JP5922801B2 - 金属および樹脂を一体成形する方法および該方法によって得られる金属−樹脂複合構造 - Google Patents
金属および樹脂を一体成形する方法および該方法によって得られる金属−樹脂複合構造 Download PDFInfo
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- JP5922801B2 JP5922801B2 JP2014556903A JP2014556903A JP5922801B2 JP 5922801 B2 JP5922801 B2 JP 5922801B2 JP 2014556903 A JP2014556903 A JP 2014556903A JP 2014556903 A JP2014556903 A JP 2014556903A JP 5922801 B2 JP5922801 B2 JP 5922801B2
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- 238000001746 injection moulding Methods 0.000 claims description 17
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
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- 239000004698 Polyethylene Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
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- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
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- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
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- 229910052742 iron Inorganic materials 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Description
A)金属シートの表面にナノ細孔を形成する工程と、
B)前記ナノ細孔を有して形成された前記金属シートの前記表面に熱可塑性樹脂を溶融し、ついで、前記金属シートの前記表面に前記熱可塑性樹脂を射出成形する工程と、を含み、
前記熱可塑性樹脂が主樹脂とポリオレフィン樹脂との混合物であり、前記主樹脂がポリフェニレンオキシドとポリアミドとの混合物であり、かつ、前記ポリオレフィン樹脂が約65℃以上約105℃以下の融点を有する。
A)金属シートの表面にナノ細孔を形成する工程と、
B)ナノ細孔を有して形成された金属シートの表面に熱可塑性樹脂を溶融し、ついで、金属シートの表面に熱可塑性樹脂を射出成形する工程と、を含み、
熱可塑性樹脂が主樹脂とポリオレフィン樹脂との混合物であり、主樹脂はポリフェニレンオキシドとポリアミドとの混合物であり、かつ、ポリオレフィン樹脂は約65℃以上約105℃以下の融点を有する。
(1)前処理
厚さ1mmの市販されているA5052アルミニウム合金板が18mm×45mmの矩形のシートに切断され、ついで、そのシートが40g/Lの水酸化ナトリウム水溶液に浸漬された。水酸化ナトリウム水溶液の温度は40℃であった。1分後、矩形のシートは水洗いされ、乾燥され、前処理されたアルミニウム合金シートが得られた。
それぞれのアルミニウム合金シートが、20重量%の硫酸溶液を含む陽極酸化処理槽に陽極として配置され、アルミニウム合金が、10分間にわたって、20ボルトの電圧、18℃で電解された。ついで、アルミニウム合金シートがブロー乾燥された。
温度が20℃で10重量%の500mlの炭酸ナトリウム溶液(pH=12)がビーカーに用意された。ステップ(2)の後のアルミニウム合金シートが炭酸ナトリウム溶液に浸漬され、5分後に引き上げられ、水を含むビーカーに配置され、1分間にわたって浸漬された。5サイクルの後、最後の水への浸漬の後に、アルミニウム合金シートがブロー乾燥された。
61重量部のポリフェニレンオキシドPPO(China Bluestar Chengrand Chemical Co.,Ltd.から市販されているPPO LXR040)と、30重量部のポリアミドPA(China Pingmei Shenma Groupから市販されているEPR27)と、1重量部の流動性改良剤、すなわち環状ポリエステル(CBT100)と、8重量部の融点が65℃のグラフトポリエチレン(Arkema Groupから市販されているLotader AX8900)とが計量され、均一に混合されて、樹脂混合物が得られた。ついで、射出成形機を用いて、ステップ(3)の後のアルミニウム合金シートの表面に、溶融された樹脂混合物が射出成形され、本実施例における金属−樹脂複合構造S1が得られた。
