JP5847334B2 - 導電性コーティングを有する透明ガラスペイン - Google Patents
導電性コーティングを有する透明ガラスペイン Download PDFInfo
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- JP5847334B2 JP5847334B2 JP2014551540A JP2014551540A JP5847334B2 JP 5847334 B2 JP5847334 B2 JP 5847334B2 JP 2014551540 A JP2014551540 A JP 2014551540A JP 2014551540 A JP2014551540 A JP 2014551540A JP 5847334 B2 JP5847334 B2 JP 5847334B2
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- 238000000576 coating method Methods 0.000 title claims description 136
- 239000011248 coating agent Substances 0.000 title claims description 132
- 239000011521 glass Substances 0.000 title claims description 121
- 239000010410 layer Substances 0.000 claims description 447
- 239000000463 material Substances 0.000 claims description 60
- 239000000758 substrate Substances 0.000 claims description 58
- 239000002346 layers by function Substances 0.000 claims description 46
- 230000006978 adaptation Effects 0.000 claims description 43
- 239000003989 dielectric material Substances 0.000 claims description 31
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 29
- 229910052709 silver Inorganic materials 0.000 claims description 24
- 239000004332 silver Substances 0.000 claims description 24
- 150000004767 nitrides Chemical class 0.000 claims description 19
- 229920001169 thermoplastic Polymers 0.000 claims description 19
- 239000004416 thermosoftening plastic Substances 0.000 claims description 18
- 239000005340 laminated glass Substances 0.000 claims description 17
- 230000003667 anti-reflective effect Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 239000011787 zinc oxide Substances 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 230000003287 optical effect Effects 0.000 claims description 13
- UVGLBOPDEUYYCS-UHFFFAOYSA-N silicon zirconium Chemical compound [Si].[Zr] UVGLBOPDEUYYCS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 10
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 10
- 238000002834 transmittance Methods 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 23
- 229910052782 aluminium Inorganic materials 0.000 description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 22
- 230000005540 biological transmission Effects 0.000 description 13
- 238000004544 sputter deposition Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 239000004020 conductor Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 238000000151 deposition Methods 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 229910052718 tin Inorganic materials 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 238000007639 printing Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000000903 blocking effect Effects 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 229910052787 antimony Inorganic materials 0.000 description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 229910052726 zirconium Inorganic materials 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000005329 float glass Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000012495 reaction gas Substances 0.000 description 5
- 238000005452 bending Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012799 electrically-conductive coating Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000005349 heatable glass Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
