JPH0546978B2 - - Google Patents
Info
- Publication number
- JPH0546978B2 JPH0546978B2 JP61275912A JP27591286A JPH0546978B2 JP H0546978 B2 JPH0546978 B2 JP H0546978B2 JP 61275912 A JP61275912 A JP 61275912A JP 27591286 A JP27591286 A JP 27591286A JP H0546978 B2 JPH0546978 B2 JP H0546978B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- pad
- electrode
- film
- semiconductor device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000004065 semiconductor Substances 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- -1 alcohol amines Chemical class 0.000 claims description 2
- 150000001412 amines Chemical group 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 20
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 20
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052814 silicon oxide Inorganic materials 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 4
- 239000010703 silicon Substances 0.000 abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 239000010949 copper Substances 0.000 abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010931 gold Substances 0.000 abstract description 2
- 229910052737 gold Inorganic materials 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 229910052581 Si3N4 Inorganic materials 0.000 abstract 1
- 230000000593 degrading effect Effects 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
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Landscapes
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Wire Bonding (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は半導体装置の製造方法、特に半導体基
板上面のアルミニウム電極表面を完全に保護した
構造の半導体装置を製造する方法に関する。
板上面のアルミニウム電極表面を完全に保護した
構造の半導体装置を製造する方法に関する。
一般に半導体チツプの表面はシリコンの酸化膜
や窒化膜等によつて覆われ、外部からの汚れ、水
分の浸入を防いでいる。しかし、半導体チツプを
外部回路と接続するために設けた電極部分(以下
パツド部分と称する。)は電気的導通のため露出
している。通常はアルミニウムで構成されている
前記パツド部分は水分等によつて腐食されること
があり、半導体装置の信頼性上問題となつてい
た。
や窒化膜等によつて覆われ、外部からの汚れ、水
分の浸入を防いでいる。しかし、半導体チツプを
外部回路と接続するために設けた電極部分(以下
パツド部分と称する。)は電気的導通のため露出
している。通常はアルミニウムで構成されている
前記パツド部分は水分等によつて腐食されること
があり、半導体装置の信頼性上問題となつてい
た。
〔発明が解決しようとする問題点〕
そこで、耐食性に乏しいパツド部分、例えば、
アルミニウムパツド部分を保護すべく、ワイヤボ
ンデイング後に化成処理によりアルミニウムパツ
ド表面に耐食性の無孔性アルミナを形成する方法
や、CVD法やスパツタリング法等によつて電気
絶縁性の金属酸化膜で覆う方法が知られている。
しかし、化成処理は陽極酸化処理で湿式処理であ
るため半導体装置の諸特性の経時変化を促し、そ
の信頼性を低下させる欠点があつた。また、チツ
プマウント、ボンデイング後に水分にさらす処理
はチツプマウント材や、パツケージ部材からのイ
オン性不純物溶出を促してチツプに好ましくな
い。CVD法やスパツタリング法では処理温度が
高温過ぎて半導体装置の組立に使用する樹脂や低
融点ろう材の融点を越えるので使用できないか、
あるいは半導体装置の諸特性を劣化させてしま
う。
アルミニウムパツド部分を保護すべく、ワイヤボ
ンデイング後に化成処理によりアルミニウムパツ
ド表面に耐食性の無孔性アルミナを形成する方法
や、CVD法やスパツタリング法等によつて電気
絶縁性の金属酸化膜で覆う方法が知られている。
しかし、化成処理は陽極酸化処理で湿式処理であ
るため半導体装置の諸特性の経時変化を促し、そ
の信頼性を低下させる欠点があつた。また、チツ
プマウント、ボンデイング後に水分にさらす処理
はチツプマウント材や、パツケージ部材からのイ
オン性不純物溶出を促してチツプに好ましくな
い。CVD法やスパツタリング法では処理温度が
高温過ぎて半導体装置の組立に使用する樹脂や低
