JPH02252677A - Decorative material for ceramic product - Google Patents
Decorative material for ceramic productInfo
- Publication number
- JPH02252677A JPH02252677A JP7457189A JP7457189A JPH02252677A JP H02252677 A JPH02252677 A JP H02252677A JP 7457189 A JP7457189 A JP 7457189A JP 7457189 A JP7457189 A JP 7457189A JP H02252677 A JPH02252677 A JP H02252677A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- decorative material
- sheet
- ceramic
- pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 65
- 239000000463 material Substances 0.000 title claims abstract description 43
- 239000000835 fiber Substances 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 26
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 17
- 239000003973 paint Substances 0.000 claims abstract description 16
- 239000012784 inorganic fiber Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 7
- 239000002241 glass-ceramic Substances 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims description 23
- 210000003298 dental enamel Anatomy 0.000 claims description 5
- 238000005034 decoration Methods 0.000 abstract description 8
- 239000002002 slurry Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000002844 melting Methods 0.000 abstract description 4
- 230000008018 melting Effects 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- 238000001354 calcination Methods 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 27
- 238000010304 firing Methods 0.000 description 21
- 238000010422 painting Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010017 direct printing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000005315 stained glass Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012237 artificial material Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052572 stoneware Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
- C04B30/02—Compositions for artificial stone, not containing binders containing fibrous materials
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は窯業製品の装飾月料に係り、特に窯業製品の加
飾効果を著し・く高めることができる装飾材料に関する
。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a decorative material for ceramic products, and particularly to a decorative material that can significantly enhance the decorative effect of ceramic products.
［従来の技術］
従来、窯業製品の装飾は手描き、スタンプ、直接印刷又
は転写絵付は等の手法によりて行なわれているが、陶磁
器、ガラスやホウロウの装飾では転写絵付けが一般的で
あった。この転写絵付けは、窯業製品の装飾用絵の具粉
末を印刷オ、イルと混合して印刷１ノた絵柄を窯業製品
の表面に転写貼付し、焼成して行なうものである。[Prior art] Traditionally, ceramic products have been decorated using techniques such as hand-painting, stamping, direct printing, or transfer painting, but transfer painting has been common for decoration of ceramics, glass, and enamel. . This transfer painting is carried out by mixing decorative paint powder for ceramic products with printing oil, transferring and pasting a printed pattern onto the surface of the ceramic product, and firing.
〜方、抄造法によるペーパー状シートとして、釉薬粉末
や陶磁器素地粉末及びセラミックス粉末等を天然バルブ
と共に抄造した釉薬シートや陶紙及びセラミックスペー
パーシートが知られており、なかでも特殊なものとして
、セラミックス繊維を抄造した成形体がある。Glaze sheets, ceramic paper, and ceramic paper sheets made from glaze powder, ceramic base powder, ceramic powder, etc. together with natural valves are known as paper-like sheets produced by the paper-making method. There are molded products made from fibers.
［発明が解決しようとする課題］
前記従来の窯業製品の装飾方法のうち、手描き絵付けは
、装飾絵の具層の厚みが不均一となる、大きな面積への
絵付けは手間がかかるなどの欠点を有する。スタンプ絵
付けは装飾絵の具層の厚みが比較的薄いものとなるため
、装飾部分の立体感に乏しく、装飾効果が低い。また、
直接印刷は曲面への絵イ」けが困難である。転写絵付り
は複雑な絵柄の装飾や量産には好都合であるが、手描き
に比べ゛Ｃ装飾絵の具層の厚みが小さく装飾部分の立体
感に乏しいものであった。！Ｉ］ち、転写絵付けのよう
に印刷による場合、絵の具層の厚みを大かく形成すると
、その絵の具の焼成収縮等により絵柄に切れ目を生じ易
いことから、絵の具層を厚くすることは困難である。[Problems to be Solved by the Invention] Among the conventional methods for decorating ceramic products, hand-painted painting has disadvantages such as uneven thickness of the decorative paint layer and the hassle of painting large areas. have In stamp painting, the thickness of the decorative paint layer is relatively thin, so the decorative part lacks a three-dimensional effect and the decorative effect is low. Also,
Direct printing makes it difficult to print images on curved surfaces. Transfer painting is convenient for decoration with complex patterns and for mass production, but compared to hand painting, the thickness of the decorative paint layer is smaller and the three-dimensional effect of the decorative parts is poor. ! I] When using printing, such as transfer painting, it is difficult to make the paint layer thicker because if the paint layer is made thicker, cuts tend to occur in the design due to firing shrinkage of the paint, etc. .
