒïŒã§ç€ºããã奜ãŸããããã«ã¢ãã
ãŒåäœïŒââïŒã®å ·äœäŸã以äžã«ç€ºãã ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ äžè¬åŒïŒïŒã§ãR4ãR5ãçžäºã«é£çµããŠçª
çŽ ååãšãšãã«ç°ç¶æ§é ã圢æããäŸãšããŠãäŸ
ãã°
ãŠã å¡©ãç¹ã«å¥œãŸãããããã§R4ã¯äžè¬åŒïŒïŒ
ãšåããã®ãè¡šãããã¡ãã«åºããšãã«åºããã³
ãžã«åºãç¹ã«å¥œãŸããã  ã¯é°ã€ãªã³ãè¡šãããäŸãã°ããã²ã³ã€ãª
ã³ïŒäŸãã°å¡©çŽ ã€ãªã³ãèçŽ ã€ãªã³ããšãŠçŽ ã€ãª
ã³ïŒãã¢ã«ãã«ç¡«é žã€ãªã³ïŒäŸãã°ã¡ãã«ç¡«é žã€
ãªã³ããšãã«ç¡«é žã€ãªã³ïŒãã¢ã«ãã«ãããã¯ã¢
ãªãŒã«ã¹ã«ãã³é žã€ãªã³ïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³
é žããšã¿ã³ã¹ã«ãã³é žããã³ãŒã³ã¹ã«ãã³é žãïœ
âãã«ãšã³ã¹ã«ãã³é žïŒãé ¢é žã€ãªã³ãç¡«é žã€ãª
ã³ãªã©ã®äŸãæããããç¹ã«å¡©çŽ ã€ãªã³ãïœâã
ã«ãšã³ã¹ã«ãã³é žã€ãªã³ã奜ãŸããã äžè¬åŒïŒïŒã§ç€ºããã奜ãŸããããã«ã¢ãã
ãŒåäœïŒââïŒã®å ·äœäŸã以äžã«ç€ºãã ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ äžè¬åŒïŒïŒã§ãR4ãR5ãçžäºã«é£çµããŠçª
çŽ ååãšãšãã«ç°ç¶æ§é ã圢æããäŸãšããŠãäŸ
ãã°
ãåŒãïŒäœãïœã¯ïŒã12ã®æŽ
æ°ãè¡šãããïŒã
ãåŒããªã©ãæãã
ããR4ãR5ãR6ã«ããç°ç¶æ§é ã圢æããäŸãš
ããŠãäŸãã°
ããŠãäŸãã°
ãåŒããªã©ãæããããã
äžè¬åŒïŒïŒã§ç€ºããã奜ãŸããããã«ã¢ãã
ãŒåäœïŒââïŒã®å ·äœäŸã以äžã«ç€ºãã ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ äžè¬åŒïŒïŒã«ãããŠãïœã¯ïŒãªãã100ã¢ã«
ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã奜ãŸããã¯ïœã¯40ãª
ãã100ã¢ã«ïŒ ãïœã¯ïŒãªãã60ã¢ã«ïŒ ã§ããã æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããã¢ãããŒå
äœãæ§ææåãšããŠæããããªããŒã®å¥œãŸããå ·
äœäŸã以äžã«ç€ºãã âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±â10 ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ æ¬çºæã®äžè¬åŒïŒïŒãããã¯ïŒïŒã§è¡šãã
ããã¢ãããŒåäœãæ§ææåãšããŠæããããªã
ãŒã®ååéã¯ãåçç¹æ§ãå¡åžé©æ£ãªã©ã®ç¹ãã
10000以äžã§ããããšã奜ãŸããããŸããã®ããª
ããŒã溶液ãšããŠäœ¿çšããå Žåã«ã¯ãå¡åžæ§ã®ç¹
ãããååéã¯1000000以äžãç¹ã«300000以äžã§
ããããšã奜ãŸããããããã«ã¢ãããŒåäœïŒâ
âïŒãããã¯ïŒââïŒãšããŠå ±éåå¯èœãªäžé£œåçµå
ãïŒååäžã«ïŒå以äžæããããã«ã¢ãããŒåäœ
ã䜿çšããå Žåã«ã¯ãããªããŒã®ååéã¯ç¡é倧
ãšãªããå¡åžæ§ã®ç¹ãããåæ£ç©ãšããŠäœ¿çšãã
ãã 次ã®å®æœäŸã§æ¬çºæã®å ·äœäŸãããã«èª¬æã
ãã åæäŸ ïŒ ããªïŒïŒ®âããã«ã€ãããŸãŒã«ïŒïŒŽâïŒã®åæ 300mlã®åå¿å®¹åšã«ïŒ®âããã«ã€ãããŸãŒã«94
ïœãDMF94ïœãå ããçªçŽ ã¬ã¹ã§ååã«çœ®æã
60âã«å ç±ããã枩床ãäžå®ã«ãªã€ããšããã§
ïŒïŒ2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ããã
ãªã«ïŒã1.243ïœæ·»å ããã次ãã§ïŒæéåŸã«ïŒïŒ
2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããª
ã«ïŒã1.243ïœæ·»å ããæŽã«ïŒæéå ç±ãç¶ããã
åå¿æº¶æ¶²ã宀枩ãŸã§å·åŽããåŸãïŒã®ã¢ã»ãã³
äžã«å ããæåºããæ²æŸ±ãåããç空也ç¥ããŠ
90ïœã®çœè²ããªããŒãåŸããåç96ïŒ åæäŸ ïŒ ããªïŒïŒ®âïŒïŒ®âãžã¡ãã«ã¢ãããããã«ã¢ã¯
ãªã«ã¢ããïŒïŒŽâïŒã®åæ 500mlã®åå¿å®¹åšã«ïŒ®ïŒïŒ®âãžã¡ãã«ã¢ããã
ããã«ã¢ã¯ãªã«ã¢ãã156.26ïœããšã¿ããŒã«450
mlãå ããçªçŽ ã¬ã¹ã§ååè±æ°ããåŸ80âã«å ç±
ããïŒïŒ2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ã
ãããªã«ïŒ1.25ïœãæ·»å ãããããã«ïŒæéåŸã«
ãåããã®ã1.25ïœæ·»å ãããã®åŸïŒæé30åå
ç±ãæ¹æãç¶ãããåå¿è©Šæã宀枩ãŸã§å·åŽãã
èžçæ°Ž300mlãå ããã»ã«ããŒã¹ã®éææäžã«å ¥
ãïŒæ¥ééæãç¶ããåçµä¹Ÿç¥ã«ãããçœè²ããª
ããŒ140.1ïœãåŸããåç89.7ïŒ åæäŸ ïŒ ããªïŒïŒ®âãã³ãžã«ã€ãããŸãªãŠã ã¯ããªãïŒ
âïŒã®åæ åæäŸïŒã§åŸãããªïŒïŒ®âããã«ã€ãããŸãŒ
ã«ïŒ24ïœãDMF220ïœããšã¿ããŒã«20ïœãæ··å
ãã90âã«å ç±ããã次ãã§ããã³ãžã«ã¯ãã©ã€
ã40ïœãåŸã ã«æ»ŽäžããïŒæéå ç±ããããã®å
å¿æ¶²ã3.5ã®ã¢ã»ãã³ã«å ããæåºçµæ¶ãå
ããç空也ç¥ããŠ51ïœã®çœè²ããªããŒãåŸããå
ç92.4ïŒ åæäŸ ïŒ ããªïŒã¹ãã¬ã³âã³ââã¡ãã«ââããã«
ãã³ãžã«ãããªãžããŠã ã¯ããªãâã³âãžãã
ã«ãã³ãŒã³ïŒïŒ±âïŒã®åæ ç¹éæ53â30328èšèŒã®æ¹æ³ã«ããåæããã åæäŸ ïŒ ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã¢ã«ã
ãªããŠã ã¯ããªãâã³âãžããã«ãã³ãŒã³ïŒïŒ±
âïŒã®åæ (i) ããªïŒãžããã«ãã³ãŒã³âã³âã¯ããã¡ãã«
ã¹ãã¬ã³ïŒéåäœåæ£ç©ã®åæ åå¿å®¹åšã«350mlã®èžçæ°Žãå ¥ããçªçŽ ã¬ã¹
ã§è±æ°ããããªãã³770 10mlãã¯ããã¡ãã«ã¹
ãã¬ã³58.0ïœïŒ0.38ã¢ã«ïŒããžããã«ãã³ãŒã³
2.6ïœïŒ0.02ã¢ã«ïŒãå ãã60âã«å ç±ããã
çªçŽ ã¬ã¹ã«ããè±æ°ãããèžçæ°Ž20mlã«éç¡«é ž
ã«ãªãŠã 1.00ïœãå ãããã®ããã³è±æ°ããã
èžçæ°Ž10mlã«äºç¡«é žæ°ŽçŽ ãããªãŠã 0.38ïœãå
ãããã®ãåæã«å ããïŒæéå ç±æ¹æãç¶ã
ãããã®åŸãäžèšã®æ··åç©ã宀枩ãŸã§å·åŽãã
éããŠéåäœåæ£ç©ïŒã©ããã¯ã¹ïŒãåŸãã (ii) åçŽååå¿ åå¿å®¹åšã«ãåºååæ¿åºŠ14.0ïŒ ãæããäžèš
ã®ã©ããã¯ã¹150ïœãèžçæ°Ž50ïœãå ãã宀枩
ã§ãâã¡ãã«ã¢ã«ããªã³11.2ïœãæ·»å ããã
ãã®åŸ70âã«ãã€ãããšææž©ããïŒæéå ç±æ¹
æããã宀枩ãŸã§å·åŽåŸéããŠéåäœåæ£ç©
åªæå€ãåŸãã åºååæ¿åºŠïŒ14.0wtïŒ æ¬çºæã®åªæå±€ã«å«ãŸããäžè¬åŒïŒïŒã§è¡šã
ãããã¢ãããŒåäœãæ§ææåãšããŠæããããª
ããŒãšãäžè¬åŒïŒïŒã§è¡šããããã¢ãããŒåäœ
ãæ§ææåãšããŠæããããªããŒãšã®æ··åæ¯
ïŒïŒïŒïŒïŒïŒïŒã¯ã奜ãŸããã¯ééæ¯ã§0.1ã
10ã奜ãŸããã¯0.2ãïŒã®éã§ããã æ¬çºæã®ããªããŒæ··åç©åªæå€ãšãã€ã³ããŒã®
æ··åæ¯ããã³ããªããŒæ··åç©åªæå€ã®å¡åžéã¯ã
åªæãããã¹ãè²çŽ ã®éãããªããŒæ··åç©åªæå€
ã®çš®é¡ãçµæãæŽã«çšããããç»å圢æéçšãªã©
ã«å¿ããŠãåœæ¥è ã容æã«å®ããããšãã§ãã
ããåªæå€ïŒãŒã©ãã³æ¯ã20ïŒ80ã80ïŒ20ïŒéé
æ¯ïŒãåªæå€å¡åžéã¯0.2ã15ïœïŒm2奜ãŸããã¯
0.5ãïŒïœïŒm2ã§äœ¿çšããã®ã奜ãŸããã æ¬çºæã«çšããããåªæå±€äžã®ãã€ã³ããŒã¯å
ç¬ã§ãããã¯çµã¿åãããŠå«æããããšãã§ã
ãããã®ãã€ã³ããŒã«ã¯ã芪氎æ§ã®ãã®ãçšãã
ããšãã§ããã芪氎æ§ãã€ã³ããŒãšããŠã¯ãéæ
ãåéæã®èŠªæ°Žæ§ã³ãã€ãã代衚çã§ãããäŸã
ã°ãŒã©ãã³ããŒã©ãã³èªå°äœãããªããã«ã¢ã«ã³