融点ろう材の融点を越えるので使用できないか、
あるいは半導体装置の諸特性を劣化させてしま
う。
上記問題点を解決する為に本発明では、金属細
線によつて結線後に、水蒸気により半導体チツプ
上の電極表面に水和酸化物を形成するのである。
線によつて結線後に、水蒸気により半導体チツプ
上の電極表面に水和酸化物を形成するのである。
以下本発明を実施例を用いて説明する。
第1図は本発明の一実施例である半導体装置の
製造方法を示す断面図である。同図において、素
子の形成を終えたシリコン基板1の表面にシリコ
ン酸化膜2が形成され、この上にアルミニウムパ
ツド3とアルミニウム配線4が形成され、これら
の上にCVDシリコン酸化膜や窒化膜などの表面
保護5がアルミニウムパツド3上の一部を除いて
全面的に形成される。これらは公知の製造方法で
製造することができる。アルミニウムパツド3
に、超音波ボンデイング法ではアルミニウムや銅
など、熱圧着ボンデイング法では金の細線6を固
着する。TAB(Tape,Autmated Bonding)の
場合には、銅のビームリード8を第2図の断面図
に示すように熱圧着する。その後露出したパツド
表面を過飽和蒸気に晒すとちみつで耐食性の水和
酸化物が得られる。アルミニウムの場合には前記
水和酸化物の組成構造は明らかではないが、ベー
マイト被膜と推定される。金属細線としてアルミ
ニウムをもちいればこの細線の表面もアルミナと
なり、耐湿性とさらに向上する。蒸気は純水を
100℃以上に加熱したものを用いれば効果はある
が一定の厚みの水和酸化物を得るには時間がかか
る。過飽和蒸気のほうが短時間で所定の被膜厚み
を得ることができる。蒸気発生装置は公知のボイ
ラー等でよく、蒸気中に不純物、特にイオン性の
不純物を含まないようにステンレス材料を使用す
るなど使用材料に留意する。生成する被膜の速度
や無孔性に強く影響を与えるからである。水蒸気
は吹きつけてもよく、蒸気吹きつけによりチツプ
表面の異物、焼きついた汚れ等が除去されるの
で、耐湿性のみならず信頼性に好影響を与える。
蒸気雰囲気にさらす際、シリコン基板側は蒸気が
結露して半導体チツプに水分が作用することのな
いように100℃以上の温度に維持しておく。組立
に使用している材料、例えば、樹脂材料は耐熱温
度が低いのでモールド製品に適用する場合にはリ
ードフレームのまま加熱テーブル上をすべらして
搬送できるので従来の製造工程に蒸気処理工程を
付加するだけでよい。高温水でも耐食効果を期待
できるが、高温水は常温の水に比較して活性度が
高く温水中に組立後、特にボンテイング後の半製
品を漬けるのはチツプマウント材や、パツケージ
部材からのイオン性不純物溶出を促してチツプに
好ましくないばかりか、樹脂材料は膨潤して強度
劣化や特性変動を生じる欠点がある。
製造方法を示す断面図である。同図において、素
子の形成を終えたシリコン基板1の表面にシリコ
ン酸化膜2が形成され、この上にアルミニウムパ
ツド3とアルミニウム配線4が形成され、これら
の上にCVDシリコン酸化膜や窒化膜などの表面
保護5がアルミニウムパツド3上の一部を除いて
全面的に形成される。これらは公知の製造方法で
製造することができる。アルミニウムパツド3
に、超音波ボンデイング法ではアルミニウムや銅
など、熱圧着ボンデイング法では金の細線6を固
着する。TAB(Tape,Autmated Bonding)の
場合には、銅のビームリード8を第2図の断面図
に示すように熱圧着する。その後露出したパツド
表面を過飽和蒸気に晒すとちみつで耐食性の水和
酸化物が得られる。アルミニウムの場合には前記
水和酸化物の組成構造は明らかではないが、ベー
マイト被膜と推定される。金属細線としてアルミ
ニウムをもちいればこの細線の表面もアルミナと
なり、耐湿性とさらに向上する。蒸気は純水を
100℃以上に加熱したものを用いれば効果はある
が一定の厚みの水和酸化物を得るには時間がかか
る。過飽和蒸気のほうが短時間で所定の被膜厚み
を得ることができる。蒸気発生装置は公知のボイ
ラー等でよく、蒸気中に不純物、特にイオン性の
不純物を含まないようにステンレス材料を使用す
るなど使用材料に留意する。生成する被膜の速度
や無孔性に強く影響を与えるからである。水蒸気
は吹きつけてもよく、蒸気吹きつけによりチツプ
表面の異物、焼きついた汚れ等が除去されるの
で、耐湿性のみならず信頼性に好影響を与える。
蒸気雰囲気にさらす際、シリコン基板側は蒸気が
結露して半導体チツプに水分が作用することのな
いように100℃以上の温度に維持しておく。組立
に使用している材料、例えば、樹脂材料は耐熱温
度が低いのでモールド製品に適用する場合にはリ
ードフレームのまま加熱テーブル上をすべらして
搬送できるので従来の製造工程に蒸気処理工程を
付加するだけでよい。高温水でも耐食効果を期待
できるが、高温水は常温の水に比較して活性度が
高く温水中に組立後、特にボンテイング後の半製
品を漬けるのはチツプマウント材や、パツケージ
部材からのイオン性不純物溶出を促してチツプに
好ましくないばかりか、樹脂材料は膨潤して強度
劣化や特性変動を生じる欠点がある。
本実施例では、4メグオームの純水を使用し、
150℃〜170℃で数分間の処理で数100オングスト
ロームの耐湿性の被膜を得た。
150℃〜170℃で数分間の処理で数100オングスト
ロームの耐湿性の被膜を得た。
本発明の次の実施例は水蒸気雰囲気に化成化を
促進する薬品を添加した雰囲気としたなかでボン
デイング後の半製品をさらす方法である。化成化
促進剤として弱アルカリ性の薬品があげられる。
例えば、アンモニア、アミン、アルコールアミン
等である。これらの薬品を水蒸気雰囲気に〜1%
含ませると被膜の生成速度が早く、化成化促進剤
を使用した場合にはそうでない場合に比較して数
倍となる。しかし、同時に多孔質化も促進するの
で耐食性を劣化させないよう条件を設定しなけれ
ばならないのは当然である。
促進する薬品を添加した雰囲気としたなかでボン
デイング後の半製品をさらす方法である。化成化
促進剤として弱アルカリ性の薬品があげられる。
例えば、アンモニア、アミン、アルコールアミン
等である。これらの薬品を水蒸気雰囲気に〜1%