一方、従来の釉薬シートは単にタイル等の平面的なもの
の表面に均一な釉薬層を形成するのに用いられ、また、
陶紙やセラミックスペーパーシート及びセラミックス繊
維成形体の使用目的は装飾のためのものでなく、更に、
これら釉薬シートや陶紙は天然バルブを内填するため、
焼成条件が制限されたり、灰分が残留する等の問題点が
あった。On the other hand, conventional glaze sheets are simply used to form a uniform glaze layer on the surface of flat objects such as tiles, and
The purpose of use of ceramic paper, ceramic paper sheets, and ceramic fiber moldings is not for decoration.
These glaze sheets and ceramic papers contain natural valves, so
There were problems such as limited firing conditions and residual ash.
本発明は上記従来の問題点を解決し、窯業製品に容易か
つ効率的に装飾を施すことができ、著１ノく高い装飾性
を付与することができる窯業製品の装飾材料を提供する
ことを目的とする。The present invention solves the above-mentioned conventional problems and provides a decorative material for ceramic products that can be easily and efficiently decorated and that can impart significantly higher decorativeness. purpose.
［課題を解決するための手段］
請求項（１）の窯業製品の装飾材料は、無機質粉末１０
０重量部及び人工繊維５〜４０重１部を含む混合物を抄
造してなることを特徴とする請求項（２）の窯業製品の
装飾材料は、請求項（１）において、無機質粉末が窯業
製品装飾用の絵の具であることを特徴とする
請求項（３）の窯業製品の装飾材料は、請求項（１）又
は（２）において、人工繊維が無ｍ買繊維及び／又は有
機質繊維であることを特徴とする
請求項（４）の窯業製品の装飾材料は、請求項（３）に
おいて、無機質繊維がガラス繊維又はセラミックス繊維
であることを特徴とする請求項（５）の窯業製品の装飾
材料は、請求項（３）において、有機質繊維が合成樹脂
繊維であることを特徴とする
請求項（６）の窯業製品の装飾材料は、請求項（１）〜
（５）において、窯業製品が陶１ｉｉｉ器、ガラス又は
ポウロウであることを特徴とする請求項（７）の窯業製
品の装飾材料は、請求項（１）〜（６）において、装飾
材料がペーパーシート形状であることを特徴とする。[Means for solving the problem] The decorative material of the ceramic product according to claim (1) comprises inorganic powder 10
The decorative material for ceramic products according to claim (2), characterized in that it is made by paper-making a mixture containing 1 part by weight of 0 parts by weight and 5 to 40 parts by weight of artificial fibers, is the decorative material for ceramic products according to claim (1), wherein the inorganic powder is The decorative material for a ceramic product according to claim (3), which is a decorative paint, is defined in claim (1) or (2), where the artificial fiber is an unpurchased fiber and/or an organic fiber. The decorative material for ceramic products according to claim (4) is characterized in that the decorative material for ceramic products according to claim (3) is characterized in that the inorganic fiber is glass fiber or ceramic fiber. In claim (3), the decorative material for ceramic products according to claim (6) is characterized in that the organic fiber is a synthetic resin fiber.
In (5), the decorative material of the ceramic product of claim (7) is characterized in that the ceramic product is ceramic 1III ware, glass, or potau. It is characterized by its sheet shape.
以下に本発明を図面を参照して詳細に説明する。The present invention will be explained in detail below with reference to the drawings.