本実施例における金属−樹脂複合構造S2は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本実施例における金属−樹脂複合構造S3は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本実施例における金属−樹脂複合構造S4は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本例における金属−樹脂複合構造DS1は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本例における金属−樹脂複合構造DS2は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本例における金属−樹脂複合構造DS3は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
本例における金属−樹脂複合構造DS4は、以下の例外を除いて、実施例1における方法とおおよそ同じ方法によって準備された。
1)金属−樹脂複合構造S1〜S4およびDS1〜DS4が引張試験のために万能試験機に固定され、それぞれの最大荷重が得られた。試験結果が表1に示された。
本出願は、2012年2月24日に中華人民共和国国家知識産権局に出願された中国特許出願番号第201210043648.8号明細書に基づく優先権およびその利益を主張し、その全体が参照によって本明細書に包含される。
Claims (11)
- 金属と樹脂とを一体成形する方法であって、
A)金属シートの表面にナノ細孔を形成する工程と、
B)前記ナノ細孔を有して形成された前記金属シートの前記表面に熱可塑性樹脂を溶融し、ついで、前記金属シートの前記表面に前記熱可塑性樹脂を射出成形する工程と、
を含み、
前記熱可塑性樹脂が主樹脂とポリオレフィン樹脂との混合物であり、前記主樹脂がポリフェニレンオキシドとポリアミドとの混合物であり、かつ、前記ポリオレフィン樹脂が約65℃以上約105℃以下の融点を有する、
ことを特徴とする方法。 - 工程A)において、金属シートの表面にナノ細孔を形成する工程が、前記金属シートの前記表面に酸化層を形成するように前記金属シートの前記表面を陽極酸化処理する工程を含み、前記酸化層が前記ナノ細孔を有して形成される、
ことを特徴とする請求項1に記載の方法。 - 前記酸化層が、約1μm以上約10μm以下の厚さを有し、前記ナノ細孔が、約10nm以上約100nm以下の細孔径と、約0.5μm以上約9.5μm以下の深さと、を有する、
ことを特徴とする請求項2に記載の方法。 - 前記金属シートの前記表面を陽極酸化処理する工程が、
約10重量%以上約30重量%以下の濃度の硫酸溶液に前処理された金属シートを陽極として配置する工程と、
前記金属シートの前記表面に約1μm以上約10μm以下の厚さの前記酸化層を形成するように、約1分間以上約40分間以下にわたって、約10ボルト以上約100ボルト以下の電圧で、約10℃以上約30℃以下の温度で前記金属を電解する工程と、
を含む、ことを特徴とする請求項2に記載の方法。 - 工程A)において、金属シートの表面にナノ細孔を形成する工程が、
前記酸化層の外表面に腐食孔を形成するように、その表面に前記酸化層を有して形成された前記金属シートをエッチング液に浸漬する工程をさらに含む、
ことを特徴とする請求項2に記載の方法。 - 前記腐食孔が前記ナノ細孔と連通され、前記腐食孔が、約200nm以上約2000nm以下の細孔径と、約0.5μm以上約9.5μm以下の深さと、を有する、
ことを特徴とする請求項5に記載の方法。 - 前記エッチング液が、前記酸化層を腐食する溶液である、
ことを特徴とする請求項5に記載の方法。 - 前記熱可塑性樹脂の100重量部を基準として、前記主樹脂の量が約70重量部以上約95重量部以下であり、前記ポリオレフィン樹脂の量が約5重量部以上約30重量部以下である、
ことを特徴とする請求項1に記載の方法。 - 前記熱可塑性樹脂の100重量部を基準として、前記熱可塑性樹脂が約1重量部以上約5重量部以下の流動性改良剤をさらに含有し、前記流動性改良剤が環状ポリエステルである、
ことを特徴とする請求項8に記載の方法。 - 前記主樹脂において、ポリフェニレンオキシドとポリアミドとの重量比が、約3:1から約1:3の間である、
ことを特徴とする請求項1または8に記載の方法。 - 前記金属が、アルミニウム、ステンレス鋼およびマグネシウムからなる群から選択される少なくとも一つである、
ことを特徴とする請求項1に記載の方法。
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