ãŒã«ãã»ã«ããŒã¹èªå°äœçã®ã¿ã³ãã¯è³ªããã³ã
ã³ãã¢ã©ãã¢ãŽã çã®å€ç³é¡ã®ãããªå€©ç¶ç©è³ªãš
ããªããã«ãããªãã³ãã¢ã¯ãªã«ã¢ããéåäœã®
氎溶æ§ããªããã«ååç©ã®ãããªåæéåç©è³ªã
å«ãã ãã®äžã§ãç¹ã«ãŒã©ãã³ãããªããã«ã¢ã«ã³ãŒ
ã«ãæå¹ã«äœ¿çšã§ãããåªæå±€ã«äœ¿çšãããŒã©ã
ã³ã¯å ¬ç¥ã®åçš®ã®ãŒã©ãã³ãçšãããããäŸãã°
ç³ç°åŠçãŒã©ãã³ãé žåŠçãŒã©ãã³ãªãŒã©ãã³ã®
補é æ³ã®ç°ãªããã®ãããããã¯ãåŸããããã
ãã®ãŒã©ãã³ãååŠçã«ããã¿ã«åãã¹ã«ããã«
åãªã©ã®å€æ§ãè¡ãªã€ããŒã©ãã³ãçšããããšã
ã§ããããŸãå¿ èŠãªå Žåã«ã¯ãè±å¡©åŠçãè¡ãªã€
ãŠäœ¿çšããããšãã§ããã åªæå±€ã«äœ¿çšããããªããã«ã¢ã«ã³ãŒã«ã¯ãå ¬
ç¥ã®åçš®ã®ããªããã«ã¢ã«ã³ãŒã«ãçšããããã
ããªããã«ã¢ã«ã³ãŒã«ã¯çš®ã ã®ã±ã³å床ãéå床
ã®ãã®ãçšãããããã±ã³å床ã¯å¥œãŸããã¯70ïŒ
以äžãç¹ã«å¥œãŸããã¯80ïŒ ä»¥äžã®ãã®ãçšããã
ããéå床ã¯å¥œãŸããã¯300ã2000ã®ãã®ãçšã
ãããã ã±ã³å床ãéå床ãç°ãªããã®ã䜵çšããŠçšã
ãããšãã§ããã ãŸãã±ã³åæ³ã«ã€ããŠã¯é žã±ã³åæ³ãã¢ã«ã«ãª
ã±ã³åæ³ã®ïŒã€ãããããããã®ã±ã³ååŠçãæœ
ãããã®ã«ã€ããŠãæ¬çºæã«çšããããšãã§ã
ãã ãããã®æ¡ä»¶ãå 足ãããã®ãšããŠãäŸãã°æ ª
åŒäŒç€Ÿã¯ã©ã¬è£œã®PVAâ105ãPVAâ124ãPVA
âCSãPVAâHCïŒä»¥äžãå®å šã±ã³åãããã
ã®ïŒãPVAâ203ãPVAâ420ãâïŒïŒä»¥äžãéš
åã±ã³åããããã®ïŒãæããããšãã§ããã æ¬çºæã®åªæå€ãå«ãåªæå±€ã¯å¡åžæ§ãé«ãã
ãªã©ã®æå³ã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãããšãã§ã
ãã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ãã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ãã¹ã«ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã äžèšã®çé¢æŽ»æ§å€ã®äžã§ãååå ã«ãšãã¬ã³ãª
ãã·ãµã€ãã®ç¹°ãè¿ãåäœãæããããªãšãã¬ã³
ã°ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€ãæå ææäžã«
å«ãŸããããšã¯å¥œãŸãããç¹ã«å¥œãŸããã¯ãšãã¬
ã³ãªããµã€ãã®ç¹°ãè¿ãåäœãïŒä»¥äžã§ãããã®
ãæãŸããã äžèšã®æ¡ä»¶ãæºããéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã
åœè©²åé以å€ã«æŒãŠãåºç¯ã«äœ¿çšããããã®æ§
é ã»æ§è³ªã»åææ³ã«ã€ããŠã¯å ¬ç¥ã§ããã代衚ç
ãªå ¬ç¥æç®ã«ã¯Surfactant Science
Seriesvolume1.Nonionic SurfactantsïŒEdited
by Martin J.SchickãMarcel Dekker
Inc.1967ïŒãSurface Active Ethylene Oxide
AdductsïŒSchoufeldt.NèPergamon Press1969ïŒ
ãªã©ãããããããã®æç®ã«èšèŒã®éã€ãªã³æ§ç
é¢æŽ»æ§å€ã§äžèšã®æ¡ä»¶ãæºãããã®ã¯æ¬çºæã§å¥œ
ãŸããçšããããã ãããã®éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãåç¬ã§ãã
ãŸãïŒçš®ä»¥äžã®æ··åç©ãšããŠãçšããããã æ¬çºæã®åªæå±€ã«åªæãããç»å圢æè²çŽ ãšã
ãŠã¯ã以äžã®ãã®ããããããªãã¡ããšããŒã«æ§
æ°Žé žåºãã¹ã«ãã³ã¢ããåºãã¹ã«ãã³é žåºãã«ã«
ããã·ã«åºãªã©ã®ã¢ããªã³æ§åºãæããã¢ãŸè²
çŽ ãã¢ãŸã¡ãã³è²çŽ ãã¢ã³ãã©ããã³è²çŽ ããã
ãããã³è²çŽ ãã¹ããªã«è²çŽ ããããè²çŽ ããã
ãªã³è²çŽ ãã«ã«ããã«è²çŽ ããã³ãã¿ãã·ã¢ãã³
è²çŽ ãªã©ã æ¬çºæã®åªæå±€ã¯ãç»åç¶ã«æ¡æ£æ§ã®è²çŽ ã圢
æåŸãæ¡æ£ããããã®åŸåºå®ãããæ¹åŒã®ã«ã©ãŒ
ç»å圢ææ³ã«ãããŠãè²çŽ ãåºå®ãããããã«çš
ããããã äžèšã®ã«ã©ãŒç»å圢ææ¹æ³ã«ã¯åžžæž©ä»è¿ã®æž©åºŠ
ã§çŸå液ã䜿çšãããã®ïŒäŸãã°ãã«ã®ãŒç¹èš±
757959å·ã«èšèŒã®ãã®ïŒãç±çŸåãå©çšãããã®
ïŒäŸãã°ç¹éæ58â58543ãå58â79247ã«èšèŒã®
ãã®ïŒãªã©çš®ã ã®åœ¢æ ãããããæ¬é¡ã®åªæå±€ã¯
ãããã«ã䜿çšãããã æ¬çºæã®åªæå±€ãçšããåçèŠçŽ ããã«è©³ãã
以äžã«è¿°ã¹ãã æ¬çºæã®åªæå€ãå«ãåçèŠçŽ ã¯éåžž(1)æ¯æ
äœã(2)æå èŠçŽ ã(3)ååèŠçŽ ãããªããçŸåã¯å
ç±ããæ¹æ³ããçŸåå€ãå±éããæ¹æ³ããããã
ããã®å ŽåãåçèŠçŽ ã«ç»åç¶ã«é²å ããããã
åŸãããã²ã³åéãçŸåãããã®éããã«å¯Ÿå¿ã
ãŠæ¡æ£æ§è²çŽ ãç»åç¶ã«çæããããã®è²çŽ ãå
åèŠçŽ ã«ç§»åããŠããã äžèšã®åçèŠçŽ ã¯ææã«ãããããã«çŸåå€ã
è£å©çŸåå€ããåŠçèŠçŽ ãå«ãŸããããšãã§ã
ãã äžèšæ æ§ã®å¥œãŸããå ·äœçæ æ§ã®ïŒã€ã¯ãã«ã®
ãŒç¹èš±757959å·ã«é瀺ãããŠãããã®ã§ããããª
ãæ¬çºæã®åªæå€ã䜿çšããããšã®ã§ããå¥ã®å¥œ
ãŸããæ æ§ã¯ãç±³åœç¹èš±3415644å·ãå3415645
å·ãå3415646å·ãå3647487å·ãåã³å3635707
å·ããã€ãç¹èš±åºé¡ïŒOLSïŒ2426980å·ãªã©ã«èš
èŒãããŠããã ãŸãæ¬çºæã®åªæå€ãçšãã奜ãŸããä»ã®å®æœ
æ æ§ã¯ç¹éæ58â58543ãå58â79247ãç¹é¡æ57
â31976ãå57â32547ã«èšèŒã®å ç±ã«ããçŸåã
ãå®æœæ æ§ã§ãããç¹ã«å¥œãŸãããã®ã§ããã å®æœäŸ ïŒ æ²èåéä¹³å€ã®äœãæ¹ã«ã€ããŠè¿°ã¹ãã ãŒã©ãã³40ïœãšKBr26ïœãæ°Ž3000mlã«æº¶è§£ã
ãããã®æº¶æ¶²ã50âã«ä¿ã¡æ¹æããã次ã«ç¡é žé
34ïœãæ°Ž200mlã«æº¶ããã液ã10åéã§äžèšæº¶æ¶²
ã«æ·»å ããã ãã®åŸKIã®3.3ïœã100mlã«æº¶ããã液ãïŒåé
ã§æ·»å ããã ããããŠã§ããæ²èåéä¹³å€ã®PHã調æŽããæ²
éãããéå°ã®å¡©ãé€å»ããã ãã®åŸPHã6.0ã«åããåé400ïœã®æ²èåéä¹³
å€ãåŸãã 次ã«ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®äœãæ¹ã«ã€ã
ãŠè¿°ã¹ãã ãŒã©ãã³28ïœãšãã³ãŸããªã¢ãŸãŒã«13.2ïœãæ°Ž
3000mlã«æº¶è§£ããããã®æº¶æ¶²ã40âã«ä¿ã¡æ¹æã
ãããã®æº¶æ¶²ã«ç¡é žé17ïœãæ°Ž100mlã«æº¶ããã
液ãïŒåéã§å ããã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®PHã調æŽãã
æ²éãããéå°ã®å¡©ãé€å»ããããã®åŸPHã6.0
ã«åãããåé400ïœã®ãã³ãŸããªã¢ãŸãŒã«ãåŸ
ãã 次ã«è²çŽ äŸäžæ§ç©è³ªã®ãŒã©ãã³åæ£ç©ãªäœãæ¹
ã«ã€ããŠè¿°ã¹ãã äžèšæ§é ã®ã·ã¢ã³è²çŽ äŸäžæ§ç©è³ªãïŒïœãã³ã
ã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹ã«ãã³é ž
ãœãŒã0.5ïœãããªâã¯ã¬ãžã«ããªã¹ããšãŒã
ïŒTCPïŒïŒïœã秀éããé ¢é žãšãã«30mlãå ãã
çŽ60âã«å ç±æº¶è§£ãããåäžãªæº¶æ¶²ãšããããã®
溶液ãšç³ç°åŠçãŒã©ãã³ã®10ïŒ æº¶æ¶²100ïœãšãæ¹
ææ··åããåŸããã¢ãžãã€ã¶ãŒã§10åéã
10000RPMã«ãŠåæ£ããã ãã®åæ£ç©ãè²çŽ äŸäžæ§ç©è³ªïŒã·ã¢ã³ïŒã®åæ£
ç©ãšããã ïŒã·ã¢ã³ã®è²çŽ äŸäžæ§ç©è³ª 次ã«æå æ§å¡åžç©ã®äœãæ¹ã«ã€ããŠè¿°ã¹ãã 以äžã®ãã®ãæ··å溶解ãããåŸããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããã€ã«ã äžã«30ÎŒïœã®ãŠãšããèå