第１図は本発明の窯業製品の装飾材料の一実施例を示す
拡大断面図である。FIG. 1 is an enlarged sectional view showing one embodiment of the decorative material for ceramic products of the present invention.
本実施例の窯業製品の装飾材料１は、窯業製品装飾用絵
の具等の無機質粉末２を１００重量部と、ガラス繊維、
セラミックス繊維等の無機質繊維３及び合成樹脂！ａ維
等の有機′ｉｔ、ＭＩｌ維４よりなる人工繊維を５〜４
０重量部混合し、この混合物を抄造法によってペーパー
状シート形状に抄造してなるものである。The decorative material 1 for ceramic products of this example includes 100 parts by weight of an inorganic powder 2 such as paint for decorating ceramic products, glass fiber,
Inorganic fibers such as ceramic fibers3 and synthetic resins! 5 to 4 artificial fibers consisting of organic fibers such as a-fibers, and 4-mil fibers.
0 parts by weight are mixed, and this mixture is made into a paper-like sheet shape by a paper-making method.
このような本発明の窯業製品の装飾材料を製造するには
、焼成して溶融もしくは焼結する窯業製品装飾用の絵の
具である無機質粉末１００重量部とガラス１８Ｍやセラ
ミックスｗ４維等の無機質１ａ維及び／又は合成樹脂繊
維である有機質繊維の人工繊維５〜４０重１部とを混合
し、得られた混合物に抄造に必要な凝集剤等の薬剤及び
水を加えてスラリーとし、これを抄造してペーパー状シ
ートとする。In order to produce the decorative material for ceramic products of the present invention, 100 parts by weight of an inorganic powder, which is a paint for decorating ceramic products that is fired and melted or sintered, and an inorganic 1A fiber such as glass 18M or ceramic W4 fiber are mixed. and/or 1 part by weight of 5 to 40 weight organic fibers, which are synthetic resin fibers, are added to the resulting mixture, and water and chemicals such as flocculants necessary for paper making are added to form a slurry, which is then made into paper. to form a paper-like sheet.
本発明において、窯業製品装飾用絵の具は、被装飾品の
物性や絵付は時の焼成温度を考慮して、一般に入手の容
易なもののなかから適宜選択して用いることがで籾る。In the present invention, the paint for decorating ceramic products can be appropriately selected from generally easily available paints, taking into account the physical properties of the object to be decorated and the firing temperature during painting.
その粒径は通常装飾用に用いられる程度で良く、例えば
０．１〜２０μｍの範囲のものが適当である。The particle size may be within the range normally used for decoration, for example, a range of 0.1 to 20 μm.
また、人工繊維の種類及び配合量は、被装飾品の物性や
絵付は焼成温度及び抄造適性の良否やシート抄造物の出
来上がりの良否、更には、絵付けの美的効果を加味して
決定されるや上記無機質粉末ｉｏｏ瓜量重量対して、人
工繊維の配合量が５重量部未満では抄造適性が不良であ
り、４０重量部を超えると作製されたシート状抄造物が
粗雑なものどなったり、また材料コストの面で高価とな
り、実用的でなくなる。従って、人工繊維は、無機質粉
末１００重皿部に刻して５〜４０重量部とする。In addition, the type and amount of artificial fibers, the physical properties and decoration of the decorated article are determined by taking into account the firing temperature, the suitability for papermaking, the quality of the sheet paper product, and the aesthetic effect of the decoration. If the amount of artificial fiber blended is less than 5 parts by weight with respect to the weight of the above-mentioned inorganic powder IOO, the suitability for paper making will be poor, and if it exceeds 40 parts by weight, the produced sheet-like paper product will be rough, Moreover, it becomes expensive in terms of material cost, making it impractical. Therefore, the artificial fiber is chopped into 100 parts by weight of inorganic powder to give a total amount of 5 to 40 parts by weight.
用いる人工ｌａ給は、抄造性、装飾性等の面から平均繊
維径３〜２０μｍ、平均繊維長さＯ，５−・２０ｍｒｎ
のものであることが好ましい。The artificial la supply to be used is an average fiber diameter of 3 to 20 μm and an average fiber length of O, 5-20 mrn, from the viewpoint of paper formability, decorative properties, etc.