含ませると被膜の生成速度が早く、化成化促進剤
を使用した場合にはそうでない場合に比較して数
倍となる。しかし、同時に多孔質化も促進するの
で耐食性を劣化させないよう条件を設定しなけれ
ばならないのは当然である。
耐食性のアルミナによつて保護されたアルミニ
ウムパツド3は外部からの水分の浸入によつて腐
食することもなく、あるいはパツド間にリーク電
流が流れてその近傍の素子の信頼性を劣化させる
ことなく、この領域でのエレクトロマイグレーシ
ヨンの発生が皆無になる。
ウムパツド3は外部からの水分の浸入によつて腐
食することもなく、あるいはパツド間にリーク電
流が流れてその近傍の素子の信頼性を劣化させる
ことなく、この領域でのエレクトロマイグレーシ
ヨンの発生が皆無になる。
第1図は、本発明の半導体装置の製造方法によ
る半導体装置の断面図である。第2図は本発明の
半導体装置の製造方法による他の半導体装置の断
面図である。 1……シリコン基板、2……シリコン酸化膜、
3……アルミニウムパツド、4……アルミニウム
配線、5……表面保護膜、6……金属細線、7…
…耐食性のアルミナ、8……ビームリード。
る半導体装置の断面図である。第2図は本発明の
半導体装置の製造方法による他の半導体装置の断
面図である。 1……シリコン基板、2……シリコン酸化膜、
3……アルミニウムパツド、4……アルミニウム
配線、5……表面保護膜、6……金属細線、7…
…耐食性のアルミナ、8……ビームリード。
Claims (1)
- 【特許請求の範囲】 1 半導体チツプ上の電極に金属細線を接続した
後、前記電極の表面を水和酸化物生成促進剤を添
加した過飽和水蒸気を含む雰囲気に晒す工程を有
することを特徴とする半導体装置の製造方法。 2 前記水和酸化物生成促進剤は、アンモニア、
アミン、アルコールアミンのなかから選ばれたも
のであることを特徴とする特許請求の範囲第1項
に記載の半導体装置の製造方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61275912A JPS63128634A (ja) | 1986-11-18 | 1986-11-18 | 半導体装置の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61275912A JPS63128634A (ja) | 1986-11-18 | 1986-11-18 | 半導体装置の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63128634A JPS63128634A (ja) | 1988-06-01 |
JPH0546978B2 true JPH0546978B2 (ja) | 1993-07-15 |
Family
ID=17562157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61275912A Granted JPS63128634A (ja) | 1986-11-18 | 1986-11-18 | 半導体装置の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63128634A (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW426980B (en) * | 1999-01-23 | 2001-03-21 | Lucent Technologies Inc | Wire bonding to copper |
JPWO2010147187A1 (ja) | 2009-06-18 | 2012-12-06 | ローム株式会社 | 半導体装置 |
US20120032354A1 (en) * | 2010-08-06 | 2012-02-09 | National Semiconductor Corporation | Wirebonding method and device enabling high-speed reverse wedge bonding of wire bonds |
JP6579653B2 (ja) * | 2015-06-24 | 2019-09-25 | ローム株式会社 | 半導体装置および半導体装置の製造方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56116634A (en) * | 1980-02-20 | 1981-09-12 | Hitachi Ltd | Semiconductor device |
JPS56162844A (en) * | 1980-05-19 | 1981-12-15 | Hitachi Ltd | Semiconductor device and manufacture thereof |
JPS59150460A (ja) * | 1983-01-31 | 1984-08-28 | Toshiba Corp | 半導体装置の製造方法 |
-
1986
- 1986-11-18 JP JP61275912A patent/JPS63128634A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56116634A (en) * | 1980-02-20 | 1981-09-12 | Hitachi Ltd | Semiconductor device |
JPS56162844A (en) * | 1980-05-19 | 1981-12-15 | Hitachi Ltd | Semiconductor device and manufacture thereof |
JPS59150460A (ja) * | 1983-01-31 | 1984-08-28 | Toshiba Corp | 半導体装置の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JPS63128634A (ja) | 1988-06-01 |
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