JP5743546B2 - 不飽和炭化水素の水素化触媒およびこの調製プロセス - Google Patents
不飽和炭化水素の水素化触媒およびこの調製プロセス Download PDFInfo
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- JP5743546B2 JP5743546B2 JP2010529409A JP2010529409A JP5743546B2 JP 5743546 B2 JP5743546 B2 JP 5743546B2 JP 2010529409 A JP2010529409 A JP 2010529409A JP 2010529409 A JP2010529409 A JP 2010529409A JP 5743546 B2 JP5743546 B2 JP 5743546B2
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- 239000003054 catalyst Substances 0.000 title claims description 180
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 19
- 229930195735 unsaturated hydrocarbon Natural products 0.000 title claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 120
- 239000011148 porous material Substances 0.000 claims description 70
- 229910052759 nickel Inorganic materials 0.000 claims description 51
- 239000000243 solution Substances 0.000 claims description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 35
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 31
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 21
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 15
- 239000000395 magnesium oxide Substances 0.000 claims description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 238000009826 distribution Methods 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000012266 salt solution Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- DGXKDBWJDQHNCI-UHFFFAOYSA-N dioxido(oxo)titanium nickel(2+) Chemical compound [Ni++].[O-][Ti]([O-])=O DGXKDBWJDQHNCI-UHFFFAOYSA-N 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 3
- 235000019792 magnesium silicate Nutrition 0.000 claims description 3
- 229910001453 nickel ion Inorganic materials 0.000 claims description 3
- IOKPLNQRQWZPGF-UHFFFAOYSA-N nickel(2+);oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[Ni+2].[Zr+4] IOKPLNQRQWZPGF-UHFFFAOYSA-N 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000006722 reduction reaction Methods 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 description 31
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 26
- 238000003756 stirring Methods 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000012065 filter cake Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229910001868 water Inorganic materials 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 229910001960 metal nitrate Inorganic materials 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- FMQXRRZIHURSLR-UHFFFAOYSA-N dioxido(oxo)silane;nickel(2+) Chemical compound [Ni+2].