Preferably.
本発明において、人工！ａ紺としては、ガラス繊維、セ
ラミックス繊維等の無機質繊維のみを用いても良く、ま
た、合成樹脂繊維等の有機質繊維のみを用いても良い。In the present invention, artificial! As the navy blue, only inorganic fibers such as glass fibers and ceramic fibers may be used, or only organic fibers such as synthetic resin fibers may be used.
人工繊維は、いずれも抄造性の向上に有効であるが、無
ｍ質繊維は本発明の装飾材料の装飾性の向上に作用し、
有機質繊維は抄造シートの強度向上に作用する。即ち、
軟化点又は融点の低い無機質繊維は、焼成時に無機質粉
末と共に溶融して色ガラス層を形成する。また、軟化点
又は融点の高い無機質繊維であれば、焼成後にガラス層
内に繊維状に残留し、趣忽の深い装飾面を提供する。ま
た、有機質繊維はその繊緒形状により抄造性を高めると
共に、抄造時の加熱により溶融して、抄紙シートの強度
を高めるが、焼成により速やかに焼失する。All artificial fibers are effective in improving paper formability, but amorphous fibers are effective in improving the decorative properties of the decorative material of the present invention.
Organic fibers work to improve the strength of the paper sheet. That is,
The inorganic fibers with a low softening point or melting point melt together with the inorganic powder during firing to form a colored glass layer. Furthermore, inorganic fibers with a high softening point or melting point remain in the glass layer in the form of fibers after firing, providing a decorative surface with a rich taste. In addition, organic fibers improve paper-forming properties due to their cord shape, and are melted by heating during paper-making to increase the strength of the paper sheet, but they are quickly burned away during baking.
本発明においては、好ましくは、無機質繊維：有機質繊
維＝５〜１５：１０〜４０（重量比）にて両者を併用す
るのが好適である。In the present invention, it is preferable to use both inorganic fibers and organic fibers in a ratio of 5 to 15:10 to 40 (weight ratio).
このような無機質粉末と人］−樟維とを所定割合で混合
してなる混合物を抄紙するにあたっては、強度等を確保
するために、必要に応じて適当な結合剤及び／又は飲集
剤等、例えば、結合剤どしてポリビニルアルコール、カ
ルボキシメチルセルロース、アクリル樹脂エマルジョン
等、凝集剤としてポリアクリルアミド系のアニオン又は
カチオンの各タイプ等を添加し、更に水を加λ、て抄紙
スラリーとして、通常の抄紙法により抄紙する。この場
合、結合剤等の添加物の添加量は、前記混合物に対して
３〜７重量％（結合剤）、水の添加量は混合物の９０〜
ｉｏｏ倍重量（スラリー濃度は０．５〜ｉｇ量％）とす
るのが好ましい。When making paper from a mixture made by mixing such inorganic powder and camphor fiber in a predetermined ratio, a suitable binder and/or aggregating agent, etc., may be added as necessary to ensure strength etc. For example, as a binder, polyvinyl alcohol, carboxymethylcellulose, acrylic resin emulsion, etc. are added, as a flocculant, various types of polyacrylamide-based anions or cations are added, and water is further added to form a papermaking slurry. Paper is made using the papermaking method. In this case, the amount of additives such as a binder added is 3 to 7% by weight (binder) based on the mixture, and the amount of water added is 90% to 7% by weight of the mixture.
Ioo times the weight (slurry concentration is 0.5 to ig%).
抄紙シートの厚みは、抄造条件を制御することにより容
易に調整することができる。The thickness of the paper sheet can be easily adjusted by controlling the paper-making conditions.
