JPH028602B2 - - Google Patents

Info

Publication number: JPH028602B2
Authority: JP; Japan
Prior art keywords: monomer; polymerization; polymer; water; dispersant
Prior art date: 1980-03-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP55037410A

Other languages

English (en)

Japanese (ja)

Other versions

JPS56135501A (en

Inventor

Minoru Nomichi

Yasuhiko Kadoi

Hiroshi Kanemura

Goro Kobayashi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Nippon Kayaku Co Ltd

Original Assignee

Nippon Kayaku Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-03-26

Filing date

1980-03-26

Publication date

1990-02-26

1980-03-26 Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd

1980-03-26 Priority to JP3741080A priority Critical patent/JPS56135501A/ja

1981-10-23 Publication of JPS56135501A publication Critical patent/JPS56135501A/ja

1990-02-26 Publication of JPH028602B2 publication Critical patent/JPH028602B2/ja

Status Granted legal-status Critical Current

Links

239000000178 monomer Substances 0.000 claims description 77
229920000642 polymer Polymers 0.000 claims description 43
239000002270 dispersing agent Substances 0.000 claims description 34
238000006116 polymerization reaction Methods 0.000 claims description 33
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 29
229920002554 vinyl polymer Polymers 0.000 claims description 29
239000007864 aqueous solution Substances 0.000 claims description 22
239000003960 organic solvent Substances 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 5
230000002209 hydrophobic effect Effects 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 2
238000010526 radical polymerization reaction Methods 0.000 claims description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 21
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 10
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 10
229950011008 tetrachloroethylene Drugs 0.000 description 10
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
239000006185 dispersion Substances 0.000 description 8
239000002245 particle Substances 0.000 description 8
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
239000003431 cross linking reagent Substances 0.000 description 7
239000003505 polymerization initiator Substances 0.000 description 7
238000003756 stirring Methods 0.000 description 7
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 6
-1 alkali metal salts Chemical class 0.000 description 6
229960002415 trichloroethylene Drugs 0.000 description 6
239000008096 xylene Substances 0.000 description 6
229940074411 xylene Drugs 0.000 description 6
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
229910001870 ammonium persulfate Inorganic materials 0.000 description 5
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 5
239000000839 emulsion Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
239000002904 solvent Substances 0.000 description 5
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 5
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 4
RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 4
239000002612 dispersion medium Substances 0.000 description 4
239000012153 distilled water Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
238000010557 suspension polymerization reaction Methods 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
229940048053 acrylate Drugs 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
229920001477 hydrophilic polymer Polymers 0.000 description 3
150000003839 salts Chemical group 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
125000004103 aminoalkyl group Chemical class 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
229920000578 graft copolymer Polymers 0.000 description 2
239000003999 initiator Substances 0.000 description 2
ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
229940047670 sodium acrylate Drugs 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
229920003169 water-soluble polymer Polymers 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 1
238000007429 general method Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
230000020169 heat generation Effects 0.000 description 1
239000007970 homogeneous dispersion Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
230000003204 osmotic effect Effects 0.000 description 1
239000013054 paper strength agent Substances 0.000 description 1
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010558 suspension polymerization method Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1

Landscapes

Polymerisation Methods In General (AREA)

JP3741080A 1980-03-26 1980-03-26 Production of polymer Granted JPS56135501A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP3741080A JPS56135501A (en)	1980-03-26	1980-03-26	Production of polymer

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP3741080A JPS56135501A (en)	1980-03-26	1980-03-26	Production of polymer

Publications (2)

Publication Number	Publication Date
JPS56135501A JPS56135501A (en)	1981-10-23
JPH028602B2 true JPH028602B2 (fr)	1990-02-26

Family

ID=12496744

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP3741080A Granted JPS56135501A (en)	1980-03-26	1980-03-26	Production of polymer

Country Status (1)

Country	Link
JP (1)	JPS56135501A (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4506062A (en) *	1982-08-09	1985-03-19	Allied Colloids Limited	Inverse suspension polymerization process
JPS6140309A (ja) *	1984-08-01	1986-02-26	Arakawa Chem Ind Co Ltd	高吸水性樹脂の製造方法
JPS6153308A (ja) *	1984-08-23	1986-03-17	Arakawa Chem Ind Co Ltd	高吸水性樹脂の製造方法
JPS6173704A (ja) *	1984-09-19	1986-04-15	Arakawa Chem Ind Co Ltd	高吸水性樹脂の製造方法
JPS61231004A (ja) *	1985-04-05	1986-10-15	Kao Corp	逆相懸濁重合用分散剤
JPH01264803A (ja) *	1988-04-16	1989-10-23	Mitsui Constr Co Ltd	コンクリート・モルタル製造用微粒状氷及びドライ状包接水の製造方法及び、それ等微粒状氷又はドライ状包接水を用いたコンクリート・モルタルの製造方法
JP3962963B2 (ja) *	1997-06-09	2007-08-22	荒川化学工業株式会社	四級アンモニウム塩基を有するポリマーおよびその製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5454186A (en) *	1977-10-07	1979-04-28	Nippon Kayaku Co Ltd	Preparation of water-soluble polymer

1980
- 1980-03-26 JP JP3741080A patent/JPS56135501A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5454186A (en) *	1977-10-07	1979-04-28	Nippon Kayaku Co Ltd	Preparation of water-soluble polymer

Also Published As

Publication number	Publication date
JPS56135501A (en)	1981-10-23

Publication	Publication Date	Title
JPS61103912A (ja)	1986-05-22	樹脂水性エマルジヨン
JPS5823801A (ja)	1983-02-12	懸濁重合法
JPS6041081B2 (ja)	1985-09-13	スチロ−ル懸濁重合物の製法
JP3034847B2 (ja)	2000-04-17	新規な会合型ポリマーと、逆相乳化重合によるその製造方法
JPH028602B2 (fr)	1990-02-26
JPH04132705A (ja)	1992-05-07	水溶性ポリマー微粒子の製造方法
JPH08120005A (ja)	1996-05-14	ポリマー粒子の製造方法
JP3440197B2 (ja)	2003-08-25	偏平状異形微粒子の製造方法および該微粒子を含むエマルジョン
JPH03109410A (ja)	1991-05-09	樹脂水性エマルジヨンの製造方法
JPS6320244B2 (fr)	1988-04-27
US3249571A (en)	1966-05-03	Process for producing aqueous polymer dispersions with polymeric nu-vinyl acetamide dispersant
JP2905318B2 (ja)	1999-06-14	逆相懸濁重合用分散剤
JPH0323087B2 (fr)	1991-03-28
JPH11181003A (ja)	1999-07-06	ポリマー微粒子の製造法
JPS61157505A (ja)	1986-07-17	油性懸濁重合用分散安定剤
JPH0574603B2 (fr)	1993-10-18
JPH01314962A (ja)	1989-12-20	液体クロマトグラフィー用充填剤
JPS59136305A (ja)	1984-08-04	水溶性球状ポリマ−の製造方法
JPH0241528B2 (fr)	1990-09-18
JP2872831B2 (ja)	1999-03-24	逆相懸濁重合用分散剤
JPS61231003A (ja)	1986-10-15	逆相懸濁重合用分散剤
JP3333785B2 (ja)	2002-10-15	球状重合体の製造方法
JPS638402A (ja)	1988-01-14	逆相懸濁重合用分散剤
JP2549940B2 (ja)	1996-10-30	高架橋重合体粒子の製造方法
JPS6024123B2 (ja)	1985-06-11	ビ−ズ状重合体の製法