JP5702469B2 - 液体洗浄組成物 - Google Patents
液体洗浄組成物 Download PDFInfo
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- JP5702469B2 JP5702469B2 JP2013529400A JP2013529400A JP5702469B2 JP 5702469 B2 JP5702469 B2 JP 5702469B2 JP 2013529400 A JP2013529400 A JP 2013529400A JP 2013529400 A JP2013529400 A JP 2013529400A JP 5702469 B2 JP5702469 B2 JP 5702469B2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
本発明に従う組成物は、様々な無生物表面用のクリーナーとして設計される。
本明細書に記載の液体洗浄組成物は、堅果の殻又は他の植物部分の剪断及び/又は磨砕により形成される研磨性洗浄粒子を含む。他の植物部分とは、限定するものではないが、茎、根、葉、種、根、及びこれらの混合物を意味する。本発明の組成物に含まれる研磨性洗浄粒子は、木材を使用して製造してもよい。
Gretag Macbeath 7000 a color−eye装置を用い、欧州西部及び北部の昼間のおおよその日光を表す「D65」光源により白色度(L*)を測定した。
本発明の組成物は、目的とする技術的効果及び処理される表面に応じて、種々の任意成分を含んでもよい。
本発明の組成物中に存在する研磨性洗浄粒子は固体粒子であり、液体組成物中に含まれる。上記研磨性洗浄粒子は液体組成物中に懸濁していてもよい。しかしながら、このような研磨性洗浄粒子が、組成物に不安定に懸濁されたり、沈降又は最上部に浮遊するということは、充分本発明の範囲内のことである。この場合には、使用者は、使用前に組成物を揺動(例えば、振盪又は撹拌)することにより、研磨性洗浄粒子を一時的に懸濁させなければならないこともある。
本明細書に記載の組成物は、任意ではあるが、極めて好ましい成分として有機溶媒又はこれらの混合物を含む。
本明細書での組成物は、非イオン性、アニオン性、双極性、両性、カチオン性の界面活性剤、又はこれらの混合物を含み得る。好適な界面活性剤は、8〜20個の炭素原子を含有する疎水性鎖を有する、非イオン性、アニオン性、双極性、カチオン性、及び両性の界面活性剤からなる群から選択されるものである。好適な界面活性剤の例は、McCutcheon’s Vol.1:Emulsifiers and Detergents,North American Ed.,McCutcheon Division,MC Publishing Co.,2002に記載されている。
R1−[CO−X(CH2)n]x−N+(R2)(R3)−(CH2)m−[CH(OH)−CH2]y−Y−(I)
(式中、R1は飽和又は不飽和C6〜22アルキル残基であり、好ましくはC8〜18アルキル残基、特に飽和C10〜16アルキル残基、例えば、飽和C12〜14アルキル残基であり、
XはNH、C1〜4のアルキル残基R4を有するNR4、O又はSであり、
nは1〜10の数であり、好ましくは2〜5、特に3であり、
xは0又は1であり、好ましくは1であり、
R2、R3は独立して、ヒドロキシエチル、好ましくはメチルなどの、ヒドロキシ置換される可能性のあるC1〜4アルキル残基であり、
mは1〜4の数であり、特に1、2又は3であり、
yは0又は1であり、
YはCOO、SO3、OPO(OR5)O又はP(O)(OR5)Oであり、R5は水素原子Hであるか又はC1〜4アルキル残基である。
R1−N+(CH3)2−CH2COO- (Ia)
R1−CO−NH(CH2)3−N+(CH3)2−CH2COO- (Ib)
R1−N+(CH3)2−CH2CH(OH)CH2SO3− Ic)
R1−CO−NH−(CH2)3−N+(CH3)2−CH2CH(OH)CH2SO3− (Id)
式中、R1は式Iの場合と同じものを意味する)。特に好ましいベタインは、カルボベタイン[式中、Y-=COO-]であり、特に式(Ia)及び式(Ib)のカルボベタイン、より好ましくは、式(Ib)のアルキルアミドベタインである。
本明細書での使用のための1つの類の任意の化合物としては、キレート剤又はこれらの混合物が挙げられる。キレート剤は、本明細書に記載の組成物中に組成物全体の0.0重量%〜10.0重量%、好ましくは0.01重量%〜約5.0重量%の範囲の量で組み込み可能である。
本発明の組成物は更に、ラジカルスカベンジャー又はその混合物を含んでもよい。
本明細書における使用に好適な香料化合物及び香料組成物は、例えば、欧州特許出願第0 957 156号の、13ページの表題「Perfume」の項に記載されているものである。本明細書に記載の組成物は、香料成分、又はその混合物を、組成物全体の最大5.0重量%の量で、好ましくは0.1重量%〜1.5重量%の量で含み得る。
本発明による液体組成物は着色していてもよい。したがって、それらの組成物は、染料、又はその混合物を含み得る。
本発明に従う液体組成物には、天然の研磨材から発生し得る微生物の増殖を予防するために、保存料を含有させてもよい。
本明細書に記載の組成物は、液体組成物を注ぐためのプラスチック瓶、搾り出し式瓶又は液体組成物をスプレーするための引き金式噴霧器を備えた瓶など、当該技術分野では既知の様々な好適なパッケージングに包装され得る。あるいは、本発明によるペースト様組成物をチューブに包装してもよい。
本発明は、本発明の液体組成物により表面を洗浄する方法を包含する。本明細書における好適な表面は、上記の「液体洗浄組成物」の項で説明されている。
Claims (12)