本発明の窯業製品の装飾材料では、無機質粉末ど共に人
工！ａ紐を配合したものを抄造するため、比較的厚さの
厚い、例えば０．２〜２．Ｏｍｒｎ程度といった装飾効
果の高いバー・バー状シート形状、その他リボン形状等
の抄紙シートとすることが可能である。The decorative materials for ceramic products of the present invention include inorganic powders and artificial materials! Since the paper is made with a-string, it is relatively thick, for example, 0.2 to 2. It is possible to make the paper sheet in the shape of a bar-bar sheet with a high decorative effect such as Omrn, or in other ribbon shapes.
次に、電光圓の窯業製品の装飾材料による装飾方法につ
いて第２図及び第３図〜第７図を参照して説明する。Next, a method of decorating Denkoen's ceramic products with decorative materials will be explained with reference to FIGS. 2 and 3 to 7.
図示の方法では、素地層５の表面に形成された釉薬Ｎ６
上に、接着剤Ｎ７を介し５て本発明の窯業製品の装飾材
料１を貼り付け、これを適当な温度即ち、用いた無機質
粉末の焼成温度で焼成する。In the illustrated method, the glaze N6 formed on the surface of the base layer 5 is
Decorative material 1 of the ceramic product of the present invention is pasted on top with adhesive N7 5, and this is fired at an appropriate temperature, that is, at the firing temperature of the inorganic powder used.
ここで用いる接着剤としてはアクリル樹脂エマルジョン
接着剤、ポリビニルアルコ・−ル接着剤、ポリエチレン
オキサイド水溶液等が挙げられる。焼成により、人工ｉ
ＪＩ維として合成樹脂繊維等の有機質繊維を配合したも
のでは、その有機質繊維が燃焼除去される。この場合、
合成樹脂繊維等は、天然バルブとは異なり、焼成時の燃
え抜けが速やかで、残留灰分が極めて少なく、装飾面を
損なうことがない。Examples of the adhesive used here include an acrylic resin emulsion adhesive, a polyvinyl alcohol adhesive, and an aqueous polyethylene oxide solution. By firing, artificial i
When JI fibers contain organic fibers such as synthetic resin fibers, the organic fibers are burned and removed. in this case,
Unlike natural bulbs, synthetic resin fibers burn out quickly during firing, have extremely low residual ash content, and do not damage the decorative surface.
焼成により得られる装飾面は、焼成条件や装飾材料の組
成等によっても異なるが、例えば、無機質粉末に軟化温
度の低い無機質繊維を配合したものでは、第３図に示す
如く、素地Ｊｉ１５の釉薬７１６上に無機質粉末と無機
質繊維が溶は合って、色ガラス層１１が形成される。ま
た、無機質粉末に軟化温度の高い無機質ｍ維を配合した
ものでは、第４図又は第５図に示す如く、無機質繊維１
２Ａ。The decorative surface obtained by firing varies depending on the firing conditions and the composition of the decorative material, but for example, in the case of a mixture of inorganic powder and inorganic fiber with a low softening temperature, as shown in FIG. Inorganic powder and inorganic fiber are melted together to form a colored glass layer 11 on top. In addition, when inorganic fibers with a high softening temperature are blended with inorganic powder, as shown in Fig. 4 or 5, inorganic fibers 1
2A.
１２Ｂが混在した色ガラス層ｔ３Ａ、１３Ｂが形成され
る。Colored glass layers t3A and 13B in which glass 12B is mixed are formed.
更に、無機質粉末として高融点のものを用い、高い焼成
温度で焼成した場合には、第６図又は第７図に示す如く
、色ガラス層１４．１５が釉薬層６に沈み込んだ状態で
形成される（第７図中、１６は無機質繊維である。）。Furthermore, when an inorganic powder with a high melting point is used and fired at a high firing temperature, the colored glass layers 14 and 15 are formed in a state sunk into the glaze layer 6, as shown in FIG. 6 or 7. (In Fig. 7, 16 is an inorganic fiber.)
本発明の窯業製品の装飾材料の装飾対象となる窯業製品
としては特に制限はなく、陶磁器、ガラス、ホウロウ等
の広範な窯業製品を挙げることができる。The ceramic products to be decorated with the decorative material of the ceramic products of the present invention are not particularly limited, and include a wide range of ceramic products such as ceramics, glass, and enamel.