ã§å¡åžãã也ç¥ããã (a) ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ 10ïœ (b) æ²èåéä¹³å€ 20ïœ (c) åèšè²çŽ äŸäžæ§ç©è³ªïŒã·ã¢ã³ïŒã®åæ£ç© 33ïœ (d) ã®ïŒïŒ 氎溶液 ïŒml (e) ã°ã¢ããžã³ããªã¯ããé ¢é žã®10ïŒ ãšã¿ããŒã«
溶液 12.5ml (f) H2NSO2NïŒCH3ïŒ2ã®10ïŒ æ°Žæº¶æ¶² ïŒml (g) æ°Ž 7.5ml æŽã«ãã®äžã«ä¿è·å±€ãšããŠæ¬¡ã®çµæç©ãèåã
25ÎŒïœã«ãªãããã«å¡åžã也ç¥ããã (h) ãŒã©ãã³10ïŒ æ°Žæº¶æ¶² 35ïœ (i) ã°ã¢ããžã³ããªã¯ããé ¢é žã®10ïŒ ãšã¿ããŒã«
溶液 ïŒml (j) ã³ãã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹
ã«ãã³é žãœãŒãã®ïŒïŒ 氎溶液 ïŒml (k) æ°Ž 56ml 次ã«è²çŽ åºå®ææã®äœãæ¹ãè¿°ã¹ããåè¿°ãã
âïŒãïŒãšïŒ±âïŒãïŒãïŒãšãäžè¡šã«ç€ºãéå
ãã200mlã®èžçæ°Žãå ãã10ïŒ ç³ç°åŠçãŒã©ã
ã³100ïœãå ããŠãåäžã«æ··åããããã®æ··å液
ããäºé žåãã¿ã³ãåæ£ããããªãšãã¬ã³ã§ã©ã
ããŒãããçŽæ¯æäœäžã«90ÎŒïœã®ãŠãšããèåãš
ãªãããã«ãåäžã«å¡åžããããã®è©Šæã也ç¥ã
ãŠãè²çŽ åºå®ææãšããŠçšããã
ãŒåäœïŒââïŒã®å ·äœäŸã以äžã«ç€ºãã ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ äžè¬åŒïŒïŒã«ãããŠãïœã¯ïŒãªãã100ã¢ã«
ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã奜ãŸããã¯ïœã¯40ãª
ãã100ã¢ã«ïŒ ãïœã¯ïŒãªãã60ã¢ã«ïŒ ã§ããã æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããã¢ãããŒå
äœãæ§ææåãšããŠæããããªããŒã®å¥œãŸããå ·
äœäŸã以äžã«ç€ºãã âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±âïŒ ïŒ±â10 ïŒããã§ïœâTsO ã¯ïœâãã«ãšã³ã¹ã«ãã³é ž
é°ã€ãªã³ãè¡šãããïŒ æ¬çºæã®äžè¬åŒïŒïŒãããã¯ïŒïŒã§è¡šãã
ããã¢ãããŒåäœãæ§ææåãšããŠæããããªã
ãŒã®ååéã¯ãåçç¹æ§ãå¡åžé©æ£ãªã©ã®ç¹ãã
10000以äžã§ããããšã奜ãŸããããŸããã®ããª
ããŒã溶液ãšããŠäœ¿çšããå Žåã«ã¯ãå¡åžæ§ã®ç¹
ãããååéã¯1000000以äžãç¹ã«300000以äžã§
ããããšã奜ãŸããããããã«ã¢ãããŒåäœïŒâ
âïŒãããã¯ïŒââïŒãšããŠå ±éåå¯èœãªäžé£œåçµå
ãïŒååäžã«ïŒå以äžæããããã«ã¢ãããŒåäœ
ã䜿çšããå Žåã«ã¯ãããªããŒã®ååéã¯ç¡é倧
ãšãªããå¡åžæ§ã®ç¹ãããåæ£ç©ãšããŠäœ¿çšãã
ãã 次ã®å®æœäŸã§æ¬çºæã®å ·äœäŸãããã«èª¬æã
ãã åæäŸ ïŒ ããªïŒïŒ®âããã«ã€ãããŸãŒã«ïŒïŒŽâïŒã®åæ 300mlã®åå¿å®¹åšã«ïŒ®âããã«ã€ãããŸãŒã«94
ïœãDMF94ïœãå ããçªçŽ ã¬ã¹ã§ååã«çœ®æã
60âã«å ç±ããã枩床ãäžå®ã«ãªã€ããšããã§
ïŒïŒ2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ããã
ãªã«ïŒã1.243ïœæ·»å ããã次ãã§ïŒæéåŸã«ïŒïŒ
2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããª
ã«ïŒã1.243ïœæ·»å ããæŽã«ïŒæéå ç±ãç¶ããã
åå¿æº¶æ¶²ã宀枩ãŸã§å·åŽããåŸãïŒã®ã¢ã»ãã³
äžã«å ããæåºããæ²æŸ±ãåããç空也ç¥ããŠ
90ïœã®çœè²ããªããŒãåŸããåç96ïŒ åæäŸ ïŒ ããªïŒïŒ®âïŒïŒ®âãžã¡ãã«ã¢ãããããã«ã¢ã¯
ãªã«ã¢ããïŒïŒŽâïŒã®åæ 500mlã®åå¿å®¹åšã«ïŒ®ïŒïŒ®âãžã¡ãã«ã¢ããã
ããã«ã¢ã¯ãªã«ã¢ãã156.26ïœããšã¿ããŒã«450
mlãå ããçªçŽ ã¬ã¹ã§ååè±æ°ããåŸ80âã«å ç±
ããïŒïŒ2â²âã¢ãŸãã¹ïŒïŒïŒïŒâãžã¡ãã«ãã¬ã
ãããªã«ïŒ1.25ïœãæ·»å ãããããã«ïŒæéåŸã«
ãåããã®ã1.25ïœæ·»å ãããã®åŸïŒæé30åå
ç±ãæ¹æãç¶ãããåå¿è©Šæã宀枩ãŸã§å·åŽãã
èžçæ°Ž300mlãå ããã»ã«ããŒã¹ã®éææäžã«å ¥
ãïŒæ¥ééæãç¶ããåçµä¹Ÿç¥ã«ãããçœè²ããª
ããŒ140.1ïœãåŸããåç89.7ïŒ åæäŸ ïŒ ããªïŒïŒ®âãã³ãžã«ã€ãããŸãªãŠã ã¯ããªãïŒ
âïŒã®åæ åæäŸïŒã§åŸãããªïŒïŒ®âããã«ã€ãããŸãŒ
ã«ïŒ24ïœãDMF220ïœããšã¿ããŒã«20ïœãæ··å
ãã90âã«å ç±ããã次ãã§ããã³ãžã«ã¯ãã©ã€
ã40ïœãåŸã ã«æ»ŽäžããïŒæéå ç±ããããã®å
å¿æ¶²ã3.5ã®ã¢ã»ãã³ã«å ããæåºçµæ¶ãå
ããç空也ç¥ããŠ51ïœã®çœè²ããªããŒãåŸããå
ç92.4ïŒ åæäŸ ïŒ ããªïŒã¹ãã¬ã³âã³ââã¡ãã«ââããã«
ãã³ãžã«ãããªãžããŠã ã¯ããªãâã³âãžãã
ã«ãã³ãŒã³ïŒïŒ±âïŒã®åæ ç¹éæ53â30328èšèŒã®æ¹æ³ã«ããåæããã åæäŸ ïŒ ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã¢ã«ã
ãªããŠã ã¯ããªãâã³âãžããã«ãã³ãŒã³ïŒïŒ±
âïŒã®åæ (i) ããªïŒãžããã«ãã³ãŒã³âã³âã¯ããã¡ãã«
ã¹ãã¬ã³ïŒéåäœåæ£ç©ã®åæ åå¿å®¹åšã«350mlã®èžçæ°Žãå ¥ããçªçŽ ã¬ã¹
ã§è±æ°ããããªãã³770 10mlãã¯ããã¡ãã«ã¹
ãã¬ã³58.0ïœïŒ0.38ã¢ã«ïŒããžããã«ãã³ãŒã³
2.6ïœïŒ0.02ã¢ã«ïŒãå ãã60âã«å ç±ããã
çªçŽ ã¬ã¹ã«ããè±æ°ãããèžçæ°Ž20mlã«éç¡«é ž
ã«ãªãŠã 1.00ïœãå ãããã®ããã³è±æ°ããã
èžçæ°Ž10mlã«äºç¡«é žæ°ŽçŽ ãããªãŠã 0.38ïœãå
ãããã®ãåæã«å ããïŒæéå ç±æ¹æãç¶ã
ãããã®åŸãäžèšã®æ··åç©ã宀枩ãŸã§å·åŽãã
éããŠéåäœåæ£ç©ïŒã©ããã¯ã¹ïŒãåŸãã (ii) åçŽååå¿ åå¿å®¹åšã«ãåºååæ¿åºŠ14.0ïŒ ãæããäžèš
ã®ã©ããã¯ã¹150ïœãèžçæ°Ž50ïœãå ãã宀枩
ã§ãâã¡ãã«ã¢ã«ããªã³11.2ïœãæ·»å ããã
ãã®åŸ70âã«ãã€ãããšææž©ããïŒæéå ç±æ¹
æããã宀枩ãŸã§å·åŽåŸéããŠéåäœåæ£ç©
åªæå€ãåŸãã åºååæ¿åºŠïŒ14.0wtïŒ æ¬çºæã®åªæå±€ã«å«ãŸããäžè¬åŒïŒïŒã§è¡šã
ãããã¢ãããŒåäœãæ§ææåãšããŠæããããª
ããŒãšãäžè¬åŒïŒïŒã§è¡šããããã¢ãããŒåäœ
ãæ§ææåãšããŠæããããªããŒãšã®æ··åæ¯
ïŒïŒïŒïŒïŒïŒïŒã¯ã奜ãŸããã¯ééæ¯ã§0.1ã
10ã奜ãŸããã¯0.2ãïŒã®éã§ããã æ¬çºæã®ããªããŒæ··åç©åªæå€ãšãã€ã³ããŒã®
æ··åæ¯ããã³ããªããŒæ··åç©åªæå€ã®å¡åžéã¯ã
åªæãããã¹ãè²çŽ ã®éãããªããŒæ··åç©åªæå€
ã®çš®é¡ãçµæãæŽã«çšããããç»å圢æéçšãªã©
ã«å¿ããŠãåœæ¥è ã容æã«å®ããããšãã§ãã
ããåªæå€ïŒãŒã©ãã³æ¯ã20ïŒ80ã80ïŒ20ïŒéé
æ¯ïŒãåªæå€å¡åžéã¯0.2ã15ïœïŒm2奜ãŸããã¯
0.5ãïŒïœïŒm2ã§äœ¿çšããã®ã奜ãŸããã æ¬çºæã«çšããããåªæå±€äžã®ãã€ã³ããŒã¯å
ç¬ã§ãããã¯çµã¿åãããŠå«æããããšãã§ã
ãããã®ãã€ã³ããŒã«ã¯ã芪氎æ§ã®ãã®ãçšãã
ããšãã§ããã芪氎æ§ãã€ã³ããŒãšããŠã¯ãéæ
ãåéæã®èŠªæ°Žæ§ã³ãã€ãã代衚çã§ãããäŸã
ã°ãŒã©ãã³ããŒã©ãã³èªå°äœãããªããã«ã¢ã«ã³
ãŒã«ãã»ã«ããŒã¹èªå°äœçã®ã¿ã³ãã¯è³ªããã³ã
ã³ãã¢ã©ãã¢ãŽã çã®å€ç³é¡ã®ãããªå€©ç¶ç©è³ªãš
ããªããã«ãããªãã³ãã¢ã¯ãªã«ã¢ããéåäœã®
氎溶æ§ããªããã«ååç©ã®ãããªåæéåç©è³ªã
å«ãã ãã®äžã§ãç¹ã«ãŒã©ãã³ãããªããã«ã¢ã«ã³ãŒ
