JP7354455B2 - エチレンビニルアルコール共重合体のアセタール化物および該アセタール化物を含む組成物 - Google Patents
エチレンビニルアルコール共重合体のアセタール化物および該アセタール化物を含む組成物 Download PDFInfo
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- JP7354455B2 JP7354455B2 JP2022543160A JP2022543160A JP7354455B2 JP 7354455 B2 JP7354455 B2 JP 7354455B2 JP 2022543160 A JP2022543160 A JP 2022543160A JP 2022543160 A JP2022543160 A JP 2022543160A JP 7354455 B2 JP7354455 B2 JP 7354455B2
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- JP
- Japan
- Prior art keywords
- vinyl alcohol
- acetalized
- acetalized product
- mass
- ethylene vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000219 Ethylene vinyl alcohol Polymers 0.000 title claims description 378
- 239000000203 mixture Substances 0.000 title claims description 122
- 229920005989 resin Polymers 0.000 claims description 189
- 239000011347 resin Substances 0.000 claims description 189
- 239000011148 porous material Substances 0.000 claims description 119
- 239000005340 laminated glass Substances 0.000 claims description 106
- 238000006359 acetalization reaction Methods 0.000 claims description 98
- 239000006185 dispersion Substances 0.000 claims description 59
- 238000004519 manufacturing process Methods 0.000 claims description 52
- 239000011521 glass Substances 0.000 claims description 43
- 239000004014 plasticizer Substances 0.000 claims description 42
- 239000005977 Ethylene Substances 0.000 claims description 41
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 40
- 239000011229 interlayer Substances 0.000 claims description 35
- 239000000178 monomer Substances 0.000 claims description 31
- 239000002904 solvent Substances 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 28
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 27
- 239000010410 layer Substances 0.000 claims description 25
- 238000002844 melting Methods 0.000 claims description 23
- 230000008018 melting Effects 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 19
- 238000004128 high performance liquid chromatography Methods 0.000 claims description 19
- 239000003963 antioxidant agent Substances 0.000 claims description 14
- 230000007423 decrease Effects 0.000 claims description 13
- 230000009477 glass transition Effects 0.000 claims description 13
- 238000004458 analytical method Methods 0.000 claims description 11
- 239000013078 crystal Substances 0.000 claims description 9
- 230000004927 fusion Effects 0.000 claims description 9
- 238000005192 partition Methods 0.000 claims description 9
- 239000003480 eluent Substances 0.000 claims description 8
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 8
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 2
- 239000000047 product Substances 0.000 description 299
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 179
- 238000000034 method Methods 0.000 description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 75
- -1 vinyl acetal resin Chemical compound 0.000 description 62
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 54
- 230000000052 comparative effect Effects 0.000 description 53
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 40
- 230000035515 penetration Effects 0.000 description 35
- 150000001241 acetals Chemical group 0.000 description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 32
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 32
- 239000008188 pellet Substances 0.000 description 29
- 150000001299 aldehydes Chemical class 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 230000005484 gravity Effects 0.000 description 27
- 238000005259 measurement Methods 0.000 description 25
- 238000003756 stirring Methods 0.000 description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- 239000007787 solid Substances 0.000 description 24
- 238000012360 testing method Methods 0.000 description 24
- 239000002245 particle Substances 0.000 description 21
- 239000002994 raw material Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- 238000005406 washing Methods 0.000 description 20
- 238000010583 slow cooling Methods 0.000 description 18
- 238000003860 storage Methods 0.000 description 16
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 14
- 239000000654 additive Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 13
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- 230000001112 coagulating effect Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical compound CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 description 10
- 229920006324 polyoxymethylene Polymers 0.000 description 10
- 229920001451 polypropylene glycol Polymers 0.000 description 10
- 229920002554 vinyl polymer Polymers 0.000 description 10
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical group CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000001291 vacuum drying Methods 0.000 description 9
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- 229920001577 copolymer Polymers 0.000 description 8
- 150000002148 esters Chemical group 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 230000003472 neutralizing effect Effects 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 7
- 239000002530 phenolic antioxidant Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000011354 acetal resin Substances 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