［作用］
本発明の窯業製品の装飾材料は、
■ 人工繊維の配合により、抄造法で作製することが可
能とされ、面積が大きく厚みの均一なペーパー状シート
が得られる。その厚みも自由に変えることができる。[Function] The decorative material for ceramic products of the present invention can be produced by the paper-making method by incorporating artificial fibers, and a paper-like sheet with a large area and uniform thickness can be obtained. Its thickness can also be changed freely.
■ 人工繊維の配合により、厚みの大きなシートが得ら
れる。■ By incorporating artificial fibers, thick sheets can be obtained.
■ 無機′Ｊｌｔ繊維を配合する場合には、焼成収縮等
による絵の真贋の切れ目発生を防止することができ、美
麗な装飾面を得ることができる。(2) When inorganic Jlt fibers are blended, it is possible to prevent the occurrence of cuts in the authenticity of the painting due to firing shrinkage, etc., and a beautiful decorative surface can be obtained.
■ 有機質繊維を配合する場合には、装飾材料の強度が
確保され、この場合、合成樹脂繊維等の有機貿繊維は天
然バルブと異なり、焼成時の燃え抜けが速やかで、残留
灰分が極微である。■ When organic fibers are blended, the strength of the decorative material is ensured, and in this case, unlike natural bulbs, organic fibers such as synthetic resin fibers burn through quickly during firing and have minimal ash content. .
等の優れた作用効果を有する。It has excellent effects such as.
本発明の窯業製品の装飾材料は、陶ｌｉｆ！器、ガラス
又はホウロウ等の窯業製品に好適であり、特にペーパー
状シート形状として極めて有利に使用することができる
。The decorative material for the ceramic products of the present invention is ceramic lif! It is suitable for ceramic products such as vessels, glass, and enamel, and can be particularly advantageously used in the form of paper-like sheets.
［実施例］
以下に実施例及び比較例を挙げて本発明をより具体的に
説明するが、本発明はその要旨を超えない限り、以下の
実施例に限定されるものではない。[Examples] The present invention will be described in more detail with reference to Examples and Comparative Examples below, but the present invention is not limited to the following Examples unless it exceeds the gist thereof.
実施例１〜１０
第１表に示す性質を有する窯業製品の装飾用絵の具であ
る無機質粉末Ａ、Ｂ及びＣと、第２表に示す性質を有す
る無機質繊維及び／又は市販の合成樹脂繊維の人工繊維
ａ−ｅとを、′ｓ４表に示す割合の混合物とし、これに
水と抄造に必要な凝集剤や結合剤等を第３表に示す配合
で添加してスラリーとし、第４表に示す厚みのペーパー
状シートに抄造した。Examples 1 to 10 Inorganic powders A, B, and C as decorative paints for ceramic products having the properties shown in Table 1, and artificial inorganic fibers and/or commercially available synthetic resin fibers having the properties shown in Table 2. Fibers a to e are mixed in the proportions shown in Table 's4, and water and a flocculant, binder, etc. necessary for papermaking are added in the proportions shown in Table 3 to form a slurry, and the mixture is shown in Table 4. It was made into a thick paper-like sheet.
得られたシートを、合成樹脂接着剤（アクリル樹脂エマ
ルジョン接着剤）にて第４表に示す窯業製品の表面に第
２図のように貼付して焼成した。The obtained sheet was attached to the surface of the ceramic products shown in Table 4 using a synthetic resin adhesive (acrylic resin emulsion adhesive) as shown in FIG. 2, and then fired.
焼成は、窯業製品により、次のような方法で行なった。Firing was performed using the following method depending on the ceramic product.
ホウロウ：
ａＯＯ℃に保持した焼成炉内に入れ、５分間後に引き出
し放冷した。Enamel: It was placed in a firing furnace maintained at aOO°C, and after 5 minutes it was taken out and allowed to cool.
白色磁器、ボーンチャイナ、ストーンウェア。White porcelain, bone china and stoneware.