ã«ãæå¹ã«äœ¿çšã§ãããåªæå±€ã«äœ¿çšãããŒã©ã
ã³ã¯å ¬ç¥ã®åçš®ã®ãŒã©ãã³ãçšãããããäŸãã°
ç³ç°åŠçãŒã©ãã³ãé žåŠçãŒã©ãã³ãªãŒã©ãã³ã®
補é æ³ã®ç°ãªããã®ãããããã¯ãåŸããããã
ãã®ãŒã©ãã³ãååŠçã«ããã¿ã«åãã¹ã«ããã«
åãªã©ã®å€æ§ãè¡ãªã€ããŒã©ãã³ãçšããããšã
ã§ããããŸãå¿ èŠãªå Žåã«ã¯ãè±å¡©åŠçãè¡ãªã€
ãŠäœ¿çšããããšãã§ããã åªæå±€ã«äœ¿çšããããªããã«ã¢ã«ã³ãŒã«ã¯ãå ¬
ç¥ã®åçš®ã®ããªããã«ã¢ã«ã³ãŒã«ãçšããããã
ããªããã«ã¢ã«ã³ãŒã«ã¯çš®ã ã®ã±ã³å床ãéå床
ã®ãã®ãçšãããããã±ã³å床ã¯å¥œãŸããã¯70ïŒ
以äžãç¹ã«å¥œãŸããã¯80ïŒ ä»¥äžã®ãã®ãçšããã
ããéå床ã¯å¥œãŸããã¯300ã2000ã®ãã®ãçšã
ãããã ã±ã³å床ãéå床ãç°ãªããã®ã䜵çšããŠçšã
ãããšãã§ããã ãŸãã±ã³åæ³ã«ã€ããŠã¯é žã±ã³åæ³ãã¢ã«ã«ãª
ã±ã³åæ³ã®ïŒã€ãããããããã®ã±ã³ååŠçãæœ
ãããã®ã«ã€ããŠãæ¬çºæã«çšããããšãã§ã
ãã ãããã®æ¡ä»¶ãå 足ãããã®ãšããŠãäŸãã°æ ª
åŒäŒç€Ÿã¯ã©ã¬è£œã®PVAâ105ãPVAâ124ãPVA
âCSãPVAâHCïŒä»¥äžãå®å šã±ã³åãããã
ã®ïŒãPVAâ203ãPVAâ420ãâïŒïŒä»¥äžãéš
åã±ã³åããããã®ïŒãæããããšãã§ããã æ¬çºæã®åªæå€ãå«ãåªæå±€ã¯å¡åžæ§ãé«ãã
ãªã©ã®æå³ã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãããšãã§ã
ãã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«ãã«ããªã³é žå¡©ãã¢ã«ã
ã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³
ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«
ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ã
ã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«
ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«
ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é ž
ãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«ã
åºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«åº
çã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ããé ž
é¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ã
ã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³
é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢
ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããªãžããŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ãã¹ã«ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã äžèšã®çé¢æŽ»æ§å€ã®äžã§ãååå ã«ãšãã¬ã³ãª
ãã·ãµã€ãã®ç¹°ãè¿ãåäœãæããããªãšãã¬ã³
ã°ãªã³ãŒã«åéã€ãªã³çé¢æŽ»æ§å€ãæå ææäžã«
å«ãŸããããšã¯å¥œãŸãããç¹ã«å¥œãŸããã¯ãšãã¬
ã³ãªããµã€ãã®ç¹°ãè¿ãåäœãïŒä»¥äžã§ãããã®
ãæãŸããã äžèšã®æ¡ä»¶ãæºããéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã
åœè©²åé以å€ã«æŒãŠãåºç¯ã«äœ¿çšããããã®æ§
é ã»æ§è³ªã»åææ³ã«ã€ããŠã¯å ¬ç¥ã§ããã代衚ç
ãªå ¬ç¥æç®ã«ã¯Surfactant Science
Seriesvolume1.Nonionic SurfactantsïŒEdited
by Martin J.SchickãMarcel Dekker
Inc.1967ïŒãSurface Active Ethylene Oxide
AdductsïŒSchoufeldt.NèPergamon Press1969ïŒ
ãªã©ãããããããã®æç®ã«èšèŒã®éã€ãªã³æ§ç
é¢æŽ»æ§å€ã§äžèšã®æ¡ä»¶ãæºãããã®ã¯æ¬çºæã§å¥œ
ãŸããçšããããã ãããã®éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãåç¬ã§ãã
ãŸãïŒçš®ä»¥äžã®æ··åç©ãšããŠãçšããããã æ¬çºæã®åªæå±€ã«åªæãããç»å圢æè²çŽ ãšã
ãŠã¯ã以äžã®ãã®ããããããªãã¡ããšããŒã«æ§
æ°Žé žåºãã¹ã«ãã³ã¢ããåºãã¹ã«ãã³é žåºãã«ã«
ããã·ã«åºãªã©ã®ã¢ããªã³æ§åºãæããã¢ãŸè²
çŽ ãã¢ãŸã¡ãã³è²çŽ ãã¢ã³ãã©ããã³è²çŽ ããã
ãããã³è²çŽ ãã¹ããªã«è²çŽ ããããè²çŽ ããã
ãªã³è²çŽ ãã«ã«ããã«è²çŽ ããã³ãã¿ãã·ã¢ãã³
è²çŽ ãªã©ã æ¬çºæã®åªæå±€ã¯ãç»åç¶ã«æ¡æ£æ§ã®è²çŽ ã圢
æåŸãæ¡æ£ããããã®åŸåºå®ãããæ¹åŒã®ã«ã©ãŒ
ç»å圢ææ³ã«ãããŠãè²çŽ ãåºå®ãããããã«çš
ããããã äžèšã®ã«ã©ãŒç»å圢ææ¹æ³ã«ã¯åžžæž©ä»è¿ã®æž©åºŠ
ã§çŸå液ã䜿çšãããã®ïŒäŸãã°ãã«ã®ãŒç¹èš±
757959å·ã«èšèŒã®ãã®ïŒãç±çŸåãå©çšãããã®
ïŒäŸãã°ç¹éæ58â58543ãå58â79247ã«èšèŒã®
ãã®ïŒãªã©çš®ã ã®åœ¢æ ãããããæ¬é¡ã®åªæå±€ã¯
ãããã«ã䜿çšãããã æ¬çºæã®åªæå±€ãçšããåçèŠçŽ ããã«è©³ãã
以äžã«è¿°ã¹ãã æ¬çºæã®åªæå€ãå«ãåçèŠçŽ ã¯éåžž(1)æ¯æ
äœã(2)æå èŠçŽ ã(3)ååèŠçŽ ãããªããçŸåã¯å
ç±ããæ¹æ³ããçŸåå€ãå±éããæ¹æ³ããããã
ããã®å ŽåãåçèŠçŽ ã«ç»åç¶ã«é²å ããããã
åŸãããã²ã³åéãçŸåãããã®éããã«å¯Ÿå¿ã
ãŠæ¡æ£æ§è²çŽ ãç»åç¶ã«çæããããã®è²çŽ ãå
åèŠçŽ ã«ç§»åããŠããã äžèšã®åçèŠçŽ ã¯ææã«ãããããã«çŸåå€ã
è£å©çŸåå€ããåŠçèŠçŽ ãå«ãŸããããšãã§ã
ãã äžèšæ æ§ã®å¥œãŸããå ·äœçæ æ§ã®ïŒã€ã¯ãã«ã®
ãŒç¹èš±757959å·ã«é瀺ãããŠãããã®ã§ããããª
ãæ¬çºæã®åªæå€ã䜿çšããããšã®ã§ããå¥ã®å¥œ
ãŸããæ æ§ã¯ãç±³åœç¹èš±3415644å·ãå3415645
å·ãå3415646å·ãå3647487å·ãåã³å3635707
å·ããã€ãç¹èš±åºé¡ïŒOLSïŒ2426980å·ãªã©ã«èš
èŒãããŠããã ãŸãæ¬çºæã®åªæå€ãçšãã奜ãŸããä»ã®å®æœ
æ æ§ã¯ç¹éæ58â58543ãå58â79247ãç¹é¡æ57
â31976ãå57â32547ã«èšèŒã®å ç±ã«ããçŸåã
ãå®æœæ æ§ã§ãããç¹ã«å¥œãŸãããã®ã§ããã å®æœäŸ ïŒ æ²èåéä¹³å€ã®äœãæ¹ã«ã€ããŠè¿°ã¹ãã ãŒã©ãã³40ïœãšKBr26ïœãæ°Ž3000mlã«æº¶è§£ã
ãããã®æº¶æ¶²ã50âã«ä¿ã¡æ¹æããã次ã«ç¡é žé
34ïœãæ°Ž200mlã«æº¶ããã液ã10åéã§äžèšæº¶æ¶²
ã«æ·»å ããã ãã®åŸKIã®3.3ïœã100mlã«æº¶ããã液ãïŒåé
ã§æ·»å ããã ããããŠã§ããæ²èåéä¹³å€ã®PHã調æŽããæ²
éãããéå°ã®å¡©ãé€å»ããã ãã®åŸPHã6.0ã«åããåé400ïœã®æ²èåéä¹³
å€ãåŸãã 次ã«ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®äœãæ¹ã«ã€ã
ãŠè¿°ã¹ãã ãŒã©ãã³28ïœãšãã³ãŸããªã¢ãŸãŒã«13.2ïœãæ°Ž
3000mlã«æº¶è§£ããããã®æº¶æ¶²ã40âã«ä¿ã¡æ¹æã
ãããã®æº¶æ¶²ã«ç¡é žé17ïœãæ°Ž100mlã«æº¶ããã
液ãïŒåéã§å ããã ãã®ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ã®PHã調æŽãã
æ²éãããéå°ã®å¡©ãé€å»ããããã®åŸPHã6.0
ã«åãããåé400ïœã®ãã³ãŸããªã¢ãŸãŒã«ãåŸ