[O-][Si]([O-])=O FMQXRRZIHURSLR-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 239000011164 primary particle Substances 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- -1 silicon dioxide compound Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- RNAMYOYQYRYFQY-UHFFFAOYSA-N 2-(4,4-difluoropiperidin-1-yl)-6-methoxy-n-(1-propan-2-ylpiperidin-4-yl)-7-(3-pyrrolidin-1-ylpropoxy)quinazolin-4-amine Chemical compound N1=C(N2CCC(F)(F)CC2)N=C2C=C(OCCCN3CCCC3)C(OC)=CC2=C1NC1CCN(C(C)C)CC1 RNAMYOYQYRYFQY-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-OUBTZVSYSA-N nickel-60 atom Chemical compound [60Ni] PXHVJJICTQNCMI-OUBTZVSYSA-N 0.000 description 1
- PXHVJJICTQNCMI-AKLPVKDBSA-N nickel-62 Chemical compound [62Ni] PXHVJJICTQNCMI-AKLPVKDBSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/866—Nickel and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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Description
撹拌器を取り付けた加熱可能な沈殿容器に水5lを入れ、それから酸化チタンを硫酸チタニル酸性溶液の形で加える。この溶液を撹拌しながら温度80℃から90℃に加熱する。この温度に到達したら、金属硝酸塩溶液と沈殿剤水溶液を平行して加え始める。金属硝酸塩溶液は、ニッケルの他にマグネシウム、アルミニウム、およびクロムを含有する。沈殿剤溶液は、ソーダ(Na2CO3)の他に、溶解した二酸化ケイ素化合物を含有する。沈殿させている間、pH値は8から8.5で一定に保つ。沈殿時間およびその後の撹拌時間はそれぞれ2時間である。
加熱可能な沈殿容器に水15lを入れ、それからSiO2成分としての珪藻土および固形TiO2(P25、Degussa Co.)を撹拌しながら加える。続いて水酸化ナトリウム水溶液(10%)を加える。溶液を85℃に加熱した後、混合金属硝酸塩溶液(ニッケルイオン、アルミニウムイオン、マグネシウムイオン、およびクロムイオンを含有)を計量しながら加える。ニッケル対SiO2、Al2O3、MgO、TiO2、Cr2O3、およびZnOのモル比は、1:0.4:0.038:0.05:0.016:0.004:0.006である。
加熱可能な沈殿容器に水10lを入れ、それからアルミン酸ナトリウム溶液(40gのAl2O3/l溶液、100gのNaOH/l)および水ガラス溶液(50gのSiO2/l溶液)を撹拌しながら加える。この溶液を90℃から95℃に加熱してから、ニッケル硝酸塩と、マグネシウム硝酸塩と、ジルコニウム硝酸塩との水溶液を、pH値の上限8.5で、計量しながら加える。金属硝酸塩溶液は、硫酸チタニル溶液の形でTiO2をさらに含有する。pH値が約8.5に到達したら、残りのニッケル硝酸塩溶液およびNaOH水溶液(10%)を温度90℃から95℃で平行して加え始める。沈殿時間は1時間、続く撹拌時間は約2時間である。
加熱可能な沈殿容器に水5lおよび固形TiO2(P25、Degussa Co.)を入れ、それから懸濁液を撹拌しながら温度90℃から95℃に加熱する。この温度に達したら、混合金属硝酸塩溶液(ニッケル、アルミニウム、およびマグネシウムを硝酸塩の形で含有)およびアルカリ溶液(沈殿剤ソーダおよび溶解したSiO2化合物の水溶液である)を平行して加える。沈殿させている間、pH値は、8.0から8.3で一定に調整される。沈殿およびその後の撹拌時間はそれぞれ約2時間である。
沈殿容器に水8lと硫酸チタニルを入れ、それから、ナトリウム水ガラス溶液を撹拌しながら30分間以内で加える。加えている間、所望の沈殿温度90℃に加熱する。この温度に達したら、ニッケル硝酸塩と、マグネシウム硝酸塩と、およびアルミニウム硝酸塩との混合溶液を加えてpH値を約8にし、それから混合物をさらに30分撹拌する。その後、水酸化ナトリウム溶液(150g/l)および残りの金属硝酸塩溶液を平行して計量しながら加えて、沈殿プロセスを続ける。沈殿させている間、温度は90℃で一定である。沈殿時間および続く撹拌時間はそれぞれ約1時間である。ニッケル対SiO2、Al2O3、MgO、およびTiO2のモル比は、1:0.65:0.038:0.05:0.016である。
沈殿容器に水10lを入れ、撹拌しながら80℃に加熱した。その後、一定温度80℃で撹拌しながら、混合金属硝酸塩溶液(ニッケル1.4kg、MgO0.050kg、Al2O30.050kg、およびFe0.0056kgを含有)とソーダ/水ガラス溶液(ソーダ2.9kgおよびSiO20.345kgを含有)を、平行して加えた。沈殿させている間のpH値は7.5であった。沈殿プロセスは1時間後に完了した。沈殿完了後、懸濁液を濾過して洗った。それから、得られたフィルターケーキを110℃で乾燥し、細かく粉砕して、350℃で焼成した。流動相中、温度400℃で、遊離触媒物質の還元を行った。触媒を窒素/空気混合物中で安定化した後、完成した触媒は以下の組成を有した:ニッケル60%、SiO218%、Al2O32.7%、MgO2%、およびFe2O30.3%。
水10l、および実施例6で用いたものと同じ組成のソーダ/水ガラス溶液を容器に入れて80℃に加熱した。その後、撹拌しながら一定温度80℃で、混合金属硝酸塩溶液(ニッケル1.4kg、Al2O30.050kg、およびFe0.0056kgを含有)を加えた。1時間の沈殿時間後、沈殿懸濁液のpH値は7.3であった。沈殿スラリーを濾過し、洗い、それから市販の噴霧乾燥機に噴霧した。噴霧した顆粒の平均粒子サイズは約10μmであった。焼成、還元、および安定化は、流動相で行った。