ソーダガラス器、窓用ガラス：
１０℃／ ｍ ｍの昇温速度で第４表に示す焼成温度ま
で加熱し、１０分間保持後自然冷却した。Soda glassware, window glass: Heated at a heating rate of 10° C./mm to the firing temperature shown in Table 4, held for 10 minutes, and then allowed to cool naturally.
焼成結果を第４表に示す。The firing results are shown in Table 4.
第１表
第２表
第３表
比較例１．２
人工繊維を用いず天然木材バルブを第４表に示す配合に
て混合したこと以外は実施例１〜１０と同様にしてシー
トを製造し、窯業製品の表面に貼付して焼成した。焼成
結果を第４表に示す。Table 1 Table 2 Table 3 Comparative Example 1.2 A sheet was produced in the same manner as in Examples 1 to 10, except that natural wood valves were mixed in the formulation shown in Table 4 without using artificial fibers. It was attached to the surface of a ceramic product and fired. The firing results are shown in Table 4.
なお、第４表におい゛て、焼成結果を示すアルキは下記
の通りである。In addition, in Table 4, the alkyls showing the firing results are as follows.
ア：第３図の如く、絵の具とガラス繊維が溶は合い、色
ガラス層を形成。A: As shown in Figure 3, the paint and glass fiber melt together to form a colored glass layer.
イ：第４図の如く、セラミックス繊維が混在し、た和紙
調風合の色ガラス層を形成。A: As shown in Figure 4, ceramic fibers are mixed to form a colored glass layer with a Japanese paper-like texture.
つ：第５図の如く、透明ガラス繊維が混在した柔らかな
凹凸を有する色ガラス層を形
成。1: As shown in Figure 5, a colored glass layer with soft irregularities in which transparent glass fibers are mixed is formed.
工：第６図の如く、やや釉薬層に沈み込んだ色ガラス層
を形成。Technique: As shown in Figure 6, a colored glass layer is formed that is slightly submerged in the glaze layer.
オニ第７図の如く、やや釉薬層に沈み込んだセラミック
ス繊維が混在した和紙調風合の色ガラス層を形成。As shown in Figure 7, a colored glass layer with a Japanese paper-like texture is formed with a mixture of ceramic fibers slightly submerged in the glaze layer.
カニ色着せガラス又はステンドガラス調の色ガラス層を
形成。Forms a colored glass layer that looks like crab-colored tinted glass or stained glass.
キ：昇温時にシートが捲れ上がり原型を留めないやや黒
変化（ガラス層中に炭素が残留）した色ガラス層を形成
。K: The sheet curls up when the temperature rises, forming a colored glass layer that does not retain its original shape and has a slight blackening (carbon remains in the glass layer).
第４表より、本発明の窯業製品の装飾材料によれば、著
しく優れた装飾性を有する多種多様な装飾面が得られる
ことが明らかである。From Table 4, it is clear that the decorative material for ceramic products of the present invention provides a wide variety of decorative surfaces with extremely excellent decorative properties.
［発明の効果］
以上詳述した通り、本発明の窯業製品の装飾材料によれ
ば、
■ 窯業製品の表面に均一な比較的広い面積で厚みのあ
る美麗な色ガラス層を容易に形成することができる。[Effects of the Invention] As detailed above, according to the decorative material for ceramic products of the present invention, ■ it is possible to easily form a thick, beautiful colored glass layer over a uniform, relatively wide area on the surface of the ceramic product; I can do it.
■ ちぎり貼り、切り抜も・貼り、重ね貼り等により、
ちぎり絵、モザイク、ステンドガラス等の風合の装飾効
果が得られる。■ By tearing and pasting, cutting out and pasting, layering, etc.
Decorative effects with textures such as chigiri-e, mosaic, and stained glass can be obtained.
■ 無機質粉末及び無機質ｗＡ維の配合比率により、七
宝焼、和紙等の様々な風合の装飾効果が得られる。■ Depending on the blending ratio of inorganic powder and inorganic wA fiber, decorative effects with various textures such as cloisonné, Japanese paper, etc. can be obtained.