ãã 次ã«è²çŽ äŸäžæ§ç©è³ªã®ãŒã©ãã³åæ£ç©ãªäœãæ¹
ã«ã€ããŠè¿°ã¹ãã äžèšæ§é ã®ã·ã¢ã³è²çŽ äŸäžæ§ç©è³ªãïŒïœãã³ã
ã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹ã«ãã³é ž
ãœãŒã0.5ïœãããªâã¯ã¬ãžã«ããªã¹ããšãŒã
ïŒTCPïŒïŒïœã秀éããé ¢é žãšãã«30mlãå ãã
çŽ60âã«å ç±æº¶è§£ãããåäžãªæº¶æ¶²ãšããããã®
溶液ãšç³ç°åŠçãŒã©ãã³ã®10ïŒ æº¶æ¶²100ïœãšãæ¹
ææ··åããåŸããã¢ãžãã€ã¶ãŒã§10åéã
10000RPMã«ãŠåæ£ããã ãã®åæ£ç©ãè²çŽ äŸäžæ§ç©è³ªïŒã·ã¢ã³ïŒã®åæ£
ç©ãšããã ïŒã·ã¢ã³ã®è²çŽ äŸäžæ§ç©è³ª 次ã«æå æ§å¡åžç©ã®äœãæ¹ã«ã€ããŠè¿°ã¹ãã 以äžã®ãã®ãæ··å溶解ãããåŸããªãšãã¬ã³ã
ã¬ãã¿ã¬ãŒããã€ã«ã äžã«30ÎŒïœã®ãŠãšããèå
ã§å¡åžãã也ç¥ããã (a) ãã³ãŸããªã¢ãŸãŒã«éä¹³å€ 10ïœ (b) æ²èåéä¹³å€ 20ïœ (c) åèšè²çŽ äŸäžæ§ç©è³ªïŒã·ã¢ã³ïŒã®åæ£ç© 33ïœ (d) ã®ïŒïŒ 氎溶液 ïŒml (e) ã°ã¢ããžã³ããªã¯ããé ¢é žã®10ïŒ ãšã¿ããŒã«
溶液 12.5ml (f) H2NSO2NïŒCH3ïŒ2ã®10ïŒ æ°Žæº¶æ¶² ïŒml (g) æ°Ž 7.5ml æŽã«ãã®äžã«ä¿è·å±€ãšããŠæ¬¡ã®çµæç©ãèåã
25ÎŒïœã«ãªãããã«å¡åžã也ç¥ããã (h) ãŒã©ãã³10ïŒ æ°Žæº¶æ¶² 35ïœ (i) ã°ã¢ããžã³ããªã¯ããé ¢é žã®10ïŒ ãšã¿ããŒã«
溶液 ïŒml (j) ã³ãã¯é žâïŒâãšãã«âããã·ã«ãšã¹ãã«ã¹
ã«ãã³é žãœãŒãã®ïŒïŒ 氎溶液 ïŒml (k) æ°Ž 56ml 次ã«è²çŽ åºå®ææã®äœãæ¹ãè¿°ã¹ããåè¿°ãã
âïŒãïŒãšïŒ±âïŒãïŒãïŒãšãäžè¡šã«ç€ºãéå
ãã200mlã®èžçæ°Žãå ãã10ïŒ ç³ç°åŠçãŒã©ã
ã³100ïœãå ããŠãåäžã«æ··åããããã®æ··å液
ããäºé žåãã¿ã³ãåæ£ããããªãšãã¬ã³ã§ã©ã
ããŒãããçŽæ¯æäœäžã«90ÎŒïœã®ãŠãšããèåãš
ãªãããã«ãåäžã«å¡åžããããã®è©Šæã也ç¥ã
ãŠãè²çŽ åºå®ææãšããŠçšããã
ãè¡šã
äžèšã®æå
æ§å¡åžç©ã«ã¿ã³ã°ã¹ãã³é»çãçš
ãã2000ã«ã¹ã¯ã§10ç§éåç¶ã«é²å ããããã®åŸ
130âã«å ç±ããããŒããããã¯äžã§30ç§éåäž
ã«å ç±ããã次ã«è²çŽ åºå®ææã®èé¢åŽã«ããã
ãïŒm2ããã80mlã®æ°ŽãäŸçµŠããåŸãå ç±åŠçã®
çµã€ãäžèšæå æ§å¡åžç©ãšäžèšæ°ŽãäŸçµŠããè²çŽ
åºå®ææãããããèé¢ãæ¥ããããã«éãåã
ããã80âã®ããŒããããã¯äžã§ïŒç§å ç±ããåŸ
è²çŽ åºå®ææãæå ææããã²ãã¯ãããšãè²çŽ
åºå®ææäžã«ãã¬ã®ã·ã¢ã³è²çŽ ãåŸãããããã
ãã®ãã¬åã®æ¿åºŠã¯ãã¯ãã¹åå°æ¿åºŠèšïŒRDâ
519ïŒãçšããŠæž¬å®ããã 次ã«ãããã®ãã¬åãæããè²çŽ åºå®ææã®è
é¢äžã«çŽ«å€ç·åžåå±€ãæããéæãã€ã«ã ãéã
åãããã¢ãã©ã¹CI65ãŠãšã¶ãªã¡ãŒã¿ãŒãçšãã
è²åäžã«ãã»ãã³å ïŒ10äžã«ã¯ã¹ïŒãïŒæ¥éç §å°
ããããã»ãã³å ç §å°ååŸã§ã®è²åã®æ¿åºŠã枬å®
ããè²åã®å ã«äœããå ç¢æ§ãè©äŸ¡ãããããã
ãã®æ倧æ¿åºŠãšåå°æ¿åºŠ1.0ã§ã®è²çŽ æ®åçã第
ïŒè¡šã«ç€ºããã
ãã2000ã«ã¹ã¯ã§10ç§éåç¶ã«é²å ããããã®åŸ
130âã«å ç±ããããŒããããã¯äžã§30ç§éåäž
ã«å ç±ããã次ã«è²çŽ åºå®ææã®èé¢åŽã«ããã
ãïŒm2ããã80mlã®æ°ŽãäŸçµŠããåŸãå ç±åŠçã®
çµã€ãäžèšæå æ§å¡åžç©ãšäžèšæ°ŽãäŸçµŠããè²çŽ
åºå®ææãããããèé¢ãæ¥ããããã«éãåã
ããã80âã®ããŒããããã¯äžã§ïŒç§å ç±ããåŸ
è²çŽ åºå®ææãæå ææããã²ãã¯ãããšãè²çŽ
åºå®ææäžã«ãã¬ã®ã·ã¢ã³è²çŽ ãåŸãããããã
ãã®ãã¬åã®æ¿åºŠã¯ãã¯ãã¹åå°æ¿åºŠèšïŒRDâ
519ïŒãçšããŠæž¬å®ããã 次ã«ãããã®ãã¬åãæããè²çŽ åºå®ææã®è
é¢äžã«çŽ«å€ç·åžåå±€ãæããéæãã€ã«ã ãéã
åãããã¢ãã©ã¹CI65ãŠãšã¶ãªã¡ãŒã¿ãŒãçšãã
è²åäžã«ãã»ãã³å ïŒ10äžã«ã¯ã¹ïŒãïŒæ¥éç §å°
ããããã»ãã³å ç §å°ååŸã§ã®è²åã®æ¿åºŠã枬å®
ããè²åã®å ã«äœããå ç¢æ§ãè©äŸ¡ãããããã
ãã®æ倧æ¿åºŠãšåå°æ¿åºŠ1.0ã§ã®è²çŽ æ®åçã第
ïŒè¡šã«ç€ºããã
ãè¡šã
ãè¡šã
å
ç
§å°åã®è²çŽ æ¿åºŠ
è¡šïŒã«ç€ºãããã«ãã·ã¢ã³è²çŽ ã«é¢ãåªæå±€ã«
第äžã¢ãã³ããªããŒãšç¬¬åã¢ã³ã¢ããŠã å¡©ããªã
ãŒãšã䜵溶ããããšã«ããã第åã¢ã³ã¢ããŠã ã
ãªããŒãåç¬ã§ç€ºãé«ã転åæ¿åºŠãç¶æãããŸãŸ
ã§ãè²åã®å å ç¢æ§ãåäžãããããšãããã€
ãã å®æœäŸ ïŒ å®æœäŸïŒã®æå æ§å¡åžç©äžã®è²çŽ äŸäžæ§ç©è³ªã®
åæ£ç©ã®ã·ã¢ã³ã®è²çŽ äŸäžæ§ç©è³ªãäžèšæ§é ã®è²
çŽ äŸäžæ§ç©è³ªã«ä»£ãã以å€ã¯å®æœäŸïŒãšå šãåæ§
ã®æäœãšåŠçãè¡ãªã€ãããã®çµæã第ïŒè¡šã«ç€º
ããã ïŒããŒã³ã¿ã®è²çŽ äŸäžæ§ç©è³ª
è¡šïŒã«ç€ºãããã«ãã·ã¢ã³è²çŽ ã«é¢ãåªæå±€ã«
第äžã¢ãã³ããªããŒãšç¬¬åã¢ã³ã¢ããŠã å¡©ããªã
ãŒãšã䜵溶ããããšã«ããã第åã¢ã³ã¢ããŠã ã
ãªããŒãåç¬ã§ç€ºãé«ã転åæ¿åºŠãç¶æãããŸãŸ
ã§ãè²åã®å å ç¢æ§ãåäžãããããšãããã€
ãã å®æœäŸ ïŒ å®æœäŸïŒã®æå æ§å¡åžç©äžã®è²çŽ äŸäžæ§ç©è³ªã®
åæ£ç©ã®ã·ã¢ã³ã®è²çŽ äŸäžæ§ç©è³ªãäžèšæ§é ã®è²
çŽ äŸäžæ§ç©è³ªã«ä»£ãã以å€ã¯å®æœäŸïŒãšå šãåæ§
ã®æäœãšåŠçãè¡ãªã€ãããã®çµæã第ïŒè¡šã«ç€º
ããã ïŒããŒã³ã¿ã®è²çŽ äŸäžæ§ç©è³ª
ãè¡šã
ãŸã第ïŒè¡šã«ç€ºãããã«ããŒã³ã¿è²çŽ ã«ã€ã
ãŠããåªæå±€ã«ç¬¬äžã¢ãã³ããªããŒãšç¬¬åã¢ã³
ã¢ããŠã å¡©ããªããŒãšã䜵çšããããšã«ããã
第åã¢ã³ã¢ããŠã å¡©ããªããŒãåç¬ã§ç€ºãé«ã
転åæ¿åºŠãç¶æãããŸãŸã§ãè²åã®å å ç¢æ§ã
åäžãããããšãããã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®æå æ§å¡åžäžã®è²çŽ äŸäžæ§ç©è³ªã®å
æ£ç©ã®ã·ã¢ã³ã®è²çŽ äŸäžç©è³ªãäžèšæ§é ã®è²çŽ äŸ
äžæ§ç©è³ªã«ä»£ãã以å€ã¯å®æœäŸïŒãšå šãåæ§ãªæ
äœãšåŠçãè¡ãªã€ãããã®çµæã第ïŒè¡šã«ç€ºã
ãã ïŒã€ãšããŒã®è²çŽ äŸäžæ§ç©è³ª
ãŠããåªæå±€ã«ç¬¬äžã¢ãã³ããªããŒãšç¬¬åã¢ã³
ã¢ããŠã å¡©ããªããŒãšã䜵çšããããšã«ããã
第åã¢ã³ã¢ããŠã å¡©ããªããŒãåç¬ã§ç€ºãé«ã
転åæ¿åºŠãç¶æãããŸãŸã§ãè²åã®å å ç¢æ§ã
åäžãããããšãããã€ãã å®æœäŸ ïŒ å®æœäŸïŒã®æå æ§å¡åžäžã®è²çŽ äŸäžæ§ç©è³ªã®å
æ£ç©ã®ã·ã¢ã³ã®è²çŽ äŸäžç©è³ªãäžèšæ§é ã®è²çŽ äŸ
äžæ§ç©è³ªã«ä»£ãã以å€ã¯å®æœäŸïŒãšå šãåæ§ãªæ
äœãšåŠçãè¡ãªã€ãããã®çµæã第ïŒè¡šã«ç€ºã
ãã ïŒã€ãšããŒã®è²çŽ äŸäžæ§ç©è³ª
ãè¡šã
ãè¡šã
ãè¡šã
ã€ãšããŒè²çŽ ã«ã€ããŠããåªæå±€ã«ç¬¬äžã¢ã
ã³ããªããŒãšç¬¬åã¢ã³ã¢ããŠã å¡©ããªããŒãšã
䜵çšããããšã«ããã第åã¢ã³ã¢ããŠã ããªã
ãŒãåç¬ã§ç€ºãé«ã転åæ¿åºŠãç¶æãããŸãŸã§
è²çŽ ã®å å ç¢æ§ãåäžãããããšãããã€ãã 以äžã®å®æœäŸïŒãïŒããæãããªããã«ãåª
æå±€ã«ç¬¬åã¢ã³ã¢ããŠã å¡©ãåç¬ã§äœ¿çšãã
ãšãé«ã転åæ¿åºŠãåŸããããã転åããè²ç»
åãå®å®ã«ä¿æããããšãé£ãããããããã®