- H05B3/86—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields the heating conductors being embedded in the transparent or reflecting material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3668—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties
- C03C17/3673—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties specially adapted for use in heating devices for rear window of vehicles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/0014—Devices wherein the heating current flows through particular resistances
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/009—Heaters using conductive material in contact with opposing surfaces of the resistive element or resistive layer
- H05B2203/01—Heaters comprising a particular structure with multiple layers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/011—Heaters using laterally extending conductive material as connecting means
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/013—Heaters using resistive films or coatings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/017—Manufacturing methods or apparatus for heaters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49082—Resistor making
- Y10T29/49083—Heater type
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
- Joining Of Glass To Other Materials (AREA)
Description
− 上記の導電性コーティングは、上下に重なって配置される少なくとも2つの機能層を有しており、各機能層には、少なくとも
− 反射防止層と、
− この反射防止層の上方の第1適合化層と、
− この第1適合化層の上方の導電層と
が含まれており、
また
− 少なくとも1つの機能層には、1つの反射防止層が含まれており、この反射防止層には少なくとも
− 2.1未満の屈折率を有する誘電性材料層と、
− 2.1以上の屈折率を有する光学的高屈折材料層とが含まれている。
(a) 反射防止層と、
(b) 第1適合化層と、
(c) 導電層とを
載置し、少なくとも1つの反射防止層を載置するため、少なくとも
− 2.1よりも小さい屈折率を有する誘電体材料層と、
− 2.1以上の屈折率を有する光学的高屈折材料層と
を載置する。
− 反射防止層4(4.1および4.2)と、
− 第1適合化層6(6.1および6.2)と、
− 導電層7(7.1および7.2)と、
− 第2適合化層8(8.1および8.2)と
が含まれている。
− 反射防止層4(4.1,4.2および4.3)と、
− 平坦化層5(5.1,5.2および5.3)と、
− 第1適合化層6(6.1,6.2および6.3)と、
− 導電層7(7.1,7.2および7.3)と、
− ブロック層11(11.1,11.2および11.3)と、
− 第2適合化層8(8.1,8.2および8.3)と
が含まれている。
ここでは、導電性コーティングを有する本発明による透明ガラスペインを作製した。透明基板1をコーティングした後、導電性コーティング2のシート抵抗を測定した。導電性コーティング2を施した透明基板1を、引き続いて約650℃の温度で曲げた。この曲げプロセスは約10分かかった。引き続いて熱可塑性中間層17を介し、各透明基板1と、同様に曲げられた第2のガラスペイン12とを約140℃の温度および約12barの圧力で積層した。ここで導電性コーティング2を熱可塑性中間層17側に配置した。
上記の複数の例と同様にこの比較例を実施した。違いは導電性コーティング2にある。2つの導電層間に配置された反射防止層には1つずつの誘電体層だけが含まれている。窒化ケイ素ベースのこのような誘電体層は、従来技術から公知である。上記の最も上および最も下にある反射防止層には、アルミニウムをドーピングしたケイ素・ジルコニウム窒化物が含まれている。本発明による例1ないし3と、一層良好に比較できるようにするため、各導電層の上側にはNiCrを含むブロック層を配置し、また最も下にある機能層には、アンチモンをドーピングしたスズ亜鉛混合酸化物を含む平坦化層が含まれている。銀を含むこれらの導電層の層厚は、本発明の例1ないし3とまったく同様に選択した。この比較例の層厚および材料を有する詳しい層の列は、表2に示されている。
Claims (19)
- 少なくとも1つの透明基板(1)と、当該透明基板(1)の少なくとも1つの表面上の少なくとも1つの導電性コーティング(2)とを含む透明ガラスペインにおいて、
− 前記導電性コーティング(2)は、上下に重なって配置される少なくとも2つの機能層(3)を有しており、各機能層(3)には、少なくとも
・ 反射防止層(4)と、
・ 当該反射防止層(4)の上方の第1適合化層(6)と、
・ 当該第1適合化層(6)の上方の導電層(7)と
が含まれており、
前記透明ガラスペインではさらに
− 前記2つの導電層(7)の間に前記反射防止層(4)のうちの少なくとも1つが配置されており、当該少なくとも1つの反射防止層(4)は、少なくとも
2.1よりも小さい屈折率を有し、少なくとも酸化スズ及び/又は窒化ケイ素が含まれる誘電体材料層(9)と、
2.1以上の屈折率を有し、少なくとも1つのケイ素・金属混合窒化物が含まれる光学的高屈折材料層(10)とを有する、
ことを特徴とする透明ガラスペイン。 - 請求項1に記載の透明ガラスペインにおいて、
前記導電性コーティング(2)は、電気的に加熱可能なコーティングである、
ことを特徴とする透明ガラスペイン。 - 請求項1に記載の透明ガラスペインにおいて、
前記導電性コーティング(2)は、赤外領域に対して反射特性を有するコーティングである、
ことを特徴とする透明ガラスペイン。 - 請求項1から3までのいずれか1項に記載の透明ガラスペインにおいて、
最も上にある機能層(3)の上方に別の反射防止層(4)が配置されている、
ことを特徴とする透明ガラスペイン。 - 請求項4に記載の透明ガラスペインにおいて、