乾燥して粉砕したNi/SiO2出発物質(平均粒子サイズ10μmおよび容積密度0.7kg/l)を結合剤としてのタイローズ(tylose)と混合し、コンデンセート水、硝酸、およびシリカゾルの溶液を加えて実験用混練機で分散した。この混練機のバッチの固形分に基づいて、加えたタイローズの量は2.5%であった。15分の混練時間後、全バッチ分を、切断デバイスを備えた実験用押出機で3mmの円筒状に押出し成形した。得られた湿潤押出し物を実験用整粒機(Caleva Co.,Model 120,England)でさらに加工処理して球状にした。それから、得られた球状物質を130℃で乾燥した。
以下の表1は、以下の比較分析に用いた、本発明による触媒と比較の触媒の組成を示す。
反応圧:30bar
反応温度:85℃、反応時間:40時間
100℃、反応時間:80時間
LHSV:1.3
気体対生成物比:400lのH2/lのケロセン
結果を表3に示す。
Claims (14)
- シリカ担持ニッケル触媒であって、ニッケル含量が40から85重量%であり(NiOとして計算)、ケイ素含量が15から60重量%であり(SiO2として計算)、チタン含量が0.5から5.0重量%であり(TiO2として計算)、鉄を0.20重量%より多くは含有せず(Feとして計算)、該触媒の成分は全体で100重量%を越えないように選択され、単峰性Ni微結晶サイズ分布を有し、還元した触媒の平均微結晶サイズが1.5から3.5nmであり、少なくとも0.60ml/gの細孔容積を有し、直径10nm以上の細孔の細孔容積の割合が少なくとも55%である、不飽和炭化水素の水素化触媒。
- 触媒のニッケルの還元レベルは52から80%であり、当該ニッケルの還元レベルは、金属ニッケル対全ニッケルの比で表される、請求項1に記載の触媒。
- アルミニウム含量が2から10重量%である(Al2O3として計算)、請求項1または2に記載の触媒。
- マグネシウム含量が0.1から3.0重量%である(MgOとして計算)、請求項1から3のいずれか一項に記載の触媒。
- 亜鉛含量が0.1から4.0重量%である(ZnOとして計算)、請求項1から4のいずれか一項に記載の触媒。
- クロム含量が0.1から0.3重量%である(Cr2O3として計算)、請求項1から5のいずれか一項に記載の触媒。
- ジルコニウム含量が0.1から3.0重量%である(ZrO2として計算)、請求項1から6のいずれか一項に記載の触媒。
- 粉末化触媒でありこの細孔容積が少なくとも0.68ml/gであるか、造形触媒であり直径10nm以上の細孔の細孔容積の割合が少なくとも65%である、請求項1から7のいずれか一項に記載の触媒。
- シリカ担体は、ケイ酸マグネシウム、アルモシリケート、TiO2、チタン酸ニッケル、二酸化ジルコニウム、ジルコン酸ニッケル、およびZnOからなる群より選択される化合物をさらに1種以上含有する、請求項1から8のいずれか一項に記載の触媒。
- ニッケルイオン源およびチタンイオン源を含むが鉄を実質的に含まない金属塩溶液を、ナトリウム水ガラス溶液と、pH8から9.5および温度70℃から100℃で反応させて、触媒物質を共沈させ、共沈した触媒物質を回収してシリカ担持ニッケル触媒を得、次いで乾燥、焼成、および還元すること、を含む、請求項1から9のいずれか一項に記載のシリカ担持ニッケル触媒の調製プロセス。
- 金属塩溶液は、Ni2+と、TiO2+と、ならびにAl3+、Cr3+、Mg2+、Zn2+、およびZrO2+から選択される1種以上のイオンとを含む、請求項10に記載のプロセス。
- ナトリウム水ガラス溶液はAl(OH)4 −、TiO2、ZnO、またはZrO2を含む、請求項10または11に記載のプロセス。
- 適した反応条件下、不飽和炭化水素を加えて、請求項1から9のいずれか一項に記載の触媒の少なくとも1つと接触させ、水素化した炭化水素を得る、不飽和炭化水素の水素化プロセス。
- 不飽和炭化水素は芳香族化合物である、請求項13に記載の不飽和炭化水素の水素化プロセス。
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FR3022160B1 (fr) | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 et 300 nm et son utilisation en hydrogenation |
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FR3104462B1 (fr) | 2019-12-17 | 2022-06-10 | Ifp Energies Now | Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique |
EP3903926A1 (en) * | 2020-04-30 | 2021-11-03 | Basf Se | Catalytic material comprising ni supported on an oxidic support comprising zr and si |
CN113181923A (zh) * | 2021-05-12 | 2021-07-30 | 湘潭大学 | 共沉淀制备NiZnTi催化剂的方法及其在硝基芳烃或卤代硝基芳烃加氢反应中的应用 |
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EP2203250B1 (en) | 2015-04-08 |
CN101827652B (zh) | 2013-01-02 |
WO2009050292A3 (en) | 2009-12-17 |
CN101827652A (zh) | 2010-09-08 |
US20130303812A1 (en) | 2013-11-14 |
US8518851B2 (en) | 2013-08-27 |
US8841498B2 (en) | 2014-09-23 |
JP2011500313A (ja) | 2011-01-06 |
WO2009050292A2 (en) | 2009-04-23 |
US20100280294A1 (en) | 2010-11-04 |
EP2203250A2 (en) | 2010-07-07 |
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