åªæå±€ã«äžçŽã¢ãã³ããªããŒãå ããŠãããšã
é«ã転åæ¿åºŠãä¿ã€ããŸãŸã§ãè²çŽ ç»åã®å å
ç¢æ§ã匷ãããããšãã§ããã ãããã€ãŠãæ¬çºæã«ãã転åæ¿åºŠãé«ãã
転åãããè²çŽ ç»åã®å å ç¢æ§ã«åªããåªæå±€
ãåŸãããããšã瀺ãããã å®æœäŸ ïŒ ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãéææ¯æäžã«æ¬¡ã®
åŠãå¡åžããæå ã·ãŒãïŒ (1) å®æœäŸïŒã®è²çŽ åºå®ææïŒã17ã«çšãããã
ã®ãšåãããªããŒã®çµæãããªãåªæå€3.0
ïœïŒm2ããã³ãŒã©ãã³3.0ïœïŒm2ãå«ãåªæå±€ã
ïŒåªæå±€ïŒã17ïŒ (2) é žåãã¿ã³20ïœïŒm2ããã³ãŒã©ãã³2.0ïœïŒ
m2ãå«ãçœè²åå°å±€ã (3) ã«ãŒãã³ãã©ãã¯2.3ïœïŒm2ããã³ãŒã©ãã³
3.1ïœïŒm2ãå«ãé®å å±€ã (4) äžèšã·ã¢ã³è²çŽ åäŸäžäœ0.96ïœïŒm2ããã³
ïŒïŒïŒâãžâïœâããã«ãã€ããããã³0.03
ïœïŒm2ã溶解ãã1.6ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšã
ã«ã©ãŠãªã«ã¢ãã䞊ã³ã«1.5ïœïŒm2ã®ãŒã©ãã³
ãå«ãå±€ã (5) 1.9ïœïŒm2ã®éãå«ãèµ€è²åå å¢æããããš
ãŠèåéã®å éšæœååçŽæ¥å転乳å€ïŒç¹éæ52
â3426å·å®æœäŸïŒã®ä¹³å€ïŒã0.040ïœïŒm2ã®ïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸã
ã¢ãŸãªãŠã ãããã€ãããã³1.4ïœïŒm2ã®ãŒã©
ãã³ãå«æããèµ€ææ§ä¹³å€å±€ã (6) 3.3ïœïŒm2ã®ãŒã©ãã³ã0.030ïœïŒm2ã®äºç¡«é ž
æ°ŽçŽ ãããªãŠã ã1.9ïœïŒm2ã®ããªã¯ã¬ãžã«ã
ã¹ããšãŒããš0.77ïœïŒm2ã®ãžããã«ãã¿ã¬ãŒã
ã®äž¡æ¹ã«æº¶è§£ãã1.2ïœïŒm2ã®ïŒïŒïŒâãžâïœ
âãªã¯ãã«ãã€ããããã³ãå«ãäžéå±€ã (7) 1.5ïœïŒm2ã®ãŒã©ãã³ã0.89ïœïŒm2ã®äžèšæ§
é ãæããããŒã³ã¿è²çŽ åäŸäžäœãš0.030ïœïŒ
m2ã®ïŒïŒïŒâãžâïœâããã«ãã€ããããã³ã®
äž¡æ¹ã溶解ãã1.5ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšãã«
ã©ãŠãªã«ã¢ãããå«æããå±€ã ããŒã³ã¿è²çŽ åäŸäžäœïŒ (8) 1.4ïœïŒm2ã®éãå«ãç·è²åå å¢æããããš
ãŠèåéã®å éšæœååçŽæ¥å転乳å€ïŒç¹é¡50â
79893å·å®æœäŸïŒã®ä¹³å€ïŒã0.010ïœïŒm2ã®ïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸã
ã¢ãŸãªãŠã ãããã€ãããã³1.0ïœïŒm2ã®ãŒã©
ãã³ãå«æããç·ææ§ä¹³å€å±€ã (9) 3.7ïœïŒm2ã®ãŒã©ãã³ã0.023ïœïŒm2ã®äºç¡«é ž
æ°ŽçŽ ãããªãŠã ã0.94ïœïŒm2ã®ïŒïŒïŒâãžâïœ
âãªã¯ãã«ãã€ããããã³ã溶解ãã1.5ïœïŒ
m2ã®ããªã¯ã¬ãžã«ãã¹ããšãŒãïŒæº¶åªïŒãš0.61
ïœïŒm2ã®ãžããã«ãã¿ã¬ãŒãïŒæº¶åªïŒãå«æã
ãäžéå±€ã (10) 2.1ïœïŒm2ã®ãŒã©ãã³ãäžèšã€ãšããŒè²çŽ äŸ
äžäœ1.5ïœïŒm2ããã³ïŒïŒïŒâãžâïœâããã«
ãã€ããããã³0.042ïœïŒm2ã®äž¡æ¹ã溶解ãã
2.5ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšãã«ã©ãŠãªã«ã¢ãã
ãå«ãå±€ã ã€ãšããŒè²çŽ åäŸäžäœïŒ (11) 2.2ïœïŒm2ã®éãå«ãéææ§å éšæœååãšãŠ
èåéçŽæ¥å転乳å€ïŒç¹éæ52â3426å·å®æœäŸ
ïŒã®ä¹³å€ïŒã0.014ïœïŒm2ã®ïŒâïŒïŒâãã«ãã«
ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸãã¢ãŸãªãŠã ã
ããã€ãããã³1.7ïœïŒm2ã®ãŒã©ãã³ãå«æã
ãéææ§ä¹³å€å±€ã (12) 0.95ïœïŒm2ã®ãŒã©ãã³ä¿è·å±€ãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãéææ¯æäœäžã«æ¬¡ã®åŠãå¡åžã
ãã«ããŒã·ãŒããšåèšã®æå ã·ãŒããšã®éã«äž
èšåŠç液ãå±éã第ïŒè¡šã«ç€ºãããããªçµæã
åŸããïŒå®æœäŸïŒãšåæ§ã®æ¹æ³ã§å ã«å¯Ÿããå
ç¢æ§ãè©äŸ¡ãããïŒ ã«ããŒã·ãŒãïŒ ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«äžåé ž
æ§ããªããŒå±€ãšããŠããªã¢ã¯ãªã«é žïŒ10ééïŒ æ°Ž
溶液ã§ç²åºŠçŽ1000cpïŒ15ïœïŒm2ããã³ãã®äžã«
äžåã¿ã€ãã³ã°å±€ãšããŠã¢ã»ãã«ã»ã«ããŒã¹
ïŒ100ïœã®ã¢ã»ãã«ã»ã«ããŒã¹ãå æ°Žå解ããŠ39.4
ïœã®é ¢é žãçæããïŒ3.8ïœïŒm2åã³ããªïŒã¹ã
ã¬ã³âã³âç¡æ°Žãã¬ã€ã³é žïŒïŒçµææ¯ãã¹ãã¬
ã³ïŒç¡æ°Žãã¬ã€ã³é žïŒçŽ60ïŒ40ãååéçŽïŒäžïŒ
0.2ïœïŒm2ãå¡åžãããã®ã
ã³ããªããŒãšç¬¬åã¢ã³ã¢ããŠã å¡©ããªããŒãšã
䜵çšããããšã«ããã第åã¢ã³ã¢ããŠã ããªã
ãŒãåç¬ã§ç€ºãé«ã転åæ¿åºŠãç¶æãããŸãŸã§
è²çŽ ã®å å ç¢æ§ãåäžãããããšãããã€ãã 以äžã®å®æœäŸïŒãïŒããæãããªããã«ãåª
æå±€ã«ç¬¬åã¢ã³ã¢ããŠã å¡©ãåç¬ã§äœ¿çšãã
ãšãé«ã転åæ¿åºŠãåŸããããã転åããè²ç»
åãå®å®ã«ä¿æããããšãé£ãããããããã®
åªæå±€ã«äžçŽã¢ãã³ããªããŒãå ããŠãããšã
é«ã転åæ¿åºŠãä¿ã€ããŸãŸã§ãè²çŽ ç»åã®å å
ç¢æ§ã匷ãããããšãã§ããã ãããã€ãŠãæ¬çºæã«ãã転åæ¿åºŠãé«ãã
転åãããè²çŽ ç»åã®å å ç¢æ§ã«åªããåªæå±€
ãåŸãããããšã瀺ãããã å®æœäŸ ïŒ ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãéææ¯æäžã«æ¬¡ã®
åŠãå¡åžããæå ã·ãŒãïŒ (1) å®æœäŸïŒã®è²çŽ åºå®ææïŒã17ã«çšãããã
ã®ãšåãããªããŒã®çµæãããªãåªæå€3.0
ïœïŒm2ããã³ãŒã©ãã³3.0ïœïŒm2ãå«ãåªæå±€ã
ïŒåªæå±€ïŒã17ïŒ (2) é žåãã¿ã³20ïœïŒm2ããã³ãŒã©ãã³2.0ïœïŒ
m2ãå«ãçœè²åå°å±€ã (3) ã«ãŒãã³ãã©ãã¯2.3ïœïŒm2ããã³ãŒã©ãã³
3.1ïœïŒm2ãå«ãé®å å±€ã (4) äžèšã·ã¢ã³è²çŽ åäŸäžäœ0.96ïœïŒm2ããã³
ïŒïŒïŒâãžâïœâããã«ãã€ããããã³0.03
ïœïŒm2ã溶解ãã1.6ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšã
ã«ã©ãŠãªã«ã¢ãã䞊ã³ã«1.5ïœïŒm2ã®ãŒã©ãã³
ãå«ãå±€ã (5) 1.9ïœïŒm2ã®éãå«ãèµ€è²åå å¢æããããš
ãŠèåéã®å éšæœååçŽæ¥å転乳å€ïŒç¹éæ52
â3426å·å®æœäŸïŒã®ä¹³å€ïŒã0.040ïœïŒm2ã®ïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸã
ã¢ãŸãªãŠã ãããã€ãããã³1.4ïœïŒm2ã®ãŒã©
ãã³ãå«æããèµ€ææ§ä¹³å€å±€ã (6) 3.3ïœïŒm2ã®ãŒã©ãã³ã0.030ïœïŒm2ã®äºç¡«é ž
æ°ŽçŽ ãããªãŠã ã1.9ïœïŒm2ã®ããªã¯ã¬ãžã«ã
ã¹ããšãŒããš0.77ïœïŒm2ã®ãžããã«ãã¿ã¬ãŒã
ã®äž¡æ¹ã«æº¶è§£ãã1.2ïœïŒm2ã®ïŒïŒïŒâãžâïœ
âãªã¯ãã«ãã€ããããã³ãå«ãäžéå±€ã (7) 1.5ïœïŒm2ã®ãŒã©ãã³ã0.89ïœïŒm2ã®äžèšæ§
é ãæããããŒã³ã¿è²çŽ åäŸäžäœãš0.030ïœïŒ
m2ã®ïŒïŒïŒâãžâïœâããã«ãã€ããããã³ã®
äž¡æ¹ã溶解ãã1.5ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšãã«
ã©ãŠãªã«ã¢ãããå«æããå±€ã ããŒã³ã¿è²çŽ åäŸäžäœïŒ (8) 1.4ïœïŒm2ã®éãå«ãç·è²åå å¢æããããš
ãŠèåéã®å éšæœååçŽæ¥å転乳å€ïŒç¹é¡50â
79893å·å®æœäŸïŒã®ä¹³å€ïŒã0.010ïœïŒm2ã®ïŒâ