前記別の反射防止層(4)および前記反射防止層(4)のうち最も下にある反射防止層(4)は、2.1以上の屈折率を有する光学的高屈折材料層として構成されており、かつ、ケイ素・金属混合窒化物を含んでいる、
ことを特徴とする透明ガラスペイン。 - 請求項1から5までのいずれか1項に記載の透明ガラスペインにおいて、
前記光学的高屈折材料層(10)の厚さは、当該光学的高屈折材料層(10)を含む前記反射防止層(4)の厚さの25%ないし75%である、
ことを特徴とする透明ガラスペイン。 - 請求項1から6までのいずれか1項に記載の透明ガラスペインにおいて、
2つの導電層(7)間に配置される各反射防止層(4)には、2.1よりも小さい屈折率を有する少なくとも1つの誘電体材料層(9)と、2.1以上の屈折率を有する少なくとも1つの光学的高屈折材料層(10)とが含まれている、
ことを特徴とする透明ガラスペイン。 - 請求項1から7までのいずれか1項に記載の透明ガラスペインにおいて、
2つの導電層(7)に配置される前記反射防止層(4)の厚さは、35nmないし70nmである、
ことを特徴とする透明ガラスペイン。 - 請求項1から8までのいずれか1項に記載の透明ガラスペインにおいて、
前記光学的高屈折材料層(10)には、少なくとも1つのケイ素・ジルコニウム混合窒化物が含まれる、
ことを特徴とする透明ガラスペイン。 - 請求項1から9までのいずれか1項に記載の透明ガラスペインにおいて、
各機能層(3)には、前記導電層(7)の上方に第2適合化層(8)が含まれている、
ことを特徴とする透明ガラスペイン。 - 請求項1から10までのいずれか1項に記載の透明ガラスペインにおいて、
各機能層(3)は、前記第1適合化層(6)の下方に平坦化層(5)を含んでいる、
ことを特徴とする透明ガラスペイン。 - 請求項11に記載の透明ガラスペインにおいて、
前記平坦化層(5)には、少なくとも1つの非晶質酸化物が含まれており、前記平坦化層(5)は3nmないし20nmの層厚を有する、
ことを特徴とする透明ガラスペイン。 - 請求項1から12までのいずれか1項に記載の透明ガラスペインにおいて、
前記導電層(7)には、少なくとも銀または銀を含有する合金が含まれており、
前記導電層(7)は、8nmないし25nmの層厚を有する、
ことを特徴とする透明ガラスペイン。 - 請求項1から13までのいずれか1項に記載の透明ガラスペインにおいて、
前記第1適合化層(6)および/または前記第2適合化層(8)には、酸化亜鉛ZnO1−δ、ただし0≦δ≦0.01が含まれており、
前記第1適合化層(6)および/または前記第2適合化層(8)は、3nmないし20nmの厚さを有する、
ことを特徴とする透明ガラスペイン。 - 請求項1から14までのいずれか1項に記載の透明ガラスペインにおいて、
各機能層(3)には少なくとも1つのブロック層(11)が含まれており、
該ブロック層(11)は、前記導電層(7)の直上および/または直下に配置されており、かつ、少なくともニオブ、チタン、ニッケル、クロムまたはこれらの合金を含んでおり、かつ、0.1nmないし2nmの層厚を有する、
ことを特徴とする透明ガラスペイン。 - 請求項1から15までのいずれか1項に記載の透明ガラスペインにおいて、
前記導電性コーティング(2)は、1オーム/スクエアより小さいシート抵抗を有する、
ことを特徴とする透明ガラスペイン。 - 請求項1から16までのいずれか1項に記載の透明ガラスペインにおいて、
前記透明基板(1)は、少なくとも1つの熱可塑性中間層(17)を介して第2のガラスペイン(12)と接合されて1つの合わせガラスを構成しており、
当該合わせガラスの全体透過率は70%を上回る、
ことを特徴とする透明ガラスペイン。 - 請求項1から17までのいずれか1項に記載の、導電性コーティング(2)を有する透明ガラスペインを製造する方法において、
少なくとも2つの機能層(3)を順次に透明基板(1)に載置し、かつ、各機能層(3)を順次に載置するため、少なくとも
(a) 反射防止層(4)と、
(b) 第1適合化層(6)と、
(c) 導電層(7)と
を載置し、反射防止層(4)のうち、前記2つの導電層(7)の間に配置される少なくとも1つの反射防止層(4)を載置するため、少なくとも
− 2.1よりも小さい屈折率を有し、少なくとも酸化スズ及び/又は窒化ケイ素が含まれる、誘電体材料層(9)と、
− 2.1以上の屈折率を有し、少なくとも1つのケイ素・金属混合窒化物が含まれる、光学的高屈折材料層(10)と
を載置する、
ことを特徴とする、
透明ガラスペインを製造する方法。 - 建築物または陸上、空中または水上水中交通用の輸送手段におけるガラスペインの構成部分としてまたはガラスペインとして、請求項1から17までのいずれか1項に記載の透明ガラスペインを使用する方法。
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2012
- 2012-10-04 EP EP12766998.4A patent/EP2803245B1/de active Active
- 2012-10-04 US US14/358,683 patent/US9215760B2/en active Active
- 2012-10-04 BR BR112014011760-8A patent/BR112014011760B1/pt active IP Right Grant
- 2012-10-04 PT PT127669984T patent/PT2803245T/pt unknown
- 2012-10-04 CN CN201280066218.6A patent/CN104025704B/zh active Active
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- 2012-10-04 WO PCT/EP2012/069567 patent/WO2013104439A1/de active Application Filing
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EP2803245A1 (de) | 2014-11-19 |
PL2803245T3 (pl) | 2017-08-31 |
WO2013104439A1 (de) | 2013-07-18 |
ES2621478T3 (es) | 2017-07-04 |
EP2803245B1 (de) | 2017-03-08 |
KR101589854B1 (ko) | 2016-01-28 |
KR20140099548A (ko) | 2014-08-12 |
JP2015507600A (ja) | 2015-03-12 |
US9215760B2 (en) | 2015-12-15 |
BR112014011760A2 (pt) | 2017-05-02 |
US20140319116A1 (en) | 2014-10-30 |
EA201491350A1 (ru) | 2014-10-30 |
MX2014008356A (es) | 2014-10-06 |
EA027187B1 (ru) | 2017-06-30 |
CN104025704B (zh) | 2016-10-12 |
PT2803245T (pt) | 2017-05-22 |
CN104025704A (zh) | 2014-09-03 |
BR112014011760B1 (pt) | 2021-01-19 |
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