- 研磨剤として被覆された洗浄粒子を含む液体洗浄組成物であって、前記被覆された洗浄粒子は、被覆された堅果の殻の粒子、他の植物及び野菜の部分に由来する被覆された粒子、被覆された木材粒子、及びこれらの混合物からなる群から選択され、前記被覆された洗浄粒子の被覆材料層は、ホワイトニング顔料及びキャリアを含有し、前記顔料は二酸化チタン、カオリン、金属炭酸塩及びこれらの混合物からなる群から選択され、前記キャリアはワックスから選択され、前記被覆された研磨洗浄粒子が、D 65光源下で測定した場合に65を超える白色度(L*)を有する、液体洗浄組成物。
- 堅果の殻の粒子が、ピスタチオナッツの殻の粒子、クルミの殻の粒子、アーモンドの殻の粒子及びこれらの混合物からなる群から選択される、請求項1に記載の液体洗浄組成物。
- 野菜粒子がコメ、トウモロコシ穂軸、ヤシバイオマス、竹、ケナフ、リンゴ種子、杏仁、オリーブの核、及びこれらの混合物に由来する、請求項1に記載の液体洗浄組成物。
- 前記被覆材料層が、1μm〜40μmである、請求項1〜3のいずれか一項に記載の液体洗浄組成物。
- 前記組成物は懸濁助剤を更に含み、前記懸濁助剤が、ポリカルボキシレートポリマー増粘剤、カルボキシメチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシメチルセルロース、スクシノグリカン、及びキサンタンガム、ゲランガム、グアーガム、イナゴマメガム、トラガカントガム、スクシノグルカンガム、若しくはこれらの誘導体のような天然起源の多糖ポリマー、又はこれらの混合物からなる群から選択される、請求項1〜4のいずれか一項に記載の液体洗浄組成物。
- 前記組成物が、前記組成物の0.1重量%〜20重量%の被覆されたクルミ粒子を含む、請求項1〜5のいずれか一項に記載の液体洗浄組成物。
- 前記組成物が、6〜8のpHを有する、請求項1〜6のいずれか一項に記載の液体洗浄組成物。
- 前記研磨性粒子が、ISO 9276−6に従い、10〜1000μmの円相当径により表される平均粒径を有する、請求項1〜7のいずれか一項に記載の液体洗浄組成物。
- 水の組成が、総液体組成物の30重量%超である、請求項1〜8のいずれか一項に記載の液体洗浄組成物。
- 前記洗浄組成物が、洗浄基材上に装填され、前記基材が、紙若しくは不織布のタオル又は拭き取り布、あるいはスポンジである、請求項1〜9のいずれか一項に記載の液体洗浄組成物。
- 請求項1〜10のいずれか一項に記載の液体洗浄組成物を使用して、表面を洗浄する方法であって、前記表面を前記組成物に接触させる、方法。
- 前記表面が、家庭用硬質表面、皿表面、皮革又は合成皮革のような表面、及び自動車車両表面からなる群から選択される無生物表面である、請求項11に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10177814 | 2010-09-21 | ||
EP10177814.0 | 2010-09-21 | ||
PCT/US2011/052251 WO2012040136A1 (en) | 2010-09-21 | 2011-09-20 | Liquid cleaning composition |
Publications (2)
Publication Number | Publication Date |
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JP2013542275A JP2013542275A (ja) | 2013-11-21 |
JP5702469B2 true JP5702469B2 (ja) | 2015-04-15 |
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Application Number | Title | Priority Date | Filing Date |
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JP2013529400A Expired - Fee Related JP5702469B2 (ja) | 2010-09-21 | 2011-09-20 | 液体洗浄組成物 |
Country Status (4)
Country | Link |
---|---|
US (1) | US8445422B2 (ja) |
EP (1) | EP2431453B1 (ja) |
JP (1) | JP5702469B2 (ja) |
WO (1) | WO2012040136A1 (ja) |
Cited By (1)
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2011
- 2011-09-20 JP JP2013529400A patent/JP5702469B2/ja not_active Expired - Fee Related
- 2011-09-20 US US13/236,678 patent/US8445422B2/en active Active
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JP2015512973A (ja) * | 2012-02-23 | 2015-04-30 | ザ プロクター アンド ギャンブルカンパニー | オリーブ仁由来の粉末研磨剤を有する液体洗浄組成物 |
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US8445422B2 (en) | 2013-05-21 |
EP2431453A1 (en) | 2012-03-21 |
WO2012040136A1 (en) | 2012-03-29 |
EP2431453B1 (en) | 2019-06-19 |
JP2013542275A (ja) | 2013-11-21 |
US20120071378A1 (en) | 2012-03-22 |
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