ïŒïŒâãã«ãã«ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸã
ã¢ãŸãªãŠã ãããã€ãããã³1.0ïœïŒm2ã®ãŒã©
ãã³ãå«æããç·ææ§ä¹³å€å±€ã (9) 3.7ïœïŒm2ã®ãŒã©ãã³ã0.023ïœïŒm2ã®äºç¡«é ž
æ°ŽçŽ ãããªãŠã ã0.94ïœïŒm2ã®ïŒïŒïŒâãžâïœ
âãªã¯ãã«ãã€ããããã³ã溶解ãã1.5ïœïŒ
m2ã®ããªã¯ã¬ãžã«ãã¹ããšãŒãïŒæº¶åªïŒãš0.61
ïœïŒm2ã®ãžããã«ãã¿ã¬ãŒãïŒæº¶åªïŒãå«æã
ãäžéå±€ã (10) 2.1ïœïŒm2ã®ãŒã©ãã³ãäžèšã€ãšããŒè²çŽ äŸ
äžäœ1.5ïœïŒm2ããã³ïŒïŒïŒâãžâïœâããã«
ãã€ããããã³0.042ïœïŒm2ã®äž¡æ¹ã溶解ãã
2.5ïœïŒm2ã®ïŒ®ïŒïŒ®âãžãšãã«ã©ãŠãªã«ã¢ãã
ãå«ãå±€ã ã€ãšããŒè²çŽ åäŸäžäœïŒ (11) 2.2ïœïŒm2ã®éãå«ãéææ§å éšæœååãšãŠ
èåéçŽæ¥å転乳å€ïŒç¹éæ52â3426å·å®æœäŸ
ïŒã®ä¹³å€ïŒã0.014ïœïŒm2ã®ïŒâïŒïŒâãã«ãã«
ãšãã«ïŒâïŒâã¡ãã«âãã³ãŸãã¢ãŸãªãŠã ã
ããã€ãããã³1.7ïœïŒm2ã®ãŒã©ãã³ãå«æã
ãéææ§ä¹³å€å±€ã (12) 0.95ïœïŒm2ã®ãŒã©ãã³ä¿è·å±€ãããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãéææ¯æäœäžã«æ¬¡ã®åŠãå¡åžã
ãã«ããŒã·ãŒããšåèšã®æå ã·ãŒããšã®éã«äž
èšåŠç液ãå±éã第ïŒè¡šã«ç€ºãããããªçµæã
åŸããïŒå®æœäŸïŒãšåæ§ã®æ¹æ³ã§å ã«å¯Ÿããå
ç¢æ§ãè©äŸ¡ãããïŒ ã«ããŒã·ãŒãïŒ ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«äžåé ž
æ§ããªããŒå±€ãšããŠããªã¢ã¯ãªã«é žïŒ10ééïŒ æ°Ž
溶液ã§ç²åºŠçŽ1000cpïŒ15ïœïŒm2ããã³ãã®äžã«
äžåã¿ã€ãã³ã°å±€ãšããŠã¢ã»ãã«ã»ã«ããŒã¹
ïŒ100ïœã®ã¢ã»ãã«ã»ã«ããŒã¹ãå æ°Žå解ããŠ39.4
ïœã®é ¢é žãçæããïŒ3.8ïœïŒm2åã³ããªïŒã¹ã
ã¬ã³âã³âç¡æ°Žãã¬ã€ã³é žïŒïŒçµææ¯ãã¹ãã¬
ã³ïŒç¡æ°Žãã¬ã€ã³é žïŒçŽ60ïŒ40ãååéçŽïŒäžïŒ
0.2ïœïŒm2ãå¡åžãããã®ã
ãè¡šã
ãè¡šã
ãè¡šã
åžžæž©ä»è¿ã®æž©åºŠã§ãçŸå液ã䜿çšããæ¡æ£è»¢å
åã®ã«ã©ãŒæå ææã®åœ¢æ ã«ãããŠããè¡šã«ç€ºã
ãããã«ãåªæå±€ã«ç¬¬äžã¢ãã³ããªããŒãšç¬¬åã¢
ã³ã¢ããŠã å¡©ããªããŒãšã䜵çšããŠçšããããšã«
ãããè²åã®å å ç¢æ§ãåäžãããããšãããã€
ãã
åã®ã«ã©ãŒæå ææã®åœ¢æ ã«ãããŠããè¡šã«ç€ºã
ãããã«ãåªæå±€ã«ç¬¬äžã¢ãã³ããªããŒãšç¬¬åã¢
ã³ã¢ããŠã å¡©ããªããŒãšã䜵çšããŠçšããããšã«
ãããè²åã®å å ç¢æ§ãåäžãããããšãããã€
ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¬¡ã®äžè¬åŒïŒïŒã§è¡šããããã¢ãããŒåäœ
ãæ§ææåãšããŠæããããªããŒãšãäžè¬åŒ
ïŒïŒã§è¡šããããã¢ãããŒåäœãæ§ææåãšã
ãŠæããããªããŒãšãå ±ã«å«ãå±€ãå°ãªããšãäž
å±€æããåçèŠçŽ ã äžè¬åŒïŒïŒ ïŒâïŒâxïŒâïŒây ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬äžã¢ãã³ãæã
ãããã«ã¢ãããŒåäœãè¡šãããã¯ç¬¬äžã¢ãã³
ããã³ç¬¬åã¢ã³ã¢ããŠã å¡©ã®ããããæããªãã
ãã«ã¢ãããŒåäœãè¡šãããïœã¯ïŒãªãã100ã¢
ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ãããã äžè¬åŒïŒïŒ ïŒâïŒâuïŒâïŒâv ãäžè¬åŒïŒïŒã«ãããŠãã¯ç¬¬åã¢ã³ã¢ããŠã
å¡©ãæããããã«ã¢ãããŒåäœãè¡šãããã¯äž
è¬åŒïŒïŒã®ïŒ£ãè¡šãããã®ãšåãã§ãããïœã¯
ïŒãªãã100ã¢ã«ïŒ ãïœã¯ïŒãªãã98ã¢ã«ïŒ ã§ã
ããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16613583A JPS6057836A (ja) | 1983-09-09 | 1983-09-09 | åçèŠçŽ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16613583A JPS6057836A (ja) | 1983-09-09 | 1983-09-09 | åçèŠçŽ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6057836A JPS6057836A (ja) | 1985-04-03 |
| JPH0554110B2 true JPH0554110B2 (ja) | 1993-08-11 |
Family
ID=15825678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16613583A Granted JPS6057836A (ja) | 1983-09-09 | 1983-09-09 | åçèŠçŽ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6057836A (ja) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09152696A (ja) | 1995-11-30 | 1997-06-10 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©ãŒåçæå ææ |
| JP4486810B2 (ja) | 2003-01-08 | 2010-06-23 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | çè²çµæç©åã³ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| EP1633824B1 (en) | 2003-06-18 | 2010-10-20 | FUJIFILM Corporation | Ink and ink-jet recording ink |
| WO2005030888A1 (en) | 2003-09-29 | 2005-04-07 | Fuji Photo Film Co., Ltd. | Ink for inkjet printing, ink set for inkjet printing, inkjet recording material and producing method for inkjet recording material, and inkjet recording method. |
| EP1702013B1 (en) | 2003-10-23 | 2014-09-10 | FUJIFILM Corporation | Ink and ink set for inkjet recording |
| JP2009034942A (ja) | 2007-08-03 | 2009-02-19 | Fujifilm Corp | ã€ã³ã¯ãžã§ããèšé²çšåªäœ |
| JP2009226781A (ja) | 2008-03-24 | 2009-10-08 | Fujifilm Corp | ã€ã³ã¯ãžã§ããç»åã®åœ¢ææ¹æ³ |
| JP2009235113A (ja) | 2008-03-25 | 2009-10-15 | Fujifilm Corp | ã€ã³ã¯ãžã§ããç»åã®åœ¢ææ¹æ³ |
| JP2010030196A (ja) | 2008-07-30 | 2010-02-12 | Fujifilm Corp | ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| JP2010030197A (ja) | 2008-07-30 | 2010-02-12 | Fujifilm Corp | ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| JP2010077285A (ja) | 2008-09-26 | 2010-04-08 | Fujifilm Corp | ã€ã³ã¯ã»ããåã³ç»å圢ææ¹æ³ |
| JP5785799B2 (ja) | 2010-07-30 | 2015-09-30 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | æ°èŠãªã¢ãŸååç©ã氎溶液ãã€ã³ã¯çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ã«ãŒããªããžãåã³ã€ã³ã¯ãžã§ããèšé²ç© |
| JP5866150B2 (ja) | 2010-07-30 | 2016-02-17 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | æ°èŠãªã¢ãŸååç©ã氎溶液ãã€ã³ã¯çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ã«ãŒããªããžãåã³ã€ã³ã¯ãžã§ããèšé²ç© |