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- 239000000123 paper Substances 0.000 description 6
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
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- 150000003839 salts Chemical class 0.000 description 5
- 238000007127 saponification reaction Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
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- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
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- 229920001155 polypropylene Polymers 0.000 description 4
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- 239000011342 resin composition Substances 0.000 description 4
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- 239000010959 steel Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 102100021202 Desmocollin-1 Human genes 0.000 description 3
- 101000968043 Homo sapiens Desmocollin-1 Proteins 0.000 description 3
- 101000880960 Homo sapiens Desmocollin-3 Proteins 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
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- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
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- 239000004611 light stabiliser Substances 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
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- 239000004417 polycarbonate Substances 0.000 description 3
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- 239000004711 α-olefin Substances 0.000 description 3
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- FJJYHTVHBVXEEQ-UHFFFAOYSA-N 2,2-dimethylpropanal Chemical compound CC(C)(C)C=O FJJYHTVHBVXEEQ-UHFFFAOYSA-N 0.000 description 2
- BYGQBDHUGHBGMD-UHFFFAOYSA-N 2-methylbutanal Chemical compound CCC(C)C=O BYGQBDHUGHBGMD-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UMVMVEZHMZTUHD-UHFFFAOYSA-N DL-Propylene glycol dibenzoate Chemical compound C=1C=CC=CC=1C(=O)OC(C)COC(=O)C1=CC=CC=C1 UMVMVEZHMZTUHD-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 2
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- 238000002834 transmittance Methods 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- XUHUMYVYHLHMCD-UHFFFAOYSA-N tris(2-cyclohexylphenyl) phosphite Chemical compound C1CCCCC1C1=CC=CC=C1OP(OC=1C(=CC=CC=1)C1CCCCC1)OC1=CC=CC=C1C1CCCCC1 XUHUMYVYHLHMCD-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- WRSPWQHUHVRNFV-UHFFFAOYSA-N tris[3,5-di(nonyl)phenyl] phosphite Chemical compound CCCCCCCCCC1=CC(CCCCCCCCC)=CC(OP(OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)=C1 WRSPWQHUHVRNFV-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F216/04—Acyclic compounds
- C08F216/06—Polyvinyl alcohol ; Vinyl alcohol
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- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B32B17/10605—Type of plasticiser
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- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
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JP2011057737A (ja) | 2009-09-07 | 2011-03-24 | Denki Kagaku Kogyo Kk | シート |
JP2017115076A (ja) | 2015-12-25 | 2017-06-29 | 株式会社クラレ | バリア用コーティング剤 |
JP2018109173A (ja) | 2016-12-28 | 2018-07-12 | 日本合成化学工業株式会社 | エチレン−ビニルアルコール系共重合体ペレットおよび、共役ポリエンおよびホウ素化合物を含有するエチレン−ビニルアルコール系共重合体ペレットの製造方法 |
WO2018180073A1 (ja) | 2017-03-28 | 2018-10-04 | 積水化学工業株式会社 | 蓄電デバイス電極用バインダー |
WO2020196186A1 (ja) | 2019-03-28 | 2020-10-01 | 株式会社クラレ | 合わせガラスの中間膜用変性ビニルアセタール樹脂 |
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JPH0625005B2 (ja) | 1986-09-22 | 1994-04-06 | 株式会社クラレ | 安全合せガラス用中間膜組成物 |
JPS6474201A (en) * | 1987-09-11 | 1989-03-20 | Kuraray Co | Manufacture of acetalized ethylene/vinyl alcohol copolymer |
JP4082780B2 (ja) | 1998-04-08 | 2008-04-30 | 日本合成化学工業株式会社 | 樹脂組成物の製造法 |
EP1759832A1 (en) | 1998-05-14 | 2007-03-07 | E.I.Du pont de nemours and company | Glass laminates for threat resistant window systems |
DE19951444A1 (de) | 1999-10-25 | 2001-04-26 | Huels Troisdorf | Verfahren und Folie zur Herstellung von Verbundsicherheitsscheiben |
JP4953528B2 (ja) | 2000-08-07 | 2012-06-13 | 株式会社クラレ | エチレン−ビニルアルコール共重合体含水組成物の製造方法 |
DE10150091A1 (de) | 2001-10-11 | 2003-04-17 | Huels Troisdorf | PVB-Folie für Verbundsicherheitsglas und Verbundsicherheitsglas |
JP4794121B2 (ja) | 2002-07-23 | 2011-10-19 | 株式会社クラレ | インキまたは塗料用バインダー |
JP2021067287A (ja) | 2019-10-18 | 2021-04-30 | 株式会社山田製作所 | バランサー装置 |
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JP2010168444A (ja) | 2009-01-21 | 2010-08-05 | Sekisui Chem Co Ltd | ポリビニルアセタール樹脂多孔質体の製造方法 |
JP2011057737A (ja) | 2009-09-07 | 2011-03-24 | Denki Kagaku Kogyo Kk | シート |
JP2017115076A (ja) | 2015-12-25 | 2017-06-29 | 株式会社クラレ | バリア用コーティング剤 |
JP2018109173A (ja) | 2016-12-28 | 2018-07-12 | 日本合成化学工業株式会社 | エチレン−ビニルアルコール系共重合体ペレットおよび、共役ポリエンおよびホウ素化合物を含有するエチレン−ビニルアルコール系共重合体ペレットの製造方法 |
WO2018180073A1 (ja) | 2017-03-28 | 2018-10-04 | 積水化学工業株式会社 | 蓄電デバイス電極用バインダー |
WO2020196186A1 (ja) | 2019-03-28 | 2020-10-01 | 株式会社クラレ | 合わせガラスの中間膜用変性ビニルアセタール樹脂 |
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CN117157334A (zh) | 2023-12-01 |
JP2023143915A (ja) | 2023-10-06 |
WO2022220085A1 (ja) | 2022-10-20 |
KR20230169157A (ko) | 2023-12-15 |
TW202307025A (zh) | 2023-02-16 |
EP4324859A1 (en) | 2024-02-21 |
JPWO2022220085A1 (zh) | 2022-10-20 |
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