■ ペーパー状シートとすることができるので、印刷や
塗装等の彩色を族１ノで用いることができる。■ Since it can be made into a paper-like sheet, coloring such as printing and painting can be used in Group 1.
等の従来にない趣き豊かな装飾が可能とされる。It is said that it is possible to create rich and unique decorations that have never been seen before.
第１図は末完用の一実施例に係る窯業製品の装飾材料の
拡大断面図、第２図は本発明の窯業製品の装飾材料の装
飾方法を説明する断面図、第３図、第４図、第５図、第
６図及び第７図は、各々、本発明の窯業製品の装飾材料
による焼成装飾部分を示す断面図である。
１・・・窯業製品の装飾材料、
２・・・無機質粉末、 ３・・・無機質！ａｆ＋ａ
、４・・・有機質繊維、 ５・・・素地層、６・・・
釉薬層、 ７・・・接着剤層、１１．１３Ａ、
１３Ｂ、１４．１５
・・・色ガラス層。FIG. 1 is an enlarged cross-sectional view of a decorative material for a ceramic product according to an embodiment of the present invention, FIG. 2 is a cross-sectional view explaining a method for decorating a decorative material for a ceramic product of the present invention, 5, 6, and 7 are sectional views each showing a fired decorative portion made of a decorative material of a ceramic product of the present invention. 1... Decorative material for ceramic products, 2... Inorganic powder, 3... Inorganic! af+a
, 4... Organic fiber, 5... Base layer, 6...
Glaze layer, 7... Adhesive layer, 11.13A,
13B, 14.15...Colored glass layer.
Claims (7)
重量部を含む混合物を抄造してなることを特徴とする窯
業製品の装飾材料。(1) Inorganic powder 100. Weight parts and artificial fibers 5-40
A decorative material for ceramic products, characterized in that it is made by paper-making a mixture containing parts by weight.
を特徴とする特許請求の範囲第１項に記載の装飾材料。(2) The decorative material according to claim 1, wherein the inorganic powder is a paint for decorating ceramic products.
ることを特徴とする特許請求の範囲第１項又は第２項に
記載の装飾材料。(3) The decorative material according to claim 1 or 2, wherein the artificial fiber is an inorganic fiber and/or an organic fiber.
あることを特徴とする特許請求の範囲第３項に記載の装
飾材料。(4) The decorative material according to claim 3, wherein the inorganic fiber is glass fiber or ceramic fiber.
る特許請求の範囲第３項に記載の装飾材料。(5) The decorative material according to claim 3, wherein the organic fiber is a synthetic resin fiber.
ることを特徴とする特許請求の範囲第１項ないし第５項
のいずれか１項に記載の装飾材料。(6) The decorative material according to any one of claims 1 to 5, wherein the ceramic product is ceramic, glass, or enamel.
許請求の範囲第１項ないし第６項のいずれか１項に記載
の装飾材料。(7) The decorative material according to any one of claims 1 to 6, which is in the form of a paper-like sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7457189A JPH02252677A (en) | 1989-03-27 | 1989-03-27 | Decorative material for ceramic product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7457189A JPH02252677A (en) | 1989-03-27 | 1989-03-27 | Decorative material for ceramic product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02252677A true JPH02252677A (en) | 1990-10-11 |
Family
ID=13551021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7457189A Pending JPH02252677A (en) | 1989-03-27 | 1989-03-27 | Decorative material for ceramic product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02252677A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020090755A (en) * | 2018-12-07 | 2020-06-11 | イビデン株式会社 | Glass particle-machined sheet, metal base bearing coat layer, and manufacturing method of metal base bearing coat layer |
-
1989
- 1989-03-27 JP JP7457189A patent/JPH02252677A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020090755A (en) * | 2018-12-07 | 2020-06-11 | イビデン株式会社 | Glass particle-machined sheet, metal base bearing coat layer, and manufacturing method of metal base bearing coat layer |
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