| JP5850654B2 (ja) | 2010-12-28 | 2016-02-03 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ |
| JP2012211293A (ja) | 2011-03-18 | 2012-11-01 | Fujifilm Corp | ã€ã³ã¯çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯åã³ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| JP5696004B2 (ja) | 2011-08-30 | 2015-04-08 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ããªã¢ãžã³åŽéãæããæ°èŠååç©ãçè²çµæç©ãã€ã³ã¯ãžã§ããçšã€ã³ã¯ãã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã«ã©ãŒãã£ã«ã¿ãŒãåã³ã«ã©ãŒãã㌠|
| WO2013069667A1 (ja) | 2011-11-08 | 2013-05-16 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | çè²çµæç©åã³ã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ |
| EP2799498B1 (en) | 2011-12-26 | 2019-05-01 | Fujifilm Corporation | Compound having xanthene skeleton, coloring composition, ink for ink jet printing, and ink jet printing method |
| WO2013129265A1 (ja) | 2012-02-29 | 2013-09-06 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | çè²çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãåã³ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| JP5836200B2 (ja) | 2012-05-30 | 2015-12-24 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ããµã³ãã³éªšæ Œãæããååç©ãçè²çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãåã³ã€ã³ã¯ãžã§ããèšé²æ¹æ³ |
| EP2669338B1 (en) | 2012-05-31 | 2017-04-05 | Fujifilm Corporation | Coloring composition, ink for inkjet recording and inkjet recording method |
| JP2014198816A (ja) | 2012-09-26 | 2014-10-23 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ã¢ãŸååç©ã氎溶液ãã€ã³ã¯çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ã«ãŒããªããžãåã³ã€ã³ã¯ãžã§ããèšé²ç© |
| EP2921531A1 (en) | 2012-11-15 | 2015-09-23 | Fujifilm Corporation | Coloring composition, ink jet recording ink, ink jet recording method, ink jet printer cartridge, and ink jet recording material |
| JP5976127B2 (ja) | 2012-11-15 | 2016-08-23 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | çè²çµæç©ã該çè²çµæç©ãçšããã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ã該ã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãçšããã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã€ã³ã¯ã«ãŒããªããžãåã³ãã€ã³ã¯ãžã§ããèšé²ç© |
| JP6170901B2 (ja) | 2014-01-10 | 2017-07-26 | å¯å£«ãã€ã«ã æ ªåŒäŒç€Ÿ | ååç©ãçè²çµæç©ãã€ã³ã¯ãžã§ããèšé²çšã€ã³ã¯ãã€ã³ã¯ãžã§ããèšé²æ¹æ³ãã€ã³ã¯ãžã§ããããªã³ã¿ã«ãŒããªããžãã€ã³ã¯ãžã§ããèšé²ç©ãã«ã©ãŒãã£ã«ã¿ãã«ã©ãŒãããŒãåã³è»¢åçšã€ã³ã¯ |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5858543A (ja) * | 1981-10-02 | 1983-04-07 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©âæå ææããã³ãããçšããã«ã©âç»å圢ææ¹æ³ |
| DE3345070A1 (de) * | 1983-12-13 | 1985-06-20 | Agfa-Gevaert Ag, 5090 Leverkusen | Bildempfangselement fuer das farbdiffusionsuebertragungsverfahren |
-
1983
- 1983-09-09 JP JP16613583A patent/JPS6057836A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5858543A (ja) * | 1981-10-02 | 1983-04-07 | Fuji Photo Film Co Ltd | ç±çŸåã«ã©âæå ææããã³ãããçšããã«ã©âç»å圢ææ¹æ³ |
| DE3345070A1 (de) * | 1983-12-13 | 1985-06-20 | Agfa-Gevaert Ag, 5090 Leverkusen | Bildempfangselement fuer das farbdiffusionsuebertragungsverfahren |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6057836A (ja) | 1985-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0554110B2 (ja) | ||
| JPS6060643A (ja) | åçèŠçŽ | |
| JPH032290B2 (ja) | ||
| JPS6023851A (ja) | åçèŠçŽ | |
| JPS6023852A (ja) | åçèŠçŽ | |
| JPH032289B2 (ja) | ||
| JPS6039644A (ja) | åçèŠçŽ | |
| JPS60122940A (ja) | åçèŠçŽ | |
| JPS5931699B2 (ja) | åçèŠçŽ | |
| JPS5931696B2 (ja) | ã«ã©âæ¡æ£è»¢åæ³çšåçææ | |
| JPS6023853A (ja) | åçèŠçŽ | |
| JPH0423257B2 (ja) | ||
| JPH0368372B2 (ja) | ||
| US3625685A (en) | Photographic color diffusion-transfer element comprising aqueous film-forming synthetic polymer suspension layers intermediate its sensitive layers and processes for their use | |
| JPH0554109B2 (ja) | ||
| JP2505263B2 (ja) | ã³ããªãâååªæå€ããã³ããã䜿çšããåçèŠçŽ | |
| JPS6029103B2 (ja) | ã«ã©âæ¡æ£è»¢åæ³çšåçèŠçŽ | |
| JPH0123776B2 (ja) | ||
| GB1581390A (en) | Photographic colour transfer film unit containing neutralisation layer | |
| JPS5857098B2 (ja) | ã«ã©âæ¡æ£è»¢åçšåçææ | |
| US4503138A (en) | Image-receiving element with unitary image-receiving and decolorizing layer | |
| US3575700A (en) | Polyvinylamide grafts in spacer layers for color diffusion transfer light sensitive units | |
| JPH0271266A (ja) | æ¡æ£è»¢ååçãã€ã«ã ãŠããã | |
| JPS6319849B2 (ja) | ||
| JPS6010302B2 (ja) | åçèŠçŽ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |